CN103709842B - A kind of Herbal essence health paint and preparation method thereof - Google Patents
A kind of Herbal essence health paint and preparation method thereof Download PDFInfo
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Abstract
The present invention relates to the paint field in chemical industrial field, particularly relate to a kind of Herbal essence health paint and preparation method thereof.The invention provides a kind of Herbal essence health paint, the feed composition of described Herbal essence health paint comprises the following component with parts by weight: draft nucleocapsid structure is breathed freely emulsion 20 ~ 40 parts, draft additive 1 ~ 2 part, 1 ~ 2 part, anionic sterilization pulvis, 50 ~ 70 parts, color stuffing powder slurry, auxiliary agent 1 ~ 10 part, deionized water 30 ~ 40 parts.The present invention is characterized in that employing a kind of draft nucleocapsid structure and to breathe freely the coating that emulsion, draft additive and negative ion pulvis make, nontoxic, free from extraneous odour, waterproof, good permeability, effectively can dispel obnoxious flavour, suppress various mould-growth, the lasting anion releasing of energy, effective Air quality improving indoor environment, improves the immunizing power of people, promotes the health of people.
Description
Technical field
The present invention relates to the paint field in chemical industrial field, particularly relate to a kind of Herbal essence health paint and preparation method thereof.
Background technology
In recent years, market there is many kind environment-protecting health interior wall coatings.Their main bamboo charcoal coating, negative ion paint, nothing add coating and Diamond Search coating etc., wherein, because the gap structure of its senior prosperity of bamboo charcoal used in bamboo charcoal coating has huge surface-area, very easily fully contact with objectionable impuritiess such as the formaldehyde in air, benzene class organic volatiles (Tvoc), its absorption field of force can purifying harmful gas molecule, reaches air purification effect; And negative ion paint is that to the addition of negative ion powder in coating be utilize nature to produce the principle of negative ion, a kind of composite minerals (i.e. rare earth and tourmaline powder) of synthetic or proportioning, market has many negative ion powders to fill a prescription not science, individual workship mixes several mineral simultaneously.Such as (calcium powder, silica powder, wheat aluminite powder)+lanthanon, rare earth element and radioelement etc., the radioelement wherein added, extremely harmful to human body.
The present invention is intended to release a kind of herbal essences health type paint, the coating adopting nucleocapsid structure air-permeable emulsion, natural herb serial pulvis, essential oil capsules and part natural nano negative ion pulvis to make, has permanent negative aeroion generating function, stronger far-infrared transmitting function, excellent antibiotic and sterilizing function; Improve IAQ (indoor air quality), the atmospheric pollution eliminating the generations such as cigarette, oil, formaldehyde, benzene kind solvent and household electrical appliances fast and electronic pollution, promote the metabolism of human body, increase body resistance against diseases and sterilization etc.
Along with " compounding technology " development in Materials science, the eighties scientists proposes the new ideas of " particle design ".Namely from particle aspect, but not the mechanically mixing of macroscopic view carrys out compound, and scientists proposes the new ideas of " hud polymerization emulsion " thus.So-called nucleocapsid, as the term suggests just refer to polymer A to be core, the latex particle of outer layer covers polymer B is the structure of shell, it mainly makes the inner side and outer side of the granule interior composition that enrichment is different respectively by stage polymerization under certain condition by two or more monomer molecules by different in kind, by the various combination of core and shell, obtain the latex particle of a series of different shape thus can give nucleocapsid different function.
The synthetic method of core-shell emulsion, mainly through three kinds of mechanism, comprises Grafting mechanism, interpenetrating polymer networks (IPN) mechanism and ionic bonding mechanism.
Core-shell emulsion is compared with general emulsion, and difference is only that the structural form of emulsion particle is different.The structural form of core-shell latex particles uniqueness substantially improves the performance of polymer emulsion.Even if when same materials forms, the polymer emulsion with latex particle with core shell structure also often has more excellent performance than general polymerization thing emulsion, therefore, since the eighties, core-shell emulsion polymerization is subject to the favor of people always, obtains many progress at core-shell technique, emulsion particle somatometry of physique, emulsion particle particle form in Influencing Mechanism of polymer performance etc.
The Environment-friendlyinternal internal wall paint used in the market mainly contains bamboo charcoal coating and negative ion paint etc.Wherein, because its highly developed gap structure of bamboo charcoal used in bamboo charcoal coating has huge surface-area, very easily with the formaldehyde in air, the objectionable impurities such as benzene and TVOC fully contacts, its absorption field of force can purify toxic gas molecule, reach air purification effect, and negative ion paint adopts negative ion powder, by a kind of composite minerals of synthetic or proportioning.Negative ion powder formula great majority are in the market unscientific, and several mineral of some individual workships mixing, containing lanthanon, rare earth element, radioelement, therefore its formula has limitation.This negative ion powder is extremely harmful to human body.
Summary of the invention
The shortcoming of prior art in view of the above, a kind of Herbal essence health paint of first aspect present invention, the feed composition of Herbal essence health paint comprises the following component with parts by weight:
Described draft nucleocapsid structure its raw material of emulsion of breathing freely comprises core portion raw material and shell portion raw material, and the weight ratio of described core portion raw material and shell portion raw material is 1:0.2-0.4, and the component of described core portion raw material comprises the following component with parts by weight:
Tensio-active agent 1-3 part;
Initiator 0.2-0.3 part;
Core portion soft monomer 10-20 part;
Core portion hard monomer 5-15 part;
Organo-siloxane monomer 3-5 part;
Essential oils of herbs 0.1-0.3 part;
Core portion function monomer 0.5-1.5 part;
Deionized water 40-45 part.
The component of described shell portion raw material comprises the following component with parts by weight:
Tensio-active agent 0.2-0.5 part;
Initiator 0.1-0.3 part;
Shell portion soft monomer 3-8 part;
Shell portion hard monomer 5-10 part;
Organo-siloxane monomer 1-2 part;
Shell portion function monomer 0.2-1.0 part;
Deionized water 5-10 part.
Preferably, the component of described core portion raw material comprises the following component with parts by weight:
Tensio-active agent 1.5-2.5 part;
Initiator 0.2-0.3 part;
Core portion soft monomer 13-17 part;
Core portion hard monomer 10-14 part;
Organo-siloxane monomer 3.5-4.5 part;
Essential oils of herbs 0.1-0.3 part;
Core portion function monomer 0.8-1.2 part;
Deionized water 40-45 part.
The component of described shell portion raw material comprises the following component with parts by weight:
Tensio-active agent 0.3-0.4 part;
Initiator 0.1-0.2 part;
Shell portion soft monomer 3.5-6 part;
Shell portion hard monomer 8-10 part;
Organo-siloxane monomer 1-2 part;
Shell portion function monomer 0.2-1.0 part;
Deionized water 5.5-8.4 part.
Preferably, described anionic sterilization pulvis is selected from one or both the mixing in negative ion powder and nano-negative ion compound disinfectant.
Preferably, described color stuffing powder slurry is selected from one or more the combination in titanium dioxide, calcium carbonate, kaolin powder, Sai Boya nanometer rubber powder (improving a kind of material of paint thixotropy, contrast ratio, abrasion resistance, application property and film performance).
Preferably, described draft additive is selected from one or both the mixing in draft nanometer pulvis and essential oils of herbs capsule.
Described draft nanometer pulvis is selected from Root of Indigowoad (dry root of IatisindigoticaFort.), giant knotweed (dry rhizome of PolygonumcuspidatumSieb.etZucc. and root), cape jasmine (dry mature fruit of GardeniajasminoidesEllis), pine needle (Cedrus), one or both mixing in tea tree (Melaleucaalternifola) or aloe (Aloeveravar.chinensis), essential oils of herbs capsule is selected from lavandula angustifolia (lavandulapedunculata) essential oil capsules, tea tree (Melaleucaalternifola) essential oil capsules, Root and stem of Cholla (Opuntiastricta) essential oil capsules, one or both mixing in eucalyptus globolus (eucalyptusglobulus) essential oil capsules.
Preferably, described core portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, 2-EHA; Shell portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, 2-EHA.
Preferably, described organo-siloxane monomer is selected from one or more the combination in vinyl silane triisopropoxide, r-methylpropionyloxy propyl group three isopropoxy silane, eight vinyl cyclotetrasiloxanes, octamethylcyclotetrasiloxane.
Preferably, described core portion function monomer is selected from the two or more combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, acrylamide; Shell portion function monomer is selected from the two or more combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, acrylamide.
Preferably, described essential oils of herbs is selected from lavandula angustifolia (lavandulapedunculata) essential oil, tea tree (Melaleucaalternifola) essential oil, crape myrtle (Lagerstroemiaindica) essential oil, China pink (Dianthuschinensis) essential oil, eucalyptus globolus (eucalyptusglobulus) essential oil, pineapple (Ananascomosus) essential oil, Root and stem of Cholla (Opuntiastricta) essential oil, aloe (Aloeveravar.chinensis) essential oil, lemongrass (MoslachinensisMaxim) essential oil, Flos Pelargonii (Pelargoniumhortorum) essential oil, one or more combination in cloves (Syzygiumaromaticum) essential oil.
Preferably, described initiator is selected from the one in ammonium persulphate, Potassium Persulphate or Sodium Persulfate.
Preferably, described tensio-active agent is the mixture of sulfo-succinic acid alkyl ethoxylated ester sodium salt, side chain alcohol ether and the polyether thiourea hydrochlorate containing allyl group alkoxyl group.
Preferably, described core portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid; Described shell portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid.
Preferably, described auxiliary agent is selected from one or more the combination in dispersion agent, wetting agent, defoamer, sterilant, mould inhibitor, flow agent, pH adjusting agent, compound film former.
Preferably, described auxiliary agent comprises following component by weight: dispersion agent 0.2-0.5 part, wetting agent 0.1-0.4 part, defoamer 0.2-0.5 part, sterilant 0.1-0.2 part, mould inhibitor 0.2-0.4 part, flow agent 0.5-1.0 part, pH adjusting agent 0.08-0.15 part, compound film former 0.5-1 part; Described defoamer comprises defoamer a and defoamer b.
Preferably, described dispersion agent is one or both the mixture in dispersion agent S-70S and dispersion agent 2320.Described dispersion agent S-70S, by Shanghai, loyal Chemical Co., Ltd. provides; Described dispersion agent 2320, by Shenzhen, Hai Chuan company limited provides.
The model of described wetting agent is LB407 or EFS4070, and by Shanghai, loyal Chemical Co., Ltd. provides; .
Described defoamer a is defoamer 315, and described defoamer b is defoamer DF538.Described defoamer 315, by Shenzhen, Hai Chuan company limited provides; Described defoamer DF538, by Shanghai, loyal Chemical Co., Ltd. provides.
Described titanium dioxide 996, by Shanghai, Yan Tai company limited provides.
Described Ls-01 superfine nano negative ion powder, by Shanghai, Lu Li Nono-material Science & Technology Ltd. provides.
Sai Boya nanometer rubber powder is a kind of a kind of material improving paint thixotropy, contrast ratio, abrasion resistance, application property and film performance, and adding sincere nonmetal mining industry company limited by Yuhang provides.
The model of described defoamer is DF538, and by Shanghai, loyal Chemical Co., Ltd. provides.
The model of described flow agent is lEV-202, and by Shanghai, loyal Chemical Co., Ltd. provides.
The model of described pH value regulator is AP-95, and by Shanghai, loyal Chemical Co., Ltd. provides.
The model of described sterilant is 515, is provided towards tinkling of pieces of jade company limited by Shanghai.
The model of described mould inhibitor is A2W, is provided towards tinkling of pieces of jade company limited by Shanghai.
The model of described wetting agent is the one in EFS-4070, and by Shanghai, loyal Chemical Co., Ltd. provides.
Preferably, described compound film former is selected from as one or both the mixture in propandiol butyl ether or 12 carbon ester alcohol.
Second aspect present invention provides a kind of preparation method of Herbal essence health paint, comprises the steps:
(1) the 26-30 part deionized water in described core portion raw material, 0.3-1 part tensio-active agent, 0.7-0.1 part initiator, 3-5 part core portion soft monomer, 1-2 part core portion hard monomer, 0.1-0.5 part core portion function monomer, 0.5-1 part organo-siloxane monomer are added reactor, be warming up to 80-87 DEG C of reaction under agitation, stable reaction 10min-15min forms seed crystal; Deionized water in remaining core portion raw material, tensio-active agent, initiator, core portion soft monomer, core portion hard monomer, core portion function monomer, essential oils of herbs, organo-siloxane monomer are made core portion pre-emulsion; Gained core portion pre-emulsion is added drop-wise in reactor; Drip off rear Inducing Graft Polymerization and be incubated 2-3 hour at 83-90 DEG C;
(2) described shell portion raw material is made shell portion pre-emulsion, gained shell portion pre-emulsion is dropped in the feed liquid of step 1 gained, the weight ratio of the feed liquid of described shell portion pre-emulsion and step 1 gained is 1:0.2-0.4, drip off rear Inducing Graft Polymerization and be incubated 2-3 hour at 83-90 DEG C, be cooled to less than 40 DEG C again, then regulate PH to 7-8, add sterilant, discharging, filter draft nucleocapsid structure is breathed freely emulsion.
(3) after the deionized water in the feed composition of described Herbal essence health paint, dispersion agent, wetting agent, 1/2 defoamer being stirred, add color stuffing powder slurry and anionic sterilization pulvis under agitation, high speed dispersion, enter again on shredder and grind, when product particle fineness reaches 18-22 μm, stop grinding.
(4) the draft nucleocapsid structure adding draft additive, mould inhibitor, sterilant, pH adjusting agent, compound film former, 1/2 defoamer, flow agent and step 2 gained in step 3 gained material is breathed freely emulsion, stir, filter, packaging, obtains Herbal essence health paint.
Preferably, the dropping temperature of described step 1 center portion pre-emulsion is 80-87 DEG C, and time for adding is 2-3 hour.
Preferably, the dropping temperature of described step 2 mesochite portion pre-emulsion is 80-87 DEG C, and time for adding is 2-3 hour.
Preferably, the solution that in described step 2, adjust ph uses is selected from AP-95, and neutralization equivalent is 330-360mgHCl/g.
The present invention breathes freely emulsion (self-control) for main film forming substance with draft nucleocapsid structure.Be solvent with water, add multiple draft nanometer pulvis, essential oils of herbs capsule, natural mineral synthesis anionic sterilization pulvis and color stuffing, auxiliary agent and be prepared from.The present invention is characterized in that employing a kind of draft nucleocapsid structure and to breathe freely the coating that emulsion, draft additive and negative ion pulvis make, nontoxic, free from extraneous odour, waterproof, good permeability, effectively can dispel obnoxious flavour, suppress various mould-growth, the lasting anion releasing of energy, effective Air quality improving indoor environment, improves the immunizing power of people, promotes the health of people.Residential houses, office building, hospital, school, hotel, market, underground garage, pharmaceutical factory, food factory, boats and ships etc. can be widely used in, improve indoor air quality and decoration and protect.
Embodiment
Below by way of specific specific examples, embodiments of the present invention are described, those skilled in the art the content disclosed by this specification sheets can understand other advantages of the present invention and effect easily.The present invention can also be implemented or be applied by embodiments different in addition, and the every details in this specification sheets also can based on different viewpoints and application, carries out various modification or change not deviating under spirit of the present invention.
Notice, in the following example, the concrete processing unit that indicates or device all adopt conventional equipment in this area or device; All force value and scope all refer to absolute pressure.
In addition should be understood that the one or more method stepss mentioned in the present invention do not repel and can also to there is additive method step or can also insert additive method step before and after described combination step between these steps clearly mentioned, except as otherwise noted; Will also be understood that, the relation that is connected between the one or more equipment/devices mentioned in the present invention is not repelled and can also to be there are other equipment/devices or can also insert other equipment/devices before and after described clustered aggregates/device between these two equipment/devices clearly mentioned, except as otherwise noted.And, except as otherwise noted, the numbering of various method steps is only the convenient tool differentiating various method steps, but not be ordering or the enforceable scope of restriction the present invention of restriction various method steps, the change of its relativeness or adjustment, when changing technology contents without essence, when being also considered as the enforceable category of the present invention.
Embodiment 1
Draft nucleocapsid structure is breathed freely the preparation of emulsion:
A. core portion raw material:
B, shell portion raw material:
By the deionized water 2/3 in above-mentioned reactant formula a component, tensio-active agent 1/3, initiator 1/3, core portion soft monomer 1/4, core portion hard monomer 1/6, core portion function monomer 1/4, organo-siloxane monomer 1/6 add in reactor, be warming up to 80-85 DEG C of reaction under agitation, after stablizing 10-15min, form seed nanocrystal emulsion, then drip the pre-emulsion that in a component, remainder forms; Time for adding is 3 hours, and temperature of reaction is 80-87 DEG C, drips off rear Inducing Graft Polymerization and is incubated 1 hour, and the emulsion particle of formation is stratum nucleare.Then pre-emulsion prepared after continuing to drip the mixing of b component, time for adding is 1.5-2 hour, and temperature of reaction is 80-87 DEG C, forms shell particle, drips off rear initiation grafting copolymerization insulation 2-3 hour, namely obtains nucleocapsid structure draft and to breathe freely shape emulsion.
Embodiment 2
The preparation of Herbal essence health paint
Formula: (unit: g)
Remove that ionized water adds dispersion agent, wetting agent, defoamer 315 stir, add titanium dioxide, water-ground limestone, kaolin, negative ion pulvis, draft nanometer pulvis, Ya Na meter rubber powder high speed dispersion 30min-45min under agitation, enter on shredder and grind, sampling detects.When product particle fineness reaches about 20 μm, stop grinding.Add breathe freely emulsion (prepared by embodiment 1), essential oils of herbs capsule, mould inhibitor, sterilant, AP-95 conditioning agent, film coalescence aid, defoamer 538, the thickening leveling agent of draft nucleocapsid structure to stir, filter, packaging, obtain Herbal essence health paint, Performance Detection is as shown in table 1.
Embodiment 3
The preparation of Herbal essence health paint
Formula: (unit: g)
Technological process:
Remove that ionized water adds dispersion agent, wetting agent, defoamer 315 stir, add titanium dioxide, water-ground limestone, kaolin, negative ion pulvis, draft nanometer pulvis, Ya Na meter rubber powder high speed dispersion 30min-45min under agitation, enter on shredder and grind, sampling detects.When product particle fineness reaches about 20 μm, stop grinding.Add breathe freely emulsion (prepared by embodiment 1), essential oils of herbs capsule, mould inhibitor, sterilant, AP-95 conditioning agent, film coalescence aid, defoamer 538, the thickening leveling agent of draft nucleocapsid structure to stir, filter, packaging, obtain Herbal essence health paint, Performance Detection is as shown in table 1.
Embodiment 4
The preparation of Herbal essence health paint
Formula: (unit: g)
Technological process:
Remove that ionized water adds dispersion agent, wetting agent, defoamer 315 stir, add titanium dioxide, water-ground limestone, kaolin, negative ion pulvis, draft nanometer pulvis, Ya Na meter rubber powder high speed dispersion 30min-45min under agitation, enter on shredder and grind, sampling detects.When product particle fineness reaches about 20 μm, stop grinding.Add breathe freely emulsion (prepared by embodiment 1), essential oils of herbs capsule, mould inhibitor, sterilant, AP-95 conditioning agent, film coalescence aid, defoamer 538, the thickening leveling agent of draft nucleocapsid structure to stir, filter, packaging, obtain Herbal essence health paint, Performance Detection is as shown in table 1.
Embodiment 5
The preparation of Herbal essence health paint
Formula: (unit: g)
Technological process:
Remove that ionized water adds dispersion agent, wetting agent, defoamer 315 stir, add titanium dioxide, water-ground limestone, kaolin, negative ion pulvis, draft nanometer pulvis, Ya Na meter rubber powder high speed dispersion 30min-45min under agitation, enter on shredder and grind, sampling detects.When product particle fineness reaches about 20 μm, stop grinding.Add breathe freely emulsion (prepared by embodiment 1), essential oils of herbs capsule, mould inhibitor, sterilant, AP-95 conditioning agent, film coalescence aid, defoamer 538, the thickening leveling agent of draft nucleocapsid structure to stir, filter, packaging, obtain Herbal essence health paint, Performance Detection is as shown in table 1.
Table 1
GB/T9756-2009 " resin latex dope "
GB18582-2008 " in indoor decorating and refurnishing materials interior wall coating limits of harmful substances "
JC/T1074-2008 " function of purifying indoor air paint materials purification performance " I class
HG/T4109-2009 " anion function coating "
GB/T1741-2007 " paint film fungus resistance assay method "
The object of the invention is to design a kind of draft nucleocapsid structure emulsion (self-control) of breathing freely is main film forming substance, adds special draft nanometer pulvis, draft capsule and based on natural mineral tourmaline.Through superfine grinding, sol-gel method coating modification, ion-exchange is adulterated the nanometer pulvis be made with means such as activated ats, has negative ion burst size high, the effect of release far infrared, "dead" and antibacterial purifying air.This product after testing, has that negative ion burst size is large, antimycotic antiseptic power is strong, nontoxic, tasteless, and indoor air purifies, and effectively can promote the health of people.
In sum, the present invention effectively overcomes various shortcoming of the prior art and tool high industrial utilization.
Above-described embodiment is illustrative principle of the present invention and effect thereof only, but not for limiting the present invention.Any person skilled in the art scholar all without prejudice under spirit of the present invention and category, can modify above-described embodiment or changes.Therefore, such as have in art usually know the knowledgeable do not depart from complete under disclosed spirit and technological thought all equivalence modify or change, must be contained by claim of the present invention.
Claims (14)
1. a Herbal essence health paint, the raw material of described Herbal essence health paint comprises the following component with parts by weight:
The breathe freely raw material of emulsion of described draft nucleocapsid structure comprises core portion raw material and shell portion raw material, and the weight ratio of described core portion raw material and shell portion raw material is 1:0.2-0.4, and described core portion raw material comprises the following component with parts by weight:
Tensio-active agent 1-3 part;
Initiator 0.2-0.3 part;
Core portion soft monomer 10-20 part;
Core portion hard monomer 5-15 part;
Organo-siloxane monomer 3-5 part;
Essential oils of herbs 0.1-0.3 part;
Core portion function monomer 0.5-1.5 part;
Deionized water 40-45 part;
Described shell portion raw material comprises the following component with parts by weight:
Tensio-active agent 0.2-0.5 part;
Initiator 0.1-0.3 part;
Shell portion soft monomer 3-8 part;
Shell portion hard monomer 5-10 part;
Organo-siloxane monomer 1-2 part;
Shell portion function monomer 0.2-1.0 part;
Deionized water 5-10 part;
Described core portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate;
Described core portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid;
Described shell portion soft monomer is selected from one or more the combination in butyl acrylate, Isooctyl acrylate monomer, ethyl acrylate;
Described shell portion hard monomer is selected from one or more the combination in methyl methacrylate, vinylbenzene, methacrylic acid, vinylformic acid;
Described core portion function monomer is selected from the two or more combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, acrylamide;
Described shell portion function monomer is selected from the two or more combination in Propylene glycol monoacrylate, Hydroxyethyl acrylate, acrylamide.
2. a kind of Herbal essence health paint as claimed in claim 1, is characterized in that, described core portion raw material comprises the following component with parts by weight:
Tensio-active agent 1.5-2.5 part;
Initiator 0.2-0.3 part;
Core portion soft monomer 13-17 part;
Core portion hard monomer 10-14 part;
Organo-siloxane monomer 3.5-4.5 part;
Essential oils of herbs 0.1-0.3 part;
Core portion function monomer 0.8-1.2 part;
Deionized water 40-45 part;
Described shell portion raw material comprises the following component with parts by weight:
Tensio-active agent 0.3-0.4 part;
Initiator 0.1-0.2 part;
Shell portion soft monomer 3.5-6 part;
Shell portion hard monomer 8-10 part;
Organo-siloxane monomer 1-2 part;
Shell portion function monomer 0.2-1.0 part;
Deionized water 5.5-8.4 part.
3. a kind of Herbal essence health paint as claimed in claim 1, is characterized in that, described anionic sterilization pulvis is selected from nano-negative ion compound disinfectant.
4. a kind of Herbal essence health paint as claimed in claim 1, is characterized in that, described color stuffing powder starches one or more the combination be selected from titanium dioxide, calcium carbonate, kaolin powder, Sai Boya nanometer rubber powder.
5. a kind of Herbal essence health paint as claimed in claim 1, is characterized in that, described draft additive is selected from one or both the mixing in draft nanometer pulvis and essential oils of herbs capsule.
6. a kind of Herbal essence health paint as claimed in claim 1, it is characterized in that, described organo-siloxane monomer is selected from one or more the combination in vinyl silane triisopropoxide, γ-methylpropionyloxy propyl group three isopropoxy silane, eight vinyl cyclotetrasiloxanes, octamethylcyclotetrasiloxane.
7. a kind of Herbal essence health paint as claimed in claim 1, it is characterized in that, described essential oils of herbs is selected from one or more the combination in Herba Lysimachiae foenumgraeci quintessence oil, tea tree ethereal oil, crape myrtle essential oil, China pink essential oil, eucalyptus quintessence oil, pineapple essential oil, Root and stem of Cholla essential oil, aloe essential oil.
8. a kind of Herbal essence health paint as claimed in claim 1, is characterized in that, described initiator is selected from the one in ammonium persulphate, Potassium Persulphate or Sodium Persulfate.
9. a kind of Herbal essence health paint as claimed in claim 1, is characterized in that, described tensio-active agent is the mixture of sulfo-succinic acid alkyl ethoxylated ester sodium salt, side chain alcohol ether and the polyether thiourea hydrochlorate containing allyl group alkoxyl group.
10. a kind of Herbal essence health paint as claimed in any one of claims 1-9 wherein, it is characterized in that, described auxiliary agent is selected from one or more the combination in dispersion agent, wetting agent, defoamer, sterilant, mould inhibitor, flow agent, pH adjusting agent and compound film former.
11. a kind of Herbal essence health paint as claimed in claim 10, it is characterized in that, described auxiliary agent comprises following component by weight: dispersion agent 0.2-0.5 part, wetting agent 0.1-0.4 part, defoamer 0.2-0.5 part, sterilant 0.1-0.2 part, mould inhibitor 0.2-0.4 part, flow agent 0.5-1.0 part, pH adjusting agent 0.08-0.15 part, compound film former 0.5-1 part.
The preparation method of 12. a kind of Herbal essence health paint as claimed in claim 11, comprises the steps:
(1) the 26-30 part deionized water in described core portion raw material, 0.3-1 part tensio-active agent, 0.07-0.1 part initiator, 3-5 part core portion soft monomer, 1-2 part core portion hard monomer, 0.1-0.5 part core portion function monomer, 0.5-1 part organo-siloxane monomer are added reactor, be warming up to 80-87 DEG C of reaction under agitation, stable reaction 10min-15min forms seed crystal; Deionized water in remaining core portion raw material, tensio-active agent, initiator, core portion soft monomer, core portion hard monomer, core portion function monomer, essential oils of herbs, organo-siloxane monomer are made core portion pre-emulsion; Gained core portion pre-emulsion is added drop-wise in reactor; Drip off rear Inducing Graft Polymerization and be incubated 2-3 hour at 83-90 DEG C;
(2) described shell portion raw material is made shell portion pre-emulsion, gained shell portion pre-emulsion is dropped in the feed liquid of step 1 gained, the weight ratio of described core portion raw material and shell portion raw material is 1:0.2-0.4, drip off rear Inducing Graft Polymerization and be incubated 2-3 hour at 83-90 DEG C, be cooled to less than 40 DEG C again, then regulate pH to 7-8, discharging, filter draft nucleocapsid structure is breathed freely emulsion;
(3) after the defoamer of the deionized water in the feed composition of described Herbal essence health paint, dispersion agent, wetting agent, half weight being stirred, add color stuffing powder slurry and anionic sterilization pulvis under agitation, high speed dispersion, enter again on shredder and grind, when product particle fineness reaches 18-22 μm, stop grinding;
(4) the draft nucleocapsid structure adding draft additive, mould inhibitor, sterilant, pH adjusting agent, compound film former, flow agent, remaining defoamer and step 2 gained in step 3 gained material is breathed freely emulsion, stir, filter, packaging, obtains Herbal essence health paint.
The preparation method of 13. a kind of Herbal essence health paint as claimed in claim 12, is characterized in that, the dropping temperature of described step 1 center portion pre-emulsion is 80-87 DEG C, and time for adding is 2-3 hour.
The preparation method of 14. a kind of Herbal essence health paint as claimed in claim 12, is characterized in that, the dropping temperature of described step 2 mesochite portion pre-emulsion is 80-87 DEG C, and time for adding is 2-3 hour.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210378249.7A CN103709842B (en) | 2012-09-29 | 2012-09-29 | A kind of Herbal essence health paint and preparation method thereof |
Applications Claiming Priority (1)
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| CN108588877B (en) * | 2018-05-10 | 2020-11-20 | 浙江纺织服装职业技术学院 | Microcapsule composite cellulose nanofiber and preparation method thereof |
| CN115386262B (en) * | 2022-09-26 | 2023-05-12 | 杭州海维特化工科技有限公司 | Gravure ink applied to slow-release essence and anions of automotive interior decorative plastic film and preparation method thereof |
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