CN103409023A - Aqueous high weather-proof matt exterior wall emulsion paint and preparation method thereof - Google Patents
Aqueous high weather-proof matt exterior wall emulsion paint and preparation method thereof Download PDFInfo
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- CN103409023A CN103409023A CN2013103509521A CN201310350952A CN103409023A CN 103409023 A CN103409023 A CN 103409023A CN 2013103509521 A CN2013103509521 A CN 2013103509521A CN 201310350952 A CN201310350952 A CN 201310350952A CN 103409023 A CN103409023 A CN 103409023A
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Abstract
The invention discloses an aqueous high weather-proof matt exterior wall emulsion paint and a preparation method thereof. The emulsion paint comprises the following components by weight: 30-40 parts of emulsion, 0.2-0.5 part of an organosilicone hydrophobic agent, 2-8 parts of diatomite, 4-7 parts of sericite powder, 20-25 parts of titanium dioxide, 6-14 parts of a calcium carbonate powder, 0.4-0.7 part of a dispersant, 0.1-0.3 part of a wetting agent, 0.3-0.6 part of a defoaming agent, 0.1-0.3 part of an antifreeze, 1.5-2 parts of a coalescing agent, 0.4-0.9 part of a thickening agent, 0.2-0.5 part of a leveling agent, 0.1-0.3 part of a preservative, 0.1-0.3 part of a mildew preventive and 20-30 parts of water. The preparation method provided by the present invention comprises steps of: pre-blending, grinding disperse, and addition of emulsion and auxiliary agent, etc. The aqueous high weather-proof matt exterior wall emulsion paint provided by the invention has advantages of soft texture, flattening and fine paint film surface, and soft matt effect.
Description
Technical field
The invention belongs to the exterior wall protection and decorate and use paint field, specifically inferior light exterior wall latex paint of a kind of aqueous high weather resistance and preparation method thereof.
Background technology
According to the statistics made by the departments concerned, in the market the inferior light emulsion paint of general water-based mainly by reducing emulsion content, the consumption that increases the powder of high oil number reduces gloss, although gloss gets off, the performance index such as weathering resistance, water tolerance, alkali resistance, washability have also descended thereupon.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides inferior light exterior wall latex paint of a kind of aqueous high weather resistance and preparation method thereof.
The inferior light exterior wall latex paint of a kind of aqueous high weather resistance is characterized in that its raw material by following parts by weight makes:
Emulsion 30-40
Organic silicon hydrophobic agent 0.2-0.5
Diatomite 2-8
Sericite in powder 4-7
Titanium dioxide 20-25
Dicalcium powder 6-14
Dispersion agent 0.4-0.7
Wetting agent 0.1-0.3
Defoamer 0.3-0.6
Frostproofer 0.1-0.3
Film coalescence aid 1.5-2
Thickening material 0.4-0.9
Flow agent 0.2-0.5
Sanitas 0.1-0.3
Mould inhibitor 0.1-0.3
Water 20-30.
The inferior light exterior wall latex paint of described a kind of aqueous high weather resistance, is characterized in that described emulsion is pure-acrylic emulsion.
The inferior light exterior wall latex paint of described a kind of aqueous high weather resistance, is characterized in that described diatomite is silicastone.
The inferior light exterior wall latex paint of described a kind of aqueous high weather resistance, is characterized in that described organic silicon hydrophobic agent is the aqueous solution of potassium methyl silicate.
The inferior light exterior wall latex paint of described aqueous high weather resistance, is characterized in that described dispersion agent is hydrophobically modified ammonium polyacrylate dipersant; Wetting agent is ethoxylation class wetting agent; Defoamer is mineral oil defoaming agent; Frostproofer is zero VOC class freeze-thaw stabiliser; Thickening material is cellulose thickener and acrylic thickener; Sanitas is 1.2-benzisothiazole-3-ketone sanitas; Mould inhibitor is IPBC class mould inhibitor.
The inferior light exterior wall latex paint of described aqueous high weather resistance, is characterized in that described cellulose thickener is Natvosol class thickening material, and described acrylic thickener is alkali swelling associative thickener.
The preparation method of the inferior light exterior wall latex paint of a kind of aqueous high weather resistance is characterized in that comprising the following steps:
1) pre-mixing: add the water of 20～25 weight parts in disperseing cylinder, add again respectively dispersion agent, wetting agent, the defoamer of 0.1～0.3 weight part, cellulose thickener, fully the jellied material of mix and blend shape;
2) grinding distribution: in disperseing cylinder, add titanium dioxide, diatomite, sericite in powder, dicalcium powder, making beating was ground 20～25 minutes, looked into the survey fineness and was less than 60um:
3) add emulsion: in disperseing cylinder, add the water of 3～5 weight parts, then add sanitas, mould inhibitor, then add emulsion, organic silicon hydrophobic agent, be uniformly mixed;
4) add auxiliary agent: in disperseing cylinder, add successively the defoamer of remaining water, acrylic thickener, frostproofer, remainder, be uniformly mixed.
The preparation method of the inferior light exterior wall latex paint of described aqueous high weather resistance, the rotating speed that it is characterized in that mix and blend in step 1) is 300～500RPM; Step 2) rotating speed that in, making beating is ground is 2000～3000RPM; The rotating speed be uniformly mixed in step 3) and step 4) is 800～1200 RPM.
The model of the production that described organic silicon hydrophobic agent can be German Wacker Chemical Co.,Ltd is BS16, can improve sticking power and water tolerance.
Described diatomite can be that U.S. world mineral products company produces, and model celite 495, control film coated surface gloss that can be balanced.
Described sericite in powder can be that Chuzhou City ten thousand bridge sericite in powder factories produce, and model C J-A4 can significantly extend work-ing life of coating.
Described filmogen adopts pure the third low gloss emulsion, can be that the model that Dow Chemical produces is pure the third low gloss emulsion of TX-200.
Described dispersion agent adopts the dispersion agent of hydrophobically modified co-poly carboxylic acid salt, and the model that can select Dow Chemical to produce is the dispersion agent of 731A.This dispersion agent hangs down smell, and dispersion efficiency is high, improves enough interionic charge repulsions and sterically hindered, can thoroughly solve the problem of layering and caking.
Described wetting agent adopts the wetting agent of ethoxylation class, can be that the model that U.S. Air Prod & Chem produces is the wetting agent of Carbowet 13-40.
Described defoamer adopts mineral oil defoaming agent, can be that the model that French Rhodia produces is the defoamer of DF681F, and the consistency of this defoamer and this formula is good.
Described cellulose thickener adopts Natvosol class thickening material, can be that the model that U.S. Ya Kualong company produces is the thickening material of HBR250, and this thickening material and system compatible stability are good, stable viscosity after storing.
Described acrylic thickener is hydrophobic alkali swelling associative thickener, can be that the model that Dow Chemical produces is the thickening material of TT935, can provide levelling property and package stability preferably for system.
Described flow agent adopts the polyurethanes flow agent, can be that the model that Dow Chemical produces is the flow agent of RM-2020NPR.
Described mould inhibitor adopts IPBC (IPBC) class mould inhibitor, can select the model that U.S. Troy company produces is the mould inhibitor of polyphase PW40, and this mould inhibitor has zero VOC, low toxicity, without cutaneous sensibility, high chemical stability and system compatibility.
Described sanitas adopts 1.2-benzisothiazole-3-ketone (BIT) class sanitas, and the model that can select Dow Chemical to produce is the sanitas of BIT 20 LE.
Described film coalescence aid can alcohol ester 12 film coalescence aid, and can select U.S. Yi Si Man production model is the film coalescence aid of alcohol ester 12.
The FT-100 frostproofer that described frostproofer adopts French Rhodia to produce, this product belong to zero VOC product, and usage quantity is few, can effectively improve the freeze-thaw stability of system.
Described titanium dioxide adopts rutile-type, and the model that can adopt du pont company production is the titanium dioxide of R-902, and this titanium dioxide hiding rare is high, whiteness good, easily disperses.
The inferior light exterior wall latex paint of aqueous high weather resistance of the present invention, the inferior light exterior wall latex paint paint film texture on the market of comparing softens and feels well, coating surface is smooth, fine and smooth, and inferior light is gentle, and weathering resistance is better, sticking power is stronger.
Embodiment
Embodiment 1
Raw material by following parts by weight is made:
TX-200 40
BS-16 0.5
Celite 495 (diatomite) 2
CJ-A4 (sericite in powder) 7
R902 (titanium dioxide) 20
Dicalcium powder 6
731A (dispersion agent) 0.4
Carbowet 13-40 (wetting agent) 0.3
DF681F (defoamer) 0.5
The FT-100(frostproofer) 0.3
Alcohol ester 12 (film coalescence aid) 2
HBR250 (thickening material) 0.4
The RM-2020NPR(flow agent) 0.2
BIT 20 LE (sanitas) 0.2
Polyphase PW40(mould inhibitor) 0.2
Water 30
Preparation process is as follows:
One, pre-mixing: add the water of 25 parts in disperseing cylinder, the defoamer, film coalescence aid, propylene glycol frostproofer and the cellulose thickener that add again respectively above dispersion agent, wetting agent, 0.2 weight part, after fully mixing, the jellied material of shape, be beneficial to the dispersion of color stuffing, the rotating speed of mix and blend is controlled at 300～500RPM:
Two, grinding distribution: add titanium dioxide, diatomite, mica powder, coarse whiting in disperseing cylinder, at rotating speed, being controlled at making beating under 2000～3000RPM ground 20～25 minutes, it is qualified to look into when surveying fineness and being less than 50um, the color stuffing particle is under the high shear rate effect of high-speed stirring, be dispersed into precursor, and obtain the stably dispersing state under the effect of dispersing auxiliary system:
Three, add emulsion: after speed lapping disperses, add 4 weight parts waters and Antisepticize and mildew preventive in disperseing cylinder, then add benzene emulsion, mix, the stirring velocity of mixing is controlled at 800～1200 RPM:
Four, add auxiliary agent: in disperseing cylinder, add successively 0.3 weight part defoamer, flow agent and the FT-100 frostproofer of 1 remaining weight parts water, acrylic thickener, remainder, mix, the rotating speed of mix and blend is controlled at 800～1200 RPM.
Embodiment 2
Raw material by following parts by weight is made:
TX-200 31.5
BS-16 0.2
Celite 495 (diatomite) 8
CJ-A4 (sericite in powder) 6
R902 (titanium dioxide) 20
Dicalcium powder 10
731A (dispersion agent) 0.5
Carbowet 13-40 (wetting agent) 0.2
DF681F (defoamer) 0.3
The FT-100(frostproofer) 0.3
Alcohol ester 12 (film coalescence aid) 1.5
HBR250 (thickening material) 0.7
The RM-2020NPR(flow agent) 0.5
BIT 20 LE (sanitas) 0.2
Polyphase PW40(mould inhibitor) 0.2
Water 25
Preparation process is as follows:
One, pre-mixing: add the water of 20 parts in disperseing cylinder, the defoamer, film coalescence aid, propylene glycol frostproofer and the cellulose thickener that add again respectively above dispersion agent, wetting agent, 0.2 weight part, after fully mixing, the jellied material of shape, be beneficial to the dispersion of color stuffing, the rotating speed of mix and blend is controlled at 300～500RPM:
Two, grinding distribution: add titanium dioxide, diatomite, mica powder, coarse whiting in disperseing cylinder, at rotating speed, being controlled at making beating under 2000～3000RPM ground 20～25 minutes, it is qualified to look into when surveying fineness and being less than 50um, the color stuffing particle is under the high shear rate effect of high-speed stirring, be dispersed into precursor, and obtain the stably dispersing state under the effect of dispersing auxiliary system:
Three, add emulsion: after speed lapping disperses, add 3 weight parts waters and Antisepticize and mildew preventive in disperseing cylinder, then add benzene emulsion, mix, the stirring velocity of mixing is controlled at 800～1200 RPM:
Four, add auxiliary agent: in disperseing cylinder, add successively 0.1 weight part defoamer, flow agent and the FT-100 frostproofer of 2 remaining weight parts waters, acrylic thickener, remainder, mix, the rotating speed of mix and blend is controlled at 800～1200 RPM.
Embodiment 3
Raw material by following parts by weight is made:
TX-200 35
BS-16 0.3
Celite 495 (diatomite) 6
CJ-A4 (sericite in powder) 7
R902 (titanium dioxide) 21
Dicalcium powder 6
731A (dispersion agent) 0.7
Carbowet 13-40 (wetting agent) 0.3
DF681F (defoamer) 0.5
The FT-100(frostproofer) 0.1
Alcohol ester 12 (film coalescence aid) 1.7
HBR250 (thickening material) 0.6
The RM-2020NPR(flow agent) 0.4
BIT 20 LE (sanitas) 0.3
Polyphase PW40(mould inhibitor) 0.1
Water 24
Preparation process is as follows:
One, pre-mixing: add the water of 18 parts in disperseing cylinder, the defoamer, film coalescence aid, propylene glycol frostproofer and the cellulose thickener that add again respectively above dispersion agent, wetting agent, 0.3 weight part, after fully mixing, the jellied material of shape, be beneficial to the dispersion of color stuffing, the rotating speed of mix and blend is controlled at 300～500RPM:
Two, grinding distribution: add titanium dioxide, diatomite, mica powder, coarse whiting in disperseing cylinder, at rotating speed, being controlled at making beating under 2000～3000RPM ground 20～25 minutes, it is qualified to look into when surveying fineness and being less than 50um, the color stuffing particle is under the high shear rate effect of high-speed stirring, be dispersed into precursor, and obtain the stably dispersing state under the effect of dispersing auxiliary system:
Three, add emulsion: after speed lapping disperses, add 4 weight parts waters and Antisepticize and mildew preventive in disperseing cylinder, then add benzene emulsion, mix, the stirring velocity of mixing is controlled at 800～1200 RPM:
Four, add auxiliary agent: in disperseing cylinder, add successively 0.2 weight part defoamer, flow agent and the FT-100 frostproofer of 2 remaining weight parts waters, acrylic thickener, remainder, mix, the rotating speed of mix and blend is controlled at 800～1200 RPM.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all being included in protection scope of the present invention.
Claims (8)
1. the inferior light exterior wall latex paint of an aqueous high weather resistance is characterized in that its raw material by following parts by weight makes:
Emulsion 30-40
Organic silicon hydrophobic agent 0.2-0.5
Diatomite 2-8
Sericite in powder 4-7
Titanium dioxide 20-25
Dicalcium powder 6-14
Dispersion agent 0.4-0.7
Wetting agent 0.1-0.3
Defoamer 0.3-0.6
Frostproofer 0.1-0.3
Film coalescence aid 1.5-2
Thickening material 0.4-0.9
Flow agent 0.2-0.5
Sanitas 0.1-0.3
Mould inhibitor 0.1-0.3
Water 20-30.
2. the inferior light exterior wall latex paint of a kind of aqueous high weather resistance as claimed in claim 1, is characterized in that described emulsion is pure-acrylic emulsion.
3. the inferior light exterior wall latex paint of a kind of aqueous high weather resistance as claimed in claim 1, is characterized in that described diatomite is silicastone.
4. the inferior light exterior wall latex paint of a kind of aqueous high weather resistance as claimed in claim 1, is characterized in that described organic silicon hydrophobic agent is the aqueous solution of potassium methyl silicate.
5. the inferior light exterior wall latex paint of aqueous high weather resistance as claimed in claim 1, is characterized in that described dispersion agent is hydrophobically modified ammonium polyacrylate dipersant; Wetting agent is ethoxylation class wetting agent; Defoamer is mineral oil defoaming agent; Frostproofer is zero VOC class freeze-thaw stabiliser; Thickening material is cellulose thickener and acrylic thickener; Sanitas is 1.2-benzisothiazole-3-ketone sanitas; Mould inhibitor is IPBC class mould inhibitor.
6. the inferior light exterior wall latex paint of aqueous high weather resistance as claimed in claim 5, is characterized in that described cellulose thickener is Natvosol class thickening material, and described acrylic thickener is alkali swelling associative thickener.
7. the preparation method of the inferior light exterior wall latex paint of an aqueous high weather resistance is characterized in that comprising the following steps:
1) pre-mixing: add the water of 18～25 weight parts in disperseing cylinder, add again respectively dispersion agent, wetting agent, the defoamer of 0.1～0.3 weight part, cellulose thickener, fully the jellied material of mix and blend shape;
2) grinding distribution: in disperseing cylinder, add titanium dioxide, diatomite, sericite in powder, dicalcium powder, making beating was ground 20～25 minutes, looked into the survey fineness and was less than 60um:
3) add emulsion: in disperseing cylinder, add the water of 3～5 weight parts, then add sanitas, mould inhibitor, then add emulsion, organic silicon hydrophobic agent, be uniformly mixed;
4) add auxiliary agent: in disperseing cylinder, add successively the defoamer of remaining water, acrylic thickener, frostproofer, remainder, be uniformly mixed.
8. the preparation method of the inferior light exterior wall latex paint of aqueous high weather resistance as claimed in claim 7, the rotating speed that it is characterized in that mix and blend in step 1) is 300～500RPM; Step 2) rotating speed that in, making beating is ground is 2000～3000RPM; The rotating speed be uniformly mixed in step 3) and step 4) is 800～1200 RPM.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105219196A (en) * | 2015-10-13 | 2016-01-06 | 三棵树涂料股份有限公司 | There is the exterior coating of excellent open hour |
| CN105295636A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Building waterproof antifouling paint and preparation method thereof |
| CN105985684A (en) * | 2015-02-10 | 2016-10-05 | 北新集团建材股份有限公司 | Matte high-weatherability high-hydrophobicity exterior wall emulsion paint and preparation method thereof |
| CN106752919A (en) * | 2017-01-12 | 2017-05-31 | 重庆伊辰涂料有限公司 | Super antifouling paint of tempering and preparation method thereof |
| CN108102497A (en) * | 2018-01-05 | 2018-06-01 | 吕跃文 | Aqueous forest negative oxygen ion exterior coating and preparation method thereof |
| FR3065861A1 (en) * | 2017-05-04 | 2018-11-09 | Hbco Herbals And Bio Chemicals Outsourcing | USE OF MONOMETHYLSILANETRIOL AND / OR ITS SALTS TO PROTECT CROPS |
| CN109554933A (en) * | 2018-12-13 | 2019-04-02 | 成都巴德富科技有限公司 | A kind of aqueous dumb light high durable environmental protection painting canvas coating material and preparation method thereof |
| CN112852302A (en) * | 2021-01-13 | 2021-05-28 | 爱上佳环保新材料有限公司 | Anti-freezing diatom milk and preparation method thereof |
| CN115353785A (en) * | 2022-09-01 | 2022-11-18 | 龙牌涂料(北京)有限公司 | Preparation method and preparation system of interior wall latex paint without added preservative |
| CN116042029A (en) * | 2022-09-30 | 2023-05-02 | 上海凡瑞得新型建材有限公司 | Elastic external wall emulsion paint and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105985684A (en) * | 2015-02-10 | 2016-10-05 | 北新集团建材股份有限公司 | Matte high-weatherability high-hydrophobicity exterior wall emulsion paint and preparation method thereof |
| CN105219196A (en) * | 2015-10-13 | 2016-01-06 | 三棵树涂料股份有限公司 | There is the exterior coating of excellent open hour |
| CN105295636A (en) * | 2015-11-30 | 2016-02-03 | 桂林市和鑫防水装饰材料有限公司 | Building waterproof antifouling paint and preparation method thereof |
| CN106752919A (en) * | 2017-01-12 | 2017-05-31 | 重庆伊辰涂料有限公司 | Super antifouling paint of tempering and preparation method thereof |
| FR3065861A1 (en) * | 2017-05-04 | 2018-11-09 | Hbco Herbals And Bio Chemicals Outsourcing | USE OF MONOMETHYLSILANETRIOL AND / OR ITS SALTS TO PROTECT CROPS |
| CN108102497A (en) * | 2018-01-05 | 2018-06-01 | 吕跃文 | Aqueous forest negative oxygen ion exterior coating and preparation method thereof |
| CN109554933A (en) * | 2018-12-13 | 2019-04-02 | 成都巴德富科技有限公司 | A kind of aqueous dumb light high durable environmental protection painting canvas coating material and preparation method thereof |
| CN112852302A (en) * | 2021-01-13 | 2021-05-28 | 爱上佳环保新材料有限公司 | Anti-freezing diatom milk and preparation method thereof |
| CN115353785A (en) * | 2022-09-01 | 2022-11-18 | 龙牌涂料(北京)有限公司 | Preparation method and preparation system of interior wall latex paint without added preservative |
| CN116042029A (en) * | 2022-09-30 | 2023-05-02 | 上海凡瑞得新型建材有限公司 | Elastic external wall emulsion paint and preparation method thereof |
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Application publication date: 20131127 |