CN105949863A - Functional diatomite putty powder and preparation method thereof - Google Patents

Functional diatomite putty powder and preparation method thereof Download PDF

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Publication number
CN105949863A
CN105949863A CN201610330151.2A CN201610330151A CN105949863A CN 105949863 A CN105949863 A CN 105949863A CN 201610330151 A CN201610330151 A CN 201610330151A CN 105949863 A CN105949863 A CN 105949863A
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China
Prior art keywords
powder
diatom ooze
lacquer putty
kieselguhr
inorganic
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CN201610330151.2A
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Chinese (zh)
Inventor
刘琨
高哲
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YINGKOU PANPAN ENVIRONMENTAL DIATOM MATERIALS Co Ltd
Central South University
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YINGKOU PANPAN ENVIRONMENTAL DIATOM MATERIALS Co Ltd
Central South University
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Priority to CN201610330151.2A priority Critical patent/CN105949863A/en
Publication of CN105949863A publication Critical patent/CN105949863A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/34Filling pastes

Abstract

The invention relates to putty powder, in particular to functional diatomite putty powder and a preparation method thereof, wherein the putty powder includes in percent by weight: 10-50% of high-temperature activated diatomite, 5-30% of an inorganic binder, 30-70% of an inorganic filler, 0.01-2% of a functional aid, 0.1-5% of an inorganic pigment, 0.5-5% of an organic binder, and 0.5-5% of an organic aid. The functional diatomite putty powder meets the related standard requirements of putty powder and diatomite, and has qualified constructability and functionality, namely having standard-meeting properties such as humidity regulation, formaldehyde clarifying performance, long duration of formaldehyde purifying performance, mold-proof performance, and mold durability.

Description

A kind of functional diatom ooze powder of lacquer putty for use on and preparation method thereof
Technical field
The present invention relates to powder of lacquer putty for use on, be specifically related to a kind of functional diatom ooze powder of lacquer putty for use on and preparation method thereof.
Background technology
Powder of lacquer putty for use on is before decorative engineering, is applied on Indoor environment body of wall, processes material with the levelling substrate surface as main purpose, including GENERAL TYPE, flexible, resistance to water three kinds.The effect of powder of lacquer putty for use on is single, but in the last few years, and in order to increase the functional of powder of lacquer putty for use on, multiple have functional raw material and be added among powder of lacquer putty for use on, and kieselguhr is exactly one of them.Have and much in powder of lacquer putty for use on, add diatomaceous report.The function powder of lacquer putty for use on of the increased anion of Chinese patent CN101942237A report contains the kieselguhr of 5-15%;Can be containing 10-35 part kieselguhr as subsidy humidity adjusting material in the inner wall putty with damping moisture-proof function of CN104403399A report;Containing 1-5 part kieselguhr in the Radiation-proof putty powder of CN103525153A report;Containing kieselguhr 1-5 part in the Anti-formaldehyde putty powder of CN103525152A report;Containing kieselguhr 20-30 part in the putty caning absorb, burying Carbon Dioxide in Air of CN101851442A report;The charcoal base aqueous clean taste sterilization powder of lacquer putty for use on of CN101967317A report contains the kieselguhr of 10-20;The interior wall low-carbon (LC) putty of CN104789023A report contains 20-40 part kieselguhr;The ceramic tile surface special putty with formaldehyde absorbing ability of CN104559406A report contains 10-15 part kieselguhr;Containing 100-130 part kieselguhr in a kind of paste heat preservation humidity conditioning putty of CN103694764A report;Containing kieselguhr 400-500 part in a kind of kieselguhr putty siccative of CN104177021A report;Containing kieselguhr 2-8 part in a kind of green powdered paint of CN1887989A report;Containing the kieselguhr used as humidity adjusting material in a kind of inner wall putty with dehumidifying and humidification function of CN103351686A and CN103351129A report;Containing kieselguhr 40-44 part in the putty powder for exterior wall of a kind of anti-strip of CN103351687A and CN103351130A report;Containing kieselguhr 46-50 part in a kind of inner wall putty of CN103351684A report;Containing kieselguhr 1-5 part in a kind of putty for interior wall of CN104559403A report;Containing kieselguhr 5-9 part in the powder of lacquer putty for use on of a kind of adsorbing contaminant gas of CN102850835A report.
In these existing reports, the most more or less add kieselguhr in the feed, then rely on kieselguhr or in diatomaceous presence, powder of lacquer putty for use on served certain functional result, including damping, formaldehyde adsorption, clean taste, absorbing carbon dioxide etc..But these reports are only to be used as a kind of filler component in powder of lacquer putty for use on by kieselguhr, the product obtained in itself or powder of lacquer putty for use on, is not a kind of brand-new functional architecture and decoration material.
The new ornament materials diatom ooze occurred in recent years is a kind of green inner wall decoration wall material with kieselguhr as main raw material(s), has elimination formaldehyde, purifies air, the regulation function such as humidity, deodorization and sterilization.Due to diatom ooze health environment-friendly, do not only have the most ornamental, also have functional, be to substitute wallpaper and the house decorative material of new generation of emulsion paint.Diatom ooze out after, corresponding industry standard is also arisen at the historic moment.Country building material industry standard JC/T The clear stipulaties general specification of diatom ooze, functional specifications, limits of harmful substances requirement in 2177-2013 (diatom ooze decorative wall material).The most various diatom ooze product categories are various, and construction technology is different, but are substantially required for smooth putty face as bottom.
For putty and this present situation of diatom ooze, it is contemplated that the application property of powder of lacquer putty for use on and functional both features of diatom ooze are brought together, form new diatom ooze powder of lacquer putty for use on, the leveling function of powder of lacquer putty for use on can be played, also can play the function affect of diatom ooze, be a kind of novel indoor fitment material for family.
At present, diatom ooze is diatom ooze, and powder of lacquer putty for use on is powder of lacquer putty for use on, has huge difference at the aspect such as purposes, technique between the two.There is not yet the functional product having diatom ooze and powder of lacquer putty for use on concurrently.This present situation of pin, it is contemplated that the application property of powder of lacquer putty for use on and functional both features of diatom ooze are brought together, form new diatom ooze powder of lacquer putty for use on, the leveling function of powder of lacquer putty for use on can be played, also can play the function affect of diatom ooze, be a kind of novel indoor fitment material for family.
Summary of the invention
The present invention provides a kind of and had both had qualified application property, has again qualified functional diatom ooze powder of lacquer putty for use on.
The technical solution used in the present invention is: a kind of functional diatom ooze powder of lacquer putty for use on, and its composition is as follows by mass percentage:
High-temperature activation kieselguhr: 10~50%, inorganic binder: 5~30%, inorganic filler: 30~70%, functional aid: 0.01~2%, inorganic pigment: 0.1~5%, organic binder bond: 0.5~5%, organic additive: 0.5~5%.
As preferably, described inorganic binder is at least one in white cement, sierozem power, Gypsum Fibrosum powder.
As preferably, described inorganic filler is calcium carbonate or magnesium calcium carbonate.
As preferably, functional aid is at least one in antifungus agent, nanometer silver, nano titanium oxide, nano zine oxide.
As preferably, described inorganic pigment is that iron oxide red, iron oxide yellow, iron oxide black, barba hispanica, ferrum is green, cobalt blue, cobalt green, ultramarine, at least one in titanium dioxide.
As preferably, described organic binder bond is redispersible latex powder.
As preferably, described organic additive is hydroxypropyl methyl cellulose or starch ether.
This product meets the relevant criterion requirement of powder of lacquer putty for use on and diatom ooze simultaneously, both there is qualified application property, have again qualified functional, i.e. adjustable wet, purifying formaldehyde performance, purifying formaldehyde effect persistency, mould proof performance, mould proof endurance qualities etc., harmful substance contents also complies with requirement simultaneously.
The present invention also provides for the preparation method of a kind of diatom ooze powder of lacquer putty for use on, and it sequentially includes the following steps:
(1) high-temperature activation kieselguhr, inorganic binder, inorganic filler, functional aid, inorganic pigment are put into in ceramic-lined Ball-stirring mill by above-mentioned mass ratio, using alumina balls or zirconia ball is abrasive media, through being thoroughly mixed superfine grinding to less than 800 mesh;
(2) organic binder bond and organic additive are joined in the superfine powder that (1) obtains by above-mentioned mass ratio, then use high speed dispersor to carry out fully dispersed 2-20 minute at rotating speed 1000-1500rpm, obtain the diatom ooze powder of lacquer putty for use on of fluffy exquisiteness.
As preferably, described high-temperature activation kieselguhr is that natural diatomaceous earth obtains kieselguhr concentrate through physical upgrading, most metal impurities are removed again by acidleach, finally carry out, at 500~1200 DEG C, the kieselguhr deep processed product that high-temperature calcination obtains, its crystal formation is low temperature cristobalite type, remains diatomaceous pattern.Compared with ordinary silicon diatomaceous earth, the kieselguhr of this high-temperature activation has purity height, density is little, pore volume is big, specific surface area is big, pore structure is improved, surface activity high, has this qualitative difference at a lot of aspects.Such as specific surface area, before the ratio activation after activation, exceed a magnitude.Therefore, high-temperature activation kieselguhr has more preferable adsorption for organic pollutant such as formaldehyde etc..
All inorganic raw materials are carried out superfine grinding in advance by the preparation method of the present invention so that the performance of diatom ooze powder of lacquer putty for use on is the most excellent, are embodied in the following aspects:
(1) using Ball-stirring mill to carry out mixing and superfine grinding, efficiency is high, the time is short, energy consumption is low, simple to operate.
(2) use ceramic-lined and alumina balls, zirconia ball as abrasive media, during superfine grinding can be avoided, introduce the impurity such as ferrum.
(3) inorganic particle is used superfine grinding, the specific surface area of diatom ooze powder of lacquer putty for use on can be improved, strengthen its absorption property for toxic and harmful further.
(4) superfine grinding is used so that the granularity of inorganic binder becomes less, thus obtains higher adhesion strength, thoroughly solves dusting problems.The inorganic binder used is white cement, sierozem power, Gypsum Fibrosum powder, is typical inorganic coagulation material.The granularity of these Binder Materials is the least, is more susceptible to aquation and sclerous reaction, and the later strength of formation is the highest.
(5) use superfine grinding so that more uniformly spreading of inorganic binder, thus improve the uniformity of intensity.For a long time extra-fine grinding makes to adequately achieve on micro-meter scale between each component content consistency and performance uniformity so that the intensity property in each position of the diatom ooze powder of lacquer putty for use on after upper wall is essentially identical, it is to avoid local strength is low, the problem of easy dry linting.
(6) superfine grinding is used so that functional aid agglomeration in diatom ooze powder of lacquer putty for use on greatly reduces, and more uniformly spreads, thus improves overall performance.The functional aid used is organic antifungus agent and inorganic nanoparticles, is affected by its surface nature, the easy spontaneous reunion of these materials, assembles agglomerating, cause skewness, affect the performance of product in powder body.Superfine grinding can make these auxiliary agents be fully contacted with kieselguhr and filler and load thereon, thus drastically increases distributing homogeneity, and then improves the antimildew and antibacterial photocatalysis performance of entirety.
(7) use superfine grinding so that inorganic pigment agglomeration in diatom ooze powder of lacquer putty for use on greatly reduces, and more uniformly spreads, thus improve the upper chromatic effect of entirety, it is to avoid the phenomenons such as variegated, colour cast, color dot, mottle.
Generally speaking, carry out after being mixed by several inorganic raw materials synchronizing superfine grinding, every raw material is greatly evenly distributed on micro-meter scale, strengthen the coordinative role between each component, on the one hand the application property making diatom ooze powder of lacquer putty for use on is more preferable, on the other hand later strength is higher, also makes it functional be promoted, and colour developing is evenly.
The high-temperature activation kieselguhr of the present invention, be natural diatomaceous earth after physical upgrading, the kieselguhr concentrate obtained removes most metal impurities by acidleach again, the most again at 500~1200 DEG C of kieselguhr deep processed products carrying out high-temperature calcination and obtain.
Detailed description of the invention
For the technological means making the present invention realize, creation characteristic, reach purpose and be easy to understand with effect, below in conjunction with specific embodiment, the present invention is expanded on further.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
High-temperature activation kieselguhr 10~50%, inorganic binder 5~30%, inorganic filler 30~70%, inorganic pigment 0.1~5%, functional aid 0.01~2% mixing are put into in ceramic-lined Ball-stirring mill by quality composition by the present invention, using alumina balls or zirconia ball is abrasive media, through being thoroughly mixed superfine grinding to less than 800 mesh;Then add organic binder bond 0.5~5% and organic additive 0.5~5%, use high speed dispersor to carry out fully dispersed 2-20 minute at rotating speed 1000-1500rpm, obtain the diatom ooze powder of lacquer putty for use on of fluffy exquisiteness.
In the present invention, inorganic binder is one or more in the common inorganic bond materials such as white cement, sierozem power, Gypsum Fibrosum powder;Inorganic filler is one or more in common calcium carbonate, magnesium calcium carbonate;Inorganic pigment is that iron oxide red, iron oxide yellow, iron oxide black, barba hispanica, ferrum is green, cobalt blue, cobalt green, ultramarine, at least one in titanium dioxide;Functional aid is at least one in various antifungus agent, nanometer silver, nano titanium oxide, nano zine oxide, plays the effects such as antibacterial, mildew-resistant, photocatalysis;Organic binder bond is redispersible latex powder;Organic additive is hydroxypropyl methyl cellulose or starch ether, plays thickening property, water-retaining property, improves the effects such as application property.
In the present invention, carry out inorganic raw material synchronizing superfine grinding, make each raw material mix homogeneously on micro-meter scale, strengthen the coordinative role between each component, on the one hand the application property making diatom ooze powder of lacquer putty for use on is more preferable, on the other hand later strength is higher, also makes it functional be promoted, and colour developing is evenly.
During use, it is only necessary to the diatom ooze powder of lacquer putty for use on of the present invention is proportionally added into a certain amount of water and carries out mixing mediation, can directly criticize and scrape the surface at construction wall, construct simple and convenient.When using as putty, with putty batch to scrape program consistent.When using as diatom ooze, can carry out batch scraping, bullet painting, printing, the technique such as plucking, form certain art pattern.
This product meets the relevant criterion requirement of powder of lacquer putty for use on and diatom ooze simultaneously, has both had qualified application property, has again qualified functional, i.e. adjustable wet, purifying formaldehyde performance, purifying formaldehyde effect persistency, mould proof performance, mould proof endurance quality etc..If material purity is high, then harmful substance contents also complies with requirement.
Embodiment 1:
High-temperature activation kieselguhr 20%, sierozem power 15%, calcium carbonate 61.45%, antifungus agent and nano titanium oxide 0.05%, titanium dioxide 0.5%, put in ceramic-lined Ball-stirring mill after mixing, after using zirconia ball agitation grinding half an hour, granularity is less than 800 mesh, takes out and pours in high speed dispersor, adds redispersible latex powder 2% and hydroxypropyl methyl cellulose 1%, after rotating speed 1000rpm disperses 3 minutes, pack packaging.
Embodiment 2:
High-temperature activation kieselguhr 40%, Gypsum Fibrosum powder 20%, calcium carbonate 32%, antifungus agent 0.2%, iron oxide red 1.3%, put in ceramic-lined Ball-stirring mill after mixing, after using zirconia ball agitation grinding half an hour, granularity is less than 800 mesh, takes out and pours in high speed dispersor, adds redispersible latex powder 2.5% and hydroxypropyl methyl cellulose 4%, after rotating speed 1000rpm disperses 5 minutes, pack packaging.
Embodiment 3:
High-temperature activation kieselguhr 14%, white cement 8%, magnesium calcium carbonate 70%, antifungus agent and nano zine oxide 1%, ultramarine 1%, put in ceramic-lined Ball-stirring mill after mixing, after using zirconia ball agitation grinding half an hour, granularity is less than 800 mesh, takes out and pours in high speed dispersor, adds redispersible latex powder 3% and hydroxypropyl methyl cellulose 3%, after rotating speed 1000rpm disperses 10 minutes, pack packaging.
Embodiment 4:
High-temperature activation kieselguhr 45%, white cement 16%, calcium carbonate 30%, nanometer silver 0.5%, iron oxide yellow 2.5%, put in ceramic-lined Ball-stirring mill after mixing, after using zirconia ball agitation grinding half an hour, granularity is less than 800 mesh, takes out and pours in high speed dispersor, adds redispersible latex powder 4% and hydroxypropyl methyl cellulose 2%, after rotating speed 1000rpm disperses 4 minutes, pack packaging.
Embodiment 5:
High-temperature activation kieselguhr 30%, sierozem power 20%, magnesium calcium carbonate 40%, antifungus agent and nano titanium oxide 1.8%, iron oxide black 3%, put in ceramic-lined Ball-stirring mill after mixing, after using zirconia ball agitation grinding half an hour, granularity is less than 800 mesh, takes out and pours in high speed dispersor, adds redispersible latex powder 2.8% and hydroxypropyl methyl cellulose 2.4%, after rotating speed 1000rpm disperses 15 minutes, pack packaging.
The product of above five embodiments, respectively by building industry industry standard JG/T 298-2010(architecture indoor putty) detect, all physical property technical specifications and the limits of harmful substances index of resistance to water (N) putty can be met.
The product of above five embodiments, respectively by building material industry standard JC/T2177-2013(diatom ooze decorative wall material) detect, all technology can be met and require index and functional specifications index (humidity, purifying formaldehyde performance, purifying formaldehyde effect persistency, mould proof performance, mould proof endurance quality).
The technical scheme provided the embodiment of the present invention above is described in detail, principle and the embodiment of the embodiment of the present invention are set forth by specific case used herein, and the explanation of above example is only applicable to help to understand the principle of the embodiment of the present invention;Simultaneously for one of ordinary skill in the art, according to the embodiment of the present invention, all will change in detailed description of the invention and range of application, in sum, this specification content should not be construed as limitation of the present invention.

Claims (9)

1. a functional diatom ooze powder of lacquer putty for use on, its composition is as follows by mass percentage:
High-temperature activation kieselguhr: 10~50%, inorganic binder: 5~30%, inorganic filler: 30~70%, functional aid: 0.01~2%, inorganic pigment: 0.1~5%, organic binder bond: 0.5~5%, organic additive: 0.5~5%.
2. diatom ooze powder of lacquer putty for use on as claimed in claim 1, it is characterised in that: described inorganic binder is at least one in white cement, sierozem power, Gypsum Fibrosum powder.
3. diatom ooze powder of lacquer putty for use on as claimed in claim 1, it is characterised in that: described inorganic filler is calcium carbonate or magnesium calcium carbonate.
4. diatom ooze powder of lacquer putty for use on as claimed in claim 1, it is characterised in that: described functional aid is at least one in antifungus agent, nanometer silver, nano titanium oxide, nano zine oxide.
5. as claimed in claim 1 diatom ooze powder of lacquer putty for use on, it is characterised in that: described inorganic pigment is that iron oxide red, iron oxide yellow, iron oxide black, barba hispanica, ferrum is green, cobalt blue, cobalt green, ultramarine, at least one in titanium dioxide.
6. diatom ooze powder of lacquer putty for use on as claimed in claim 1, it is characterised in that: described organic binder bond is redispersible latex powder.
7. diatom ooze powder of lacquer putty for use on as claimed in claim 1, it is characterised in that: described organic additive is hydroxypropyl methyl cellulose or starch ether.
8. a preparation method for diatom ooze powder of lacquer putty for use on described in any one in claim 1 to 7, it sequentially includes the following steps:
(1) high-temperature activation kieselguhr, inorganic binder, inorganic filler, functional aid, inorganic pigment are put into in ceramic-lined Ball-stirring mill by above-mentioned mass ratio, using alumina balls or zirconia ball is abrasive media, through being thoroughly mixed superfine grinding to less than 800 mesh;
(2) organic binder bond and organic additive are joined in the superfine powder that (1) obtains by above-mentioned mass ratio, then use high speed dispersor to carry out fully dispersed 2-20 minute at rotating speed 1000-1500rpm, obtain the diatom ooze powder of lacquer putty for use on of fluffy exquisiteness.
9. the preparation method of diatom ooze powder of lacquer putty for use on as claimed in claim 1, it is characterized in that: described high-temperature activation kieselguhr is that natural diatomaceous earth obtains kieselguhr concentrate through physical upgrading, remove impurity by acidleach again, finally carry out, at 500~1200 DEG C, the kieselguhr deep processed product that high-temperature calcination obtains.
CN201610330151.2A 2016-05-18 2016-05-18 Functional diatomite putty powder and preparation method thereof Pending CN105949863A (en)

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Cited By (13)

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CN106495624A (en) * 2016-10-25 2017-03-15 新疆振翔建材有限责任公司 Interior wall diatom ooze dry powder emulsion paint and preparation method thereof
CN106747185A (en) * 2016-11-29 2017-05-31 青岛海之星生物科技有限公司 It is a kind of long-acting except net taste diatom ooze of aldehyde and preparation method thereof
CN106833090A (en) * 2017-04-12 2017-06-13 程艳青 A kind of indoor Multifunctional diatom ooze powder of lacquer putty for use on and preparation method thereof
CN107140935A (en) * 2017-05-11 2017-09-08 张维秀 A kind of nano material composite modified diatomaceous air cleaning new material
CN107286720A (en) * 2017-08-15 2017-10-24 长兴国锋塑料有限公司 The inner wall putty powder and its production technology of a kind of environmental protection
CN107312415A (en) * 2017-08-21 2017-11-03 马鞍山市三川机械制造有限公司 A kind of Automobile flywheel shell surface coating
CN107963861A (en) * 2017-11-27 2018-04-27 中华制漆(深圳)有限公司 Novel and multifunctional inorganic coating and its preparation method and application
CN108383432A (en) * 2018-04-13 2018-08-10 临江市恒越新材料有限公司 A kind of mould proof diatom coating of multicolour photocatalysis and preparation method thereof
CN108587265A (en) * 2018-04-20 2018-09-28 吉林建筑大学 A kind of high activity functional form diatom ooze and preparation method thereof
CN108795143A (en) * 2018-08-27 2018-11-13 金陵科技学院 A kind of cement polymer putty for exempting from plastering construction operation
CN109135360A (en) * 2018-08-27 2019-01-04 苏州煜水生物科技有限公司 A kind of novel biotechnology diatom ooze decorative paint and preparation method thereof
CN109233415A (en) * 2017-07-11 2019-01-18 上海前引科技有限公司 A kind of antimildew and antibacterial anion diatom ooze powder of lacquer putty for use on
CN112011208A (en) * 2020-10-20 2020-12-01 广东博智林机器人有限公司 Putty surface decoration material and preparation method and use method thereof

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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106495624A (en) * 2016-10-25 2017-03-15 新疆振翔建材有限责任公司 Interior wall diatom ooze dry powder emulsion paint and preparation method thereof
CN106495624B (en) * 2016-10-25 2019-02-26 新疆振翔建材有限责任公司 Interior wall diatom ooze dry powder emulsion paint and preparation method thereof
CN106747185A (en) * 2016-11-29 2017-05-31 青岛海之星生物科技有限公司 It is a kind of long-acting except net taste diatom ooze of aldehyde and preparation method thereof
CN106833090A (en) * 2017-04-12 2017-06-13 程艳青 A kind of indoor Multifunctional diatom ooze powder of lacquer putty for use on and preparation method thereof
CN107140935A (en) * 2017-05-11 2017-09-08 张维秀 A kind of nano material composite modified diatomaceous air cleaning new material
CN109233415A (en) * 2017-07-11 2019-01-18 上海前引科技有限公司 A kind of antimildew and antibacterial anion diatom ooze powder of lacquer putty for use on
CN107286720A (en) * 2017-08-15 2017-10-24 长兴国锋塑料有限公司 The inner wall putty powder and its production technology of a kind of environmental protection
CN107312415B (en) * 2017-08-21 2018-09-28 马鞍山市三川机械制造有限公司 A kind of Automobile flywheel shell surface coating
CN107312415A (en) * 2017-08-21 2017-11-03 马鞍山市三川机械制造有限公司 A kind of Automobile flywheel shell surface coating
CN107963861A (en) * 2017-11-27 2018-04-27 中华制漆(深圳)有限公司 Novel and multifunctional inorganic coating and its preparation method and application
CN107963861B (en) * 2017-11-27 2020-09-11 中华制漆(深圳)有限公司 Multifunctional inorganic coating and preparation method and application thereof
CN108383432A (en) * 2018-04-13 2018-08-10 临江市恒越新材料有限公司 A kind of mould proof diatom coating of multicolour photocatalysis and preparation method thereof
CN108587265A (en) * 2018-04-20 2018-09-28 吉林建筑大学 A kind of high activity functional form diatom ooze and preparation method thereof
CN109135360A (en) * 2018-08-27 2019-01-04 苏州煜水生物科技有限公司 A kind of novel biotechnology diatom ooze decorative paint and preparation method thereof
CN108795143A (en) * 2018-08-27 2018-11-13 金陵科技学院 A kind of cement polymer putty for exempting from plastering construction operation
CN112011208A (en) * 2020-10-20 2020-12-01 广东博智林机器人有限公司 Putty surface decoration material and preparation method and use method thereof

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Application publication date: 20160921