CN110054939A - A kind of coating and preparation method thereof for historical relic's protection - Google Patents
A kind of coating and preparation method thereof for historical relic's protection Download PDFInfo
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- CN110054939A CN110054939A CN201810612183.0A CN201810612183A CN110054939A CN 110054939 A CN110054939 A CN 110054939A CN 201810612183 A CN201810612183 A CN 201810612183A CN 110054939 A CN110054939 A CN 110054939A
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- historical relic
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- acrylic emulsion
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
A kind of coating and preparation method thereof for historical relic's protection, it is related to technical field of paint preparation.A kind of coating for historical relic's protection, is made of following raw material: organic solvent, styrene-acrylic emulsion, isothiazolinone, quaternary ammonium salt bactericide, castor oil, ethyl alcohol, septichen phenyl ester, acrylic emulsion, polyurethane, polychloroprene latex, volatilizer, defoaming agent, dispersing agent, filler, deionized water.According to metering proportion, take above-mentioned raw materials that preparation can be completed according to a kind of coating for historical relic's protection and preparation method thereof processing.After adopting the above technical scheme, the invention has the following beneficial effects: cleaning often step it is simple, cleaning effect is excellent; good bactericidal effect can be played to historical relic, can be carried out guarantor's color to historical relic, be able to extend the characteristic of historical relic; antiultraviolet is strong, historical relic resistance to oxidation, waterproof; not moisture-sensitive; wear-resisting property is strong, has fire resisting, offers convenience to historical relic's protection; historical relic can completely be showed masses, prevent historical relic from losing.
Description
Technical field
The present invention relates to technical field of paint preparation, and in particular to a kind of for the coating of historical relic's protection and its preparation side
Method.
Background technique
Historical relic's protection refers to the system taken the left over by history object with historical value, cultureal value, scientific value
The measure for preventing it to be damaged is arranged, this process is called historical relic's protection.
China is world-famous ancient civilized country, and people of all nationalities create valuable text jointly in very long historical progress
Change legacy.It protects cultural heritage, passes on Chinese civilization, be connection national sentiment tie, promote national unity, maintenance unification of the motherland
And the important foundation of social stability, and maintenance world culture diversity and it is creative, promote mankind's joint development it is important before
It mentions.
Cultural heritage includes matter input and non-material cultural heritage.Matter input is primarily referred to as having and go through
The historical relic of history, art and scientific value, including Immovable Cultural Relics and Movable Cultural Relics.Immovable Cultural Relics include that ancient culture is lost
Location, ancient tomb, ancient building, the Cave Temple, stone inscription, mural painting, modern times important relics and representative building etc.
3415, existing museum, China, wherein 2384, historical relic system museum, line turning 575, run by the community museum
456, preliminarily form leading with national museum, provincial museum and key industry museum are backbone, state-owned
Based on museum, the museum that runs by the community is supplement, and museum's system of shop main body diversification is done in type diversification.
At present for historical relic's protection during, especially when historical relic is unearthed, need to historical relic carry out " special cleaning ",
But conventional cleaning often complex steps, cleaning effect is poor, good bactericidal effect cannot be played to historical relic, cannot to historical relic into
Row protects color, it is difficult to extend the characteristic of historical relic, antiultraviolet is poor, easily leads to historical relic oxidation, not waterproof, moisture-sensitive, wear-resisting property
Difference does not also have fire resisting, brings many troubles to historical relic's protection, historical relic completely cannot be showed masses, easily cause historical relic
Loss.
Summary of the invention
In view of the defects and deficiencies of the prior art, the present invention intends to provide a kind of coating for historical relic's protection and
Preparation method, often step is simple for cleaning, and cleaning effect is excellent, and good bactericidal effect can be played to historical relic, can be to historical relic
Guarantor's color is carried out, the characteristic of historical relic is able to extend, antiultraviolet is strong, historical relic resistance to oxidation, waterproof, not moisture-sensitive, and wear-resisting property is strong,
Have fire resisting, offer convenience to historical relic's protection, historical relic can completely be showed masses, prevent historical relic from losing.
To achieve the above object, the present invention is using following technical scheme:
A kind of coating for historical relic's protection, it is made of the raw material of following parts by weight: 500-900 parts of organic solvent, phenylpropyl alcohol
100-130 parts of lotion, 30-70 parts of isothiazolinone, 35-75 parts of quaternary ammonium salt bactericide, 50-80 parts of castor oil, ethyl alcohol 100-120
Part, 10-90 parts of polychloroprene latex, is waved 15-55 parts of septichen phenyl ester, 75-95 parts of acrylic emulsion, 45-65 parts of polyurethane
Send out agent 10-30 parts, 5-25 parts of defoaming agent, 25-40 parts of dispersing agent, 80-100 parts of filler, 400-800 parts of deionized water.It
Preparation method comprises the steps of: one, fetches organic solvent, places it in centrifugal device, and styrene-acrylic emulsion is added, and starts
Centrifugal work, the speed of centrifugation are 500r/min, the when a length of 0.3H-0.5H of centrifugation;Two, the mixture after centrifugation is placed on
In blender, and under the oxygen-free environment, it is added isothiazolinone, mixing speed 300r/min, the when a length of 0.6H of stirring,
Quaternary ammonium salt bactericide is added every 0.1H in period, after all adding, mixing speed is improved to 900r/min, 0.3H- is stirred
0.5H;Three, the mixture after having stirred is placed at low ambient temperatures, and ethyl alcohol, castor oil are sequentially placed into, and is stirred rapidly, and quiet
It sets;Four, by the rapid temperature raising of mixture after standing, 65 degrees Celsius are lifted temperature to, septichen phenyl ester is added, makes it naturally anti-
Answer, when reaction a length of 1H, during which every 10 degrees Celsius of 0.2H temperature raising;Five, propylene yogurt is added in the mixture after having reacted
Liquid places into dispersing agent after uniform stirring, keeps 125 degrees Celsius of temperature, sufficiently reacts to it;Six, by reacted mixing
Object is cooled to 35 degrees Celsius, and is put into polyurethane, uniform stirring 0.2H, adds polychloroprene latex, stirs 0.5H, and be placed on furnace
In, temperature boils 0.2H;Seven, deionized water dilution is added, in dilution in the mixture natural cooling after boiling temperature after having cooled down
Volatilizer is added, completes the preparation of coating.
The organic solvent is isopropanol.A kind of organic compound of isopropanol, the isomer of normal propyl alcohol, alias diformazan
Base methanol, 2- propyl alcohol also make IPA in industry;Colourless transparent liquid has the smell like ethyl alcohol and acetone mixture;It is dissolved in water,
It is dissolved in most organic solvents such as alcohol, ether, benzene, chloroform.
Filler is added after styrene-acrylic emulsion is added in the step 1.Material is added in filler also known as filler, compound
In can improve material performance, or can increase-volume, weight gain, reduce the solid matter of the cost of material, not only improve the property of product
Can, it has been greatly reduced production cost.
Defoaming agent is added after isothiazolinone is added in the step 2.Defoaming agent is also referred to as defomaing agent, is added in food
Surface tension is reduced during work, and foam is inhibited to generate or eliminate the food additives for having generated foam.
The temperature environment that low temperature environment in the step 3 is 0 degree Celsius -10 degrees Celsius.Suitable temperature environment, has
It is reacted conducive to ethyl alcohol, castor oil with the mixture after having stirred.
After adopting the above technical scheme, the invention has the following beneficial effects: cleaning often step it is simple, cleaning effect is excellent, energy
Good bactericidal effect is played to historical relic, guarantor's color can be carried out to historical relic, be able to extend the characteristic of historical relic, antiultraviolet is strong, historical relic
Resistance to oxidation, waterproof, not moisture-sensitive, wear-resisting property is strong, has fire resisting, offers convenience to historical relic's protection, can be complete by historical relic
Masses are showed, prevent historical relic from losing.
Specific embodiment
Embodiment 1
Present embodiment the technical solution adopted is that:
A kind of coating for historical relic's protection, it is made of the raw material of following parts by weight: 500 parts of organic solvent, styrene-acrylic emulsion
100 parts, 30 parts of isothiazolinone, 35 parts of quaternary ammonium salt bactericide, 50 parts of castor oil, 100 parts of ethyl alcohol, septichen phenyl ester 15
Part, 25 parts of dispersing agent, is filled out 75 parts of acrylic emulsion, 45 parts of polyurethane, 10 parts of polychloroprene latex, 10 parts of volatilizer, 5 parts of defoaming agent
Fill 80 parts of agent, 400 parts of deionized water.Its preparation method comprises the steps of: one, fetches organic solvent, place it in from
In center device, and styrene-acrylic emulsion is added, starts centrifugal work, the speed of centrifugation is 500r/min, the when a length of 0.3H- of centrifugation
0.5H;Two, the mixture after centrifugation is placed in blender, and under oxygen-free environment, isothiazolinone, stirring speed is added
Degree is 300r/min, during which the when a length of 0.6H of stirring is added quaternary ammonium salt bactericide every 0.1H, after all adding, will stir
Speed is improved to 900r/min, stirs 0.3H-0.5H;Three, the mixture after having stirred is placed at low ambient temperatures, is successively put
Enter ethyl alcohol, castor oil, stirs rapidly, and stand;Four, by the rapid temperature raising of mixture after standing, 65 degrees Celsius are lifted temperature to, is added
Septichen phenyl ester, allows its natural reaction, when reaction a length of 1H, during which every 10 degrees Celsius of 0.2H temperature raising;Five, it is reacting
Acrylic emulsion is added in mixture after complete, dispersing agent is placed into after uniform stirring, 125 degrees Celsius of temperature is kept, to it
Sufficiently reaction;Six, reacted mixture is cooled to 35 degrees Celsius, and is put into polyurethane, uniform stirring 0.2H adds chlorine
Fourth latex stirs 0.5H, and is placed in furnace, and temperature boils 0.2H;Seven, the mixture natural cooling after boiling temperature adds after having cooled down
Enter deionized water dilution, volatilizer is added in dilution, completes the preparation of coating.
Isothiazolinone: key by disconnecting bacterium and algae protein matter, which serves, kills livestock, and contacts with microorganism
Afterwards, it promptly can irreversibly inhibit its growth, so as to cause the death of microbial cell, therefore have to bacterium, fungi, algae etc.
There are very strong inhibition and killing effect.
Quaternary ammonium salt bactericide is mainly that cation passes through electrostatic force, hydrogen bond force and surfactant molecule and protein point
Hydrophobic binding between son adsorbs electronegative bacterial body, is gathered on cell wall, generating chamber's inhibition effect, cause bacterial growth by
Suppression and it is dead;Its hydrophobic alkyl can also be acted on the hydrophilic group of bacterium simultaneously, change the permeability of film, and lysis then occurs and makees
With destruction eucaryotic cell structure causes the dissolution and death of cell;With influence, use efficient, less toxic, do not change vulnerable to pH value
Conveniently, there is the features such as stronger release effect, stable chemical performance, preferable dispersion and corrosion inhibition to rete malpighii.
Septichen phenyl ester is a kind of organic compound, and molecular formula is C13H10O3, can absorb ultraviolet light.
Acrylic emulsion is used for silk fabrics, leather finishing agent;The processing of finishing agent, paper for photo printing paper
Agent;For timber, plank, floor transparent confinement priming paint;For metal water paint, the binder of plastics water paint;For high score
Sub- material antistatic agent, the flocculant of sewage, petroleum Solid Free Drilling additives.
Polyurethane mechanical strength with higher and oxidation stability;Flexibility with higher and resilience;With excellent
Good oil resistivity, solvent resistance, water resistance and fire resistance;Tool has been widely used.
Polychloroprene latex performance is stablized, and acid and alkali corrosion can be resisted;Anti-permeability performance is superior, and cohesive force is strong, is usually applied to waterproof
Antiseptic project.
Deionized water refers to the pure water eliminated in after ionic species impurity.
Castor oil is the glyceryl ester of fatty acid, and castor oil is present in the seed of castor-oil plant, and content is 35%~57.% "
With squeeze or solvent extraction be made castor oil;It being calculated by hydroxyl, castor oil contains 70% three-functionality-degree and 30% two degrees of functionality,
Hydroxyl average functionality is 2.7;It is that the adhesive for polyurethane that raw material manufactures has preferable cryogenic property, hydrolysis with castor oil
Property and excellent electrical insulating property.
Styrene-acrylic emulsion is to be obtained by styrene and acrylate monomer through emulsion copolymerization;Its is water-fast, alkaline-resisting, scrub resistance energy
It is good.
Embodiment 2
Difference of the present embodiment from embodiment 1 is that it is made of the raw material of following parts by weight: 700 parts of organic solvent, benzene
115 parts of acrylic emulsion, 50 parts of isothiazolinone, 55 parts of quaternary ammonium salt bactericide, 65 parts of castor oil, 110 parts of ethyl alcohol, septichen
35 parts of phenyl ester, 85 parts of acrylic emulsion, 55 parts of polyurethane, 50 parts of polychloroprene latex, 20 parts of volatilizer, 15 parts of defoaming agent, dispersing agent
30 parts, 90 parts of filler, 600 parts of deionized water.Other raw material compositions, preparation method are same as Example 1.
Embodiment 3
Difference of the present embodiment from embodiment 1 is that it is made of the raw material of following parts by weight: 900 parts of organic solvent, benzene
130 parts of acrylic emulsion, 0 part of isothiazolinone, 75 parts of quaternary ammonium salt bactericide, 80 parts of castor oil, 120 parts of ethyl alcohol, septichen
55 parts of phenyl ester, 95 parts of acrylic emulsion, 65 parts of polyurethane, 90 parts of polychloroprene latex, 30 parts of volatilizer, 25 parts of defoaming agent, dispersing agent
40 parts, 100 parts of filler, 800 parts of deionized water.Other raw material compositions, preparation method are same as Example 1.
After adopting the above technical scheme, the invention has the following beneficial effects: cleaning often step it is simple, cleaning effect is excellent, energy
Good bactericidal effect is played to historical relic, guarantor's color can be carried out to historical relic, be able to extend the characteristic of historical relic, antiultraviolet is strong, historical relic
Resistance to oxidation, waterproof, not moisture-sensitive, wear-resisting property is strong, has fire resisting, offers convenience to historical relic's protection, can be complete by historical relic
Masses are showed, prevent historical relic from losing.
The above is only used to illustrate the technical scheme of the present invention and not to limit it, and those of ordinary skill in the art are to this hair
The other modifications or equivalent replacement that bright technical solution is made, as long as it does not depart from the spirit and scope of the technical scheme of the present invention,
It is intended to be within the scope of the claims of the invention.
Claims (9)
1. a kind of coating for historical relic's protection, it is characterised in that it is made of the raw material of following parts by weight: organic solvent
500-900 parts, 100-130 parts of styrene-acrylic emulsion, 30-70 parts of isothiazolinone, 35-75 parts of quaternary ammonium salt bactericide, castor oil 50-80
Part, 100-120 parts of ethyl alcohol, 15-55 parts of septichen phenyl ester, 75-95 parts of acrylic emulsion, 45-65 parts of polyurethane, neoprene
10-90 parts of latex, 10-30 parts of volatilizer, 5-25 parts of defoaming agent, 25-40 parts of dispersing agent, 80-100 parts of filler, deionized water
400-800 parts.
2. a kind of preparation method for coating for historical relic's protection, it is characterised in that it comprises the steps of: one, fetch organic solvent,
It places it in centrifugal device, and styrene-acrylic emulsion is added, start centrifugal work, the speed of centrifugation is 500r/min, centrifugation
Shi Changwei 0.3H-0.5H;Two, the mixture after centrifugation is placed in blender, and under oxygen-free environment, isothiazole is added
During which quaternary ammonium salt bactericide is added every 0.1H in quinoline ketone, mixing speed 300r/min, the when a length of 0.6H of stirring, all plus
After complete, mixing speed is improved to 900r/min, 0.3H-0.5H is stirred;Three, the mixture after having stirred is placed on low temperature ring
Under border, it is sequentially placed into ethyl alcohol, castor oil, is stirred rapidly, and stand;Four, by the rapid temperature raising of mixture after standing, 65 are lifted temperature to
Degree Celsius, septichen phenyl ester is added, allows its natural reaction, when reaction a length of 1H, it is during which Celsius every 0.2H temperature raising 10
Degree;Five, acrylic emulsion is added in the mixture after having reacted, dispersing agent is placed into after uniform stirring, is kept for 125 degrees Celsius
Temperature, sufficiently reacted to it;Six, reacted mixture is cooled to 35 degrees Celsius, and is put into polyurethane, uniform stirring
0.2H adds polychloroprene latex, stirs 0.5H, and be placed in furnace, temperature boils 0.2H;Seven, the mixture after boiling temperature is naturally cold
But, deionized water dilution is added after having cooled down, volatilizer is added in dilution, completes the preparation of coating.
3. a kind of coating for historical relic's protection according to claim 1, it is characterised in that it is by following parts by weight
Raw material composition: 500 parts of organic solvent, 100 parts of styrene-acrylic emulsion, 30 parts of isothiazolinone, 35 parts of quaternary ammonium salt bactericide, castor oil 50
Part, 100 parts of ethyl alcohol, 15 parts of septichen phenyl ester, 75 parts of acrylic emulsion, 45 parts of polyurethane, 10 parts of polychloroprene latex, volatilization
10 parts of agent, 5 parts of defoaming agent, 25 parts of dispersing agent, 80 parts of filler, 400 parts of deionized water.
4. a kind of coating for historical relic's protection according to claim 1, it is characterised in that it is by following parts by weight
Raw material composition: 700 parts of organic solvent, 115 parts of styrene-acrylic emulsion, 50 parts of isothiazolinone, 55 parts of quaternary ammonium salt bactericide, castor oil 65
Part, 110 parts of ethyl alcohol, 35 parts of septichen phenyl ester, 85 parts of acrylic emulsion, 55 parts of polyurethane, 50 parts of polychloroprene latex, volatilization
20 parts of agent, 15 parts of defoaming agent, 30 parts of dispersing agent, 90 parts of filler, 600 parts of deionized water.
5. a kind of coating for historical relic's protection according to claim 1, it is characterised in that it is by following parts by weight
Raw material composition: 900 parts of organic solvent, 130 parts of styrene-acrylic emulsion, 0 part of isothiazolinone, 75 parts of quaternary ammonium salt bactericide, castor oil 80
Part, 120 parts of ethyl alcohol, 55 parts of septichen phenyl ester, 95 parts of acrylic emulsion, 65 parts of polyurethane, 90 parts of polychloroprene latex, volatilization
30 parts of agent, 25 parts of defoaming agent, 40 parts of dispersing agent, 100 parts of filler, 800 parts of deionized water.
6. a kind of coating for historical relic's protection according to claim 1, it is characterised in that: the organic solvent is isopropyl
Alcohol.
7. a kind of preparation method for coating for historical relic's protection according to claim 2, it is characterised in that: the step 1
In filler is added after styrene-acrylic emulsion is added.
8. a kind of preparation method for coating for historical relic's protection according to claim 2, it is characterised in that: the step 2
In defoaming agent is added after isothiazolinone is added.
9. a kind of preparation method for coating for historical relic's protection according to claim 2, it is characterised in that: the step 3
In low temperature environment be 0 degree Celsius -10 degrees Celsius of temperature environment.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN112831227A (en) * | 2020-12-31 | 2021-05-25 | 河南蓝翎环科防水材料有限公司 | Nano-polymer cultural relic waterproof protective coating and production process thereof |
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CN104387875A (en) * | 2014-11-26 | 2015-03-04 | 昆山瑞昱化工有限公司 | Environment-friendly waterproof paint |
CN107118648A (en) * | 2017-07-04 | 2017-09-01 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
CN107141919A (en) * | 2017-06-12 | 2017-09-08 | 杭州裕昌成建筑材料有限公司 | A kind of photosensitive coating and its preparation technology |
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CN101024748A (en) * | 2006-02-23 | 2007-08-29 | 富思特制漆(北京)有限公司 | Base paint for cultural-relic protection and preparing method therefor |
CN102382535A (en) * | 2011-08-19 | 2012-03-21 | 石宇 | Waterproof paint film |
CN104387875A (en) * | 2014-11-26 | 2015-03-04 | 昆山瑞昱化工有限公司 | Environment-friendly waterproof paint |
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CN107118648A (en) * | 2017-07-04 | 2017-09-01 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
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CN112831227A (en) * | 2020-12-31 | 2021-05-25 | 河南蓝翎环科防水材料有限公司 | Nano-polymer cultural relic waterproof protective coating and production process thereof |
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Application publication date: 20190726 |