CN101377069A - Conditioning deodorization antibiotic mildew-proof wallpaper - Google Patents
Conditioning deodorization antibiotic mildew-proof wallpaper Download PDFInfo
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Abstract
The present invention relates to a humidity-regulating, odor-removing, antibacterial and mould-proof wallpaper, which can effectively regulate the air humidity, absorb the polluting gases in the air and inhibit the reproduction of bacteria and mould. The wallpaper is produced by the drying, cooling and embossing of a basal paper and pasty material coated on the basal paper. According to weight percentages, the pasty material is made from 20 percent to 60 percent of PVC, 25 percent to 50 percent of filling, 5 percent to 15 percent of titanium pigment, 3 percent to 5 percent of the mixture of nano-ZnO and nano-TiO2, 1.5 percent to 3.5 percent of mould inhibitor, 1.5 percent to 3.5 percent of plasticiser, 0.5 percent to 2.5 percent of viscosity depressant, 1.5 percent to 2.5 percent of stabilizer and 0.5 percent to 1.0 percent of bisphenol A. Firstly, the PVC is made into paste and then uniformly mixed with the bisphenol A and the plasticiser; secondly, after being uniformly mixed with the filling, the paste is uniformly mixed with the titanium pigment, the nano-ZnO, the nano-TiO2 and the mould inhibitor and then the stabilizer; and finally, the viscosity depressant is added to regulate the viscosity of the paste in order to obtain the pasty material, which is then coated on the basal paper. The wallpaper has the advantages of no toxicity, no offensive odor, environment-friendliness, long service life, waterproofness and no deformation.
Description
One, technical field
The present invention relates to constructional ornamental material, particularly a kind of conditioning deodorization antibiotic mildew-proof wallpaper.
Two, background technology
Wallpaper has numerous species, mainly comprises: paper substrate wallpaper, textiles wallpaper, natural material wallpaper, plastic wallpaper, glass fibre wallpaper (also claiming glass fibre) or the like.
This is the earliest wallpaper for the paper substrate wallpaper, but surface impression case or embossing.Gas permeable substrate is good, and the moisture in the body of wall basic unit is outwards distributed, the unlikely phenomenons such as variable color, bubbling that cause.This wallpaper low price, shortcoming be poor performance, not water-fast, be not easy to clean, be not easy to construction, present less production;
This is higher kind in the wallpaper for the textiles wallpaper.Mainly be to be made into fibers such as silk, wool, cotton, fiber crops.Texture is good, good permeability, quality softness, but that the technical and manufacturability of paper requires is very high, and price is expensive, is difficult for popularization and application;
This is a kind of wallpaper made from natural plants such as grass, fiber crops, timber, leaves for the natural material wallpaper; Also useful rare tree timber is thinly sliced and is made.Though the honest nature of style, the cost height is not suitable for affordable housing.
This is to produce maximum, most widely used a kind of wallpaper at present for a plastic wallpaper.This is to be basic unit with the body paper with certain performance, is surface layer to polyvinyl chloride (pvc) film, makes through operations such as compound, stamp, embossing.Plastic wallpaper divides common wallpaper and foaming wallpaper, and every kind is divided some kinds again.Common wallpaper be with every square metre 80 the gram paper do base material, be coated with every square metre 100 the gram about the pvc resin, form through stamp, embossing.Comprising monochromatic embossing, printing and embossing, have photo-embossing peace photo-embossing etc. several, is the wallpaper of the most common use.The foaming wallpaper is to do base material with the paper of every square metre 100 gram, scribble every square metre 300 to 400 gram and be mixed with the pvc paste resin of blowing agent, with behind the stamp again foamable form.This class wallpaper has kinds such as high foamed printing, low foamed printing and foamed printing embossing.The flexible ridge design of high foaming wall surface is a kind of decoration and the multi-functional wallpaper of sound-absorbing.
The glass fibre wallpaper also claims the glass fibre wall paper, is to be base material with the medium-alkali glass fibre, and the surface is coated with wear resistant resin, stamps the novel glass ornament materials of multicolour pattern again.
Above-mentioned various wallpaper is mainly classified according to material, along with enhancing and the development of technology of people to environmental consciousness and health perception, has occurred many functional wallpapers in recent years: antibiotic mildew-proof wallpaper, sound-absorbing wallpaper, damping wallpaper, temperature adjustment wallpaper or the like.Also there is the appearance of antibiotic mildew-proof wallpaper in China, and the antibiotic wallpaper of damping that Japan produces also enters Chinese market.Above-mentioned various wallpaper in use, for various reasons, material cause particularly, the damping ability, peculiar smell is big, the antibacterial and mouldproof ability, be unfavorable for the healthy of people, in today of development in science and technology, this unfavorable environmental protection and healthy wallpaper, be unsuitable for using in finishing, it is imperative that it improves with innovation.
Three, summary of the invention
At above-mentioned situation; for overcoming the prior art deficiency; purpose of the present invention just provides a kind of conditioning deodorization antibiotic mildew-proof wallpaper; can effectively solve the adjusting air humidity; dusty gas in the absorbed air; suppressing bacterium and mould breeds on wallpaper; be beneficial to the healthy problem of environmental protection and people; the technical scheme of its solution is: be basic unit's paper with the body paper; with polyvinyl chloride (pvc) is filmogen; fibrous sepiolite or attapulgite and zeolite are filler, and titanium dioxide is a pigment, and sodium rice ZnO, TiO
2With mould inhibitor and other auxiliary agent component, make through operations such as compound, embossing, therefore, the present invention is: made by overcoating (coating) slurry thickener drying, cooling, embossing on basic unit's paper and the basic unit's paper, said slurry thickener is by weight percent meter: PVC 20～60%, filler 25～50%, titanium dioxide 5～15%, nano-ZnO and nano-TiO
2Mixture 3～5%, mould inhibitor 1.5～3.5%, plasticizer 1.5～3.5%, thinner 0.5～2.5%, stabilizing agent 1.5～2.5% and bisphenol-A 0.5～1.0%, total amount and be 100% to make, wherein, earlier PVC is made pasty state and (claim paste resin again, the PVC heating and melting can be become the slurry pasty state) with bisphenol-A, plasticizer mixing and stirring, add again after filler mixes thoroughly, add titanium dioxide (being titanium oxide) and nano-ZnO, nano-TiO
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, per 80～100g/m
2The slurry thickener of overcoating 100g～300g on basic unit's paper (being to be coated with 100g～300g slurry thickener on each square metre basic unit paper), the drying gel, the cooling after, republish wallpaper of the present invention.Dry gel, cooling, printing all adopt existing technology to get final product.
Said filler is any of sepiolite, zeolite, attapulgite or wherein two kinds, if two kinds, its two part by weight is 1-5: 5-1, generally is aborning to calculate with the percentage that accounts for total material weight.
Wherein, said PVC is a polyvinyl chloride, makes film-forming resin and uses; Sepiolite and zeolite mixture or attapulgite and zeolite mixture have ventilative and moisture absorbing as filler, and sepiolite is fibrous, and particle diameter is less than 300 microns, and the particle diameter of zeolite and attapulgite is less than 300 microns; Titanium dioxide is a titanium dioxide, has the pigment effect, sodium rice ZnO and nano-TiO
2Antibiotic, bacteriostasis that mixture has; Mould inhibitor is Zinc Pyrithione (ZOE), 1,2 one benzisothiazole-3-ketone (BIT), and Co., Ltd produces for Changzhou fine jade chemical industry difficult to understand, or 1,2-benzisothiazole-3-ketone (BIT); Plasticizer is 1,2-dicarboxyl diisononyl esters (DINCH), or citrate (ATBC); Thinner is the TXIB thinner, for Jin Xing Shenzhen petrochemical industry row is produced; Stabilizing agent is any in calcium/zinc composite heat stabilizer, mercaptan tin octylate (T890), thiol methyl tin (T190), the thiol-butyl tin (T109); Bisphenol-A i.e. 2,2 pairs of (4-carboxyl phenyl) propane, as antioxidant, and the function that have anti-oxidant, anti-aging, increases the service life; Creativeness of the present invention is, two or more of employing sepiolite, attapulgite and zeolite is as filler (granularity of material is less than 300 microns), increase its duct and gas permeability and adsorptivity, reach and have gas permeability and bigger specific area preferably, absorb and discharge the water in air molecule thereby have, regulate the ability of air themperature.Owing to adopted these porous mineral materials, how its specific area also has the effect that absorbs dusty gas in the air than macropore in addition; Add nano-ZnO and TiO
2As anti-biotic material, wallpaper is had suppress vegetative antibacterial action, add anti-fungus material, make wallpaper mildew not in wet environment, never degenerate, and also have the mutual support of other components, effectively improved product quality, nontoxic, free from extraneous odour, environmental protection, long service life, waterproof, indeformable, be existing wallpaper can't compare, be that one on the wallpaper created greatly, economic and social benefit is huge.
Four, the specific embodiment
Below in conjunction with concrete condition specific implementation method of the present invention is elaborated.
Embodiment 1
Wallpaper of the present invention is with 90g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC33%, sepiolite and zeolite mixture 45.5%, wherein sepiolite 25.5%, zeolite 20%, titanium dioxide 10%, nano-ZnO 3%, nano-TiO
21%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate (T890) 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 900g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing, wallpaper of the present invention.
Above-mentioned example 1 makes wallpaper after testing, has obtained gratifying effect, and environmental-protecting performance is better than GB18582-2001 interior decoration ornament materials safety standard.
The damping effect detection; Moisture adsorption and releasing cyclic test for the first time is 25 ℃ in temperature, relative temperature be under the condition of 90%RH the saturated moisture absorption time be 36 hours, maximum hygroscopicity is 80g/m
2In temperature is 25 ℃, and relative temperature is moisture releasing amount 75%g/m under the 35%RH
2Moisture adsorption and releasing cyclic test for the second time, with the identical condition of the cycling condition first time under, maximum hygroscopicity is 75%g/m
2, the moisture releasing amount still is 75%g/m
2
The antibacterial and mouldproof effect detection: acting on 24 hours, is 95% to the antibiotic rate of staphylococcus aureus, and colibacillary antibiotic rate is reached 90%; The mildew-resistant grade is 0 grade, does not have mouldy phenomenon.
The absorbing formaldehyde effect detection; In the Laboratory Module of 1m3, detect the assimilation effect of PARA FORMALDEHYDE PRILLS(91,95), reach 80%.
Embodiment 2
Wallpaper of the present invention is with 90g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC28%, attapulgite and zeolite mixture 45.5%, wherein attapulgite 25.5%, zeolite 20%, titanium dioxide 15%, nano-ZnO 2%, nano-TiO
22%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate (T890) 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 90g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing, wallpaper of the present invention.
Above-mentioned example 2 makes wallpaper after testing, has obtained gratifying effect, and environmental-protecting performance is better than GB18582-2001 interior decoration ornament materials safety standard.
The damping effect detection; Moisture adsorption and releasing cyclic test for the first time is 25 ℃ in temperature, relative temperature be under the condition of 90%RH the saturated moisture absorption time be 36 hours, maximum hygroscopicity is 78g/m
2In temperature is 25 ℃, and relative temperature is moisture releasing amount 70%g/m under the 35%RH
2Moisture adsorption and releasing cyclic test for the second time, with the identical condition of the cycling condition first time under, maximum hygroscopicity is 70%g/m
2, the moisture releasing amount still is 70%g/m
2
The antibacterial and mouldproof effect detection: acting on 24 hours, is 93% to the antibiotic rate of staphylococcus aureus, and colibacillary antibiotic rate is reached 92%; The mildew-resistant grade is 0 grade, does not have mouldy phenomenon.
The absorbing formaldehyde effect detection; In the Laboratory Module of 1m3, detect the assimilation effect of PARA FORMALDEHYDE PRILLS(91,95), reach 80%.
Embodiment 3
Wallpaper of the present invention is with 80g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC40%, attapulgite and zeolite mixture 35%, wherein attapulgite 20%, zeolite 15%, titanium dioxide 13.5%, nano-ZnO 2%, nano-TiO
22%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate (T890) 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 80g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing, wallpaper of the present invention.
Above-mentioned example 3 makes wallpaper after testing, has obtained gratifying effect, and environmental-protecting performance is better than GB18582-2001 interior decoration ornament materials safety standard.
The damping effect detection; Moisture adsorption and releasing cyclic test for the first time is 25 ℃ in temperature, relative temperature be under the condition of 90%RH the saturated moisture absorption time be 36 hours, maximum hygroscopicity is 70g/m
2In temperature is 25 ℃, and relative temperature is moisture releasing amount 63%g/m under the 35%RH
2Moisture adsorption and releasing cyclic test for the second time, with the identical condition of the cycling condition first time under, maximum hygroscopicity is 63%g/m
2, the moisture releasing amount still is 63%g/m
2
The antibacterial and mouldproof effect detection: acting on 24 hours, is 93% to the antibiotic rate of staphylococcus aureus, and colibacillary antibiotic rate is reached 93%; The mildew-resistant grade is 0 grade, does not have mouldy phenomenon.
The absorbing formaldehyde effect detection; In the Laboratory Module of 1m3, detect the assimilation effect of PARA FORMALDEHYDE PRILLS(91,95), reach 60%.
Embodiment 4
Wallpaper of the present invention is with 100g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC 35%, sepiolite and attapulgite mixture 48.5%, wherein sepiolite 30%, attapulgite 18.5%, titanium dioxide 5%, nano-ZnO 3%, nano-TiO
21%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate (T890) 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 100g/m
2The slurry thickener of overcoating 300g on basic unit's paper, drying gel, cooling, printing, wallpaper of the present invention.
Above-mentioned example 4 makes wallpaper after testing, has obtained gratifying effect, and environmental-protecting performance is better than GB18582-2001 interior decoration ornament materials safety standard.
The damping effect detection; Moisture adsorption and releasing cyclic test for the first time is 25 ℃ in temperature, relative temperature be under the condition of 90%RH the saturated moisture absorption time be 36 hours, maximum hygroscopicity is 85g/m
2In temperature is 25 ℃, and relative temperature is moisture releasing amount 77%g/m under the 35%RH
2Moisture adsorption and releasing cyclic test for the second time, with the identical condition of the cycling condition first time under, maximum hygroscopicity is 77%g/m
2, the moisture releasing amount still is 77%g/m
2
The antibacterial and mouldproof effect detection: acting on 24 hours, is 95% to the antibiotic rate of staphylococcus aureus, and colibacillary antibiotic rate is reached 92%; The mildew-resistant grade is 0 grade, does not have mouldy phenomenon.
The absorbing formaldehyde effect detection; In the Laboratory Module of 1m3, detect the assimilation effect of PARA FORMALDEHYDE PRILLS(91,95), reach 82%.
Embodiment 5
Wallpaper of the present invention is with 100g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC 55%, sepiolite and mixed stone mixture 25%, wherein sepiolite 20%, zeolite 5%, titanium dioxide 5%, nano-ZnO 3%, nano-TiO
21%, 1,2-benzisothiazole-3-ketone (BIT) 3%, citrate 3%, alkylphenol polyoxyethylene 2%, thiol methyl tin (T190) 2% and bisphenol-A 1% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 100g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing, wallpaper of the present invention.
Above-mentioned example 5 makes wallpaper after testing, has obtained gratifying effect, and environmental-protecting performance is better than GB18582-2001 interior decoration ornament materials safety standard.
The damping effect detection; Moisture adsorption and releasing cyclic test for the first time is 25 ℃ in temperature, relative temperature be under the condition of 90%RH the saturated moisture absorption time be 36 hours, maximum hygroscopicity is 60g/m
2In temperature is 25 ℃, and relative temperature is moisture releasing amount 54%g/m under the 35%RH
2Moisture adsorption and releasing cyclic test for the second time, with the identical condition of the cycling condition first time under, maximum hygroscopicity is 54%g/m
2, the moisture releasing amount still is 54%g/m
2
The antibacterial and mouldproof effect detection: acting on 24 hours, is 93% to the antibiotic rate of staphylococcus aureus, and colibacillary antibiotic rate is reached 92%; The mildew-resistant grade is 0 grade, does not have mouldy phenomenon.
The absorbing formaldehyde effect detection; In the Laboratory Module of 1m3, detect the assimilation effect of PARA FORMALDEHYDE PRILLS(91,95), reach 55%.
Above-mentioned each example has all obtained close satisfactory result all through repeatedly product test, shows that properties of product are stable, and reliable in quality has actual production and using value, and being that one on the wallpaper is big improves and create.
Claims (8)
1, a kind of conditioning deodorization antibiotic mildew-proof wallpaper, make by overcoating slurry thickener drying, cooling, embossing on basic unit's paper and the basic unit's paper, it is characterized in that, said slurry thickener is by weight percent meter: PVC20～60%, filler 25～50%, titanium dioxide 5～15%, nano-ZnO and nano-TiO
2Mixture 3～5%, mould inhibitor 1.5～3.5%, plasticizer 1.5～3.5%, thinner 0.5～2.5%, stabilizing agent 1.5～2.5% and bisphenol-A 0.5～1.0%, total amount and be 100% to make, wherein, earlier PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, add titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, per 80～100g/m
2The slurry thickener of overcoating 100g～300g on basic unit's paper, after drying gel, the cooling, republish; Said filler is any of sepiolite, zeolite, attapulgite or wherein two kinds, if two kinds, its two part by weight is 1-5: 5-1.
2, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, said sepiolite is a fibrous sepiolite, and particle diameter is less than 300 microns, and zeolite, attapulgite particle diameter are less than 300 microns.
3, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, said mould inhibitor is Zinc Pyrithione, 1,2 one benzisothiazole-3-ketone or 1, any in the 2-benzisothiazole-3-ketone; Plasticizer is 1,2-dicarboxyl diisononyl esters, or any in the citrate; Thinner is the TXIB thinner; Stabilizing agent is any in calcium/zinc composite heat stabilizer, mercaptan tin octylate, thiol methyl tin, the thiol-butyl tin.
4, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, with 90g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC33%, sepiolite and zeolite mixture 45.5%, wherein sepiolite 25.5%, zeolite 20%, titanium dioxide 10%, nano-ZnO 3%, nano-TiO
21%, ZOE2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 900g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing.
5, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, with 90g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC 28%, attapulgite and zeolite mixture 45.5%, wherein attapulgite 25.5%, zeolite 20%, titanium dioxide 15%, nano-ZnO 2%, nano-TiO
22%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 90g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing.
6, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, with 80g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC 40%, attapulgite and zeolite mixture 35%, wherein attapulgite 20%, zeolite 15%, titanium dioxide 13.5%, nano-ZnO 2%, nano-TiO
22%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 80g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing.
7, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, with 100g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC 35%, sepiolite and attapulgite mixture 48.5%, wherein sepiolite 30%, attapulgite 18.5%, titanium dioxide 5%, nano-ZnO 3%, nano-TiO
21%, ZOE 2%, 1,2-dicarboxyl diisononyl esters 2%, TXIB thinner 1.0%, mercaptan tin octylate 2% and bisphenol-A 0.5% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 100g/m
2The slurry thickener of overcoating 300g on basic unit's paper, drying gel, cooling, printing.
8, a kind of conditioning deodorization antibiotic mildew-proof wallpaper according to claim 1 is characterized in that, with 100g/m
2Basic unit's paper making carrier, coating slurry thickener on basic unit's paper carrier, after the drying gel, cooling, printing are made, said slurry thickener is by weight percent meter: PVC 55%, sepiolite and mixed stone mixture 25%, wherein sepiolite 20%, zeolite 5%, titanium dioxide 5%, nano-ZnO 3%, nano-TiO
21%, 1,2-benzisothiazole-3-ketone 3%, citrate 3%, alkylphenol polyoxyethylene 2%, thiol methyl tin 2% and bisphenol-A 1% are made, at first PVC is made pasty state and bisphenol-A, plasticizer mixing and stirring, add sepiolite and zeolite mixture again, or attapulgite and zeolite mixture mix thoroughly, adds titanium dioxide and nano-ZnO, nano-TiO again
2And after mould inhibitor mixes, dispersion stirs, add the stabilizing agent mixing and stirring, and add thinner at last and reconcile viscosity, make overcoating slurry thickener, every 100g/m
2The slurry thickener of overcoating 100g on basic unit's paper, drying gel, cooling, printing.
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| CNB2008101415247A CN100526554C (en) | 2008-10-07 | 2008-10-07 | Conditioning, flavor-removing, antibiotic and antifungus wallpaper |
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| CNB2008101415247A CN100526554C (en) | 2008-10-07 | 2008-10-07 | Conditioning, flavor-removing, antibiotic and antifungus wallpaper |
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| CN100526554C CN100526554C (en) | 2009-08-12 |
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| CN101914257A (en) * | 2010-08-26 | 2010-12-15 | 中国丝绸博物馆 | Method for preparing high-efficiency composite humidity controlling agent |
| WO2012037112A1 (en) * | 2010-09-15 | 2012-03-22 | Exxonmobil Research And Engineering Company | Method and apparatus for removing contaminant from fluid |
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