A kind of environment-friendly type antibiotic deodorizing wallpaper
Technical field
The present invention relates to a kind of environment-friendly type antibiotic deodorizing wallpaper.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material quite widely.The feature that other house decorative materials multiple such as color is various, pattern enriches because wallpaper has, luxurious style, safety and environmental protection, easy construction, affordable are incomparable, therefore obtain the universal of certain degree at developed countries and regions such as America and Europe, Southeast Asia, Japan.In recent years, China's indoor decorating is persistently overheating, and the wallpaper be once given the cold shoulder has come into parlor, bedroom, hotel, meeting room etc. again with its gorgeous new attitude.
In the past, wallpaper comes into the life of people as just a kind of decorative material, people to its require many ornamental with aesthetic property above, along with the raising of people's living standard, people need to want the wallpaper of high-quality to decorate the life of oneself, and people's other Functional Requirement to wallpaper also gets more and more.
Along with improving constantly of people's material and cultural life, people for healthy and cleaning problems care and the life seek of the peaceful and comfortable equivalent comfort energy of gracefulness is also being improved day by day.But in the middle of daily life, unavoidable kitchen, toilet, hospital ward, bedroom peculiar smell and the life stink such as tobacco, body sweat, often affect the comfortableness of people's life.Particularly along with the arrival of aging society, the aged person of bed and the person of recuperating increase, and for preventing stench, the demand of environmental protect also increases thereupon, and these all can promote development that is antibacterial, deodorising product undoubtedly.Wallpaper, as a megatrend of nowadays interior decoration, also inevitably relates to antibacterial, this problem of deodorizing.At present, antibacterial and deodouring wallpaper special on the market lacks very much, and the Performance Ratio of wallpaper this respect is poor.Therefore, the novel wallpaper developing a kind of antibacterial and deodouring function admirable is necessary.
Summary of the invention
Goal of the invention: the object of the invention is to solve the deficiencies in the prior art, provides a kind of environment-friendly type antibiotic deodorizing wallpaper.
Technical scheme: in order to realize above object, a kind of environment-friendly type antibiotic deodorizing wallpaper of the present invention, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, and described basic unit is provided with coating layer above, is provided with antibiotic layer above described coating layer, absorbing and deodorizing layer is provided with above described antibiotic layer, be provided with printed pattern layer above described absorbing and deodorizing layer, described printed pattern layer coated thereon has antibacterial and deodouring composite bed, is provided with coating layer above described antibacterial and deodouring composite bed; Described coating layer is made up of the material of following mass percent: PP:35-40 part, active carbon 5-8 part, zeolite 5-8 part, softener 1-2 part, retention agent 0.2-0.4 part, wet strength agent 1-2 part, aluminum orthophoshpate 3-5 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, mould inhibitor 3-4 part, fire retardant 3-4 part, titanium dioxide 2-3 part, remainder is deionized water, and the thickness of described coating layer is 0.5-1mm; Described antibiotic layer comprises following composition by weight: polyvinyl alcohol 20-22 part, zeolite with carrying silver 0.5-1 part, deionized water 75-80 part, and the thickness of described antibiotic layer is 0.4-0.6mm.Active carbon is contained in coating layer of the present invention, zeolite, aluminum orthophoshpate, the deodorant such as copper acid methyl cellulose, wherein active carbon, active carbon is the fine porous material of a kind of surface texture, has deodorization, especially adsorb ammonia, ethene, the characteristic of aldehydes gas is better, and zeolite is porous inorganic substances, has absorption, catalyst and ion exchanging function, have the premium properties of adsorption of hydrogen sulfide and ammonia, has good deodorizing effect, the easy adsorb ammonia of aluminum orthophoshpate, the tools such as amine material frowzy, simultaneously also fine to the adsorption effect of mercaptan, be a kind of well deodorant of copper acid methyl cellulose, gas permeability is high, effective, deodorizing capability can keep six months, can eliminate completely in 30 minutes the stench of ammonia and hydrogen sulfide, and this several deodorant merges and uses, substantially can stink completely in deodorization chamber * winding paper, and meanwhile, coating layer also comprises antiseptic, mould inhibitor, fire retardant, makes the properties of wallpaper more balanced, superior, the main component in coating layer is PP, but not PVC, can not Vinyl Chloride Monomer be produced, environmental protection, the water proofing property coating that bottom is provided with, the coating layer that topmost is provided with, protects wallpaper further, extends the service life of wallpaper, the absorbing and deodorizing layer that the present invention is also provided with, antibiotic layer, antibacterial and deodouring composite bed, multiple protective, make the antibacterial and deodouring performance of wallpaper obtain the raising of largeizationr, performance is more superior, employ polyvinyl alcohol and zeolite with carrying silver in antibiotic layer, the polyvinyl alcohol under aforementioned proportion and zeolite with carrying silver mixed liquor, have superior anti-microbial property.
The material of described water proofing property coating is JS water-repellent paint, and coating layer thickness is 0.5-0.8mm.
The material of described basic unit is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth.
The main material of described absorbing and deodorizing layer is diatomite, and thickness is 1-2mm.The feature that the porous that diatomite has, high porosity, specific area are large, adsorptivity is strong, has good deodorizing effect.
Antibacterial and deodouring composite bed comprises the material of following mass percent: chitin 10-15 part, microcapsule essence 5-8 part, curing agent 3-5 part, softener stearic acid triethanolamine ester quaternary 1-2 part, the thickness of described antibacterial and deodouring composite bed is 0.3-0.5mm.Chitin has antibacterial effect well, and microcapsule essence has directionality, has deodorizing effect, and both share, and makes wallpaper also have armaticity while antibacterial and deodouring.
Described coating layer is polyethylene film, and thickness is 0.2-0.4mm.
Described softener is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is organosilicon antibacterial agent CTU-1, and mould inhibitor is Zinc Pyrithione, fire retardant is magnesium hydroxide.Used various reagents ratios comparatively environmental protection, the heavy metal prohibitted the use not containing national regulation.
Described curing agent is calcium carbonate.
Beneficial effect: environment-friendly type antibiotic deodorizing wallpaper provided by the invention compared with prior art, has the following advantages:
1, wallpaper of the present invention, is provided with antiseptic, deodorant at coating layer, makes wallpaper have antibacterial and deodouring, be provided with again absorbing and deodorizing layer, antibiotic layer, antibacterial and deodouring composite bed further simultaneously, multiple protective, make the antibacterial and deodouring performance of wallpaper obtain the raising of largeizationr, performance is more superior;
2, the water proofing property coating, the coating layer that are provided with of the present invention, protects wallpaper further, extends the service life of wallpaper;
3, the reagent environmental protection of each layer use of the present invention, meet the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer, also can not cause secondary pollution;
4, wallpaper of the present invention is except antibacterial and deodouring superior performance, and the performance of each side such as its mildew resistance, anti-flammability, flexibility is all more balanced, excellent, is the multi-functional wallpaper of a environmental type on the whole.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention;
In figure: 1-water proofing property coating, 2-basic unit, 3-coating layer, 4-antibiotic layer, 5-absorbing and deodorizing layer, 6-printed pattern layer, 7-antibacterial and deodouring composite bed, 8-coating layer.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; but illustrate that protection scope of the present invention is not limited to the concrete scope of the present embodiment simultaneously; based on the embodiment in the present invention; those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1
A kind of environment-friendly type antibiotic deodorizing wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with antibiotic layer 4 above, and described antibiotic layer 4 is provided with absorbing and deodorizing layer 5 above, and described absorbing and deodorizing layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 coated thereon has antibacterial and deodouring composite bed 7, and described antibacterial and deodouring composite bed 7 is provided with coating layer 8 above.
Described water proofing property coating 1 material is JS water-repellent paint, and coating layer thickness is 0.5mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:36 part, active carbon 5.5 parts, 5.4 parts, zeolite, softener stearic acid triethanolamine ester quaternary 1.1 parts, retention agent guar gum 0.2 part, wet strength agent PAE resin 1 part, aluminum orthophoshpate 3 parts, copper acid methyl cellulose 2 parts, antiseptic organosilicon antibacterial agent CTU-14 part, mould inhibitor Zinc Pyrithione 3 parts, fire retardant magnesium hydroxide 3 parts, titanium dioxide 2 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.6mm;
Described antibiotic layer 4 comprises following composition by weight: polyvinyl alcohol 20 parts, zeolite with carrying silver 0.6 part, deionized water 76 parts, and the thickness of described antibiotic layer 4 is 0.4mm; Zeolite with carrying silver preparation method in described antibiotic layer 4 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7,70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, and the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times; Coating fluid in antibiotic layer 4 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution;
The material of described absorbing and deodorizing layer 5 is diatomite, and thickness is 1.2mm;
Described antibacterial and deodouring composite bed 7 comprises the material of following mass percent: chitin 11 parts, microcapsule essence 5.5 parts, 3 parts, curing agent calcium carbonate, softener stearic acid triethanolamine ester quaternary 1 part, and the thickness of described antibacterial and deodouring composite bed 7 is 0.3mm;
Described coating layer 8 is polyethylene film, and thickness is 0.2mm.
embodiment 2
A kind of environment-friendly type antibiotic deodorizing wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with antibiotic layer 4 above, and described antibiotic layer 4 is provided with absorbing and deodorizing layer 5 above, and described absorbing and deodorizing layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 coated thereon has antibacterial and deodouring composite bed 7, and described antibacterial and deodouring composite bed 7 is provided with coating layer 8 above.
Described water proofing property coating 1 material is JS water-repellent paint, and coating layer thickness is 0.64mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:38 part, active carbon 6.5 parts, 6.5 parts, zeolite, softener stearic acid triethanolamine ester quaternary 1.6 parts, retention agent guar gum 0.3 part, wet strength agent PAE resin 1.6 parts, aluminum orthophoshpate 4 parts, copper acid methyl cellulose 2.6 parts, antiseptic organosilicon antibacterial agent CTU-14.5 part, mould inhibitor Zinc Pyrithione 3.5 parts, fire retardant magnesium hydroxide 3.4 parts, titanium dioxide 2.6 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.8mm;
Described antibiotic layer 4 comprises following composition by weight: polyvinyl alcohol 21 parts, zeolite with carrying silver 0.8 part, deionized water 78 parts, and the thickness of described antibiotic layer 4 is 0.5mm; Zeolite with carrying silver preparation method in described antibiotic layer 4 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7,70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, and the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times; Coating fluid in antibiotic layer 4 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution;
The material of described absorbing and deodorizing layer 5 is diatomite, and thickness is 1.6mm;
Described antibacterial and deodouring composite bed 7 comprises the material of following mass percent: chitin 13.6 parts, microcapsule essence 7 parts, 4 parts, curing agent calcium carbonate, softener stearic acid triethanolamine ester quaternary 1.5 parts, and the thickness of described antibacterial and deodouring composite bed 7 is 0.4mm;
Described coating layer 8 is polyethylene film, and thickness is 0.3mm.
embodiment 3
A kind of environment-friendly type antibiotic deodorizing wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with antibiotic layer 4 above, and described antibiotic layer 4 is provided with absorbing and deodorizing layer 5 above, and described absorbing and deodorizing layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 coated thereon has antibacterial and deodouring composite bed 7, and described antibacterial and deodouring composite bed 7 is provided with coating layer 8 above.
Described water proofing property coating 1 material is JS water-repellent paint, and coating layer thickness is 0.8mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:40 part, active carbon 8 parts, 8 parts, zeolite, softener stearic acid triethanolamine ester quaternary 2 parts, retention agent guar gum 0.4 part, wet strength agent PAE resin 2 parts, aluminum orthophoshpate 5 parts, copper acid methyl cellulose 3 parts, antiseptic organosilicon antibacterial agent CTU-15 part, mould inhibitor Zinc Pyrithione 4 parts, fire retardant magnesium hydroxide 4 parts, titanium dioxide 3 parts, remainder is deionized water, and the thickness of described coating layer 3 is 1mm;
Described antibiotic layer 4 comprises following composition by weight: polyvinyl alcohol 22 parts, zeolite with carrying silver 1 part, deionized water 80 parts, and the thickness of described antibiotic layer 4 is 0.6mm; Zeolite with carrying silver preparation method in described antibiotic layer 4 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7,70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, and the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times; Coating fluid in antibiotic layer 4 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution;
The material of described absorbing and deodorizing layer 5 is diatomite, and thickness is 2mm;
Described antibacterial and deodouring composite bed 7 comprises the material of following mass percent: chitin 15 parts, microcapsule essence 8 parts, 5 parts, curing agent calcium carbonate, softener stearic acid triethanolamine ester quaternary 2 parts, and the thickness of described antibacterial and deodouring composite bed 7 is 0.5mm;
Described coating layer 8 is polyethylene film, and thickness is 0.4mm.
The manufacture craft of the wallpaper of example wallpaper routinely time above-mentioned, through paste producing, coating, drying, printing, foaming, embossing, cooling, trimming, rolling.
The wallpaper obtained according to above-described embodiment meets the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer, have excellent antibacterial and deodouring performance, be the antibacterial and deodouring wallpaper of a environment-friendly type simultaneously.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its objective is to allow and is familiar with these those skilled in the art and can understands content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalents done by Spirit Essence of the present invention or modification, all should be encompassed within protection scope of the present invention.