CN101787237A - Powder emulsion paint for interior wall - Google Patents
Powder emulsion paint for interior wall Download PDFInfo
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- CN101787237A CN101787237A CN201010106715A CN201010106715A CN101787237A CN 101787237 A CN101787237 A CN 101787237A CN 201010106715 A CN201010106715 A CN 201010106715A CN 201010106715 A CN201010106715 A CN 201010106715A CN 101787237 A CN101787237 A CN 101787237A
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- interior wall
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Abstract
The invention relates to a powder emulsion paint for an interior wall, comprising the following components by weight percent: 25-35% of re-dispersible crylic acid rubber powder, 2-3% of polyving akohol, 15-20% of triple superphosphate, 10-15% of nanometer calcium carbonate, 14-20% of titanium white, 6-10% of lithopone, 4-6% of kaolin, 0.5-2% attapulgite, 0.5-1% of sodium polyacrylate, 0.5-0.8% of hydroxyethyl cellulose, 0.1-0.23% of sodium dodecyl benzene sulfonate, 0.24-0.4% of lauryl sodium sulfate, 0.15-0.5% of sodium tripolyphosphate, 0.6-0.8% of fatty alcohol-polyoxyethylene ether, and 0.01-0.05% of sodium hydroxide. The invention has no organic solvent; porous nanometer filler can be used for absorbing indoor harmful substance; the invention can be stored for a long time without any deterioration or precipitation; and the powder dispersed by water can be emulsified into an emulsion paint state, and the powder can be prepared into different use concentrations based on construction requirements.
Description
Technical field
The invention belongs to building material field, particularly a kind of emulsion paint, especially a kind of powder emulsion paint for interior wall.
Background technology
Latex coating is being commonly called as of synthetic resin emulsion coating.Resin can be dissolved in the water and become the colloidal solution of homogeneous person and be called water soluble resin.Being dispersed in fine resin particle group (particle dia is 0.1～1.0 μ m) becomes emulsion person and is called latex in the water.
As everyone knows, the basal component of emulsion paint comprises:
(1) filmogen, general high molecular synthetic resin breast, the just macromolecule emulsion of often saying;
(2) color stuffing is mainly given the performance of aspects such as color after the emulsion paint film forming, hardness, water tolerance;
(3) various auxiliary agents, mainly be to improve the quality of emulsion paint such as every index performance of stability in storage, application property and paint film, improvement for emulsion paint at present mainly concentrates in the selection and consumption of auxiliary agent, improve the quality of emulsion paint by selection to auxiliary agent, but the existence of a large amount of auxiliary agents has certain pollution to environment, and this is to make as sanitas and contain harmful material in the emulsion paint because a lot of auxiliary agents contain formaldehyde, benzene class etc.Particularly use on interiro wall latex paint, the objectionable impurities of slow release spreads in the limited space and can bring serious irreversible lesion to HUMAN HEALTH, and this also is a drawback place of emulsion paint.
On the present house ornamentation market much is emulsion paint and solvent borne building coating, and wherein emulsion paint occupies dominant position.Existing emulsion paint product also has storage weak point in period except above-mentioned drawback, easily precipitation is perishable, not anti-freezing, packed and transported cost height, and the shortcoming that can only brush and spray in construction process.
Summary of the invention
At the weak point that exists in the problems referred to above, the invention provides a kind of organic solvent that do not contain, can suck indoor objectionable impurities by the vesicular Nano filling, standing storage is never degenerated, can not precipitated, in use with a kind of powder emulsion paint for interior wall that can be emulsified into the emulsion paint state after the water-dispersion voluntarily.
For achieving the above object, the invention provides a kind of powder emulsion paint for interior wall, comprise redispersible acrylic rubber powder, polyvinyl alcohol, coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, Sodium dodecylbenzene sulfonate and sodium lauryl sulphate, also comprise tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether and sodium hydroxide, the weight percentage ranges of each component is:
Redispersible acrylic rubber powder 25～35%, polyvinyl alcohol 2～3%, coarse whiting 15～20%, nano-calcium carbonate 10～15%, titanium dioxide 14～20%, zinc sulfide white 6～10%, kaolin 4～6%, Attapulgite 0.5～2%, sodium polyacrylate 0.5～1%, Natvosol 0.5～0.8%, Sodium dodecylbenzene sulfonate 0.1～0.23%, sodium lauryl sulphate 0.24～0.4%, tripoly phosphate sodium STPP 0.15～0.5%, fatty alcohol-polyoxyethylene ether 0.6～0.8%, sodium hydroxide 0.01～0.05%.
Described nano-calcium carbonate is made by the calcite after the hypergravity preparation, and its particle diameter is 35～40nm.
Contain 16～18 C atoms in the molecular formula of described fatty alcohol-polyoxyethylene ether.
The alcoholysis degree of described polyvinyl alcohol is 87～89%, and molecular weight is 27000～32000.
Compared with prior art, the present invention has the following advantages:
The invention provides a kind of powder emulsion paint for interior wall, be mixed and made into by following multiple component, the weight percentage ranges of each component is: redispersible acrylic rubber powder 25～35%, polyvinyl alcohol 2～3%, coarse whiting 15～20%, nano-calcium carbonate 10～15%, titanium dioxide 14～20%, zinc sulfide white 6～10%, kaolin 4～6%, Attapulgite 0.5～2%, sodium polyacrylate 0.5～1%, Natvosol 0.5～0.8%, Sodium dodecylbenzene sulfonate 0.1～0.23%, sodium lauryl sulphate 0.24～0.4%, tripoly phosphate sodium STPP 0.15～0.5%, fatty alcohol-polyoxyethylene ether 0.6～0.8%, sodium hydroxide 0.01～0.05%.The present invention does not contain organic solvent, can suck indoor objectionable impurities by the vesicular Nano filling, never degenerate during the standing storage, do not precipitate, convenient transportation, be easy to the packing, in use with can being emulsified into the emulsion paint state voluntarily after the water-dispersion, and according to construction requirement such as blade coating, spraying, brushing, the different working concentration of roller coating configuration.
Embodiment
The invention provides a kind of powder emulsion paint for interior wall, comprise the redispersible acrylic rubber powder, polyvinyl alcohol, coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether and sodium hydroxide, the weight percentage ranges of each component is: redispersible acrylic rubber powder 25～35%, polyvinyl alcohol 2～3%, coarse whiting 15～20%, nano-calcium carbonate 10～15%, titanium dioxide 14～20%, zinc sulfide white 6～10%, kaolin 4～6%, Attapulgite 0.5～2%, sodium polyacrylate 0.5～1%, Natvosol 0.5～0.8%, Sodium dodecylbenzene sulfonate 0.1～0.23%, sodium lauryl sulphate 0.24～0.4%, tripoly phosphate sodium STPP 0.15～0.5%, fatty alcohol-polyoxyethylene ether 0.6～0.8%, sodium hydroxide 0.01～0.05%.
Nano-calcium carbonate is made by the calcite after the hypergravity preparation, and its particle diameter is 35～40nm.
Contain 16～18 C atoms in the molecular formula of fatty alcohol-polyoxyethylene ether.
The alcoholysis degree of polyvinyl alcohol is 87～89%, and molecular weight is 27000～32000.
Preparation method of the present invention is: successively coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, sodium hydroxide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether, polyvinyl alcohol and redispersible acrylic rubber powder are dropped in the pneumatic stirrer by above-mentioned raw material quality per-cent.By controlling compressed-air actuated flow with high speed dispersion raw mix 0.5～1.0h, at stirring at low speed 0.5～1.0h, reduce to room temperature then, use the waterproof woven bag to pack and get final product.
Embodiment one
The invention provides a kind of powder emulsion paint for interior wall, comprise the redispersible acrylic rubber powder, polyvinyl alcohol, coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether and sodium hydroxide, the weight percent numerical value of each component is: redispersible acrylic rubber powder 25%, polyvinyl alcohol 2%, coarse whiting 15%, nano-calcium carbonate 10%, titanium dioxide 14%, zinc sulfide white 6%, kaolin 4%, Attapulgite 0.5%, sodium polyacrylate 0.5%, Natvosol 0.5%, Sodium dodecylbenzene sulfonate 0.1%, sodium lauryl sulphate 0.24%, tripoly phosphate sodium STPP 0.15%, fatty alcohol-polyoxyethylene ether 0.6%, sodium hydroxide 0.01%.
Wherein, nano-calcium carbonate is made by the calcite after the hypergravity preparation, and its particle diameter is 35～40nm.Contain 16～18 C atoms in the molecular formula of fatty alcohol-polyoxyethylene ether.The alcoholysis degree of polyvinyl alcohol is 87～89%, and molecular weight is 27000～32000.
Preparation method of the present invention is: successively coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, sodium hydroxide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether, polyvinyl alcohol and redispersible acrylic rubber powder are dropped in the pneumatic stirrer by above-mentioned raw material quality per-cent.By controlling compressed-air actuated flow with high speed dispersion raw mix 0.5～1.0h, at stirring at low speed 0.5～1.0h, reduce to room temperature then, use the waterproof woven bag to pack and get final product.
Embodiment two
The invention provides a kind of powder emulsion paint for interior wall, comprise the redispersible acrylic rubber powder, polyvinyl alcohol, coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether and sodium hydroxide, the weight percent numerical value of each component is: redispersible acrylic rubber powder 30%, polyvinyl alcohol 2.5%, coarse whiting 18%, nano-calcium carbonate 12%, titanium dioxide 18%, zinc sulfide white 8%, kaolin 5%, Attapulgite 1%, sodium polyacrylate 0.8%, Natvosol 0.7%, Sodium dodecylbenzene sulfonate 0.2%, sodium lauryl sulphate 0.23%, tripoly phosphate sodium STPP 0.3%, fatty alcohol-polyoxyethylene ether 0.7%, sodium hydroxide 0.03%.
Wherein, nano-calcium carbonate is made by the calcite after the hypergravity preparation, and its particle diameter is 35～40nm.Contain 16～18 C atoms in the molecular formula of fatty alcohol-polyoxyethylene ether.The alcoholysis degree of polyvinyl alcohol is 87～89%, and molecular weight is 27000～32000.
Preparation method of the present invention is: successively coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, sodium hydroxide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether, polyvinyl alcohol and redispersible acrylic rubber powder are dropped in the pneumatic stirrer by above-mentioned raw material quality per-cent.By controlling compressed-air actuated flow with high speed dispersion raw mix 0.5～1.0h, at stirring at low speed 0.5～1.0h, reduce to room temperature then, use the waterproof woven bag to pack and get final product.
Embodiment three
The invention provides a kind of powder emulsion paint for interior wall, comprise the redispersible acrylic rubber powder, polyvinyl alcohol, coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether and sodium hydroxide, the weight percent numerical value of each component is: redispersible acrylic rubber powder 35%, polyvinyl alcohol 3%, coarse whiting 20%, nano-calcium carbonate 15%, titanium dioxide 20%, zinc sulfide white 10%, kaolin 6%, Attapulgite 2%, sodium polyacrylate 1%, Natvosol 0.8%, Sodium dodecylbenzene sulfonate 0.23%, sodium lauryl sulphate 0.4%, tripoly phosphate sodium STPP 0.5%, fatty alcohol-polyoxyethylene ether 0.8%, sodium hydroxide 0.05%.
Wherein, nano-calcium carbonate is made by the calcite after the hypergravity preparation, and its particle diameter is 35～40nm.Contain 16～18 C atoms in the molecular formula of fatty alcohol-polyoxyethylene ether.The alcoholysis degree of polyvinyl alcohol is 87～89%, and molecular weight is 27000～32000.
Preparation method of the present invention is: successively coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, sodium hydroxide, Sodium dodecylbenzene sulfonate, sodium lauryl sulphate, tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether, polyvinyl alcohol and redispersible acrylic rubber powder are dropped in the pneumatic stirrer by above-mentioned raw material quality per-cent.By controlling compressed-air actuated flow with high speed dispersion raw mix 0.5～1.0h, at stirring at low speed 0.5～1.0h, reduce to room temperature then, use the waterproof woven bag to pack and get final product.
The detection index of correlation of the emulsion paint for preparing is as follows:
Test basis " synthetic resin emulsion interior wall coating " GB/T 9756-2009 tests, and particular content is as follows:
Test basis " limits of harmful substances in the indoor decorating material interior wall coating " GB/T18582-2008 tests, and particular content is as follows:
By above detection, but still be the product requirement that all reaches the premium grads emulsion paint aspect the environmental protection no matter in construction with the reemulsification type powder emulsion paint of the present invention preparation.
The present invention has fundamentally solved the drawback in production, storage and the use of traditional emulsion paint.
Low cost product of the present invention, do not use any anticorrosion and bactericidal agent and volatility organic additive, paint film water-tolerant after the not only feasible construction of the use of nano level and protruded packing simultaneously, and obnoxious flavour such as formaldehyde, ammonia, benzene and peculiar smell reach and purify the air of a room and the purpose of useful HUMAN HEALTH in effective removal air that can continue for a long time, are optimal environmentfriendly products of wall body decoration at home.
Only the above person only is preferred embodiment of the present invention, is familiar with the professional person of this skill such as. after understanding technique means of the present invention, natural energy is changed under instruction of the present invention according to the needs of reality.Therefore all equal variation and modifications of being done according to the present patent application claim once should still belong in the scope that patent of the present invention contains.
Claims (7)
1. powder emulsion paint for interior wall, comprise redispersible acrylic rubber powder, polyvinyl alcohol, coarse whiting, nano-calcium carbonate, titanium dioxide, zinc sulfide white, kaolin, Attapulgite, sodium polyacrylate, Natvosol, Sodium dodecylbenzene sulfonate and sodium lauryl sulphate, it is characterized in that, also comprise tripoly phosphate sodium STPP, fatty alcohol-polyoxyethylene ether and sodium hydroxide, the weight percentage ranges of each component is:
Redispersible acrylic rubber powder 25～35%, polyvinyl alcohol 2～3%, coarse whiting 15～20%, nano-calcium carbonate 10～15%, titanium dioxide 14～20%, zinc sulfide white 6～10%, kaolin 4～6%, Attapulgite 0.5～2%, sodium polyacrylate 0.5～1%, Natvosol 0.5～0.8%, Sodium dodecylbenzene sulfonate 0.1～0.23%, sodium lauryl sulphate 0.24～0.4%, tripoly phosphate sodium STPP 0.15～0.5%, fatty alcohol-polyoxyethylene ether 0.6～0.8%, sodium hydroxide 0.01～0.05%.
2. a kind of powder emulsion paint for interior wall as claimed in claim 1, it is characterized in that the weight percent numerical value of each component is: redispersible acrylic rubber powder 25%, polyvinyl alcohol 2%, coarse whiting 15%, nano-calcium carbonate 10%, titanium dioxide 14%, zinc sulfide white 6%, kaolin 4%, Attapulgite 0.5%, sodium polyacrylate 0.5%, Natvosol 0.5%, Sodium dodecylbenzene sulfonate 0.1%, sodium lauryl sulphate 0.24%, tripoly phosphate sodium STPP 0.15%, fatty alcohol-polyoxyethylene ether 0.6%, sodium hydroxide 0.01%.
3. a kind of powder emulsion paint for interior wall as claimed in claim 1, it is characterized in that the weight percent numerical value of each component is: redispersible acrylic rubber powder 30%, polyvinyl alcohol 2.5%, coarse whiting 18%, nano-calcium carbonate 12%, titanium dioxide 18%, zinc sulfide white 8%, kaolin 5%, Attapulgite 1%, sodium polyacrylate 0.8%, Natvosol 0.7%, Sodium dodecylbenzene sulfonate 0.2%, sodium lauryl sulphate 0.23%, tripoly phosphate sodium STPP 0.3%, fatty alcohol-polyoxyethylene ether 0.7%, sodium hydroxide 0.03%.
4. a kind of powder emulsion paint for interior wall as claimed in claim 1, it is characterized in that the weight percent numerical value of each component is: redispersible acrylic rubber powder 35%, polyvinyl alcohol 3%, coarse whiting 20%, nano-calcium carbonate 15%, titanium dioxide 20%, zinc sulfide white 10%, kaolin 6%, Attapulgite 2%, sodium polyacrylate 1%, Natvosol 0.8%, Sodium dodecylbenzene sulfonate 0.23%, sodium lauryl sulphate 0.4%, tripoly phosphate sodium STPP 0.5%, fatty alcohol-polyoxyethylene ether 0.8%, sodium hydroxide 0.05%.
5. as any described a kind of powder emulsion paint for interior wall in the claim 1 to 4, it is characterized in that described nano-calcium carbonate is made by the calcite after the hypergravity preparation, its particle diameter is 35～40nm.
6. as any described a kind of powder emulsion paint for interior wall in the claim 1 to 4, it is characterized in that, contain 16～18 C atoms in the molecular formula of described fatty alcohol-polyoxyethylene ether.
7. as any described a kind of powder emulsion paint for interior wall in the claim 1 to 4, it is characterized in that the alcoholysis degree of described polyvinyl alcohol is 87～89%, molecular weight is 27000～32000.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010106715A CN101787237B (en) | 2010-02-08 | 2010-02-08 | Powder emulsion paint for interior wall |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010106715A CN101787237B (en) | 2010-02-08 | 2010-02-08 | Powder emulsion paint for interior wall |
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| CN101787237A true CN101787237A (en) | 2010-07-28 |
| CN101787237B CN101787237B (en) | 2012-10-10 |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967328A (en) * | 2010-11-12 | 2011-02-09 | 孙志勋 | Dry powder emulsion paint for inner and outer wall decoration |
| CN102321417A (en) * | 2011-08-16 | 2012-01-18 | 河南城建学院 | Exterior wall fireproof emulsion paint |
| CN102532977A (en) * | 2011-12-30 | 2012-07-04 | 黑龙江省玉琦装饰涂料有限公司 | Composite multifunctional health paint mate and preparation method thereof |
| CN102816489A (en) * | 2012-08-21 | 2012-12-12 | 江苏紫石化工科技有限公司 | Interior wall stain resistant emulsion paint and preparation method thereof |
| CN103665982A (en) * | 2013-12-02 | 2014-03-26 | 南通瑞普埃尔生物工程有限公司 | Acrylic latex paint and preparation method thereof |
| CN114316698A (en) * | 2021-12-28 | 2022-04-12 | 湖北三棵树新材料科技有限公司 | High-performance powdery latex paint powder and preparation method thereof |
| EP4001363A1 (en) * | 2020-11-11 | 2022-05-25 | Diessner GmbH & Co. KG Lack- und Farbenfabrik | Titanium dioxide-free dispersion paint without preservatives |
-
2010
- 2010-02-08 CN CN201010106715A patent/CN101787237B/en active Active
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101967328A (en) * | 2010-11-12 | 2011-02-09 | 孙志勋 | Dry powder emulsion paint for inner and outer wall decoration |
| CN102321417A (en) * | 2011-08-16 | 2012-01-18 | 河南城建学院 | Exterior wall fireproof emulsion paint |
| CN102321417B (en) * | 2011-08-16 | 2013-06-12 | 河南城建学院 | Exterior wall fireproof emulsion paint |
| CN102532977A (en) * | 2011-12-30 | 2012-07-04 | 黑龙江省玉琦装饰涂料有限公司 | Composite multifunctional health paint mate and preparation method thereof |
| CN102816489A (en) * | 2012-08-21 | 2012-12-12 | 江苏紫石化工科技有限公司 | Interior wall stain resistant emulsion paint and preparation method thereof |
| CN103665982A (en) * | 2013-12-02 | 2014-03-26 | 南通瑞普埃尔生物工程有限公司 | Acrylic latex paint and preparation method thereof |
| EP4001363A1 (en) * | 2020-11-11 | 2022-05-25 | Diessner GmbH & Co. KG Lack- und Farbenfabrik | Titanium dioxide-free dispersion paint without preservatives |
| CN114316698A (en) * | 2021-12-28 | 2022-04-12 | 湖北三棵树新材料科技有限公司 | High-performance powdery latex paint powder and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101787237B (en) | 2012-10-10 |
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Denomination of invention: Powder emulsion paint for interior wall Effective date of registration: 20160902 Granted publication date: 20121010 Pledgee: Chuzhou credit Company limited by guarantee Pledgor: Wang Xiaodi| Beijing Tianwei Paragon chemical products Ltd. Registration number: 2016990000762 |
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