CN107227053A - A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof - Google Patents
A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof Download PDFInfo
- Publication number
- CN107227053A CN107227053A CN201710439762.5A CN201710439762A CN107227053A CN 107227053 A CN107227053 A CN 107227053A CN 201710439762 A CN201710439762 A CN 201710439762A CN 107227053 A CN107227053 A CN 107227053A
- Authority
- CN
- China
- Prior art keywords
- modified
- parts
- meng clays
- hydrophobic coating
- clean
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof, each component and its parts by weight are as follows：Modified 3~20 parts of Yi Meng clays；60~75 parts of waterborne acrylic copolymer；0.3~5 part of active solvent；5~10 parts of crosslinking agent；1~2 part of dispersant；0.05~0.2 part of defoamer；1~5 part of mill base；5~20 parts of deionized water.Present invention hydrophobic coating reasonable component formula easy to clean, on the basis of effectively reduction coating cost, effectively increases the easy to clean and hydrophobic property of coating surface, advancing angle >=135 ° with distilled water, roll angle≤6 °.
Description
Technical field
The present invention relates to hydrophobic coating field, specifically a kind of modified Yi Meng clays hydrophobic coating easy to clean and its system
Preparation Method.
Background technology
With the gradually enhancing of environmental consciousness, people increasingly pay attention to house decoration material and furniture is covered with paint, lacquer, colour wash, etc. process and is harmful to
The release of material more and more enters the visual field of people, caused to healthy influence, environment-friendly water-based cold coating
Extensive concern.Coating surface hydrophobe characteristic has very for service life, the cleaning complexity of furniture surface of coating
How important influence, make coating surface have hydrophobic property easy to clean, is urgent problem to be solved.
Yi Meng clays are a kind of phyllosilicates, mainly by silicon-oxy tetrahedron lamella (silica) and aluminum oxide octahedral sheet
Layer (aluminum oxide) is combined, and a number of oh group is contained on its surface, can occur condensation reaction with other coagents.
Coating surface hydrophobic property can be realized by the surface-hydrophobicized processing to Yi Meng clays.
For the surface modification treatment of Yi Meng clays, such as Chinese invention patent application《A kind of Yi Meng clays are in wood surface
The method for building super-drainage structure》(application number 201410849406.7) disclose " a kind of Yi Meng clays wood surface build
The method of super-drainage structure, including the steps: (1), using natural Yi Meng clays as raw material, modification obtains hydrophobicity
The Yi Meng clays of energy；(2) by the Yi Meng clay diameter oriented controls of obtained hydrophobic performance, prepare including nanoscale and micron
Double microscopic particles of level, the particle diameter of nano level particle between 20~500nm, the particle diameters of micron particles 5~15 μm it
Between；(3) double microscopic particles will be prepared wood surface in wood surface or is immersed in by vacuum suction, so that in wood surface
Build super-drainage structure." beneficial effect of the invention is to provide a kind of Yi Meng clays and builds super-drainage structure in wood surface
Method, wood surface is attached to by modified Yi Meng clays, double microcosmic super-hydrophobic structures is formed uniformly, with connecing for distilled water
Feeler >=150 °, are in rolling contact angle≤10 °.But find in actual use, the invention using cationic surfactant (l,
N, N, N~trimethyl~1~cetyl ammonium bromide) and Yi Meng clays progress cation exchange, and the method for cation exchange
Carried out generally in pure water, because surfactant is present, a large amount of bubbles can be produced during stirring and heating, and then drop
Low efficiency of pcr product simultaneously makes troubles to production.
Chinese invention patent application is disclosed《An a kind of one step preparation method of hydrophobic Yi Meng clays》(application number
201610299050.3), disclose and " comprise the following steps: first add modifying agent in alcohol solution, stirring is completely dispersed
Yi Meng clay powders are added after even, slurries are obtained in 60~80 DEG C of reactions；Then the above-mentioned slurries by step are filtered,
The drying grinding of obtained filter cake be can obtain into hydrophobic Yi Meng clays powder." the obtained powder of the invention have it is preferably hydrophobic
Performance and hydrophobic performance stabilization, have good compatibility with organic matter, can be dispersed in the polymer.But Shi Jishiyong mistake
Found in journey, the modifying agent used due to the invention is hydrophobic for any one in DOW CORNING Z6173 or DOW CORNING 11~100
Contact angle be 108 °, its chief active group be alkyl functional group, by the hydrophobic Yi Meng clays powder of the invention be used for aqueous third
Olefin(e) acid cold coating, then the synergy due to modified clay with water-based acrylic resin coating composition each other is not obvious,
Cause it to disperse in resin unstable, result in that practicality is poor, property easy to clean is also poor.
The content of the invention
For the deficiencies in the prior art, the invention provides a kind of modified Yi Meng clays hydrophobic coating easy to clean and
Its preparation method, improves the hydrophobic property easy to clean that coating surface has, while reducing the cost of coating.
The present invention solves the technical scheme that the technical problem uses：
A kind of modified Yi Meng clays hydrophobic coating easy to clean, each component and its parts by weight are as follows:
Modified 3~20 parts of Yi Meng clays；
60~75 parts of waterborne acrylic copolymer；
0.3~5 part of active solvent；
5~10 parts of crosslinking agent；
1~2 part of dispersant；
0.05~0.2 part of defoamer；
1~5 part of mill base；
5~20 parts of deionized water.
The grain diameter of described modification Yi Meng clays is 50nm~8000nm, and modifying agent is the ethoxy of 3~aminopropyl three
Base silane.
Described active solvent is dipropylene glycol methyl ether and dipropylene in mass ratio 1: the mixture of (2~12).
Described crosslinking agent is GMA.
Described dispersant is sodium carboxymethylcellulose.
Described defoamer is organosiloxane.
Described mill base is universal lacquer mill base.
The preparation method of described a kind of modified Yi Meng clays hydrophobic coating easy to clean, it is characterised in that including following step
It is rapid:
(1) 3~aminopropyltriethoxywerene werene solution is prepared: by 3~aminopropyltriethoxywerene werene, anhydrous second
Alcohol, deionized water are (1~5): (85~90) by weight: (5~10) mixing；
(2) Yi Meng clays are crossed into 325 mesh mesh screens, screenings add step (1) resulting solution be configured to mass concentration 5%~
10% clay solution, gained clay solution ph is adjusted to 3~5.5 with glacial acetic acid；
(3) clay solution obtained by step (2) is heated to 75~80 DEG C, isothermal reaction 0.5~24 hour is cooled to room
Temperature；
(4) by clay solution centrifugal obtained by step (3), and with washes of absolute alcohol to unreacted 3~aminopropyl three
Ethoxysilane is removed；
(5) clay obtained by step (4) be dried in vacuo 1~24 hour at 40 DEG C, be fully ground, obtain being modified Yi Meng glutinous
Soil；
(6) by weight by waterborne acrylic copolymer, active solvent, crosslinking agent, dispersant, defoamer, mill base and go
Ionized water is mixed, and is stirred, then modified Yi Meng clays mixing by weight obtained by addition step (5), and stirring 20~
120min is abundant to mixing, and obtains the modified Yi Meng clays hydrophobic coating easy to clean.
The coating is prepared from using waterborne acrylic copolymer as main body, and waterborne acrylic copolymer has good
Water soluble characteristic and environmental protection characteristic, while active reactive group, can crosslink reaction with other components.
Crosslinking agent is GMA, and the crosslinking agent contains epoxide group and double bond, can be with coating composition
Other groups react, formed crosslinking.
Dispersant is that sodium carboxymethylcellulose has preferable dispersion effect to Yi Meng clays.
Beneficial effects of the present invention：
(1) hydrophobic coating easy to clean of the invention has the effect of antifouling anti-mildew.
(2) hydrophobic coating easy to clean of the invention is applied to Wood and artificial board, and realization hydrophobic effect occurs on surface, made
Surface keeps cleaning, and is readily cleaned；With advancing angle >=135 ° of distilled water, roll angle≤6 °.
(3) hydrophobic coating reasonable component formula easy to clean of the invention, preparation method is simple, effectively reduce coating into
This.
Brief description of the drawings
Fig. 1 is that the modified Yi Meng clays hydrophobic coating easy to clean of the present invention covers with paint, lacquer, colour wash, etc. the anaplasia at any time of the contact angle after wood surface
Water droplet keeps the form in photo in the photo of change, figure, and contact angle is 138.5 °；When it's 180 seconds has past the time, contact angle is still
138.0 °, illustrate that there is good hydrophobic effect by modified coating.
Embodiment
Further specific descriptions are done to the present invention with reference to embodiments, but are not limited to these embodiments.
In following examples, signified number is parts by weight.
Embodiment 1：
(1) modified Yi Meng clays are the preparation of component A：
By 3~aminopropyltriethoxywerene werene: absolute ethyl alcohol: the weight ratio of deionized water is 5: 85: 10 mixed preparings 3
~aminopropyltriethoxywerene werene solution；Yi Meng clays are crossed into 325 mesh mesh screens, 3~aminopropyl obtained by screenings addition
Triethoxysilane solution is configured to the clay solution of mass concentration 6%, and gained clay solution ph is adjusted with glacial acetic acid and is
4.5,80 DEG C are heated to, isothermal reaction 24 hours is cooled to room temperature；Centrifugation, and with washes of absolute alcohol 4 times extremely unreacted 3
~aminopropyltriethoxywerene werene is removed；It is dried in vacuo 12 hours, is fully ground at 40 DEG C, the particle of modified Yi Meng clays
Footpath is 50nm~8000nm.
(2) preparation of B component：By 75 parts of waterborne acrylic copolymer；2 parts of active solvent (wherein dipropylene glycol methyl ether 0.3
Part, dipropylene is 1.7 parts)；5 parts of crosslinking agent GMA；Dispersant sodium carboxymethylcellulose 1
Part；0.08 part of defoamer organosiloxane；2 parts of mill base；9.92 parts of deionized water is mixed and stirred for uniformly, obtaining B component.
(3) B component obtained by 5 parts of component A and step (2) is mixed, and stirring extremely mixes abundant for 20 minutes, produces the present invention
Hydrophobic coating easy to clean.
Embodiment 2：
(1) modified Yi Meng clays are the preparation of component A：
By 3~aminopropyltriethoxywerene werene: absolute ethyl alcohol: the weight ratio of deionized water is 4: 88: 8 mixed preparings 3
~aminopropyltriethoxywerene werene solution；Yi Meng clays are crossed into 325 mesh mesh screens, 3~aminopropyl obtained by screenings addition
Triethoxysilane solution is configured to the clay solution of mass concentration 8%, and gained clay solution ph is adjusted with glacial acetic acid and is
3.5,80 DEG C are heated to, isothermal reaction 24 hours is cooled to room temperature；Centrifugation, and with washes of absolute alcohol 4 times extremely unreacted 3
~aminopropyltriethoxywerene werene is removed；It is dried in vacuo 12 hours, is fully ground at 40 DEG C.The particle of modified Yi Meng clays
Footpath is 50nm~8000nm.
(2) preparation of B component：By 65 parts of waterborne acrylic copolymer；3 parts of active solvent (wherein dipropylene glycol methyl ether 0.5
Part, 2.5 parts of dipropylene)；8 parts of crosslinking agent GMA；1 part of dispersant sodium carboxymethylcellulose；
0.05 part of defoamer organosiloxane；3 parts of mill base；9.95 parts of deionized water is mixed and stirred for uniformly.
(3) B component obtained by 10 parts of component A and step (2) is mixed, and stirring extremely mixes abundant for 30 minutes, i.e., it is of the invention
Hydrophobic coating easy to clean.
Embodiment 3：
(1) modified Yi Meng clays are the preparation of component A：
By 3~aminopropyltriethoxywerene werene: absolute ethyl alcohol: the weight ratio of deionized water is 2: 88: 10 mixed preparings 3
~aminopropyltriethoxywerene werene solution；Yi Meng clays are crossed into 325 mesh mesh screens, 3~aminopropyl obtained by screenings addition
Triethoxysilane solution is configured to the clay solution of mass concentration 10%, and gained clay solution ph is adjusted with glacial acetic acid and is
3.5,75 DEG C are heated to, isothermal reaction 24 hours is cooled to room temperature；Centrifugation, and with washes of absolute alcohol 4 times extremely unreacted 3
~aminopropyltriethoxywerene werene is removed；It is dried in vacuo 12 hours, is fully ground at 40 DEG C.The particle of modified Yi Meng clays
Footpath is 50nm~8000nm.
(2) preparation of B component：By 60 parts of waterborne acrylic copolymer, 2 parts of active solvent (wherein dipropylene glycol methyl ether with
Dipropylene Wei not be 0.25 part and 1.75 parts), 10 parts of crosslinking agent GMA, scattered agent carboxymethyl it is fine
14.95 parts of plain 1 part of the sodium of dimension, 0.05 part of defoamer organosiloxane, 2 parts of mill base and deionized water are mixed and stirred for uniformly.
(3) B component obtained by 10 parts of component A and step (2) is mixed, and stirring extremely mixes abundant for 30 minutes, produces this hair
Bright hydrophobic coating easy to clean.
Embodiment 4：
(1) modified Yi Meng clays are the preparation of component A：
By 3~aminopropyltriethoxywerene werene: absolute ethyl alcohol: the weight ratio of deionized water is 3: 88: 9 mixed preparings 3
~aminopropyltriethoxywerene werene solution；Yi Meng clays are crossed into 325 mesh mesh screens, 3~aminopropyl obtained by screenings addition
Triethoxysilane solution is configured to the clay solution of mass concentration 5%, and gained clay solution ph is adjusted with glacial acetic acid and is
4.0,75 DEG C are heated to, isothermal reaction 24 hours is cooled to room temperature；Centrifugation, and with washes of absolute alcohol 4 times extremely unreacted 3
~aminopropyltriethoxywerene werene is removed；It is dried in vacuo 12 hours, is fully ground at 40 DEG C.The particle of modified Yi Meng clays
Footpath is 50nm~8000nm.
(2) preparation of B component：By 70 parts of waterborne acrylic copolymer；2 parts of active solvent (wherein dipropylene glycol methyl ether
0.25 part, 1.75 parts of dipropylene)；5 parts of crosslinking agent GMA；Dispersant sodium carboxymethylcellulose
1 part；0.08 part of defoamer organosiloxane；2 parts of mill base；14.92 parts of deionized water is mixed and stirred for uniformly.
(3) B component obtained by 3 parts of component A and step (2) is mixed, and stirring extremely mixes abundant for 20 minutes, produces this implementation
The hydrophobic coating easy to clean of mode.
Embodiment 5：
(1) modified Yi Meng clays are the preparation of component A：
By 3~aminopropyltriethoxywerene werene: absolute ethyl alcohol: the weight ratio of deionized water is 5: 85: 10 mixed preparings 3
~aminopropyltriethoxywerene werene solution；Yi Meng clays are crossed into 325 mesh mesh screens, 3~aminopropyl obtained by screenings addition
Triethoxysilane solution is configured to the clay solution of mass concentration 8%, and gained clay solution ph is adjusted with glacial acetic acid and is
5.0,80 DEG C are heated to, isothermal reaction 24 hours is cooled to room temperature；Centrifugation, and with washes of absolute alcohol 4 times extremely unreacted 3
~aminopropyltriethoxywerene werene is removed；It is dried in vacuo 12 hours, is fully ground at 40 DEG C.The particle of modified Yi Meng clays
Footpath is 50nm~8000nm.
(2) preparation of B component: by 60 parts of waterborne acrylic copolymer；2 parts of active solvent (wherein dipropylene glycol methyl ether
0.25 part, 1.75 parts of dipropylene)；10 parts of crosslinking agent GMA；Dispersant carboxymethyl cellulose
1 part of sodium；0.05 part of defoamer organosiloxane；2 parts of mill base；9.95 parts of deionized water is mixed and stirred for uniformly.
(3) B component obtained by 15 parts of component A and step (2) is mixed, and stirring extremely mixes abundant for 120 minutes, produces this hair
Bright hydrophobic coating easy to clean.
The coating of above-mentioned five embodiments, is covered with paint, lacquer, colour wash, etc. after wood surface, advancing angle >=135 ° with distilled water, and roll angle≤
6°。
It is pointed out that the hydrophobic coating execution conditions easy to clean of the present invention are 15~35 DEG C of temperature, humidity 40~
80%.
Further, the optimal execution conditions of hydrophobic coating easy to clean of the invention are 25 DEG C of temperature, humidity 55%.
By the coating of the present invention compared with existing coating, environmental protection characteristic is good, pollutes small；The hydrophobic coating easy to clean of the present invention
For Wood and artificial board, hydrophobic effect can occur on surface, surface is kept cleaning, and be readily cleaned.
Although above the present invention is described in detail with a general description of the specific embodiments,
On the basis of invention, it can be made some modifications or improvements, this will be apparent to those skilled in the art.Therefore,
These modifications or improvements, belong to the scope of protection of present invention without departing from theon the basis of the spirit of the present invention.
Claims (8)
1. a kind of modified Yi Meng clays hydrophobic coating easy to clean, it is characterised in that each component and its parts by weight are as follows：
Modified 3~20 parts of Yi Meng clays；
60~75 parts of waterborne acrylic copolymer；
0.3~5 part of active solvent；
5~10 parts of crosslinking agent；
1~2 part of dispersant；
0.05~0.2 part of defoamer；
1~5 part of mill base；
5~20 parts of deionized water.
2. a kind of modified Yi Meng clays hydrophobic coating easy to clean according to claim 1, it is characterised in that described modification
The grain diameter of Yi Meng clays is 50nm~8000nm, and modifying agent is 3~aminopropyltriethoxywerene werene.
3. a kind of modified Yi Meng clays hydrophobic coating easy to clean according to claim 1, it is characterised in that described activity
Solvent is dipropylene glycol methyl ether and dipropylene in mass ratio 1: the mixture of (2~12).
4. a kind of modified Yi Meng clays hydrophobic coating easy to clean according to claim 1, it is characterised in that described crosslinking
Agent is GMA.
5. a kind of modified Yi Meng clays hydrophobic coating easy to clean according to claim 1, it is characterised in that described is scattered
Agent is sodium carboxymethylcellulose.
6. a kind of modified Yi Meng clays hydrophobic coating easy to clean according to claim 1, it is characterised in that described froth breaking
Agent is organosiloxane.
7. a kind of modified Yi Meng clays hydrophobic coating easy to clean according to claim 1, it is characterised in that described mill base
For universal lacquer mill base.
8. a kind of preparation method of modified Yi Meng clays hydrophobic coating easy to clean according to one of claim 1 to 7, it is special
Levy and be, comprise the following steps:
(1) 3~aminopropyltriethoxywerene werene solution is prepared：By 3~aminopropyltriethoxywerene werene, absolute ethyl alcohol, go
Ionized water is (1~5): (85~90) by weight: (5~10) mixing；
(2) Yi Meng clays are crossed into 325 mesh mesh screens, screenings adds step (1) resulting solution and is configured to mass concentration 5%~10%
Clay solution, adjust gained clay solution ph to 3~5.5 with glacial acetic acid；
(3) clay solution obtained by step (2) is heated to 75~80 DEG C, isothermal reaction 0.5~24 hour is cooled to room temperature；
(4) by clay solution centrifugal obtained by step (3), and with washes of absolute alcohol to the unreacted ethoxy of 3~aminopropyl three
Base silane is removed；
(5) clay obtained by step (4) is dried in vacuo 1~24 hour at 40 DEG C, is fully ground, obtains being modified Yi Meng clays；
(6) by weight by waterborne acrylic copolymer, active solvent, crosslinking agent, dispersant, defoamer, mill base and deionization
Water is mixed, and is stirred, then modified Yi Meng clays mixing by weight obtained by addition step (5), and stirring 20~
120min is abundant to mixing, and obtains the modified Yi Meng clays hydrophobic coating easy to clean.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710439762.5A CN107227053A (en) | 2017-06-12 | 2017-06-12 | A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710439762.5A CN107227053A (en) | 2017-06-12 | 2017-06-12 | A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107227053A true CN107227053A (en) | 2017-10-03 |
Family
ID=59935317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710439762.5A Pending CN107227053A (en) | 2017-06-12 | 2017-06-12 | A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107227053A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113402960A (en) * | 2021-05-27 | 2021-09-17 | 亚振家居股份有限公司 | Graphene oxide modified waterborne antibacterial polyurethane coating for woodware and preparation process |
| CN115770215A (en) * | 2022-12-13 | 2023-03-10 | 南京正科医药股份有限公司 | Urapidil hydrochloride injection and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101139502A (en) * | 2006-09-07 | 2008-03-12 | 北京翰高兄弟科技发展有限公司 | Organosilicon acrylic resin hydrophobic coating |
| CN105111859A (en) * | 2015-08-28 | 2015-12-02 | 中科纳达控股股份有限公司 | Nano antimicrobial internal wall paint containing illite-montmorillonite clay and preparation method thereof |
| CN105949506A (en) * | 2016-05-06 | 2016-09-21 | 北京化工大学 | One-step preparation method of hydrophobic illite montmorillonite clay |
| CN106046980A (en) * | 2016-06-28 | 2016-10-26 | 山东科技大学 | Surface treatment and anti-fouling method for stainless steel material |
-
2017
- 2017-06-12 CN CN201710439762.5A patent/CN107227053A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101139502A (en) * | 2006-09-07 | 2008-03-12 | 北京翰高兄弟科技发展有限公司 | Organosilicon acrylic resin hydrophobic coating |
| CN105111859A (en) * | 2015-08-28 | 2015-12-02 | 中科纳达控股股份有限公司 | Nano antimicrobial internal wall paint containing illite-montmorillonite clay and preparation method thereof |
| CN105949506A (en) * | 2016-05-06 | 2016-09-21 | 北京化工大学 | One-step preparation method of hydrophobic illite montmorillonite clay |
| CN106046980A (en) * | 2016-06-28 | 2016-10-26 | 山东科技大学 | Surface treatment and anti-fouling method for stainless steel material |
Non-Patent Citations (4)
| Title |
|---|
| 孙卫东: "《精细有机化学品化学》", 28 February 2006, 内蒙古科学技术出版社 * |
| 张俊甫: "《精细化工概论》", 31 October 1991, 中央广播电视大学出版社 * |
| 杨晓梅: "水溶性丙烯酸涂料的合成研究", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 贾红兵 等: "《高分子材料》", 30 November 2009, 南京大学出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113402960A (en) * | 2021-05-27 | 2021-09-17 | 亚振家居股份有限公司 | Graphene oxide modified waterborne antibacterial polyurethane coating for woodware and preparation process |
| CN115770215A (en) * | 2022-12-13 | 2023-03-10 | 南京正科医药股份有限公司 | Urapidil hydrochloride injection and preparation method thereof |
| CN115770215B (en) * | 2022-12-13 | 2024-02-23 | 南京正科医药股份有限公司 | Urapidil hydrochloride injection and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101885943B (en) | Nano-glass heat insulation paint and preparation method thereof | |
| CN105968852B (en) | The lignin-base zinc oxide composite particles and preparation method and application of anti-ultraviolet radiation | |
| CN108752988A (en) | A kind of preparation method of super-hydrophobic silicon colloidal sol and super-hydrophobic coat | |
| CN104725990B (en) | A kind of preparation method of the self-cleaning coating based on modified nano-titanium dioxide | |
| CN108517154A (en) | A kind of aqueous, floride-free super hydrophobic coating and preparation method | |
| CN106916515B (en) | A kind of Functional Powder Coating and preparation method thereof | |
| CN105400239A (en) | Preparation method of modified silicon dioxide obtained via super-hydrophobic modification | |
| CN106366892B (en) | A kind of resistance to scratch-type open air powdery paints | |
| CN110028862A (en) | A kind of compound super hydrophobic coating of modified Nano and preparation method thereof | |
| CN109517516A (en) | A kind of cerium bentonite modified watersoluble polyurethane paint and preparation method thereof | |
| CN107151941B (en) | Photocatalyst suspension, resist blocking and that automatically cleaning wood-based plate facing paper and preparation method thereof | |
| CN105505093A (en) | Environment-friendly glass baking paint and preparation method thereof | |
| CN110437683A (en) | A kind of anion ordor removing coating and preparation method thereof | |
| CN107163735A (en) | A kind of metope high-elastic waterproof coating and preparation method thereof | |
| CN107227053A (en) | A kind of modified Yi Meng clays hydrophobic coating easy to clean and preparation method thereof | |
| CN104449130A (en) | Corrosion-oxidation-resistant and environment-friendly waterborne coating for glass door and preparation method of waterborne coating | |
| CN111675935A (en) | Water-based negative ion auxiliary agent and water-based negative ion UV paint | |
| CN109266085A (en) | A kind of reductive modification sulfonated graphene and its preparation method and application | |
| CN108658130A (en) | A method of preparing iron oxide and aerosil simultaneously from iron tailings | |
| CN110358437A (en) | A kind of high-performance environment-friendly water paint and preparation method thereof | |
| CN109233390B (en) | Environment-friendly epoxy resin coating for buildings | |
| CN110423531A (en) | Environment-friendly water-based paint of one kind and preparation method thereof | |
| CN109401159A (en) | A kind of preparation method of the enhanced water resistance acrylic resin with uvioresistant performance | |
| CN108997871A (en) | A kind of environment-friendly type emulsion paint | |
| CN108102434A (en) | A kind of nanometer of toughening inorganic zinc coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20171003 |