CN103254797B - A kind of Photocatalyst water wax and preparation method thereof - Google Patents
A kind of Photocatalyst water wax and preparation method thereof Download PDFInfo
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- CN103254797B CN103254797B CN201310136524.9A CN201310136524A CN103254797B CN 103254797 B CN103254797 B CN 103254797B CN 201310136524 A CN201310136524 A CN 201310136524A CN 103254797 B CN103254797 B CN 103254797B
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Abstract
The present invention relates to furniture wax technical field, particularly relate to a kind of Photocatalyst water wax and preparation method thereof, the present invention includes water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, defoamer, water-base resin, AMP95 and water, and by being obtained by mixing under different stirring velocity in batches; The present invention can form the protective membrane of one deck light at furniture surface, make furniture present more smooth beautiful color, has the functions such as waterproof, anti-oxidant, uvioresistant simultaneously; And objectionable impuritiess such as reducing formaldehyde in indoor air can be decomposed, health more can be protected healthy for a long time while protection furniture.
Description
Technical field
The present invention relates to furniture wax technical field, particularly relate to a kind of Photocatalyst water wax and preparation method thereof.
Background technology
Formaldehyde, generally believed it is indoor first killer by all circles, it is very serious to human body especially infant, pregnant women, old man and chronic.Its main source has several aspect:
(1), as all kinds of Phenol aldehyde resin wood-based plates of the finishing material such as wall dunnage, top ceiling, such as plywood, thin plank, fiberboard and shaving board etc.;
(2) finishing material, containing formaldehyde components also likely outwardly distributed, such as WALL CLOTH, wallpaper, paint and coating pipe;
(3), the likely Interior Display of emitting formaldehyde and daily necessities, such as furniture, chemical fibre carpet and porous plastics etc.;
(4), can some material of emitting formaldehyde after burning, such as cigarette and some organic materialss;
(5), some perfume compound, kill mosquito liquid also containing formaldehyde components;
(6), at home in metope (coating) floor, furniture and some articles for use, pendulum decorations for anticorrosive mildewproof all prior with Antisepticize and mildew preventive process, most of sanitas all has impact to human body, and especially the harm of formaldehyde to human body is the most serious.
These objectionable impuritiess exist in everyday environments and household goods, and constantly discharge some objectionable impurities, and release period can more than 10 years.If do not eliminate these objectionable impuritiess in home environment, long-term accumulated has very large threat to HUMAN HEALTH.
At present, remove the method for formaldehyde except ventilation and plant absorption, mainly containing two kinds: one is physisorphtion, mainly utilizes the PARA FORMALDEHYDE PRILLS(91,95) of activated carbon, Exocarpium cocois (Cocos nucifera L), polymer formaldehyde-trapping agent and so on to carry out physical absorption.Advantage is harmless to human non-toxic, and shortcoming absorption rate and effect are not too desirable.
Two is chemical processes, and wherein one utilizes de-aldehyde agent, directly brushes on sheet material or the seam crossing of sheet material, and infiltration sheet material is combined with formaldehyde and forms solid; This method acts on root, but be not preferably assembled into cupboard, or uses in the making processes of sheet material again, just can reach best effect.If directly cashier's office in a shop brushed at finished product, because plate surface processes, the effect that aldehydes removal liquid infiltrates is bad.Another kind utilizes spraying, and this benefit is exactly formaldehyde that can be free in Quick Catch air, does not have what taste; But can crystallisate be produced after some chemical substance and formaldehyde effect, any corner may be dropped on, have certain influence to HUMAN HEALTH; If eaten by mistake, consequence is comparatively serious.
Therefore people are in order to reduce indoor formaldehyde as far as possible, and except as far as possible adopting the starting material of environmental protection, also can add some in such as coating can the functional agent of formaldehyde adsorption.But with regard to furniture, in order to the stupid stain of furniture surface, dirt, the removal slight scratches in surface and grinding marks fast, thoroughly can be removed, usually also can at outermost layer wiping coating of wax, it is made to form the protective membrane of one deck light at furniture surface, make furniture present more smooth beautiful color, there is the several functions such as waterproof, anti-oxidant, uvioresistant simultaneously; But the contact of the existence of cere meeting barriers function coating and air, reduces the function except formaldehyde of functional paint.
Summary of the invention
In order to solve the problem, the object of the invention is to, provide one can protect furniture very well, there is the Photocatalyst water wax of good absorption Formaldehyde in Environment function simultaneously.
The present invention is achieved through the following technical solutions:
A kind of Photocatalyst water wax, comprises the following material calculated according to weight percent:
Preferably, described water-borne wax slurry is the one or more combination thing in paraffin, PE wax, PP wax or palm wax.
Preferably, described water-base resin is the PUD water-base resin that minimum film-forming temperature is less than 0 DEG C.
Preferably, described nano inorganic pigment is nanometer grade silica (SiO
2), nano level aluminium sesquioxide (A1
2o
3), nanoscale boron (B
2o
3), nano level ferric oxide (Fe
2o
3), nanoscale magnesium (MgO), nano size Titania (TiO
2) in one or more combination thing.
Wherein, described nano inorganic pigment more preferably forms by comprising the following material calculated according to weight percent:
Preferably, described nano inorganic pigment stirs 30 ~ 40min preparation and obtains after being mixed according to the proportioning of above-mentioned amount by described nanometer grade silica, nano level aluminium sesquioxide, nanoscale boron, nano level ferric oxide, nanoscale magnesium, nano size Titania under 900 ~ 1100rpm.
Prepare the method for described Photocatalyst water wax, comprise following preparation process:
First the nano inorganic pigment of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 8 ~ 15min under 500 ~ 700rpm;
Then add described defoamer and stir 8 ~ 15min under 700 ~ 100rpm;
Then low whipping speed constant while add water-base resin, stir 5min;
Finally add described AMP95, under 700 ~ 1000rpm, stir 8 ~ 15min; Obtained described Photocatalyst water wax.
The present invention includes water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, defoamer, water-base resin, AMP95 and water, and by being obtained by mixing under different stirring velocity in batches; Wherein water-borne wax slurry can be paraffin, PE wax, PP wax, palm wax, mainly for promoting feel, and protection coated article.Sterilant for not containing formaldehyde have sterilant, the effect of propylene glycol mainly increases operability; Water is deionized water or tap water, can produce bubble in stirring, the preferred organosilicon of defoamer and mineral oil type defoamer; Water-base resin is PUD water-base resin, and minimum film-forming temperature is less than 0 DEG C, not containing organic solvent.AMP95 is pH value adjusting agent, and adjusted to ph is 8 ~ 9, increases stability in storage.
The present invention adopts nano inorganic pigment, can discharge negative ion, and the objectionable impurities in air is combined and then decomposes to fall objectionable impurities; The wherein composition of the multiple nano-scale oxide different ratio of nano inorganic pigment optimization, such combination carries out compatibility according to the different performance of often kind of material, ensure the persistence of its anion releasing, while ensureing the objectionable impurities validity such as described water-borne wax slurry adsorption-decomposition function formaldehyde, ensure its lasting adsorption-decomposition function ability.For making nano inorganic pigment energy extended stationary periods on furniture or articles for use, the objectionable impurities that the material (resin) that need add energy film forming discharges from furniture or articles for use, just can, by negative ion decomposition, avoid evaporateing in air at once.Wax has defencive function, can reduce furniture or articles for use and be subject to externality (as: scratch or adhesion dust).Solvent-borne type wax can affect environment by volatile organic solvent, so adopt environment-friendly type water wax.The storage of water is subject to bacterial contamination and smelly, and adding can the growth of anti-bacteria containing the sterilant of formaldehyde.Do not add essence, there is no smell completely.
The present invention not only has the function of wax completely, fast, thoroughly can remove the stupid stain of furniture surface, dirt, the removal slight scratches in surface and grinding marks, the protective membrane of one deck light can also be formed at furniture surface, make furniture present more smooth beautiful color, there is the abilities such as waterproof, anti-oxidant, uvioresistant simultaneously; And by the wiping of furniture or spraying; wax layer is near furniture side on the one hand; can well decompose with sealing by the furniture objectionable impuritiess such as formaldehyde that produce itself; make it can not be distributed in air; the opposing party's mercolized wax layer is near air side, and containing nano inorganic pigment by it can under uviolizing, the objectionable impurities generation redox reactions such as catalysis formaldehyde, benzene, VOC; thus decompose the objectionable impurities reduced in room air, furniture not only can be protected health more to be protected healthy for a long time simultaneously.
Concrete embodiment
Below in conjunction with embodiment, the present invention is described in further detail, understands the present invention to help those skilled in the art.
Embodiment 1
A kind of Photocatalyst water wax, comprises the following material calculated according to weight percent: water-based PP wax 25.0%, sterilant 0.3%, propylene glycol 1.5%, nanometer grade silica 3.0%, defoamer 0.15%, water-base resin 12.0%, AMP950.01% and water.
Prepare the method for described Photocatalyst water wax, comprise following preparation process:
First the photocatalyst of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 15min under 700rpm; Then add described defoamer and stir 15min under 700rpm; Then low whipping speed constant while add water-base resin, stir 5min; Finally add described AMP95, under 700rpm, stir 15min obtain described Photocatalyst water wax.
Embodiment 2
A kind of Photocatalyst water wax, comprises the following material calculated according to weight percent: water-based paraffin 30.0%, sterilant 0.2%, propylene glycol 1.0%, nano inorganic pigment 5.0%, defoamer 0.1%, water-base resin 10.0%, AMP950.02% and water.
Wherein, described nano inorganic pigment is obtained by mixing by comprising the following material calculated according to weight percent: nanometer grade silica 1.5%, nano level aluminium sesquioxide 0.5%, nanoscale boron 0.5%, nano level ferric oxide 1.0%, nanoscale magnesium 0.5% and nano size Titania 1.0% are stirred under 1000rpm 30min and prepare and obtain.
Prepare the method for described Photocatalyst water wax, comprise following preparation process:
First the photocatalyst of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 10min under 800rpm; Then add described defoamer and stir 10min under 900rpm; Then low whipping speed constant while add water-base resin, stir 5min; Finally add described AMP95, under 800rpm, stir 10min obtain described Photocatalyst water wax.
Embodiment 3
A kind of Photocatalyst water wax, comprises the following material calculated according to weight percent: water-based PE wax 30.0%, sterilant 0.2%, propylene glycol 1.0%, nano inorganic pigment 5.0%, defoamer 0.1%, water-base resin 10.0%, AMP950.02% and water.
Wherein, described nano inorganic pigment is obtained by mixing by comprising the following material calculated according to weight percent: nanometer grade silica 1.2%, nano level aluminium sesquioxide 0.8%, nanoscale boron 0.3%, nano level ferric oxide 0.8%, nanoscale magnesium 0.8% and nano size Titania 1.1% are stirred under 900rpm 35min and prepare and obtain.
Prepare the method for described Photocatalyst water wax, comprise following preparation process:
First the photocatalyst of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 10min under 800rpm; Then add described defoamer and stir 10min under 800rpm; Then low whipping speed constant while add water-base resin, stir 5min; Finally add described AMP95, under 800rpm, stir 10min obtain described Photocatalyst water wax.
Embodiment 4
A kind of Photocatalyst water wax, comprises the following material calculated according to weight percent: water-based palm wax 30.0%, sterilant 0.2%, propylene glycol 1.0%, nano inorganic pigment 5.0%, defoamer 0.1%, water-base resin 10.0%, AMP95 0.02% and water.
Wherein, described nano inorganic pigment is obtained by mixing by comprising the following material calculated according to weight percent: nanometer grade silica 1.8%, nano level aluminium sesquioxide 0.3%, nanoscale boron 0.8%, nano level ferric oxide 1.0%, nanoscale magnesium 0.3% and nano size Titania 0.8% are stirred under 1000rpm 30min and prepare and obtain.
Prepare the method for described Photocatalyst water wax, comprise following preparation process:
First the photocatalyst of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 10min under 800rpm; Then add described defoamer and stir 10min under 800rpm; Then low whipping speed constant while add water-base resin, stir 5min; Finally add described AMP95, under 800rpm, stir 10min obtain described Photocatalyst water wax.
Embodiment 5
A kind of Photocatalyst water wax, comprises the following material calculated according to weight percent:
Water-borne wax slurry 32.0%(comprising paraffin 5.0%, PE wax 5.0% and palm wax 22.0%), sterilant 0.25%, propylene glycol 1.2%, nano inorganic pigment 6.0%, defoamer 0.12%, water-base resin 9.5%, AMP950.25% and water.
Wherein, described nano inorganic pigment is obtained by mixing by comprising the following material calculated according to weight percent: nanometer grade silica 0.5%, nano level aluminium sesquioxide 0.5%, nanoscale boron 0.5%, nano level ferric oxide 1.0%, nanoscale magnesium 0.5% and nano size Titania 1.0% are stirred under 1000rpm 30min and prepare and obtain.
Prepare the method for described Photocatalyst water wax, comprise following preparation process:
First the photocatalyst of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 8min under 700rpm; Then add described defoamer and stir 8min under 1000rpm; Then low whipping speed constant while add water-base resin, stir 5min; Finally add described AMP95, under 1000rpm, stir 8min obtain described Photocatalyst water wax.
Above-described embodiment, just preferred embodiment of the present invention, is not used for limiting the scope of the present invention, therefore all equivalences done with the structure described in the claims in the present invention, feature and principle change or modify, and all should be included within the claims in the present invention scope.
The present invention JC/T1074-2008 method detected, its result is as follows:
1, purifying formaldehyde performance:
2, purifying formaldehyde is performance lasting:
As seen from the above table, no matter the present invention is in purifying formaldehyde performance, or have obvious effect in purifying formaldehyde is performance lasting, along with the increase of time, detected formaldehyde content reduces, and illustrates that the present invention has the function of decomposing and absorbing formaldehyde.
Claims (5)
1. a Photocatalyst water wax, is characterized in that, comprises the following material calculated according to weight percent:
Described water-base resin is the PUD water-base resin that minimum film-forming temperature is less than 0 DEG C;
Described nano inorganic pigment is nanometer grade silica, nano level aluminium sesquioxide, nanoscale boron, nano level ferric oxide, nanoscale magnesium and nano size Titania.
2. Photocatalyst water wax according to claim 1, is characterized in that, described water-borne wax slurry is the one or more combination thing in paraffin, PE wax, PP wax or palm wax.
3. Photocatalyst water wax according to claim 1, is characterized in that, described nano inorganic pigment forms by comprising the following material calculated according to weight percent:
4. Photocatalyst water wax according to claim 3, it is characterized in that, described nano inorganic pigment stirs 30 ~ 40min preparation and obtains after being mixed according to the proportioning of above-mentioned amount by described nanometer grade silica, nano level aluminium sesquioxide, nanoscale boron, nano level ferric oxide, nanoscale magnesium, nano size Titania under 900 ~ 1100rpm.
5. prepare the method for Photocatalyst water wax described in any one in Claims 1 to 4, it is characterized in that, comprise following preparation process:
First the nano inorganic pigment of above-mentioned amount, water-borne wax slurry, sterilant, propylene glycol, nano inorganic pigment, water are stirred 8 ~ 15min under 500 ~ 700rpm;
Then add described defoamer and stir 8 ~ 15min under 700 ~ 100rpm;
Then low whipping speed constant while add water-base resin, stir 5min;
Finally add described AMP95, under 700 ~ 1000rpm, stir 8 ~ 15min obtain described Photocatalyst water wax.
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| CN201310136524.9A CN103254797B (en) | 2013-04-18 | 2013-04-18 | A kind of Photocatalyst water wax and preparation method thereof |
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| CN103254797B true CN103254797B (en) | 2015-10-28 |
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| CN106239664A (en) * | 2016-08-25 | 2016-12-21 | 阜南县永兴工艺品有限公司 | A kind of high temperature resistant aging resistance straw treatment fluid and preparation method thereof |
| CN107556915A (en) * | 2017-10-10 | 2018-01-09 | 佛山市三水区白坭镇巨财红木厂 | A kind of wear-resisting paraffin of furniture |
| CN109705727A (en) * | 2018-12-27 | 2019-05-03 | 广东顺德三阳化学有限公司 | A kind of nanometer of protection liquid and preparation method thereof, household items protection product and nano protective film |
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| JP2007070546A (en) * | 2005-09-08 | 2007-03-22 | Matsushita Electric Works Ltd | Natural wax and moisture absorbing and releasing material with decoration given by using the same |
| CN101182402A (en) * | 2006-11-13 | 2008-05-21 | 北京金源化学集团有限公司 | Aqueous antibiotic floor wax |
| CN101597457A (en) * | 2008-06-07 | 2009-12-09 | 济南公泰科技有限公司 | Nanometer photocatalyst aqueous polyester coating for woodenware |
| CN102408828A (en) * | 2011-09-29 | 2012-04-11 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
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2013
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007070546A (en) * | 2005-09-08 | 2007-03-22 | Matsushita Electric Works Ltd | Natural wax and moisture absorbing and releasing material with decoration given by using the same |
| CN101182402A (en) * | 2006-11-13 | 2008-05-21 | 北京金源化学集团有限公司 | Aqueous antibiotic floor wax |
| CN101597457A (en) * | 2008-06-07 | 2009-12-09 | 济南公泰科技有限公司 | Nanometer photocatalyst aqueous polyester coating for woodenware |
| CN102408828A (en) * | 2011-09-29 | 2012-04-11 | 刘光君 | Nano silicon dioxide modified hard wood wax oil and preparation method thereof |
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