CN104629566A - Antibacterial anion paint - Google Patents

Antibacterial anion paint Download PDF

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Publication number
CN104629566A
CN104629566A CN201510026073.2A CN201510026073A CN104629566A CN 104629566 A CN104629566 A CN 104629566A CN 201510026073 A CN201510026073 A CN 201510026073A CN 104629566 A CN104629566 A CN 104629566A
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parts
nano
negative ion
germ resistance
mixture
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张存标
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ANHUI CARNIVAL PAINT INDUSTRY Co Ltd
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ANHUI CARNIVAL PAINT INDUSTRY Co Ltd
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Priority to CN201510026073.2A priority Critical patent/CN104629566A/en
Publication of CN104629566A publication Critical patent/CN104629566A/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K2003/026—Phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2296—Oxides; Hydroxides of metals of zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
    • C08K2003/3045—Sulfates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate

Abstract

The invention discloses an antibacterial anion paint which is prepared from the following raw materials in parts by weight: 35-60 parts of nano titanium dioxide/silicone-acrylic composite emulsion, 20-35 parts of titanium white, 3-6 parts of nano calcium carbonate, 2-6 parts of precipitated baryte, 3-8 parts of talcum powder, 3-10 parts of dolomite powder, 3-8 parts of bamboo vinegar, 1-5 parts of modified nano zinc oxide, 1-6 parts of opal, 1.2-1.8 parts of 2,2,4-trimethyl-1,3-pentadiol monoisobutyrate, 1-3 parts of mint extract, 1-5 parts of polyalcohol, 0.3-1.2 parts of flame retardant, 0.2-0.8 part of thickener, 0.1-0.3 part of preservative, 0.1-0.5 part of wetting agent, 0.1-0.5 part of dispersing agent and 10-15 parts of water. The antibacterial anion paint has the advantages of high strength, favorable antibacterial property, excellent heat resistance and excellent weather resistance.

Description

A kind of germ resistance negative ion paint
Technical field
The present invention relates to technical field of coatings, particularly relate to a kind of germ resistance negative ion paint.
Background technology
Coating is the indispensable valuable cargo of modern society, has a wide range of applications at numerous areas such as covil construction, industrial production, house decoration, anticorrosion protection.
Negative ion paint is a kind of green health type environmental protection coating material, this coating not only has high strength, persistence and obvious decoration function, and sustainable anion releasing, thus negative ion concentration reaches the object of environmental protect in increase air, make that the live and work environment of people is more healthy, more environmental protection.But along with the continuation deterioration of environment and the in short supply gradually of the energy, the performance of people to negative ion paint is had higher requirement, the germ resistance of existing negative ion paint is not very desirable.
Summary of the invention
The present invention proposes a kind of germ resistance negative ion paint, its intensity is high, and germ resistance is good, and heat-resisting weather resistance is excellent.
The present invention proposes a kind of germ resistance negative ion paint, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 35-60 part, titanium dioxide 20-35 part, nano-calcium carbonate 3-6 part, process white 2-6 part, talcum powder 3-8 part, ground dolomite 3-10 part, bamboo vinegar liquid 3-8 part, modified nano zinc oxide 1-5 part, opal 1-6 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1.2-1.8 part, Folium Menthae extract 1-3 part, polyvalent alcohol 1-5 part, fire retardant 0.3-1.2 part, thickening material 0.2-0.8 part, sanitas 0.1-0.3 part, wetting agent 0.1-0.5 part, dispersion agent 0.1-0.5 part, water 10-15 part.
Preferably, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 45-52 part, titanium dioxide 28-32 part, nano-calcium carbonate 4.5-5.6 part, process white 3-4.6 part, talcum powder 4.5-6 part, ground dolomite 8-9.5 part, bamboo vinegar liquid 5.6-6.5 part, modified nano zinc oxide 1.8-3.5 part, opal 3-5 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1.5-1.8 part, Folium Menthae extract 1.5-2.3 part, polyvalent alcohol 2.5-4 part, fire retardant 0.5-1.0 part, thickening material 0.5-0.8 part, sanitas 0.15-0.23 part, wetting agent 0.25-0.4 part, dispersion agent 0.18-0.35 part, water 12-14 part.
Preferably, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 48 parts, titanium dioxide 30 parts, nano-calcium carbonate 5 parts, process white 3.8 parts, talcum powder 5 parts, ground dolomite 8.5 parts, bamboo vinegar liquid 6 parts, modified nano zinc oxide 3 parts, 3.8 parts, opal, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.5 parts, Folium Menthae extract 1.8 parts, polyvalent alcohol 3 parts, fire retardant 0.8 part, thickening material 0.6 part, sanitas 0.2 part, wetting agent 0.3 part, dispersion agent 0.25 part, 12 parts, water.
Preferably, the properties-correcting agent of described modified nano zinc oxide is one or more the mixture in stearic acid, silane coupling agent, trolamine, diisopropanolamine (DIPA).
Preferably, described polyvalent alcohol is one or more the mixture in tetramethylolmethane, glycerol, polyvinyl alcohol, polyoxyethylene glycol, dipentaerythritol.
Preferably, described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:3-4:1-3 weight ratio.
Preferably, described thickening material is the mixture of a kind of in Walocel MT 20.000PV, Natvosol or two kinds.
Preferably, described dispersion agent is one or more the mixture in trolamine, polyvinylpyrrolidone, sodium lauryl sulphate.
Germ resistance negative ion paint of the present invention is prepared from according to the common process of this area, particularly: proportionally take above-mentioned each raw material, is mixed by each raw material and obtains described germ resistance negative ion paint.
In the present invention, have selected nano titanium oxide/silicone-acrylic compound emulsion as filmogen, nano titanium oxide/silicone-acrylic compound emulsion not only has the excellent film-forming properties of acrylate, photostabilization and erosion resistance, but also have the thermotolerance of polysiloxane excellence concurrently, water tolerance and oil-proofness, in addition, nano titanium oxide has excellent Ultraviolet Light, there is stronger anion emission ability, be compound in organosilicon crylic acid latex, ultra-oxygen anion free radical and hydroxyl free radical degradation of formaldehyde can not only be produced under light illumination, play sterilization, the effect of degradable organic pollutant, but also hardness and the intensity of film can be increased, have selected nano-calcium carbonate, process white, talcum powder, ground dolomite cooperation titanium dioxide, modified nano zinc oxide and opal as filler, the easy act energy of coating is improved while giving coating weathering resistance, resistance to acids and bases, reduce the permeability of film, enhance the weather resistance of film, opal in filler, titanium dioxide, modified nano zinc oxide can transmitting anions, make coating have self-cleaning property, and further increase intensity and the hardness of coating, bamboo vinegar liquid has effect that is antibacterial, anti-oxidant, sterilization, joins in coating, enhances the anti-microbial property of coating, Folium Menthae extract is as natural antiseptic-germicide, join in coating and coordinate with nano titanium oxide/organosilicon crylic acid latex, titanium dioxide, modified nano zinc oxide, opal, the coating obtained has stronger anion emission ability, impart the ability of the high germ resistance of coating and degradation of organic substances, meet the requirement of environmental protection, in addition, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate coordinates as film coalescence aid with polyvalent alcohol, improves the frost resistance of coating while improving the film forming properties of coating, has widened the range of application of coating.
Carry out Performance Detection to germ resistance negative ion paint of the present invention, its detected result is as shown in the table:
Test item Detected result
State in a reservoir Without lump, stir after uniformly state
Appearance of film Smooth, uniform color
Application property Brush two roads accessible
Surface drying time ≤1.5h
Alkali resistance 24h is without exception
Abrasion resistance >=1200 times
Negative ion generation >=3150/cm 3×min
VOC volatile organic compounds ≤3.2g/L
Free formaldehyde ≤0.1g/kg
Soluble chromium ≤0.45mg/kg
Soluble cadmium ≤0.22mg/kg
Soluble mercury ≤0.24mg/kg
Dissoluble lead ≤0.076mg/kg
Low-temperature stability Never degenerate
Contrast ratio ≥0.9
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In a particular embodiment, germ resistance negative ion paint of the present invention, in its raw material, the weight part of nano titanium oxide/silicone-acrylic compound emulsion can be 38.4, 39.2, 40, 42, 47.6, 49, 51, 53, 56, 58, 59.4 parts, the weight part of titanium dioxide can be 20.8, 21, 23, 24, 25.6, 27, 29, 31, 34, 34.6 parts, the weight part of nano-calcium carbonate can be 3.4, 3.8, 4, 5.3, 5.78 parts, the weight part of process white can be 2.6, 2.8, 3.4, 3.7, 4, 4.3, 4.8, 5, 5.3, 5.74 parts, talcous weight part can be 3.2, 3.7, 3.9, 4, 4.3, 5.6, 5.8, 6.4, 6.7, 7, 7.3, 7.6 parts, the weight part of ground dolomite can be 3.4, 3.9, 4.5, 6, 6.7, 8.3, 8.7, 9, 9.3 parts, the weight part of bamboo vinegar liquid can be 3.4, 3.8, 4, 4.6, 4.8, 5, 5.3, 5.8, 6.4, 6.7, 7, 7.3, 7.8 parts, the weight part of modified nano zinc oxide can be 1.3, 2, 2.5, 2.9, 3.4, 3.8, 4, 4.6 parts, opaline weight part can be 1.3, 1.8, 2, 2.4, 2.7, 3.4, 3.6, 4, 4.5, 5.7 parts, the weight part of 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate can be 1.35, 1.4, 1.56, 1.6, 1.73 parts, the weight part of Folium Menthae extract can be 1.2, 1.45, 1.9, 2, 2.4, 2.56, 2.6, 2.75, 2.83 parts, the weight part of polyvalent alcohol can be 1.5, 2, 2.3, 3.4, 4.5, 4.8 parts, the weight part of fire retardant can be 0.34, 0.42, 0.6, 0.67, 0.83, 0.9, 1.13 parts, the weight part of thickening material can be 0.26, 0.34, 0.4, 0.53, 0.67, 0.7, 0.73, 0.78 part, the weight part of sanitas can be 0.13, 0.17, 0.24, 0.27, 0.28 part, the weight part of wetting agent can be 0.16, 0.23, 0.34, 0.45 part, the weight part of dispersion agent can be 0.13, 0.2, 0.26, 0.3, 0.34, 0.4, 0.45 part, the weight part of water can be 10.5, 11, 11.6, 13, 14.5 parts.
Embodiment 1
Germ resistance negative ion paint of the present invention, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 35 parts, titanium dioxide 35 parts, nano-calcium carbonate 3 parts, process white 6 parts, talcum powder 3 parts, ground dolomite 10 parts, bamboo vinegar liquid 3 parts, modified nano zinc oxide 5 parts, 1 part, opal, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.8 parts, Folium Menthae extract 1 part, polyvalent alcohol 5 parts, fire retardant 0.3 part, thickening material 0.8 part, sanitas 0.1 part, wetting agent 0.5 part, dispersion agent 0.1 part, 15 parts, water.
Embodiment 2
Germ resistance negative ion paint of the present invention, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 60 parts, titanium dioxide 20 parts, nano-calcium carbonate 6 parts, process white 2 parts, talcum powder 8 parts, ground dolomite 3 parts, bamboo vinegar liquid 8 parts, modified nano zinc oxide 1 part, 6 parts, opal, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.2 parts, Folium Menthae extract 3 parts, polyvalent alcohol 1 part, fire retardant 1.2 parts, thickening material 0.2 part, sanitas 0.3 part, wetting agent 0.1 part, dispersion agent 0.5 part, 10 parts, water;
Wherein, the properties-correcting agent of described modified nano zinc oxide is stearic acid; Described polyvalent alcohol is that tetramethylolmethane, glycerol are by the mixture of 1:2 weight ratio; Described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:3:1 weight ratio; Described thickening material is Walocel MT 20.000PV; Described dispersion agent is trolamine.
Embodiment 3
Germ resistance negative ion paint of the present invention, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 45 parts, titanium dioxide 32 parts, nano-calcium carbonate 4.5 parts, process white 4.6 parts, talcum powder 4.5 parts, ground dolomite 9.5 parts, bamboo vinegar liquid 5.6 parts, modified nano zinc oxide 3.5 parts, 3 parts, opal, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.8 parts, Folium Menthae extract 1.5 parts, polyvalent alcohol 4 parts, fire retardant 0.5 part, thickening material 0.8 part, sanitas 0.15 part, wetting agent 0.4 part, dispersion agent 0.18 part, 12 parts, water;
Wherein, the properties-correcting agent of described modified nano zinc oxide is that silane coupling agent, trolamine are by the mixture of 1:5 weight ratio; Described polyvalent alcohol is tetramethylolmethane; Described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:4:1 weight ratio; Described thickening material is that Walocel MT 20.000PV, Natvosol are by the mixture of any weight ratio; Described dispersion agent is polyvinylpyrrolidone.
Embodiment 4
Germ resistance negative ion paint of the present invention, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 52 parts, titanium dioxide 28 parts, nano-calcium carbonate 5.6 parts, process white 3 parts, talcum powder 6 parts, ground dolomite 8 parts, bamboo vinegar liquid 6.5 parts, modified nano zinc oxide 1.8 parts, 5 parts, opal, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.5 parts, Folium Menthae extract 2.3 parts, polyvalent alcohol 2.5 parts, fire retardant 1.0 parts, thickening material 0.5 part, sanitas 0.23 part, wetting agent 0.25 part, dispersion agent 0.35 part, 14 parts, water;
Wherein, the properties-correcting agent of described modified nano zinc oxide is that stearic acid, silane coupling agent, trolamine, diisopropanolamine (DIPA) are by the mixture of 1:4:3:2 weight ratio; Described polyvalent alcohol is that tetramethylolmethane, glycerol, polyvinyl alcohol, polyoxyethylene glycol, dipentaerythritol are by the mixture of 1:2:5:3:2 weight ratio; Described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:3:3 weight ratio; Described thickening material is that Walocel MT 20.000PV, Natvosol are by the mixture of 1:5 weight ratio; Described dispersion agent is that trolamine, polyvinylpyrrolidone, sodium lauryl sulphate are by the mixture of 1:5:3 weight ratio.
Embodiment 5
Germ resistance negative ion paint of the present invention, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 56 parts, titanium dioxide 21 parts, nano-calcium carbonate 4 parts, process white 3.4 parts, talcum powder 6.7 parts, ground dolomite 8.3 parts, bamboo vinegar liquid 6.4 parts, modified nano zinc oxide 3.8 parts, 2.7 parts, opal, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1.4 parts, Folium Menthae extract 2 parts, polyvalent alcohol 3.4 parts, fire retardant 0.67 part, thickening material 0.26 part, sanitas 0.17 part, wetting agent 0.34 part, dispersion agent 0.13 part, 14.5 parts, water,
Wherein, the properties-correcting agent of described modified nano zinc oxide is trolamine; Described polyvalent alcohol is polyoxyethylene glycol; Described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:4:3 weight ratio; Described thickening material is Walocel MT 20.000PV; Described dispersion agent is sodium lauryl sulphate.
Embodiment 6
Germ resistance negative ion paint of the present invention, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 48 parts, titanium dioxide 30 parts, nano-calcium carbonate 5 parts, process white 3.8 parts, talcum powder 5 parts, ground dolomite 8.5 parts, bamboo vinegar liquid 6 parts, modified nano zinc oxide 3 parts, 3.8 parts, opal, 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate 1.5 parts, Folium Menthae extract 1.8 parts, polyvalent alcohol 3 parts, fire retardant 0.8 part, thickening material 0.6 part, sanitas 0.2 part, wetting agent 0.3 part, dispersion agent 0.25 part, 12 parts, water;
Wherein, the properties-correcting agent of described modified nano zinc oxide is that stearic acid, silane coupling agent, trolamine, diisopropanolamine (DIPA) are by the mixture of any weight ratio; Described polyvalent alcohol is that tetramethylolmethane, glycerol, polyvinyl alcohol, polyoxyethylene glycol, dipentaerythritol are by the mixture of any weight ratio; Described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:3:2 weight ratio; Described thickening material is that Walocel MT 20.000PV, Natvosol are by the mixture of any weight ratio; Described dispersion agent is that trolamine, polyvinylpyrrolidone, sodium lauryl sulphate are by the mixture of any weight ratio.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (8)

1. a germ resistance negative ion paint, it is characterized in that, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 35-60 part, titanium dioxide 20-35 part, nano-calcium carbonate 3-6 part, process white 2-6 part, talcum powder 3-8 part, ground dolomite 3-10 part, bamboo vinegar liquid 3-8 part, modified nano zinc oxide 1-5 part, opal 1-6 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1.2-1.8 part, Folium Menthae extract 1-3 part, polyvalent alcohol 1-5 part, fire retardant 0.3-1.2 part, thickening material 0.2-0.8 part, sanitas 0.1-0.3 part, wetting agent 0.1-0.5 part, dispersion agent 0.1-0.5 part, water 10-15 part.
2. germ resistance negative ion paint according to claim 1, it is characterized in that, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 45-52 part, titanium dioxide 28-32 part, nano-calcium carbonate 4.5-5.6 part, process white 3-4.6 part, talcum powder 4.5-6 part, ground dolomite 8-9.5 part, bamboo vinegar liquid 5.6-6.5 part, modified nano zinc oxide 1.8-3.5 part, opal 3-5 part, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1.5-1.8 part, Folium Menthae extract 1.5-2.3 part, polyvalent alcohol 2.5-4 part, fire retardant 0.5-1.0 part, thickening material 0.5-0.8 part, sanitas 0.15-0.23 part, wetting agent 0.25-0.4 part, dispersion agent 0.18-0.35 part, water 12-14 part.
3. germ resistance negative ion paint according to claim 1 or 2, it is characterized in that, its raw material comprises following component by weight: nano titanium oxide/silicone-acrylic compound emulsion 48 parts, titanium dioxide 30 parts, nano-calcium carbonate 5 parts, process white 3.8 parts, talcum powder 5 parts, ground dolomite 8.5 parts, bamboo vinegar liquid 6 parts, modified nano zinc oxide 3 parts, 3.8 parts, opal, 2, 2, 4-trimethylammonium-1, 3-pentanediol mono isobutyrate 1.5 parts, Folium Menthae extract 1.8 parts, polyvalent alcohol 3 parts, fire retardant 0.8 part, thickening material 0.6 part, sanitas 0.2 part, wetting agent 0.3 part, dispersion agent 0.25 part, 12 parts, water.
4. germ resistance negative ion paint according to any one of claim 1-3, is characterized in that, the properties-correcting agent of described modified nano zinc oxide is one or more the mixture in stearic acid, silane coupling agent, trolamine, diisopropanolamine (DIPA).
5. germ resistance negative ion paint according to any one of claim 1-4, is characterized in that, described polyvalent alcohol is one or more the mixture in tetramethylolmethane, glycerol, polyvinyl alcohol, polyoxyethylene glycol, dipentaerythritol.
6. germ resistance negative ion paint according to any one of claim 1-5, is characterized in that, described fire retardant is that nano-sized magnesium hydroxide, red phosphorus, ammonium polyphosphate are by the mixture of 1:3-4:1-3 weight ratio.
7. germ resistance negative ion paint according to any one of claim 1-6, is characterized in that, described thickening material is the mixture of a kind of in Walocel MT 20.000PV, Natvosol or two kinds.
8. germ resistance negative ion paint according to any one of claim 1-7, is characterized in that, described dispersion agent is one or more the mixture in trolamine, polyvinylpyrrolidone, sodium lauryl sulphate.
CN201510026073.2A 2015-01-19 2015-01-19 Antibacterial anion paint Pending CN104629566A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817895A (en) * 2015-05-22 2015-08-05 展辰涂料集团股份有限公司 Natural deep-sea mineral clay latex paint and preparation method thereof
CN105256574A (en) * 2015-11-25 2016-01-20 绍兴市柯桥区原色纺织科技有限公司 Antibacterial flame-retardant coating for garment fabric
CN105421064A (en) * 2015-12-21 2016-03-23 绍兴水墨印象数码印花有限公司 Flame-retardant antibacterial coating for textile fabric
CN107217478A (en) * 2017-06-23 2017-09-29 太仓大唐化纤厂 A kind of chemical fibre used additives
CN107728339A (en) * 2017-11-06 2018-02-23 苏州菲博特环保科技有限公司 Negative-ion energy glasses
CN109260934A (en) * 2018-11-12 2019-01-25 大连正润环保工程有限公司 A kind of negative oxygen ion biology removes aldehyde taste removal integration paint formulation
CN115093754A (en) * 2022-07-13 2022-09-23 承德建元科技股份有限公司 Multifunctional composite reflective cooling coating and preparation method thereof

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CN1648178A (en) * 2004-01-19 2005-08-03 范存玉 Long action negative ion antiseptic function paint
CN1673288A (en) * 2004-12-16 2005-09-28 许绍凰 Nanometer bactericidal negative ion outer wall paint
CN1673289A (en) * 2004-12-16 2005-09-28 许绍凰 Nanometer negative ion outer wall paint
CN1760289A (en) * 2004-10-14 2006-04-19 大连振邦氟涂料股份有限公司 Emulsion coating of negative ion and preparation method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1648178A (en) * 2004-01-19 2005-08-03 范存玉 Long action negative ion antiseptic function paint
CN1760289A (en) * 2004-10-14 2006-04-19 大连振邦氟涂料股份有限公司 Emulsion coating of negative ion and preparation method
CN1673288A (en) * 2004-12-16 2005-09-28 许绍凰 Nanometer bactericidal negative ion outer wall paint
CN1673289A (en) * 2004-12-16 2005-09-28 许绍凰 Nanometer negative ion outer wall paint

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104817895A (en) * 2015-05-22 2015-08-05 展辰涂料集团股份有限公司 Natural deep-sea mineral clay latex paint and preparation method thereof
CN105256574A (en) * 2015-11-25 2016-01-20 绍兴市柯桥区原色纺织科技有限公司 Antibacterial flame-retardant coating for garment fabric
CN105421064A (en) * 2015-12-21 2016-03-23 绍兴水墨印象数码印花有限公司 Flame-retardant antibacterial coating for textile fabric
CN107217478A (en) * 2017-06-23 2017-09-29 太仓大唐化纤厂 A kind of chemical fibre used additives
CN107728339A (en) * 2017-11-06 2018-02-23 苏州菲博特环保科技有限公司 Negative-ion energy glasses
CN109260934A (en) * 2018-11-12 2019-01-25 大连正润环保工程有限公司 A kind of negative oxygen ion biology removes aldehyde taste removal integration paint formulation
CN115093754A (en) * 2022-07-13 2022-09-23 承德建元科技股份有限公司 Multifunctional composite reflective cooling coating and preparation method thereof
CN115093754B (en) * 2022-07-13 2024-03-22 承德建元科技股份有限公司 Multifunctional composite reflective cooling coating and preparation method thereof

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Application publication date: 20150520