CN104060500B - A kind of environment-friendly type antibiotic Waterproof wallpaper - Google Patents

A kind of environment-friendly type antibiotic Waterproof wallpaper Download PDF

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CN104060500B
CN104060500B CN201410236307.1A CN201410236307A CN104060500B CN 104060500 B CN104060500 B CN 104060500B CN 201410236307 A CN201410236307 A CN 201410236307A CN 104060500 B CN104060500 B CN 104060500B
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bamboo
thickness
environment
wallpaper
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CN104060500A (en
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吴海军
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Suzhou Shengdian Enterprise Management Consulting Co.,Ltd.
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SUZHOU CHENGSHENG INFORMATION TECHNOLOGY Co Ltd
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Abstract

The invention provides and give a kind of environment-friendly type antibiotic Waterproof wallpaper, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, described basic unit is provided with coating layer above, bamboo is provided with above described coating layer, bamboo-carbon fibre back-up coat is provided with above described bamboo, described bamboo-carbon fibre back-up coat is provided with antibiotic layer, printed pattern layer is provided with above described antibiotic layer, described printed pattern layer coated thereon has damp-proof layer, be provided with polytetrafluoroethylene floor above described damp-proof layer, described polytetrafluoroethylene floor is provided with coating layer.The bamboo that the present invention is provided with, polytetrafluoroethylene (PTFE), damp-proof layer, coating layer these four layers all has certain moisture resistance, and quadruple is protected, and makes wallpaper of the present invention have excellent moisture resistance; The present invention has been provided with antibiotic layer, bamboo, coating layer all have antibiotic property, triple protection, makes wallpaper of the present invention have excellent antibiotic property.

Description

A kind of environment-friendly type antibiotic Waterproof wallpaper
Technical field
The present invention relates to a kind of environment-friendly type antibiotic Waterproof wallpaper.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material quite widely.The feature that other house decorative materials multiple such as color is various, pattern enriches because wallpaper has, luxurious style, safety and environmental protection, easy construction, affordable are incomparable, therefore obtain the universal of certain degree at developed countries and regions such as America and Europe, Southeast Asia, Japan.In recent years, China's indoor decorating is persistently overheating, and the wallpaper be once given the cold shoulder has come into parlor, bedroom, hotel, meeting room etc. again with its gorgeous new attitude.
In the past, wallpaper comes into the life of people as just a kind of decorative material, people to its require many ornamental with aesthetic property above, along with the raising of people's living standard, people need to want the wallpaper of high-quality to decorate the life of oneself, and people's other Functional Requirement to wallpaper also gets more and more.
The moisture resistance of wallpaper is a kind of important performance, if wallpaper does not have moisture resistance, so not only can greatly reduce the service life of wallpaper, if wallpaper does not have moisture resistance simultaneously, can slowly become moist, so also can grow various bacterium, the environment of indoor inhabitation is deteriorated.
Along with improving constantly of people's material and cultural life, people for healthy and cleaning problems care and the life seek of the peaceful and comfortable equivalent comfort energy of gracefulness is also being improved day by day.But in the middle of daily life, unavoidable kitchen, toilet, hospital ward, bedroom peculiar smell and the life stink such as tobacco, body sweat, often affect the comfortableness of people's life.Particularly along with the arrival of aging society, the aged person of bed and the person of recuperating increase, and for preventing stench, the demand of environmental protect also increases thereupon, and these all can promote development that is antibacterial, deodorising product undoubtedly.
Wallpaper in the market also has the little of humidity resistance when possessing antibacterial and deodouring simultaneously, is therefore necessary to develop a kind of environment-friendly type antibiotic Waterproof wallpaper.
Summary of the invention
Goal of the invention: the object of the invention is to solve the deficiencies in the prior art, provides a kind of environment-friendly type antibiotic Waterproof wallpaper.
Technical scheme: in order to realize above object, a kind of environment-friendly type antibiotic Waterproof wallpaper of the present invention, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, described basic unit is provided with coating layer above, bamboo is provided with above described coating layer, bamboo-carbon fibre back-up coat is provided with above described bamboo, described bamboo-carbon fibre back-up coat is provided with antibiotic layer, printed pattern layer is provided with above described antibiotic layer, described printed pattern layer coated thereon has damp-proof layer, polytetrafluoroethylene floor is provided with above described damp-proof layer, described polytetrafluoroethylene floor is provided with coating layer, described coating layer is made up of the material of following mass percent: PP:35-40 part, sepiolite 5-8 part, zeolite 5-8 part, softener 1-2 part, retention agent 0.3-0.5 part, wet strength agent 1-2 part, aluminum orthophoshpate 3-5 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, mould inhibitor 3-4 part, fire retardant 3-4 part, titanium dioxide 2-3 part, remainder is deionized water, and the thickness of described coating layer is 0.1-0.3mm, described antibiotic layer comprises following composition by weight: polyvinyl alcohol 20-22 part, zeolite with carrying silver 0.5-1 part, deionized water 75-80 part, and the thickness of described antibiotic layer is 0.1-0.3mm, described damp-proof layer comprises following composition by weight: paraffin 10-12 part, glass fibre 8-10 part, sepiolite 5-8 part, EVA resin 10-15 part, and the thickness of described damp-proof layer is 0.2-0.4mm.Sepiolite is contained in coating layer of the present invention, zeolite, aluminum orthophoshpate, the deodorant such as copper acid methyl cellulose, wherein sepiolite is a kind of fibrous rich-magnesium clay mineral, there is good absorption, fire-retardant, the performance such as high temperature resistant, and itself be environment-protecting asepsis material, the noxious materials such as the ammonia in air can be gone out as deodorant, can also use as fire retardant, zeolite is porous inorganic substances, there is absorption, catalyst and ion exchanging function, there is the premium properties of adsorption of hydrogen sulfide and ammonia, there is good deodorizing effect, the easy adsorb ammonia of aluminum orthophoshpate, the tools such as amine material frowzy, simultaneously also fine to the adsorption effect of mercaptan, a kind of well deodorant of copper acid methyl cellulose, gas permeability is high, effective, deodorizing capability can keep six months, can eliminate completely in 30 minutes the stench of ammonia and hydrogen sulfide, this several deodorant merges use, substantially can stink completely in deodorization chamber * winding paper, simultaneously, coating layer also comprises antiseptic, mould inhibitor, fire retardant, make the properties of wallpaper more balanced, superior, main component in coating layer is PP, but not PVC, Vinyl Chloride Monomer can not be produced, environmental protection, the water proofing property coating that bottom is provided with, the coating layer that topmost is provided with, protects wallpaper further, extends the service life of wallpaper, the present invention is also provided with bamboo, take full advantage of that bamboo-carbon fibre moisture absorption is ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, environmental protection, the feature such as humidity regulation, the bamboo-carbon fibre back-up coat be provided with carries out reinforcement protection to coating layer and bamboo further, employ polyvinyl alcohol and zeolite with carrying silver in antibiotic layer, the polyvinyl alcohol under aforementioned proportion and zeolite with carrying silver mixed liquor, have superior anti-microbial property, be provided with polytetrafluoroethylene floor, polytetrafluoroethylene (PTFE) is a kind of excellent environment-friendly type waterproof ventilative material, and wallpaper can be made to have water-proof breathable properties well, the present invention is also provided with damp-proof layer in addition, makes wallpaper have excellent moisture resistance.
The material of described water proofing property coating is JS water-repellent paint, and coating layer thickness is 0.2-0.4mm.
The material of described basic unit is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth.
The thickness of described bamboo is 0.2-0.4mm.
The thickness of described bamboo-carbon fibre back-up coat is 0.1-0.3mm.
The thickness of described polytetrafluoroethylene floor is 0.2-0.3mm.
Described coating layer is polyethylene film, and thickness is 0.2-0.4mm.Polyethylene has excellent moisture resistance, makes the moisture resistance of wallpaper more superior.
Described softener is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is shitosan, and mould inhibitor is Zinc Pyrithione, fire retardant is magnesium hydroxide.Used various reagents ratios comparatively environmental protection, the heavy metal prohibitted the use not containing national regulation.
Beneficial effect: environment-friendly type antibiotic Waterproof wallpaper provided by the invention compared with prior art, has the following advantages:
1, wallpaper of the present invention, is provided with antiseptic, deodorant, fire retardant, mould inhibitor, antistatic additive at coating layer, makes wallpaper have antibacterial and deodouring, anti-flammability, anti-mildew resistance, static behaviour, the overall performance comparative superiority of wallpaper;
2, the water proofing property coating, the coating layer that are provided with of the present invention, protects wallpaper further, extends the service life of wallpaper;
3, the present invention is also provided with bamboo, take full advantage of that bamboo-carbon fibre moisture absorption is ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, environmental protection, the feature such as humidity regulation, the bamboo-carbon fibre back-up coat be provided with carries out reinforcement protection to coating layer and bamboo further; Be provided with polytetrafluoroethylene floor, polytetrafluoroethylene (PTFE) is a kind of excellent environment-friendly type waterproof ventilative material, and wallpaper can be made to have water-proof breathable properties well; The present invention is also provided with damp-proof layer in addition, makes wallpaper have excellent moisture resistance, and coating layer also has moisture resistance simultaneously; The bamboo that the present invention is provided with, polytetrafluoroethylene (PTFE), damp-proof layer, coating layer these four layers all has certain moisture resistance, and quadruple is protected, and makes wallpaper of the present invention have excellent moisture resistance;
4, the present invention has been provided with antibiotic layer, bamboo, coating layer all have antibiotic property, triple protection, makes wallpaper of the present invention have excellent antibiotic property;
5, the reagent environmental protection of each layer use of the present invention, meet the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer, also can not cause secondary pollution;
6, while wallpaper of the present invention has good antibacterial and deodouring, also having good moisture resistance, is the multi-functional wallpaper of a environmental type on the whole.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention;
In figure: 1-water proofing property coating, 2-basic unit, 3-coating layer, 4-bamboo, 5-bamboo-carbon fibre back-up coat, 6-antibiotic layer, 7-printed pattern layer, 8-damp-proof layer, 9-polytetrafluoroethylene floor, 10-coating layer.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; but illustrate that protection scope of the present invention is not limited to the concrete scope of the present embodiment simultaneously; based on the embodiment in the present invention; those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1
A kind of environment-friendly type antibiotic Waterproof wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with bamboo 4 above, described bamboo 4 is provided with bamboo-carbon fibre back-up coat 5 above, described bamboo-carbon fibre back-up coat 5 is provided with antibiotic layer 6, described antibiotic layer 6 is provided with printed pattern layer 7 above, described printed pattern layer 7 coated thereon has damp-proof layer 8, described damp-proof layer 8 is provided with polytetrafluoroethylene floor 9 above, and described polytetrafluoroethylene floor 9 is provided with coating layer 10.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.2mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:35 part, sepiolite 5 parts, 5 parts, zeolite, softener stearic acid triethanolamine ester quaternary 1 part, retention agent guar gum 0.3 part, wet strength agent PAE resin 1 part, aluminum orthophoshpate 3 parts, copper acid methyl cellulose 2 parts, antiseptic shitosan 4 parts, mould inhibitor Zinc Pyrithione 3 parts, fire retardant magnesium hydroxide 3 parts, titanium dioxide 2 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.3mm;
The thickness of described bamboo 4 is 0.2mm;
The thickness of described bamboo-carbon fibre back-up coat 5 is 0.1mm;
Described antibiotic layer 6 comprises following composition by weight: polyvinyl alcohol 20 parts, zeolite with carrying silver 0.5 part, deionized water 75 parts, and the thickness of described antibiotic layer 6 is 0.3mm; Zeolite with carrying silver preparation method in described antibiotic layer 6 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7,70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, and the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times; Coating fluid in antibiotic layer 6 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution;
Described damp-proof layer 8 comprises following composition by weight: 10 parts, paraffin, 8 parts, glass fibre, sepiolite 5 parts, EVA resin 10 parts, and the thickness of described damp-proof layer 8 is 0.4mm;
The thickness of described polytetrafluoroethylene floor 9 is 0.2mm;
Described coating layer 10 is polyethylene film, and thickness is 0.2mm.Polyethylene has excellent moisture resistance, makes the moisture resistance of wallpaper more superior.
embodiment 2
A kind of environment-friendly type antibiotic Waterproof wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with bamboo 4 above, described bamboo 4 is provided with bamboo-carbon fibre back-up coat 5 above, described bamboo-carbon fibre back-up coat 5 is provided with antibiotic layer 6, described antibiotic layer 6 is provided with printed pattern layer 7 above, described printed pattern layer 7 coated thereon has damp-proof layer 8, described damp-proof layer 8 is provided with polytetrafluoroethylene floor 9 above, and described polytetrafluoroethylene floor 9 is provided with coating layer 10.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.3mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:38 part, sepiolite 6 parts, 7 parts, zeolite, softener stearic acid triethanolamine ester quaternary 1.5 parts, retention agent guar gum 0.4 part, wet strength agent PAE resin 1.5 parts, aluminum orthophoshpate 4 parts, copper acid methyl cellulose 2.5 parts, antiseptic shitosan 4.5 parts, mould inhibitor Zinc Pyrithione 3.5 parts, fire retardant magnesium hydroxide 3.5 parts, titanium dioxide 2.5 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.2mm;
The thickness of described bamboo 4 is 0.3mm;
The thickness of described bamboo-carbon fibre back-up coat 5 is 0.2mm;
Described antibiotic layer 6 comprises following composition by weight: polyvinyl alcohol 21 parts, zeolite with carrying silver 0.8 part, deionized water 78 parts, and the thickness of described antibiotic layer 6 is 0.2mm; Zeolite with carrying silver preparation method in described antibiotic layer 6 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7,70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, and the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times; Coating fluid in antibiotic layer 6 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution;
Described damp-proof layer 8 comprises following composition by weight: 11 parts, paraffin, 9 parts, glass fibre, sepiolite 7 parts, EVA resin 12 parts, and the thickness of described damp-proof layer 8 is 0.3mm;
The thickness of described polytetrafluoroethylene floor 9 is 0.2mm;
Described coating layer 10 is polyethylene film, and thickness is 0.3mm.Polyethylene has excellent moisture resistance, makes the moisture resistance of wallpaper more superior.
embodiment 3
A kind of environment-friendly type antibiotic Waterproof wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with bamboo 4 above, described bamboo 4 is provided with bamboo-carbon fibre back-up coat 5 above, described bamboo-carbon fibre back-up coat 5 is provided with antibiotic layer 6, described antibiotic layer 6 is provided with printed pattern layer 7 above, described printed pattern layer 7 coated thereon has damp-proof layer 8, described damp-proof layer 8 is provided with polytetrafluoroethylene floor 9 above, and described polytetrafluoroethylene floor 9 is provided with coating layer 10.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.4mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:40 part, sepiolite 8 parts, 8 parts, zeolite, softener stearic acid triethanolamine ester quaternary 2 parts, retention agent guar gum 0.5 part, wet strength agent PAE resin 2 parts, aluminum orthophoshpate 5 parts, copper acid methyl cellulose 3 parts, antiseptic shitosan 5 parts, mould inhibitor Zinc Pyrithione 4 parts, fire retardant magnesium hydroxide 4 parts, titanium dioxide 3 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.1mm;
The thickness of described bamboo 4 is 0.4mm;
The thickness of described bamboo-carbon fibre back-up coat 5 is 0.3mm;
Described antibiotic layer 6 comprises following composition by weight: polyvinyl alcohol 22 parts, zeolite with carrying silver 1 part, deionized water 80 parts, and the thickness of described antibiotic layer 6 is 0.1mm; Zeolite with carrying silver preparation method in described antibiotic layer 6 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7,70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, and the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times; Coating fluid in antibiotic layer 6 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution;
Described damp-proof layer 8 comprises following composition by weight: 12 parts, paraffin, 10 parts, glass fibre, sepiolite 8 parts, EVA resin 15 parts, and the thickness of described damp-proof layer 8 is 0.2mm;
The thickness of described polytetrafluoroethylene floor 9 is 0.3mm;
Described coating layer 10 is polyethylene film, and thickness is 0.4mm.Polyethylene has excellent moisture resistance, makes the moisture resistance of wallpaper more superior.
The manufacture craft of the wallpaper of example wallpaper routinely time above-mentioned, through paste producing, coating, drying, printing, foaming, embossing, cooling, trimming, rolling.
The wallpaper obtained according to above-described embodiment meets the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer, while wallpaper of the present invention has good antibacterial moisture resistance, be the multi-functional wallpaper of a environmental type on the whole.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its objective is to allow and is familiar with these those skilled in the art and can understands content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalents done by Spirit Essence of the present invention or modification, all should be encompassed within protection scope of the present invention.

Claims (8)

1. an environment-friendly type antibiotic Waterproof wallpaper, it is characterized in that: comprise basic unit (2), the back side of described basic unit (2) is provided with water proofing property coating (1), described basic unit (2) is provided with coating layer (3) above, described coating layer (3) is provided with bamboo (4) above, described bamboo (4) is provided with bamboo-carbon fibre back-up coat (5) above, described bamboo-carbon fibre back-up coat (5) is provided with antibiotic layer (6), described antibiotic layer (6) is provided with printed pattern layer (7) above, described printed pattern layer (7) coated thereon has damp-proof layer (8), described damp-proof layer (8) is provided with polytetrafluoroethylene floor (9) above, described polytetrafluoroethylene floor (9) is provided with coating layer (10), described coating layer (3) is made up of the material of following composition by weight: PP:35-40 part, sepiolite 5-8 part, zeolite 5-8 part, softener 1-2 part, retention agent 0.3-0.5 part, wet strength agent 1-2 part, aluminum orthophoshpate 3-5 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, mould inhibitor 3-4 part, fire retardant 3-4 part, titanium dioxide 2-3 part, remainder is deionized water, and the thickness of described coating layer (3) is 0.1-0.3mm, described antibiotic layer (6) comprises following composition by weight: polyvinyl alcohol 20-22 part, zeolite with carrying silver 0.5-1 part, deionized water 75-80 part, and the thickness of described antibiotic layer (6) is 0.1-0.3mm, described damp-proof layer (8) comprises following composition by weight: paraffin 10-12 part, glass fibre 8-10 part, sepiolite 5-8 part, EVA resin 10-15 part, and the thickness of described damp-proof layer (8) is 0.2-0.4mm.
2. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, is characterized in that: the material of described water proofing property coating (1) is JS water-repellent paint, and coating layer thickness is 0.2-0.4mm.
3. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, is characterized in that: the material of described basic unit (2) is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth.
4. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, is characterized in that: the thickness of described bamboo (4) is 0.2-0.4mm.
5. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, is characterized in that: the thickness of described bamboo-carbon fibre back-up coat (5) is 0.1-0.3mm.
6. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, is characterized in that: the thickness of described polytetrafluoroethylene floor (9) is 0.2-0.3mm.
7. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, is characterized in that: described coating layer (10) is polyethylene film, and thickness is 0.2-0.4mm.
8. environment-friendly type antibiotic Waterproof wallpaper according to claim 1, it is characterized in that: described softener is stearic acid triethanolamine ester quaternary, retention agent is guar gum, and wet strength agent is PAE resin, antiseptic is shitosan, and mould inhibitor is Zinc Pyrithione, fire retardant is magnesium hydroxide.
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CN106812024A (en) * 2015-12-01 2017-06-09 周依宁 A kind of Moisture-proof wallpaper
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CN106088495A (en) * 2016-06-20 2016-11-09 钱学东 A kind of antimildew and antibacterial composite wallpaper
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CN107009686A (en) * 2017-04-26 2017-08-04 杨太松 A kind of stalk cellulose corrugated paper moistureproof with antibacterial and preparation method thereof
CN107386010A (en) * 2017-08-01 2017-11-24 合肥图森工业设计有限公司 A kind of oil-stain-preventing wallpaper and preparation method thereof
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