CN108373668A - A kind of anion indoor coating preparation method of health environment-friendly - Google Patents
A kind of anion indoor coating preparation method of health environment-friendly Download PDFInfo
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- CN108373668A CN108373668A CN201611050895.5A CN201611050895A CN108373668A CN 108373668 A CN108373668 A CN 108373668A CN 201611050895 A CN201611050895 A CN 201611050895A CN 108373668 A CN108373668 A CN 108373668A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0853—Vinylacetate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention belongs to technical field of coatings, and in particular to a kind of anion indoor coating preparation method of health environment-friendly.The present invention utilizes water-fast environment-friendly adhesive and opacity polymer latex composite compounding technology, it is aided with a kind of preferred efficiently anion mineral additive, health environment-friendly auxiliary agent and manufactured health environment-friendly coating, asepsis environment-protecting, water-tolerant, strong covering power, effectively inhibit the growth of various moulds, can sustained release anion, dispel the pernicious gas in air, be effectively improved the air quality of living environment, the immunity of people is improved, people's health is promoted.The buildings such as residential houses and dense population place such as market, office building, hospital, school, hotel, underground garage, industrial building are can be widely applied for, the indoor air quality in these places is made to be effectively improved, and the protection played and decoration function.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of anion indoor coating preparation method of health environment-friendly.
Background technology
With the high speed development of today's society, requirement of the people to life comfort level increasingly improves, to the residence of health environment-friendly
Firmly environment is also more paid close attention to and is paid attention to.According to ASSOCIATE STATISTICS, all one's life of the mankind has 70% or so time to spend indoors, because
This indoor air quality becomes hot spot of people's attention.And the indoor air pollutants having found have more than 300 kinds, wherein to human body
Be easy to cause injury, it is even carcinogenic just have more than 20 kinds, greatly threaten the healthy living of the mankind.In recent years, people more come
More influence of the concern indoor air quality to health of people, decoration material is more focused on its material health and
The feature of environmental protection.For coating products, in addition to the basis mask performance of coating, consumer more pays close attention to its environmental-protecting performance, including
Whether containing poisonous and harmful substances such as formaldehyde, VOC etc..
Negative aeroion is the neutral molecule combination electronics in air and the negatively charged gas ion formed, it is extensively
It is present in atmosphere, it puts by such as air collision, thunder and lightning, radiation, water impact, photosynthesis of plant, substance tip
All multimodes such as electricity generate, and to human health, living environment quality has prodigious benefit.When negative ion concentration reaches in air
When to a certain extent, the breeding of a variety of germs can be inhibited, reduced blood pressure and dispelling fatigue, the growth and development of human body are promoted, because
And people liken negative aeroion to " vitamin in air ", are one of the important indicators for weighing air cleaner degree.People
The main method that work generates anion is to make air ionization, from air molecule or a part of electronics of atom abstraction, and in others
Property molecule or atom combine form new anion.The manual method of common generating negative ions has following several：1) Jules Renard is imitated
(water fall effect) is answered, using artificial flow, the impact force of waterfall, fountain, wave, hydrone is made to ionize, generates anion.It is this
The project scale of method is big, and cost is high, is suitable only for Garden Engineering and downtown streets man-made tourist site；2) corona discharge utilizes high-voltage electricity
The corona discharge of pole acts on, and the hydrone in air is made to ionize, and generates anion.This method can generate ozone and nitrogen oxygen simultaneously
Compound, to human health；3) heat, squeeze, friction, using electric heating or human body to the extrusion friction of health treatment, make sky
Hydrone ionization in gas, generates anion.This method is generally used for health products, easy to use, but the negative ion amount generated
Seldom, to enhancement of environment function unobvious.4) natural minerals utilize the natural of tourmaline or other anion mineral materials
Anion indoor coating is that emerging a health paint product, cardinal principle were by addition one in the market in recent years
The natural mineral matter of anion can be discharged a bit to reach release anion, to purify the purpose of air.
The anion mineral material added in anion indoor coating is a kind of material with special crystalline structure, it
Crystal structure is cyclic annular oxygen-octahedron, and oxygen-octahedron is directed toward a direction, the i.e. X position of crystal structure jointly.The position
Cation be very easy to generate transition, and form anion vacancy.Therefore, the material of this crystalline structure has spontaneous polarization
Effect, electrostatic field can be had by macroscopically then showing as its surrounding materials, and permanently be existed, and not influenced by external electrical field.Add
Added the anion coated film of anion mineral material macroscopically showing as any surface finish densification, but on microcosmic be one layer by
The perforated membrane that macromolecular fibre net is formed.By countless gaps air molecule is made with the filler particles in emulsion paint
With.The specific releasing mechanism of its anion is that the vapor in air is in contact by hole with the anion powder in coating,
Under the action of anion powder a large amount of anion is discharged by reacting as follows.
4H2O+2e→2H2O2 -+2H2↑
However there are many problems in the anion mineral material for being commercially as coating additive in actual use：1) it bears
Ion mineral material is often the natural products of the Nature, and this material often itself can carry deep color, usually
Yellowish-brown or black.And the basic colors of coating is white, the dosage control of additive can impact product.Additive
Dosage is very few, and the effect of purification air may be not achieved；Additive amount is excessive, then can influence the appearance color and stabilization of product
Property；2) individual workship of some anion mineral materials and small processing factory can illegally add some in mineral process and contain
For radioactive substance to reach higher anion burst size, such material can cause unpredictable shadow to health
It rings.
Invention content
In order to overcome the problems of in the prior art, the purpose of the present invention is to provide a kind of health environment-friendly bear from
Seed cell's inside courtyard and its preparation and application.
To achieve the goals above and other related purposes, the present invention adopt the following technical scheme that：
The first aspect of the present invention provides a kind of anion indoor coating of health environment-friendly, includes the original of following parts by weight
Expect ingredient：0.1~0.4 parts by weight of wetting agent；0.5~1.2 parts by weight of dispersant；0.3~0.9 parts by weight of antifoaming agent；Film forming helps
0.2~0.6 parts by weight of agent；0.3~0.9 parts by weight of antifreezing agent；0.2~0.6 parts by weight of thickener；0.2~0.5 weight of levelling agent
Part；0.1~0.5 parts by weight of mould inhibitor；0.1~0.5 parts by weight of fungicide；0.1~0.4 parts by weight of multifunctional assistant；Titanium dioxide
15~25 parts by weight；15~30 parts by weight of filler；0.5~1.8 parts by weight of anion mineral additive；Water-fast environment-friendly adhesive 20
~40 parts by weight；3~8 parts by weight of opacity polymer lotion；18~25 parts by weight of water.
Preferably, the anion mineral additive be selected from iron dravite, opal, six ring stones, sea-gull stone, stone needle,
Any one of serpentine, astroies, medical stone, volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, shell are more
The combination of kind.
Preferably, the anion mineral additive is "dead".
Preferably, purity >=98% of the anion mineral additive.
Preferably, the grain size of the anion mineral additive is in Nano grade, d50≤ 0.8um, d97≤2.0um。
Preferably, the shell structure of the opacity polymer lotion by modified polystyrene, modified poly (methyl methacrylate),
Modified polyacrylonitrile any one or more of forms.
Preferably, it is 30%~50% (V/ that the inside of the opacity polymer lotion, which has hollow microporous structure, cavity rate,
V%).
Preferably, the hollow latex particles diameter of the opacity polymer lotion is 400~500nm.
The opacity polymer lotion that can specifically use includes but not limited to the THYOSIL-E451 of DIRANSA companies, west
Pacify the Unihub-E that flower bud sharpens ZG-001, DOW company of work.
Preferably, the wetting agent is non-ionic wetting agent.It is highly preferred that the wetting agent changes for nonionic polyether
Property type siloxane wetting agent.The nonionic polyether modified siloxane class wetting agent is without APEO and formaldehyde and VOC content pole
It is low.Wetting agent includes but not limited to workable for specific：Wet 510, the Air of BYK-347, Tego company of BYK companies
EnviroGem 360 of Product companies etc..
Preferably, the dispersant is anionic polycarboxylate's sodium salt dispersant.The dispersant is free of APEO and first
Aldehyde and VOC content is extremely low.Dispersant includes but not limited to workable for specific：The Disperbyk-102 of BYK companies,
The Dispersogen 4387 of Clariant companies, COATEX P30 of COATEX companies etc..
Preferably, the antifoaming agent is nonionic mineral oil defoaming agent.The antifoaming agent without APEO and formaldehyde and
VOC content is extremely low.Antifoaming agent includes but not limited to workable for specific：Drewplus T-4201 of Ashland companies,
The Dispelair CF 550 of Blankburn companies, the BYK-034 etc. of BYK companies.
Preferably, the coalescents are Lauryl Alcohol esters coalescents.The coalescents are free of APEO and formaldehyde
And VOC content is extremely low.Antifoaming agent includes but not limited to workable for specific：OE-300, DOW company of Eastman companies
UCAR Filmer IBT, CHISSO companies CS-12 etc..
Preferably, the antifreezing agent is low-carbon alcohols.The antifreezing agent is free of APEO and formaldehyde and VOC content is extremely low.It is preferred that
Ground, the antifreezing agent are selected from the combination of ethylene glycol, propylene glycol or diethylene glycol (DEG) any one or more of.It is specific workable antifreeze
Agent includes but not limited to：The ethylene glycol of Iranian Worldwide, Inc, the propylene glycol of DOW companies, Samsung companies diethylene glycol (DEG).
Preferably, the thickener is hydroxyethyl cellulose.The viscosity of the thickener is 30000~60000mPas.
Thickener includes but not limited to workable for specific：The hydroxyethyl cellulose of Clariant companies, the ethoxy of Samsung companies
Cellulose, Ashland companies hydroxyethyl cellulose.
Preferably, the levelling agent is nonionic levelling agent.Preferably, the levelling agent is that nonionic is modified poly- silicon
Oxygen alkane levelling agent.The levelling agent is free of APEO and formaldehyde and VOC content is extremely low.The levelling agent that can specifically use includes but not
Be limited to the Metolat 366 of Munzing companies, BYK-337, De Qian company of BYK companies Levelol W-409.
Preferably, the mould inhibitor is compound benzene sulfone or imidazoles high-efficiency broad spectrum dry film antibacterial mildew inhibitor.The mould inhibitor
Without APEO and formaldehyde and VOC content it is extremely low.The mould inhibitor that can specifically use includes but not limited to Clariant companies
NIPACIDE DFX-1, AMICAL Flowable of DOW companies, Progiven companies Fongal DO A2W.
Preferably, the fungicide is compound different Anthelvet ketone antibiotic bactericide.The fungicide without APEO and
Formaldehyde and VOC content is extremely low.The fungicide that can specifically use includes but not limited to：The NIPACIDE BIT of Clariant companies
20, KATHON LXE of DOW companies, Avecia companies Proxel LV.
Preferably, the multifunctional assistant is denatured ethanol amine salt.The multifunctional assistant is without APEO and formaldehyde and VOC
Content is extremely low.Multifunctional assistant includes but not limited to workable for specific：SYNTHRO-STAB25B, DOW of SYNTHRO companies
The AMP-95 of company, the Codisbuffer G3 of Shenzhen Hai Run chemical companies.
Preferably, the titanium dioxide is rutile type titanium white.Titanium white part includes but not limited to workable for specific：Du Pont
The R902 of company, the R980 of Shi Yuan companies of Japan, Sichuan Long Mangtai industry company R996.
Preferably, the filler is selected from calcium carbonate, any one of sub-nanometer glue is won in calcined kaolin, mica powder, match or
A variety of combinations.The filler that can specifically use includes but not limited to the carbonic acid that Hangzhou Yuhang adds sincere nonmetallic mining industry Co., Ltd
Sub-nanometer glue is won in calcium, calcined kaolin, mica powder, match.
Preferably, the mesh of the grain size of the filler >=800.Preferably, the grain size of the filler is 800~2000 mesh.It is more excellent
It is selected as 1250 mesh.
Preferably, the various applicable water-fast environment-friendly adhesives in this field can be selected in the water-fast environment-friendly adhesive.Specifically may be used
The resistance to water environmental protection used bonds：The aqueous acrylate and vinyl acetate emulsion ROVACETM-661 of DOW companies, Celanese Corp.
The aqueous pure-acrylic emulsion SF-400 of aqueous ethene-vinyl acetate copolymer emulsion Celvolit-1475, DOW companies, Henkel Corp.
The combination of waterborne styrene-acrylic emulsion Vinacryl-7199 any one or more ofs.
The second aspect of the present invention provides a kind of method for the anion indoor coating preparing aforementioned health environment-friendly, including
Step：
(1) by the deionized water in raw material components, dispersant, wetting agent, antifreezing agent, part antifoaming agent, part thickener
It stirs；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, part thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, remaining defoaming are added in step (2) resulting material
Agent, levelling agent, remaining thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, filter, packaging is to get strong
The anion indoor coating of Kang Huanbao.
The third aspect of the present invention provides the anion indoor coating of aforementioned health environment-friendly in purifying the air of a room
Purposes.
Compared with prior art, the present invention has the advantages that：
(1) present invention using after the water-fast environment-friendly adhesive and opacity polymer latex composite compounding of health environment-friendly gained lotion as
Main film forming substance, using water as solvent, be aided with preferred anion mineral additive, it is prepared by filler and health environment-friendly auxiliary agent and
At.The invention is characterized in that using water-fast environment-friendly adhesive and opacity polymer latex composite compounding technology, it is aided with a kind of preferred height
Imitate anion mineral additive, health environment-friendly auxiliary agent and manufactured health environment-friendly coating, asepsis environment-protecting, water-tolerant, covering power
By force, effectively inhibit the growth of various moulds, can sustained release anion, dispel the pernicious gas in air, be effectively improved residence
The firmly air quality of environment improves the immunity of people, promotes people's health.It can be widely applied for residential houses and dense population
The buildings such as place such as market, office building, hospital, school, hotel, underground garage, industrial building make the room air in these places
Quality is effectively improved, and the protection played and decoration function.
(2) the anion mineral additive selected by is "dead" safely, sustainable for good and all to discharge anion, and it is negative
Ion release can be accurately controlled in 1000~8000/cm3Within the scope of (test environment：25 ± 2 DEG C of temperature, relative humidity
50 ± 5%R.H.)；The negative aeroion amount of inducing can be accurately controlled in 3000~7000/(scm2) within the scope of.
(3) the opacity polymer lotion added can provide the covering power of coating significantly；Improve the washable of indoor coating
Brush performance；The dosage of pigment titanium white is reduced to reduce cost, and reduces the titanium dioxide poly- influence to coating excessively；Improve coating
Colour retention.
Specific implementation mode
Before further describing the specific embodiments of the present invention, it should be appreciated that protection scope of the present invention is not limited to down
State specific specific embodiment；It is also understood that the term used in the embodiment of the present invention is specific specific in order to describe
Embodiment, the protection domain being not intended to be limiting of the invention.The test method of actual conditions is not specified in the following example,
Usually according to normal condition, or according to the condition proposed by each manufacturer.
When embodiment provides numberical range, it should be appreciated that except non-present invention is otherwise noted, two ends of each numberical range
Any one numerical value can be selected between point and two endpoints.Unless otherwise defined, in the present invention all technologies for using and
Scientific terminology is identical as the normally understood meaning of those skilled in the art of the present technique.Except used in embodiment specific method, equipment,
Outside material, the record according to those skilled in the art to the grasp of the prior art and the present invention can also use and this
Any method, equipment and the material of the similar or equivalent prior art of method, equipment described in inventive embodiments, material come real
The existing present invention.
Embodiment 1
One, the anion indoor coating of the health environment-friendly of the present embodiment, includes the material composition of following parts by weight：
0.1 parts by weight of wetting agent；1.2 parts by weight of dispersant；0.3 parts by weight of antifoaming agent；0.6 parts by weight of coalescents；It is anti-
Freeze 0.3 parts by weight of agent；0.2 parts by weight of thickener；0.5 parts by weight of levelling agent；0.1 parts by weight of mould inhibitor；0.5 weight of fungicide
Part；0.1 parts by weight of multifunctional assistant；25 parts by weight of titanium dioxide；6 parts by weight of calcium carbonate；5 parts by weight of calcined kaolin；Mica powder 2
Parts by weight；2 parts by weight of sub-nanometer glue are won in match；0.5 parts by weight of anion mineral additive；40 parts by weight of water-fast environment-friendly adhesive；
3 parts by weight of opacity polymer lotion；18 parts by weight of deionized water.
The raw material information of each component is as follows：Moisten the BYK-347 that reagent is BYK companies；Dispersant is BYK companies
Disperbyk-102；Antifoaming agent is the BYK-034 of BYK companies；The coalescents are the OE-300 of Eastman companies；It is described
Antifreezing agent is the ethylene glycol of Iranian Worldwide, Inc；The thickener is the hydroxyethyl cellulose of Clariant companies；The levelling
Agent is the BYK-337 of BYK companies；The mould inhibitor is the NIPACIDE DFX-1 of Clariant companies；Fungicide is
The NIPACIDE BIT 20 of Clariant companies；Multifunctional assistant is the Codisbuffer G3 of Shenzhen Hai Run chemical companies；Institute
State the R996 that titanium dioxide is Sichuan Long Mangtai industry company；The grain size of calcium carbonate is 800 mesh；The grain size of calcined kaolin is 800 mesh；
The grain size of mica powder is 800 mesh；The grain size that sub-nanometer glue is won in match is 800 mesh；The preparation method of anion mineral additive includes：
(1) it uses radioactivity prospecting instrument to carry out Stepwise Screening to former stone each component iron dravite, opal, six ring stones, will not meet
It is required that permanently dispelled containing radioactive material material, it is ensured that raw material are "dead"；(2) "dead" iron magnesium is electrical
Stone, opal, the vibrations screening of six ring stone mixed grindings, remove the impurity in former stone；(3) by double plate magnetic separator, in nature
It is purified in the high-intensity magnetic field of humidity, reaches 98% or more purity；(4) the mineral mountain flour after purification is used into GS wet types
Ball-stirring mill carries out fine crushing, its grain size is made to reach Nano grade (d50≤0.8um,d97≤ 2.0um), finally obtain bear from
Daughter mineral additive；Water-fast environment-friendly adhesive is the aqueous ethene-vinyl acetate copolymer emulsion Celvolit- of Celanese Corp.
1475；Opacity polymer lotion is the Unihub-E of DOW companies.
Two, the preparation method of the anion indoor coating of the health environment-friendly of the present embodiment：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, 1/2 antifoaming agent, 1/4 thickener are filled
Divide and stirs evenly；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, 1/2 thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, 1/2 defoaming are added in step (2) resulting material
Agent, levelling agent, 1/4 thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, and filtering, packaging is to get strong
The anion indoor coating of Kang Huanbao.
Three, performance test：
The anion indoor coating of health environment-friendly prepared by the present embodiment is tested for the property, the results detailed in Table 1.
Embodiment 2
One, the anion indoor coating of the health environment-friendly of the present embodiment, includes the material composition of following parts by weight：
0.4 parts by weight of wetting agent；0.5 parts by weight of wetting agent；0.9 parts by weight of antifoaming agent；0.2 parts by weight of coalescents；It is anti-
Freeze 0.9 parts by weight of agent；0.6 parts by weight of thickener；0.2 parts by weight of levelling agent；0.5 parts by weight of mould inhibitor；0.1 weight of fungicide
Part；0.4 parts by weight of multifunctional assistant；15 parts by weight of titanium dioxide；8 parts by weight of calcium carbonate；7 parts by weight of calcined kaolin；Mica powder 3
Parts by weight；2 parts by weight of sub-nanometer glue are won in match；1.8 parts by weight of anion mineral additive；20 parts by weight of water-fast environment-friendly adhesive；
8 parts by weight of opacity polymer lotion；25 parts by weight of deionized water.
The raw material information of each component is as follows：Moisten the Wet 510 that reagent is Tego companies；Dispersant is Clariant companies
Dispersogen 4387；Antifoaming agent is the Dispelair CF 550 of Blankburn companies；The coalescents are DOW public
The UCAR Filmer IBT of department；The antifreezing agent is the diethylene glycol (DEG) of Samsung companies；The thickener is Samsung companies
Hydroxyethyl cellulose；The levelling agent is the Levelol W-409 of De Qian companies；The mould inhibitor is the AMICAL of DOW companies
Flowable；Fungicide is the KATHON LXE of DOW companies；Multifunctional assistant is the AMP-95 of DOW companies；The titanium dioxide is
The R980 of Japanese Shi Yuan companies；The grain size of calcium carbonate is 2000 mesh；The grain size of calcined kaolin is 2000 mesh；The grain size of mica powder
For 2000 mesh；The grain size that sub-nanometer glue is won in match is 2000 mesh；The preparation method of anion mineral additive includes：(1) it uses and puts
Penetrating property survey meter carries out Stepwise Screening to former stone each component sea-gull stone, stone needle, serpentine, astroies, medical stone, will not meet
It is required that permanently dispelled containing radioactive material material, it is ensured that raw material are "dead"；(2) by "dead" sea-gull stone, stone acupuncture needle
Stone, serpentine, astroies, the vibrations screening of medical stone mixed grinding, remove the impurity in former stone；(3) pass through double plate magnetic separation
Machine is purified in the high-intensity magnetic field of natural humidity, reaches 98% or more purity；(4) by the mineral mountain flour after purification
Fine crushing is carried out using GS wet srirred mills, its grain size is made to reach Nano grade (d50≤0.8um,d97≤ 2.0um), most
Anion mineral additive is obtained eventually；Water-fast environment-friendly adhesive is the waterborne styrene-acrylic emulsion Vinacryl-7199 of Henkel Corp.；It hides
Lid polymer emulsion is the ZG-001 that Xi'an flower bud sharpens work.
Two, the preparation method of the anion indoor coating of the health environment-friendly of the present embodiment：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, 1/2 antifoaming agent, 1/4 thickener are filled
Divide and stirs evenly；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, 1/2 thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, 1/2 defoaming are added in step (2) resulting material
Agent, levelling agent, 1/4 thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, and filtering, packaging is to get strong
The anion indoor coating of Kang Huanbao.
Three, performance test：
The anion indoor coating of health environment-friendly prepared by the present embodiment is tested for the property, the results detailed in Table 1.
Embodiment 3
One, the anion indoor coating of the health environment-friendly of the present embodiment, includes the material composition of following parts by weight：
0.2 parts by weight of wetting agent；0.7 parts by weight of dispersant；0.7 parts by weight of antifoaming agent；0.4 parts by weight of coalescents；It is anti-
Freeze 0.5 parts by weight of agent；0.5 parts by weight of thickener；0.4 parts by weight of levelling agent；0.3 parts by weight of mould inhibitor；0.3 weight of fungicide
Part；0.3 parts by weight of multifunctional assistant；18 parts by weight of titanium dioxide；11 parts by weight of calcium carbonate；9 parts by weight of calcined kaolin；Mica powder
8 parts by weight；2 parts by weight of sub-nanometer glue are won in match；1.0 parts by weight of anion mineral additive；30 parts by weight of water-fast environment-friendly adhesive；
5 parts by weight of opacity polymer lotion；22 parts by weight of deionized water.
The raw material information of each component is as follows：Moisten the EnviroGem 360 that reagent is Air Product companies；Dispersant is
The COATEX P30 of COATEX companies；Antifoaming agent is the Drewplus T-4201 of Ashland companies；The coalescents are
The CS-12 of CHISSO companies；The antifreezing agent is the propylene glycol of DOW companies；The thickener is the ethoxy of Ashland companies
Cellulose；The levelling agent is the Metolat 366 of Munzing companies；The mould inhibitor is the Fongal of Progiven companies
DO A2W；Fungicide is the Proxel LV of Avecia companies；Multifunctional assistant is the SYNTHRO-STAB of SYNTHRO companies
25B；The titanium dioxide is the R902 of E.I.Du Pont Company；The grain size of calcium carbonate is 1250 mesh；The grain size of calcined kaolin is 1250 mesh；
The grain size of mica powder is 1250 mesh；The grain size that sub-nanometer glue is won in match is 1250 mesh；The preparation method packet of anion mineral additive
It includes：(1) radioactivity prospecting instrument is used to carry out former stone each component volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, shell
Stepwise Screening is permanently dispelled undesirable containing radioactive material material, it is ensured that raw material are "dead"；(2) by nothing
Radioactive volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, the vibrations screening of shell mixed grinding, remove in former stone
Impurity；(3) it by double plate magnetic separator, is purified in the high-intensity magnetic field of natural humidity, reaches 98% or more purity；
(4) the mineral mountain flour after purification is subjected to fine crushing using GS wet srirred mills, its grain size is made to reach Nano grade (d50≤
0.8um,d97≤ 2.0um), finally obtain anion mineral additive；Water-fast environment-friendly adhesive is aqueous pure third breast of DOW companies
Liquid SF-400；Opacity polymer lotion is the THYOSIL-E451 of DIRANSA companies.
Two, the preparation method of the anion indoor coating of the health environment-friendly of the present embodiment：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, 1/2 antifoaming agent, 1/4 thickener are filled
Divide and stirs evenly；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, 1/2 thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, 1/2 defoaming are added in step (2) resulting material
Agent, levelling agent, 1/4 thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, and filtering, packaging is to get strong
The anion indoor coating of Kang Huanbao.
Three, performance test：
The anion indoor coating of health environment-friendly prepared by the present embodiment is tested for the property, the results detailed in Table 1.
Embodiment 4 (comparative example 1)
One, the anion indoor coating of the health environment-friendly of the present embodiment, includes the material composition of following parts by weight：
0.2 parts by weight of wetting agent；0.7 parts by weight of dispersant；0.7 parts by weight of antifoaming agent；0.4 parts by weight of coalescents；It is anti-
Freeze 0.5 parts by weight of agent；0.5 parts by weight of thickener；0.4 parts by weight of levelling agent；0.3 parts by weight of mould inhibitor；0.3 weight of fungicide
Part；0.3 parts by weight of multifunctional assistant；18 parts by weight of titanium dioxide；11 parts by weight of calcium carbonate；9 parts by weight of calcined kaolin；Mica powder
8 parts by weight；2 parts by weight of sub-nanometer glue are won in match；1.0 parts by weight of anion mineral additive；30 parts by weight of water-fast environment-friendly adhesive；
10 parts by weight of opacity polymer lotion；22 parts by weight of deionized water.
The raw material information of each component is as follows：Moisten the EnviroGem 360 that reagent is Air Product companies；Dispersant is
The COATEX P30 of COATEX companies；Antifoaming agent is the Drewplus T-4201 of Ashland companies；The coalescents are
The CS-12 of CHISSO companies；The antifreezing agent is the propylene glycol of DOW companies；The thickener is the ethoxy of Ashland companies
Cellulose；The levelling agent is the Metolat 366 of Munzing companies；The mould inhibitor is the Fongal of Progiven companies
DO A2W；Fungicide is the Proxel LV of Avecia companies；Multifunctional assistant is the SYNTHRO-STAB of SYNTHRO companies
25B；The titanium dioxide is the R902 of E.I.Du Pont Company；The grain size of calcium carbonate is 1250 mesh；The grain size of calcined kaolin is 1250 mesh；
The grain size of mica powder is 1250 mesh；The grain size that sub-nanometer glue is won in match is 1250 mesh；The preparation method packet of anion mineral additive
It includes：(1) radioactivity prospecting instrument is used to carry out former stone each component volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, shell
Stepwise Screening is permanently dispelled undesirable containing radioactive material material, it is ensured that raw material are "dead"；(2) by nothing
Radioactive volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, the vibrations screening of shell mixed grinding, remove in former stone
Impurity；(3) it by double plate magnetic separator, is purified in the high-intensity magnetic field of natural humidity, reaches 98% or more purity；
(4) the mineral mountain flour after purification is subjected to fine crushing using GS wet srirred mills, its grain size is made to reach Nano grade (d50≤
0.8um,d97≤ 2.0um), finally obtain anion mineral additive；Water-fast environment-friendly adhesive is aqueous pure third breast of DOW companies
Liquid SF-400；Opacity polymer lotion is the THYOSIL-E451 of DIRANSA companies.
Two, the preparation method of the anion indoor coating of the health environment-friendly of the present embodiment：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, 1/2 antifoaming agent, 1/4 thickener are filled
Divide and stirs evenly；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, 1/2 thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, 1/2 defoaming are added in step (2) resulting material
Agent, levelling agent, 1/4 thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, and filtering, packaging is to get strong
The anion indoor coating of Kang Huanbao.
Three, performance test：
The anion indoor coating of health environment-friendly prepared by the present embodiment is tested for the property, the results detailed in Table 1.
Embodiment 5 (comparative example 2)
One, the anion indoor coating of the health environment-friendly of the present embodiment, includes the material composition of following parts by weight：
0.2 parts by weight of wetting agent；0.7 parts by weight of dispersant；0.7 parts by weight of antifoaming agent；0.4 parts by weight of coalescents；It is anti-
Freeze 0.5 parts by weight of agent；0.5 parts by weight of thickener；0.4 parts by weight of levelling agent；0.3 parts by weight of mould inhibitor；0.3 weight of fungicide
Part；0.3 parts by weight of multifunctional assistant；18 parts by weight of titanium dioxide；11 parts by weight of calcium carbonate；9 parts by weight of calcined kaolin；Mica powder
8 parts by weight；2 parts by weight of sub-nanometer glue are won in match；1.0 parts by weight of anion mineral additive；30 parts by weight of water-fast environment-friendly adhesive；
1 parts by weight of opacity polymer lotion；22 parts by weight of deionized water.
The raw material information of each component is as follows：Moisten the EnviroGem 360 that reagent is Air Product companies；Dispersant is
The COATEX P30 of COATEX companies；Antifoaming agent is the Drewplus T-4201 of Ashland companies；The coalescents are
The CS-12 of CHISSO companies；The antifreezing agent is the propylene glycol of DOW companies；The thickener is the ethoxy of Ashland companies
Cellulose；The levelling agent is the Metolat 366 of Munzing companies；The mould inhibitor is the Fongal of Progiven companies
DO A2W；Fungicide is the Proxel LV of Avecia companies；Multifunctional assistant is the SYNTHRO-STAB of SYNTHRO companies
25B；The titanium dioxide is the R902 of E.I.Du Pont Company；The grain size of calcium carbonate is 1250 mesh；The grain size of calcined kaolin is 1250 mesh；
The grain size of mica powder is 1250 mesh；The grain size that sub-nanometer glue is won in match is 1250 mesh；The preparation method packet of anion mineral additive
It includes：(1) radioactivity prospecting instrument is used to carry out former stone each component volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, shell
Stepwise Screening is permanently dispelled undesirable containing radioactive material material, it is ensured that raw material are "dead"；(2) by nothing
Radioactive volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, the vibrations screening of shell mixed grinding, remove in former stone
Impurity；(3) it by double plate magnetic separator, is purified in the high-intensity magnetic field of natural humidity, reaches 98% or more purity；
(4) the mineral mountain flour after purification is subjected to fine crushing using GS wet srirred mills, its grain size is made to reach Nano grade (d50≤
0.8um,d97≤ 2.0um), finally obtain anion mineral additive；Water-fast environment-friendly adhesive is aqueous pure third breast of DOW companies
Liquid SF-400；Opacity polymer lotion is the THYOSIL-E451 of DIRANSA companies.
Two, the preparation method of the anion indoor coating of the health environment-friendly of the present embodiment：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, 1/2 antifoaming agent, 1/4 thickener are filled
Divide and stirs evenly；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, 1/2 thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, 1/2 defoaming are added in step (2) resulting material
Agent, levelling agent, 1/4 thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, and filtering, packaging is to get strong
The anion indoor coating of Kang Huanbao.
Embodiment 6 (comparative example 3)
One, the anion indoor coating of the health environment-friendly of the present embodiment, includes the material composition of following parts by weight：
0.2 parts by weight of wetting agent；0.7 parts by weight of dispersant；0.7 parts by weight of antifoaming agent；0.4 parts by weight of coalescents；It is anti-
Freeze 0.5 parts by weight of agent；0.5 parts by weight of thickener；0.4 parts by weight of levelling agent；0.3 parts by weight of mould inhibitor；0.3 weight of fungicide
Part；0.3 parts by weight of multifunctional assistant；18 parts by weight of titanium dioxide；11 parts by weight of calcium carbonate；9 parts by weight of calcined kaolin；Mica powder
8 parts by weight；2 parts by weight of sub-nanometer glue are won in match；0 parts by weight of anion mineral additive；30 parts by weight of water-fast environment-friendly adhesive；It hides
10 parts by weight of lid polymer emulsion；22 parts by weight of deionized water.
The raw material information of each component is as follows：Moisten the EnviroGem 360 that reagent is Air Product companies；Dispersant is
The COATEX P30 of COATEX companies；Antifoaming agent is the Drewplus T-4201 of Ashland companies；The coalescents are
The CS-12 of CHISSO companies；The antifreezing agent is the propylene glycol of DOW companies；The thickener is the ethoxy of Ashland companies
Cellulose；The levelling agent is the Metolat 366 of Munzing companies；The mould inhibitor is the Fongal of Progiven companies
DO A2W；Fungicide is the Proxel LV of Avecia companies；Multifunctional assistant is the SYNTHRO-STAB of SYNTHRO companies
25B；The titanium dioxide is the R902 of E.I.Du Pont Company；The grain size of calcium carbonate is 1250 mesh；The grain size of calcined kaolin is 1250 mesh；
The grain size of mica powder is 1250 mesh；The grain size that sub-nanometer glue is won in match is 1250 mesh；The preparation method packet of anion mineral additive
It includes：(1) radioactivity prospecting instrument is used to carry out former stone each component volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, shell
Stepwise Screening is permanently dispelled undesirable containing radioactive material material, it is ensured that raw material are "dead"；(2) by nothing
Radioactive volcanic rock, germanite, ingenious military move stone, hokutolite, Doctor king stone, the vibrations screening of shell mixed grinding, remove in former stone
Impurity；(3) it by double plate magnetic separator, is purified in the high-intensity magnetic field of natural humidity, reaches 98% or more purity；
(4) the mineral mountain flour after purification is subjected to fine crushing using GS wet srirred mills, its grain size is made to reach Nano grade (d50≤
0.8um,d97≤ 2.0um), finally obtain anion mineral additive；Water-fast environment-friendly adhesive is aqueous pure third breast of DOW companies
Liquid SF-400；Opacity polymer lotion is the THYOSIL-E451 of DIRANSA companies.
Two, the preparation method of the anion indoor coating of the health environment-friendly of the present embodiment：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, 1/2 antifoaming agent, 1/4 thickener are filled
Divide and stirs evenly；
(2) continue stirring condition under, in step (1) resulting material be added titanium dioxide, 1/2 thickener, filler and bear from
Daughter mineral additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding
Mill；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, 1/2 defoaming are added in step (2) resulting material
Agent, levelling agent, 1/4 thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, and filtering, packaging is to get strong
The anion indoor coating of Kang Huanbao.
Three, performance test：
The anion indoor coating of health environment-friendly prepared by the present embodiment is tested for the property, the results detailed in Table 1.
Embodiment 7
The anion indoor coating of health environment-friendly obtained by above-described embodiment is tested for the property, reference standard：GB/
T9756-2009《Resin latex dope》；GB/T18582-2008《Have in indoor decorating and refurnishing materials interior wall coating
Evil substance limitation》；JCT 1074-2008《Function of purifying indoor air coating material purifying property》；HG/T4109-2009《It is negative
Ion functional paint》；GB 6566-2010《Radioactive material radionuclides limitation》, the results are shown in Table 1：
Table 1
The above, only presently preferred embodiments of the present invention, not to the present invention in any form with substantial limitation,
It should be pointed out that for those skilled in the art, under the premise of not departing from the method for the present invention, can also make
Several improvement and supplement, these are improved and supplement also should be regarded as protection scope of the present invention.All those skilled in the art,
Without departing from the spirit and scope of the present invention, when made using disclosed above technology contents it is a little more
Dynamic, modification and the equivalent variations developed, are the equivalent embodiment of the present invention；Meanwhile all substantial technologicals pair according to the present invention
The variation, modification and evolution of any equivalent variations made by above-described embodiment, still fall within the range of technical scheme of the present invention
It is interior.
Claims (10)
1. a kind of anion indoor coating of health environment-friendly, includes the material composition of following parts by weight：0.1~0.4 weight of wetting agent
Measure part；0.5~1.2 parts by weight of dispersant；0.3~0.9 parts by weight of antifoaming agent；0.2~0.6 parts by weight of coalescents；Antifreezing agent
0.3~0.9 parts by weight；0.2~0.6 parts by weight of thickener；0.2~0.5 parts by weight of levelling agent；0.1~0.5 weight of mould inhibitor
Part；0.1~0.5 parts by weight of fungicide；0.1~0.4 parts by weight of multifunctional assistant；15~25 parts by weight of titanium dioxide；Filler 15~
30 parts by weight；0.5~1.8 parts by weight of anion mineral additive；20~40 parts by weight of water-fast environment-friendly adhesive；Opacity polymer
3~8 parts by weight of lotion；18~25 parts by weight of water.
2. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that the anion mineral add
Add agent be selected from iron dravite, opal, six ring stones, sea-gull stone, stone needle, serpentine, astroies, medical stone, volcanic rock,
The combination of germanite, ingenious military move stone, hokutolite, Doctor king stone, shell any one or more of.
3. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that the anion mineral add
Add agent that there are any one of following characteristics or multinomial：(1) the anion mineral additive is "dead"；And/or (2) are described
Purity >=98% of anion mineral additive.
4. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that the anion mineral add
Add the grain size of agent in Nano grade, d50≤ 0.8um, d97≤2.0um。
5. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that the opacity polymer breast
Liquid has any one of following characteristics or multinomial：(1) shell structure of the opacity polymer lotion by modified polystyrene, change
Property polymethyl methacrylate, modified polyacrylonitrile any one or more of composition；And/or (2) described opacity polymer breast
It is 30%~50% (V/V%) that the inside of liquid, which has hollow microporous structure, cavity rate,.
6. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that the opacity polymer breast
The hollow latex particles diameter of liquid is 400~500nm.
7. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that further include in following characteristics
Any one or multinomial：(1) wetting agent is non-ionic wetting agent；And/or (2) described dispersant is the poly- carboxylic of anionic
Acid sodium-salt class dispersant；And/or (3) described antifoaming agent is nonionic mineral oil defoaming agent；And/or (4) described film forming helps
Agent is Lauryl Alcohol esters coalescents；And/or (5) described antifreezing agent is low-carbon alcohols；And/or (6) described thickener is hydroxyl second
Base cellulose；And/or (7) described levelling agent is nonionic levelling agent；And/or (8) described mould inhibitor is compound benzene sulfone or miaow
Azole high-efficiency broad spectrum dry film antibacterial mildew inhibitor；And/or (9) described fungicide is compound different Anthelvet ketone antibiotic bactericide；With/
Or (10) described multifunctional assistant is denatured ethanol amine salt；And/or (11) described titanium dioxide is rutile type titanium white；And/or
(12) filler is selected from the combination of calcium carbonate, calcined kaolin, mica powder, the rich sub-nanometer glue any one or more of of match.
8. the anion indoor coating of health environment-friendly according to claim 1, which is characterized in that further include in following characteristics
Any one or multinomial：(1) wetting agent is nonionic polyether modified siloxane class wetting agent；(2) the antifreezing agent choosing
From ethylene glycol, the combination of propylene glycol or diethylene glycol (DEG) any one or more of；(3) levelling agent is that nonionic is modified poly- silicon
Oxygen alkane levelling agent；(4) mesh of the grain size of the filler >=800.
9. the method for the anion indoor coating of health environment-friendly as described in any one of claim 1~8, including step：
(1) deionized water in raw material components, dispersant, wetting agent, antifreezing agent, part antifoaming agent, part thickener is abundant
It stirs evenly；
(2) continue under stirring condition, titanium dioxide, part thickener, filler and anion mine are added in step (1) resulting material
Object additive, high speed dispersion, then it is transferred to grinding in grinder, when product particle fineness reaches 18~22um, stop grinding；
(3) mould inhibitor, fungicide, multifunctional assistant, coalescents, remaining antifoaming agent, stream are added in step (2) resulting material
Flat agent, remaining thickener, water-fast environment-friendly adhesive and opacity polymer lotion, stir evenly, filter, pack to get healthy ring
The anion indoor coating of guarantor.
10. use of the anion indoor coating of health environment-friendly in purifying the air of a room as described in any one of claim 1~8
On the way.
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|---|---|---|---|
| CN201610980794 | 2016-11-08 | ||
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| CN109832888A (en) * | 2019-01-24 | 2019-06-04 | 江苏沃荷乳胶科技有限公司 | A kind of anion latex pillow and preparation method thereof |
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| CN111234612A (en) * | 2020-03-06 | 2020-06-05 | 北京仲基应用技术研究院有限公司 | Long-acting insect-expelling and purifying functional coating and preparation method and construction method thereof |
| CN116396652A (en) * | 2023-06-06 | 2023-07-07 | 广州百能建筑科技有限公司 | Building waterproof coating composition and preparation method thereof |
| CN116396652B (en) * | 2023-06-06 | 2023-08-11 | 广州百能建筑科技有限公司 | Building waterproof coating composition and preparation method thereof |
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