CN102504654A - Coating for children and preparation method thereof - Google Patents
Coating for children and preparation method thereof Download PDFInfo
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- CN102504654A CN102504654A CN2011103278443A CN201110327844A CN102504654A CN 102504654 A CN102504654 A CN 102504654A CN 2011103278443 A CN2011103278443 A CN 2011103278443A CN 201110327844 A CN201110327844 A CN 201110327844A CN 102504654 A CN102504654 A CN 102504654A
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Abstract
The invention provides a coating for children, which comprises the following components in parts by weight: 30-40 parts of volatile organic compounds (VOC)-free odorless emulsion, 6-10 parts of kieselguhr, 0.4-0.6 part of negative ion additive, 20-23 parts of titanium dioxide, 6-14 parts of heavy calcium powder, 0.4-0.7 part of dispersing agent, 0.1-0.3 part of wetting agent, 0.3-0.6 part of defoaming agent, 0.1-0.3 part of anti-freezing agent, 0.4-0.9 part of thickening agent, 0.1-0.2 part of preservative, 0.1-0.2 part of mildew preventive and 20-30 parts of tap water, wherein the thickening agent comprises 0.2-0.4 part of cellulose thickening agent and 0.2-0.5 part of acrylic acid thickening agent. The VOC content in the coating tends to zero. The coating is capable of adsorbing and removing harmful gases released from furniture and finishing materials and various indoor foreign odors, is capable of purifying indoor air and inhibiting bacterium and mould propagate, and has the effects of thermal insulation and noise reduction.
Description
Technical field
The present invention relates to interior wall protection and decoration and use paint field, be specifically related to a kind of children's coating and preparation method thereof.
Background technology
At present, to newborn infant or the tender skin of the children below 10 years old, to the high request of growing environment, young father and mother more and more pay attention to the feature of environmental protection of house decoration material.
According to the statistics made by the departments concerned; At present the upper respiratory tract infection that causes because of finishing pollution every year of China children that die that cause death have 800,000 approximately; Wherein children's below 10,000 years old the cause of the death is relevant with room air pollution more than 30, and particularly some newly-built and newly-decorated kindergartens and family room's environment pollution are very serious.And in children room finishing and finishing material, the hidden danger of coating and paint is maximum, and formaldehyde that it contains and benzene class material are the maximum killers of children's health, are the major reasons that causes childhood lymphoblastic leukemia and cancer; Comprise polyoxyethylene nonylphenol (NPEO) 80-85% among the APEO that contains (TX10 class); Polyoxyethylene octylphenol ether (OPEO) is more than 15%; Dodecyl phenol polyethenoxy ether (DPEO) and binonylphenol Soxylat A 25-7 (DNPEO) each 1%; APEO has similar female hormone effect, and meeting disruptive hormone secretion has very big harm to human body.
Yet dragons and fishes jumbled together for rubber-emulsion paint on the market, contain excess VOC (volatile organic compounds), APEO mostly, and scrub performance is poor, causes dry linting easily, is not suitable for children and uses.
Summary of the invention
The problem that the present invention solves is to provide a kind of children's coating, and VOC content goes to zero, and does not contain APEO, absorbs and decomposing formaldehyde.The present invention also provides the preparation method of this children's coating.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A kind of children's coating comprises the component of following weight part:
Said thickening material is cellulose thickener and acrylic thickener, and said cellulose thickener is 0.2-0.4 part, and said acrylic thickener is 0.2-0.5 part.
As preferably, said anionic additive is natural tourmalinite class anionic additive.
As preferably, said dispersion agent is polycarboxylate sodium's class dispersion agent.
As preferably, said wetting agent is an ethoxylation class wetting agent.
As preferably, said skimmer is tri-glyceride, alcohol ether and emulsifier mixture defoamer.
As preferably, said frostproofer is zero VOC class freeze-thaw stabiliser.
As preferably, said cellulose thickener is a Natvosol class thickening material.
As preferably, said acrylic thickener is an alkali swelling associative thickener.
As preferably, said sanitas is a 1.2-benzisothiazole-3-ketone sanitas.
As preferably, said mould inhibitor is an IPBC class mould inhibitor.
A kind of preparation method of children's coating may further comprise the steps:
Pre-mixing: in the water of 17～20 weight parts, add dispersion agent, wetting agent, 0.1-0.2 weight part skimmer, cellulose thickener respectively, thorough mixing;
Grind and disperse: in mixture, add white titanium pigment, zeyssatite, dicalcium powder again, making beating is ground to fineness≤60um;
Add emulsion: add 3～5 weight parts waters and sanitas, mould inhibitor in the mixture after grinding, add distinguish the flavor of only emulsion, anionic additive of zero VOC then and mix;
Add auxiliary agent: the skimmer, the frostproofer that in the mixture that obtains, add remaining water, acrylic thickener, remainder successively mix;
The parts by weight of each component are: the zero VOC emulsion 30-40 part of distinguishing the flavor of only, zeyssatite 6-10 part, anionic additive 0.4-0.6 part, white titanium pigment 20-23 part; Dicalcium powder 6-14 part, dispersion agent 0.4-0.7 part, wetting agent 0.1-0.3 part, skimmer 0.3-0.6 part; Frostproofer 0.1-0.3 part, cellulose thickener 0.2-0.4 part, acrylic thickener 0.2-0.5 part; Sanitas 0.1-0.2 part, mould inhibitor 0.1-0.2 part, tap water 20-30 part; Wherein fiber-like thickening material and acrylic thickener have 0.4-0.9 part altogether.
Use the zero VOC emulsion of distinguishing the flavor of only in children's coating provided by the invention, thereby make the VOC content in the coating go to zero, emulsion uses clean flavor technology to make coating realize clean flavor truly; Zeyssatite and anionic additive have also been added; Adsorbable and obnoxious flavoures such as the formaldehyde of dispeling from furniture, finishing material (sheet material, paint, sticker etc.) release, ammonia, benzene; Dispel various foreign flavor indoors; Purify the air of a room, the bacterium and the mould that suppress in metope and the room air grow, and also have effects such as heat insulating, reduction noise.
Embodiment
In order further to understand the present invention, below in conjunction with embodiment the preferred embodiment of the invention is described, describe just to further specifying feature and advantage of the present invention but should be appreciated that these, rather than to the restriction of claim of the present invention.
Children's coating of the present invention comprises the component of following weight part: the zero VOC emulsion 30-40 part of distinguishing the flavor of only, zeyssatite 6-10 part, anionic additive 0.4-0.6 part, white titanium pigment 20-23 part; Dicalcium powder 6-14 part, dispersion agent 0.4-0.7 part, wetting agent 0.1-0.3 part; Skimmer 0.3-0.6 part, frostproofer 0.1-0.3 part, thickening material 0.4-0.9 part; Sanitas 0.1-0.2 part, mould inhibitor 0.1-0.2 part, tap water 20-30 part; Said thickening material is cellulose thickener and acrylic thickener, and said cellulose thickener is 0.2-0.4 part, and said acrylic thickener is 0.2-0.5 part.
The present invention zero VOC model that emulsion can select for use Celanese Corp. to produce of distinguishing the flavor of only is the emulsion of Celvolit CP1788; This emulsion has lower minimum film-forming temperature (MFFT), zero VOC, does not contain APEO; Excellent scrub performance, and adopt clean flavor technology makes nontoxic, the environmental protection of coating.
Characteristics such as zeyssatite has exquisiteness, loose, light weight, porous, sorptive force and perviousness is strong and particle is tiny can be eliminated peculiar smell for a long time, keep the indoor wall cleaning for a long time; Can absorb obnoxious flavoures such as formaldehyde, ammonia, benzene, purify air; Make paint film ventilative; Thermal conductivity is low, and thermal and insulating performance is excellent; Has good sound insulation noise reduction effect.
The sustainable release of anionic additive is of value to the negative ion of HUMAN HEALTH, effectively dispels from furniture, finishing material (sheet material, paint, sticker etc.) obnoxious flavoures such as the formaldehyde that discharges, ammonia, benzene, dispels various foreign flavor indoors, purifies the air of a room; The bacterium and the mould that suppress in metope and the room air grow.The anionic additive function is lasting, safe in utilization, the performance of coating is had no adverse effects; The natural tourmalinite class anionic additive that is used for coating in the market all can use, and the model of producing like Beijing Lanno Environmental Protection Science & Technology Co., Ltd. is a HB-TL negative ion paint additive.
White titanium pigment is an optimal white pigment commonly used in the coating, and it has very high reflection potential and very low receptivity to visible light, and good lightness is arranged, and adopts rutile-type.
Dicalcium powder is a water-ground limestone, is used for coating and can makes not sedimentation of coating, be prone to dispersion, good luster, can adopt 800 orders or 1000 orders.
Dispersion agent can adopt the polycarboxylate sodium, has dissemination, can reduce mill base viscosity, improve coating stability in storage, increase gloss and leveling characteristics.The model of producing like the lucky Buddhist nun in German Bake company is the dispersion agent of LOPON 800; This dispersion agent is the clean flavor dispersion agent that VOC goes to zero; And dispersion efficiency is high, improves enough interionic charge repulsions and sterically hindered, can thoroughly solve the problem of layering and caking.
Wetting agent can reduce the finished product surface tension, makes color stuffing be more prone to wetting dispersion.The present invention selects the wetting agent of ethoxylation class for use, and the model of producing like U.S. Air Prod & Chem is the wetting agent of Carbowet 13-40, and this wetting agent has zero VOC and do not contain characteristics such as APE, and with the compatible stable height of this formula system.
Skimmer can prevent that coating from use producing foam; Avoid disadvantages such as bubble burst generation pin hole, shrinkage cavity in the dried coating film; The present invention selects tri-glyceride, alcohol ether and emulsifier mixture defoamer for use, and the model of producing like the lucky Buddhist nun in German Bake company is the skimmer of LOPON E81.This skimmer has characteristics such as zero VOC and clean flavor, and good with the consistency of this prescription, be not easy to occur the shrinkage cavity phenomenon, and defoaming effectiveness is high.
Frostproofer can prevent the coating sharp freezing, and the present invention selects zero VOC class freeze-thaw stabiliser for use, the frostproofer of the FT-100 that produces like French Rhodia, and this product belongs to zero VOC product, and usage quantity is few, can effectively improve the freeze-thaw stability of system.
Thickening material can improve the viscosity of dispersed material and be beneficial to dispersion, prevents that color stuffing from sinking to the bottom caking, improves paint stability.Thickening material of the present invention adopts cellulose thickener and acrylic thickener, and cellulose thickener can be selected Natvosol class thickening material for use, and is good with the system compatible stability, stores the back stable viscosity; Acrylic thickener is an alkali swelling associative thickener; The model of producing like Britain this special chemical company of sea name is the thickening material of RHEOLATE425; This thickening material is environment-friendly type, low smell, does not contain APE and VOC, can leveling characteristics and package stability preferably be provided for system.
Sanitas of the present invention adopts 1.2-benzisothiazole-3-ketone (BIT) sanitas; But sterilization and anticorrosion, not release formaldehyde, non-volatile, good stability, the model of producing like Dow Chemical is the sanitas of BT NV2; This sanitas is a zero VOC broad-spectrum sterilization anticorrosive additive
Mould inhibitor adopts IPBC (3-iodo-2-propynyl butyl carbamate) type mould inhibitor; IPBC is a kind of iodine Antimicrobe compound that contains; Be a kind of effective mildew-resistant and anti-algae chemical assistant and good environment arranged and toxicity report is described; Be that the whole world is used for one of most important industrial bactericide of coating protecting, the model of producing like U.S. Troy company is the mould inhibitor of polyphase PW40, and this mould inhibitor has zero VOC, low toxicity, no cutaneous sensibility, high chemical stability and system compatibility.
The preparation method of children's coating provided by the invention may further comprise the steps:
Pre-mixing: in the water of 17～20 weight parts, add dispersion agent, wetting agent, 0.1-0.2 weight part skimmer and cellulose thickener respectively; Thorough mixing forms the dispersion that gelationus material is beneficial to color stuffing, and the controllable rotation speed of mixing stirring is built in 300～500RPM;
Grind and disperse: in mixture, add white titanium pigment, zeyssatite, dicalcium powder again; Can rotating speed be controlled to pull an oar under 2000～3000RPM and grind 20～25 minutes; Look into that to survey making beating qualified when being ground to fineness≤60um; The color stuffing particle is dispersed into simple particle under the high shear rate effect of high-speed stirring, and under the effect of dispersing auxiliary system, obtains the stably dispersing state;
Add emulsion: grind at a high speed disperse after, in mixture, add 3～5 weight parts waters and sanitas, mould inhibitor, add distinguish the flavor of only emulsion, anionic additive of zero VOC then and mix, the blended stirring velocity can be controlled in 800～1200RPM;
Add auxiliary agent: the skimmer, the frostproofer that in above mixture, add remaining water, acrylic thickener, remainder successively mix, and the controllable rotation speed that mixing is stirred is built in 800～1200RPM.
Embodiment 1:
Raw material comprises:
Functional materials: distinguish the flavor of only 33 parts of emulsions of Celvolit CP 1,788 zero VOC,
The model that U.S. world's mineral products company produces is 7 parts in the zeyssatite of celite 495,
The model that Beijing Lanno Environmental Protection Science & Technology Co., Ltd. produces is 0.5 part of a HB-TL negative ion paint additive,
Color stuffing: the model of du pont company production is 22 parts of the white titanium pigments of R-706, and the model that wide Fujian material company produces is 8 parts of the dicalcium powders of CC-1000,
Auxiliary agent: the model that the lucky Buddhist nun in German Bake company produces is 0.5 part of the dispersion agent of LOPON 800,
The model that U.S. Air Prod & Chem produces is 0.1 part of the wetting agent of Carbowet 13-40,
The model that Germany Bake lucky Buddhist nun company produces is 0.3 part of the skimmer of LOPON E81,
France's Rhodia production model is 0.15 part of the frostproofer of FT-100,
The model that Dow Chemical produces is 0.35 part of the thickening material of QP30000H,
The model that this special chemical company of state's sea name produces is 0.5 part of the thickening material of RHEOLATE425,
The model that Dow Chemical produces is 0.15 part of a BT NV2 sanitas,
The model that U.S. Troy company produces is 0.1 part of the mould inhibitor of polyphase PW40,27 parts in tap water.
The water that in disperseing cylinder, adds 20 parts adds above dispersion agent, wetting agent, 0.1 part of skimmer and cellulose thickener respectively again, and thorough mixing forms gelationus material, mixes the rotating speed that stirs and is controlled at 500RPM:
In disperseing cylinder, add white titanium pigment, zeyssatite, dicalcium powder, be controlled to pull an oar under the 2500RPM at rotating speed and ground 25 minutes, looking into and surveying fineness is 55um:
In disperseing cylinder, add 5 parts of water and sanitas, mould inhibitor again, add distinguish the flavor of only emulsion, anionic additive of zero VOC then and mix, mix, stirring velocity is controlled at 1000RPM:
0.2 part of skimmer, frostproofer in disperseing cylinder, adding 2 parts of remaining water, acrylic thickener, remainder successively mix, and mix the rotating speed that stirs and are controlled at 1200RPM, and the coating preparation is accomplished.
Embodiment 2:
Raw material comprises:
Functional materials: distinguish the flavor of only 40 parts of emulsions of Celvolit CP 1,788 zero VOC,
8 parts in celite 495 zeyssatite,
0.4 part of HB-TL negative ion paint additive,
Color stuffing: 21 parts of R-706 white titanium pigments,
10 parts of CC-1000 dicalcium powders,
0.6 part of auxiliary agent: LOPON 800 dispersion agent,
0.2 part of Carbowet 13-40 wetting agent,
0.6 part of LOPON E81 skimmer,
0.1 part of FT-100 frostproofer,
0.2 part of QP30000H thickening material,
0.4 part of RHEOLATE425 thickening material,
0.2 part of BT NV2 sanitas,
0.2 part of polyphase PW40 mould inhibitor,
30 parts in tap water.
The water that in disperseing cylinder, adds 23 parts adds above dispersion agent, wetting agent, 0.2 part of skimmer and cellulose thickener respectively again, and thorough mixing forms gelationus material, mixes the rotating speed that stirs and is controlled at 450RPM:
In disperseing cylinder, add white titanium pigment, zeyssatite, dicalcium powder, be controlled to pull an oar under the 3000RPM at rotating speed and ground 22 minutes, looking into and surveying fineness is 53um:
In disperseing cylinder, add 4 parts of water and sanitas, mould inhibitor again, add distinguish the flavor of only emulsion, anionic additive of zero VOC then and mix, mix, stirring velocity is controlled at 1200RPM:
0.4 part of skimmer, frostproofer in disperseing cylinder, adding 3 parts of remaining water, acrylic thickener, remainder successively mix, and mix the rotating speed that stirs and are controlled at 1000RPM, and the coating preparation is accomplished.Children's coating to the embodiment of the invention 1,2 preparation detects, VOC content all＜1g/L, meet German blue sky fully and make environmental evidence.
More than children's coating provided by the present invention and preparation method thereof has been carried out detailed introduction.Used concrete example among this paper principle of the present invention and embodiment are set forth, the explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.
Claims (11)
1. children's coating is characterized in that, comprises the component of following weight part:
Said thickening material is cellulose thickener and acrylic thickener, and said cellulose thickener is 0.2-0.4 part, and said acrylic thickener is 0.2-0.5 part.
2. children's coating according to claim 1 is characterized in that, said anionic additive is natural tourmalinite class anionic additive.
3. children's coating according to claim 1 is characterized in that, said dispersion agent is polycarboxylate sodium's class dispersion agent.
4. children's coating according to claim 1 is characterized in that, said wetting agent is an ethoxylation class wetting agent.
5. children's coating according to claim 1 is characterized in that, said skimmer is tri-glyceride, alcohol ether and emulsifier mixture defoamer.
6. children's coating according to claim 1 is characterized in that, said frostproofer is zero VOC class freeze-thaw stabiliser.
7. children's coating according to claim 1 is characterized in that, said cellulose thickener is a Natvosol class thickening material.
8. children's coating according to claim 1 is characterized in that, said acrylic thickener is an alkali swelling associative thickener.
9. children's coating according to claim 1 is characterized in that, said sanitas is a 1.2-benzisothiazole-3-ketone sanitas.
10. children's coating according to claim 1 is characterized in that, said mould inhibitor is an IPBC class mould inhibitor.
11. the preparation method of children's coating is characterized in that, may further comprise the steps:
Pre-mixing: in the water of 17～20 weight parts, add dispersion agent, wetting agent, 0.1-0.2 weight part skimmer, cellulose thickener respectively, thorough mixing;
Grind and disperse: in mixture, add white titanium pigment, zeyssatite, dicalcium powder again, making beating is ground to fineness≤60um;
Add emulsion: add 3～5 weight parts waters and sanitas, mould inhibitor in the mixture after grinding, add distinguish the flavor of only emulsion, anionic additive of zero VOC then and mix;
Add auxiliary agent: the skimmer, the frostproofer that in the mixture that obtains, add remaining water, acrylic thickener, remainder successively mix;
The parts by weight of each component are: the zero VOC emulsion 30-40 part of distinguishing the flavor of only, zeyssatite 6-10 part, anionic additive 0.4-0.6 part, white titanium pigment 20-23 part; Dicalcium powder 6-14 part, dispersion agent 0.4-0.7 part, wetting agent 0.1-0.3 part, skimmer 0.3-0.6 part; Frostproofer 0.1-0.3 part, cellulose thickener 0.2-0.4 part, acrylic thickener 0.2-0.5 part; Sanitas 0.1-0.2 part, mould inhibitor 0.1-0.2 part, tap water 20-30 part; Wherein fiber-like thickening material and acrylic thickener have 0.4-0.9 part altogether.
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| CN102766405A (en) * | 2012-08-09 | 2012-11-07 | 浙江志强涂料有限公司 | Children coating and preparation method thereof |
| CN103131269A (en) * | 2012-08-06 | 2013-06-05 | 上海三银制漆有限公司 | Synthetic resin emulsion wall coating and preparation method thereof |
| CN103450761A (en) * | 2013-09-16 | 2013-12-18 | 深圳市宜丽环保科技有限公司 | Heat-insulation and heat-preservation water-based coating material with air purifying function |
| CN104119800A (en) * | 2014-07-15 | 2014-10-29 | 三棵树涂料股份有限公司 | Special-effect heath indoor wall aqueous paint composition and preparation method thereof |
| CN105176220A (en) * | 2015-10-28 | 2015-12-23 | 漳州三德利油漆涂料有限公司 | Synthetic latex diatom inner wall emulsion paint and preparation method thereof |
| CN105385266A (en) * | 2015-12-08 | 2016-03-09 | 云南昆惠能通科技有限公司 | Environment-friendly indoor multifunctional diatomite wall paint |
| CN105462380A (en) * | 2015-12-03 | 2016-04-06 | 三棵树涂料股份有限公司 | Economical deodorizing and mildew-proof wall paint and preparation method thereof |
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| CN102766405A (en) * | 2012-08-09 | 2012-11-07 | 浙江志强涂料有限公司 | Children coating and preparation method thereof |
| CN103450761A (en) * | 2013-09-16 | 2013-12-18 | 深圳市宜丽环保科技有限公司 | Heat-insulation and heat-preservation water-based coating material with air purifying function |
| CN103450761B (en) * | 2013-09-16 | 2015-10-28 | 深圳市宜丽环保科技有限公司 | A kind of heat-insulation thermal-insulation water-based paint with air purification function |
| CN104119800B (en) * | 2014-07-15 | 2017-12-08 | 三棵树涂料股份有限公司 | Water-based coating compositions of special efficacy health indoor wall and preparation method thereof |
| CN104119800A (en) * | 2014-07-15 | 2014-10-29 | 三棵树涂料股份有限公司 | Special-effect heath indoor wall aqueous paint composition and preparation method thereof |
| CN105176220A (en) * | 2015-10-28 | 2015-12-23 | 漳州三德利油漆涂料有限公司 | Synthetic latex diatom inner wall emulsion paint and preparation method thereof |
| CN105462380A (en) * | 2015-12-03 | 2016-04-06 | 三棵树涂料股份有限公司 | Economical deodorizing and mildew-proof wall paint and preparation method thereof |
| CN105385266A (en) * | 2015-12-08 | 2016-03-09 | 云南昆惠能通科技有限公司 | Environment-friendly indoor multifunctional diatomite wall paint |
| CN106147487A (en) * | 2016-08-18 | 2016-11-23 | 苏州大乘环保建材有限公司 | Interior anion is except methanal paint and preparation method thereof |
| CN106752919A (en) * | 2017-01-12 | 2017-05-31 | 重庆伊辰涂料有限公司 | Super antifouling paint of tempering and preparation method thereof |
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Application publication date: 20120620 |