CN103469987A - Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper - Google Patents

Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper Download PDF

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Publication number
CN103469987A
CN103469987A CN2013103483273A CN201310348327A CN103469987A CN 103469987 A CN103469987 A CN 103469987A CN 2013103483273 A CN2013103483273 A CN 2013103483273A CN 201310348327 A CN201310348327 A CN 201310348327A CN 103469987 A CN103469987 A CN 103469987A
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CN
China
Prior art keywords
environment
formaldehyde
wallpaper
antimildew
friendly type
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CN2013103483273A
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Chinese (zh)
Inventor
吴海军
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苏州国昊壁纸有限公司
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Priority to CN2013103483273A priority Critical patent/CN103469987A/en
Publication of CN103469987A publication Critical patent/CN103469987A/en

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Abstract

The invention provides a type of environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper, which is characterized by comprising a base layer, wherein the surface of the base layer is provided with an absorption layer; the surface of the adsorption layer is provided with a coating layer; the adsorption layer is provided with an absorbent; the coating layer consists of the following materials in percentage by mass: 35-45 percent of PVC (Polyvinyl Chloride), 5-10 percent of anti-bacterial agent, 3-4 percent of mold-proof agent, 5-15 percent of anion powder, 4-5 percent of titanium dioxide and 5-10 percent of natural gypsum. The wallpaper provided by the invention plays roles in protecting the environment, removing formaldehyde, resisting bacteria and preventing mold, and is a type of environment-friendly wallpaper.

Description

Environment-friendly type is except formaldehyde antimildew and antibacterial wallpaper
Technical field
The present invention relates to a kind of environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
Background technology
Wallpaper is by apply materials, equipment and technology gimmick, take the indoor wall ornament materials that color and figure line composite design are infinitely abundant as feature, expressive force, can conveniently meet diversity individual character esthetic requirement and fashion demand, is international and domestic most popular indoor wall ornament materials now.Wallpaper is the same with other ornament materials, and along with the development of World Economics culture, development is changing.
The development of wallpaper is four developing stage of experience approximately:
1, the paper substrate wallpaper stage: the paper substrate wallpaper is the wallpaper developed the earliest, but paper impression case, embossing or fabric.Advantage: gas permeable substrate is good, can make the moisture in body of wall basic unit outwards distribute, and is difficult for causing the phenomenons such as variable color, bubbling, low price.Shortcoming: poor performance, not water-fast, be not easy to clean and construction easy fracture, less production at present.
2, the foaming wallpaper stage: be foaming wallpaper period prevailing the eighties in last century." foaming " claims again the foaming of half tone embossment, refers to and add blowing agent in raw material, is aided with in process of production high temperature, makes blowing agent complete the process of similar " fermentation ".Advantage: third dimension is strong, can increase the spatial impression in room.Shortcoming: not wear-resisting, easily scratch, polluted.
3, the glue surface wallpaper stage: in the phase at the end of the eighties in last century, occurred the glue surface wallpaper on market, this is to produce at present at most, most widely used a kind of wallpaper.It is the body paper with certain performance be basic unit, polyvinyl chloride (PVC) film of take is surface layer, through operations such as compound, stamp, embossing, makes.Advantage: do not foam, quality is harder, waterproof, and protection against the tide, durable, the stamp exquisiteness, embossing texture is good, can show arbitrarily various patterns and decorative pattern on wallpaper, and color representation power is good, practical.Shortcoming: can volatilize some organic compounds, easily aging, airtight, the recovery of can not degrading.
4, the environmental protection wallpaper stage: in recent years, to health, nontoxic, harmless, free from extraneous odour, good permeability, the new green environment protection wallpaper that decoration functions is strong extensively get consumer reception.Wherein paper substrate wallpaper, one Bucky wall paper, quartz fibre ornament are Typical Representatives.
Formaldehyde is a kind of plasm poisonous substance that destroys biological cell protein, can people's skin, respiratory tract and internal organ be caused damage, anesthesia people's nervous centralis, can cause pulmonary edema, hepatic coma, kidney failure etc. the World Health Organization confirms that formaldehyde is teratogenesis, carcinogen, be allergen, Long Term Contact will cause gene mutation.The formaldehyde pollution problem mainly concentrates in room, textile and food. and contain in the artificial boards such as the veneer in indoor decoration material and furniture, fiberboard, shaving board and take in a large number formaldehyde as main Lauxite, all contain formaldehyde in all kinds of paint, coating.
Some wallpapers except formaldehyde also have been full of in the market, but the release period of formaldehyde reaches 3-15, general can only when concentration of formaldehyde is larger, remove formaldehyde except the formaldehyde wallpaper, the follow-up formaldehyde discharged can't be removed, and that those follow-up formaldehyde that discharge are present in is indoor, still human body is had to very strong toxic action.Therefore, that develops a kind of environment-friendly type can be fundamentally, and the wallpaper except formaldehyde of continuation is imperative.
Summary of the invention
goal of the invention: purpose of the present invention just is to provide a kind of environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
technical scheme:for achieving the above object, the present invention has taked following technical scheme:
A kind of environment-friendly type is except formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit, described substrate surface is provided with adsorption layer, described adsorption layer surface is provided with coating layer, described adsorption layer is provided with adsorbent, described coating layer is comprised of the material of following mass percent: PVC:35-45 part, antiseptic 5-10 part, mould inhibitor: 3-4 part, negative ion powder: 5-15 part, titanium dioxide: 4-5 part, the plaster of paris: 5-10 part, remainder is deionized water.The coating layer that wallpaper of the present invention is provided with has well except the effect of formaldehyde antimildew and antibacterial, the negative ion powder that coating layer is provided with and the plaster of paris have well except the formaldehyde effect, the polyvinyl chloride resin used relatively environmental protection Wu pollutes, generally speaking, wallpaper of the present invention environmental protection is arranged, except formaldehyde, mildew-resistant, antibiotic effect.Because the release period of formaldehyde reaches 3-15, therefore, the present invention has added again the adsorption layer of one deck, the formaldehyde that adsorption layer slowly releases in can well absorption chamber, add negative ion powder and the plaster of paris of coating layer, just can well reach short-term and the long-term formaldehyde effect that removes.
Described adsorbent is at least one in modified molecular screen, active carbon, kieselguhr.
Described antiseptic is nano-ZnO and nano-TiO 2mixture, its average grain diameter is 40-90nm, described nano-TiO 2with the ratio of nano-ZnO be 1:1-1:3.Nano level ZnO and TiO 2mixture good antibacterial action is arranged.
Described mould inhibitor is ZPT.
The tourmaline of the silicate that described negative ion powder is boracic.Negative ion powder is a kind of good formaldehyde scavenger, equally with the plaster of paris can well remove formaldehyde.
The material of described basic unit is nonwoven, pure cotton cloth, chemical fabric or blended cloth.
Environment-friendly type is except the preparation method of formaldehyde antimildew and antibacterial wallpaper, it is characterized in that this preparation method is: by the compression moulding forming machine, adsorption layer and basic unit's compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
beneficial effect:adopt the present invention of technique scheme to have the following advantages:
Wallpaper of the present invention is provided with adsorption layer and coating layer, the negative ion powder be provided with in coating layer and the plaster of paris are all good formaldehyde scavengers, and coating layer also is provided with antiseptic and mould inhibitor, moreover, the adsorbent that adsorption layer of the present invention is provided with also can have good suction-operated by PARA FORMALDEHYDE PRILLS(91,95), two-tube and under, so not only can effectively remove in a short time indoor formaldehyde, the formaldehyde of removing indoor follow-up release that can also be long-term, play good environmental-protection function, on the whole, wallpaper of the present invention has environmental protection, except formaldehyde, antibiotic, the effect of mildew-resistant, it is a kind of wallpaper of environmental protection.
The accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
In figure: 1-basic unit, 2-adsorption layer, 3-coating layer.
The specific embodiment
Below by specific embodiment, the present invention is further set forth.
Embodiment 1:
A kind of environment-friendly type according to the present embodiment is removed formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit 1, described basic unit 1 surface is provided with adsorption layer 2, described adsorption layer 2 surfaces are provided with coating layer 3, described adsorption layer 2 is provided with adsorbent, and described coating layer 3 is comprised of the material of following mass percent: PVC:35 part, nano-TiO 2: 3 parts, nano-ZnO: 3 parts, mould inhibitor ZPT: 3 parts, negative ion powder: 10 parts, titanium dioxide: 4 parts, the plaster of paris: 8 parts, remainder is deionized water.
Described adsorption layer 2 adsorbent used is active carbon.
This environment-friendly type is as follows except the preparation method of formaldehyde antimildew and antibacterial wallpaper:
By the compression moulding forming machine, adsorption layer 2 and basic unit's 1 compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer 3 by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
Embodiment 2:
A kind of environment-friendly type according to the present embodiment is removed formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit 1, described basic unit 1 surface is provided with adsorption layer 2, described adsorption layer 2 surfaces are provided with coating layer 3, described adsorption layer 2 is provided with adsorbent, and described coating layer 3 is comprised of the material of following mass percent: PVC:40 part, nano-TiO 2: 2 parts, nano-ZnO: 4 parts, mould inhibitor ZPT: 3 parts, negative ion powder: 10 parts, titanium dioxide: 5 parts, the plaster of paris: 8 parts, remainder is deionized water.
The mixture that described adsorption layer 2 adsorbent used is kieselguhr and active carbon, both ratios are 1:2.
This environment-friendly type is as follows except the preparation method of formaldehyde antimildew and antibacterial wallpaper:
By the compression moulding forming machine, adsorption layer 2 and basic unit's 1 compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer 3 by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
Embodiment 3:
A kind of environment-friendly type according to the present embodiment is removed formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit 1, described basic unit 1 surface is provided with adsorption layer 2, described adsorption layer 2 surfaces are provided with coating layer 3, described adsorption layer 2 is provided with adsorbent, and described coating layer 3 is comprised of the material of following mass percent: PVC:45 part, nano-TiO 2: 2 parts, nano-ZnO: 6 parts, mould inhibitor ZPT: 4 parts, negative ion powder: 15 parts, titanium dioxide: 4 parts, the plaster of paris: 5 parts, remainder is deionized water.
Described adsorption layer 2 adsorbent used is kieselguhr.
This environment-friendly type is as follows except the preparation method of formaldehyde antimildew and antibacterial wallpaper:
By the compression moulding forming machine, adsorption layer 2 and basic unit's 1 compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer 3 by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
Embodiment 4:
A kind of environment-friendly type according to the present embodiment is removed formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit 1, described basic unit 1 surface is provided with adsorption layer 2, described adsorption layer 2 surfaces are provided with coating layer 3, described adsorption layer 2 is provided with adsorbent, and described coating layer 3 is comprised of the material of following mass percent: PVC:45 part, nano-TiO 2: 2 parts, nano-ZnO: 4 parts, mould inhibitor ZPT: 3 parts, negative ion powder: 15 parts, titanium dioxide: 4 parts, the plaster of paris: 8 parts, remainder is deionized water.
Described adsorption layer 2 adsorbent used is modified molecular screen.
This environment-friendly type is as follows except the preparation method of formaldehyde antimildew and antibacterial wallpaper:
By the compression moulding forming machine, adsorption layer 2 and basic unit's 1 compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer 3 by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
Embodiment 5:
A kind of environment-friendly type according to the present embodiment is removed formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit 1, described basic unit 1 surface is provided with adsorption layer 2, described adsorption layer 2 surfaces are provided with coating layer 3, described adsorption layer 2 is provided with adsorbent, and described coating layer 3 is comprised of the material of following mass percent: PVC:45 part, nano-TiO 2: 3 parts, nano-ZnO: 6 parts, mould inhibitor ZPT: 3 parts, negative ion powder: 15 parts, titanium dioxide: 5 parts, the plaster of paris: 10 parts, remainder is deionized water.
Described adsorption layer 2 adsorbent used is modified molecular screen and diatomaceous mixture, and both ratios are 1:2.
This environment-friendly type is as follows except the preparation method of formaldehyde antimildew and antibacterial wallpaper:
By the compression moulding forming machine, adsorption layer 2 and basic unit's 1 compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer 3 by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
Embodiment 6:
A kind of environment-friendly type according to the present embodiment is removed formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit 1, described basic unit 1 surface is provided with adsorption layer 2, described adsorption layer 2 surfaces are provided with coating layer 3, described adsorption layer 2 is provided with adsorbent, and described coating layer 3 is comprised of the material of following mass percent: PVC:40 part, nano-TiO 2: 4 parts, nano-ZnO: 6 parts, mould inhibitor ZPT: 3 parts, negative ion powder: 10 parts, titanium dioxide: 5 parts, the plaster of paris: 10 parts, remainder is deionized water.
The mixture that described adsorption layer 2 adsorbent used is modified molecular screen and active carbon, both ratios are 1:2.
This environment-friendly type is as follows except the preparation method of formaldehyde antimildew and antibacterial wallpaper:
By the compression moulding forming machine, adsorption layer 2 and basic unit's 1 compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer 3 by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
The material of wallpaper of the present invention basic unit 1 is nonwoven, pure cotton cloth, chemical fabric or blended cloth.
Wallpaper of the present invention is provided with coating layer 3 and adsorption layer 1, and the negative ion powder contained in coating layer 3 and the plaster of paris are good formaldehyde scavengers, can well remove indoor formaldehyde, the mould inhibitor contained and antiseptic (nano-TiO 2with the nano-ZnO mixture) can play the antimildew and antibacterial effect, PVC used is a kind of resin of environment-friendly type, pollution-free to air; The adsorbent that simultaneously adsorption layer 2 is provided with can be long-term adsorption chamber in the follow-up formaldehyde discharged slowly.Wallpaper of the present invention so just reached environmental protection, except formaldehyde, mildew-resistant, antibiotic effect, be a good green wallpaper.
It is only below several specific embodiment of the present invention; should understand these embodiment only is not used in and limits the scope of the invention for the present invention is described; after having read the present invention; those skilled in the art all fall within claims of the present invention to the modification of the various equivalent form of values of the present invention and limit, and protection scope of the present invention should be as the criterion with claim of the present invention.

Claims (7)

1. an environment-friendly type is except formaldehyde antimildew and antibacterial wallpaper, it is characterized in that: it comprises basic unit (1), described basic unit (1) surface is provided with adsorption layer (2), described adsorption layer (2) surface is provided with coating layer (3), described adsorption layer (2) is provided with adsorbent, described coating layer (3) is comprised of the material of following mass percent: PVC:35-45 part, antiseptic 5-10 part, mould inhibitor: 3-4 part, negative ion powder: 5-15 part, titanium dioxide: 4-5 part, the plaster of paris: 5-10 part, remainder is deionized water.
2. environment-friendly type according to claim 1 is except formaldehyde antimildew and antibacterial wallpaper, and it is characterized in that: described adsorbent is at least one in modified molecular screen, active carbon, kieselguhr.
3. environment-friendly type according to claim 1 is except formaldehyde antimildew and antibacterial wallpaper, and it is characterized in that: described antiseptic is nano-ZnO and nano-TiO 2mixture, its average grain diameter is 40-90nm, described nano-TiO 2with the ratio of nano-ZnO be 1:1-1:3.
4. environment-friendly type according to claim 1 is except formaldehyde antimildew and antibacterial wallpaper, and it is characterized in that: described mould inhibitor is ZPT.
5. environment-friendly type according to claim 1, except formaldehyde antimildew and antibacterial wallpaper, is characterized in that: the tourmaline of the silicate that described negative ion powder is boracic.
6. environment-friendly type according to claim 1 is except formaldehyde antimildew and antibacterial wallpaper, and it is characterized in that: the material of described basic unit (1) is nonwoven, pure cotton cloth, chemical fabric or blended cloth.
7. an environment-friendly type as claimed in claim 1 is except the preparation method of formaldehyde antimildew and antibacterial wallpaper, it is characterized in that this preparation method is: by the compression moulding forming machine, described adsorption layer (2) and basic unit (1) compression moulding are combined, do as a whole, and then the upper coating fluid of described coating on the whole, described coating fluid prepares batching by described coating layer (3) by formula, stir and make, through super-dry gel, cooling, printing, embossing, can make described environment-friendly type except formaldehyde antimildew and antibacterial wallpaper.
CN2013103483273A 2013-08-12 2013-08-12 Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper CN103469987A (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103938826A (en) * 2014-03-16 2014-07-23 王兆进 Diatomaceous earth wallpaper
CN104060500A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Environment-friendly antibacterial moistureproof wallpaper
CN104060499A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Green environmental protection wallpaper with strong breathability
CN104074101A (en) * 2014-05-30 2014-10-01 苏州国昊壁纸有限公司 Environment-friendly antibacterial and deodorization wallpaper
CN104074100A (en) * 2014-05-30 2014-10-01 苏州国昊壁纸有限公司 Color-changeable antibacterial and environment-friendly wallpaper
CN104074324A (en) * 2014-05-30 2014-10-01 苏州国昊壁纸有限公司 Environment-friendly wallpaper containing bamboo charcoal fiber
CN104746382A (en) * 2015-03-11 2015-07-01 山东鲁南新材料股份有限公司 Wallpaper base paper capable of adsorbing formaldehyde and production method thereof
CN105386369A (en) * 2015-11-16 2016-03-09 太仓东能环保设备有限公司 Novel deodorant wallpaper and preparation method thereof
CN106284885A (en) * 2016-08-22 2017-01-04 桐乡嘉力丰实业股份有限公司 A kind of colour changing wall paper pointing out concentration of formaldehyde and preparation technology thereof
CN106318109A (en) * 2016-08-08 2017-01-11 马晓洁 Anti-corrosion two-component epoxy resin paint and preparation method and application thereof
CN107201160A (en) * 2017-07-19 2017-09-26 安徽三品技术服务有限公司 A kind of mould proof PVC wallpaper of waterproof
CN107571558A (en) * 2017-07-29 2018-01-12 马鞍山市康辉纸箱纸品有限公司 A kind of child room corrugated paper wallpaper
EP3240832A4 (en) * 2014-12-30 2018-09-26 J.M. Huber Corporation Aluminosilicates and coatings made therefrom for voc removal
CN109694597A (en) * 2017-10-24 2019-04-30 江苏凤凰木业有限公司 A kind of environmental wood door
CN110241991A (en) * 2019-06-11 2019-09-17 杭州圣艾侬壁布有限公司 One kind is except formaldehyde wall cloth and preparation method thereof

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JP2000280433A (en) * 1999-03-31 2000-10-10 Dainippon Printing Co Ltd Mineral decorative plate
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CN102585724A (en) * 2012-01-17 2012-07-18 佛山市美涂士家居饰品有限公司 Negative ion anti-formaldehyde ecological wallpaper glue
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JP2000280433A (en) * 1999-03-31 2000-10-10 Dainippon Printing Co Ltd Mineral decorative plate
CN1632010A (en) * 2004-11-23 2005-06-29 中国建筑材料科学研究院 Decoration paint with air-purifying, sterilization and dampness adjusting function for internal wall
KR20060071496A (en) * 2004-12-22 2006-06-27 성경출 Natural mineral composition for flooring and the preparating method thereof
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Cited By (21)

* Cited by examiner, † Cited by third party
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CN103938826A (en) * 2014-03-16 2014-07-23 王兆进 Diatomaceous earth wallpaper
CN104060500A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Environment-friendly antibacterial moistureproof wallpaper
CN104060499A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Green environmental protection wallpaper with strong breathability
CN104074101A (en) * 2014-05-30 2014-10-01 苏州国昊壁纸有限公司 Environment-friendly antibacterial and deodorization wallpaper
CN104074100A (en) * 2014-05-30 2014-10-01 苏州国昊壁纸有限公司 Color-changeable antibacterial and environment-friendly wallpaper
CN104074324A (en) * 2014-05-30 2014-10-01 苏州国昊壁纸有限公司 Environment-friendly wallpaper containing bamboo charcoal fiber
CN104074101B (en) * 2014-05-30 2016-04-20 太仓市微贯机电有限公司 A kind of environment-friendly type antibiotic deodorizing wallpaper
CN104074324B (en) * 2014-05-30 2016-02-24 太仓市微贯机电有限公司 A kind of environment-friendly type wallpaper containing bamboo-carbon fibre
CN104060500B (en) * 2014-05-30 2016-02-24 苏州诚晟信息技术有限公司 A kind of environment-friendly type antibiotic Waterproof wallpaper
CN104074100B (en) * 2014-05-30 2016-04-20 太仓市微贯机电有限公司 A kind of antibacterial environment protection type wallpaper of changeable colour
EP3240832A4 (en) * 2014-12-30 2018-09-26 J.M. Huber Corporation Aluminosilicates and coatings made therefrom for voc removal
US10589210B2 (en) 2014-12-30 2020-03-17 Evonik Operations Gmbh Aluminosilicates and coatings made therefrom for VOC removal
CN104746382A (en) * 2015-03-11 2015-07-01 山东鲁南新材料股份有限公司 Wallpaper base paper capable of adsorbing formaldehyde and production method thereof
CN105386369A (en) * 2015-11-16 2016-03-09 太仓东能环保设备有限公司 Novel deodorant wallpaper and preparation method thereof
CN105386369B (en) * 2015-11-16 2018-08-03 太仓东能环保设备有限公司 A kind of preparation method of deodorization wallpaper
CN106318109A (en) * 2016-08-08 2017-01-11 马晓洁 Anti-corrosion two-component epoxy resin paint and preparation method and application thereof
CN106284885A (en) * 2016-08-22 2017-01-04 桐乡嘉力丰实业股份有限公司 A kind of colour changing wall paper pointing out concentration of formaldehyde and preparation technology thereof
CN107201160A (en) * 2017-07-19 2017-09-26 安徽三品技术服务有限公司 A kind of mould proof PVC wallpaper of waterproof
CN107571558A (en) * 2017-07-29 2018-01-12 马鞍山市康辉纸箱纸品有限公司 A kind of child room corrugated paper wallpaper
CN109694597A (en) * 2017-10-24 2019-04-30 江苏凤凰木业有限公司 A kind of environmental wood door
CN110241991A (en) * 2019-06-11 2019-09-17 杭州圣艾侬壁布有限公司 One kind is except formaldehyde wall cloth and preparation method thereof

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