CN102766405A - Children coating and preparation method thereof - Google Patents
Children coating and preparation method thereof Download PDFInfo
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- CN102766405A CN102766405A CN2012102821102A CN201210282110A CN102766405A CN 102766405 A CN102766405 A CN 102766405A CN 2012102821102 A CN2012102821102 A CN 2012102821102A CN 201210282110 A CN201210282110 A CN 201210282110A CN 102766405 A CN102766405 A CN 102766405A
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Abstract
The invention provides a children coating and a preparation method of the children coating. The children coating provided by the invention comprises the following raw materials: wood fibers, a purified emulsion, kieselguhr, an anion additive, titanium dioxide, triple superphosphate powder, a dispersing agent, a wetting agent, a defoaming agent, a thickening agent, a preservative, a mildew preventive and tap water and the like. The wood fibers are added into the environmentally-friendly children coating by the invention so as to change the structure and the texture of a surface of a paint film, thereby feeling soft and smooth; and in addition, the porosity of the paint film is improved by the wood fibers in the paint film, the breathable performance is good, the quantity of heat and the transmission capacity of voice are reduced, and a good humidifying function can be created by the gaps of the paint film.
Description
Technical field
The invention belongs to interior wall protection and decoration and use paint field, specifically is a kind of children's coating and preparation method thereof.
Background technology
According to the statistics made by the departments concerned; At present the upper respiratory tract infection that causes because of finishing pollution every year of China children that die that cause death have 800,000 approximately; Wherein children's below 10,000 years old the cause of the death is relevant with room air pollution more than 30, and particularly some newly-built and newly-decorated kindergartens and family room's environment pollution are very serious.And in children room finishing and finishing material, existing interior wall coating VOC content contain AEPO, and texture is ice-cold stiff than higher, and it is functional outstanding inadequately to lack aesthetic feeling.In temperature lower season, metope texture is ice-cold, and touch meeting lets the people not feel well, and feel is gentle inadequately refreshing.At plum rain season, because ambient moisture is bigger, dewfall appears in metope easily can't regulate indoor humidity.In addition, because existing metope paint film internal structure is closely knit, can't play the effect of sound-insulating and heat-insulating.Wallpaper then can contain formaldehyde, and VCO content also is not suitable for the children room finishing and uses than higher and easy mildew bacterium.
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Summary of the invention
The present invention is directed to the deficiency of existing interior wall children coating and wallpaper, provide a kind of texture gentle refreshing, can damping, heat insulation, sound insulation, absorption and decomposing formaldehyde, do not contain the gentle feel children coating of feeling well of APEO and low VOC.
Technical scheme of the present invention is following:
A kind of children's coating is characterized in that its raw material by following parts by weight processes:
Wood fibre 1-4 part
Clean flavor emulsion 30-40 part
Zeyssatite 5-9 part
Anionic additive 0.4-0.6 part
White titanium pigment 20-25 part
Dicalcium powder 6-14 part
Dispersion agent 0.4-0.7 part
Wetting agent 0.1-0.3 part
Skimmer 0.3-0.6 part
Frostproofer 0.1-0.3 part
Thickening material 0.4-0.9 part
Sanitas 0.1-0.2 part
Mould inhibitor 0.1-0.2 part
Tap water 20-30 part.
Described children's coating is characterized in that its raw material by following parts by weight processes:
Wood fibre 1.5-2 part
Clean flavor emulsion 33-40 part
Zeyssatite 7-8 part
Anionic additive 0.4-0.5 part
White titanium pigment 21-23 part
Dicalcium powder 8-10 part
Dispersion agent 0.5-0.6 part
Wetting agent 0.1-0.2 part
Skimmer 0.3-0.6 part
Frostproofer 0.1-0.15 part
Thickening material 0.7-0.85 part
Sanitas 0.1-0.15 part
Mould inhibitor 0.1-0.2 part
Tap water 27-30 part.
Described children's coating is characterized in that said wood fibre is the natural organic after treatment wadding fibrous material of renewable timber.
Described children's coating is characterized in that said clean flavor emulsion is the zero VOC emulsion of distinguishing the flavor of only.
Described children's coating is characterized in that said anionic additive is natural tourmalinite class anionic additive.
Described children's coating is characterized in that said dispersion agent is polycarboxylate sodium's class dispersion agent; Wetting agent is an ethoxylation class wetting agent; Skimmer is a mineral oil defoaming agent; Frostproofer is zero VOC class freeze-thaw stabiliser; Thickening material is cellulose thickener or acrylic thickener; Sanitas is a 1.2-benzisothiazole-3-ketone sanitas; Mould inhibitor is an IPBC class mould inhibitor.
Described children's coating is characterized in that said cellulose thickener is a Natvosol class thickening material, and said acrylic thickener is an alkali swelling associative thickener.
The preparation method of described children's coating is characterized in that may further comprise the steps:
1) pre-mixing: in disperseing cylinder, add the water of 17～20 weight parts, add dispersion agent, wetting agent, the skimmer of 0.1～0.2 weight part, cellulose thickener respectively again, thorough mixing stirs and forms gelationus material;
2) grind dispersion: in disperseing cylinder, add white titanium pigment, wood fibre, zeyssatite, dicalcium powder; Making beating was ground 20～25 minutes; It is qualified to look into when surveying fineness and being less than 60um; The color stuffing particle is dispersed into simple particle under the high shear rate effect of high-speed stirring, and under the effect of dispersing auxiliary system, obtains the stably dispersing state:
3) add emulsion: in disperseing cylinder, add the water of 3～5 weight parts, add sanitas, mould inhibitor again, add clean flavor emulsion, anionic additive then, mix;
4) add auxiliary agent: in disperseing cylinder, add the skimmer of remaining water, acrylic thickener, frostproofer, remainder successively, mix.
The preparation method of described children's coating is characterized in that mixing the rotating speed that stirs in the step 1) is 300～500RPM; Step 2) rotating speed that making beating is ground in is 2000～3000RPM; The rotating speed that mixes in step 3) and the step 4) is 800～1200 RPM.
Distinguish the flavor of only model that emulsion can select for use Celanese Corp. to produce of the present invention is 1608 emulsion; This emulsion has lower minimum film-forming temperature (MFFT), zero VOC, does not contain APEO; Excellent scrub performance, and adopt clean flavor technology makes nontoxic, the environmental protection of coating.
Wood fibre has that proportion is little, specific surface area is big, has excellent insulating, heat insulation, sound insulation, insulation and permeability, and thermal expansion is not evenly flaked and do not ftractureed, and improves the effect of paint film feel.Characteristics such as zeyssatite has exquisiteness, loose, light weight, porous, sorptive force and perviousness is strong and particle is tiny can be eliminated peculiar smell for a long time, keep the indoor wall cleaning for a long time; Can absorb obnoxious flavoures such as formaldehyde, ammonia, benzene, purify air; Make paint film ventilative; Thermal conductivity is low, and thermal and insulating performance is excellent; Has good sound insulation noise reduction effect.
The sustainable release of anionic additive is of value to the negative ion of HUMAN HEALTH, effectively dispels from furniture, finishing material (sheet material, paint, sticker etc.) obnoxious flavoures such as the formaldehyde that discharges, ammonia, benzene, dispels various foreign flavor indoors, purifies the air of a room; The bacterium and the mould that suppress in metope and the room air grow.The anionic additive function is lasting, safe in utilization, the performance of coating is had no adverse effects; The natural tourmalinite class anionic additive that is used for coating in the market all can use, and the model of producing like Beijing Lanno Environmental Protection Science & Technology Co., Ltd. is a HB-TL negative ion paint additive.
White titanium pigment is an optimal white pigment commonly used in the coating, and it has very high reflection potential and very low receptivity to visible light, and good lightness is arranged, and adopts rutile-type.
Dicalcium powder is a water-ground limestone, is used for coating and can makes not sedimentation of coating, be prone to dispersion, good luster, can adopt 800 orders or 1000 orders.
Dispersion agent can adopt the polycarboxylate sodium, has dissemination, can reduce mill base viscosity, improve coating stability in storage, increase gloss and leveling characteristics.The model of producing like the lucky Buddhist nun in German Bake company is the dispersion agent of LOPON 800; This dispersion agent is the clean flavor dispersion agent that VOC goes to zero; And dispersion efficiency is high, improves enough interionic charge repulsions and sterically hindered, can thoroughly solve the problem of layering and caking.
Wetting agent can reduce the finished product surface tension, makes color stuffing be more prone to wetting dispersion.The present invention selects the wetting agent of ethoxylation class for use, and the model of producing like U.S. Air Prod & Chem is the wetting agent of Carbowet 13-40, and this wetting agent has zero VOC and do not contain characteristics such as APE, and with the compatible stable height of this formula system.
Skimmer can prevent that coating from use producing foam, avoids disadvantages such as bubble burst generation pin hole, shrinkage cavity in the dried coating film, and the present invention selects mineral oil defoaming agent for use, like the skimmer of the AV1425 of U.S. Ya Shilan company.This skimmer has zero VOC, and good with the consistency of this prescription, is not easy to occur the shrinkage cavity phenomenon, and defoaming effectiveness is high.
Frostproofer can prevent the coating sharp freezing, and the present invention selects zero VOC class freeze-thaw stabiliser for use, the frostproofer of the FT-100 that produces like French Rhodia, and this product belongs to zero VOC product, and usage quantity is few, can effectively improve the freeze-thaw stability of system.
Thickening material can improve the viscosity of dispersed material and be beneficial to dispersion, prevents that color stuffing from sinking to the bottom caking, improves paint stability.Thickening material of the present invention adopts cellulose thickener and acrylic thickener, and cellulose thickener can be selected Natvosol class thickening material for use, and is good with the system compatible stability, stores the back stable viscosity; Acrylic thickener is an alkali swelling associative thickener; The model of producing like Britain this special chemical company of sea name is the thickening material of RHEOLATE425; This thickening material is environment-friendly type, low smell, does not contain APE and VOC, can leveling characteristics and package stability preferably be provided for system.
Sanitas of the present invention adopts 1.2-benzisothiazole-3-ketone (BIT) sanitas; But sterilization and anticorrosion; Not release formaldehyde, non-volatile, good stability, the model of producing like Dow Chemical is the sanitas of BIT 20 LE, this sanitas is a zero VOC broad-spectrum sterilization anticorrosive additive; Requirement for the pH of formula system and temperature is all very wide in range, and BIT 20 LE that are made up of aqueous components fully still are a antisepsis and sterilization auxiliary agent that does not truly contain formaldehyde.
Mould inhibitor adopts 3-iodo-2-propynyl butyl carbamate (IPBC) type mould inhibitor; IPBC is a kind of iodine Antimicrobe compound that contains; Be a kind of effective mildew-resistant and anti-algae chemical assistant and good environment arranged and toxicity report is described; Be that the whole world is used for one of most important industrial bactericide of coating protecting; The model of producing like U.S. Troy company is the mould inhibitor of polyphase PW40, and this mould inhibitor has zero VOC, low toxicity, no cutaneous sensibility, high chemical stability and system compatibility.
Use the zero VOC emulsion of distinguishing the flavor of only in children's coating provided by the invention, thereby make the VOC content in the coating go to zero, emulsion uses clean flavor technology to make coating realize clean flavor truly; Wood fibre, zeyssatite and anionic additive have also been added; Adsorbable and obnoxious flavoures such as the formaldehyde of dispeling from furniture, finishing material (sheet material, paint, sticker etc.) release, ammonia, benzene; Dispel various foreign flavor indoors, purify the air of a room, the bacterium and the mould that suppress in metope and the room air grow; Also have heat insulating, reduce effects such as noise and adjusting humidity, also give paint film gentle refreshing feel simultaneously.
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Embodiment
Embodiment 1
Adopt the raw material of following parts by weight:
Functional materials:
33 parts of clean flavor emulsions (Celanese Corp. produces, model 1608)
2 parts of wood fibres (German Rui Dengmeier father and son company produces, model BE 600-10)
7 parts in zeyssatite (U.S. world's mineral products company produces, and model celite 495)
0.5 part of negative ion paint additive (Beijing Lanno Environmental Protection Science & Technology Co., Ltd. produces, model HB-TL)
Color stuffing:
23 parts of white titanium pigments (du pont company production, model R-706)
8 parts of dicalcium powders (wide Fujian material company produces model C C-1000)
Auxiliary agent:
0.5 part of dispersion agent (the lucky Buddhist nun in German Bake company produces, and model LOPON 800)
0.1 part of wetting agent (U.S. Air Prod & Chem produces, model C arbowet 13-40)
0.3 part of skimmer (U.S. Ya Shilan company produces, model AV1425)
0.15 part of frostproofer (French Rhodia produces, model FT-100)
0.3 part of thickening material (Dow Chemical produces, model QP30000H)
0.4 part of thickening material (Britain this special chemical company of sea name produces model RHEOLATE425)
0.1 part of sanitas (Dow Chemical produces, model BIT 20 LE)
0.1 part of mould inhibitor (U.S. Troy company produces, model polyphase PW40)
27 parts in tap water
The preparation method:
The water that in disperseing cylinder, adds 20 parts adds above dispersion agent, wetting agent, 0.1 part of skimmer and cellulose thickener respectively again, and thorough mixing forms gelationus material, mixes the rotating speed that stirs and is controlled at 500RPM:
In disperseing cylinder, add white titanium pigment, wood fibre, zeyssatite, dicalcium powder, be controlled to pull an oar under the 2500RPM at rotating speed and ground 25 minutes, looking into and surveying fineness is 55um:
In disperseing cylinder, add 5 parts of water and sanitas, mould inhibitor again, the clean flavor of interpolation emulsion, anionic additive mix then, mix, and stirring velocity is controlled at 1000 RPM:
0.2 part of skimmer, frostproofer in disperseing cylinder, adding 2 parts of remaining water, acrylic thickener, remainder successively mix, and mix the rotating speed that stirs and are controlled at 1200 RPM, and the coating preparation is accomplished.
Embodiment 2
Raw material with following parts by weight:
Functional materials:
40 parts of clean flavor emulsions (Celanese Corp. produces, model 1608)
1.5 parts of wood fibres (German Rui Dengmeier father and son company produces, model BE 600-10)
8 parts in zeyssatite (U.S. world's mineral products company produces, and model celite 495)
0.4 part of negative ion paint additive (Beijing Lanno Environmental Protection Science & Technology Co., Ltd. produces, model HB-TL)
Color stuffing:
21 parts of white titanium pigments (du pont company production, model R-706)
10 parts of dicalcium powders (wide Fujian material company produces model C C-1000)
Auxiliary agent:
0.6 part of dispersion agent (the lucky Buddhist nun in German Bake company produces, and model LOPON 800)
0.2 part of wetting agent (U.S. Air Prod & Chem produces, model C arbowet 13-40)
0.6 part of skimmer (U.S. Ya Shilan company produces, model AV1425)
0.1 part of frostproofer (French Rhodia produces, model FT-100)
0.35 part of thickening material (Dow Chemical produces, model QP30000H)
0.5 part of thickening material (Britain this special chemical company of sea name produces model RHEOLATE425)
0.15 part of sanitas (Dow Chemical produces, model BIT 20 LE)
0.2 part of mould inhibitor (U.S. Troy company produces, model polyphase PW40)
30 parts in tap water
The preparation method:
The water that in disperseing cylinder, adds 23 parts adds above dispersion agent, wetting agent, 0.2 part of skimmer and cellulose thickener respectively again, and thorough mixing forms gelationus material, mixes the rotating speed that stirs and is controlled at 450RPM:
In disperseing cylinder, add white titanium pigment, wood fibre, zeyssatite, dicalcium powder, be controlled to pull an oar under the 3000RPM at rotating speed and ground 22 minutes, looking into and surveying fineness is 53um:
In disperseing cylinder, add 4 parts of water and sanitas, mould inhibitor again, the clean flavor of interpolation emulsion, anionic additive mix then, mix, and stirring velocity is controlled at 1200 RPM:
0.4 part of skimmer, frostproofer in disperseing cylinder, adding 3 parts of remaining water, acrylic thickener, remainder successively mix, and mix the rotating speed that stirs and are controlled at 1000 RPM, and the coating preparation is accomplished.
Children's coating to the embodiment of the invention 1,2 preparation detects, VOC content all＜1g/L, meet German blue sky fully and make environmental evidence.
The above is merely preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of within spirit of the present invention and principle, being done, is equal to and replaces and improvement etc., all is included within protection scope of the present invention.
Claims (9)
1. children's coating is characterized in that its raw material by following parts by weight processes:
Wood fibre 1-4 part
Clean flavor emulsion 30-40 part
Zeyssatite 5-9 part
Anionic additive 0.4-0.6 part
White titanium pigment 20-25 part
Dicalcium powder 6-14 part
Dispersion agent 0.4-0.7 part
Wetting agent 0.1-0.3 part
Skimmer 0.3-0.6 part
Frostproofer 0.1-0.3 part
Thickening material 0.4-0.9 part
Sanitas 0.1-0.2 part
Mould inhibitor 0.1-0.2 part
Tap water 20-30 part.
2. children's coating as claimed in claim 1 is characterized in that its raw material by following parts by weight processes:
Wood fibre 1.5-2 part
Clean flavor emulsion 33-40 part
Zeyssatite 7-8 part
Anionic additive 0.4-0.5 part
White titanium pigment 21-23 part
Dicalcium powder 8-10 part
Dispersion agent 0.5-0.6 part
Wetting agent 0.1-0.2 part
Skimmer 0.3-0.6 part
Frostproofer 0.1-0.15 part
Thickening material 0.7-0.85 part
Sanitas 0.1-0.15 part
Mould inhibitor 0.1-0.2 part
Tap water 27-30 part.
3. children's coating as claimed in claim 1 is characterized in that said wood fibre is the natural organic after treatment wadding fibrous material of renewable timber.
4. children's coating as claimed in claim 1 is characterized in that said clean flavor emulsion is the zero VOC emulsion of distinguishing the flavor of only.
5. children's coating as claimed in claim 1 is characterized in that said anionic additive is natural tourmalinite class anionic additive.
6. children's coating as claimed in claim 1 is characterized in that said dispersion agent is polycarboxylate sodium's class dispersion agent; Wetting agent is an ethoxylation class wetting agent; Skimmer is a mineral oil defoaming agent; Frostproofer is zero VOC class freeze-thaw stabiliser; Thickening material is cellulose thickener or acrylic thickener; Sanitas is a 1.2-benzisothiazole-3-ketone sanitas; Mould inhibitor is an IPBC class mould inhibitor.
7. children's coating as claimed in claim 6 is characterized in that said cellulose thickener is a Natvosol class thickening material, and said acrylic thickener is an alkali swelling associative thickener.
8. like the preparation method of any described children's coating in the claim 1 to 7, it is characterized in that may further comprise the steps:
1) pre-mixing: in disperseing cylinder, add the water of 17～20 weight parts, add dispersion agent, wetting agent, the skimmer of 0.1～0.2 weight part, cellulose thickener respectively again, thorough mixing stirs and forms gelationus material;
2) grinding disperses: in disperseing cylinder, add white titanium pigment, wood fibre, zeyssatite, dicalcium powder, making beating was ground 20～25 minutes, looked into the survey fineness and was less than 60um:
3) add emulsion: in disperseing cylinder, add the water of 3～5 weight parts, add sanitas, mould inhibitor again, add clean flavor emulsion, anionic additive then, mix;
4) add auxiliary agent: in disperseing cylinder, add the skimmer of remaining water, acrylic thickener, frostproofer, remainder successively, mix.
9. the preparation method of children's coating as claimed in claim 8 is characterized in that mixing the rotating speed that stirs in the step 1) is 300～500RPM; Step 2) rotating speed that making beating is ground in is 2000～3000RPM; The rotating speed that mixes in step 3) and the step 4) is 800～1200 RPM.
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| CN2012102821102A CN102766405A (en) | 2012-08-09 | 2012-08-09 | Children coating and preparation method thereof |
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| CN2012102821102A CN102766405A (en) | 2012-08-09 | 2012-08-09 | Children coating and preparation method thereof |
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| CN103865335A (en) * | 2014-04-01 | 2014-06-18 | 天津银塔实业有限公司 | Wall paint and preparation method thereof |
| CN104556845A (en) * | 2015-01-31 | 2015-04-29 | 广东华兹卜化学工业有限公司 | Silicate inner wall coating |
| CN105111856A (en) * | 2015-09-16 | 2015-12-02 | 三棵树涂料股份有限公司 | Environment-friendly interior wall stone imitation paint and preparation method thereof |
| CN106366707A (en) * | 2016-08-29 | 2017-02-01 | 浙江德尔福新型建材有限公司 | Inorganic crosslinking nano coating varnish and preparation method thereof |
| CN106752555A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料（上海）股份有限公司 | Formaldehydeless green inner wall paint of a kind of net taste and preparation method thereof |
| CN107162483A (en) * | 2017-07-13 | 2017-09-15 | 安庆市星空化工涂料有限责任公司 | A kind of coating for child room |
| CN108003683A (en) * | 2018-01-05 | 2018-05-08 | 吕跃文 | Water-based forest negative oxygen ion interior wall coating and preparation method thereof |
| CN108504223A (en) * | 2018-02-23 | 2018-09-07 | 广州昊特建材有限公司 | Smell-clearing full-effective children paint and preparation method thereof |
| CN110128884A (en) * | 2019-06-18 | 2019-08-16 | 淮北庆丰涂料有限公司 | A kind of children special-purpose metope net taste paint and preparation method thereof |
| CN110157842A (en) * | 2019-06-26 | 2019-08-23 | 中原工学院 | A kind of universal Wound treatment agent of chrome tanning vegetable leather and preparation method thereof |
| CN110373112A (en) * | 2019-08-16 | 2019-10-25 | 浙江志强涂料有限公司 | A kind of low smell, Diamond Search, the interiro wall latex paint except formaldehyde |
| CN110511677A (en) * | 2019-09-17 | 2019-11-29 | 四川圣达高环保科技有限公司 | A kind of environmental protection anion face paint and preparation method thereof |
| CN110591443A (en) * | 2019-09-17 | 2019-12-20 | 四川圣达高环保科技有限公司 | Environment-friendly negative ion primer and preparation method thereof |
| CN110723922A (en) * | 2019-08-26 | 2020-01-24 | 辽宁多米乐漆业有限公司 | Formula and preparation method of diatom ooze negative oxygen ion children paint |
| CN112961589A (en) * | 2021-03-05 | 2021-06-15 | 广东美涂士建材股份有限公司 | Wood fiber environment-friendly paint |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103865335A (en) * | 2014-04-01 | 2014-06-18 | 天津银塔实业有限公司 | Wall paint and preparation method thereof |
| CN104556845A (en) * | 2015-01-31 | 2015-04-29 | 广东华兹卜化学工业有限公司 | Silicate inner wall coating |
| CN105111856A (en) * | 2015-09-16 | 2015-12-02 | 三棵树涂料股份有限公司 | Environment-friendly interior wall stone imitation paint and preparation method thereof |
| CN106752555A (en) * | 2015-11-25 | 2017-05-31 | 铂恩塞尔新材料（上海）股份有限公司 | Formaldehydeless green inner wall paint of a kind of net taste and preparation method thereof |
| CN106366707A (en) * | 2016-08-29 | 2017-02-01 | 浙江德尔福新型建材有限公司 | Inorganic crosslinking nano coating varnish and preparation method thereof |
| CN107162483A (en) * | 2017-07-13 | 2017-09-15 | 安庆市星空化工涂料有限责任公司 | A kind of coating for child room |
| CN108003683A (en) * | 2018-01-05 | 2018-05-08 | 吕跃文 | Water-based forest negative oxygen ion interior wall coating and preparation method thereof |
| CN108504223A (en) * | 2018-02-23 | 2018-09-07 | 广州昊特建材有限公司 | Smell-clearing full-effective children paint and preparation method thereof |
| CN110128884A (en) * | 2019-06-18 | 2019-08-16 | 淮北庆丰涂料有限公司 | A kind of children special-purpose metope net taste paint and preparation method thereof |
| CN110157842A (en) * | 2019-06-26 | 2019-08-23 | 中原工学院 | A kind of universal Wound treatment agent of chrome tanning vegetable leather and preparation method thereof |
| CN110157842B (en) * | 2019-06-26 | 2021-10-15 | 中原工学院 | Universal wound surface treating agent for chrome tanning and vegetable tanning and preparation method thereof |
| CN110373112A (en) * | 2019-08-16 | 2019-10-25 | 浙江志强涂料有限公司 | A kind of low smell, Diamond Search, the interiro wall latex paint except formaldehyde |
| CN110723922A (en) * | 2019-08-26 | 2020-01-24 | 辽宁多米乐漆业有限公司 | Formula and preparation method of diatom ooze negative oxygen ion children paint |
| CN110511677A (en) * | 2019-09-17 | 2019-11-29 | 四川圣达高环保科技有限公司 | A kind of environmental protection anion face paint and preparation method thereof |
| CN110591443A (en) * | 2019-09-17 | 2019-12-20 | 四川圣达高环保科技有限公司 | Environment-friendly negative ion primer and preparation method thereof |
| CN112961589A (en) * | 2021-03-05 | 2021-06-15 | 广东美涂士建材股份有限公司 | Wood fiber environment-friendly paint |
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Application publication date: 20121107 |