CN104074323B - A kind of environmental protection wallpaper of aroma type - Google Patents
A kind of environmental protection wallpaper of aroma type Download PDFInfo
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- CN104074323B CN104074323B CN201410235728.2A CN201410235728A CN104074323B CN 104074323 B CN104074323 B CN 104074323B CN 201410235728 A CN201410235728 A CN 201410235728A CN 104074323 B CN104074323 B CN 104074323B
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Abstract
The invention provides the environmental protection wallpaper giving a kind of aroma type, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, described basic unit is provided with coating layer above, is provided with bamboo, is provided with flame-retardant layer above described bamboo above described coating layer, printed pattern layer is provided with above described flame-retardant layer, be provided with antibiotic aromatic layer above described printed pattern layer, be provided with polytetrafluoroethylene floor above described antibiotic aromatic layer, described polytetrafluoroethylene floor is provided with coating layer.Wallpaper of the present invention, is provided with separately antibiotic aromatic layer, by nano essence and shitosan and sodium phosphate trimer with the use of, wallpaper is given out a sweet perfume taste, can dwelling environment be promoted.While wallpaper of the present invention has good armaticity, also having antibacterial, mildew-resistant, deodorizing, protection against the tide, the performance such as fire-retardant, is the multi-functional wallpaper of a environmental type on the whole.
Description
Technical field
The present invention relates to a kind of environmental protection wallpaper of aroma type.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material quite widely.The feature that other house decorative materials multiple such as color is various, pattern enriches because wallpaper has, luxurious style, safety and environmental protection, easy construction, affordable are incomparable, therefore obtain the universal of certain degree at developed countries and regions such as America and Europe, Southeast Asia, Japan.In recent years, China's indoor decorating is persistently overheating, and the wallpaper be once given the cold shoulder has come into parlor, bedroom, hotel, conference room etc. again with its gorgeous new attitude.
In the past, wallpaper comes into the life of people as just a kind of decorative material, people to its require many ornamental with aesthetic property above, along with the raising of people's living standard, people need to want the wallpaper of high-quality to decorate the life of oneself, people's other Functional Requirement to wallpaper also gets more and more, required by having performances such as some Performance Ratios of wallpaper are as ventilative in environmental protection, antibacterial, deodorizing, moisture absorption, but the armaticity seldom requirement to wallpaper.
If the taste that wallpaper can give out a sweet perfume, the quality of indoor dwelling environment so can be made greatly to improve, and live in and give out a sweet perfume in the environment of atmosphere, the body and mind of people can be loosened, be in a cheerful frame of mind, the aspects such as operating efficiency can improve greatly, and quality of life increases.Therefore the environmental protection wallpaper developing a kind of aroma type is necessary.
Summary of the invention
Goal of the invention: the object of the invention is to solve the deficiencies in the prior art, provides a kind of environmental protection wallpaper of aroma type.
Technical scheme: in order to realize above object, the environmental protection wallpaper of a kind of aroma type of the present invention, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, described basic unit is provided with coating layer above, bamboo is provided with above described coating layer, flame-retardant layer is provided with above described bamboo, printed pattern layer is provided with above described flame-retardant layer, antibiotic aromatic layer is provided with above described printed pattern layer, be provided with polytetrafluoroethylene floor above described antibiotic aromatic layer, described polytetrafluoroethylene floor is provided with coating layer; Described coating layer is made up of the material of following mass percent: PP:30-35 part, sepiolite 5-7 part, zeolite 4-6 part, softening agent 1-2 part, retention agent 0.3-0.5 part, wet strength agent 1-2 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, dimethyl fumarate 1-2 part, calcium propionate 0.4-0.6 part, aluminium hydroxide 4-5 part, nano titanium oxide 2-3 part, ethanol 5-8 part, remainder is deionized water, and the thickness of described coating layer is 0.3-0.5mm; Described flame-retardant layer comprises following composition by weight: magnalium hydrotalcite colloid 8-10 part, retention agent CPAM0.05-0.08 part, sepiolite 2-4 part, and the thickness of described flame-retardant layer is 0.1-0.2mm; Described antibiotic aromatic layer comprises following composition by weight: shitosan 10-15 part, curing compound calcium carbonate 1-2 part, softening agent 1-2 part, sodium phosphate trimer 10-12 part, nano essence 0.03-0.05 part, the thickness of described antibiotic aromatic layer is 0.08-0.12mm.Sepiolite is contained in coating layer of the present invention, zeolite, the deodorant such as copper acid methyl cellulose, wherein sepiolite is a kind of fibrous rich-magnesium clay mineral, there is good absorption, fire-retardant, the performance such as high temperature resistant, and itself be environment-protecting asepsis material, the noxious materials such as the ammonia in air can be gone out as deodorant, can also use as fire retardant, zeolite is porous inorganic substances, there is absorption, catalyst and ion exchanging function, there is the premium properties of adsorption of hydrogen sulfide and ammonia, there is good deodorizing effect, a kind of well deodorant of copper acid methyl cellulose, gas permeability is high, effective, deodorizing capability can keep six months, can eliminate completely in 30 minutes the stench of ammonia and hydrogen sulfide, this several deodorant merges use, substantially can stink completely in deodorization chamber * winding paper, include antiseptic and nano titanium oxide in coating layer of the present invention, nano titanium oxide has good antibacterial effect, include dimethyl fumarate, calcium propionate in coating layer, these two kinds of materials all have excellent anti-mold effect, have the zeolite of deodorizing effect simultaneously, and it also has good anti-mold effect simultaneously, meanwhile, coating layer also comprises softener etc., makes the properties of wallpaper more balanced, superior, sepiolite in coating layer, aluminium hydroxide are all good fire retardants, and environmental protection, two kinds of fire retardants with the use of, flame retardant effect is more excellent, main component in coating layer is PP, but not PVC, can not produce VCM, environmental protection, other auxiliary agents of employing are also environmental protection toxic effects, the water proofing property coating that the bottom of wallpaper is provided with, the coating layer that topmost is provided with, protects wallpaper further, extends the application life of wallpaper, the present invention is also provided with bamboo, take full advantage of that bamboo-carbon fibre moisture absorption is ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, environmental protection, the feature such as humidity regulation, be provided with polytetrafluoroethylene floor, polytetrafluoroethylene (PTFE) is a kind of excellent environment-friendly type waterproof ventilative material, and wallpaper can be made to have water-proof breathable properties well, wallpaper is also provided with flame-retardant layer in addition, and the anti-flammability of wallpaper is improved greatly, finally, wallpaper is provided with separately antibiotic aromatic layer, by nano essence and shitosan and sodium phosphate trimer with the use of, make respective fragrance.Antibacterial, fire resistance obtains maximum performance, and the armaticity of nano essence is far longer than the armaticity of common essence, and such wallpaper gives out pure and fresh fragrance, and the quality of indoor dwelling environment is promoted greatly.
The material of described water proofing property coating is JS water-repellent paint, and coating layer thickness is 0.2-0.4mm.
The material of described basic unit is non-woven fabrics, pure cotton cloth or blended cloth.
The thickness of described bamboo is 0.2-0.4mm.
The thickness of described polytetrafluoroethylene floor is 0.2-0.3mm.
Described coating layer is polyethylene sheeting, and thickness is 0.2-0.4mm.Polyethylene has excellent moisture resistance, makes the moisture resistance of wallpaper more superior.
Described softening agent is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is shitosan.
The particle diameter of described nano essence is 140-160nm, and when particle diameter is about 150nm, fragrant bacteria-eliminating efficacy is best, and the particle diameter of nano titanium oxide is 10-100nm, and when particle diameter is about 30nm, antibacterial effect is best.
Beneficial effect: the environmental protection wallpaper of aroma type provided by the invention compared with prior art, has the following advantages:
1, wallpaper of the present invention, is provided with separately antibiotic aromatic layer, by nano essence and shitosan and sodium phosphate trimer with the use of, wallpaper is given out a sweet perfume taste, can dwelling environment be promoted;
2, wallpaper of the present invention, is provided with the reagent such as deodorant, antiseptic, mould inhibitor, fire retardant, softener, makes the overall performance comparative superiority of wallpaper at coating layer;
3, the water proofing property coating, the coating layer that are provided with of the present invention, protects wallpaper further, extends the application life of wallpaper;
4, the present invention has been provided with polytetrafluoroethylene floor, and polytetrafluoroethylene (PTFE) is a kind of excellent environment-friendly type waterproof ventilative material, and wallpaper can be made to have water-proof breathable properties well; Coating layer also has moisture resistance simultaneously; Wallpaper of the present invention is made to have excellent moisture resistance and gas permeability like this; Be provided with bamboo, taken full advantage of that bamboo-carbon fibre moisture absorption is ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, environmental protection, the feature such as humidity regulation; Wallpaper is also provided with flame-retardant layer in addition, and the anti-flammability of wallpaper is improved greatly;
5, the reagent environmental protection of each layer use of the present invention, meet the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing VCM, also can not cause secondary pollution;
6, while wallpaper of the present invention has good armaticity, also having antibacterial, mildew-resistant, deodorizing, protection against the tide, the performance such as fire-retardant, is the multi-functional wallpaper of a environmental type on the whole.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention;
In figure: 1-water proofing property coating, 2-basic unit, 3-coating layer, 4-bamboo, 5-flame-retardant layer, 6-printed pattern layer, 7-antibiotic aromatic layer, 8-polytetrafluoroethylene floor, 9-coating layer.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; but illustrate that protection scope of the present invention is not limited to the concrete scope of the present embodiment simultaneously; based on the embodiment in the present invention; those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1
A kind of environmental protection wallpaper of aroma type, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, and described coating layer 3 is provided with bamboo 4 above, and described bamboo 4 is provided with flame-retardant layer 5 above, described flame-retardant layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 is provided with antibiotic aromatic layer 7 above, and described antibiotic aromatic layer 7 is provided with polytetrafluoroethylene floor 8 above, and described polytetrafluoroethylene floor 8 is provided with coating layer 9.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.2mm;
The material of described basic unit 2 is non-woven fabrics, pure cotton cloth or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:30 part, sepiolite 5 parts, 4 parts, zeolite, softening agent stearic acid triethanolamine ester quaternary 1 part, retention agent guar gum 0.3 part, wet strength agent PAE resin 1 part, copper acid methyl cellulose 2 parts, antiseptic shitosan 4 parts, dimethyl fumarate 1 part, calcium propionate 0.4 part, 4 parts, aluminium hydroxide, the nano titanium oxide 2 parts of particle diameter 33nm, ethanol 5 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.5mm;
The thickness of described bamboo 4 is 0.2mm;
Described flame-retardant layer 5 comprises following composition by weight: 8 parts, magnalium hydrotalcite colloid, retention agent CPAM0.05 part, sepiolite 2 parts, and the preparation method of magnalium hydrotalcite colloid is as follows: be the Mg (NO of 3: 1 by magnalium ratio under room temperature
3)
2.6H
2o and Al (NO
3)
3.9H
2o dissolves in deionized water, fixing total ion concentration 0.5mol/L, then slowly joining mass concentration under being stirred by obtained solution is in 10% sodium carbonate liquor, add rear vigorous stirring 1h, then slowly stir 2h, have precipitation in the process and generate, then left at room temperature 48h, decompress filter, after filter cake spends deionized water twice at 70-80 DEG C peptization 5h, hydrotalcite colloid can be obtained; The thickness of described flame-retardant layer 5 is 0.2mm;
Described antibiotic aromatic layer 7 comprises following composition by weight: the nano essence 0.03 part of shitosan 10 parts, 1 part, curing compound calcium carbonate, softening agent stearic acid triethanolamine ester quaternary 1 part, sodium phosphate trimer 10 parts, particle diameter 151nm, and the thickness of described antibiotic aromatic layer 7 is 0.12mm;
The thickness of described polytetrafluoroethylene floor 8 is 0.2mm;
Described coating layer 9 is polyethylene sheeting, and thickness is 0.2mm.
embodiment 2
A kind of environmental protection wallpaper of aroma type, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, and described coating layer 3 is provided with bamboo 4 above, and described bamboo 4 is provided with flame-retardant layer 5 above, described flame-retardant layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 is provided with antibiotic aromatic layer 7 above, and described antibiotic aromatic layer 7 is provided with polytetrafluoroethylene floor 8 above, and described polytetrafluoroethylene floor 8 is provided with coating layer 9.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.3mm;
The material of described basic unit 2 is non-woven fabrics, pure cotton cloth or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:33 part, sepiolite 6 parts, 5 parts, zeolite, softening agent stearic acid triethanolamine ester quaternary 1.4 parts, retention agent guar gum 0.4 part, wet strength agent PAE resin 1.5 parts, copper acid methyl cellulose 2.6 parts, antiseptic shitosan 4.5 parts, dimethyl fumarate 1.5 parts, calcium propionate 0.5 part, 4.4 parts, aluminium hydroxide, the nano titanium oxide 2.5 parts of particle diameter 33nm, ethanol 6.4 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.4mm;
The thickness of described bamboo 4 is 0.3mm;
Described flame-retardant layer 5 comprises following composition by weight: 9 parts, magnalium hydrotalcite colloid, retention agent CPAM0.07 part, sepiolite 3 parts, and the preparation method of magnalium hydrotalcite colloid is as follows: be the Mg (NO of 3: 1 by magnalium ratio under room temperature
3)
2.6H
2o and Al (NO
3)
3.9H
2o dissolves in deionized water, fixing total ion concentration 0.5mol/L, then slowly joining mass concentration under being stirred by obtained solution is in 10% sodium carbonate liquor, add rear vigorous stirring 1h, then slowly stir 2h, have precipitation in the process and generate, then left at room temperature 48h, decompress filter, after filter cake spends deionized water twice at 70-80 DEG C peptization 5h, hydrotalcite colloid can be obtained; The thickness of described flame-retardant layer 5 is 0.15mm;
Described antibiotic aromatic layer 7 comprises following composition by weight: the nano essence 0.04 part of shitosan 13 parts, 1.5 parts, curing compound calcium carbonate, softening agent stearic acid triethanolamine ester quaternary 1.4 parts, sodium phosphate trimer 11 parts, particle diameter 151nm, and the thickness of described antibiotic aromatic layer 7 is 0.1mm;
The thickness of described polytetrafluoroethylene floor 8 is 0.25mm;
Described coating layer 9 is polyethylene sheeting, and thickness is 0.3mm.
embodiment 3
A kind of environmental protection wallpaper of aroma type, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, and described coating layer 3 is provided with bamboo 4 above, and described bamboo 4 is provided with flame-retardant layer 5 above, described flame-retardant layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 is provided with antibiotic aromatic layer 7 above, and described antibiotic aromatic layer 7 is provided with polytetrafluoroethylene floor 8 above, and described polytetrafluoroethylene floor 8 is provided with coating layer 9.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.4mm;
The material of described basic unit 2 is non-woven fabrics, pure cotton cloth or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:35 part, sepiolite 7 parts, 6 parts, zeolite, softening agent stearic acid triethanolamine ester quaternary 2 parts, retention agent guar gum 0.5 part, wet strength agent PAE resin 2 parts, copper acid methyl cellulose 3 parts, antiseptic shitosan 5 parts, dimethyl fumarate 2 parts, calcium propionate 0.6 part, 5 parts, aluminium hydroxide, the nano titanium oxide 3 parts of particle diameter 33nm, ethanol 8 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.3mm;
The thickness of described bamboo 4 is 0.4mm;
Described flame-retardant layer 5 comprises following composition by weight: 10 parts, magnalium hydrotalcite colloid, retention agent CPAM0.08 part, sepiolite 4 parts, and the preparation method of magnalium hydrotalcite colloid is as follows: be the Mg (NO of 3: 1 by magnalium ratio under room temperature
3)
2.6H
2o and Al (NO
3)
3.9H
2o dissolves in deionized water, fixing total ion concentration 0.5mol/L, then slowly joining mass concentration under being stirred by obtained solution is in 10% sodium carbonate liquor, add rear vigorous stirring 1h, then slowly stir 2h, have precipitation in the process and generate, then left at room temperature 48h, decompress filter, after filter cake spends deionized water twice at 70-80 DEG C peptization 5h, hydrotalcite colloid can be obtained; The thickness of described flame-retardant layer 5 is 0.1mm;
Described antibiotic aromatic layer 7 comprises following composition by weight: the nano essence 0.05 part of shitosan 15 parts, 2 parts, curing compound calcium carbonate, softening agent stearic acid triethanolamine ester quaternary 2 parts, sodium phosphate trimer 12 parts, particle diameter 151nm, and the thickness of described antibiotic aromatic layer 7 is 0.08mm;
The thickness of described polytetrafluoroethylene floor 8 is 0.3mm;
Described coating layer 9 is polyethylene sheeting, and thickness is 0.4mm.
The manufacture craft of the wallpaper of example wallpaper routinely time above-mentioned, through paste producing, coating, drying, printing, foaming, embossing, cooling, trimming, rolling.
The wallpaper obtained according to above-described embodiment meets the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing VCM, have excellent armaticity, antibiotic property, deodorization, mildew resistance, moisture resistance, gas permeability, be the multi-functional wallpaper of a environment-friendly type simultaneously.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its objective is to allow and is familiar with these those skilled in the art and can understands content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalents done by Spirit Essence of the present invention or modification, all should be encompassed within protection scope of the present invention.
Claims (8)
1. the environmental protection wallpaper of an aroma type, it is characterized in that: comprise basic unit (2), the back side of described basic unit (2) is provided with water proofing property coating (1), described basic unit (2) is provided with coating layer (3) above, described coating layer (3) is provided with bamboo (4) above, described bamboo (4) is provided with flame-retardant layer (5) above, described flame-retardant layer (5) is provided with printed pattern layer (6) above, described printed pattern layer (6) is provided with antibiotic aromatic layer (7) above, described antibiotic aromatic layer (7) is provided with polytetrafluoroethylene floor (8) above, described polytetrafluoroethylene floor (8) is provided with coating layer (9), described coating layer (3) is made up of the material of following composition by weight: PP30-35 part, sepiolite 5-7 part, zeolite 4-6 part, softening agent 1-2 part, retention agent 0.3-0.5 part, wet strength agent 1-2 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, dimethyl fumarate 1-2 part, calcium propionate 0.4-0.6 part, aluminium hydroxide 4-5 part, nano titanium oxide 2-3 part, ethanol 5-8 part, remainder is deionized water, and the thickness of described coating layer (3) is 0.3-0.5mm, described flame-retardant layer (5) comprises following composition by weight: magnalium hydrotalcite colloid 8-10 part, retention agent CPAM0.05-0.08 part, sepiolite 2-4 part, and the thickness of described flame-retardant layer (5) is 0.1-0.2mm, described antibiotic aromatic layer (7) comprises following composition by weight: shitosan 10-15 part, curing compound calcium carbonate 1-2 part, softening agent 1-2 part, sodium phosphate trimer 10-12 part, nano essence 0.03-0.05 part, the thickness of described antibiotic aromatic layer (7) is 0.08-0.12mm.
2. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: the material of described water proofing property coating (1) is JS water-repellent paint, and coating layer thickness is 0.2-0.4mm.
3. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: the material of described basic unit (2) is non-woven fabrics, pure cotton cloth or blended cloth.
4. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: the thickness of described bamboo (4) is 0.2-0.4mm.
5. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: the thickness of described polytetrafluoroethylene floor (8) is 0.2-0.3mm.
6. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: described coating layer (9) is polyethylene sheeting, and thickness is 0.2-0.4mm.
7. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: described softening agent is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is shitosan.
8. the environmental protection wallpaper of aroma type according to claim 1, is characterized in that: the particle diameter of described nano essence is 140-160nm, and the particle diameter of nano titanium oxide is 10-100nm.
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| CN104947512A (en) * | 2015-05-13 | 2015-09-30 | 河南栖美生物科技有限公司 | Olive cellulose wallpaper and preparation method thereof |
| CN106079701A (en) * | 2016-06-21 | 2016-11-09 | 钱学东 | A kind of mosquito-proof composite wallpaper of mildew-resistant |
| CN106320620A (en) * | 2016-08-23 | 2017-01-11 | 柳州市国正机电物资有限责任公司 | Wallpaper |
| CN106283923B (en) * | 2016-09-14 | 2018-11-27 | 福建农林大学 | A kind of appendix has the mildew-proof wallpaper and preparation method thereof of load medicine chitosan |
| CN107386008A (en) * | 2017-07-27 | 2017-11-24 | 安徽宽居电器有限公司 | A kind of manufacturing process of Environment-friendlywallpaper wallpaper |
| CN113524804A (en) * | 2021-07-19 | 2021-10-22 | 杭州富氧环境科技有限公司 | Antibacterial and antiviral negative oxygen ion material and preparation method thereof |
| CN115094680A (en) * | 2022-06-01 | 2022-09-23 | 金东纸业（江苏）股份有限公司 | Flame-retardant decorative paper and preparation method thereof |
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| CN103195221A (en) * | 2013-03-29 | 2013-07-10 | 苏州国昊壁纸有限公司 | Light air purification wall covering |
| CN203440711U (en) * | 2013-06-28 | 2014-02-19 | 深圳市时代装饰工程有限公司 | Environment-friendly flame-proof wallpaper |
| CN203613759U (en) * | 2013-11-12 | 2014-05-28 | 地球卫士（绥化）环保新材料有限公司 | Stone paper-based and bamboo charcoal composite wallpaper |
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| JP3224430B2 (en) * | 1992-09-30 | 2001-10-29 | オカモト株式会社 | Wall paper |
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|---|---|---|---|---|
| CN103195221A (en) * | 2013-03-29 | 2013-07-10 | 苏州国昊壁纸有限公司 | Light air purification wall covering |
| CN203440711U (en) * | 2013-06-28 | 2014-02-19 | 深圳市时代装饰工程有限公司 | Environment-friendly flame-proof wallpaper |
| CN203613759U (en) * | 2013-11-12 | 2014-05-28 | 地球卫士（绥化）环保新材料有限公司 | Stone paper-based and bamboo charcoal composite wallpaper |
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