CN104497685A - Negative ion-containing antibacterial haze-cleaning paint - Google Patents
Negative ion-containing antibacterial haze-cleaning paint Download PDFInfo
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- CN104497685A CN104497685A CN201410699463.1A CN201410699463A CN104497685A CN 104497685 A CN104497685 A CN 104497685A CN 201410699463 A CN201410699463 A CN 201410699463A CN 104497685 A CN104497685 A CN 104497685A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
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- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention relates to the technical field of functional building paint and provides negative ion-containing antibacterial haze-cleaning paint. Through raw material grinding and mixing, the negative ion-containing antibacterial haze-cleaning paint is prepared from 15-40 parts by weight of a film-forming emulsion, 8-30 parts by weight of a negative ion additive, 0.5-20 parts by weight of a silver ion additive, 5-35 parts by weight of a pigment and a filler, 5-15 parts by weight of an assistant and 20-50 parts by weight of deionized water. Through use of the negative ion additive, the coating film has a negative ion continuous-release function and can purify air so that a PM 2.5 concentration is reduced. The silver ion additive has lasting antibacterial and mildew-resistant functions. The preparation method is simple and convenient and is conducive to reduction of an industrial production cost. The negative ion-containing antibacterial haze-cleaning paint has low VOC (volatile organic compound) content, can greatly reduce environmental pollution, is environmentally friendly, is especially suitable for occasions such as residential buildings, commercial buildings and common buildings and has a wide application prospect.
Description
Technical field
The invention belongs to Functional Architectural Coatings in China technical field, particularly the clean haze coating of a kind of negative ion antibiotic.
Background technology
The physical and mental health of the PM2.5 that topsoil exceeds standard especially continuously serious threat resident.PM2.5 mainly damages respiratory system and cardiovascular systems, comprise respiratory tract irriate, cough, expiratory dyspnea, reduction pulmonary function, exacerbate asthma, cause chronic bronchitis, irregular pulse, non-lethal heart trouble, heart and lung diseases patient too early dead.Old man, child and heart and lung diseases patient are the sensitive groups that PM2.5 pollutes.Weather scientist and medical expert think, the harm of the haze weather caused by fine particle to HUMAN HEALTH is even larger than sandstorm.The particulate matter that particle diameter is more than 10 microns, outside the nose that can be blocked in people; The particulate matter of particle diameter between 2.5 microns to 10 microns, can enter the upper respiratory tract, but part excretes by sputum etc., also can be stopped by the fine hair of nasal cavity in addition, relatively little to human health damage; And the fine particle of particle diameter below 2.5 microns, 1/20 size of diameter deficiency human tau hair, is not easily stopped.Directly can enter segmental bronchus after being inhaled into human body, the gaseous interchange of interference lung, causes the disease comprising the aspects such as asthma, bronchitis and cardiovascular diseases.
How effectively to reduce the target that PM2.5 has become whole society's active pursuit.At present, market there is the products such as the mouth mask that can stop PM2.5, air filter clearing machine, negative ion air cleaner.Wherein negative ion air cleaner utilizes the negative ion of high density and PM2.5 effect effectively to remove PM2.5, and effect obtains the accreditation of numerous feeler mechanism and R&D institution.
The research application of coating capable of releasing negative ion is less.Publication number is that the Chinese invention patent application of CN 201110374894.7 discloses a kind of negative ion paint and preparation method thereof, comprises the acrylic resin of 20 ~ 30 weight parts, the titanium dioxide of 10 ~ 15 weight parts, the calcium carbonate of 15 ~ 20 weight parts, the composite negative ion material of 1 ~ 4 weight part, the zinc oxide of 1 ~ 3 weight part, the talcum powder of 7 ~ 11 weight parts, the ethylene glycol of 1 ~ 2 weight part, the tripoly phosphate sodium STPP of 6 ~ 1 weight parts, the water of 21 ~ 25 weight parts, the auxiliary agent of 0.3 ~ 0.7 weight part; Wherein composite negative ion material is the mixture of a certain proportion of electric shock nano-tourmaline and nano-tourmaline.But the negative aeroion amount of inducing of this technical scheme is lower, air purification effect is general and without antibacterial effect.In addition, publication number is that the Chinese invention patent application of CN03129256.9 also discloses a kind of antibacterial negative ion coating, its know-why mainly adopts the anion powder of 0.01 ~ 1 weight part and the inorganic nano silver-series antibacterial agent of 0.01 ~ 1 weight part, and anion powder is wherein the grinding powder of tourmalinite and strange ice stone mixed ore.But the negative aeroion amount of inducing of this technical scheme is lower, air purification effect is general.
Summary of the invention
The technical problem to be solved in the present invention is, overcomes deficiency of the prior art, provides a kind of negative ion antibiotic clean haze coating.The present invention, by introducing the composition such as anionic additive and silver ions additive in filming emulsion, reaches the object of antibacterial and clean haze.
For technical solution problem, solution of the present invention is:
There is provided a kind of negative ion antibiotic clean haze coating, be by the raw material of following weight part through grinding, mix:
Described filming emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion, epoxy resin latex;
Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000 ~ 50000cm
-3;
Described silver ions additive is the silver ion complex aqueous solution of 50 ~ 1000ppm;
Described color stuffing is one or more in titanium dioxide, zinc sulfide white, kaolin, diatomite, calcium carbonate, pure aluminium silicate, mica or talcum powder;
Described auxiliary agent is one or more in film coalescence aid, dispersion agent, wetting agent, defoamer, thickening material, frostproofer or pH adjusting agent.
Prepare the method for the clean haze coating of negative ion antibiotic of the present invention, comprise the following steps:
(1) grind
Deionized water, anionic additive, color stuffing and part of auxiliary are added in shredder, under the speed of 1000r/min ~ 3000r/min, grind 20min ~ 60min, obtain slurry;
(2) dispersed with stirring
The slurry that step (1) obtains is transferred in dispersion machine, the auxiliary agent of filming emulsion, silver ions additive and remainder is added in slurry, dispersed with stirring 15min ~ 45min under the speed of 500r/min ~ 2000r/min, through 80 ~ 100 object screen filtrations, obtain the clean haze coating of negative ion antibiotic;
The parts by weight of described each raw material are as described below:
Described auxiliary agent is one or more in film coalescence aid, dispersion agent, wetting agent, defoamer, thickening material, frostproofer or pH adjusting agent; The auxiliary agent of the remainder described in step (2) refers to defoamer.
In the present invention, according to the color needs of the clean haze coating of negative ion antibiotic, certain colour developing pigment (color stuffing) can be added.
Filming emulsion, it is mainly as the base material of coating, and have vital role to the weathering resistance, mechanical property etc. of coating, described filming emulsion all can adopt commercially available prod.
Described anionic additive has the function of sustained release negative ion, especially reduces on purifying air the impact that small particle size suspended substance (PM2.5) has particularly important.The present invention uses enough electric shock nano-tourmalines to be anionic additive, makes coating can discharge a large amount of negative ion amounts, extends negative ion diffusion concentration and diffusion length, makes small particle size suspended substance electrostatic precipitation.
Described silver ion complex is by being played antibacterial and antimildew function by the Polymer adsorption in filming emulsion and desorption, be different from conventional silver salt antimicrobial agent and discharge silver ions by ionization equilibrium, therefore only need micro silver ion composition can have long-term antibacterial and mouldproof effect.
In described auxiliary agent, film coalescence aid specifically can select 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, dispersion agent specifically can select polycarboxylate sodium's type dispersion agent, wetting agent can specifically select Soxylat A 25-7 wetting agent, and defoamer specifically can select methyl-silicone oil, and thickening material specifically can select Natvosol type thickening material, frostproofer specifically can select propylene glycol, and pH adjusting agent specifically can select 2-amino-2-methyl-1-propanol.
Compared with prior art, tool of the present invention has the following advantages:
The composition such as anionic additive and silver ions additive introduced by the clean haze coating of negative ion antibiotic of the present invention in filming emulsion, makes film forming matter have sustained release anion function by anionic additive, thus purifies air and especially can reduce PM2.5 concentration.Meanwhile, silver ions additive possesses lasting antibacterial and antimildew function.And preparation method of the present invention is simple, convenient, be conducive to reducing industrial production cost.In addition, VOC (i.e. volatile organic compounds) content of negative ion antibiotic of the present invention clean haze coating is lower, significantly can reduce environmental pollution, environmental friendliness.
The preparation method of the clean haze coating of negative ion antibiotic of the present invention, raw material is ground and can obtain after dispersed with stirring the clean haze coating of negative ion antibiotic of the present invention, its preparation technology is simple, easy to implement, easy and simple to handle, be conducive to industrialization scale operation, reduce industrial production cost, there is good economic benefit.
Negative ion antibiotic of the present invention clean haze coating has the clean haze effect of good antibacterial effect, is specially adapted to the occasions such as civil construction, commercial building, public building, has broad application prospects.
Embodiment
Below in conjunction with case study on implementation, the present invention is further described." part " in the following example all refers to weight part.
Embodiment 1
Deionized water 35 parts, propylene glycol 0.7 part, 2 is added in shredder, 2,4-trimethylammonium-1, (the CZ-101 type electric shock nano-tourmaline that Hangzhou Ge Ling novel material company limited produces, negative ion concentration is 2000cm for 3-pentanediol mono isobutyrate 3 parts, talcum powder 5 parts, anionic additive 30 parts
-3), polycarboxylate sodium's type dispersion agent 0.3 part (Nuo Pu section SN-5040), Natvosol type thickening material 1.5 parts (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 0.8 part, under the speed of 1000r/min, grind 35min, obtain slurry;
Be transferred to by slurry in dispersion machine, by pure-acrylic emulsion 20 parts, (ROHM AND HAAS is easily tough to be reached
tM2468), (Lishui is sub-YN-500 goldenly for silver ions additive 5 parts, 50ppm) and methyl-silicone oil 0.5 part add in this slurry, dispersed with stirring 20min under the speed of 500r/min, through 100 object screen filtrations, obtains the clean haze coating products of negative ion antibiotic of the present invention.
To sum up, the coating products of the present embodiment is prepared by the raw material of following weight part:
Embodiment 2
Deionized water 20 parts, 2 is added in shredder, 2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 2 parts, Rutile type Titanium Dioxide 10 parts, kaolin 5 parts, 3 parts, diatomite, (lattice spirit novel material CZ-102, negative ion concentration is 10000cm to anionic additive 15 parts
-3), polycarboxylate sodium's type dispersion agent 0.5 part (Nuo Pu section SN-5040), Natvosol type thickening material 1.2 parts (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 0.8 part, under the speed of 1500r/min, grind 20min, obtain slurry;
Slurry is transferred in dispersion machine, by benzene emulsion 30 parts (ROHM AND HAAS AS-398), silver ions additive 0.5 part (the golden sub-YN-500 in ground in Lishui, 1000ppm) and methyl-silicone oil 0.5 part add in this slurry, dispersed with stirring 45min under the speed of 800r/min, through 90 object screen filtrations, obtain the clean haze coating products of negative ion antibiotic of the present invention.
To sum up, the coating products of the present embodiment is prepared by the raw material of following weight part:
Embodiment 3
Deionized water 50 parts, propylene glycol 6.5 parts, 2 is added in shredder, 2, (lattice spirit novel material CZ-103, negative ion concentration is 30000cm for 4-trimethylammonium-1,3-pentanediol mono isobutyrate 4 parts, 15 parts, zinc sulfide white, pure aluminium silicate 5 parts, 5 parts, calcium carbonate, anionic additive 20 parts
-3), polycarboxylate sodium's type dispersion agent 1.5 parts (Nuo Pu section SN-5040), Natvosol type thickening material 1.2 parts (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 0.8 part, under the speed of 2000r/min, grind 60min, obtain slurry;
Slurry is transferred in dispersion machine, by organosilicon crylic acid latex 40 parts (east subfamily power BC-3206), silver ions additive 20 parts (the golden sub-YN-500 in ground in Lishui, 200ppm) and methyl-silicone oil 1.0 parts add in this slurry, dispersed with stirring 15min under the speed of 1500r/min, through 80 object screen filtrations, obtain the clean haze coating products of negative ion antibiotic of the present invention.
To sum up, the coating products of the present embodiment is prepared by the raw material of following weight part:
Embodiment 4
In shredder, add deionized water 40 parts, propylene glycol 4 parts, Rutile type Titanium Dioxide 20 parts, pure aluminium silicate 5 parts, 5 parts, mica, pure aluminium silicate 5 parts, (lattice spirit novel material CZ-105, negative ion concentration is 50000cm to anionic additive 8 parts
-3), polycarboxylate sodium's type dispersion agent 0.3 part (Nuo Pu section SN-5040), Natvosol type thickening material 0.5 part (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 0.2 part, under the speed of 3000r/min, grind 45min, obtain slurry;
Slurry is transferred in dispersion machine, by epoxy resin latex 15 parts, silver ions additive 2 parts (the golden sub-YN-500 in ground in Lishui, 500ppm) and methyl-silicone oil 0.5 part add in this slurry, dispersed with stirring 30min under the speed of 2000r/min, through 90 object screen filtrations, obtain the clean haze coating products of negative ion antibiotic of the present invention.
To sum up, the coating products of the present embodiment is prepared by the raw material of following weight part:
Comparative example 1
Deionized water 15 parts, propylene glycol 0.5 part, 2 is added in shredder, 2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 3 parts, Rutile type Titanium Dioxide 15 parts, kaolin 5 parts, 1 part, diatomite, BIT 0.2 part, poly carboxylic acid sodium form dispersion agent (Nuo Pu section SN-5040) 0.3 part, Natvosol type thickening material (Tao Shi CellusizeER-30M) 1.5 parts and 2-amino-2-methyl-1-propanol 0.8 part, under the speed of 3000r/min, grind 45min, obtain slurry;
Be transferred to by slurry in dispersion machine, by pure-acrylic emulsion 40 parts, (ROHM AND HAAS is easily tough to be reached
tM2468) and mineral oil antifoam agent 0.5 part add in slurry, dispersed with stirring 30min under the speed of 600r/min, through 100 object screen filtrations, obtains coating products.
Compared with the present invention, this coating products has lacked the composition such as anionic additive and silver ions additive, does not have negative ion releasing function and the long-term antibacterial and antimildew function of silver ions, and only relies on BIT to possess the antibacterial of short-term.
Common coating products prepared by negative ion antibiotic of the present invention clean haze coating products embodiment 1 ~ 4 obtained and comparative example 1 tests antibacterial and mouldproof by HG/T 3950-2007, adopt PM2.5 detector in the 10L encloses container of surrounding sprayed coating, test the removal effect of PM2.5, result is as shown in table 1.
Table 1
From table 1, industry highest ranking is reached by the antibacterial and mouldproof performance of the clean haze coating products of negative ion antibiotic of the present invention of anionic additive and silver ions additive improved, negative ion antibiotic of the present invention clean haze coating has good PM2.5 removal effect simultaneously, is applicable to the occasions such as civil construction, commercial building, public building.
The using method of negative ion antibiotic clean haze coating in the present invention: undertaken using by general exterior coating use-pattern and usage quantity.
Claims (8)
1. the clean haze coating of negative ion antibiotic, is characterized in that, be by the raw material of following weight part through grinding, mix:
Described filming emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion or epoxy resin latex;
Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000 ~ 50000cm
-3;
Described silver ions additive is the silver ion complex aqueous solution of 50 ~ 1000ppm;
Described color stuffing is one or more in titanium dioxide, zinc sulfide white, kaolin, diatomite, calcium carbonate, pure aluminium silicate, mica or talcum powder;
Described auxiliary agent is one or more in film coalescence aid, dispersion agent, wetting agent, defoamer, thickening material, frostproofer or pH adjusting agent.
2. the clean haze coating of negative ion antibiotic according to claim 1, is characterized in that, described film coalescence aid is 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate.
3. the clean haze coating of negative ion antibiotic according to claim 1, is characterized in that, described dispersion agent is polycarboxylate sodium's type dispersion agent.
4. the clean haze coating of negative ion antibiotic according to claim 1, is characterized in that, described wetting agent is Soxylat A 25-7 wetting agent.
5. the clean haze coating of negative ion antibiotic according to claim 1, it is characterized in that, described defoamer is methyl-silicone oil.
6. the clean haze coating of negative ion antibiotic according to claim 1, is characterized in that, described thickening material is Natvosol type thickening material.
7. the clean haze coating of negative ion antibiotic according to claim 1, it is characterized in that, described frostproofer is propylene glycol.
8. the clean haze coating of negative ion antibiotic according to claim 1, it is characterized in that, described pH adjusting agent is 2-amino-2-methyl-1-propanol.
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| CN201410699463.1A CN104497685A (en) | 2014-11-27 | 2014-11-27 | Negative ion-containing antibacterial haze-cleaning paint |
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Cited By (19)
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| CN105176360A (en) * | 2015-11-02 | 2015-12-23 | 西安康普瑞新材料科技有限公司 | Ionic membrane processing technology and ionic membrane |
| CN105175767A (en) * | 2015-11-02 | 2015-12-23 | 西安康普瑞新材料科技有限公司 | Ionic membrane processing technology and ionic membrane |
| CN105255341A (en) * | 2015-11-02 | 2016-01-20 | 西安康普瑞新材料科技有限公司 | Negative-ion coating and preparation method thereof |
| CN105754441A (en) * | 2016-03-25 | 2016-07-13 | 无锡南理工科技发展有限公司 | Preparation method of water-based paint with sterilization function |
| CN105802412A (en) * | 2016-03-25 | 2016-07-27 | 无锡南理工科技发展有限公司 | Water-based coating doped with nanometer titanium dioxide and having sterilization function |
| CN105925158A (en) * | 2016-05-31 | 2016-09-07 | 深圳市宜丽环保科技股份有限公司 | Special spraying material applied to surface of casing of household electric appliance and having air purification function |
| CN106116401A (en) * | 2016-06-21 | 2016-11-16 | 安徽铭源新型建材科技有限公司 | A kind of negative oxygen ion function coating, preparation method and application |
| CN106221469A (en) * | 2016-08-26 | 2016-12-14 | 上海绿特丹保温工程有限公司 | A kind of water-water reflective insulation anti-fog haze multicolor finish |
| CN106752552A (en) * | 2017-03-13 | 2017-05-31 | 境洁环保科技（上海）有限公司 | Multifunctional coating and preparation method thereof |
| CN106883649A (en) * | 2017-04-12 | 2017-06-23 | 程艳青 | A kind of multi-functional environment-protection water paint and preparation method thereof |
| CN107083123A (en) * | 2017-06-20 | 2017-08-22 | 炫杰复合材料（上海）有限公司 | A kind of negative oxygen ion coating and preparation method thereof |
| CN107216754A (en) * | 2017-06-12 | 2017-09-29 | 广州立邦涂料有限公司 | One kind is except haze interiro wall latex paint and preparation method thereof |
| CN107400434A (en) * | 2017-09-07 | 2017-11-28 | 深圳市嘉达高科产业发展有限公司 | Mould proof exterior coating and preparation method thereof |
| CN107936652A (en) * | 2017-05-11 | 2018-04-20 | 东莞市金基环保科技有限公司 | Anti-fog haze low-carbon health coating |
| CN108059902A (en) * | 2017-12-21 | 2018-05-22 | 广东德新科技孵化器有限公司 | A kind of furniture surface spray paint and preparation method thereof |
| CN108912992A (en) * | 2018-06-13 | 2018-11-30 | 重庆文理学院 | A kind of anion air purifying wall finiss and its production technology |
| CN109705713A (en) * | 2018-12-27 | 2019-05-03 | 东易生态科技(广州)有限公司 | It is a kind of to be sprayed at the anion generation liquid to form a film on hard material |
| CN110240845A (en) * | 2019-06-26 | 2019-09-17 | 广东七色世界环保新材料有限公司 | Multi-functional indoor negative ion paint and preparation method thereof |
| CN112898810A (en) * | 2021-01-22 | 2021-06-04 | 周志茹 | Silver ion long-acting bactericidal wall coating and preparation method thereof |
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