CN102828447A - Negative-ion anti-formaldehyde ecological wallpaper - Google Patents
Negative-ion anti-formaldehyde ecological wallpaper Download PDFInfo
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- CN102828447A CN102828447A CN2011101579450A CN201110157945A CN102828447A CN 102828447 A CN102828447 A CN 102828447A CN 2011101579450 A CN2011101579450 A CN 2011101579450A CN 201110157945 A CN201110157945 A CN 201110157945A CN 102828447 A CN102828447 A CN 102828447A
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Abstract
The invention provides negative-ion anti-formaldehyde ecological wallpaper, comprising a wallpaper substrate, and a surface coating layer compounded on the surface of the wallpaper substrate, wherein the surface coating layer comprises paint, negative-ion powder and a formaldehyde remover. In the negative-ion anti-formaldehyde ecological wallpaper provided by the invention, the formaldehyde remover has the effects of adsorbing, fixing and degrading formaldehyde and has good removal effect for formaldehyde of surrounding environment; and not only does the negative-ion powder have durable negative-ion generation function, far-infrared emission function and good sterilization and bacteriostasis function, but also negative ions relieved by the negative-ion powder have strong redox capacity, can decompose organic gases such as formaldehyde and the like, thereby improving the capability for removing formaldehyde continuously and durably of the formaldehyde remover. Experimental results show that the negative-ion anti-formaldehyde ecological wallpaper provided by the invention can remove formaldehyde in the environment chronically, durably and effectively, purifies indoor air, and is helpful for keeping human health.
Description
Technical field
The invention belongs to building material technical field, relate in particular to the ecological wallpaper of the anti-formaldehyde of a kind of anion.
Background technology
Wallpaper is claimed wallpaper again, is a kind of speciality paper that is used for decorative wall, has advantages such as attractive in appearance, elegant, convenient, practicality, is widely used in the human settlement.
Wallpaper itself is the ornament materials of environmental protection; But other building materials among the human settlement; Like the decoration paver on artificial boards such as various shaving boards, fiberboard, glued board or metope, ground etc.; Owing to having used Lauxite, melamine resin and phenolic resins etc. to continue to discharge in the ambient free formaldehyde as the binding agent of raw material with formaldehyde, cause room air pollution, be detrimental to health.
For formaldehyde pollution in the decontamination chamber, prior art discloses multiple formaldehyde scavenger, through brushing, put on the skin and be coated with or method such as spraying is coated in plate surface and reaches the purpose of removing formaldehyde.Like application number is that 200910138500.0 Chinese patent document discloses a kind of strong osmotic property formaldehyde scavenger; Hydrazides class material by 2~5%, 5~10% urea, 5~15% inorganic amine compounds, 0.1~0.5% JFC, 0~1.0% pH value conditioning agent and 70~85% water are formed, and this formaldehyde scavenger can be used for removing the formaldehyde in various sheet materials and the goods thereof.But present disclosed formaldehyde scavenger is generally strong reductant-oxidant, is mainly used in the removing of formaldehyde in the sheet material, directly is applied in when formaldehyde removing is carried out on the wallpaper surface and can destroys the attractive in appearance of wallpaper.
Application number is that 20101051093.6 Chinese patent document discloses a kind of anti-formaldehyde wall paper; Mainly be in 1000g wall paper, to add 40~80g nano titanium oxide/filter aid-2 composite; The formaldehyde in the wall paper material can not only fixed and absorb to this composite; And can absorb airborne formaldehyde, reach the purpose of eliminating and reducing formaldehyde harm.But nano titanium oxide/filter aid-2 composite absorbing formaldehyde limited in one's ability is difficult to continue to bring into play the fixedly effect of formaldehyde after its absorption is saturated, thereby makes this wallpaper be difficult to long-term performance except that the formaldehyde effect.
Summary of the invention
In view of this, the technical problem that the present invention will solve is to provide the anti-formaldehyde of a kind of anion ecological wallpaper, and the ecological wallpaper PARA FORMALDEHYDE PRILLS(91,95) of the anti-formaldehyde of anion provided by the invention has higher removal efficient, and can be for a long time, continue the content of formaldehyde in the reduction environment.
The invention provides the ecological wallpaper of the anti-formaldehyde of a kind of anion, comprising:
Wallpaper basic unit;
Be compound in the top finishing layer of said wallpaper substrate surface, said top finishing layer comprises coating, negative ion powder and formaldehyde remover.
Preferably, in the said top finishing layer, the mass percent that said negative ion powder accounts for said top finishing layer is 0.5%~15%.
Preferably, the granularity of said negative ion powder is less than 15 μ m.
Preferably, in the said top finishing layer, the mass percent that said formaldehyde remover accounts for said top finishing layer is 0.5%~15%.
Preferably, said formaldehyde remover is a modified molecular screen.
Preferably, the granularity of said formaldehyde remover is less than 15 μ m.
Preferably, between said wallpaper basic unit and said top finishing layer, also be provided with polyvinyl chloride layer.
Preferably, said wallpaper basic unit is hanging raw stock, pure paper, non-woven paper, nonwoven fabric, textile cloth, chemical fabric or blended cloth.
Compared with prior art; The ecological wallpaper of the anti-formaldehyde of anion provided by the invention comprises wallpaper basic unit and the top finishing layer that is compound in said wallpaper substrate surface; Said top finishing layer also comprises negative ion powder and formaldehyde remover except comprising water-based or oil paint commonly used.In the ecological wallpaper of the anti-formaldehyde of anion provided by the invention, the formaldehyde remover has absorption, the fixing also effect of degradation of formaldehyde, and the formaldehyde in the surrounding environment is had good removal effect; And negative ion powder not only has lasting negative ion generating function, far-infrared transmitting function, good bactericidal function; And the anion of its release has strong redox ability; Can be with organic gas; Like decomposition such as formaldehyde, thereby improve the ability that the formaldehyde remover continues, removes formaldehyde for a long time.The ecological wallpaper of the anti-formaldehyde of anion provided by the invention not only has efficiently, removes lastingly the ability of formaldehyde in the environment for use; And can discharge anion and far infrared, have bactericidal, the function of deodorizing, taste removal, human body is had certain function of health care.Experiment shows that the ecological wallpaper of the anti-formaldehyde of anion provided by the invention can for a long time, lastingly, effectively be removed the formaldehyde in the environment, purifies the air of a room, and keeps health.
The specific embodiment
The invention provides the ecological wallpaper of the anti-formaldehyde of a kind of anion, comprising:
Wallpaper basic unit;
Be compound in the top finishing layer of said wallpaper substrate surface, said top finishing layer comprises coating, negative ion powder and formaldehyde remover.
The ecological wallpaper of the anti-formaldehyde of anion provided by the invention comprises wallpaper basic unit and top finishing layer; Wherein, Added negative ion powder and formaldehyde remover in the top finishing layer, removal formaldehyde that can be efficient, lasting, and have the function that discharges anion and far infrared, bactericidal.
In the present invention, the ecological wallpaper of the anti-formaldehyde of said anion comprises wallpaper basic unit, and said wallpaper basic unit can well known to a person skilled in the art the wallpaper base material for hanging raw stock, pure paper, non-woven paper, nonwoven fabric, textile cloth, chemical fabric or blended cloth etc.
The ecological wallpaper of the anti-formaldehyde of said anion also comprises the top finishing layer, and said top finishing layer is compounded in the surface of said wallpaper basic unit, has the protective bulkhead paper substrate, makes effects such as wallpaper is more attractive in appearance, and have functions such as bactericidal, deodorizing taste removal.In the present invention, said top finishing layer comprises coating, negative ion powder and formaldehyde remover.
Said coating is the main component of said top finishing layer, and it can comprise multiple compositions such as film forming matter, auxiliary agent or pigment, and effect is to form film in the wallpaper substrate surface, plays the protective bulkhead paper substrate, increases the wallpaper aesthetic property.The present invention has no restriction to said coating, can the coating of wallpaper substrate surface film forming all can, like mercerising coating, low luster coating, luminous light-storing paint, clear dope etc.Said coating can be water paint, also can be oil paint, and those skilled in the art can carry out the selection of coating according to the main application of wallpaper basic unit and wallpaper.
In said top finishing layer, also comprise the formaldehyde remover; Said formaldehyde remover is called formaldehyde catching agent, formaldehyde absorbent, formaldehyde scavenger etc. again; Its role is to adsorb, the free formaldehyde in the fixing and degraded surrounding air, reduce the content of formaldehyde in the wallpaper environment for use.In the present invention, the mass percent that said formaldehyde remover accounts for said top finishing layer is preferably 0.5%~15%, and more preferably 1%~10%, most preferably be 3%~5%.The present invention does not have particular restriction to the kind of said formaldehyde remover; Can be for the fixing formaldehyde remover of formaldehyde of adsorption mechanism; Have the adsorbent of loose structure like molecular sieve, nano titanium oxide, active carbon etc., also can be for the formaldehyde remover of removing formaldehyde with redox mechanism etc.In the present invention, the granularity of said formaldehyde remover is preferably less than 15 μ m, more preferably less than 10 μ m.
In the present invention, said formaldehyde remover is modified molecular screen more preferably, comprises Al like chemical composition
2O
3, SiO
2, CaO, MgO, K
2O and Fe
2O
3Deng molecular sieve; Said modified molecular screen is preferably the composite modified molecular sieve with macropore and microcellular structure, and wherein, the average pore diameter of said macropore is preferably 80nm~120nm, more preferably 90nm~110nm; The average pore diameter of said micropore is 0.28nm~0.35nm, more preferably 0.28nm~0.3nm.
The ecological wallpaper of the anti-formaldehyde of anion provided by the invention also comprises negative ion powder; Said negative ion powder can continue to discharge anion; This anion has stronger redox ability; Can be with decomposition such as organic gas such as formaldehyde, thus the ability that the formaldehyde remover continues, removes formaldehyde for a long time improved.
In the present invention, said negative ion powder has lasting negative ion generating function, far-infrared transmitting function and good bactericidal function.Said negative ion powder can continue to produce anion, and this anion can the release gas molecule in absorbed air middle reaches, particle type gas molecule and cation type gas molecule, thereby plays the effect that purifies air; This anion can also become carbon dioxide and water like decomposition such as formaldehyde with organic gas, thereby plays the ability that continues to remove formaldehyde.
In the present invention, the mass percent that said negative ion powder accounts for said top finishing layer is preferably 0.5%~15%, and more preferably 1%~10%, most preferably be 3%~5%.The granularity of said negative ion powder is preferably less than 15 μ m, more preferably less than 10 μ m.
In the present invention, polyvinyl chloride layer can also be provided with between said wallpaper basic unit and the said top finishing layer, ecological wallpaper of the anti-formaldehyde of foamed anion or the ecological wallpaper of the anti-formaldehyde of embossing anion can be obtained.
The ecological wallpaper of the anti-formaldehyde of anion provided by the invention is preferably according to following method preparation:
The wallpaper base material is printed according to method well known to those skilled in the art;
Coating, negative ion powder and formaldehyde remover are mixed, obtain top finishing layer mixture;
Said top finishing layer mixture is coated on the surface of said wallpaper base material, obtains the ecological wallpaper of the anti-formaldehyde of anion after dry, the cooling.
In the present invention, can said top finishing layer mixture be coated said wallpaper substrate surface through intaglio printing, screen painting, flexographic printing or other printing coating methods and form the top finishing layer.
When the ecological wallpaper of the anti-formaldehyde of said anion comprises polyvinyl chloride layer, can prepare according to following method:
Wallpaper base material and Welvic or polychloroethylene film is compound through modes such as calendering, coatings;
The wallpaper base material that will be compounded with polyvinyl chloride layer then prints;
Coating, negative ion powder and formaldehyde remover are mixed, obtain top finishing layer mixture;
Said top finishing layer mixture is coated on the surface of said polyvinyl chloride layer, obtains the ecological wallpaper of the anti-formaldehyde of anion after drying or foaming, embossing, the cooling.
When the ecological wallpaper of the anti-formaldehyde of said anion comprises polyvinyl chloride layer; The ecological wallpaper of the anti-formaldehyde of said anion can pass through foaming and obtain the wallpaper that foams; Embossing processing well known to those skilled in the art is carried out to said wallpaper in the foaming back, can obtain the ecological wallpaper of the anti-formaldehyde of anion after the cooling.
After obtaining the ecological wallpaper of the anti-formaldehyde of anion; Ability to the ecological wallpaper of the anti-formaldehyde of said anion is removed formaldehyde is tested; The result shows, the ecological wallpaper of the anti-formaldehyde of anion provided by the invention not only can effectively be removed formaldehyde, and can be for a long time, continue removal formaldehyde.
In order to further specify the present invention, the ecological wallpaper of the anti-formaldehyde of anion provided by the invention is described in detail below in conjunction with embodiment.
Below among each embodiment, negative ion powder is available from Beijing Health-care Science & Technology Co., Ltd., model is TZY01-05;
Molecular sieve formaldehyde remover is available from Beijing Health-care Science & Technology Co., Ltd., and model is TZY01-12;
The wallpaper base material is available from Finland Ahlstrom company.
Embodiment 1
The negative ion powder and the molecular sieve formaldehyde remover that in the 10kg water paint, add gross weight 1.0kg; Wherein, The mass ratio of negative ion powder and molecular sieve formaldehyde remover is 1: 1; Obtain mixture after stirring, water paint comprises: 0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydromethyl propionic acid, 0.2kg ethylenediamine and 6.5kg water;
After the printing of wallpaper base material, said mixture is coated on the said wallpaper base material, heat drying, cooling obtain wallpaper after cutting.
Test method according to building material industry standard JC/T 1074-2008 provides is removed the formaldehyde measure of merit to said wallpaper, and the result is referring to table 1, the ecological wallpaper of the anti-formaldehyde of the anion that table 1 provides for the embodiment of the invention 1 remove the aldehyde test result.
The ecological wallpaper of the anti-formaldehyde of the anion that table 1 embodiment of the invention 1 provides remove the aldehyde test result
Can know that by table 1 removing formaldehyde efficient and can reach 94.8% behind the ecological wallpaper 168h of the anti-formaldehyde of the anion that the embodiment of the invention 1 provides explains that the ecological wallpaper of the anti-formaldehyde of anion provided by the invention has the ability of removing formaldehyde efficiently, lastingly.
Embodiment 2
In the 10kg water paint, adding gross weight is negative ion powder and the molecular sieve formaldehyde remover of 1.0kg; Wherein, The mass ratio of negative ion powder and molecular sieve formaldehyde remover is 2: 1; Obtain mixture after stirring, water paint comprises: 0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydromethyl propionic acid, 0.2kg ethylenediamine and 6.5kg water;
After the printing of wallpaper base material, said mixture is coated on the said wallpaper base material, heat drying, cooling obtain wallpaper after cutting.
Test method according to building material industry standard JC/T 1074-2008 provides is removed the formaldehyde measure of merit to said wallpaper, and the result is referring to table 2, the ecological wallpaper of the anti-formaldehyde of the anion that table 2 provides for the embodiment of the invention 2 remove the aldehyde test result.
The ecological wallpaper of the anti-formaldehyde of the anion that table 2 embodiment of the invention 2 provides remove the aldehyde test result
Can know that by table 2 removing formaldehyde efficient and can reach 95.2% behind the ecological wallpaper 168h of the anti-formaldehyde of the anion that the embodiment of the invention 2 provides explains that the ecological wallpaper of the anti-formaldehyde of anion provided by the invention has the ability of removing formaldehyde efficiently, lastingly.
Embodiment 3
In the 10kg water paint, adding gross weight is negative ion powder and the molecular sieve formaldehyde remover of 1.0kg; Wherein, The mass ratio of negative ion powder and molecular sieve formaldehyde remover is 1: 2; Obtain mixture after stirring, water paint comprises: 0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydromethyl propionic acid, 0.2kg ethylenediamine and 6.5kg water;
After the printing of wallpaper base material, said mixture is coated on the said wallpaper base material, heat drying, cooling obtain wallpaper after cutting.
Test method according to building material industry standard JC/T 1074-2008 provides is removed the formaldehyde measure of merit to said wallpaper, and the result is referring to table 3, the ecological wallpaper of the anti-formaldehyde of the anion that table 3 provides for the embodiment of the invention 3 remove the aldehyde test result.
The ecological wallpaper of the anti-formaldehyde of the anion that table 3 embodiment of the invention 3 provides remove the aldehyde test result
Can know that by table 3 removing formaldehyde efficient and can reach 94.1% behind the ecological wallpaper 168h of the anti-formaldehyde of the anion that the embodiment of the invention 3 provides explains that the ecological wallpaper of the anti-formaldehyde of anion provided by the invention has the ability of removing formaldehyde efficiently, lastingly.
Embodiment 4
In the 10kg water paint, adding gross weight is 1.0kg negative ion powder and molecular sieve formaldehyde remover; Wherein, The mass ratio of negative ion powder and molecular sieve formaldehyde remover is 2: 3; Obtain mixture after stirring, water paint comprises: 0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydromethyl propionic acid, 0.2kg ethylenediamine and 6.5kg water;
After the printing of wallpaper base material, said mixture is coated on the said wallpaper base material, heat drying, cooling obtain wallpaper after cutting.
Test method according to building material industry standard JC/T 1074-2008 provides is removed the formaldehyde measure of merit to said wallpaper, and the result is referring to table 4, the ecological wallpaper of the anti-formaldehyde of the anion that table 4 provides for the embodiment of the invention 4 remove the aldehyde test result.
The ecological wallpaper of the anti-formaldehyde of the anion that table 4 embodiment of the invention 4 provides remove the aldehyde test result
Can know that by table 4 removing formaldehyde efficient and can reach 94.5% behind the ecological wallpaper 168h of the anti-formaldehyde of the anion that the embodiment of the invention 4 provides explains that the ecological wallpaper of the anti-formaldehyde of anion provided by the invention has the ability of removing formaldehyde efficiently, lastingly.
Embodiment 5
In the 10kg water paint, adding gross weight is negative ion powder and the molecular sieve formaldehyde remover of 1.0kg; Wherein, The mass ratio of negative ion powder and molecular sieve formaldehyde remover is 3: 2; Obtain mixture after stirring, water paint comprises: 0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydromethyl propionic acid, 0.2kg ethylenediamine and 6.5kg water;
After the printing of wallpaper base material, said mixture is coated on the said wallpaper base material, heat drying, cooling obtain wallpaper after cutting.
Test method according to building material industry standard JC/T 1074-2008 provides is removed the formaldehyde measure of merit to said wallpaper, and the result is referring to table 5, the ecological wallpaper of the anti-formaldehyde of the anion that table 5 provides for the embodiment of the invention 5 remove the aldehyde test result.
The ecological wallpaper of the anti-formaldehyde of the anion that table 5 embodiment of the invention 5 provides remove the aldehyde test result
Can know that by table 5 removing formaldehyde efficient and can reach 95.1% behind the ecological wallpaper 168h of the anti-formaldehyde of the anion that the embodiment of the invention 5 provides explains that the ecological wallpaper of the anti-formaldehyde of anion provided by the invention has the ability of removing formaldehyde efficiently, lastingly.
Comparative example 1
In the 10kg water paint, add 1.0kg formaldehyde remover, obtain mixture after stirring, wherein, water paint comprises: 0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydromethyl propionic acid, 0.2kg ethylenediamine and 6.5kg water;
After the printing of wallpaper base material, said mixture is coated on the said wallpaper base material, heat drying, cooling obtain wallpaper after cutting.
Test method according to building material industry standard JC/T 1074-2008 provides is removed the formaldehyde measure of merit to said wallpaper, and the result is referring to table 6, the wallpaper that table 6 provides for comparative example 1 of the present invention remove the aldehyde test result.
The wallpaper that table 6 comparative example 1 of the present invention provides remove the aldehyde test result
Can know that by table 6 the formaldehyde efficient of removing behind the wallpaper 168h that is not added with negative ion powder that comparative example 1 of the present invention provides is merely 84.8%.
Can know that by the foregoing description and comparative example the ecological wallpaper of the anti-formaldehyde of anion provided by the invention not only can effectively be removed formaldehyde, and has persistence preferably.
The above only is a preferred implementation of the present invention; Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention; Can also make some improvement and retouching, these improvement and retouching also should be regarded as protection scope of the present invention.
Claims (8)
1. the ecological wallpaper of the anti-formaldehyde of an anion comprises:
Wallpaper basic unit;
Be compound in the top finishing layer of said wallpaper substrate surface, said top finishing layer comprises coating, negative ion powder and formaldehyde remover.
2. the ecological wallpaper of the anti-formaldehyde of anion according to claim 1 is characterized in that in the said top finishing layer, the mass percent that said negative ion powder accounts for said top finishing layer is 0.5%~15%.
3. the ecological wallpaper of the anti-formaldehyde of anion according to claim 1 is characterized in that the granularity of said negative ion powder is less than 15 μ m.
4. the ecological wallpaper of the anti-formaldehyde of anion according to claim 1 is characterized in that in the said top finishing layer, the mass percent that said formaldehyde remover accounts for said top finishing layer is 0.5%~15%.
5. the ecological wallpaper of the anti-formaldehyde of anion according to claim 4 is characterized in that said formaldehyde remover is a modified molecular screen.
6. the ecological wallpaper of the anti-formaldehyde of anion according to claim 5 is characterized in that the granularity of said formaldehyde remover is less than 15 μ m.
7. the ecological wallpaper of the anti-formaldehyde of anion according to claim 1 is characterized in that, between said wallpaper basic unit and said top finishing layer, also is provided with polyvinyl chloride layer.
8. according to the ecological wallpaper of the anti-formaldehyde of any described anion of claim 1~7, it is characterized in that said wallpaper basic unit is hanging raw stock, pure paper, non-woven paper, nonwoven fabric, textile cloth, chemical fabric or blended cloth.
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Cited By (7)
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CN103469987A (en) * | 2013-08-12 | 2013-12-25 | 苏州国昊壁纸有限公司 | Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper |
CN103612452A (en) * | 2013-11-22 | 2014-03-05 | 袁伟 | Environment-friendly multifunctional water-based coating |
CN106087550A (en) * | 2016-06-23 | 2016-11-09 | 福建省优雅环保壁纸有限公司 | A kind of Novel wall paper capable of releasing negative ion and preparation method thereof |
CN106087462A (en) * | 2016-07-12 | 2016-11-09 | 福建省优雅环保壁纸有限公司 | A kind of environment-friendly novel pollution-free anion wallpaper and preparation method thereof |
CN106193483A (en) * | 2016-07-11 | 2016-12-07 | 赵昶然 | Oxygen source haze high-concentration anion health environment-friendly flame-retardant multifunctional wall cloth makes construction technology and product |
CN106677482A (en) * | 2016-12-27 | 2017-05-17 | 南京双全科技有限公司 | Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof |
CN113756528A (en) * | 2021-05-28 | 2021-12-07 | 江苏东宇墙纸有限公司 | Wallpaper capable of generating negative ions and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN103469987A (en) * | 2013-08-12 | 2013-12-25 | 苏州国昊壁纸有限公司 | Environment-friendly, formaldehyde-removing, mold-proof and anti-bacterial wallpaper |
CN103612452A (en) * | 2013-11-22 | 2014-03-05 | 袁伟 | Environment-friendly multifunctional water-based coating |
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CN106087550A (en) * | 2016-06-23 | 2016-11-09 | 福建省优雅环保壁纸有限公司 | A kind of Novel wall paper capable of releasing negative ion and preparation method thereof |
CN106193483A (en) * | 2016-07-11 | 2016-12-07 | 赵昶然 | Oxygen source haze high-concentration anion health environment-friendly flame-retardant multifunctional wall cloth makes construction technology and product |
CN106087462A (en) * | 2016-07-12 | 2016-11-09 | 福建省优雅环保壁纸有限公司 | A kind of environment-friendly novel pollution-free anion wallpaper and preparation method thereof |
CN106677482A (en) * | 2016-12-27 | 2017-05-17 | 南京双全科技有限公司 | Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof |
CN113756528A (en) * | 2021-05-28 | 2021-12-07 | 江苏东宇墙纸有限公司 | Wallpaper capable of generating negative ions and preparation method thereof |
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