CN107936652A - Anti-fog haze low-carbon health coating - Google Patents
Anti-fog haze low-carbon health coating Download PDFInfo
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Abstract
The invention discloses a kind of anti-fog haze low-carbon health coating, it contains following components：The anti-fog haze material of pure water, pH adjusting agent, cellulose thickener, dispersion moisture agent, defoamer, super nano-antiradiation, nano-titanium dioxide, nano-far-infrared auxiliary agent, heavy calcium carbonate, 828 titanium dioxides, calcined kaolin, anti-static dust-proof agent, VOC-free emulsion or resin, defoamer, fungicide, nano silver antimicrobials and thickener.The formulation for coating material of the present invention is reasonable, it is innovative that a variety of material fusions with specific function such as graphene, nano-negative ion, nano-tourmaline, nano-titanium dioxide, nano-far-infrared auxiliary agent, antistatic dedusting agent are integral, not only there is the mould proof, dust-proof of general environmental protection coating material, anti-pollution, colorful decoration function, and realize the Diamond Search content technical barrier of product, there is anti-fog haze, persistently purification air, antibiotic and sterilizing, the release function such as far infrared and negative oxygen ion, beneficial to wide popularization and application.
Description
Technical field
The invention belongs to paint field, and in particular to a kind of anti-fog haze low-carbon health coating.
Background technology
Haze directly stimulates the respiratory tract of people, to itself there is the people of some respiratory disorders, cardiovascular and cerebrovascular disease, it is likely that
The function of cardiopulmonary can be reduced, causes chronic bronchitis, asthma, expiratory dyspnea etc..Pellet (PM10) in haze,
Fine particle (PM2.5) damages body health of people.Can also and PM2.5 is in addition to can be in pulmonary deposition, among it
Adhere to many heavy metals, these heavy metals are all harmful substance in itself, and contain carcinogen and carcinogenic promoting agent, into human body after one
Determine the generation that can cause lung cancer for degree.Lung cancer cure rate is relatively very low.For pregnant woman, be particularly pregnant first trimester
Pregnant woman, haze are likely to cause that development of fetus is slow, the infant of low-birth weight.Meanwhile Zhong Nanshan academician proposes treating indoor air pollution
It is more important than outdoor air pollution.The meaning between the lines is that we should more pay attention to the improvement of room air pollution because we 80%
Time, so current, no matter outdoor, indoor haze air treating was very urgent, extremely urgent indoors.
Domestic multifunctional coating field needs continuous technological innovation, has had many producers, school, research institute being directed to
The new building coating removed haze and prevent haze is researched and developed, wherein patent document CN201610741103.2 is mainly urged with light
Change material and add conventional negative ion powder, its emphasis direction is to be used for external wall negative ion paint, has been selected in formula with alcohol ester
Coalescents and conventional non-VOC-free emulsion and resin based on 12, secondary environmental pollution can be caused for dope for inner wall of architecture.
Wherein patent document CN201610728560.8 and CN201610741103.2 is that same company applies, is equally to be used for exterior wall
The colorful reflective heat-insulation paint of water-water, principle play the same tune on different musical instruments with CN201610741103.2, and more alcohol esters have been selected in formula
Coalescents and conventional non-VOC-free emulsion and resin based on 12, can more cause two secondary environments dirty for dope for inner wall of architecture.
Another related patents file CN201610134709.X then discloses a kind of heat preservation putty priming paint for adding negative ion powder, as anion
Priming paint is kept the temperature, it is difficult to effectively solve the problems, such as that the higher color of concentration of existing negative ion paint is poorer, unsightly.
Research through this area scientific research personnel finds, at present the anion burst size of the coating of country major vendor production with
Radiation value is directly proportional as follows：
Meanwhile current negative ion paint, anti-fog haze coating, anion in the patented products such as haze coating except being used for except haze
Core material is exactly anion material, and according to table above, product anion release concentration is higher, and radiation value is higher, difficult
To meet high concentration, this radiationless requirement at the same time, or at all be formulated design at the beginning of just do not consider and voluntarily monitor product
The security of radiation value, there are the security risk of radiation injury of the radioactive substance ray to human body.
The content of the invention
For above-mentioned deficiency, present invention aims at, there is provided it is a kind of to go to zero the anti-of VOC content for inner wall of building
Mould, dust-proof, anti-pollution, colorful decoration function, and there is anti-fog haze, persistently purify air, antibiotic and sterilizing, release far infrared and bear
The anti-fog haze low-carbon health coating of oxonium ion.
To achieve the above object, technical solution provided by the present invention is：A kind of anti-fog haze low-carbon health coating, its group
Divide and its percentage by weight is as follows：
Pure water 10.0~35%；
PH adjusting agent 0.1~0.2%；
Cellulose thickener 0.2~0.5%；
Dispersion moisture agent 0.3~0.6%；
Defoamer 0.1~0.5%；
The super anti-fog haze material 1.0~3.0% of nano-antiradiation；
Nano-titanium dioxide 1.0~3.0%；
Nano-far-infrared auxiliary agent 1.0~3.0%；
Heavy calcium carbonate 8.0~25%；
828 titanium dioxides 8.0~20%；
Calcined kaolin 5.0~8%；
Anti-static dust-proof agent 0.5~3%；
VOC-free emulsion or resin 20.0~35%；
Defoamer 0.1~0.2%；
Fungicide 0.1~0.2%；
Nano silver antimicrobials 1.0~2.0%；
Thickener 0.2~1.0%；
The component and its percentage by weight of the wherein described anti-fog haze material of super nano-antiradiation are as follows：Graphene 5~30%, receives
Rice anion 5~20%, nano-tourmaline 10~50%.The graphene is current most thin, maximum intensity, electrical and thermal conductivity performance
A kind of most strong novel nano-material, has high intensity and pliability, at room temperature best electrical and thermal conductivity, than traditional
Carbon conductive filler（Carbon black, graphite, carbon nanotubes, carbon fiber etc.）, can be with more excellent electric conductivity and mechanical performance
Various atoms and molecule are adsorbed and be desorbed, there is super-hydrophobicity and super-oleophilic, its electron mobility can reach 2 × 105cm2/
140 times of electron mobility in Vs, about silicon, 20 times of GaAs, temperature stability is high, and electrical conductivity is up to 108Ω/ m,
Surface resistance is about 31 Ω/sq（310Ω/m2）, it is lower than copper or silver, it is conductive best material at room temperature.Specific surface area is big
（2630m2/g）, thermal conductivity（It is 5000Wm at room temperature-1·K-1）It is 36 times of silicon, 20 times of GaAs, be copper（At room temperature
401W·m·K）More than ten times.The nano negative ion material, 10000-50000/cubes lis of its negative oxygen ion burst size
Rice, persistently has very strong purification air, antibiotic and sterilizing, smoke abatement and dust control, anti-electromagnetic radiation, settles PM2.5 particles in air, with
And superpower far-infrared transmitting function, feature are natural, tasteless, nontoxic, radiation values in safe range.The nano-tourmaline
It is the powder or equal volume suspension liquid that a kind of unit is Nano grade, nano-tourmaline has than micron-size tourmaline more
Forever there is 0.06 milliampere of micro-current on high anion yield and far infrared transmissivity, surface, absorb and retain thin in sedimentation air
The function of small particle PM2.5 and PM10, there is piezoelectricity and pyroelectricity.
The anti-static dust-proof agent is macromolecule permanent anti-static agent, can eliminate coating surface electrostatic, and air is absorbed and retain in sedimentation
The PM2.5 and dust particale thing of middle floating.
The nano-titanium dioxide, belongs to high-activity nano titanium dioxide, has less than a 20 nanometers particle diameters, consolidating in solution
Body material particle size is distributed with 20 rans.
As a modification of the present invention, the far-infrared material is far-infrared composite ceramics powder, under room temperature wavelength 2~
Infrared emittance in 18 μ ms is up to more than 92%.The mesh number of the powdered whiting is 800~1500 mesh；Calcine kaolinite
Soil is the superfine powder by processed 3000~5000 mesh of high-temperature calcination.Titanium dioxide is rutile type titanium white, described to disappear
Infusion is polyether-modified silicon defoaming agent.The purifying formaldehyde functional latex or resin are phenylpropyl alcohol, purified petroleum benzin, silicon benzene, fluorine carbon, acetic acid second
One or more complexs in enester/ethylene copolymer emulsion/resin.The cellulose thickener is hydroxyethyl cellulose；
Dispersion moisture agent is alkyl polyoxyethylene ether and the compound of Sodium Polyacrylate.The pH adjusting agent is 2- amino-2-methyls -1-
Propyl alcohol.Fungicide is dense for -3 ketone of 5- chloro-2-methyl -4- isothiazolines and -4 isothiazoline -3- ketone of 2- methyl and formaldehyde composition
Contracting liquid.The Nano silver auxiliary agent occurs electronics to carry the cation of positive charge, through chemical reaction and shifts to be formed, usually with water-soluble
Liquid form exists, its solution water white transparency, without any solid particle
Beneficial effects of the present invention are：Formulation for coating material provided by the invention is reasonable, fully with the superconducting of graphene, anti-spoke
Penetrate, is antistatic, is wear-resistant, outside the excellent properties such as anticorrosion, while comprehensively utilizing the work(of nano-negative ion and nano-tourmaline
Can characteristic, persistently release beneficial to negative oxygen ion and far infrared and micro-current, play smoke abatement and dust control, absorb and retain floated in sedimentation air it is micro-
The anti-fog haze performance such as fine particle PM2.5, PM10；Also there is nano-titanium dioxide（Photocatalyst）Durable antibiotic disinfection, purification
The indoor decoration pollution such as air peculiar smell, last decomposition formaldehyde, toluene, ammonia, TVOC.After coating application drying, radiation value is in 0.30 μ
In the range of Sv/hr safety values, substitute at present it is all by national standard production VOC contents 1-120g/L interior wall coating with it is multi-functional
Coating, and diatom ooze, wallpaper wall paper, import coating etc., realize the electrostatic in quick elimination and neutralization metope and air（Positive electricity
Lotus）With lasting releasing negative oxygen ion（Negative electrical charge）Performance, while can continuing purge formaldehyde in air, toluene, TVOC, ammonia, nitrogen sulphur
The multi-functional dope for inner wall of architecture such as oxide, is truly realized green ecological and environment protection health, while allowing child away from haze
Away from finishing pollution, good health and a long life new environment is founded for each family.Zhong Nanshan academician proposes that treating indoor air pollution compares room
Outer air pollution is more important.The meaning between the lines is that we should more pay attention to the improvement of room air pollution, because civilized most times
Indoors, should not be simply only pay attention to outdoor air pollution.The anti-fog haze low-carbon health coating of the present invention can with 24 it is small when continue not
The beneficial negative oxygen ion of disconnected release high concentration and quick removing formaldehyde pollution so that building body is just as a natural super air
Clarifier, can absorb and retain particulates thing PM2.5 and PM10 in expansion chamber, and mist is administered while resisting haze comprehensively
Haze, improves indoor and outdoor air quality, realizes that building wall accomplishes green ecological and environment protection health, being capable of low-carbon energy-saving, maintenance life
Life, good health and a long life new environment is founded for our each living space.The anti-fog haze low-carbon health coating of the present invention meets Zhong Nanshan institute
Scholar's speech content and the market demand, more meet the main trend in environmental and ecological epoch, and easily prepared, should beneficial to being widely popularized
With.
With reference to embodiment, the invention will be further described.
Embodiment
Embodiment 1：A kind of anti-fog haze low-carbon health coating is present embodiments provided, its component and its weight percent is such as
Under：Pure water 26%, pH adjusting agent 0.1%, cellulose thickener 0.3%, dispersion moisture agent 0.3%, defoamer 0.1%, super nanometer
The anti-fog haze material 3% of radiation protection, nano-titanium dioxide 1%, nano-far-infrared auxiliary agent 1%, heavy calcium carbonate 24.7%, 828 titanium whites
Powder 8%, calcined kaolin 8%, anti-static dust-proof agent 1%, VOC-free emulsion or resin 25%, defoamer 0.1%, fungicide 0.1%, receives
Rice silver antibacterial agent 1%, thickener 0.3%.The component and its percentage by weight of the wherein described anti-fog haze material of super nano-antiradiation
It is as follows：Graphene 5~30%, is preferably 25%；Nano-negative ion 5~20%, is preferably 15%；Nano-tourmaline 10~50%, preferably
For 40%.
In the present embodiment, preferably, the pure water refers to H free from foreign meter2O, is pure, clean, is not contained miscellaneous
Matter or the water of bacterium, such as organic pollution, inorganic salts, any additive and all kinds of impurity, especially heavy metal substance.It is to accord with
The water for closing standards for drinking water quality is raw water.By electric dialyzator method, ion-exchanger method, hyperfiltration, the way of distillation and
Other appropriate processing methods, which are made, to be formed, and is sealed in container, and is free of any additive, and water white transparency is capable of direct drinking.
In the present embodiment, preferably, the nano-titanium dioxide is high-activity nano titanium dioxide, it have 20 nanometers with
Lower particle diameter, the solid matter granularity in solution are distributed with 20 rans.Touched with 100~200 nanometers conventional of photocatalytic titanium oxide
Matchmaker is irradiated by ultraviolet occurs that catalysis is different, and the product is because having strong adsorptivity and nano-particle characteristic
Potential transfer and the metathesis reaction for producing high-energy, it is anti-can to produce catalysis under dim light and fluorescent lamp and without ultraviolet light conditions
Should（Redox reaction）, releasing negative oxygen ion, produces the hydrogen-oxygen free radical with strong oxdiative power, can significantly, constantly
Ground eliminates the pernicious gases such as formaldehyde, benzene, ammonia and total volatile organism, while plays deodorization, antibacterial, mould proof, purification air
Effect.It is preferred that Liuzhou Ruo Si new materials Science and Technology Ltd. and Shenzhen Jing Cai new materials Science and Technology Ltd. product.
Preferably, the far-infrared material is ultra-fine far-infrared composite ceramics powder, it is a kind of white powder, through special nanometer
The compound far-infrared health care function material of novel nano that complex technique refines.Detected through China National Measuring Science Research Inst., often
Infrared emittance under temperature in 2~18 μ m of wavelength is up to 92%.With farsighted red with human body radiation absorption respective wavelength
External radiation rate, is good body-care far-infrared radiation material, and there is uvioresistant, sterilization to eliminate peculiar smell, prevent and cure diseases
It etc. function, can effectively improve microcirculation in human body, promote normal microcirculation blood flow to increase by 2~3 times, improve tissue oxygen supply, change
Kind metabolism, strengthen immunity.It is preferred that Nanjing Haitai nanometer and the positive nano-far-infrared auxiliary agent in Shanghai Shanghai.
The preferred phenylpropyl alcohol of the purifying formaldehyde functional latex or resin, purified petroleum benzin, silicon benzene, fluorine carbon,（VAE）Vinylacetate/second
One or more complexs of alkene copolymer lotion/resin, have Formaldehyde decomposition purification function, and go to zero VOC content, without into
Film auxiliary agent, antifreezing agent can form good paint film and freeze thawing resistance stability, preferably BASF 7048G, the 8162 of ten thousand China's chemistry
Etc. such product..
In the present embodiment, the preferred hydroxyethyl cellulose of cellulose thickener (HEC), thickener is preferably that acrylic acid gathers
Compound；Dispersion moisture agent is preferably the compound of alkyl polyoxyethylene ether and Sodium Polyacrylate；Defoamer is preferably polyether-modified
Silicon defoaming agent；PH adjusting agent is preferably 2-amino-2-methyl-1-propanol；Fungicide is preferably 5- chloro-2-methyl -4- isothiazole
The concentrate of the ketone of quinoline -3 and -4 isothiazoline -3- ketone of 2- methyl and formaldehyde composition；The powder of the preferred 800-1500 mesh of powdered whiting
Body, have chemical purity is high, inertia is big, be not easy to chemically react, heat endurance is good, whiteness is high, oil absorbency is low, index of refraction is low, no
Containing the crystallization water, the advantages that low wearing valve of hardness is small, nontoxic, tasteless, odorless, good dispersion；Calcined kaolin is preferably through high temperature
The superfine powder for 3000~5000 mesh that calcination processing is crossed, has the characteristics that whiteness is high, purity is high, easily scattered；Titanium dioxide is preferred
For rutile type titanium white, main component is titanium dioxide；Nano silver antimicrobials are preferably the cation for carrying positive charge, through changing
Learn reaction generation electronics to shift to be formed, usually exist as an aqueous solution, its solution water white transparency, without any solid particle；Receive
The silver-colored auxiliary agent of rice can also be called nano silver antimicrobials.It is preferred that all raw material must be Diamond Search content.
The present embodiment product have detection negative oxygen ion burst size up to 3300/cubic centimetre more than；Far infrared transmission
Rate is up to more than 0.88；Anti-fog haze is efficient up to more than 95%；PM2.5 efficiency is settled up to more than 96.5%；Antistatic coefficient electricity
Resistance value is up to below 108 Ω cm；The micro- electricity in surface is up to more than 0.6 milliampere；Purifying formaldehyde efficiency is up to 95.7%；Toluene purifies
Efficiency is up to 98.1%；TVOC purification efficiencies are up to 98.3%；Nox purification rate is up to 98%；Antimicrobial efficiency is up to 99.99%；
Mould proof grade is at 0 grade；Product is radiated within 0.15 μ Sv/hr safety values.
Embodiment 2, present embodiments provides a kind of anti-fog haze low-carbon health coating, its is substantially the same manner as Example 1, difference
It is that its component and its percentage by weight are as follows：Pure water 20%, pH adjusting agent 0.1%, cellulose thickener 0.2%, disperses profit
Humectant 0.3%, defoamer 0.1%, the super anti-fog haze material 6% of nano-antiradiation, nano-titanium dioxide 2%, nano-far-infrared auxiliary agent
2%, heavy calcium carbonate 16.8%, 828 titanium dioxides 10%, calcined kaolin 10%, anti-static dust-proof agent 2%, VOC-free emulsion or tree
Fat 28%, defoamer 0.1%, fungicide 0.1%, nano silver antimicrobials 2%, thickener 0.3%.There is the present embodiment product detection to bear
Oxonium ion burst size up to 4500/cubic centimetre more than；Far infrared transmissivity is up to more than 0.90；Anti-fog haze is efficient to be reached
More than 96%；PM2.5 efficiency is settled up to more than 97.5%；Antistatic coefficient resistance value is up to below 102 Ω cm；Surface is micro-
Electricity is up to more than 0.6 milliampere；Purifying formaldehyde efficiency is up to 98.7%；Toluene purification efficiency is up to 99.1%；TVOC purification efficiencies can
Up to 98.6%；Nox purification rate is up to 99.1%；Antimicrobial efficiency is up to 99.99%；Mould proof grade is at 0 grade；Product radiation exists
Within 0.22 μ Sv/hr safety values.
Embodiment 3, present embodiments provides a kind of anti-fog haze low-carbon health coating, its is substantially the same manner as Example 1, difference
It is that its component and its percentage by weight are as follows：Pure water 13%, pH adjusting agent 0.1%, cellulose thickener 0.2%, disperses profit
Humectant 0.3%, defoamer 0.1%, the super anti-fog haze material 10% of nano-antiradiation, nano-titanium dioxide 3%, nano-far-infrared auxiliary agent
3%, heavy calcium carbonate 14.8%, 828 titanium dioxides 12%, calcined kaolin 6.5%, anti-static dust-proof agent 3%, VOC-free emulsion or tree
Fat 32%, defoamer 0.1%, fungicide 0.1%, nano silver antimicrobials 1.5%, thickener 0.3%.The present embodiment product has detection
Negative oxygen ion burst size up to 5500/cubic centimetre more than；Far infrared transmissivity is up to more than 0.92；Anti-fog haze is efficient to be reached
More than 98%；PM2.5 efficiency is settled up to more than 98.5%；Antistatic coefficient resistance value is up to below 85 Ω cm；The micro- electricity in surface
Up to more than 0.6 milliampere；Purifying formaldehyde efficiency is up to 98.9%；Toluene purification efficiency is up to 99.5 %；TVOC purification efficiencies are reachable
98.8%；Nox purification rate is up to 99.5%；Antimicrobial efficiency is up to 99.99%；Mould proof grade is at 0 grade；Product is radiated 0.28
Within μ Sv/hr safety values.
Embodiment 4, present embodiments provides a kind of anti-fog haze low-carbon health coating, its is substantially the same manner as Example 1, difference
It is that its component and its percentage by weight are as follows：Pure water 35%, pH adjusting agent 0.2%, cellulose thickener 0.5%, disperses profit
Humectant 0.6%, defoamer 0.5%, the super anti-fog haze material 3.3% of nano-antiradiation, nano-titanium dioxide 2.5%, nano-far-infrared
Auxiliary agent 1.5%, heavy calcium carbonate 8%, 828 titanium dioxides 20%, calcined kaolin 5%, anti-static dust-proof agent 0.5%, VOC-free emulsion
Or resin 20%, defoamer 0.2%, fungicide 0.2%, nano silver antimicrobials 1%, thickener 1%.
Embodiment 5, present embodiments provides a kind of anti-fog haze low-carbon health coating, its is substantially the same manner as Example 1, difference
It is that its component and its percentage by weight are as follows：Pure water 10%, pH adjusting agent 0.2%, cellulose thickener 0.4%, disperses profit
Humectant 0.4%, defoamer 0.3%, the super anti-fog haze material 7.8% of nano-antiradiation, nano-titanium dioxide 1.3%, nano-far-infrared
Auxiliary agent 2%, heavy calcium carbonate 25%, 828 titanium dioxides 8%, calcined kaolin 6%, anti-static dust-proof agent 2%, VOC-free emulsion or tree
Fat 35%, defoamer 0.2%, fungicide 0.2%, nano silver antimicrobials 1%, thickener 0.2%.
Above-described embodiment is only the preferable embodiment of the present invention, and the present invention cannot enumerate out whole embodiment party
Formula, all technical solutions using one of above-described embodiment, or the equivalent variations done according to above-described embodiment, are protected in the present invention
In the range of shield.
Arranged with reference to above-mentioned case, formulation for coating material of the invention is reasonable, innovative that graphene, nano-negative ion, nanometer is electric
A variety of material fusion one with specific function such as stone, nano-titanium dioxide, nano-far-infrared auxiliary agent, antistatic dedusting agent,
Not only there is the mould proof, dust-proof of general environmental protection coating material, anti-pollution, colorful decoration function, and realize the Diamond Search content of product
Technical barrier, product persistently release beneficial negative oxygen ion and far infrared and micro-current, play smoke abatement and dust control, absorb and retain sedimentation PM2.5,
The anti-fog haze performance such as PM10；Also there is durable antibiotic disinfection, purification air, last decomposition formaldehyde, toluene, ammonia, TVOC etc. interior
Finishing pollution performance.Significantly after coating drying, radiation value substitutes current in the range of 0.30 μ Sv/hr safety values
It is all by national standard production VOC contents 1-120g/L interior wall coating and multifunctional coating, and diatom ooze, wallpaper wall paper,
Import coating etc., realizes the electrostatic in quick elimination and neutralization metope and air（Positive charge）With lasting releasing negative oxygen ion（It is negative
Electric charge）Performance, while the multi-functional inner wall of building such as energy continuing purge formaldehyde in air, toluene, TVOC, ammonia, nitrogen oxysulfide
Coating, is truly realized green ecological and environment protection health, away from finishing pollution while allowing child away from haze, is formed for each family
Make good health and a long life new environment.If our country ownership external walls and interior wall are all promoted and using this products, in wall surface coating
The anti-fog haze material of super nano-antiradiation can be with 24 beneficial negative oxygen ions that high concentration is constantly discharged when small and quick clear
Except formaldehyde pollution, building body can absorb and retain particulates in expansion chamber just as a natural super air purifier
Thing PM2.5 and PM10, administer haze while resisting haze comprehensively, improve indoor and outdoor air quality, realize all building walls
Accomplish green ecological and environment protection health, can low-carbon energy-saving, maintenance life, more meet the big of environmental and ecological epoch multifunctional coating
Trend.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party
Formula make a change and modification.Therefore, the invention is not limited in embodiment disclosed and described above, to the present invention's
Some modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, although used in this specification
Some specific terms, but these terms are merely for convenience of description, do not limit the present invention in any way.Such as the present invention
Described in above-described embodiment, using other coating obtained from same or similarity method and component, model is protected in the present invention
In enclosing.
Claims (10)
1. a kind of anti-fog haze low-carbon health coating, it is characterised in that its component and its percentage by weight is as follows：
The component and its percentage by weight of the wherein described anti-fog haze material of super nano-antiradiation are as follows：Graphene 5~30%, receives
Rice anion 5~20%, nano-tourmaline 10~50%.
2. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the nano-titanium dioxide belongs to high
Active nano titanic oxide, has the solid matter of less than 20 nanometers particle diameters.
3. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the far-infrared material is far infrared
Composite ceramic, the infrared emittance under room temperature in 2~18 μ m of wavelength are up to more than 92%.
4. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the mesh number of the powdered whiting is
800~1500 mesh；Calcined kaolin is the superfine powder by processed 3000~5000 mesh of high-temperature calcination.
5. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that titanium dioxide is rutile titanium dioxide
Powder, the defoamer are polyether-modified silicon defoaming agent.
6. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the purifying formaldehyde functional latex or
Resin is phenylpropyl alcohol, one or more complexs in purified petroleum benzin, silicon benzene, fluorine carbon, vinyl acetate/ethylene/copolymer emulsion/resin.
7. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the cellulose thickener is hydroxyl second
Base cellulose；Dispersion moisture agent is alkyl polyoxyethylene ether and the compound of Sodium Polyacrylate.
8. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the pH adjusting agent for 2- amino-
2- methyl isophthalic acids-propyl alcohol.
9. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the fungicide is the chloro- 2- first of 5-
The concentrate of -3 ketone of base -4- isothiazolines and -4 isothiazoline -3- ketone of 2- methyl and formaldehyde composition.
10. anti-fog haze low-carbon health coating according to claim 1, it is characterised in that the Nano silver auxiliary agent is carrying
The cation of positive charge, occurs electronics through chemical reaction and shifts to be formed, usually exist as an aqueous solution, its solution is colourless
It is bright, without any solid particle.
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| CN201710328584.9A CN107936652A (en) | 2017-05-11 | 2017-05-11 | Anti-fog haze low-carbon health coating |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893019A (en) * | 2018-06-05 | 2018-11-27 | 广东佳士利纳米新材料有限公司 | One kind removing aldehyde antibiotic emulsion paint |
| CN109364379A (en) * | 2018-08-03 | 2019-02-22 | 广东丰森第五能源科技有限公司 | A kind of nanometer new material radiating resonance wave frequency function with far infrared energy-saving |
| CN109654622A (en) * | 2018-12-05 | 2019-04-19 | 程友明 | A kind of negative ion powder formula and smoke-removing air purification device rich in graphene |
| CN112126331A (en) * | 2020-09-16 | 2020-12-25 | 江苏晨光涂料有限公司 | Negative oxygen ion paint |
| CN112409872A (en) * | 2020-12-03 | 2021-02-26 | 鲁嘉涂料（福建）有限公司 | Environment-friendly water-based wood paint and preparation method thereof |
| CN113527973A (en) * | 2021-08-16 | 2021-10-22 | 魏宇彤 | Method for preparing exterior wall latex paint capable of releasing negative oxygen ion infrared rays |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104497685A (en) * | 2014-11-27 | 2015-04-08 | 浙江大学自贡创新中心 | Negative ion-containing antibacterial haze-cleaning paint |
| CN105838128A (en) * | 2016-03-10 | 2016-08-10 | 赵昶然 | Brushing process for oxygen-source anti-haze high-concentration negative-ion healthy heat-insulating indoor and outdoor paint and product |
| CN106348649A (en) * | 2016-08-26 | 2017-01-25 | 上海绿特丹保温工程有限公司 | Photocatalytic anti-fog sand-wall shape negative ion coating |
-
2017
- 2017-05-11 CN CN201710328584.9A patent/CN107936652A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104497685A (en) * | 2014-11-27 | 2015-04-08 | 浙江大学自贡创新中心 | Negative ion-containing antibacterial haze-cleaning paint |
| CN105838128A (en) * | 2016-03-10 | 2016-08-10 | 赵昶然 | Brushing process for oxygen-source anti-haze high-concentration negative-ion healthy heat-insulating indoor and outdoor paint and product |
| CN106348649A (en) * | 2016-08-26 | 2017-01-25 | 上海绿特丹保温工程有限公司 | Photocatalytic anti-fog sand-wall shape negative ion coating |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108893019A (en) * | 2018-06-05 | 2018-11-27 | 广东佳士利纳米新材料有限公司 | One kind removing aldehyde antibiotic emulsion paint |
| CN109364379A (en) * | 2018-08-03 | 2019-02-22 | 广东丰森第五能源科技有限公司 | A kind of nanometer new material radiating resonance wave frequency function with far infrared energy-saving |
| CN109654622A (en) * | 2018-12-05 | 2019-04-19 | 程友明 | A kind of negative ion powder formula and smoke-removing air purification device rich in graphene |
| CN112126331A (en) * | 2020-09-16 | 2020-12-25 | 江苏晨光涂料有限公司 | Negative oxygen ion paint |
| CN112126331B (en) * | 2020-09-16 | 2021-08-10 | 江苏晨光涂料有限公司 | Negative oxygen ion paint |
| CN112409872A (en) * | 2020-12-03 | 2021-02-26 | 鲁嘉涂料（福建）有限公司 | Environment-friendly water-based wood paint and preparation method thereof |
| CN113527973A (en) * | 2021-08-16 | 2021-10-22 | 魏宇彤 | Method for preparing exterior wall latex paint capable of releasing negative oxygen ion infrared rays |
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