CN104497686A - Preparation method of negative ion texture paint - Google Patents
Preparation method of negative ion texture paint Download PDFInfo
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- CN104497686A CN104497686A CN201410699533.3A CN201410699533A CN104497686A CN 104497686 A CN104497686 A CN 104497686A CN 201410699533 A CN201410699533 A CN 201410699533A CN 104497686 A CN104497686 A CN 104497686A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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Abstract
The invention relates to the technical field of functional building paint and provides a preparation method of negative ion texture paint. The preparation method comprises the following steps of adding quartz sand and negative ion basic paint into a high speed dispenser, carrying out stirring at a high speed of 200-1000r/min for 5-10min, and adding a thickening agent aqueous solution into the mixture according to a specified ratio so that viscosity is adjusted. Through use of the negative ion additive, the coating film has a negative ion continuous-release function. The preparation method is simple and convenient and is conducive to reduction of an industrial production cost. The negative ion texture paint has low VOC (volatile organic compound) content, can greatly reduce environmental pollution, is environmentally friendly, has good negative ion release performances and decorativeness, is especially suitable for occasions such as residential buildings, commercial buildings and common buildings and has a wide application prospect.
Description
Technical field
The invention belongs to Functional Architectural Coatings in China technical field, particularly a kind of preparation method of negative ion texture coating.
Background technology
The health of negative ion to human body has important effect, has become the important parameter weighing Air quality.After negative ion is inhaled into human body, by respiratory system and blood circulation, improve human body respiration function and endocrine function, enhance metabolism, strengthen the immunological competence of human body.Meanwhile, because negative ion is to the neutralizing effect of positive ion, deodorizing, dedusting, anticorrosion, antibacterial, decomposing formaldehyde and smog, the effect that purifies air can be played.But urban environment is due to reasons such as trade waste discharge, waste incineration, toxic chemicals, electromagnetic radiation pollutions, causes ion to fall sharply, is unfavorable for healthy.Therefore, the active demand that in room, negative ion concentration has become is increased.
Along with the continuous progress of technology, the appearance of negative ion building materials especially negative ion paint, provides low cost, easily approach for improving indoor-outdoor air negative ion concentration.Publication number is that the Chinese invention patent application of CN 201110374894.7 discloses a kind of negative ion paint and preparation method thereof, comprises the acrylic resin of 20 ~ 30 weight parts, the titanium dioxide of 10 ~ 15 weight parts, the calcium carbonate of 15 ~ 20 weight parts, the composite negative ion material of 1 ~ 4 weight part, the zinc oxide of 1 ~ 3 weight part, the talcum powder of 7 ~ 11 weight parts, the ethylene glycol of 1 ~ 2 weight part, the tripoly phosphate sodium STPP of 6 ~ 1 weight parts, the water of 21 ~ 25 weight parts, the auxiliary agent of 0.3 ~ 0.7 weight part; Wherein composite negative ion material is the mixture of a certain proportion of electric shock nano-tourmaline and nano-tourmaline.In addition, publication number is that the Chinese invention patent application of CN03129256.9 also discloses a kind of antibacterial negative ion coating, its know-why mainly adopts the anion powder of 0.01 ~ 1 weight part and the inorganic nano silver-series antibacterial agent of 0.01 ~ 1 weight part, and anion powder is wherein the grinding powder of tourmalinite and strange ice stone mixed ore.But above-mentioned patent is only limitted to emulsion paint, be difficult to be applicable to the higher occasion of finishing effect requirement.
Summary of the invention
The technical problem to be solved in the present invention is, overcomes deficiency of the prior art, provides a kind of preparation method of negative ion texture coating.
For technical solution problem, solution of the present invention is:
A kind of preparation method of negative ion texture coating is provided, comprises the following steps:
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stirs 5 ~ 10min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity;
The parts by weight of each raw material of negative ion texture coating are as follows:
Negative ion base paint 20 ~ 40 parts;
Quartz sand 60 ~ 80 parts;
Aqueous thickener solution 5 ~ 20 parts;
The solid content of described aqueous thickener solution is 0.5 ~ 10 part, containing at least one in Natvosol, the swelling acrylic thickener of alkali, sodium bentonite;
Described negative ion base paint is prepared by following method:
(1) stirring at low speed:
Deionized water, part of auxiliary are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stir 5 ~ 10min; Described part of auxiliary refers to other auxiliary agent except defoamer;
(2) high speed dispersion:
Anionic additive, color stuffing are continued to be added in aforementioned high speed dispersor, under the speed of 1000 ~ 3000r/min, stirs 10 ~ 30min, obtain slurry;
(3) stirring at low speed dispersion:
Synthetic resin emulsion and remaining auxiliary agent are added in afore-mentioned slurry, dispersed with stirring 5 ~ 15min under the speed of 200 ~ 1000r/min, through 80 ~ 100 object screen filtrations, obtain negative ion base paint;
The parts by weight of each raw material of negative ion base paint are as follows:
Described synthetic resin emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion, epoxy resin latex; Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000 ~ 50000cm
-3; Described color stuffing is one or more in titanium dioxide, zinc sulfide white, kaolin, diatomite, calcium carbonate, pure aluminium silicate, mica, talcum powder; Described auxiliary agent is one or more in film coalescence aid, dispersion agent, wetting agent, defoamer, thickening material, antiseptic-germicide, frostproofer, pH adjusting agent.
Present invention also offers a kind of preparation method of negative ion texture coating, comprise the following steps:
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stirs 5 ~ 10min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity;
The parts by weight of each raw material of negative ion texture coating are as follows:
Negative ion base paint 20 ~ 40 parts;
Quartz sand 60 ~ 80 parts;
Aqueous thickener solution 5 ~ 20 parts;
The solid content of described aqueous thickener solution is 0.5 ~ 10 part, containing at least one in Natvosol, the swelling acrylic thickener of alkali, sodium bentonite;
Described negative ion base paint is prepared by following method:
(1) stirring at low speed:
By deionized water, propylene glycol, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, BIT, polycarboxylate sodium's type dispersion agent, Natvosol type thickening material and 2-amino-2-methyl-1-propanol are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stir 5 ~ 10min;
(2) high speed dispersion:
Titanium dioxide, kaolin, calcium carbonate, anionic additive are added in high speed dispersor, under the speed of 1000 ~ 3000r/min, grinds 10 ~ 30min, obtain slurry;
(3) stirring at low speed:
Synthetic resin emulsion and mineral oil antifoam agent are added in this slurry, dispersed with stirring 5 ~ 15min under the speed of 500 ~ 2000r/min, through 80 ~ 100 object screen filtrations, obtain negative ion base paint;
The parts by weight of each raw material of negative ion base paint are as follows:
Described synthetic resin emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion, epoxy resin latex; Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000 ~ 50000cm
-3.
In the present invention:
Described filming emulsion, it is mainly as the base material of coating, has vital role to the weathering resistance, mechanical property etc. of coating.As preferably, described filming emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion, epoxy resin latex, and affiliated emulsion all can adopt commercially available prod.
Described anionic additive has the function of sustained release negative ion.Anionic additive of the present invention is commercially available electric shock nano-tourmaline.
In described auxiliary agent, film coalescence aid specifically can select 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, dispersion agent specifically can select polycarboxylate sodium's type dispersion agent, wetting agent can specifically select propylene glycol or glycerine, defoamer specifically can select methyl-silicone oil, thickening material specifically can select Natvosol type thickening material, antiseptic-germicide specifically can select isothiazolones (as BIT), and frostproofer specifically can select propylene glycol, and pH adjusting agent specifically can select 2-amino-2-methyl-1-propanol.
Compared with prior art, tool of the present invention has the following advantages:
The present invention introduces anionic additive in coating, makes film forming matter have sustained release anion function by anionic additive.Meanwhile, preparation method of the present invention is simple, convenient, is conducive to reducing industrial production cost.In addition, VOC (i.e. volatile organic compounds) content of negative ion texture coating of the present invention is lower, significantly can reduce environmental pollution, environmental friendliness.
Preparation method of the present invention, grinds raw material and can obtain coating after dispersed with stirring, and its preparation technology is simple, easy to implement, easy and simple to handle, is conducive to industrialization scale operation, reduces industrial production cost, has good economic benefit.
Coating of the present invention has good Negative ion disengagement and ornamental, is specially adapted to the occasions such as civil construction, commercial building, public building, has broad application prospects.
Embodiment
Below in conjunction with case study on implementation, the present invention is further described." part " in the following example all refers to weight part.
Embodiment 1
The first step: the preparation of negative ion base paint
Deionized water 30 parts, propylene glycol 2.5 parts, 2 is added in high speed dispersor machine, 2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 0.8 part, BIT 0.5 part, polycarboxylate sodium's type dispersion agent 0.1 part (Nuo Pu section SN-5040), Natvosol type thickening material 2 parts (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 1 part, disperse 10min under the speed of 200r/min; Add Rutile type Titanium Dioxide 15 parts, kaolin 5 parts, 10 parts, calcium carbonate again, (lattice spirit novel material CZ-101, negative ion concentration is 2000cm to anionic additive 5 parts
-3), under the speed of 3000r/min, disperse 10min to obtain slurry; Under the speed of 600r/min, organosilicon crylic acid latex 20 parts and mineral oil antifoam agent 0.1 part are added in this slurry, dispersed with stirring 10min, through 100 object screen filtrations, obtain negative ion base paint of the present invention.
To sum up, in the present embodiment, negative ion base paint is prepared by the raw material of following weight part:
Second step: the preparation of negative ion texture coating
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 1000r/min, stirs 5min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity; The parts by weight of each raw material are as follows:
Negative ion base paint 20 parts;
Quartz sand 60 parts;
Aqueous thickener solution 5 parts;
The solid content of described aqueous thickener solution is 0.5 part, and it contains thing is admittedly Natvosol.
Embodiment 2
The first step: the preparation of negative ion base paint
Deionized water 20 parts, propylene glycol 0.5 part, 2 is added in high speed dispersor machine, 2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 6.1 parts, BIT 0.1 part, polycarboxylate sodium's type dispersion agent 0.5 part (Nuo Pu section SN-5040), Natvosol type thickening material 1.3 parts (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 1.0 parts, disperse 7min under the speed of 350r/min; Add 8 parts, zinc sulfide white, 12 parts, diatomite again, (lattice spirit novel material CZ-102, negative ion concentration is 50000cm to anionic additive 30 parts
-3), under the speed of 2000r/min, disperse 30min to obtain slurry; Under the speed of 1000r/min, epoxy resin latex 50 parts and mineral oil antifoam agent 0.5 part are added in this slurry, dispersed with stirring 5min, 80 object screen filtrations, obtain negative ion base paint of the present invention.
Second step: the preparation of negative ion texture coating
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 200r/min, stirs 10min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity; The parts by weight of each raw material are as follows:
Negative ion base paint 40 parts;
Quartz sand 80 parts;
Aqueous thickener solution 20 parts;
The solid content of described aqueous thickener solution is 10 parts, and it contains thing is admittedly the swelling acrylic thickener of alkali.
Embodiment 3
The first step: the preparation of negative ion base paint
Deionized water 40 parts, propylene glycol 0.7 part, 2 is added in high speed dispersor machine, 2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 0.5 part, BIT 0.2 part, polycarboxylate sodium's type dispersion agent 1 part (Nuo Pu section SN-5040), Natvosol type thickening material 1 part (Tao Shi Cellusize ER-30M) and 2-amino-2-methyl-1-propanol 0.6 part, disperse 5min under the speed of 1000r/min; Add pure aluminium silicate 5 parts, 1 part, mica, talcum powder 9 parts again, (lattice spirit novel material CZ-103, negative ion concentration is 10000cm to anionic additive 20 parts
-3), under the speed of 1000r/min, disperse 20min to obtain slurry; Under the speed of 200r/min, by pure-acrylic emulsion 40 parts, (ROHM AND HAAS is easily tough to be reached
tM2468) and mineral oil antifoam agent 1 part add in this slurry, dispersed with stirring 15min, through 90 object screen filtrations, obtains negative ion base paint of the present invention.
Second step: the preparation of negative ion texture coating
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 500r/min, stirs 8min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity; The parts by weight of each raw material are as follows:
Negative ion base paint 30 parts;
Quartz sand 70 parts;
Aqueous thickener solution 16 parts;
The solid content of described aqueous thickener solution is 6 parts, and it contains thing is admittedly sodium bentonite.
Embodiment 4
The first step: the preparation of negative ion base paint
By deionized water, propylene glycol, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, BIT, polycarboxylate sodium's type dispersion agent, Natvosol type thickening material and 2-amino-2-methyl-1-propanol are added in high speed dispersor, under the speed of 800r/min, stir 7min; Titanium dioxide, kaolin, calcium carbonate, anionic additive are added in high speed dispersor, under the speed of 2000r/min, grinds 20min, obtain slurry; Synthetic resin emulsion and mineral oil antifoam agent are added in this slurry, dispersed with stirring 10min under the speed of 1000r/min, through 90 object screen filtrations, obtain negative ion base paint.
The negative ion base paint of the present embodiment is prepared by the raw material of following weight part:
Described synthetic resin emulsion is epoxy resin latex; Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 30000cm
-3.
Second step: the preparation of negative ion texture coating
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 200r/min, stirs 5min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity; The parts by weight of each raw material are as follows:
Negative ion base paint 20 parts;
Quartz sand 60 parts;
Aqueous thickener solution 5 parts;
The solid content of described aqueous thickener solution is 0.5 part, admittedly containing system Natvosol.
Embodiment 5
The first step: the preparation of negative ion base paint
By deionized water, propylene glycol, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, BIT, polycarboxylate sodium's type dispersion agent, Natvosol type thickening material and 2-amino-2-methyl-1-propanol are added in high speed dispersor, under the speed of 200r/min, stir 5min; Titanium dioxide, calcium carbonate, anionic additive are added in high speed dispersor, under the speed of 1000r/min, grinds 10min, obtain slurry; Synthetic resin emulsion and mineral oil antifoam agent are added in this slurry, dispersed with stirring 5min under the speed of 500r/min, through 80 object screen filtrations, obtain negative ion base paint.
The negative ion base paint of the present embodiment is prepared by the raw material of following weight part:
Described synthetic resin emulsion is organosilicon crylic acid latex; Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000cm
-3.
Second step: the preparation of negative ion texture coating
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 1000r/min, stirs 10min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity; The parts by weight of each raw material are as follows:
Negative ion base paint 40 parts;
Quartz sand 80 parts;
Aqueous thickener solution 20 parts;
The solid content of described aqueous thickener solution is 10 parts, admittedly containing the swelling acrylic thickener of system alkali.
Embodiment 6
The first step: the preparation of negative ion base paint
By deionized water, propylene glycol, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, BIT, polycarboxylate sodium's type dispersion agent, Natvosol type thickening material and 2-amino-2-methyl-1-propanol are added in high speed dispersor, under the speed of 1000r/min, stir 10min; Titanium dioxide, kaolin, calcium carbonate, anionic additive are added in high speed dispersor, under the speed of 3000r/min, grinds 30min, obtain slurry; Synthetic resin emulsion and mineral oil antifoam agent are added in this slurry, dispersed with stirring 15min under the speed of 2000r/min, through 100 object screen filtrations, obtain negative ion base paint.
The negative ion base paint of the present embodiment is prepared by the raw material of following weight part:
Described synthetic resin emulsion is polyaminoester emulsion; Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 50000cm
-3.
Second step: the preparation of negative ion texture coating
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 500r/min, stirs 7min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity; The parts by weight of each raw material are as follows:
Negative ion base paint 30 parts;
Quartz sand 70 parts;
Aqueous thickener solution 10 parts;
The solid content of described aqueous thickener solution is 5 parts, admittedly containing system sodium bentonite.
The negative ion texture coating product of the present invention embodiment 1 ~ 3 obtained tests the negative aeroion amount of inducing by HGT 4109-2009, and result is as shown in table 1.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Negative aeroion induces | 300/(scm 2) | 520/(scm 2) | 480/(scm 2) |
From table 1, the negative ion texture coating product of the present invention improved by anionic additive has the higher negative aeroion amount of inducing, and is applicable to the occasions such as civil construction, commercial building, public building.
Claims (2)
1. a preparation method for negative ion texture coating, is characterized in that, comprises the following steps:
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stirs 5 ~ 10min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity;
The parts by weight of each raw material of negative ion texture coating are as follows:
Negative ion base paint 20 ~ 40 parts;
Quartz sand 60 ~ 80 parts;
Aqueous thickener solution 5 ~ 20 parts;
The solid content of described aqueous thickener solution is 0.5 ~ 10 part, containing at least one in Natvosol, the swelling acrylic thickener of alkali, sodium bentonite;
Described negative ion base paint is prepared by following method:
(1) stirring at low speed:
Deionized water, part of auxiliary are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stir 5 ~ 10min; Described part of auxiliary refers to other auxiliary agent except defoamer;
(2) high speed dispersion:
Anionic additive, color stuffing are continued to be added in aforementioned high speed dispersor, under the speed of 1000 ~ 3000r/min, stirs 10 ~ 30min, obtain slurry;
(3) stirring at low speed dispersion:
Synthetic resin emulsion and remaining auxiliary agent are added in afore-mentioned slurry, dispersed with stirring 5 ~ 15min under the speed of 200 ~ 1000r/min, through 80 ~ 100 object screen filtrations, obtain negative ion base paint;
The parts by weight of each raw material of negative ion base paint are as follows:
Described synthetic resin emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion, epoxy resin latex;
Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000 ~ 50000cm
-3;
Described color stuffing is one or more in titanium dioxide, zinc sulfide white, kaolin, diatomite, calcium carbonate, pure aluminium silicate, mica, talcum powder;
Described auxiliary agent is one or more in film coalescence aid, dispersion agent, wetting agent, defoamer, thickening material, antiseptic-germicide, frostproofer, pH adjusting agent.
2. a preparation method for negative ion texture coating, is characterized in that, comprises the following steps:
Quartz sand and negative ion base paint are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stirs 5 ~ 10min; And the proportioning of regulation adds aqueous thickener solution adjusting viscosity;
The parts by weight of each raw material of negative ion texture coating are as follows:
Negative ion base paint 20 ~ 40 parts;
Quartz sand 60 ~ 80 parts;
Aqueous thickener solution 5 ~ 20 parts;
The solid content of described aqueous thickener solution is 0.5 ~ 10 part, containing at least one in Natvosol, the swelling acrylic thickener of alkali, sodium bentonite;
Described negative ion base paint is prepared by following method:
(1) stirring at low speed:
By deionized water, propylene glycol, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate, BIT, polycarboxylate sodium's type dispersion agent, Natvosol type thickening material and 2-amino-2-methyl-1-propanol are added in high speed dispersor, under the speed of 200 ~ 1000r/min, stir 5 ~ 10min;
(2) high speed dispersion:
Titanium dioxide, kaolin, calcium carbonate, anionic additive are added in high speed dispersor, under the speed of 1000 ~ 3000r/min, grinds 10 ~ 30min, obtain slurry;
(3) stirring at low speed:
Synthetic resin emulsion and mineral oil antifoam agent are added in this slurry, dispersed with stirring 5 ~ 15min under the speed of 500 ~ 2000r/min, through 80 ~ 100 object screen filtrations, obtain negative ion base paint;
The parts by weight of each raw material of negative ion base paint are as follows:
Described synthetic resin emulsion is the one in pure-acrylic emulsion, benzene emulsion, vinyl acetate emulsion, organosilicon crylic acid latex, polyaminoester emulsion, epoxy resin latex;
Described anionic additive is electric shock nano-tourmaline, and its negative ion concentration is 2000 ~ 50000cm
-3.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410699533.3A CN104497686A (en) | 2014-11-27 | 2014-11-27 | Preparation method of negative ion texture paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410699533.3A CN104497686A (en) | 2014-11-27 | 2014-11-27 | Preparation method of negative ion texture paint |
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| Publication Number | Publication Date |
|---|---|
| CN104497686A true CN104497686A (en) | 2015-04-08 |
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| CN201410699533.3A Pending CN104497686A (en) | 2014-11-27 | 2014-11-27 | Preparation method of negative ion texture paint |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280662A (en) * | 2015-05-17 | 2017-01-04 | 北京富莱明新材料有限公司 | A kind of paint or the preparation method of coating |
| CN106752507A (en) * | 2016-12-06 | 2017-05-31 | 啄木鸟漆业集团有限公司 | A kind of preparation method of anion texture paint |
| CN107728339A (en) * | 2017-11-06 | 2018-02-23 | 苏州菲博特环保科技有限公司 | Negative-ion energy glasses |
| CN108610811A (en) * | 2016-12-07 | 2018-10-02 | 任细川 | A kind of functionality negative ion paint and preparation method thereof |
| CN109111195A (en) * | 2018-06-26 | 2019-01-01 | 江苏新亿源环保科技有限公司 | A kind of preparation method of negative ion type function artificial stone |
| CN109749556A (en) * | 2019-01-29 | 2019-05-14 | 柳州贝丽嘉涂料有限公司 | Negative oxygen ion coating and preparation method thereof |
| CN116120770A (en) * | 2023-01-13 | 2023-05-16 | 卡本科技集团股份有限公司 | Texture paint and preparation method thereof |
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| CN1861703A (en) * | 2006-06-20 | 2006-11-15 | 北京清大华研科技发展有限公司 | Multifunctional thick liquid paint |
| CN101440232A (en) * | 2007-11-20 | 2009-05-27 | 陈莹 | Multifunctional thick pulp nano colorful wall artistic paint |
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| CN1441010A (en) * | 2003-03-28 | 2003-09-10 | 饶俊明 | Air purifying paint |
| CN1861703A (en) * | 2006-06-20 | 2006-11-15 | 北京清大华研科技发展有限公司 | Multifunctional thick liquid paint |
| CN101440232A (en) * | 2007-11-20 | 2009-05-27 | 陈莹 | Multifunctional thick pulp nano colorful wall artistic paint |
| CN101935188A (en) * | 2009-07-02 | 2011-01-05 | 余春冠 | Stereoscopic coating for removing harmful gases |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280662A (en) * | 2015-05-17 | 2017-01-04 | 北京富莱明新材料有限公司 | A kind of paint or the preparation method of coating |
| CN106752507A (en) * | 2016-12-06 | 2017-05-31 | 啄木鸟漆业集团有限公司 | A kind of preparation method of anion texture paint |
| CN108610811A (en) * | 2016-12-07 | 2018-10-02 | 任细川 | A kind of functionality negative ion paint and preparation method thereof |
| CN107728339A (en) * | 2017-11-06 | 2018-02-23 | 苏州菲博特环保科技有限公司 | Negative-ion energy glasses |
| CN109111195A (en) * | 2018-06-26 | 2019-01-01 | 江苏新亿源环保科技有限公司 | A kind of preparation method of negative ion type function artificial stone |
| CN109749556A (en) * | 2019-01-29 | 2019-05-14 | 柳州贝丽嘉涂料有限公司 | Negative oxygen ion coating and preparation method thereof |
| CN109749556B (en) * | 2019-01-29 | 2020-11-13 | 柳州贝丽嘉涂料有限公司 | Negative oxygen ion coating and preparation method thereof |
| CN116120770A (en) * | 2023-01-13 | 2023-05-16 | 卡本科技集团股份有限公司 | Texture paint and preparation method thereof |
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Application publication date: 20150408 |