Summary of the invention
Goal of the invention: the object of the invention is in order to solve the deficiencies in the prior art, a kind of environment-friendly type antibiotic deodorizing wallpaper is provided.
Technical scheme: in order to realize above object, a kind of environment-friendly type antibiotic deodorizing wallpaper of the present invention, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, and described basic unit is provided with coating layer above, above described coating layer, is provided with antibiotic layer, above described antibiotic layer, be provided with absorbing and deodorizing layer, above described absorbing and deodorizing layer, be provided with printed pattern layer, above described printed pattern layer, be coated with antibacterial and deodouring composite bed, above described antibacterial and deodouring composite bed, be provided with coating layer; Described coating layer is made up of the material of following mass percent: PP:35-40 part, active carbon 5-8 part, zeolite 5-8 part, softener 1-2 part, retention agent 0.2-0.4 part, wet strength agent 1-2 part, aluminum orthophoshpate 3-5 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, mould inhibitor 3-4 part, fire retardant 3-4 part, titanium dioxide 2-3 part, remainder is deionized water, and the thickness of described coating layer is 0.5-1mm; Described antibiotic layer comprises following composition by weight: polyvinyl alcohol 20-22 part, and zeolite with carrying silver 0.5-1 part, deionized water 75-80 part, the thickness of described antibiotic layer is 0.4-0.6mm.In coating layer of the present invention, comprise active carbon, zeolite, aluminum orthophoshpate, the deodorant such as copper acid methyl cellulose, wherein active carbon, active carbon is the fine porous material of a kind of surface texture, has deodorization, especially adsorb ammonia, ethene, the characteristic of aldehydes gas is better, and zeolite is porous inorganic substances, has absorption, catalyst and ion exchanging function, have the premium properties of adsorption of hydrogen sulfide and ammonia, has good deodorizing effect, the easy adsorb ammonia of aluminum orthophoshpate, the tools such as amine material frowzy, simultaneously also fine to the adsorption effect of mercaptan, be a kind of well deodorant of copper acid methyl cellulose, gas permeability is high, effective, deodorizing capability can keep six months, can eliminate completely in 30 minutes the stench of ammonia and hydrogen sulfide, and this several deodorant merges use, the stink in deodorization chamber * winding paper substantially completely, and meanwhile, coating layer also comprises antiseptic, mould inhibitor, fire retardant, makes the properties of wallpaper more balanced, superior, the main component in coating layer is PP, but not PVC can not produce Vinyl Chloride Monomer, environmental protection, the water proofing property coating that bottom is provided with, the coating layer that topmost is provided with, has further protected wallpaper, has extended the service life of wallpaper, absorbing and deodorizing layer, antibiotic layer, antibacterial and deodouring composite bed that the present invention is also provided with, multiple protective, makes the antibacterial and deodouring performance of wallpaper obtain the raising of largeizationr, and performance is more superior, in antibiotic layer, used polyvinyl alcohol and zeolite with carrying silver, the polyvinyl alcohol under aforementioned proportion and zeolite with carrying silver mixed liquor, have superior anti-microbial property.
The material of described water proofing property coating is JS water-repellent paint, and coating layer thickness is 0.5-0.8mm.
The material of described basic unit is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth.
The main material of described absorbing and deodorizing layer is diatomite, and thickness is 1-2mm.The feature that porous, high porosity, specific area are large, adsorptivity is strong that diatomite has, has good deodorizing effect.
Antibacterial and deodouring composite bed comprises the material of following mass percent: chitin 10-15 part, microcapsule essence 5-8 part, curing agent 3-5 part, softener stearic acid triethanolamine ester quaternary 1-2 part, the thickness of described antibacterial and deodouring composite bed is 0.3-0.5mm.Chitin has antibacterial effect well, and microcapsule essence has directionality, has deodorizing effect, and both share, and makes wallpaper in antibacterial and deodouring, also have armaticity.
Described coating layer is polyethylene film, and thickness is 0.2-0.4mm.
Described softener is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is organosilicon antibacterial agent CTU-1, and mould inhibitor is that Zinc Pyrithione, fire retardant are magnesium hydroxide.Various reagents ratio used, compared with environmental protection, does not contain the heavy metal banning use of of national regulation.
Described curing agent is calcium carbonate.
Beneficial effect: environment-friendly type antibiotic deodorizing wallpaper provided by the invention compared with prior art, has the following advantages:
1, wallpaper of the present invention, is provided with antiseptic, deodorant at coating layer, makes wallpaper have antibacterial and deodouring, further be provided with again absorbing and deodorizing layer, antibiotic layer, antibacterial and deodouring composite bed simultaneously, multiple protective, makes the antibacterial and deodouring performance of wallpaper obtain the raising of largeizationr, and performance is more superior;
2, the present invention is provided with water proofing property coating, coating layer, further protected wallpaper, extended the service life of wallpaper;
3, each layer of reagent environmental protection using of the present invention, meet the regulation of GB18585-2001, do not contain the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that ban use of of national regulation, do not contain formaldehyde, do not contain Vinyl Chloride Monomer, can not cause secondary pollution yet;
4, wallpaper of the present invention is except antibacterial and deodouring superior performance, and the performance of the each side such as its mildew resistance, anti-flammability, flexibility is all more balanced, good, is the multi-functional wallpaper of a environmental type on the whole.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; but illustrate that protection scope of the present invention is not limited to the concrete scope of the present embodiment simultaneously; based on the embodiment in the present invention; those of ordinary skill in the art, not making the every other embodiment obtaining under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1
A kind of environment-friendly type antibiotic deodorizing wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, above described basic unit 2, be provided with coating layer 3, described coating layer 3 is provided with antibiotic layer 4 above, and described antibiotic layer 4 is provided with absorbing and deodorizing layer 5 above, and described absorbing and deodorizing layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 is coated with antibacterial and deodouring composite bed 7 above, and described antibacterial and deodouring composite bed 7 is provided with coating layer 8 above.
Described water proofing property coating 1 material is JS water-repellent paint, and coating layer thickness is 0.5mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:36 part, 5.5 parts of active carbons, 5.4 parts, zeolite, 1.1 parts of softener stearic acid triethanolamine ester quaternaries, 0.2 part of retention agent guar gum, 1 part of wet strength agent PAE resin, 3 parts of aluminum orthophoshpates, 2 parts of copper acid methyl celluloses, 4 parts of antiseptic organosilicon antibacterial agent CTU-1,3 parts of mould inhibitor Zinc Pyrithione, 3 parts of fire retardant magnesium hydroxides, 2 parts of titanium dioxides, remainder is deionized water, and the thickness of described coating layer 3 is 0.6mm;
Described antibiotic layer 4 comprises following composition by weight: 20 parts of polyvinyl alcohol, and 0.6 part of zeolite with carrying silver, 76 parts of deionized waters, the thickness of described antibiotic layer 4 is 0.4mm; Zeolite with carrying silver preparation method in described antibiotic layer 4 is: the AgNO3 crystal that accurately takes 4.2 g left and right, by deionized water dissolving and be diluted to 0.1 mol/L, stand-by, and then the zeolite that takes 10g left and right is scattered in the AgNO3 of 100 mL 0.1mol/L, rare nitric acid adjusts pH value to 7 left and right, 70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reaction 2-3 h at this temperature, reaction finishes rear decompress filter and separates, and the filter cake obtaining is with being drying to obtain needed zeolite with carrying silver after deionized water washing for several times; Coating fluid in antibiotic layer 4 is mainly first with deionized water, polyvinyl alcohol to be uniformly dissolved, and then the zeolite with carrying silver making is put into stirring and dissolving in poly-vinyl alcohol solution;
The material of described absorbing and deodorizing layer 5 is diatomite, and thickness is 1.2mm;
Described antibacterial and deodouring composite bed 7 comprises the material of following mass percent: 11 parts of chitins, 5.5 parts of microcapsule essences, 3 parts, curing agent calcium carbonate, 1 part of softener stearic acid triethanolamine ester quaternary, and the thickness of described antibacterial and deodouring composite bed 7 is 0.3mm;
Described coating layer 8 is polyethylene film, and thickness is 0.2mm.
embodiment 2
A kind of environment-friendly type antibiotic deodorizing wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, above described basic unit 2, be provided with coating layer 3, described coating layer 3 is provided with antibiotic layer 4 above, and described antibiotic layer 4 is provided with absorbing and deodorizing layer 5 above, and described absorbing and deodorizing layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 is coated with antibacterial and deodouring composite bed 7 above, and described antibacterial and deodouring composite bed 7 is provided with coating layer 8 above.
Described water proofing property coating 1 material is JS water-repellent paint, and coating layer thickness is 0.64mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:38 part, 6.5 parts of active carbons, 6.5 parts, zeolite, 1.6 parts of softener stearic acid triethanolamine ester quaternaries, 0.3 part of retention agent guar gum, 1.6 parts of wet strength agent PAE resins, 4 parts of aluminum orthophoshpates, 2.6 parts of copper acid methyl celluloses, 4.5 parts of antiseptic organosilicon antibacterial agent CTU-1,3.5 parts of mould inhibitor Zinc Pyrithione, 3.4 parts of fire retardant magnesium hydroxides, 2.6 parts of titanium dioxides, remainder is deionized water, and the thickness of described coating layer 3 is 0.8mm;
Described antibiotic layer 4 comprises following composition by weight: 21 parts of polyvinyl alcohol, and 0.8 part of zeolite with carrying silver, 78 parts of deionized waters, the thickness of described antibiotic layer 4 is 0.5mm; Zeolite with carrying silver preparation method in described antibiotic layer 4 is: the AgNO3 crystal that accurately takes 4.2 g left and right, by deionized water dissolving and be diluted to 0.1 mol/L, stand-by, and then the zeolite that takes 10g left and right is scattered in the AgNO3 of 100 mL 0.1mol/L, rare nitric acid adjusts pH value to 7 left and right, 70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reaction 2-3 h at this temperature, reaction finishes rear decompress filter and separates, and the filter cake obtaining is with being drying to obtain needed zeolite with carrying silver after deionized water washing for several times; Coating fluid in antibiotic layer 4 is mainly first with deionized water, polyvinyl alcohol to be uniformly dissolved, and then the zeolite with carrying silver making is put into stirring and dissolving in poly-vinyl alcohol solution;
The material of described absorbing and deodorizing layer 5 is diatomite, and thickness is 1.6mm;
Described antibacterial and deodouring composite bed 7 comprises the material of following mass percent: 13.6 parts of chitins, 7 parts of microcapsule essences, 4 parts, curing agent calcium carbonate, 1.5 parts of softener stearic acid triethanolamine ester quaternaries, and the thickness of described antibacterial and deodouring composite bed 7 is 0.4mm;
Described coating layer 8 is polyethylene film, and thickness is 0.3mm.
embodiment 3
A kind of environment-friendly type antibiotic deodorizing wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, above described basic unit 2, be provided with coating layer 3, described coating layer 3 is provided with antibiotic layer 4 above, and described antibiotic layer 4 is provided with absorbing and deodorizing layer 5 above, and described absorbing and deodorizing layer 5 is provided with printed pattern layer 6 above, described printed pattern layer 6 is coated with antibacterial and deodouring composite bed 7 above, and described antibacterial and deodouring composite bed 7 is provided with coating layer 8 above.
Described water proofing property coating 1 material is JS water-repellent paint, and coating layer thickness is 0.8mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:40 part, 8 parts of active carbons, 8 parts, zeolite, 2 parts of softener stearic acid triethanolamine ester quaternaries, 0.4 part of retention agent guar gum, 2 parts of wet strength agent PAE resins, 5 parts of aluminum orthophoshpates, 3 parts of copper acid methyl celluloses, 5 parts of antiseptic organosilicon antibacterial agent CTU-1,4 parts of mould inhibitor Zinc Pyrithione, 4 parts of fire retardant magnesium hydroxides, 3 parts of titanium dioxides, remainder is deionized water, and the thickness of described coating layer 3 is 1mm;
Described antibiotic layer 4 comprises following composition by weight: 22 parts of polyvinyl alcohol, and 1 part of zeolite with carrying silver, 80 parts of deionized waters, the thickness of described antibiotic layer 4 is 0.6mm; Zeolite with carrying silver preparation method in described antibiotic layer 4 is: the AgNO3 crystal that accurately takes 4.2 g left and right, by deionized water dissolving and be diluted to 0.1 mol/L, stand-by, and then the zeolite that takes 10g left and right is scattered in the AgNO3 of 100 mL 0.1mol/L, rare nitric acid adjusts pH value to 7 left and right, 70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reaction 2-3 h at this temperature, reaction finishes rear decompress filter and separates, and the filter cake obtaining is with being drying to obtain needed zeolite with carrying silver after deionized water washing for several times; Coating fluid in antibiotic layer 4 is mainly first with deionized water, polyvinyl alcohol to be uniformly dissolved, and then the zeolite with carrying silver making is put into stirring and dissolving in poly-vinyl alcohol solution;
The material of described absorbing and deodorizing layer 5 is diatomite, and thickness is 2mm;
Described antibacterial and deodouring composite bed 7 comprises the material of following mass percent: 15 parts of chitins, 8 parts of microcapsule essences, 5 parts, curing agent calcium carbonate, 2 parts of softener stearic acid triethanolamine ester quaternaries, and the thickness of described antibacterial and deodouring composite bed 7 is 0.5mm;
Described coating layer 8 is polyethylene film, and thickness is 0.4mm.
The manufacture craft of the wallpaper of example wallpaper routinely above-mentioned time, through paste producing, coating, dry, printing, foaming, embossing, cooling, trimming, rolling.
The wallpaper making according to above-described embodiment meets the regulation of GB18585-2001, do not contain the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that ban use of of national regulation, do not contain formaldehyde, do not contain Vinyl Chloride Monomer, have good antibacterial and deodouring performance, be the antibacterial and deodouring wallpaper of a environment-friendly type simultaneously.
Above-described embodiment is only explanation technical conceive of the present invention and feature, its objective is to allow to be familiar with these those skilled in the art and can to understand content of the present invention enforcement according to this, can not limit the scope of the invention with this.All equivalents that Spirit Essence has been done according to the present invention or modification, within all should being encompassed in protection scope of the present invention.