CN107118648A - A kind of new type environment friendly coating and preparation method thereof - Google Patents
A kind of new type environment friendly coating and preparation method thereof Download PDFInfo
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- CN107118648A CN107118648A CN201710537090.1A CN201710537090A CN107118648A CN 107118648 A CN107118648 A CN 107118648A CN 201710537090 A CN201710537090 A CN 201710537090A CN 107118648 A CN107118648 A CN 107118648A
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- environment friendly
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- friendly coating
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- 238000000576 coating method Methods 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 62
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 52
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 52
- 239000000843 powder Substances 0.000 claims abstract description 47
- 239000011248 coating agent Substances 0.000 claims abstract description 41
- 239000011032 tourmaline Substances 0.000 claims abstract description 41
- 229940070527 tourmaline Drugs 0.000 claims abstract description 41
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 41
- 239000000654 additive Substances 0.000 claims abstract description 35
- 230000000996 additive Effects 0.000 claims abstract description 35
- 239000000945 filler Substances 0.000 claims abstract description 34
- 239000002270 dispersing agent Substances 0.000 claims abstract description 33
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 29
- 239000000839 emulsion Substances 0.000 claims abstract description 28
- CWSZBVAUYPTXTG-UHFFFAOYSA-N 5-[6-[[3,4-dihydroxy-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxymethyl]-3,4-dihydroxy-5-[4-hydroxy-3-(2-hydroxyethoxy)-6-(hydroxymethyl)-5-methoxyoxan-2-yl]oxyoxan-2-yl]oxy-6-(hydroxymethyl)-2-methyloxane-3,4-diol Chemical compound O1C(CO)C(OC)C(O)C(O)C1OCC1C(OC2C(C(O)C(OC)C(CO)O2)OCCO)C(O)C(O)C(OC2C(OC(C)C(O)C2O)CO)O1 CWSZBVAUYPTXTG-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims abstract description 26
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims abstract description 26
- 235000019501 Lemon oil Nutrition 0.000 claims abstract description 26
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 26
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 26
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims abstract description 26
- 239000010501 lemon oil Substances 0.000 claims abstract description 26
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 26
- 239000003638 reducing agent Substances 0.000 claims abstract description 26
- 235000009566 rice Nutrition 0.000 claims abstract description 26
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 26
- 125000000129 anionic group Chemical group 0.000 claims abstract description 25
- 239000008367 deionised water Substances 0.000 claims abstract description 25
- 239000003822 epoxy resin Substances 0.000 claims abstract description 25
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 25
- VTHJTEIRLNZDEV-UHFFFAOYSA-L Magnesium hydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims abstract description 21
- 239000000347 magnesium hydroxide Substances 0.000 claims abstract description 21
- 229910001862 magnesium hydroxide Inorganic materials 0.000 claims abstract description 21
- GJRQTCIYDGXPES-UHFFFAOYSA-N Isobutyl acetate Chemical compound CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 230000000694 effects Effects 0.000 claims abstract description 10
- 239000000463 material Substances 0.000 claims abstract description 10
- 241000209094 Oryza Species 0.000 claims description 25
- 238000010438 heat treatment Methods 0.000 claims description 21
- 150000001450 anions Chemical class 0.000 claims description 15
- 239000004375 Dextrin Substances 0.000 claims description 14
- 229920001353 Dextrin Polymers 0.000 claims description 14
- 235000019425 dextrin Nutrition 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- -1 butyl ester Chemical class 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 8
- 238000000227 grinding Methods 0.000 claims description 8
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 8
- 238000007792 addition Methods 0.000 claims description 7
- 239000004744 fabric Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 238000001802 infusion Methods 0.000 claims description 7
- 150000002500 ions Chemical class 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 125000005372 silanol group Chemical group 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 6
- 235000019738 Limestone Nutrition 0.000 claims description 4
- QORWJWZARLRLPR-UHFFFAOYSA-H Tricalcium phosphate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 4
- 239000001506 calcium phosphate Substances 0.000 claims description 4
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 4
- 235000011010 calcium phosphates Nutrition 0.000 claims description 4
- 239000006028 limestone Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 3
- 239000010453 quartz Substances 0.000 claims description 3
- 229910052904 quartz Inorganic materials 0.000 claims description 3
- 239000011787 zinc oxide Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 210000000481 Breast Anatomy 0.000 claims 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000010703 silicon Substances 0.000 claims 2
- 239000004593 Epoxy Substances 0.000 claims 1
- 230000003213 activating Effects 0.000 claims 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims 1
- 125000003700 epoxy group Chemical group 0.000 claims 1
- 230000000844 anti-bacterial Effects 0.000 abstract description 4
- 238000005034 decoration Methods 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000010521 absorption reaction Methods 0.000 abstract description 3
- 230000000845 anti-microbial Effects 0.000 abstract description 3
- 240000007594 Oryza sativa Species 0.000 abstract 1
- 239000004575 stone Substances 0.000 description 7
- 238000001035 drying Methods 0.000 description 6
- 239000002736 nonionic surfactant Substances 0.000 description 6
- 238000001238 wet grinding Methods 0.000 description 6
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 5
- 229910052749 magnesium Inorganic materials 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- TZCXTZWJZNENPQ-UHFFFAOYSA-L Barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 3
- 239000010428 baryte Substances 0.000 description 3
- 229910052601 baryte Inorganic materials 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxyl anion Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000001684 chronic Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000000875 corresponding Effects 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 125000001997 phenyl group Chemical class [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of new type environment friendly coating, include the raw material of following parts by weight：20~40 parts of silicone acrylic emulsion, 15~25 parts of epoxy resin, 15~30 parts of glutinous rice, 10~20 parts of diatomite, 5~12 parts of hydroxyethyl cellulose, 3~6 parts of lemon oil, 5~7 parts of isobutyl ester, 3~8 parts of activated carbon, 4~9 parts of magnesium hydroxide, 5~18 parts of filler, 2~4 parts of titanium dioxide, 2~3 parts of defoamer, 1.5~2.5 parts of photostabilizer, 0.8~1.7 part of water reducer, 1~2 part of dispersant, 2~4 parts of tourmaline powder anionic additive, 15~45 parts of deionized water.The new type environment friendly coating is except possessing the decoration functions that common environmental protection coating material possesses, additionally it is possible to effectively realize antibacterial purpose, the anti-microbial property duration is long, effect stability, and possesses the function of absorption harmful substance, energy-conserving and environment-protective simultaneously.
Description
Technical field
The invention belongs to environment-friendly materials technical field, and in particular to a kind of new type environment friendly coating and preparation method thereof.
Background technology
Coating is to be coated in the body surface protected or decorated, and can be continuous thin with coated article formation firm attachment
Film, is typically based on resin or oil or emulsion, to add or without pigment, filler, add corresponding additive, use organic solvent
Or the thick liquid that water is formulated.With the raising of modern people's living standard, the Environmental Protection Level to fitment material for family will
Seek more and more higher.Existing decoration coating type is various, but many materials containing harmful to human, such as first in existing coating
Aldehyde, benzene class thing and heavy metal etc., these materials can have a strong impact on the living environment of people, and induce many chronic diseases,
The life and health of people is caused to be on the hazard.
The content of the invention
The invention provides a kind of new type environment friendly coating and preparation method thereof, the problem of solving in above-mentioned background technology,
The new type environment friendly coating is excellent except possessing the decoration functions that common environmental protection coating material possesses, performance, and stability is good, additionally it is possible to effectively
Antibacterial purpose is realized, the anti-microbial property duration is long, effect stability, and possess the function of absorption harmful substance, energy-saving ring simultaneously
Protect.
In order to solve the problem of prior art is present, adopt the following technical scheme that：
A kind of new type environment friendly coating, includes the raw material of following parts by weight：20~40 parts of silicone acrylic emulsion, 15~25 parts of epoxy resin,
15~30 parts of glutinous rice, 10~20 parts of diatomite, 5~12 parts of hydroxyethyl cellulose, 3~6 parts of lemon oil, 5~7 parts of isobutyl ester, work
3~8 parts of charcoal of property, 4~9 parts of magnesium hydroxide, 5~18 parts of filler, 2~4 parts of titanium dioxide, 2~3 parts of defoamer, photostabilizer 1.5~
2.5 parts, 0.8~1.7 part of water reducer, 1~2 part of dispersant, 2~4 parts of tourmaline powder anionic additive, deionized water 15~45
Part.
It is preferred that, the new type environment friendly coating includes the raw material of following parts by weight：25~35 parts of silicone acrylic emulsion, asphalt mixtures modified by epoxy resin
17~23 parts of fat, 18~27 parts of glutinous rice, 13~16 parts of diatomite, 9~11 parts of hydroxyethyl cellulose, 4~5 parts of lemon oil, isobutyl
5.2~6.3 parts of ester, 4~7 parts of activated carbon, 6~8 parts of magnesium hydroxide, 9~14 parts of filler, 2.6~3.4 parts of titanium dioxide, defoamer
2.1~2.8 parts, 1.9~2.3 parts of photostabilizer, 1.2~1.5 parts of water reducer, 1.3~1.6 parts of dispersant, tourmaline powder anion
2.3~3.5 parts of additive, 28~36 parts of deionized water.
It is preferred that, the new type environment friendly coating includes the raw material of following parts by weight：33 parts of silicone acrylic emulsion, epoxy resin 20
Part, 25 parts of glutinous rice, 14 parts of diatomite, 10 parts of hydroxyethyl cellulose, 4.3 parts of lemon oil, 6 parts of isobutyl ester, 5 parts of activated carbon, hydrogen-oxygen
Change 7 parts of magnesium, 12 parts of filler, 2.9 parts of titanium dioxide, 2.5 parts of defoamer, 2.2 parts of photostabilizer, 1.4 parts of water reducer, 1.5 parts of dispersant,
3 parts of tourmaline powder anionic additive, 30 parts of deionized water.
It is preferred that, the filler use lime stone, zinc oxide, barite, quartz, sericite or calcium phosphate in one kind or
Any several mixture.
It is preferred that, the photostabilizer is septichen phenyl ester.
It is preferred that, the dispersant is silanol class nonionic surfactant.
It is preferred that, the tourmaline powder anionic additive has following methods preparation：Electricity of the selection with negative ion effect
Gas stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, filtration material drying
Afterwards, the tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 80~90 DEG C of water-bath, is allowed to be gelatinized,
Dextrin is made；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, the heating stirring in 80~90 DEG C of water-bath
15~25 minutes, infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive are added, with 2000~3000r/
Min speed is scattered 10~20 minutes at a high speed；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 110~130 DEG C, stirred 5~10 minutes with 1100~1300r/min speed, be cooled to normal temperature, produce the novel environment friendly
Coating.
Compared with prior art, it has the advantages that the present invention：
New type environment friendly coating of the present invention possesses the decoration functions that common environmental protection coating material possesses, and performance is excellent, and stability is good, also
Antibacterial purpose can be effectively realized, the anti-microbial property duration is long, effect stability, and possess the work(of absorption harmful substance simultaneously
Can, energy-conserving and environment-protective, the preparation method is simple, environmentally safe, is adapted to promote, specific as follows：
（1）Environmental protection paint of the present invention by strictly controlling each raw material between proportioning and preparation process in technological parameter,
Add tourmaline powder anionic additive and activated carbon so that the environmental protection paint antibacterial effect substantially, and duration length, simultaneously
The harmful substances such as effective formaldehyde adsorption, protection is played a part of to surrounding environment and human body；
（2）New type environment friendly coating of the present invention as raw material, can improve the water resistance, stably of wallpaper using silicone acrylic emulsion
Property, heat resistance and film forming；The silicone acrylic emulsion, its stability is good, small, the stain resistance for the environmental protection coating material prepared of emulsion grain
It is good, there is excellent water resistance and dirt-resistant self-cleaning, excellent resistance to weathering into glued membrane, it is adaptable to inner wall of building.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：20 parts of silicone acrylic emulsion, epoxy resin 15
Part, 15 parts of glutinous rice, 10 parts of diatomite, 5 parts of hydroxyethyl cellulose, 3 parts of lemon oil, 5 parts of isobutyl ester, 3 parts of activated carbon, magnesium hydroxide
4 parts, 5 parts of filler, 2 parts of titanium dioxide, 2 parts of defoamer, 1.5 parts of photostabilizer, 0.8 part of water reducer, 1 part of dispersant, tourmaline powder bear
2 parts of ionic additive, 15 parts of deionized water.
Wherein, the filler is lime stone.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 80 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 15 points of heating stirring in 80 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 2000r/min speed at a high speed
It is scattered 10 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 110 DEG C, stirred 5 minutes with 1100r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 2
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：40 parts of silicone acrylic emulsion, epoxy resin 25
Part, 30 parts of glutinous rice, 20 parts of diatomite, 12 parts of hydroxyethyl cellulose, 6 parts of lemon oil, 7 parts of isobutyl ester, 8 parts of activated carbon, hydroxide
9 parts of magnesium, 18 parts of filler, 4 parts of titanium dioxide, 3 parts of defoamer, 2.5 parts of photostabilizer, 1.7 parts of water reducer, 2 parts of dispersant, tourmaline powder
4 parts of anionic additive, 45 parts of deionized water.
Wherein, the filler uses lime stone, the mixture of zinc oxide.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 90 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 25 points of heating stirring in 90 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 3000r/min speed at a high speed
It is scattered 20 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 130 DEG C, stirred 10 minutes with 1300r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 3
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：25 parts of silicone acrylic emulsion, epoxy resin 17
Part, 18 parts of glutinous rice, 13 parts of diatomite, 9 parts of hydroxyethyl cellulose, 4 parts of lemon oil, 5.2 parts of isobutyl ester, 4 parts of activated carbon, hydroxide
6 parts of magnesium, 9 parts of filler, 2.6 parts of titanium dioxide, 2.1 parts of defoamer, 1.9 parts of photostabilizer, 1.2 parts of water reducer, 1.3 parts of dispersant, electricity
2.3 parts of gas stone flour anionic additive, 28 parts of deionized water.
Wherein, the filler is barite.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 82 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 18 points of heating stirring in 82 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 2300r/min speed at a high speed
It is scattered 12 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 118 DEG C, stirred 7 minutes with 1150r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 4
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：35 parts of silicone acrylic emulsion, epoxy resin 23
Part, 27 parts of glutinous rice, 16 parts of diatomite, 11 parts of hydroxyethyl cellulose, 5 parts of lemon oil, 6.3 parts of isobutyl ester, 7 parts of activated carbon, hydrogen-oxygen
Change 8 parts of magnesium, 14 parts of filler, 3.4 parts of titanium dioxide, 2.8 parts of defoamer, 2.3 parts of photostabilizer, 1.5 parts of water reducer, 1.6 parts of dispersant,
3.5 parts of tourmaline powder anionic additive, 36 parts of deionized water.
Wherein, the filler is the mixture in sericite and calcium phosphate.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 87 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, the heating stirring in 80~90 DEG C of water-bath
23 minutes, infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive are added, with 2750r/min speed
It is scattered 13 minutes at a high speed；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 125 DEG C, stirred 9 minutes with 1250r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 5
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：33 parts of silicone acrylic emulsion, epoxy resin 20
Part, 25 parts of glutinous rice, 14 parts of diatomite, 10 parts of hydroxyethyl cellulose, 4.3 parts of lemon oil, 6 parts of isobutyl ester, 5 parts of activated carbon, hydrogen-oxygen
Change 7 parts of magnesium, 12 parts of filler, 2.9 parts of titanium dioxide, 2.5 parts of defoamer, 2.2 parts of photostabilizer, 1.4 parts of water reducer, 1.5 parts of dispersant,
3 parts of tourmaline powder anionic additive, 30 parts of deionized water.
Wherein, the filler is the mixture of barite, quartz, sericite and calcium phosphate.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 85 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 20 points of heating stirring in 85 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 2500r/min speed at a high speed
It is scattered 15 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 120 DEG C, stirred 7 minutes with 1200r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of new type environment friendly coating, it is characterised in that include the raw material of following parts by weight：20~40 parts of silicone acrylic emulsion, epoxy
It is 15~25 parts of resin, 15~30 parts of glutinous rice, 10~20 parts of diatomite, 5~12 parts of hydroxyethyl cellulose, 3~6 parts of lemon oil, different
5~7 parts of butyl ester, 3~8 parts of activated carbon, 4~9 parts of magnesium hydroxide, 5~18 parts of filler, 2~4 parts of titanium dioxide, 2~3 parts of defoamer,
1.5~2.5 parts of photostabilizer, 0.8~1.7 part of water reducer, 1~2 part of dispersant, 2~4 parts of tourmaline powder anionic additive, go
15~45 parts of ionized water.
2. new type environment friendly coating according to claim 1, it is characterised in that include the raw material of following parts by weight：The breast of silicon third
25~35 parts of liquid, 17~23 parts of epoxy resin, 18~27 parts of glutinous rice, 13~16 parts of diatomite, 9~11 parts of hydroxyethyl cellulose,
4~5 parts of lemon oil, 5.2~6.3 parts of isobutyl ester, 4~7 parts of activated carbon, 6~8 parts of magnesium hydroxide, 9~14 parts of filler, titanium dioxide
2.6~3.4 parts, 2.1~2.8 parts of defoamer, 1.9~2.3 parts of photostabilizer, 1.2~1.5 parts of water reducer, dispersant 1.3~1.6
Part, 2.3~3.5 parts of tourmaline powder anionic additive, 28~36 parts of deionized water.
3. new type environment friendly coating according to claim 1, it is characterised in that include the raw material of following parts by weight：The breast of silicon third
33 parts of liquid, 20 parts of epoxy resin, 25 parts of glutinous rice, 14 parts of diatomite, 10 parts of hydroxyethyl cellulose, 4.3 parts of lemon oil, isobutyl ester 6
Part, 5 parts of activated carbon, 7 parts of magnesium hydroxide, 12 parts of filler, 2.9 parts of titanium dioxide, 2.5 parts of defoamer, 2.2 parts of photostabilizer, water reducer
1.4 parts, 1.5 parts of dispersant, 3 parts of tourmaline powder anionic additive, 30 parts of deionized water.
4. new type environment friendly coating according to claim 1, it is characterised in that the filler is using lime stone, zinc oxide, again
One kind or any several mixture in spar, quartz, sericite or calcium phosphate.
5. new type environment friendly coating according to claim 1, it is characterised in that the photostabilizer is septichen benzene
Ester.
6. new type environment friendly coating according to claim 1, it is characterised in that the dispersant is silanol class non-ionic surface
Activating agent.
7. new type environment friendly coating according to claim 1, it is characterised in that the tourmaline powder anionic additive have with
It is prepared by lower section method：Tourmaline of the selection with negative ion effect, carries out attrition grinding, is then dispersed in water miberal powder, wet method
Grinding, with 1000 mesh filter-cloth filterings, after filtration material is dried, is made the tourmaline anion additive.
8. a kind of method for preparing any one of claim 1~7 new type environment friendly coating, it is characterised in that including following step
Suddenly：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 80~90 DEG C of water-bath, is allowed to be gelatinized,
Dextrin is made；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, the heating stirring in 80~90 DEG C of water-bath
15~25 minutes, infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive are added, with 2000~3000r/
Min speed is scattered 10~20 minutes at a high speed；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 110~130 DEG C, stirred 5~10 minutes with 1100~1300r/min speed, be cooled to normal temperature, produce the novel environment friendly
Coating.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108084869A (en) * | 2018-01-24 | 2018-05-29 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN108299877A (en) * | 2017-09-28 | 2018-07-20 | 马鞍山松鹤信息科技有限公司 | A kind of finishing special environment protection coating and its preparation process |
| CN109593412A (en) * | 2018-11-07 | 2019-04-09 | 泉州市东宝建材科技有限公司 | A kind of automatically cleaning exterior wall surface coating and preparation method thereof |
| CN109943172A (en) * | 2018-12-23 | 2019-06-28 | 朱进平 | A kind of aqueous silicon-acrylic coatings of compound resin base and preparation method thereof |
| CN110054939A (en) * | 2018-06-14 | 2019-07-26 | 金陵科技学院 | A kind of coating and preparation method thereof for historical relic's protection |
| CN110159148A (en) * | 2018-03-26 | 2019-08-23 | 浙江亿美达门业有限公司 | A kind of timber that moisture-proof, antibiotic effect is good |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802425A (en) * | 2016-04-06 | 2016-07-27 | 郜杰 | Environment-friendly and anti-bacterial interior wall coating containing shell powder |
| CN106479236A (en) * | 2016-11-03 | 2017-03-08 | 威海裕隆水产开发有限公司 | A kind of environmental protection coating material |
| CN106752494A (en) * | 2016-11-23 | 2017-05-31 | 温州兴南环保科技有限公司 | A kind of environmental protection coating material |
-
2017
- 2017-07-04 CN CN201710537090.1A patent/CN107118648A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802425A (en) * | 2016-04-06 | 2016-07-27 | 郜杰 | Environment-friendly and anti-bacterial interior wall coating containing shell powder |
| CN106479236A (en) * | 2016-11-03 | 2017-03-08 | 威海裕隆水产开发有限公司 | A kind of environmental protection coating material |
| CN106752494A (en) * | 2016-11-23 | 2017-05-31 | 温州兴南环保科技有限公司 | A kind of environmental protection coating material |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108299877A (en) * | 2017-09-28 | 2018-07-20 | 马鞍山松鹤信息科技有限公司 | A kind of finishing special environment protection coating and its preparation process |
| CN108084869A (en) * | 2018-01-24 | 2018-05-29 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN110159148A (en) * | 2018-03-26 | 2019-08-23 | 浙江亿美达门业有限公司 | A kind of timber that moisture-proof, antibiotic effect is good |
| CN110159148B (en) * | 2018-03-26 | 2020-08-11 | 浙江亿美达门业有限公司 | Wooden door with moisture-proof and antibacterial effects |
| CN110054939A (en) * | 2018-06-14 | 2019-07-26 | 金陵科技学院 | A kind of coating and preparation method thereof for historical relic's protection |
| CN109593412A (en) * | 2018-11-07 | 2019-04-09 | 泉州市东宝建材科技有限公司 | A kind of automatically cleaning exterior wall surface coating and preparation method thereof |
| CN109943172A (en) * | 2018-12-23 | 2019-06-28 | 朱进平 | A kind of aqueous silicon-acrylic coatings of compound resin base and preparation method thereof |
| CN110903708A (en) * | 2019-12-12 | 2020-03-24 | 广东长鑫环保科技有限公司 | Preparation method of plant coating capable of releasing small-particle-size negative ions |
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Application publication date: 20170901 |