CN113756528A - Wallpaper capable of generating negative ions and preparation method thereof - Google Patents

Wallpaper capable of generating negative ions and preparation method thereof Download PDF

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Publication number
CN113756528A
CN113756528A CN202110592983.2A CN202110592983A CN113756528A CN 113756528 A CN113756528 A CN 113756528A CN 202110592983 A CN202110592983 A CN 202110592983A CN 113756528 A CN113756528 A CN 113756528A
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powder
raw materials
diatomite
wallpaper
sodium bicarbonate
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Pending
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CN202110592983.2A
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Chinese (zh)
Inventor
刘宏宇
沈卫东
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Jiangsu Dongyu Wallpaper Co ltd
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Jiangsu Dongyu Wallpaper Co ltd
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Priority to CN202110592983.2A priority Critical patent/CN113756528A/en
Publication of CN113756528A publication Critical patent/CN113756528A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E04BUILDING
    • E04FFINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
    • E04F13/00Coverings or linings, e.g. for walls or ceilings
    • E04F13/002Coverings or linings, e.g. for walls or ceilings made of webs, e.g. of fabrics, or wallpaper, used as coverings or linings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C67/00Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00
    • B29C67/24Shaping techniques not covered by groups B29C39/00 - B29C65/00, B29C70/00 or B29C73/00 characterised by the choice of material
    • B29C67/242Moulding mineral aggregates bonded with resin, e.g. resin concrete
    • B29C67/243Moulding mineral aggregates bonded with resin, e.g. resin concrete for making articles of definite length
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29LINDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
    • B29L2007/00Flat articles, e.g. films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2227Oxides; Hydroxides of metals of aluminium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/34Silicon-containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers
    • C08K7/04Fibres or whiskers inorganic
    • C08K7/14Glass
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/22Expanded, porous or hollow particles
    • C08K7/24Expanded, porous or hollow particles inorganic
    • C08K7/26Silicon- containing compounds

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Structural Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Architecture (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Materials Engineering (AREA)
  • Civil Engineering (AREA)
  • Paper (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)

Abstract

The invention discloses wallpaper capable of generating negative ions and a preparation method thereof, wherein the wallpaper comprises a negative ion diffusion layer and a base layer, and the negative ion diffusion layer is prepared by mixing the following raw materials: 60-70% of PVC resin, 10-20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder, wherein the base layer is made of non-woven fabric. The wallpaper capable of generating negative ions and the preparation method thereof provided by the invention have the advantages that the added water-based negative ions are stirred together with other raw materials and are concentrated into paste, so that the problem of sinking of the water-based negative ions is avoided, the raw materials for manufacturing the wallpaper are uniform in concentration, and the wallpaper provided by the invention can continuously release a large amount of negative oxygen ions, increase the concentration of indoor negative ions and improve the air quality of a room.

Description

Wallpaper capable of generating negative ions and preparation method thereof
Technical Field
The invention relates to the field of wallpaper, and particularly relates to wallpaper capable of generating negative ions and a preparation method thereof.
Background
The existing wallpaper capable of generating negative ions is prepared by dissolving negative ion powder in a water-based printing medium, printing the negative ion powder on the surface of the wallpaper, and printing other colors to prepare the wallpaper, so that the negative oxygen ions of the wallpaper product can be released. There are disadvantages in that the uniformity of color is not good, the printed product is not fine enough, and it is easy to precipitate in an aqueous medium, and the effect is poor, in products which cannot be directly added to the color, such as colored products.
Disclosure of Invention
The invention mainly aims to provide wallpaper capable of generating negative ions and a preparation method thereof, which can effectively solve the problems in the background art.
In order to achieve the purpose, the invention adopts the technical scheme that:
the wallpaper capable of generating negative ions comprises a negative ion diffusion layer and a base layer, wherein the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 60-70% of PVC resin, 10-20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder, wherein the base layer is made of non-woven fabric.
Preferably, the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 60% of PVC resin, 20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder.
Preferably, the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 62% of PVC resin, 18% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 2% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
Preferably, the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 64% of PVC resin, 16% of anion powder, 3% of modified filler, 3% of diatomite, 1% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 1% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
Preferably, the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 66% of PVC resin, 14% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 2% of vermiculite powder and 3% of perlite powder.
Preferably, the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 68% of PVC resin, 12% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 2% of vermiculite powder and 3% of perlite powder.
Preferably, the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 70% of PVC resin, 10% of anion powder, 3% of modified filler, 3% of diatomite, 1% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 1% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
Preferably, the preparation method of the wallpaper capable of generating the negative ions is characterized by comprising the following steps: the method comprises the following operation steps:
s1: preparing raw materials according to portions;
s2: grinding anion powder, modified filler, diatomite, nano ceramic powder, aluminum hydroxide, sodium bicarbonate, glass fiber, vermiculite powder and perlite powder into fine powder, and sieving with 1800-mesh sieve;
s3: melting PVC resin, sequentially adding anion powder, modified filler, diatomite, nano ceramic powder, aluminum hydroxide, sodium bicarbonate, glass fiber, vermiculite powder and fine perlite powder, and uniformly stirring;
s4: pouring the colloid into a mold, heating at low temperature, keeping the semi-colloid semi-solid state, and performing coining molding;
s5: and (4) placing the non-woven fabric on the top of the sound insulation layer, and carrying out stamping, cooling and forming.
Compared with the prior art, the invention has the following beneficial effects:
in the invention, the formula is simple, the raw materials are convenient to select and purchase, the use cost is low, the performance of the produced wallpaper product is stable, and the wallpaper produced by the invention has high surface smoothness, good smoothness and no peculiar smell; the added water-based negative ions and other raw materials are stirred together and concentrated into paste, so that the problem of water-based negative ions sinking is avoided, the raw material concentration for manufacturing the wallpaper is uniform, and the wallpaper provided by the invention can continuously release a large amount of negative oxygen ions, increase the indoor negative ion concentration and improve the air quality of a room.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The first embodiment is as follows:
the embodiment relates to wallpaper capable of generating negative ions, which comprises a negative ion diffusion layer and a base layer, wherein the negative ion diffusion layer is formed by mixing the following raw materials: 60-70% of PVC resin, 10-20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder, wherein the base layer is made of non-woven fabric.
In the invention, the negative ion diffusion layer is formed by mixing the following raw materials: 60% of PVC resin, 20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder.
In the invention, the negative ion diffusion layer is formed by mixing the following raw materials: 62% of PVC resin, 18% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 2% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
In the invention, the negative ion diffusion layer is formed by mixing the following raw materials: 64% of PVC resin, 16% of anion powder, 3% of modified filler, 3% of diatomite, 1% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 1% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
In the invention, the negative ion diffusion layer is formed by mixing the following raw materials: 66% of PVC resin, 14% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 2% of vermiculite powder and 3% of perlite powder.
In the invention, the negative ion diffusion layer is formed by mixing the following raw materials: 68% of PVC resin, 12% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 2% of vermiculite powder and 3% of perlite powder.
In the invention, the negative ion diffusion layer is formed by mixing the following raw materials: 70% of PVC resin, 10% of anion powder, 3% of modified filler, 3% of diatomite, 1% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 1% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
The second embodiment is as follows:
the embodiment relates to a preparation method of wallpaper capable of generating negative ions, which is characterized by comprising the following steps: the method comprises the following operation steps:
s1: preparing raw materials according to portions;
s2: grinding anion powder, modified filler, diatomite, nano ceramic powder, aluminum hydroxide, sodium bicarbonate, glass fiber, vermiculite powder and perlite powder into fine powder, and sieving with 1800-mesh sieve;
s3: melting PVC resin, sequentially adding anion powder, modified filler, diatomite, nano ceramic powder, aluminum hydroxide, sodium bicarbonate, glass fiber, vermiculite powder and fine perlite powder, and uniformly stirring;
s4: pouring the colloid into a mold, heating at low temperature, keeping the semi-colloid semi-solid state, and performing coining molding;
s5: and (4) placing the non-woven fabric on the top of the sound insulation layer, and carrying out stamping, cooling and forming.
The invention has simple formula, convenient raw material selection and low use cost, and the produced wallpaper product has stable performance, and the wallpaper produced by the invention has high surface smoothness, good smoothness and no peculiar smell; the added water-based negative ions and other raw materials are stirred together and concentrated into paste, so that the problem of water-based negative ions sinking is avoided, the raw material concentration for manufacturing the wallpaper is uniform, and the wallpaper provided by the invention can continuously release a large amount of negative oxygen ions, increase the indoor negative ion concentration and improve the air quality of a room.
Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that changes, modifications, substitutions and alterations can be made in these embodiments without departing from the principles and spirit of the invention, the scope of which is defined in the appended claims and their equivalents.

Claims (8)

1. The utility model provides a wall paper that can produce anion, includes anion diffusion layer and basic unit, its characterized in that: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 60-70% of PVC resin, 10-20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder, wherein the base layer is made of non-woven fabric.
2. The wallpaper capable of generating negative ions according to claim 1, wherein: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 60% of PVC resin, 20% of anion powder, 1-3% of modified filler, 1-3% of diatomite, 1-3% of nano ceramic powder, 1-3% of aluminum hydroxide, 1-3% of sodium bicarbonate, 1-3% of glass fiber, 1-3% of vermiculite powder and 1-3% of perlite powder.
3. The wallpaper capable of generating negative ions according to claim 1, wherein: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 62% of PVC resin, 18% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 2% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
4. The wallpaper capable of generating negative ions according to claim 1, wherein: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 64% of PVC resin, 16% of anion powder, 3% of modified filler, 3% of diatomite, 1% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 1% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
5. The wallpaper capable of generating negative ions according to claim 1, wherein: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 66% of PVC resin, 14% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 2% of vermiculite powder and 3% of perlite powder.
6. The wallpaper capable of generating negative ions according to claim 1, wherein: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 68% of PVC resin, 12% of anion powder, 2% of modified filler, 2% of diatomite, 2% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 3% of glass fiber, 2% of vermiculite powder and 3% of perlite powder.
7. The wallpaper capable of generating negative ions according to claim 1, wherein: the negative ion diffusion layer is formed by mixing the following raw materials in parts by weight: 70% of PVC resin, 10% of anion powder, 3% of modified filler, 3% of diatomite, 1% of nano ceramic powder, 3% of aluminum hydroxide, 3% of sodium bicarbonate, 1% of glass fiber, 3% of vermiculite powder and 3% of perlite powder.
8. The method for preparing wallpaper capable of generating negative ions according to claim 1, wherein the wallpaper comprises: the method comprises the following operation steps:
s1: preparing raw materials according to portions;
s2: grinding anion powder, modified filler, diatomite, nano ceramic powder, aluminum hydroxide, sodium bicarbonate, glass fiber, vermiculite powder and perlite powder into fine powder, and sieving with 1800-mesh sieve;
s3: melting PVC resin, sequentially adding anion powder, modified filler, diatomite, nano ceramic powder, aluminum hydroxide, sodium bicarbonate, glass fiber, vermiculite powder and fine perlite powder, and uniformly stirring;
s4: pouring the colloid into a mold, heating at low temperature, keeping the semi-colloid semi-solid state, and performing coining molding;
s5: and (4) placing the non-woven fabric on the top of the sound insulation layer, and carrying out stamping, cooling and forming.
CN202110592983.2A 2021-05-28 2021-05-28 Wallpaper capable of generating negative ions and preparation method thereof Pending CN113756528A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202110592983.2A CN113756528A (en) 2021-05-28 2021-05-28 Wallpaper capable of generating negative ions and preparation method thereof

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Application Number Priority Date Filing Date Title
CN202110592983.2A CN113756528A (en) 2021-05-28 2021-05-28 Wallpaper capable of generating negative ions and preparation method thereof

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Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007046602A1 (en) * 2005-10-17 2007-04-26 Hyo Chul Jun Aqueous foam wallpaper having enhanced embossing formability and fabricating method thereof
CN101377069A (en) * 2008-10-07 2009-03-04 河南红旗渠建设集团有限公司 Conditioning deodorization antibiotic mildew-proof wallpaper
CN102285172A (en) * 2011-07-07 2011-12-21 广东玉兰装饰材料有限公司 Anion wall paper and method for preparing same
CN102828447A (en) * 2011-06-13 2012-12-19 瑞宝(北京)装饰设计有限公司 Negative-ion anti-formaldehyde ecological wallpaper
CN103726413A (en) * 2013-11-29 2014-04-16 淮北龙盘工贸有限责任公司 Novel compound wallpaper
CN104059311A (en) * 2014-05-08 2014-09-24 浙江恒润装饰材料有限公司 Negative ion wallpaper and preparation method thereof
CN106703311A (en) * 2016-12-22 2017-05-24 安徽易有墙纸有限公司 Heat-resisting waterproof wallpaper and production method thereof
CN107090745A (en) * 2017-05-24 2017-08-25 江苏爱舍墙纸有限公司 It is a kind of to produce wallpaper of anion and preparation method thereof
CN107502077A (en) * 2017-09-06 2017-12-22 浙江爱丽莎环保科技股份有限公司 A kind of preparation method of pebble anion foam wallpaper, thickener used and thickener
CN108755274A (en) * 2018-06-01 2018-11-06 肥西县碧涛建材有限公司 A kind of novel mildew resistant becomes wallpaper and preparation method thereof
CN109021455A (en) * 2018-08-19 2018-12-18 柳州市家富连装饰有限公司 A kind of moistureproof and mildewproof PVC wallpaper and preparation method thereof
CN110407549A (en) * 2019-06-28 2019-11-05 普定县创家亿建材有限公司 A kind of decorative board material and preparation method thereof

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2007046602A1 (en) * 2005-10-17 2007-04-26 Hyo Chul Jun Aqueous foam wallpaper having enhanced embossing formability and fabricating method thereof
CN101377069A (en) * 2008-10-07 2009-03-04 河南红旗渠建设集团有限公司 Conditioning deodorization antibiotic mildew-proof wallpaper
CN102828447A (en) * 2011-06-13 2012-12-19 瑞宝(北京)装饰设计有限公司 Negative-ion anti-formaldehyde ecological wallpaper
CN102285172A (en) * 2011-07-07 2011-12-21 广东玉兰装饰材料有限公司 Anion wall paper and method for preparing same
CN103726413A (en) * 2013-11-29 2014-04-16 淮北龙盘工贸有限责任公司 Novel compound wallpaper
CN104059311A (en) * 2014-05-08 2014-09-24 浙江恒润装饰材料有限公司 Negative ion wallpaper and preparation method thereof
CN106703311A (en) * 2016-12-22 2017-05-24 安徽易有墙纸有限公司 Heat-resisting waterproof wallpaper and production method thereof
CN107090745A (en) * 2017-05-24 2017-08-25 江苏爱舍墙纸有限公司 It is a kind of to produce wallpaper of anion and preparation method thereof
CN107502077A (en) * 2017-09-06 2017-12-22 浙江爱丽莎环保科技股份有限公司 A kind of preparation method of pebble anion foam wallpaper, thickener used and thickener
CN108755274A (en) * 2018-06-01 2018-11-06 肥西县碧涛建材有限公司 A kind of novel mildew resistant becomes wallpaper and preparation method thereof
CN109021455A (en) * 2018-08-19 2018-12-18 柳州市家富连装饰有限公司 A kind of moistureproof and mildewproof PVC wallpaper and preparation method thereof
CN110407549A (en) * 2019-06-28 2019-11-05 普定县创家亿建材有限公司 A kind of decorative board material and preparation method thereof

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