CN110511677A - A kind of environmental protection anion face paint and preparation method thereof - Google Patents
A kind of environmental protection anion face paint and preparation method thereof Download PDFInfo
- Publication number
- CN110511677A CN110511677A CN201910877393.7A CN201910877393A CN110511677A CN 110511677 A CN110511677 A CN 110511677A CN 201910877393 A CN201910877393 A CN 201910877393A CN 110511677 A CN110511677 A CN 110511677A
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- titanium dioxide
- coarse whiting
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D201/00—Coating compositions based on unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of environmentally friendly anion face paints, are made of the raw material for including following weight proportion: 220-250 parts of pure water, 3-7 parts of dispersing agent, 2-6 parts of wetting agent, 1-3 parts of preservative, 1-3 parts of mould inhibitor, 45-55 parts of polyethylene glycol, 2-4 parts of hydroxyethyl cellulose, 4-10 parts of defoaming agent, 45-55 parts of titanium dioxide, 140-160 parts of coarse whiting, 340-400 parts of finishing coat lotion, 70-90 parts of plant additive, 12-18 parts of coalescing agent, 15-25 parts of stabilizer, 4-10 parts of levelling agent, 1-3 parts of thickener.The invention also discloses the preparation methods of the environmental protection anion face paint.
Description
Technical field
The present invention relates to technical field of coatings, especially a kind of environmentally friendly anion face paint and preparation method thereof.
Background technique
It, can be with there are no highly effective method with current technology level for the status of the long-term release formaldehyde of adhesive
Thoroughly radical cure can only make the content and burst size of the substances such as formaldehyde by the dosage and good process means for controlling harmful substance
Reach bottom line, but its effect is very unobvious.
It is mostly the emulsion paint for adding formaldehyde removing substance that formaldehyde existing for current market, which closes product,.This functional painting
Although material has certain formaldehyde removing effect, relies solely on common water paint smearing and be wrapped in plate surface, although right
Formaldehyde can also play certain sealing process, reduce the burst size of formaldehyde, but its sealing process is extremely limited, there are permeability
Difference, the defects of coating structure is not close.In addition to this, the paint film of emulsion paint is difficult to remove, the wood furniture in face of being not necessarily to japanning,
This functional coating is with regard to helpless.
Summary of the invention
To solve problems of the prior art, the present invention provides a kind of environmentally friendly anion face paint and its preparation sides
Method, environmental protection anion face paint can high-intensitive sustained release negative oxygen ion for a long time, have purifying formaldehyde, PM2.5, toluene,
The functions such as VOC.
The technical solution adopted by the present invention is that:
A kind of environmental protection anion face paint, is made of the raw material for including following weight proportion: 220-250 parts of pure water divides
3-7 parts of powder, 2-6 parts of wetting agent, 1-3 parts of preservative, 1-3 parts of mould inhibitor, 45-55 parts of polyethylene glycol, hydroxyethyl cellulose 2-4
Part, 4-10 parts of defoaming agent, 45-55 parts of titanium dioxide, 140-160 parts of coarse whiting, 340-400 parts of finishing coat lotion, plant additive 70-90
Part, 12-18 parts of coalescing agent, 15-25 parts of stabilizer, 4-10 parts of levelling agent, 1-3 parts of thickener.
Preferably, by including that the raw material of following weight proportion is made: 230-240 parts of pure water, 4-6 parts of dispersing agent, wetting
3-5 parts of agent, 1.5-2.5 parts of preservative, 1.5-2.5 parts of mould inhibitor, 48-52 parts of polyethylene glycol, hydroxyethyl cellulose 2.5-3.5
Part, 6-8 parts of defoaming agent, 48-52 parts of titanium dioxide, 145-155 parts of coarse whiting, 350-390 parts of finishing coat lotion, plant additive 75-85
Part, 14-16 parts of coalescing agent, 18-22 parts of stabilizer, 6-8 parts of levelling agent, 1.5-2.5 parts of thickener.
Preferably, by include following weight proportion raw material be made: 233 parts of pure water, 5 parts of dispersing agent, 4 parts of wetting agent,
2 parts of preservative, 2 parts of mould inhibitor, 50 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, 7 parts of defoaming agent, 50 parts of titanium dioxide, coarse whiting 150
Part, 370 parts of finishing coat lotion, 80 parts of plant additive, 15 parts of coalescing agent, 20 parts of stabilizer, 7 parts of levelling agent, 2 parts of thickener.
Dispersing agent: optional non-ionic acetylenic glycols series of surfactants has the double effects of wetting and dispersion, is free of
It is APEO, nontoxic.
Wetting agent: optional non-ionic acetylenic glycols modified surface active agent can be improved system and moisten to the dynamic of various substrates
Wet ability promotes flowing levelling, no silicon, oil-free, nontoxic, is free of alkyl phenol polyoxyethylene ether class compound.
Preservative: optional methyl -4- isothiazoline -3- ketone, nontoxic, broad-spectrum antibacterial sterilization, lasting effect are long, can effectively press down
It makes and goes out except mushroom and various microorganisms, be free of any heavy metal.
Mould inhibitor: optional modified pentachlorophenol, environment-friendly and low-toxicity fungicide have the microorganisms such as mould, saccharomycete, algae
Special efficacy has efficient, lasting fungus and mildew resistance ability.
Polyethylene glycol: optional ethylene polyethenoxy ether, it is nontoxic, nonirritant, have good water solubility, and with many
Organic matter component has good intermiscibility, has excellent lubricity, moisture retention, dispersibility, cementability, antistatic property and softness
Property.
Hydroxyethyl cellulose: being a kind of white or faint yellow, tasteless, nontoxic threadiness or pulverulent solids, by alkalinity
Cellulose and the etherified reaction preparation of ethylene oxide (or chlorethanol), belong to non-ionic soluble fibre element ethers.Hydroxy ethyl fiber
Element has good thickening, suspension, dispersion, emulsification, bonding, film forming, protects moisture and provide the characteristics such as protecting colloid.
Defoaming agent: optional waterborne organic silicon, have good antifoam performance, can eliminate microvesicle and persistently it is still, be free of alkane
Base phenol polyethenoxy ethers compound.
Titanium dioxide: there are the characteristics such as nontoxic, reinforcement, anti-aging, filling effect, the strong, strong covering power of weatherability.
Coarse whiting: playing the role of increasing the volume of product, reduce production cost as filler, has good whiteness, light
The characteristics such as damp degree.
Finishing coat lotion: liquid monomer+water+initiator+surfactant is taken, and generates the solid particle being dispersed in water.
It is with solution polymer not soluble in water, it is obtained to be added surfactant, just produces the polymer under high velocity agitation
Lotion.
Plant additive: for lemon-grass, wormwood, aloe, the short leaf of bamboo, camphortree leaf, tea tree shell, bamboo charcoal, lavender, inulin institute
Essence is extracted, and adds kaolin, titanium dioxide, barium sulfate, coarse whiting and is mixed with;Natural plants in the plant additive
Ingredient can discharge the anion beneficial to human body by 8-10 in the passive state, and winter temperature is 18 degrees Celsius to 25 degrees Celsius,
Humidity is 50% to 70%;Summer temperature is 23 degrees Celsius to 28 degrees Celsius, and humidity is 50% to 75%, it is released within this range
Exoergic power is 2500~5000/m3。
Coalescing agent: optional alcohol ester 12 has certain volatility, can be trapped in play in film in film forming procedure and make
With all volatilizing after film forming, do not influence film performance.
Stabilizer: can increase the stability chemicals of solution, colloid, solid, mixture, can slow down reaction, keep
The effects of chemical balance reduces surface tension, prevents light, thermal decomposition or oxygenolysis.
Levelling agent: being a kind of common coating additive, it can promote coating formed during the drying and film forming process one it is smooth,
Smooth, uniform film.It can be effectively reduced and cover with paint, lacquer, colour wash, etc. liquid surface tension, improve a substance of its levelability and uniformity.It can change
The kind permeability for covering with paint, lacquer, colour wash, etc. liquid, increases spreadability at a possibility that generating spot and spot when can be reduced brushing, make film forming uniformly, from
So.
Thickener: being a kind of auxiliary rheological agents, can not only coating be made to thicken, and prevents sagging phenomenon occur in construction, and
The excellent mechanical performance of coating and storage stability can be assigned.For water paint lower for viscosity, it is very important
One analog assistant.
A kind of preparation method of environmentally friendly anion face as described above paint, includes the following steps:
A, lemon-grass, wormwood, aloe, the short leaf of bamboo, camphortree leaf, tea tree shell, bamboo charcoal, lavender, the extracted essence of inulin are prepared
China, and add kaolin, titanium dioxide, barium sulfate, coarse whiting and be mixed to prepare plant additive;
B, pure water is taken according to the ratio, dispersing agent, wetting agent, preservative, mould inhibitor, polyethylene glycol, hydroxyethyl cellulose, is disappeared
Infusion, titanium dioxide, coarse whiting, finishing coat lotion, plant additive, coalescing agent, stabilizer, levelling agent, thickener, after mixing
Obtain finished product.
The beneficial effects of the present invention are: unique plant additive is added, the selected plant material lemongrass of the plant additive
Grass, wormwood, aloe, the short leaf of bamboo, camphortree leaf, tea tree shell, bamboo charcoal, lavender, inulin extraction essence form, in the plant additive
Natural plant composition can high-intensitive sustained release negative oxygen ion for a long time, there are the function such as purifying formaldehyde, PM2.5, toluene, VOC
Can, it can promote blood circulation, help for sleep, prevent body illness.
Specific embodiment
The embodiment of the present invention is described in detail below.
Embodiment 1
A kind of environmental protection anion face paint, is made: 220 parts of pure water, dispersing agent 3 of the raw material for including following weight proportion
Part, 2 parts of wetting agent, 1 part of preservative, 1 part of mould inhibitor, 45 parts of polyethylene glycol, 2 parts of hydroxyethyl cellulose, 4 parts of defoaming agent, titanium white
45 parts of powder, 140 parts of coarse whiting, 340 parts of finishing coat lotion, 70 parts of plant additive, 12 parts of coalescing agent, 15 parts of stabilizer, levelling agent 4
Part, 1 part of thickener.
Embodiment 2
A kind of environmental protection anion face paint, is made: 233 parts of pure water, dispersing agent 5 of the raw material for including following weight proportion
Part, 4 parts of wetting agent, 2 parts of preservative, 2 parts of mould inhibitor, 50 parts of polyethylene glycol, 3 parts of hydroxyethyl cellulose, 7 parts of defoaming agent, titanium white
50 parts of powder, 150 parts of coarse whiting, 370 parts of finishing coat lotion, 80 parts of plant additive, 15 parts of coalescing agent, 20 parts of stabilizer, levelling agent 7
Part, 2 parts of thickener.
Embodiment 3
A kind of environmental protection anion face paint, is made: 250 parts of pure water, dispersing agent 7 of the raw material for including following weight proportion
Part, 6 parts of wetting agent, 3 parts of preservative, 3 parts of mould inhibitor, 55 parts of polyethylene glycol, 4 parts of hydroxyethyl cellulose, 10 parts of defoaming agent, titanium white
55 parts of powder, 160 parts of coarse whiting, 400 parts of finishing coat lotion, 90 parts of plant additive, 18 parts of coalescing agent, 25 parts of stabilizer, levelling agent
10 parts, 3 parts of thickener.
Embodiment 4
A kind of preparation method such as the environmentally friendly anion face paint in above-described embodiment, includes the following steps:
A, lemon-grass, wormwood, aloe, the short leaf of bamboo, camphortree leaf, tea tree shell, bamboo charcoal, lavender, the extracted essence of inulin are prepared
China, and add kaolin, titanium dioxide, barium sulfate, coarse whiting and be mixed to prepare plant additive;
B, pure water is taken according to the ratio, dispersing agent, wetting agent, preservative, mould inhibitor, polyethylene glycol, hydroxyethyl cellulose, is disappeared
Infusion, titanium dioxide, coarse whiting, finishing coat lotion, plant additive, coalescing agent, stabilizer, levelling agent, thickener, after mixing
Obtain finished product.
A specific embodiment of the invention above described embodiment only expresses, the description thereof is more specific and detailed, but simultaneously
Limitations on the scope of the patent of the present invention therefore cannot be interpreted as.It should be pointed out that for those of ordinary skill in the art
For, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to guarantor of the invention
Protect range.
Claims (5)
1. a kind of environmental protection anion face paint, which is characterized in that be made of the raw material for including following weight proportion: pure water 220-
250 parts, 3-7 parts of dispersing agent, 2-6 parts of wetting agent, 1-3 parts of preservative, 1-3 parts of mould inhibitor, 45-55 parts of polyethylene glycol, ethoxy
2-4 parts of cellulose, 4-10 parts of defoaming agent, 45-55 parts of titanium dioxide, 140-160 parts of coarse whiting, 340-400 parts of finishing coat lotion, plant add
Add 70-90 parts of agent, 12-18 parts of coalescing agent, 15-25 parts of stabilizer, 4-10 parts of levelling agent, 1-3 parts of thickener.
2. environmental protection anion face according to claim 1 paint, which is characterized in that by the raw material including following weight proportion
Be made: 230-240 parts of pure water, 4-6 parts of dispersing agent, 3-5 parts of wetting agent, 1.5-2.5 parts of preservative, 1.5-2.5 parts of mould inhibitor,
48-52 parts of polyethylene glycol, 2.5-3.5 parts of hydroxyethyl cellulose, 6-8 parts of defoaming agent, 48-52 parts of titanium dioxide, coarse whiting 145-155
Part, 350-390 parts of finishing coat lotion, 75-85 parts of plant additive, 14-16 parts of coalescing agent, 18-22 parts of stabilizer, levelling agent 6-
8 parts, 1.5-2.5 parts of thickener.
3. environmental protection anion face according to claim 1 paint, which is characterized in that by the raw material including following weight proportion
It is made: 233 parts of pure water, 5 parts of dispersing agent, 4 parts of wetting agent, 2 parts of preservative, 2 parts of mould inhibitor, 50 parts of polyethylene glycol, ethoxy
3 parts of cellulose, 7 parts of defoaming agent, 50 parts of titanium dioxide, 150 parts of coarse whiting, 370 parts of finishing coat lotion, 80 parts of plant additive, film forming help
15 parts of agent, 20 parts of stabilizer, 7 parts of levelling agent, 2 parts of thickener.
4. environmental protection anion face according to claim 1-3 paint, which is characterized in that the plant additive is
Lemon-grass, wormwood, aloe, the short leaf of bamboo, camphortree leaf, tea tree shell, bamboo charcoal, lavender, the extracted essence of inulin, and add kaolinite
Soil, titanium dioxide, barium sulfate, coarse whiting are mixed with.
5. a kind of preparation method of environmentally friendly anion face as claimed in claim 4 paint, which is characterized in that including walking as follows
It is rapid:
A, lemon-grass, wormwood, aloe, the short leaf of bamboo, camphortree leaf, tea tree shell, bamboo charcoal, lavender, the extracted essence of inulin are prepared, and
Addition kaolin, titanium dioxide, barium sulfate, coarse whiting are mixed to prepare plant additive;
B, pure water, dispersing agent, wetting agent, preservative, mould inhibitor, polyethylene glycol, hydroxyethyl cellulose, defoaming are taken according to the ratio
Agent, titanium dioxide, coarse whiting, finishing coat lotion, plant additive, coalescing agent, stabilizer, levelling agent, thickener, after mixing
Finished product.
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CN201910877393.7A CN110511677A (en) | 2019-09-17 | 2019-09-17 | A kind of environmental protection anion face paint and preparation method thereof |
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CN201910877393.7A CN110511677A (en) | 2019-09-17 | 2019-09-17 | A kind of environmental protection anion face paint and preparation method thereof |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111849358A (en) * | 2020-08-11 | 2020-10-30 | 中科沸石(成都)科技有限公司 | Environment-friendly negative ion zeolite surface coating agent and preparation method thereof |
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