CN108084869A - A kind of new type environment friendly coating and preparation method thereof - Google Patents
A kind of new type environment friendly coating and preparation method thereof Download PDFInfo
- Publication number
- CN108084869A CN108084869A CN201810066230.6A CN201810066230A CN108084869A CN 108084869 A CN108084869 A CN 108084869A CN 201810066230 A CN201810066230 A CN 201810066230A CN 108084869 A CN108084869 A CN 108084869A
- Authority
- CN
- China
- Prior art keywords
- parts
- new type
- environment friendly
- type environment
- friendly coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of new type environment friendly coating, include the raw material of following parts by weight：15~30 parts of polyurethane acrylic resin, 10~20 parts of epoxy resin, 13~24 parts of glycerine, 8~13 parts of trimethylolpropane, 5~8 parts of trimellitic anhydride, 1~2 part of antifoaming agent, 0.5~1 part of aluminium oxide, 0.6~0.8 part of epoxidized soybean oil, 1~3 part of dipropylene, 1~2 part of ultra-violet absorber, 0.7~1.3 part of levelling agent, 3~5 parts of tourmaline miberal powder, 4~8 parts of modification infusorial earth, 6~12 parts of Concave-convex clay rod, 30~50 parts of deionized water.The new type environment friendly coating has toxic gas and dust, purification air, the effect for improving environment in sterilization, deodorization, absorption air without formaldehyde, benzene etc. harmful substance, is conducive to the life and health of people.
Description
Technical field
The invention belongs to environment-friendly materials technical fields, and in particular to a kind of new type environment friendly coating and preparation method thereof.
Background technology
It is higher and higher to the Environmental Protection Level requirement of fitment material for family with the raising of modern people's living standard.It is existing
Decoration coating type it is various, and to meet the market requirement, coating material production producer is to the R ＆ D Level of environmental protection coating material also not
Disconnected to improve, still, existing environmental protection coating material is not very perfect, and such as only the index of volatile matter is reduced and complies with mark
It is accurate.Although the development trend of coating industry is to reach Diamond Search, the coating of tasteless health, due to being limited to the factors such as technology, city
Almost without the environmental protection coating material of real Diamond Search on face, wherein some harmful substances contained（Such as formaldehyde, benzene class object, heavy metal
Deng）The living environment of people can be seriously affected, and induces many chronic diseases, the life and health of people is caused to be subject to prestige
The side of body.
The content of the invention
The present invention provides a kind of new type environment friendly coatings and preparation method thereof, solve the problems, such as in above-mentioned background technology,
The new type environment friendly coating has toxic gas in sterilization, deodorization, absorption air without formaldehyde, benzene etc. harmful substance
With dust, purification air, the effect for improving environment, be conducive to the life and health of people.
It is existing in the prior art in order to solve the problems, such as, it adopts the following technical scheme that：
A kind of new type environment friendly coating includes the raw material of following parts by weight：15~30 parts of polyurethane acrylic resin, epoxy resin 10
~20 parts, 13~24 parts of glycerine, 8~13 parts of trimethylolpropane, 5~8 parts of trimellitic anhydride, 1~2 part of antifoaming agent, oxygen
Change 0.5~1 part of aluminium, 0.6~0.8 part of epoxidized soybean oil, 1~3 part of dipropylene, 1~2 part of ultra-violet absorber, levelling
0.7~1.3 part of agent, 3~5 parts of tourmaline miberal powder, 4~8 parts of modification infusorial earth, 6~12 parts of Concave-convex clay rod, deionized water 30
~50 parts.
Preferably, the new type environment friendly coating includes the raw material of following parts by weight：Polyurethane acrylic resin 20~26
Part, 13~17 parts of epoxy resin, 15~22 parts of glycerine, 9~11 parts of trimethylolpropane, 6~7 parts of trimellitic anhydride disappear
1.4~1.8 parts of infusion, 0.7~0.9 part of aluminium oxide, 0.63~0.72 part of epoxidized soybean oil, dipropylene 1.5~2.1
Part, 1.3~1.8 parts of ultra-violet absorber, 0.9~1.1 part of levelling agent, 3.3~4.6 parts of tourmaline miberal powder, modification infusorial earth 5~
7 parts, 8~10 parts of Concave-convex clay rod, 35~45 parts of deionized water.
Preferably, the new type environment friendly coating includes the raw material of following parts by weight：25 parts of polyurethane acrylic resin, ring
16 parts of oxygen resin, 18 parts of glycerine, 10 parts of trimethylolpropane, 6.2 parts of trimellitic anhydride, 1.6 parts of antifoaming agent, aluminium oxide
0.8 part, 0.7 part of epoxidized soybean oil, 1.8 parts of dipropylene, 1.4 parts of ultra-violet absorber, 1 part of levelling agent, electrical stone ore
3.8 parts of powder, 6 parts of modification infusorial earth, 9 parts of Concave-convex clay rod, 42 parts of deionized water.
Preferably, the preparation method of the modification infusorial earth, comprises the following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 10~15% sodium hydroxide solution, colophony powder 5
Part, 3 parts of carboxymethyl cellulose；
（2）After the diatomite is put into volumetric concentration for 10~15% sodium hydroxide solutions immersion, 3~4h, then PH is adjusted into
Property；
（3）Take out treated diatomite, water content 3~5% be dried at a temperature of 42~48 DEG C, after immediately add in pine
Face powder is uniformly mixed；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
Preferably, the antifoaming agent is dimethyl silicone polymer.
Preferably, the levelling agent is acrylic compounds levelling agent.
A kind of method for preparing the new type environment friendly coating, includes the following steps：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 10~20 points
Clock, rate of dispersion are 200~300r/min；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 45~55 DEG C, heat preservation is 40~60 minutes scattered, and rate of dispersion is 800~1100r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 10~20 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
Preferably, the step（4）The speed that high speed is disperseed is 1500~2000r/min.
Preferably, the step（5）Middle mixing speed is 200~300r/min, and mixing time is 13~18 minutes.
Compared with prior art, the present invention it has the advantages that：
New type environment friendly coating of the present invention has sterilization, deodorization, absorption sky without formaldehyde, benzene etc. harmful substance
Toxic gas and dust, purification air, the effect for improving environment, are conducive to the life and health of people in gas, specific as follows：
（1）New type environment friendly coating of the present invention is using polyurethane acrylic resin, epoxy resin, glycerine, trihydroxy methyl
Propane, trimellitic anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent,
As raw material, the coating prepared is free of the harmful substances such as formaldehyde, benzene for tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod,
And there is ultra-fine greasy, the plentiful, strong covering power of film quality；
（2）New type environment friendly coating of the present invention can efficiently generate the tourmaline miberal powder of anion, tourmaline due to containing
Miberal powder and polyurethane acrylic resin, epoxy resin, the third three synergistic effects, have rational high score after the coating coating being made out
The compactness extent of sub- film, moisture in air can be touched easily by the anion material in the gap and coating of polymeric membrane
It hits, substantial amounts of hydrone is ionized into hydroxide ion and hydrogen ion, hydrogen under the forceful electric power field action near tourmaline mineral powder granular
Oxygen radical ion enters air, attracts moisture in air, forms hydration hydroxyl ion, is anion, so as to increase in air
The concentration of anion reaches toxic gas and dust in sterilization, deodorization, absorption air, reaches purification air, improves environment
Purpose.
Specific embodiment
With reference to specific embodiment, the present invention is further explained.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：15 parts of polyurethane acrylic resin, ring
10 parts of oxygen resin, 13 parts of glycerine, 8 parts of trimethylolpropane, 5 parts of trimellitic anhydride, 1 part of antifoaming agent, 0.5 part of aluminium oxide,
0.6 part of epoxidized soybean oil, 1 part of dipropylene, 0.7 part of levelling agent, 3 parts of tourmaline miberal powder, change 1 part of ultra-violet absorber
4 parts of diatomite of property, 6 parts of Concave-convex clay rod, 30 parts of deionized water.
Wherein, the preparation method of the modification infusorial earth, comprises the following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 10% sodium hydroxide solution, 5 parts of colophony powder, carboxylic
3 parts of methylcellulose；
（2）After the diatomite is put into volumetric concentration for 10% sodium hydroxide solution immersion 3h, then pH is adjusted to neutrality；
（3）Take out treated diatomite, water content 3% be dried at a temperature of 42 DEG C, after add in immediately colophony powder mixing
Uniformly；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
Wherein, the antifoaming agent is dimethyl silicone polymer.
Wherein, the levelling agent is acrylic compounds levelling agent.
A kind of method for preparing the new type environment friendly coating, includes the following steps：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 10 minutes, point
It is 200r/min to dissipate speed；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 45 DEG C, heat preservation is 40 minutes scattered, rate of dispersion 800r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 10 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
Wherein, the step（4）The speed that high speed is disperseed is 1500r/min.
Wherein, the step（5）Middle mixing speed is 200r/min, and mixing time is 13 minutes.
Embodiment 2
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：30 parts of polyurethane acrylic resin, ring
20 parts of oxygen resin, 24 parts of glycerine, 13 parts of trimethylolpropane, 8 parts of trimellitic anhydride, 2 parts of antifoaming agent, 1 part of aluminium oxide, ring
0.8 part of oxygen soybean oil, 3 parts of dipropylene, 2 parts of ultra-violet absorber, 1.3 parts of levelling agent, 5 parts of tourmaline miberal powder, modification
8 parts of diatomite, 12 parts of Concave-convex clay rod, 50 parts of deionized water.
Wherein, the preparation method of the modification infusorial earth, comprises the following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 15% sodium hydroxide solution, 5 parts of colophony powder, carboxylic
3 parts of methylcellulose；
（2）After the diatomite is put into volumetric concentration for 15% sodium hydroxide solution immersion 4h, then pH is adjusted to neutrality；
（3）Take out treated diatomite, water content 5% be dried at a temperature of 48 DEG C, after add in immediately colophony powder mixing
Uniformly；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
Wherein, the antifoaming agent is dimethyl silicone polymer.
Wherein, the levelling agent is acrylic compounds levelling agent.
A kind of method for preparing the new type environment friendly coating, includes the following steps：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 20 minutes, point
It is 300r/min to dissipate speed；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 55 DEG C, heat preservation is 60 minutes scattered, rate of dispersion 1100r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 20 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
Wherein, the step（4）The speed that high speed is disperseed is 2000r/min.
Wherein, the step（5）Middle mixing speed is 300r/min, and mixing time is 18 minutes.
Embodiment 3
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：20 parts of polyurethane acrylic resin, ring
13 parts of oxygen resin, 15 parts of glycerine, 9 parts of trimethylolpropane, 6 parts of trimellitic anhydride, 1.4 parts of antifoaming agent, aluminium oxide 0.7
Part, 0.63 part of epoxidized soybean oil, 1.5 parts of dipropylene, 1.3 parts of ultra-violet absorber, 0.9 part of levelling agent, electrical stone ore
3.3 parts of powder, 5 parts of modification infusorial earth, 8 parts of Concave-convex clay rod, 35 parts of deionized water.
Wherein, the preparation method of the modification infusorial earth, comprises the following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 11% sodium hydroxide solution, 5 parts of colophony powder, carboxylic
3 parts of methylcellulose；
（2）After the diatomite is put into volumetric concentration for 11% sodium hydroxide solution immersion 3.2h, then pH is adjusted to neutrality；
（3）Take out treated diatomite, water content 3.5% be dried at a temperature of 43 DEG C, after add in colophony powder immediately and mix
It closes uniform；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
Wherein, the antifoaming agent is dimethyl silicone polymer.
Wherein, the levelling agent is acrylic compounds levelling agent.
A kind of method for preparing the new type environment friendly coating, includes the following steps：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 13 minutes, point
It is 220r/min to dissipate speed；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 48 DEG C, heat preservation is 45 minutes scattered, rate of dispersion 900r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 12 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
Wherein, the step（4）The speed that high speed is disperseed is 1800/min.
Wherein, the step（5）Middle mixing speed is 230r/min, and mixing time is 14 minutes.
Embodiment 4
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：26 parts of polyurethane acrylic resin, ring
17 parts of oxygen resin, 22 parts of glycerine, 11 parts of trimethylolpropane, 7 parts of trimellitic anhydride, 1.8 parts of antifoaming agent, aluminium oxide 0.9
Part, 0.72 part of epoxidized soybean oil, 2.1 parts of dipropylene, 1.8 parts of ultra-violet absorber, 1.1 parts of levelling agent, electrical stone ore
4.6 parts of powder, 7 parts of modification infusorial earth, 10 parts of Concave-convex clay rod, 45 parts of deionized water.
Wherein, the preparation method of the modification infusorial earth, comprises the following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 13% sodium hydroxide solution, 5 parts of colophony powder, carboxylic
3 parts of methylcellulose；
（2）After the diatomite is put into volumetric concentration for 13% sodium hydroxide solution immersion 3.5h, then pH is adjusted to neutrality；
（3）Take out treated diatomite, water content 4% be dried at a temperature of 45 DEG C, after add in immediately colophony powder mixing
Uniformly；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
Wherein, the antifoaming agent is dimethyl silicone polymer.
Wherein, the levelling agent is acrylic compounds levelling agent.
A kind of method for preparing the new type environment friendly coating, includes the following steps：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 15 minutes, point
It is 250r/min to dissipate speed；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 50 DEG C, heat preservation is 50 minutes scattered, rate of dispersion 1000r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 15 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
Wherein, the step（4）The speed that high speed is disperseed is 1700r/min.
Wherein, the step（5）Middle mixing speed is 250r/min, and mixing time is 15 minutes.
Embodiment 5
The present embodiment is related to a kind of new type environment friendly coating, includes the raw material of following parts by weight：25 parts of polyurethane acrylic resin, ring
16 parts of oxygen resin, 18 parts of glycerine, 10 parts of trimethylolpropane, 6.2 parts of trimellitic anhydride, 1.6 parts of antifoaming agent, aluminium oxide
0.8 part, 0.7 part of epoxidized soybean oil, 1.8 parts of dipropylene, 1.4 parts of ultra-violet absorber, 1 part of levelling agent, electrical stone ore
3.8 parts of powder, 6 parts of modification infusorial earth, 9 parts of Concave-convex clay rod, 42 parts of deionized water.
Wherein, the preparation method of the modification infusorial earth, comprises the following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 14% sodium hydroxide solution, 5 parts of colophony powder, carboxylic
3 parts of methylcellulose；
（2）After the diatomite is put into volumetric concentration for 14% sodium hydroxide solution immersion 3.8h, then pH is adjusted to neutrality；
（3）Take out treated diatomite, water content 4.5% be dried at a temperature of 47 DEG C, after add in colophony powder immediately and mix
It closes uniform；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
Wherein, the antifoaming agent is dimethyl silicone polymer.
Wherein, the levelling agent is acrylic compounds levelling agent.
A kind of method for preparing the new type environment friendly coating, includes the following steps：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 19 minutes, point
It is 280r/min to dissipate speed；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 52 DEG C, heat preservation is 55 minutes scattered, rate of dispersion 1050r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 18 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
Wherein, the step（4）The speed that high speed is disperseed is 1900r/min.
Wherein, the step（5）Middle mixing speed is 280r/min, and mixing time is 17 minutes.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (9)
1. a kind of new type environment friendly coating, which is characterized in that include the raw material of following parts by weight：Polyurethane acrylic resin 15~30
Part, 10~20 parts of epoxy resin, 13~24 parts of glycerine, 8~13 parts of trimethylolpropane, 5~8 parts of trimellitic anhydride disappear
1~2 part of infusion, 0.5~1 part of aluminium oxide, 0.6~0.8 part of epoxidized soybean oil, 1~3 part of dipropylene, ultraviolet radiation absorption
1~2 part of agent, 0.7~1.3 part of levelling agent, 3~5 parts of tourmaline miberal powder, 4~8 parts of modification infusorial earth, Concave-convex clay rod 6~12
Part, 30~50 parts of deionized water.
2. new type environment friendly coating according to claim 1, which is characterized in that include the raw material of following parts by weight：Polyurethane
20~26 parts of acrylic resin, 13~17 parts of epoxy resin, 15~22 parts of glycerine, 9~11 parts of trimethylolpropane, inclined benzene three
6~7 parts of formic anhydride, 1.4~1.8 parts of antifoaming agent, 0.7~0.9 part of aluminium oxide, 0.63~0.72 part of epoxidized soybean oil, dipropyl two
1.5~2.1 parts of alcohol butyl ether, 1.3~1.8 parts of ultra-violet absorber, 0.9~1.1 part of levelling agent, tourmaline miberal powder 3.3~4.6
Part, 5~7 parts of modification infusorial earth, 8~10 parts of Concave-convex clay rod, 35~45 parts of deionized water.
3. new type environment friendly coating according to claim 1, which is characterized in that include the raw material of following parts by weight：Polyurethane
25 parts of acrylic resin, 16 parts of epoxy resin, 10 parts of trimethylolpropane, 6.2 parts of trimellitic anhydride, disappear at 18 parts of glycerine
1.6 parts of infusion, 0.8 part of aluminium oxide, 0.7 part of epoxidized soybean oil, 1.8 parts of dipropylene, 1.4 parts of ultra-violet absorber, stream
Flat 1 part of agent, 3.8 parts of tourmaline miberal powder, 6 parts of modification infusorial earth, 9 parts of Concave-convex clay rod, 42 parts of deionized water.
4. new type environment friendly coating according to claim 1, which is characterized in that the preparation method of the modification infusorial earth, bag
Include following steps：
（1）Prepare the following raw material counted in parts by weight：30 parts of diatomite, 50 parts of 10~15% sodium hydroxide solution, colophony powder 5
Part, 3 parts of carboxymethyl cellulose；
（2）After the diatomite is put into volumetric concentration for 10~15% sodium hydroxide solutions immersion, 3~4h, then PH is adjusted into
Property；
（3）Take out treated diatomite, water content 3~5% be dried at a temperature of 42~48 DEG C, after immediately add in pine
Face powder is uniformly mixed；
（4）It is eventually adding carboxymethyl cellulose to be uniformly mixed, material is ground into 8.0~10.0 μm of powder, obtain modified diatom
Soil.
5. new type environment friendly coating according to claim 1, which is characterized in that the antifoaming agent is dimethyl silicone polymer.
6. new type environment friendly coating according to claim 1, which is characterized in that the levelling agent is acrylic compounds levelling agent.
A kind of 7. method for preparing any one of claim 1~6 new type environment friendly coating, which is characterized in that including walking as follows
Suddenly：
（1）Polyurethane acrylic resin, epoxy resin, glycerine, trimethylolpropane, trimellitic acid are weighed by above-mentioned formula
Acid anhydride, antifoaming agent, aluminium oxide, epoxidized soybean oil, dipropylene, ultra-violet absorber, levelling agent, tourmaline miberal powder, modification
Diatomite, Concave-convex clay rod, deionized water, it is spare；
（2）Deionized water, antifoaming agent and epoxidized soybean oil are put into Scattered Kettle and disperseed, the jitter time is 10~20 points
Clock, rate of dispersion are 200~300r/min；
（3）By polyurethane acrylic resin, epoxy resin, glycerine, tourmaline miberal powder, modification infusorial earth, Concave-convex clay rod
It adds in into Scattered Kettle, and is heated to 45~55 DEG C, heat preservation is 40~60 minutes scattered, and rate of dispersion is 800~1100r/min；
（4）Hydroxymethyl-propane, trimellitic anhydride, aluminium oxide, dipropylene and levelling agent are added in into Scattered Kettle, it is high
Speed is 10~20 minutes scattered；
（5）First by step（4）The slurry of gained, which is placed in ball mill, is milled to less than 10 μm of fineness, then is placed in Scattered Kettle,
Ultra-violet absorber is added in, is uniformly mixed to get the new type environment friendly coating.
8. preparation method according to claim 7, which is characterized in that the step（4）The speed that high speed is disperseed is
1500~2000r/min.
9. preparation method according to claim 7, which is characterized in that the step（5）Middle mixing speed for 200~
300r/min, mixing time are 13~18 minutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810066230.6A CN108084869A (en) | 2018-01-24 | 2018-01-24 | A kind of new type environment friendly coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810066230.6A CN108084869A (en) | 2018-01-24 | 2018-01-24 | A kind of new type environment friendly coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108084869A true CN108084869A (en) | 2018-05-29 |
Family
ID=62182745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810066230.6A Withdrawn CN108084869A (en) | 2018-01-24 | 2018-01-24 | A kind of new type environment friendly coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108084869A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982430A (en) * | 2019-12-16 | 2020-04-10 | 江门市壹家美环境工程有限公司 | Moistureproof environment-friendly coating |
| CN113618856A (en) * | 2021-08-18 | 2021-11-09 | 江苏华缘高科股份有限公司 | Negative ion moisture-proof ecological plate and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214985A (en) * | 2013-03-21 | 2013-07-24 | 马鞍山市中澜橡塑制品有限公司 | Modified diatomite-containing hot melt adhesive and preparation method thereof |
| CN105062335A (en) * | 2015-07-23 | 2015-11-18 | 安吉祺隆新型建材有限公司 | Method for preparing functional environmentally-friendly paint |
| CN107118648A (en) * | 2017-07-04 | 2017-09-01 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
| CN107189558A (en) * | 2017-06-30 | 2017-09-22 | 广西顺帆投资有限公司 | Environmental protection coating material prepared by a kind of modified starch and preparation method thereof |
-
2018
- 2018-01-24 CN CN201810066230.6A patent/CN108084869A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103214985A (en) * | 2013-03-21 | 2013-07-24 | 马鞍山市中澜橡塑制品有限公司 | Modified diatomite-containing hot melt adhesive and preparation method thereof |
| CN105062335A (en) * | 2015-07-23 | 2015-11-18 | 安吉祺隆新型建材有限公司 | Method for preparing functional environmentally-friendly paint |
| CN107189558A (en) * | 2017-06-30 | 2017-09-22 | 广西顺帆投资有限公司 | Environmental protection coating material prepared by a kind of modified starch and preparation method thereof |
| CN107118648A (en) * | 2017-07-04 | 2017-09-01 | 合肥市大卓电力有限责任公司 | A kind of new type environment friendly coating and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110982430A (en) * | 2019-12-16 | 2020-04-10 | 江门市壹家美环境工程有限公司 | Moistureproof environment-friendly coating |
| CN113618856A (en) * | 2021-08-18 | 2021-11-09 | 江苏华缘高科股份有限公司 | Negative ion moisture-proof ecological plate and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105907201A (en) | Environmentally-friendly aqueous spray paint and preparation method thereof | |
| CN104610806B (en) | A kind of nano-silicon dioxide modified Compound waterborne ink and preparation method thereof | |
| CN107118648A (en) | A kind of new type environment friendly coating and preparation method thereof | |
| CN102190753A (en) | Preparation method for macroporous weak-acidic cation exchange resin | |
| CN108084869A (en) | A kind of new type environment friendly coating and preparation method thereof | |
| CN108373668A (en) | A kind of anion indoor coating preparation method of health environment-friendly | |
| CN103709842A (en) | Herbal essence health paint and preparation method thereof | |
| CN105439548B (en) | A kind of breathing brick and preparation method containing ceramic polished waste residue | |
| CN107805000A (en) | A kind of epoxy water-permeable brick | |
| CN104759252A (en) | A method of preparing porous carbon by adopting spherical zinc oxide as a template and applications of the porous carbon | |
| CN107149809A (en) | A kind of sterilizing and air filtration core and preparation method thereof | |
| CN104479523A (en) | Highly hydrophobicuv (ultraviolet) leather surface treating agent and preparation method thereof | |
| CN105542668A (en) | Environment-friendly adhesive for plates | |
| CN111116100A (en) | Preparation method of antibacterial flame-retardant quartz plate | |
| CN107603294A (en) | A kind of shell magma coating that can remove formaldehyde and preparation method thereof | |
| CN104312535A (en) | Lignin weatherproof fiberboard adhesive and production method thereof | |
| CN101148552A (en) | Micro VOC anion environmental protection inner wall paint | |
| CN112093803B (en) | Production method of silicon dioxide for high-dispersity beer anti-clouding agent | |
| CN107189576A (en) | A kind of glutinous rice coating | |
| CN108658130B (en) | Method for simultaneously preparing iron oxide and silicon dioxide aerogel from iron tailings | |
| CN104610808B (en) | A kind of nano zinc oxide modified Compound waterborne ink and preparation method thereof | |
| CN102430284B (en) | Filtering medium for removing benzophenone in water, preparation method thereof, filter core and purifier | |
| CN112299745B (en) | Slow-release concrete curing agent and preparation method and application thereof | |
| CN107227053A (en) | A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof | |
| CN105692845A (en) | Preparing technology for shaddock peel natural coagulants |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180529 |
|
| WW01 | Invention patent application withdrawn after publication |