CN110159148A - A kind of timber that moisture-proof, antibiotic effect is good - Google Patents

A kind of timber that moisture-proof, antibiotic effect is good Download PDF

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Publication number
CN110159148A
CN110159148A CN201810251488.3A CN201810251488A CN110159148A CN 110159148 A CN110159148 A CN 110159148A CN 201810251488 A CN201810251488 A CN 201810251488A CN 110159148 A CN110159148 A CN 110159148A
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China
Prior art keywords
parts
proof
timber
good
moisture
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Granted
Application number
CN201810251488.3A
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Chinese (zh)
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CN110159148B (en
Inventor
吴东君
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ZHEJIANG YIMEIDA DOOR INDUSTRY Co Ltd
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ZHEJIANG YIMEIDA DOOR INDUSTRY Co Ltd
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Publication of CN110159148A publication Critical patent/CN110159148A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B29/005Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material next to another layer of paper or cardboard layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/63Additives non-macromolecular organic
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/30Coverings, e.g. protecting against weather, for decorative purposes
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/70Door leaves
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/70Door leaves
    • E06B3/7001Coverings therefor; Door leaves imitating traditional raised panel doors, e.g. engraved or embossed surfaces, with trim strips applied to the surfaces
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/70Door leaves
    • E06B3/72Door leaves consisting of frame and panels, e.g. of raised panel type
    • E06B3/74Door leaves consisting of frame and panels, e.g. of raised panel type with wooden panels or frame
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2250/00Layers arrangement
    • B32B2250/26All layers being made of paper or paperboard
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2286Oxides; Hydroxides of metals of silver
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/38Boron-containing compounds
    • C08K2003/387Borates
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B3/00Window sashes, door leaves, or like elements for closing wall or like openings; Layout of fixed or moving closures, e.g. windows in wall or like openings; Features of rigidly-mounted outer frames relating to the mounting of wing frames
    • E06B3/70Door leaves
    • E06B2003/7049Specific panel characteristics
    • E06B2003/7053Specific panel characteristics corrugated

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Civil Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Laminated Bodies (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention discloses a kind of timber that moisture-proof, antibiotic effect is good, including front panel, rear panel, side sealing, side strip, end edge item, and connects the inner frame formed with end edge item by side sealing, side strip;The front panel includes corrugated board, and the decorative layer above corrugated board is set, the corrugated board includes upper layer cardboard, and be arranged in it is below the cardboard of upper layer and with upper layer cardboard lower layer paperboard disposed in parallel, and it is vertically arranged being between upper paper plate and lower layer paperboard and is in the equally distributed intermediate core of honeycomb, the decorative layer is melamine plate, and the surface of the decorative layer is coated with antibacterial paint vehicle;The timber shockproof properties are good, have the advantages that damp-proof and moth-proof and antibacterial and mouldproof, and anti-pressure ability is strong, is unlikely to deform, and light-weight, recyclable recycling.

Description

A kind of timber that moisture-proof, antibiotic effect is good
Technical field
The present invention relates to a kind of timbers that moisture-proof, antibiotic effect is good.
Background technique
Wooden door used in China's building field is generally divided into log door and filled type Combined wooden door at present, log door by In all being manufactured with timber, a large amount of forest reserves need to be consumed, in the today for increasingly focusing on environmental protection, in some insignificant fields, Log door is gradually filled replaced formula composite door, and log door is now mostly used in a small number of top-grade buildings;Filled type Combined wooden door Surface decoration layer is generally paster, wood skin, and surface layer is made of the high-density plate that solid wood or wood fragments bits are pressed into, the material of sandwich layer filling Generally wood fragments bits, leftover pieces reduce lumber consumption though this Combined wooden door can reduce the manufacturing cost of timber, due to The problems such as material of sandwich layer filling is mostly light material, and anti-pressure ability is weaker, easily-deformable after being moistened;If in more humidity Place uses this Combined wooden door, and timber deformation is big, service life is short, while timber is easy to happen the problem of damaging by worms.
Therefore, it is good to seek a kind of shockproof properties, has the advantages that damp-proof and moth-proof and antibacterial and mouldproof, anti-pressure ability is strong, is not easy Deformation, and light-weight, the recyclable timber recycled is meaningful.
Summary of the invention
In view of this, that it is an object of the present invention to provide a kind of shockproof properties is good, have the advantages that damp-proof and moth-proof and antibacterial and mouldproof, Anti-pressure ability is strong, is unlikely to deform, and light-weight, the recyclable timber recycled.
In order to solve the above-mentioned technical problem, the technical scheme is that
A kind of timber that moisture-proof, antibiotic effect is good, including front panel, rear panel, side sealing, side strip, end edge item, and by Side sealing, side strip connect the inner frame to be formed with end edge item;The front panel includes corrugated board, and is arranged in corrugation Decorative layer above cardboard, the corrugated board include upper layer cardboard, and below the cardboard of upper layer and and upper paper is arranged in Plate lower layer paperboard disposed in parallel, and be vertically arranged being between upper paper plate and lower layer paperboard and uniformly divide in honeycomb The intermediate core of cloth, the decorative layer are melamine plate, and the surface of the decorative layer is coated with antibacterial paint vehicle.
Preferably, the antibacterial paint vehicle is made of the raw material that following parts by weight match: bisphenol A epoxide resin 20-30 Part, 2-4 parts of furfuryl alcohol resin, 3-5 parts of dravite powder, 3-5 parts of elbaite powder, 3-5 parts of borax, 1-3 parts of leaf of bamboo phenolic ketone, hydroxyl second 12-14 parts of base cellulose, 2-4 parts of calcium carbonate, 1-3 parts of nano phase ag_2 o, 8-10 parts of ethyl alcohol, 6-8 parts of dimethyl silicone polymer, pyrrole 4-6 parts of pyridine thioketones zinc, 1-3 parts of waterglass, 1-3 parts of 2,4-DihydroxyBenzophenone and 70-80 parts of deionized water.
Preferably, being provided with crossbeam in the inner frame, it is provided between two adjacent beams and is used to support cross The vertical beam of beam.
Preferably, all being connected by stake-fastening between the side sealing, side strip and end edge item.
Preferably, the front panel, rear panel and side sealing, side strip and end edge item are close by high temperature hot pressing viscose glue Fitting setting.
Preferably, the intermediate core passes through bonding connection with upper layer cardboard and lower layer paperboard respectively.
Preferably, the rear panel is consistent with the structure of front panel.
Another technical problem to be solved by the invention is to provide a kind of preparation method of antibacterial paint vehicle, comprising the following steps:
1) 20-30 parts of bisphenol A epoxide resin, 2-4 parts of furfuryl alcohol resin, 12-14 parts of hydroxyethyl cellulose and deionized water are taken 70-80 parts are put into reaction kettle, under conditions of 110-120 DEG C, stir 20-30min with the speed of 80-100r/min, are made Mixture A, it is spare;
2) 3-5 parts of borax, 1-3 parts of leaf of bamboo phenolic ketone, 1-3 parts of nano phase ag_2 o, 4-6 parts of zinc pyrithione and ethyl alcohol 8-10 are taken It part is put into container, is stirred 5-7 minutes using material-compound tank with the speed of 30-40r/min, make borax, leaf of bamboo phenolic ketone, nano oxidized Silver, zinc pyrithione and ethyl alcohol are uniformly mixed, and antibacterial agent is made, spare;
3) 2-4 parts of calcium carbonate, 3-5 parts of dravite powder, elbaite are sequentially added in the mixture A that step 1) obtains 3-5 parts of powder, 6-8 parts of dimethyl silicone polymer and 1-3 parts of waterglass stir 40-50min under conditions of 80-90 DEG C, are made Mixture B, it is spare;
4) when the temperature for the mixture B that step 3) obtains is cooled to 40-50 DEG C, the antibacterial agent that step 2) is obtained is added Wherein, it is then added 2,4-DihydroxyBenzophenone 1-3 parts, and 20-30min is stirred with the speed of 120-140r/min, is made Paint vehicle is mixed, it is spare;
5) the mixing paint vehicle that step 4) obtains is poured out from reaction kettle, and is statically placed under germ-free condition, is cooled to room temperature, Then it is carried out canned and sealed up for safekeeping to get antibacterial paint vehicle.
The technology of the present invention effect major embodiment is in the following areas: by upper layer cardboard, and be arranged in it is below the cardboard of upper layer and With upper layer cardboard lower layer paperboard disposed in parallel, and it is vertically arranged being between upper paper plate and lower layer paperboard and in honeycomb The corrugated board of the equally distributed intermediate core composition of shape is not only light-weight, and anti-pressure ability is good, and being capable of damp-proof and moth-proof, antidetonation effect Fruit is good;Crossbeam and vertical beam are provided in inner frame, crossbeam and plastics are arranged in cross, after arrangement is uniform, can pass through cross Mutual stress between beam and vertical beam, is distributed to stress on each beam, strengthens the stress intensity of timber, it is not easy to deform;Dress Decorations layer is melamine plate, can play certain flame retardant effect, while the surface of decorative layer is coated with antibacterial paint vehicle, antimicrobial paint Material by bisphenol A epoxide resin, furfuryl alcohol resin, dravite powder, elbaite powder, borax, leaf of bamboo phenolic ketone, hydroxyethyl cellulose, Calcium carbonate, nano phase ag_2 o, ethyl alcohol, dimethyl silicone polymer, zinc pyrithione, waterglass, 2,4-DihydroxyBenzophenone and Deionized water is made, wherein using bisphenol A epoxide resin and furfuryl alcohol resin as basic material, and add with outer infrared emittance With compared with high-negative ion dravite powder and elbaite powder and calcium carbonate with high hardness as filler, and be added by borax, Antibacterial agent made of leaf of bamboo phenolic ketone, nano phase ag_2 o, zinc pyrithione and ethyl alcohol, by dispersing agent, levelling agent and ultraviolet radiation absorption Agent hydroxyethyl cellulose, dimethyl silicone polymer, waterglass and 2,4-DihydroxyBenzophenone, and by the specific side of the present invention Method is prepared, durable antibacterial effect, is able to suppress the growth of microorganism, and adhesive force is strong, good film-forming property, will not be because of the external world Other factors and generate peeling and colour fading, can effective protection timber, while will not be detrimental to health.
Detailed description of the invention
Fig. 1 is a kind of structural schematic diagram for the timber that moisture-proof, antibiotic effect is good of the present invention;
Fig. 2 is a kind of cross-sectional view of the corrugated board for the timber that moisture-proof, antibiotic effect is good of the present invention;
Fig. 3 is a kind of vertical view of the intermediate core of the corrugated board for the timber that moisture-proof, antibiotic effect is good laid flat of the present invention Figure.
Specific embodiment
Below in conjunction with attached drawing 1-3, a specific embodiment of the invention is described in further detail, so that technical solution of the present invention It is more readily understood and grasps.
In the present embodiment, it is to be understood that term " centre ", "upper", "lower", " top ", " right side ", " left end ", " top ", " back side ", " middle part ", etc. instructions orientation or positional relationship be based on the orientation or positional relationship shown in the drawings, only It is of the invention for ease of description, rather than the device or element of indication or suggestion meaning must have a particular orientation, with spy Fixed orientation construction and operation, therefore be not considered as limiting the invention.
In addition, the connection or fixed form between component if not otherwise specified in this embodiment, connection or solid Determine mode can for fixed by bolt commonly used in the prior art or pin fix or pin shaft connection etc. modes, therefore, this It is not described in detail in embodiment.
Embodiment 1
A kind of timber that moisture-proof, antibiotic effect is good, as shown in Figure 1, including front panel 1, rear panel, side sealing 2, side strip 3, end edge item 4, and the inner frame formed, the side sealing 2, side strip 3 are connected by side sealing 2, side strip 3 and end edge item 4 It is all connect by stake-fastening between end edge item 4, the front panel 1, rear panel and side sealing 2, side strip 3 and end edge item 4 Setting is fitted closely by high temperature hot pressing viscose glue, the rear panel is consistent with the structure of front panel 1;The front panel 1 includes Corrugated board 11, and the decorative layer 12 of 11 top of corrugated board is set, the decorative layer 12 is melamine plate, the decoration The surface of layer 12 is coated with antibacterial paint vehicle;It is provided with crossbeam 5 in the inner frame, is provided between two adjacent beams 5 Be used to support the vertical beam 6 of crossbeam 5, mutually fixed between crossbeam 5 and vertical beam 6 by screw, crossbeam 5 and vertical beam 4 in be arranged cross by Power is uniform, plays the role of preventing timber from deforming.
As Figure 2-3, the corrugated board 11 includes upper layer cardboard 111, and is arranged below upper layer cardboard 111 And with the lower layer paperboard 112 disposed in parallel of upper layer cardboard 111, and be vertically arranged and be upper paper plate 111 and lower layer paperboard It is between 112 and be in the equally distributed intermediate core 113 of honeycomb, the intermediate core 113 respectively with upper layer cardboard 111 and Lower layer paperboard 112 passes through bonding connection.Intermediate core 5 is uniformly distributed in honeycomb, and corrugated board 2 is enable very effectively to divide Stress, and corrugated board 2 has certain width, and the anti-pressure ability of itself is also good, and material is light, will not increase very much Add the weight of timber.
The antibacterial paint vehicle is made of the raw material that following parts by weight match: 30 parts of bisphenol A epoxide resin, furfuryl alcohol resin 4 Part, 5 parts of dravite powder, 5 parts of elbaite powder, 5 parts of borax, 3 parts of leaf of bamboo phenolic ketone, 14 parts of hydroxyethyl cellulose, calcium carbonate 4 Part, 3 parts of nano phase ag_2 o, 10 parts of ethyl alcohol, 8 parts of dimethyl silicone polymer, 6 parts of zinc pyrithione, 3 parts of waterglass, 2,4- dihydroxy 3 parts and 80 parts of deionized water of base benzophenone.
A kind of preparation method of antibacterial paint vehicle, comprising the following steps:
1) 30 parts of bisphenol A epoxide resin, 4 parts of furfuryl alcohol resin, 14 parts of hydroxyethyl cellulose and 80 parts of deionized water is taken to be put into In reaction kettle, under conditions of 120 DEG C, 30min is stirred with the speed of 100r/min, mixture A is made, it is spare;
2) 5 parts of borax, 3 parts of leaf of bamboo phenolic ketone, 3 parts of nano phase ag_2 o, 6 parts of zinc pyrithione and 10 parts of ethyl alcohol is taken to be put into container It is interior, stirred 7 minutes using material-compound tank with the speed of 40r/min, make borax, leaf of bamboo phenolic ketone, nano phase ag_2 o, zinc pyrithione and Ethyl alcohol is uniformly mixed, and antibacterial agent is made, spare;
3) 4 parts of calcium carbonate, 5 parts of dravite powder, elbaite powder 5 are sequentially added in the mixture A that step 1) obtains Part, 8 parts of dimethyl silicone polymer and 3 parts of waterglass stir 50min under conditions of 90 DEG C, and mixture B is made, spare;
4) when the temperature for the mixture B that step 3) obtains is cooled to 50 DEG C, it is added in the antibacterial agent that step 2) is obtained In, 3 parts of 2,4-DihydroxyBenzophenone are then added, and 30min is stirred with the speed of 140r/min, mixing paint vehicle is made, it is standby With;
5) the mixing paint vehicle that step 4) obtains is poured out from reaction kettle, and is statically placed under germ-free condition, is cooled to room temperature, Then it is carried out canned and sealed up for safekeeping to get antibacterial paint vehicle.
Embodiment 2
A kind of timber that moisture-proof, antibiotic effect is good, as shown in Figure 1, including front panel 1, rear panel, side sealing 2, side strip 3, end edge item 4, and the inner frame formed, the side sealing 2, side strip 3 are connected by side sealing 2, side strip 3 and end edge item 4 It is all connect by stake-fastening between end edge item 4, the front panel 1, rear panel and side sealing 2, side strip 3 and end edge item 4 Setting is fitted closely by high temperature hot pressing viscose glue, the rear panel is consistent with the structure of front panel 1;The front panel 1 includes Corrugated board 11, and the decorative layer 12 of 11 top of corrugated board is set, the decorative layer 12 is melamine plate, the decoration The surface of layer 12 is coated with antibacterial paint vehicle;It is provided with crossbeam 5 in the inner frame, is provided between two adjacent beams 5 Be used to support the vertical beam 6 of crossbeam 5, mutually fixed between crossbeam 5 and vertical beam 6 by screw, crossbeam 5 and vertical beam 4 in be arranged cross by Power is uniform, plays the role of preventing timber from deforming.
As Figure 2-3, the corrugated board 11 includes upper layer cardboard 111, and is arranged below upper layer cardboard 111 And with the lower layer paperboard 112 disposed in parallel of upper layer cardboard 111, and be vertically arranged and be upper paper plate 111 and lower layer paperboard It is between 112 and be in the equally distributed intermediate core 113 of honeycomb, the intermediate core 113 respectively with upper layer cardboard 111 and Lower layer paperboard 112 passes through bonding connection.Intermediate core 5 is uniformly distributed in honeycomb, and corrugated board 2 is enable very effectively to divide Stress, and corrugated board 2 has certain width, and the anti-pressure ability of itself is also good, and material is light, will not increase very much Add the weight of timber.
The antibacterial paint vehicle is made of the raw material that following parts by weight match: 20 parts of bisphenol A epoxide resin, furfuryl alcohol resin 2 Part, 3 parts of dravite powder, 3 parts of elbaite powder, 3 parts of borax, 1 part of leaf of bamboo phenolic ketone, 12 parts of hydroxyethyl cellulose, calcium carbonate 2 Part, 1 part of nano phase ag_2 o, 8 parts of ethyl alcohol, 6 parts of dimethyl silicone polymer, 4 parts of zinc pyrithione, 1 part of waterglass, 2,4- dihydroxy 1 part and 70 parts of deionized water of benzophenone.
A kind of preparation method of antibacterial paint vehicle, comprising the following steps:
1) 20 parts of bisphenol A epoxide resin, 2 parts of furfuryl alcohol resin, 12 parts of hydroxyethyl cellulose and 70 parts of deionized water is taken to be put into In reaction kettle, under conditions of 110 DEG C, 20min is stirred with the speed of 80r/min, mixture A is made, it is spare;
2) 3 parts of borax, 1 part of leaf of bamboo phenolic ketone, 1 part of nano phase ag_2 o, 4 parts of zinc pyrithione and 8 parts of ethyl alcohol is taken to be put into container It is interior, stirred 5 minutes using material-compound tank with the speed of 30r/min, make borax, leaf of bamboo phenolic ketone, nano phase ag_2 o, zinc pyrithione and Ethyl alcohol is uniformly mixed, and antibacterial agent is made, spare;
3) 2 parts of calcium carbonate, 3 parts of dravite powder, elbaite powder 3 are sequentially added in the mixture A that step 1) obtains Part, 6 parts of dimethyl silicone polymer and 1 part of waterglass stir 40min under conditions of 80 DEG C, and mixture B is made, spare;
4) when the temperature for the mixture B that step 3) obtains is cooled to 40 DEG C, it is added in the antibacterial agent that step 2) is obtained In, it is then added 1 part of 2,4-DihydroxyBenzophenone, and 20min is stirred with the speed of 120r/min, mixing paint vehicle is made, it is standby With;
5) the mixing paint vehicle that step 4) obtains is poured out from reaction kettle, and is statically placed under germ-free condition, is cooled to room temperature, Then it is carried out canned and sealed up for safekeeping to get antibacterial paint vehicle.
Embodiment 3
A kind of timber that moisture-proof, antibiotic effect is good, as shown in Figure 1, including front panel 1, rear panel, side sealing 2, side strip 3, end edge item 4, and the inner frame formed, the side sealing 2, side strip 3 are connected by side sealing 2, side strip 3 and end edge item 4 It is all connect by stake-fastening between end edge item 4, the front panel 1, rear panel and side sealing 2, side strip 3 and end edge item 4 Setting is fitted closely by high temperature hot pressing viscose glue, the rear panel is consistent with the structure of front panel 1;The front panel 1 includes Corrugated board 11, and the decorative layer 12 of 11 top of corrugated board is set, the decorative layer 12 is melamine plate, the decoration The surface of layer 12 is coated with antibacterial paint vehicle;It is provided with crossbeam 5 in the inner frame, is provided between two adjacent beams 5 Be used to support the vertical beam 6 of crossbeam 5, mutually fixed between crossbeam 5 and vertical beam 6 by screw, crossbeam 5 and vertical beam 4 in be arranged cross by Power is uniform, plays the role of preventing timber from deforming.
As Figure 2-3, the corrugated board 11 includes upper layer cardboard 111, and is arranged below upper layer cardboard 111 And with the lower layer paperboard 112 disposed in parallel of upper layer cardboard 111, and be vertically arranged and be upper paper plate 111 and lower layer paperboard It is between 112 and be in the equally distributed intermediate core 113 of honeycomb, the intermediate core 113 respectively with upper layer cardboard 111 and Lower layer paperboard 112 passes through bonding connection.Intermediate core 5 is uniformly distributed in honeycomb, and corrugated board 2 is enable very effectively to divide Stress, and corrugated board 2 has certain width, and the anti-pressure ability of itself is also good, and material is light, will not increase very much Add the weight of timber.
The antibacterial paint vehicle is made of the raw material that following parts by weight match: 25 parts of bisphenol A epoxide resin, furfuryl alcohol resin 3 Part, 4 parts of dravite powder, 4 parts of elbaite powder, 4 parts of borax, 2 parts of leaf of bamboo phenolic ketone, 13 parts of hydroxyethyl cellulose, calcium carbonate 3 Part, 2 parts of nano phase ag_2 o, 9 parts of ethyl alcohol, 7 parts of dimethyl silicone polymer, 5 parts of zinc pyrithione, 2 parts of waterglass, 2,4- dihydroxy 2 parts and 75 parts of deionized water of benzophenone.
A kind of preparation method of antibacterial paint vehicle, comprising the following steps:
1) 25 parts of bisphenol A epoxide resin, 3 parts of furfuryl alcohol resin, 13 parts of hydroxyethyl cellulose and 75 parts of deionized water is taken to be put into In reaction kettle, under conditions of 115 DEG C, 25min is stirred with the speed of 90r/min, mixture A is made, it is spare;
2) 4 parts of borax, 2 parts of leaf of bamboo phenolic ketone, 2 parts of nano phase ag_2 o, 5 parts of zinc pyrithione and 9 parts of ethyl alcohol is taken to be put into container It is interior, stirred 6 minutes using material-compound tank with the speed of 35r/min, make borax, leaf of bamboo phenolic ketone, nano phase ag_2 o, zinc pyrithione and Ethyl alcohol is uniformly mixed, and antibacterial agent is made, spare;
3) 3 parts of calcium carbonate, 4 parts of dravite powder, elbaite powder 4 are sequentially added in the mixture A that step 1) obtains Part, 7 parts of dimethyl silicone polymer and 2 parts of waterglass stir 45min under conditions of 85 DEG C, and mixture B is made, spare;
4) when the temperature for the mixture B that step 3) obtains is cooled to 45 DEG C, it is added in the antibacterial agent that step 2) is obtained In, 2 parts of 2,4-DihydroxyBenzophenone are then added, and 25min is stirred with the speed of 130r/min, mixing paint vehicle is made, it is standby With;
5) the mixing paint vehicle that step 4) obtains is poured out from reaction kettle, and is statically placed under germ-free condition, is cooled to room temperature, Then it is carried out canned and sealed up for safekeeping to get antibacterial paint vehicle.
Experimental example
One, antibacterial test
Experimental subjects: antibacterial paint vehicle made from the embodiment of the present invention 1, embodiment 2 and embodiment 3.
Laboratory Request: meet Laboratory biosafety management as defined in GB 19489 and implementation condition requirement:
Experimental method: detection method passes through quantitative inoculation Escherichia coli ATYCC according to the standard of GBT 21866-2008 25922 and staphylococcus aureus ATCC 6538 makes bacterium uniformly contact template on template to be tested with the method for pad pasting, After culture in 24 hours, the viable count in template is detected, and calculate the antibacterium rate of template.
Table 1 is the anti-bacteria test result of three groups of paint vehicles:
Table 1
Two, fungus-proof test
Experimental subjects: antibacterial paint vehicle made from the embodiment of the present invention 1, embodiment 2 and embodiment 3.
Test mould kind: aspergillus niger AS3.4463, Aspergillus terreus AS3.3935, paecilomyces varioti AS3.4253, penicillium funiculosum AS3.3875, Aureobasidium pullulans AS3.3984 and Chaetomium globosum AS3.4254.
Experimental method: antibiotic paint made from the embodiment of equivalent 1, embodiment 2 and embodiment 3 is coated on examines respectively On template, then at above-mentioned mould kind of inspection template coating equivalent, and after 24 hours, mould kind on three groups of coating of growth is observed Situation.
Evaluation criterion: 0 grade is not grown, is amplified observation under 50 times under microscope and is had no growth;1 grade i.e. trace growth and meat Eye visible growth, but area coverage is grown less than 10%;2 grades of i.e. growth area coverages are greater than 10%.
Table 2 is the fungus-proof test result of three groups of paint vehicles:
Table 2
Three, adhesive force is tested
Experimental subjects: antibacterial paint vehicle made from the embodiment of the present invention 1, embodiment 2 and embodiment 3.
Experimental method: coloring is carried out to above-mentioned three groups of coating and adhesive force is tested, adhesive force is tested according to GB/T9286- The cross cut test of 1998 paint and varnish paint films is tested;Coloring by paint vehicle to the absorptivity of paint ink be index into Row test.
Table 3 is the fungus-proof test result of three groups of paint vehicles:
Table 3
Experimental data in conjunction with upper table, in antibacterial test and fungus-proof test, it can be seen that antibacterial paint vehicle produced by the present invention Antibacterial and anti-mold effect are significant, and adhesive force and coloring are good.
The technology of the present invention effect major embodiment is in the following areas: by upper layer cardboard, and be arranged in it is below the cardboard of upper layer and With upper layer cardboard lower layer paperboard disposed in parallel, and it is vertically arranged being between upper paper plate and lower layer paperboard and in honeycomb The corrugated board of the equally distributed intermediate core composition of shape is not only light-weight, and anti-pressure ability is good, and being capable of damp-proof and moth-proof, antidetonation effect Fruit is good;Crossbeam and vertical beam are provided in inner frame, crossbeam and plastics are arranged in cross, after arrangement is uniform, can pass through cross Mutual stress between beam and vertical beam, is distributed to stress on each beam, strengthens the stress intensity of timber, it is not easy to deform;Dress Decorations layer is melamine plate, can play certain flame retardant effect, while the surface of decorative layer is coated with antibacterial paint vehicle, antimicrobial paint Material by bisphenol A epoxide resin, furfuryl alcohol resin, dravite powder, elbaite powder, borax, leaf of bamboo phenolic ketone, hydroxyethyl cellulose, Calcium carbonate, nano phase ag_2 o, ethyl alcohol, dimethyl silicone polymer, zinc pyrithione, waterglass, 2,4-DihydroxyBenzophenone and Deionized water is made, wherein using bisphenol A epoxide resin and furfuryl alcohol resin as basic material, and add with outer infrared emittance With compared with high-negative ion dravite powder and elbaite powder and calcium carbonate with high hardness as filler, and be added by borax, Antibacterial agent made of leaf of bamboo phenolic ketone, nano phase ag_2 o, zinc pyrithione and ethyl alcohol, by dispersing agent, levelling agent and ultraviolet radiation absorption Agent hydroxyethyl cellulose, dimethyl silicone polymer, waterglass and 2,4-DihydroxyBenzophenone, and by the specific side of the present invention Method is prepared, and antibacterial, anti-mold effect are good, is able to suppress the growth of microorganism, and adhesive force is strong, good film-forming property, will not be because of Extraneous other factors and generate peeling and colour fading, can effective protection timber, while will not be detrimental to health.
Certainly, above is representative instance of the invention, and in addition to this, the present invention can also have other a variety of specific implementations Mode, all technical solutions formed using equivalent substitution or equivalent transformation, is all fallen within the scope of protection of present invention.

Claims (7)

1. a kind of timber that moisture-proof, antibiotic effect is good, including front panel, rear panel, side sealing, side strip, end edge item, and by side Edge sealing, side strip connect the inner frame to be formed with end edge item;It is characterized by: the front panel includes corrugated board, and Decorative layer above corrugated board is set, the corrugated board includes upper layer cardboard, and be arranged in it is below the cardboard of upper layer, And with upper layer cardboard lower layer paperboard disposed in parallel, and be vertically arranged being between upper paper plate and lower layer paperboard and in bee The equally distributed intermediate core of nest shape, the decorative layer are melamine plate, and the surface of the decorative layer is coated with antibacterial paint vehicle.
2. a kind of timber that moisture-proof, antibiotic effect is good as described in claim 1, it is characterised in that: the antibacterial paint vehicle is by following The raw material of parts by weight proportion is made: 20-30 parts of bisphenol A epoxide resin, 2-4 parts of furfuryl alcohol resin, 3-5 parts of dravite powder, lithium 3-5 parts of tourmaline powder, 3-5 parts of borax, 1-3 parts of leaf of bamboo phenolic ketone, 12-14 parts of hydroxyethyl cellulose, 2-4 parts of calcium carbonate, nano oxygen Change 1-3 parts of silver, 8-10 parts of ethyl alcohol, 6-8 parts of dimethyl silicone polymer, 4-6 parts of zinc pyrithione, 1-3 parts of waterglass, 2,4- dihydroxy 1-3 parts and deionized water 70-80 parts of base benzophenone.
3. a kind of timber that moisture-proof, antibiotic effect is good as described in claim 1, it is characterised in that: setting in the inner frame There is crossbeam, is provided with the vertical beam for being used to support crossbeam between two adjacent beams.
4. a kind of timber that moisture-proof, antibiotic effect is good as described in claim 1, it is characterised in that: the side sealing, side strip It is all connect by stake-fastening between end edge item.
5. a kind of timber that moisture-proof, antibiotic effect is good as described in claim 1, it is characterised in that: the front panel, rear panel Setting is fitted closely by high temperature hot pressing viscose glue with side sealing, side strip and end edge item.
6. a kind of timber that moisture-proof, antibiotic effect is good as described in claim 1, it is characterised in that: the intermediate core respectively with Upper layer cardboard and lower layer paperboard pass through bonding connection.
7. a kind of timber that moisture-proof, antibiotic effect is good as described in claim 1, it is characterised in that: the rear panel and front panel Structure it is consistent.
CN201810251488.3A 2018-03-26 2018-03-26 Wooden door with moisture-proof and antibacterial effects Active CN110159148B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03180336A (en) * 1989-12-08 1991-08-06 Sekisui Chem Co Ltd Manufacture of fitting made of steel
CN2154900Y (en) * 1993-05-20 1994-02-02 杨二黑 Multifunction steel-wooden structure sub-door
CN2866766Y (en) * 2006-02-10 2007-02-07 马靖 Cabinet door leaves
CN201129117Y (en) * 2007-10-11 2008-10-08 管宝贵 Door panel
CN203729810U (en) * 2013-11-28 2014-07-23 嘉善巨力蜂窝制品有限公司 Wood door
CN107118648A (en) * 2017-07-04 2017-09-01 合肥市大卓电力有限责任公司 A kind of new type environment friendly coating and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH03180336A (en) * 1989-12-08 1991-08-06 Sekisui Chem Co Ltd Manufacture of fitting made of steel
CN2154900Y (en) * 1993-05-20 1994-02-02 杨二黑 Multifunction steel-wooden structure sub-door
CN2866766Y (en) * 2006-02-10 2007-02-07 马靖 Cabinet door leaves
CN201129117Y (en) * 2007-10-11 2008-10-08 管宝贵 Door panel
CN203729810U (en) * 2013-11-28 2014-07-23 嘉善巨力蜂窝制品有限公司 Wood door
CN107118648A (en) * 2017-07-04 2017-09-01 合肥市大卓电力有限责任公司 A kind of new type environment friendly coating and preparation method thereof

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