CN107118648A - A kind of new type environment friendly coating and preparation method thereof - Google Patents
A kind of new type environment friendly coating and preparation method thereof Download PDFInfo
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- CN107118648A CN107118648A CN201710537090.1A CN201710537090A CN107118648A CN 107118648 A CN107118648 A CN 107118648A CN 201710537090 A CN201710537090 A CN 201710537090A CN 107118648 A CN107118648 A CN 107118648A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of new type environment friendly coating, include the raw material of following parts by weight：20~40 parts of silicone acrylic emulsion, 15~25 parts of epoxy resin, 15~30 parts of glutinous rice, 10~20 parts of diatomite, 5~12 parts of hydroxyethyl cellulose, 3~6 parts of lemon oil, 5~7 parts of isobutyl ester, 3~8 parts of activated carbon, 4~9 parts of magnesium hydroxide, 5~18 parts of filler, 2~4 parts of titanium dioxide, 2~3 parts of defoamer, 1.5~2.5 parts of photostabilizer, 0.8~1.7 part of water reducer, 1~2 part of dispersant, 2~4 parts of tourmaline powder anionic additive, 15~45 parts of deionized water.The new type environment friendly coating is except possessing the decoration functions that common environmental protection coating material possesses, additionally it is possible to effectively realize antibacterial purpose, the anti-microbial property duration is long, effect stability, and possesses the function of absorption harmful substance, energy-conserving and environment-protective simultaneously.
Description
Technical field
The invention belongs to environment-friendly materials technical field, and in particular to a kind of new type environment friendly coating and preparation method thereof.
Background technology
Coating is to be coated in the body surface protected or decorated, and can be continuous thin with coated article formation firm attachment
Film, is typically based on resin or oil or emulsion, to add or without pigment, filler, add corresponding additive, use organic solvent
Or the thick liquid that water is formulated.With the raising of modern people's living standard, the Environmental Protection Level to fitment material for family will
Seek more and more higher.Existing decoration coating type is various, but many materials containing harmful to human, such as first in existing coating
Aldehyde, benzene class thing and heavy metal etc., these materials can have a strong impact on the living environment of people, and induce many chronic diseases,
The life and health of people is caused to be on the hazard.
The content of the invention
The invention provides a kind of new type environment friendly coating and preparation method thereof, the problem of solving in above-mentioned background technology,
The new type environment friendly coating is excellent except possessing the decoration functions that common environmental protection coating material possesses, performance, and stability is good, additionally it is possible to effectively
Antibacterial purpose is realized, the anti-microbial property duration is long, effect stability, and possess the function of absorption harmful substance, energy-saving ring simultaneously
Protect.
In order to solve the problem of prior art is present, adopt the following technical scheme that：
A kind of new type environment friendly coating, includes the raw material of following parts by weight：20~40 parts of silicone acrylic emulsion, 15~25 parts of epoxy resin,
15~30 parts of glutinous rice, 10~20 parts of diatomite, 5~12 parts of hydroxyethyl cellulose, 3~6 parts of lemon oil, 5~7 parts of isobutyl ester, work
3~8 parts of charcoal of property, 4~9 parts of magnesium hydroxide, 5~18 parts of filler, 2~4 parts of titanium dioxide, 2~3 parts of defoamer, photostabilizer 1.5~
2.5 parts, 0.8~1.7 part of water reducer, 1~2 part of dispersant, 2~4 parts of tourmaline powder anionic additive, deionized water 15~45
Part.
It is preferred that, the new type environment friendly coating includes the raw material of following parts by weight：25~35 parts of silicone acrylic emulsion, asphalt mixtures modified by epoxy resin
17~23 parts of fat, 18~27 parts of glutinous rice, 13~16 parts of diatomite, 9~11 parts of hydroxyethyl cellulose, 4~5 parts of lemon oil, isobutyl
5.2~6.3 parts of ester, 4~7 parts of activated carbon, 6~8 parts of magnesium hydroxide, 9~14 parts of filler, 2.6~3.4 parts of titanium dioxide, defoamer
2.1~2.8 parts, 1.9~2.3 parts of photostabilizer, 1.2~1.5 parts of water reducer, 1.3~1.6 parts of dispersant, tourmaline powder anion
2.3~3.5 parts of additive, 28~36 parts of deionized water.
It is preferred that, the new type environment friendly coating includes the raw material of following parts by weight：33 parts of silicone acrylic emulsion, epoxy resin 20
Part, 25 parts of glutinous rice, 14 parts of diatomite, 10 parts of hydroxyethyl cellulose, 4.3 parts of lemon oil, 6 parts of isobutyl ester, 5 parts of activated carbon, hydrogen-oxygen
Change 7 parts of magnesium, 12 parts of filler, 2.9 parts of titanium dioxide, 2.5 parts of defoamer, 2.2 parts of photostabilizer, 1.4 parts of water reducer, 1.5 parts of dispersant,
3 parts of tourmaline powder anionic additive, 30 parts of deionized water.
It is preferred that, the filler use lime stone, zinc oxide, barite, quartz, sericite or calcium phosphate in one kind or
Any several mixture.
It is preferred that, the photostabilizer is septichen phenyl ester.
It is preferred that, the dispersant is silanol class nonionic surfactant.
It is preferred that, the tourmaline powder anionic additive has following methods preparation：Electricity of the selection with negative ion effect
Gas stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, filtration material drying
Afterwards, the tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 80~90 DEG C of water-bath, is allowed to be gelatinized,
Dextrin is made；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, the heating stirring in 80~90 DEG C of water-bath
15~25 minutes, infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive are added, with 2000~3000r/
Min speed is scattered 10~20 minutes at a high speed；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 110~130 DEG C, stirred 5~10 minutes with 1100~1300r/min speed, be cooled to normal temperature, produce the novel environment friendly
Coating.
Compared with prior art, it has the advantages that the present invention：
New type environment friendly coating of the present invention possesses the decoration functions that common environmental protection coating material possesses, and performance is excellent, and stability is good, also
Antibacterial purpose can be effectively realized, the anti-microbial property duration is long, effect stability, and possess the work(of absorption harmful substance simultaneously
Can, energy-conserving and environment-protective, the preparation method is simple, environmentally safe, is adapted to promote, specific as follows：
（1）Environmental protection paint of the present invention by strictly controlling each raw material between proportioning and preparation process in technological parameter,
Add tourmaline powder anionic additive and activated carbon so that the environmental protection paint antibacterial effect substantially, and duration length, simultaneously
The harmful substances such as effective formaldehyde adsorption, protection is played a part of to surrounding environment and human body；
（2）New type environment friendly coating of the present invention as raw material, can improve the water resistance, stably of wallpaper using silicone acrylic emulsion
Property, heat resistance and film forming；The silicone acrylic emulsion, its stability is good, small, the stain resistance for the environmental protection coating material prepared of emulsion grain
It is good, there is excellent water resistance and dirt-resistant self-cleaning, excellent resistance to weathering into glued membrane, it is adaptable to inner wall of building.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments be merely to illustrate the present invention and without
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：20 parts of silicone acrylic emulsion, epoxy resin 15
Part, 15 parts of glutinous rice, 10 parts of diatomite, 5 parts of hydroxyethyl cellulose, 3 parts of lemon oil, 5 parts of isobutyl ester, 3 parts of activated carbon, magnesium hydroxide
4 parts, 5 parts of filler, 2 parts of titanium dioxide, 2 parts of defoamer, 1.5 parts of photostabilizer, 0.8 part of water reducer, 1 part of dispersant, tourmaline powder bear
2 parts of ionic additive, 15 parts of deionized water.
Wherein, the filler is lime stone.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 80 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 15 points of heating stirring in 80 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 2000r/min speed at a high speed
It is scattered 10 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 110 DEG C, stirred 5 minutes with 1100r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 2
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：40 parts of silicone acrylic emulsion, epoxy resin 25
Part, 30 parts of glutinous rice, 20 parts of diatomite, 12 parts of hydroxyethyl cellulose, 6 parts of lemon oil, 7 parts of isobutyl ester, 8 parts of activated carbon, hydroxide
9 parts of magnesium, 18 parts of filler, 4 parts of titanium dioxide, 3 parts of defoamer, 2.5 parts of photostabilizer, 1.7 parts of water reducer, 2 parts of dispersant, tourmaline powder
4 parts of anionic additive, 45 parts of deionized water.
Wherein, the filler uses lime stone, the mixture of zinc oxide.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 90 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 25 points of heating stirring in 90 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 3000r/min speed at a high speed
It is scattered 20 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 130 DEG C, stirred 10 minutes with 1300r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 3
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：25 parts of silicone acrylic emulsion, epoxy resin 17
Part, 18 parts of glutinous rice, 13 parts of diatomite, 9 parts of hydroxyethyl cellulose, 4 parts of lemon oil, 5.2 parts of isobutyl ester, 4 parts of activated carbon, hydroxide
6 parts of magnesium, 9 parts of filler, 2.6 parts of titanium dioxide, 2.1 parts of defoamer, 1.9 parts of photostabilizer, 1.2 parts of water reducer, 1.3 parts of dispersant, electricity
2.3 parts of gas stone flour anionic additive, 28 parts of deionized water.
Wherein, the filler is barite.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 82 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 18 points of heating stirring in 82 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 2300r/min speed at a high speed
It is scattered 12 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 118 DEG C, stirred 7 minutes with 1150r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 4
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：35 parts of silicone acrylic emulsion, epoxy resin 23
Part, 27 parts of glutinous rice, 16 parts of diatomite, 11 parts of hydroxyethyl cellulose, 5 parts of lemon oil, 6.3 parts of isobutyl ester, 7 parts of activated carbon, hydrogen-oxygen
Change 8 parts of magnesium, 14 parts of filler, 3.4 parts of titanium dioxide, 2.8 parts of defoamer, 2.3 parts of photostabilizer, 1.5 parts of water reducer, 1.6 parts of dispersant,
3.5 parts of tourmaline powder anionic additive, 36 parts of deionized water.
Wherein, the filler is the mixture in sericite and calcium phosphate.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 87 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, the heating stirring in 80~90 DEG C of water-bath
23 minutes, infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive are added, with 2750r/min speed
It is scattered 13 minutes at a high speed；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 125 DEG C, stirred 9 minutes with 1250r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
Embodiment 5
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：33 parts of silicone acrylic emulsion, epoxy resin 20
Part, 25 parts of glutinous rice, 14 parts of diatomite, 10 parts of hydroxyethyl cellulose, 4.3 parts of lemon oil, 6 parts of isobutyl ester, 5 parts of activated carbon, hydrogen-oxygen
Change 7 parts of magnesium, 12 parts of filler, 2.9 parts of titanium dioxide, 2.5 parts of defoamer, 2.2 parts of photostabilizer, 1.4 parts of water reducer, 1.5 parts of dispersant,
3 parts of tourmaline powder anionic additive, 30 parts of deionized water.
Wherein, the filler is the mixture of barite, quartz, sericite and calcium phosphate.
Wherein, the photostabilizer is septichen phenyl ester.
Wherein, the dispersant is silanol class nonionic surfactant.
Wherein, the tourmaline powder anionic additive has following methods preparation：Selection is electric with negative ion effect
Stone, carries out attrition grinding, is then dispersed in water miberal powder, wet grinding, with 1000 mesh filter-cloth filterings, and filtration is expected after drying,
The tourmaline anion additive is made.
A kind of method for preparing the new type environment friendly coating, comprises the following steps：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 85 DEG C of water-bath, is allowed to be gelatinized, be made
Dextrin；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, 20 points of heating stirring in 85 DEG C of water-bath
Clock, adds infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive, with 2500r/min speed at a high speed
It is scattered 15 minutes；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 120 DEG C, stirred 7 minutes with 1200r/min speed, be cooled to normal temperature, produce the new type environment friendly coating.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of new type environment friendly coating, it is characterised in that include the raw material of following parts by weight：20~40 parts of silicone acrylic emulsion, epoxy
It is 15~25 parts of resin, 15~30 parts of glutinous rice, 10~20 parts of diatomite, 5~12 parts of hydroxyethyl cellulose, 3~6 parts of lemon oil, different
5~7 parts of butyl ester, 3~8 parts of activated carbon, 4~9 parts of magnesium hydroxide, 5~18 parts of filler, 2~4 parts of titanium dioxide, 2~3 parts of defoamer,
1.5~2.5 parts of photostabilizer, 0.8~1.7 part of water reducer, 1~2 part of dispersant, 2~4 parts of tourmaline powder anionic additive, go
15~45 parts of ionized water.
2. new type environment friendly coating according to claim 1, it is characterised in that include the raw material of following parts by weight：The breast of silicon third
25~35 parts of liquid, 17~23 parts of epoxy resin, 18~27 parts of glutinous rice, 13~16 parts of diatomite, 9~11 parts of hydroxyethyl cellulose,
4~5 parts of lemon oil, 5.2~6.3 parts of isobutyl ester, 4~7 parts of activated carbon, 6~8 parts of magnesium hydroxide, 9~14 parts of filler, titanium dioxide
2.6~3.4 parts, 2.1~2.8 parts of defoamer, 1.9~2.3 parts of photostabilizer, 1.2~1.5 parts of water reducer, dispersant 1.3~1.6
Part, 2.3~3.5 parts of tourmaline powder anionic additive, 28~36 parts of deionized water.
3. new type environment friendly coating according to claim 1, it is characterised in that include the raw material of following parts by weight：The breast of silicon third
33 parts of liquid, 20 parts of epoxy resin, 25 parts of glutinous rice, 14 parts of diatomite, 10 parts of hydroxyethyl cellulose, 4.3 parts of lemon oil, isobutyl ester 6
Part, 5 parts of activated carbon, 7 parts of magnesium hydroxide, 12 parts of filler, 2.9 parts of titanium dioxide, 2.5 parts of defoamer, 2.2 parts of photostabilizer, water reducer
1.4 parts, 1.5 parts of dispersant, 3 parts of tourmaline powder anionic additive, 30 parts of deionized water.
4. new type environment friendly coating according to claim 1, it is characterised in that the filler is using lime stone, zinc oxide, again
One kind or any several mixture in spar, quartz, sericite or calcium phosphate.
5. new type environment friendly coating according to claim 1, it is characterised in that the photostabilizer is septichen benzene
Ester.
6. new type environment friendly coating according to claim 1, it is characterised in that the dispersant is silanol class non-ionic surface
Activating agent.
7. new type environment friendly coating according to claim 1, it is characterised in that the tourmaline powder anionic additive have with
It is prepared by lower section method：Tourmaline of the selection with negative ion effect, carries out attrition grinding, is then dispersed in water miberal powder, wet method
Grinding, with 1000 mesh filter-cloth filterings, after filtration material is dried, is made the tourmaline anion additive.
8. a kind of method for preparing any one of claim 1~7 new type environment friendly coating, it is characterised in that including following step
Suddenly：
（1）Silicone acrylic emulsion, epoxy resin, glutinous rice, diatomite, hydroxyethyl cellulose, lemon oil, isobutyl are weighed by above-mentioned formula
Ester, activated carbon, magnesium hydroxide, filler, titanium dioxide, defoamer, photostabilizer, water reducer, dispersant, the addition of tourmaline powder anion
Agent and deionized water, it is standby；
（2）Glutinous rice, diatomite, activated carbon, magnesium hydroxide, filler and titanium dioxide are put into stirrer for mixing uniformly, ground to form
Powder, crosses 100~200 mesh, plus deionized water, mixture is placed in into heating stirring in 80~90 DEG C of water-bath, is allowed to be gelatinized,
Dextrin is made；
（3）Hydroxyethyl cellulose, lemon oil and isobutyl ester are added in dextrin, the heating stirring in 80~90 DEG C of water-bath
15~25 minutes, infusion, photostabilizer, water reducer, dispersant and tourmaline powder anionic additive are added, with 2000~3000r/
Min speed is scattered 10~20 minutes at a high speed；
（4）To step（3）Silicone acrylic emulsion and epoxy resin are added in gained slurry, is well mixed, is added into reactor, heating
To 110~130 DEG C, stirred 5~10 minutes with 1100~1300r/min speed, be cooled to normal temperature, produce the novel environment friendly
Coating.
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108084869A (en) * | 2018-01-24 | 2018-05-29 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN108299877A (en) * | 2017-09-28 | 2018-07-20 | 马鞍山松鹤信息科技有限公司 | A kind of finishing special environment protection coating and its preparation process |
| CN109593412A (en) * | 2018-11-07 | 2019-04-09 | 泉州市东宝建材科技有限公司 | A kind of automatically cleaning exterior wall surface coating and preparation method thereof |
| CN109943172A (en) * | 2018-12-23 | 2019-06-28 | 朱进平 | A kind of aqueous silicon-acrylic coatings of compound resin base and preparation method thereof |
| CN110054939A (en) * | 2018-06-14 | 2019-07-26 | 金陵科技学院 | A kind of coating and preparation method thereof for historical relic's protection |
| CN110159148A (en) * | 2018-03-26 | 2019-08-23 | 浙江亿美达门业有限公司 | A kind of timber that moisture-proof, antibiotic effect is good |
| CN110903708A (en) * | 2019-12-12 | 2020-03-24 | 广东长鑫环保科技有限公司 | Preparation method of plant coating capable of releasing small-particle-size negative ions |
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| CN105802425A (en) * | 2016-04-06 | 2016-07-27 | 郜杰 | Environment-friendly and anti-bacterial interior wall coating containing shell powder |
| CN106479236A (en) * | 2016-11-03 | 2017-03-08 | 威海裕隆水产开发有限公司 | A kind of environmental protection coating material |
| CN106752494A (en) * | 2016-11-23 | 2017-05-31 | 温州兴南环保科技有限公司 | A kind of environmental protection coating material |
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| CN105802425A (en) * | 2016-04-06 | 2016-07-27 | 郜杰 | Environment-friendly and anti-bacterial interior wall coating containing shell powder |
| CN106479236A (en) * | 2016-11-03 | 2017-03-08 | 威海裕隆水产开发有限公司 | A kind of environmental protection coating material |
| CN106752494A (en) * | 2016-11-23 | 2017-05-31 | 温州兴南环保科技有限公司 | A kind of environmental protection coating material |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108299877A (en) * | 2017-09-28 | 2018-07-20 | 马鞍山松鹤信息科技有限公司 | A kind of finishing special environment protection coating and its preparation process |
| CN108084869A (en) * | 2018-01-24 | 2018-05-29 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN110159148A (en) * | 2018-03-26 | 2019-08-23 | 浙江亿美达门业有限公司 | A kind of timber that moisture-proof, antibiotic effect is good |
| CN110159148B (en) * | 2018-03-26 | 2020-08-11 | 浙江亿美达门业有限公司 | Wooden door with moisture-proof and antibacterial effects |
| CN110054939A (en) * | 2018-06-14 | 2019-07-26 | 金陵科技学院 | A kind of coating and preparation method thereof for historical relic's protection |
| CN109593412A (en) * | 2018-11-07 | 2019-04-09 | 泉州市东宝建材科技有限公司 | A kind of automatically cleaning exterior wall surface coating and preparation method thereof |
| CN109943172A (en) * | 2018-12-23 | 2019-06-28 | 朱进平 | A kind of aqueous silicon-acrylic coatings of compound resin base and preparation method thereof |
| CN110903708A (en) * | 2019-12-12 | 2020-03-24 | 广东长鑫环保科技有限公司 | Preparation method of plant coating capable of releasing small-particle-size negative ions |
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Application publication date: 20170901 |