CN103482905A - Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings - Google Patents
Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings Download PDFInfo
- Publication number
- CN103482905A CN103482905A CN201310430321.0A CN201310430321A CN103482905A CN 103482905 A CN103482905 A CN 103482905A CN 201310430321 A CN201310430321 A CN 201310430321A CN 103482905 A CN103482905 A CN 103482905A
- Authority
- CN
- China
- Prior art keywords
- parts
- component
- agent
- environment
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings comprises A compositions, B compositions and a C composition, wherein the A compositions comprise the following substances in parts by weight: 25-35 parts of polyaspartic acid ester resin, 20 parts of an aromatics mixed solvent, 8-10 parts of nano-scale ceramic powder, 2-4 parts of mica powder, 10-18 parts of diacetone alcohol, 3-8 parts of ethylene glycol monobutyl ether, 7-11 parts of a cellulose thickener solution with the mass percent of 2%, 1.0-1.4 parts of a polyphosphate dispersing agent solution with the mass percent of 10%, 1-3 parts of an emulgator, 0.1-0.3 part of sodium hydroxide, 30-50 parts of ethyl alcohol, 70-100 parts of deionized water, 140-180 parts of titanium dioxide; the B compositions comprise the following substances in parts by weight: 3-5 parts of a paint curing agent, 0.02-1 part of an initiator, 1 part of a dispersing agent, 0.6 part of a flatting agent, 0.3 part of an antifoaming agent, 0.3 part of a defoaming agent, 25 parts of a modified ammonia curing agent, 2-4 parts of tetrachloroisophthalonitrile, 3-5 parts of a dry film antiseptic; the C composition is an environment-friendly color mixed-phase inorganic pigment.
Description
Technical field
The present invention relates to a kind of new anti-corrosion coating and preparation method thereof, more particularly, relate to a kind of environment-friendly type building beyond the region of objective existence uvioresistant, high-temperature resistant coating for wall.
Background technology
In prior art, skin coating commonly used is mostly to be coating prepared by base-material with vinylbenzene-ACRYLIC EMULSION, pure acrylic latex or elastomeric propylene yogurt liquid.Its shortcoming is to produce fine cracks after being applied to body of wall, puts forth effort poor, anti-pollution characteristic and poor performance at low temperatures etc.; In addition, owing to there being vinylbenzene in coating, be material, smell is quite dense; When exterior wall applies, smell distributes in a large number in atmosphere, has caused pollution; And the set time of such coating is relatively long, therefore, should be noted that Changes in weather during coating, in the rainfall connected, can not construct, therefore, larger limitation is arranged.In the NORTHWEST CHINA area, the sweltering heat in summer, sun heat radiation intensity is high, and the body surface temperature can be up to more than more than 70 degrees centigrade, and winter-spring season dust storm is very large, very strong to the wind abrasion of paint film.Practical anti-blown sand coating adopts urethane in the market, and weathering resistance and anti-blown sand performance are general, and there is no the solar heat reflection function, do not have the effect of cooling energy-saving.
Because the temperature of the outer surface of building shined upon for a long time is lasting, raise, outer surface of building is that the temperature of the material of construction outside surfaces such as cement, concrete, ceramic tile, metal, insulating brick can reach 40-50 ℃, on color steel, water-proof material, temperature can reach 60 ℃, reaches the temperature of scalding the people.Under such outer surface of building high temperature, in habitat, the inevitable rising of temperature in factory building workshop etc., to normal human subject live, material is deposited, the safety of equipment all causes very large impact, likely can produce the great potential safety hazards such as blast, if excess Temperature, need cooling, caused the significant wastage of the energy simultaneously.
In order to reduce the thermal radiation of the sun, reflect the absorption reduced the sunlight heat by raising, therefore having coating heat insulation, that reflect functions such as lowering the temperature, anticorrosion arises at the historic moment, become having reduced to a great extent sun heat radiation harm in the urgent need to, these coating and thering are fabulous market outlook of painting industry.But there is certain toxicity in traditional reflective insulation material, and unstable chemcial property, is difficult for prolonged preservation, heat-reflecting heat-insulating performance and reaches in time the variation of environment and the defect of variation etc.Consider above-mentioned practical situation, those skilled in the art is being devoted to study a kind of novel water corrosion-resistant epoxy paint always, replace existing solvent-borne type protective system, and simultaneously need again to have sticking power preferably, lower cost and better simply preparation method.
Summary of the invention
For the deficiency existed on prior art, the invention provides a kind of unioresistant, high-temperature resistant coating.
To achieve these goals, technical scheme of the present invention is as follows:
A kind of environment-friendly type building beyond the region of objective existence wall uvioresistant, high-temperature resistant coating, it is by the A component, B component and component C form, each component consists of by weight: contain following material and content: based on polyaspartic ester resin 25-35 part, 20 parts of aromatic hydrocarbons mixed solvents, nanometer scale ceramics powder 8-10 part, 2～4 parts of mica powders, diacetone alcohol 10-18 part, ethylene glycol monobutyl ether: 3～8 parts, 7～11 parts of the cellulose thickener solution of 2% mass percent, 1.0～1.4 parts of the polyphosphoric acid salt dispersant solutions of 10% mass percent, emulsifying agent: 1～3 part, sodium hydroxide: 0.1～0.3 part, ethanol: 30～50 parts, deionized water: 70～100 parts, titanium dioxide: 140～180 parts, component B, by by weight, includes following material and content: coating curing agent: 0.02～1 part of 3～5 part, initiator, dispersion agent 1, flow agent 0.6, defoamer 0.3, deaerating agent 0.3, 25 parts, modification Ammonia solidifying agent, daconil M: 2～4 parts, dry film mould inhibitor: 5 ~ 3 parts, component C is environment protection colour mixed phase mineral dye, skin coating described above, it prepares by the following method:
The first step: each raw material of weighing: based on polyaspartic ester resin 25-35 part, 20 parts of aromatic hydrocarbons mixed solvents, diacetone alcohol 10-18 part, ethylene glycol monobutyl ether: 3～8 parts, emulsifying agent: 1～3 part, sodium hydroxide: 0.1～0.3 part, ethanol: 30～50 parts, deionized water: 70～100 parts, titanium dioxide: press 18～22 parts of titanium dioxides for 140～180 parts, 8～15 parts of talcum powder, 5～10 parts, calcium carbonate, 2～4 parts of mica powders, 7～11 parts of the cellulose thickener solution of 2% mass percent, 1.0～1.4 parts of the polyphosphoric acid salt dispersant solutions of 10% mass percent take and are separated,
Second step: abrasive grains raw material: titanium dioxide, talcum powder, calcium carbonate, mica powder are mixed and be ground to particle minimum diameter≤50 μ m by shredder, the fine particle that obtains mixing,
The 3rd step: dissolve: the fine particle of the mixing that the second step grinding is obtained and other raw material that the first step takes are put into reaction vessel together, while being heated to 50～60 ℃, stir, and churning time is 45～60 minutes, obtains mixed emulsion;
The 4th step: filter: the 3rd step gained mixed emulsion is obtained to environment-friendly type building beyond the region of objective existence wall coating by 80～100 mesh sieve inherent filtrations;
The 5th step: ratio takes the various raw materials of component B the mixing and stirring container of packing into and obtains finished product component B by weight;
The 6th step: according to component A: component B: component C=(600～1000): (30～50): 1 weight ratio takes component C and inserts in container the component C that gets product; And rationally take in proportion component A and component B;
The 7th step: by the 6th step, claim the finished product component C insert in finished product component B, fully stirring and dissolving, obtain lysate; Lysate is joined in finished product component A, stir and obtain the skin epoxypaint.
Described dispersion agent is EFKA-5065 dispersion agent and the EFKA-4050 dispersion agent mixture according to 1:3; The EFKA-3777 flow agent that described flow agent is and EFKA-3239 flow agent are according to the mixture of 2:1, and defoamer is hydrophobically modified silicon-dioxide or mineral oil.Defoamer is polydimethylsiloxane or silicone emulsion or the fatty acid ester compounded thing of higher alcohols or polyoxyethylene polyoxypropylene tetramethylolmethane ether or polyoxyethylene polyoxy propyl alcohol amidogen ether or polypropylene glycerol aether and polyoxypropylene.Described mould inhibitor is Sodium Fluoride or 10, the two phenoxazine arsenic of 10 '-oxo.
Therefore, the present invention has following main beneficial effect: good fluidity, anti-go mouldy and that anti-corrosion performance is good, coating is dry is fast with setting rate, color matching flexibly, be convenient to rapid construction, making method is simple, easy to operate, required equipment is simple and easy, do not need the input of a large amount of equipment aspects.
Embodiment
In order to further illustrate the present invention, below in conjunction with embodiment, inner wall heat-preservation coating provided by the invention is described in detail, but they can not be interpreted as to limiting the scope of the present invention.
Embodiment 1
A kind of environment-friendly type building beyond the region of objective existence wall uvioresistant, high-temperature resistant coating, it is by the A component, B component and component C form, each component consists of by weight: contain following material and content: based on polyaspartic ester resin 25-35 part, 20 parts of aromatic hydrocarbons mixed solvents, nanometer scale ceramics powder 8-10 part, 2～4 parts of mica powders, diacetone alcohol 10-18 part, ethylene glycol monobutyl ether: 3～8 parts, 7～11 parts of the cellulose thickener solution of 2% mass percent, 1.0～1.4 parts of the polyphosphoric acid salt dispersant solutions of 10% mass percent, emulsifying agent: 1～3 part, sodium hydroxide: 0.1～0.3 part, ethanol: 30～50 parts, deionized water: 70～100 parts, titanium dioxide: 140～180 parts, component B, by by weight, includes following material and content: coating curing agent: 0.02～1 part of 3～5 part, initiator, dispersion agent 1, flow agent 0.6, defoamer 0.3, deaerating agent 0.3, 25 parts, modification Ammonia solidifying agent, daconil M: 2～4 parts, dry film mould inhibitor: 5 ~ 3 parts, component C is environment protection colour mixed phase mineral dye, skin coating described above, it prepares by the following method:
The first step: each raw material of weighing: based on polyaspartic ester resin 25-35 part, 20 parts of aromatic hydrocarbons mixed solvents, diacetone alcohol 10-18 part, ethylene glycol monobutyl ether: 3～8 parts, emulsifying agent: 1～3 part, sodium hydroxide: 0.1～0.3 part, ethanol: 30～50 parts, deionized water: 70～100 parts, titanium dioxide: press 18～22 parts of titanium dioxides for 140～180 parts, 8～15 parts of talcum powder, 5～10 parts, calcium carbonate, 2～4 parts of mica powders, 7～11 parts of the cellulose thickener solution of 2% mass percent, 1.0～1.4 parts of the polyphosphoric acid salt dispersant solutions of 10% mass percent take and are separated,
Second step: abrasive grains raw material: titanium dioxide, talcum powder, calcium carbonate, mica powder are mixed and be ground to particle minimum diameter≤50 μ m by shredder, the fine particle that obtains mixing,
The 3rd step: dissolve: the fine particle of the mixing that the second step grinding is obtained and other raw material that the first step takes are put into reaction vessel together, while being heated to 50～60 ℃, stir, and churning time is 45～60 minutes, obtains mixed emulsion;
The 4th step: filter: the 3rd step gained mixed emulsion is obtained to environment-friendly type building beyond the region of objective existence wall coating by 80～100 mesh sieve inherent filtrations;
The 5th step: ratio takes the various raw materials of component B the mixing and stirring container of packing into and obtains finished product component B by weight;
The 6th step: according to component A: component B: component C=(600～1000): (30～50): 1 weight ratio takes component C and inserts in container the component C that gets product; And rationally take in proportion component A and component B;
The 7th step: by the 6th step, claim the finished product component C insert in finished product component B, fully stirring and dissolving, obtain lysate; Lysate is joined in finished product component A, stir and obtain the skin epoxypaint.
Described dispersion agent is EFKA-5065 dispersion agent and the EFKA-4050 dispersion agent mixture according to 1:3; The EFKA-3777 flow agent that described flow agent is and EFKA-3239 flow agent are according to the mixture of 2:1, and defoamer is hydrophobically modified silicon-dioxide or mineral oil.Defoamer is polydimethylsiloxane or silicone emulsion or the fatty acid ester compounded thing of higher alcohols or polyoxyethylene polyoxypropylene tetramethylolmethane ether or polyoxyethylene polyoxy propyl alcohol amidogen ether or polypropylene glycerol aether and polyoxypropylene.Described mould inhibitor is Sodium Fluoride or 10, the two phenoxazine arsenic of 10 '-oxo.
The present invention detects the performance of the coating obtained, and detailed process is as follows:
The conventional physicalies such as outward appearance, application property and water tolerance of the inner wall heat-preservation coating that adopts " GB/T 9756-2009 synthetic paint resin emulsion interior wall coating " to detect to obtain the present embodiment to obtain;
The harmful substance contents of the interior wall that adopts " limits of harmful substances standard in GB 18582-2008 indoor decorating and refurnishing materials interior wall coating " to provide the present embodiment is measured;
Fungicidal properties excellence: product of the present invention is coated on the exterior wall that does not get sunlight of buildings, under the natural condition of 20-40 ℃ of outside air temperatures, spray identical tap water continuous every day for metope of the same area, in 60 days, use on skin of the present invention and do not see any mildew, and, in prior art, used at random the exterior coating of 20 brands, mildew is in various degree arranged.
The present invention has passed through following Performance Detection: the coating that has adopted preparation method of the present invention to obtain, and its key technical indexes as shown in the table:
| Sequence number | Interventions Requested | Technical requirements | Assay | Conclusion |
| 1 | Condition in container | Without lump, be uniform state after stirring | Meet the requirements | Qualified |
| 2 | Smell | Tasteless | Meet the requirements | Qualified |
| 3 | Application property | Brush two roads accessible | Meet the requirements | Qualified |
| 4 | Low-temperature stability (20 ℃) | Never degenerate | Meet the requirements | Qualified |
| 5 | 25 ℃ of set times | ≤24h | 12h | Qualified |
| 6 | Appearance of film | Normally | Meet the requirements | Qualified |
| 7 | Water-fastness | 96h is without extremely | Meet the requirements | Qualified |
| 8 | Acid resistance | 48h is without extremely | Meet the requirements | Qualified |
| 9 | Abrasion resistance (inferior) | ≥500 | 2500 | Qualified |
| 10 | Midew proof | During humidity 40%, continuous 60 days without mildew | Without mildew | Qualified |
As can be seen from the above table, the water corrosion-resistant epoxy paint prepared by method of the present invention, comparing other water-based anticorrosive paint has following advantage:
1. higher to the sticking power of base material;
2. the chemical-resistant of filming is better;
3. can mix use with other waterborne polymeric, complementary on performance;
4. raw material variety is few, pollution-free, and making method is simple, and required equipment is few: without benzene, aldehydes matter, therefore pollution-free in the present invention, and basic odorlessness; Starting material in the present invention easily purchase and cost relatively low; Only need in the present invention once to heat and get final product, and carry out under normal pressure, therefore do not need complicated reactor, security improves greatly.
Above demonstration and described ultimate principle of the present invention and principal character and advantage of the present invention.The technician of the industry should understand; the present invention is not restricted to the described embodiments; that in above-described embodiment and specification sheets, describes just illustrates principle of the present invention; without departing from the spirit and scope of the present invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the claimed scope of the invention.The claimed scope of the present invention is defined by appending claims and equivalent thereof.
Claims (4)
1. an environment-friendly type building beyond the region of objective existence wall uvioresistant, high-temperature resistant coating, it is by the A component, B component and component C form, each component consists of by weight: contain following material and content: component A is by by weight, include following material and content: based on polyaspartic ester resin 25-35 part, 20 parts of aromatic hydrocarbons mixed solvents, nanometer scale ceramics powder 8-10 part, 2～4 parts of mica powders, diacetone alcohol 10-18 part, ethylene glycol monobutyl ether: 3～8 parts, 7～11 parts of the cellulose thickener solution of 2% mass percent, 1.0～1.4 parts of the polyphosphoric acid salt dispersant solutions of 10% mass percent, emulsifying agent: 1～3 part, sodium hydroxide: 0.1～0.3 part, ethanol: 30～50 parts, deionized water: 70～100 parts, titanium dioxide: 140～180 parts, component B, by by weight, includes following material and content: coating curing agent: 0.02～1 part of 3～5 part, initiator, dispersion agent 1, flow agent 0.6, defoamer 0.3, deaerating agent 0.3, 25 parts, modification Ammonia solidifying agent, daconil M: 2～4 parts, dry film mould inhibitor: 5 ~ 3 parts, component C is environment protection colour mixed phase mineral dye, skin coating described above, it prepares by the following method:
The first step: each raw material of weighing: based on polyaspartic ester resin 25-35 part, 20 parts of aromatic hydrocarbons mixed solvents, diacetone alcohol 10-18 part, ethylene glycol monobutyl ether: 3～8 parts, emulsifying agent: 1～3 part, sodium hydroxide: 0.1～0.3 part, ethanol: 30～50 parts, deionized water: 70～100 parts, titanium dioxide: press 18～22 parts of titanium dioxides for 140～180 parts, 8～15 parts of talcum powder, 5～10 parts, calcium carbonate, 2～4 parts of mica powders, 7～11 parts of the cellulose thickener solution of 2% mass percent, 1.0～1.4 parts of the polyphosphoric acid salt dispersant solutions of 10% mass percent take and are separated,
Second step: abrasive grains raw material: titanium dioxide, talcum powder, calcium carbonate, mica powder are mixed and be ground to particle minimum diameter≤50 μ m by shredder, the fine particle that obtains mixing,
The 3rd step: dissolve: the fine particle of the mixing that the second step grinding is obtained and other raw material that the first step takes are put into reaction vessel together, while being heated to 50～60 ℃, stir, and churning time is 45～60 minutes, obtains mixed emulsion;
The 4th step: filter: the 3rd step gained mixed emulsion is obtained to environment-friendly type building beyond the region of objective existence wall coating by 80～100 mesh sieve inherent filtrations;
The 5th step: ratio takes the various raw materials of component B the mixing and stirring container of packing into and obtains finished product component B by weight;
The 6th step: according to component A: component B: component C=(600～1000): (30～50): 1 weight ratio takes component C and inserts in container the component C that gets product; And rationally take in proportion component A and component B;
The 7th step: by the 6th step, claim the finished product component C insert in finished product component B, fully stirring and dissolving, obtain lysate; Lysate is joined in finished product component A, stir and obtain the skin epoxypaint.
2. environment-friendly type building beyond the region of objective existence according to claim 1 uvioresistant, high-temperature resistant coating for wall is characterized in that: described dispersion agent is EFKA-5065 dispersion agent and the EFKA-4050 dispersion agent mixture according to 1:3; The EFKA-3777 flow agent that described flow agent is and EFKA-3239 flow agent are according to the mixture of 2:1, and defoamer is hydrophobically modified silicon-dioxide or mineral oil.
3. environment-friendly type building beyond the region of objective existence according to claim 1 uvioresistant, high-temperature resistant coating for wall, it is characterized in that: defoamer is polydimethylsiloxane or silicone emulsion or the fatty acid ester compounded thing of higher alcohols or polyoxyethylene polyoxypropylene tetramethylolmethane ether or polyoxyethylene polyoxy propyl alcohol amidogen ether or polypropylene glycerol aether and polyoxypropylene.
4. environment-friendly type building beyond the region of objective existence according to claim 1 uvioresistant, high-temperature resistant coating for wall, it is characterized in that: described mould inhibitor is Sodium Fluoride or 10, the two phenoxazine arsenic of 10 '-oxo.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310430321.0A CN103482905B (en) | 2013-09-22 | 2013-09-22 | Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310430321.0A CN103482905B (en) | 2013-09-22 | 2013-09-22 | Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103482905A true CN103482905A (en) | 2014-01-01 |
| CN103482905B CN103482905B (en) | 2015-07-01 |
Family
ID=49823569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310430321.0A Expired - Fee Related CN103482905B (en) | 2013-09-22 | 2013-09-22 | Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103482905B (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925105A (en) * | 2016-06-27 | 2016-09-07 | 青岛华联装饰工程有限公司 | Quick-dried external building coating material and preparation method thereof |
| CN106082880A (en) * | 2016-06-27 | 2016-11-09 | 青岛华联装饰工程有限公司 | A kind of environmental protection flame retardant architectural decoration coating material and preparation method thereof |
| CN106118159A (en) * | 2016-06-27 | 2016-11-16 | 青岛华联装饰工程有限公司 | A kind of uvioresistant, resistant to elevated temperatures skin coating and preparation method thereof |
| CN110863343A (en) * | 2019-11-27 | 2020-03-06 | 浙江圣山科纺有限公司 | Environment-friendly ultraviolet-resistant finishing agent and outdoor cloth using same |
| CN112979990A (en) * | 2021-02-06 | 2021-06-18 | 佛山市万化科技有限公司 | Water-based polyaspartic acid ester emulsion and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0274549A (en) * | 1988-09-08 | 1990-03-14 | Hitachi Chem Co Ltd | Production of translucent artificial stone |
| KR100260020B1 (en) * | 1998-02-05 | 2000-06-15 | 장병주 | Liquefied non-shrinkage mixture for crack prevention of cement mortar and concrete |
| CN102108244A (en) * | 2010-12-22 | 2011-06-29 | 北京东方雨虹防水技术股份有限公司 | Fatty group polyurea finish with high elongation rate and preparation method thereof |
| CN102250505A (en) * | 2011-07-27 | 2011-11-23 | 株洲时代电气绝缘有限责任公司 | Putty for repairing aerogenerator blade and preparation method therefore |
| CN102775877A (en) * | 2012-07-19 | 2012-11-14 | 洛阳七维防腐工程材料有限公司 | Method for preparing and spaying anticorrosion coating for western wind farm tower |
-
2013
- 2013-09-22 CN CN201310430321.0A patent/CN103482905B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0274549A (en) * | 1988-09-08 | 1990-03-14 | Hitachi Chem Co Ltd | Production of translucent artificial stone |
| KR100260020B1 (en) * | 1998-02-05 | 2000-06-15 | 장병주 | Liquefied non-shrinkage mixture for crack prevention of cement mortar and concrete |
| CN102108244A (en) * | 2010-12-22 | 2011-06-29 | 北京东方雨虹防水技术股份有限公司 | Fatty group polyurea finish with high elongation rate and preparation method thereof |
| CN102250505A (en) * | 2011-07-27 | 2011-11-23 | 株洲时代电气绝缘有限责任公司 | Putty for repairing aerogenerator blade and preparation method therefore |
| CN102775877A (en) * | 2012-07-19 | 2012-11-14 | 洛阳七维防腐工程材料有限公司 | Method for preparing and spaying anticorrosion coating for western wind farm tower |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105925105A (en) * | 2016-06-27 | 2016-09-07 | 青岛华联装饰工程有限公司 | Quick-dried external building coating material and preparation method thereof |
| CN106082880A (en) * | 2016-06-27 | 2016-11-09 | 青岛华联装饰工程有限公司 | A kind of environmental protection flame retardant architectural decoration coating material and preparation method thereof |
| CN106118159A (en) * | 2016-06-27 | 2016-11-16 | 青岛华联装饰工程有限公司 | A kind of uvioresistant, resistant to elevated temperatures skin coating and preparation method thereof |
| CN110863343A (en) * | 2019-11-27 | 2020-03-06 | 浙江圣山科纺有限公司 | Environment-friendly ultraviolet-resistant finishing agent and outdoor cloth using same |
| CN110863343B (en) * | 2019-11-27 | 2023-06-06 | 浙江圣山科纺有限公司 | Environment-friendly ultraviolet-resistant finishing agent and outdoor cloth applying same |
| CN112979990A (en) * | 2021-02-06 | 2021-06-18 | 佛山市万化科技有限公司 | Water-based polyaspartic acid ester emulsion and preparation method thereof |
| CN112979990B (en) * | 2021-02-06 | 2022-08-02 | 佛山市万化科技有限公司 | Water-based polyaspartic acid ester emulsion and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103482905B (en) | 2015-07-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102731052B (en) | Aqueous organic-inorganic composite coating and preparation method thereof | |
| CN102408220B (en) | All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof | |
| CN105567021B (en) | A kind of aqueous cold pigment multifunctional thermal-insulation exterior wall true stone paint and preparation method thereof | |
| CN107619626B (en) | Water-based high-temperature-resistant high-humidity-resistant inorganic coating and preparation method thereof | |
| CN102311690B (en) | Waterborne exterior elastic reflective heat insulation coating and production method thereof | |
| CN103482905B (en) | Environment-friendly ultraviolet light resistant and high-temperature resistant paint for outer walls of buildings | |
| WO2017028471A1 (en) | Water-based reflective heat-insulating faux stone texture coating system for construction and preparation method thereof | |
| CN106752526A (en) | A kind of aqueous light reflection industrial heat preservation coating and preparation method thereof | |
| CN104087089A (en) | Environment-friendly inorganic exterior-wall heat-insulation thermal-insulation coating and preparation process thereof | |
| CN103627272B (en) | Liquid rock particles of artificial granite sand textured coating | |
| CN104877484B (en) | Petrochemical industry oil tank aqueous energy-saving heat-insulating thermal insulation coatings and preparation method thereof | |
| CN103045036B (en) | Environment-friendly type building exterior wall coating material | |
| CN107083129B (en) | Water-based ultrathin steel structure fireproof coating and preparation method thereof | |
| CN101323719A (en) | Construction curtain wall ceramic | |
| CN104530889A (en) | Heat-insulating heat-preserving coating and preparation method thereof | |
| CN108219562A (en) | Colorful environmental protection coating material of sunlight heat reflecting heat insulation water burnt-in sand and preparation method thereof | |
| CN104356798A (en) | Intumescent flame-retardant coating for glass door and preparing method of coating | |
| CN105017955A (en) | Heat-shielding thermal-insulation paint | |
| CN103540243A (en) | Nano flame-retardant coating | |
| CN113736331A (en) | Multifunctional outer wall colorful coating and preparation method thereof | |
| CN102372979A (en) | Anti-sticking aqueous fluoro-silicone coating and preparation method thereof | |
| CN107502102A (en) | A kind of high weather resistant water-thinned multicolor finish of water resistant low temperature and preparation method thereof | |
| CN102010645B (en) | Waterborne epoxy coating specially for nuclear power stations and preparation method thereof | |
| CN106752539B (en) | With the thick-slurry type interior wall coating and preparation method thereof for keeping the temperature anti-formaldehyde effect | |
| CN103555084A (en) | Novel anti-ultraviolet high-temperature-resistant coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150701 Termination date: 20150922 |
|
| EXPY | Termination of patent right or utility model |