CN106280998B - A kind of diatom ooze coating of high-efficient purification and oil rub resistance - Google Patents

A kind of diatom ooze coating of high-efficient purification and oil rub resistance Download PDF

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Publication number
CN106280998B
CN106280998B CN201610651349.0A CN201610651349A CN106280998B CN 106280998 B CN106280998 B CN 106280998B CN 201610651349 A CN201610651349 A CN 201610651349A CN 106280998 B CN106280998 B CN 106280998B
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parts
diatom ooze
ooze coating
rub resistance
efficient purification
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CN106280998A (en
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林森安
洪永顺
刘双华
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Guangdong Longhu Sci&tech Co Ltd
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Guangdong Longhu Sci&tech Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/04—Polysiloxanes
    • C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1668—Vinyl-type polymers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662—Synthetic film-forming substance
    • C09D5/1675—Polyorganosiloxane-containing compositions
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1687—Use of special additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention provides it is a kind of can high-efficient purification room air and with fine oil rub resistance effect diatom ooze coating, the coating includes the diatomite that parts by weight are 15~20 parts, 10~30 parts of fluorine richness organosilicon, 5~10 parts of acrylic emulsion, 1~5 part of photocatalyst material, 20~55 parts of filler, 1~3 part of thickener, 0.3~0.5 part of antifoaming agent, 0.3~0.7 part of wetting dispersing agent, 0.2~0.5 part of antimildew disinfectant and 15~35 parts of water, wherein fluorine richness organosilicon is the organosilicon product that the trade mark of German Wacker Chemie GmbH's production is WACKER BS 38；Photocatalyst material is the photochemical catalyst that the trade mark that Guangdong Longhu Technology Shares Co., Ltd. produces is CLAUVIS P 10；Thickener includes hydroxyethyl cellulose, polyurethane thickener and alkali swollen thickener.The diatom ooze coating of the present invention, not only good decorating effect, but also can the indoor poisonous and harmful substance of efficient absorption, low contamination and grease proofness, can more play the excellent specific property of diatom ooze coating to greatest extent.

Description

A kind of diatom ooze coating of high-efficient purification and oil rub resistance
Technical field
The present invention relates to a kind of coating more particularly to a kind of diatom ooze coatings for inner wall decoration, specifically relate to A kind of energy high-efficient purification room air and the diatom ooze coating with fine oil rub resistance effect.
Background technology
With the continuous improvement of people's living standards, home decoration is also increasingly valued by people, but the study found that Many home decoration materials more or less understand the small molecules harmful substance such as slow release aldehydes, phenols, alcohols, easily to people Body health damages.With continuous promotion of the people to health requirements, indoor environment is improved, reduces finishing pollution by more More people are paid attention to.Diatom ooze is the new coating using diatomite as main raw material(s), due to its with excellent environmental-protecting performance and Pursuing for finishing owner is received, in recent years, the home decoration that wallpaper and emulsion paint are substituted using diatom ooze is more and more.Diatom is A kind of nano level porous material, porosity are up to 90%, and rule is fitly arranged in round and aciculiform, on unit area Fine hole number it is more than charcoal go out thousands of times, therefore moisturizing, absorption particulate in air and poisonous and harmful gas can be played The effect of body.The universal hygroscopicity of liquid diatom ooze coating currently on the market is fine, but its scrub performance is poor, spot-resistant Difference, since home life environment more or less can all generate certain oil smoke, and diatom ooze has extremely strong adsorptivity, will certainly Absorption oil smoke causes the hole of paint film to be blocked, and not only influences beautiful but also can lose original adsorption function, in addition, diatom Mud adsorbs particulate in air and toxic and harmful gas reaches a certain level, and detergent power also can decline and lose.Therefore, such as What keeps the unimpeded of diatom ooze material hole, plays the excellent specific property of diatom ooze coating to greatest extent, increasingly diversified to meet The demand of home furnishings market becomes the emphasis of industry research.
Invention content
To overcome the problems, such as present on, the object of the present invention is to provide the diatom mash of a kind of high-efficient purification and oil rub resistance Material.
In order to achieve the above object, the high-efficient purification of the present invention and the diatom ooze coating of oil rub resistance, including following each component and Parts by weight：
15~20 parts of diatomite
10~30 parts of fluorine richness organosilicon
5~10 parts of acrylic emulsion
1~5 part of photocatalyst material
20~55 parts of filler
1~3 part of coalescents
0.6~1.5 part of thickener
0.3~0.5 part of antifoaming agent
0.3~0.7 part of wetting dispersing agent
0.2~0.5 part of antimildew disinfectant
15~35 parts of water
Above-mentioned fluorine richness organosilicon is that the trade mark of German Wacker Chemie GmbH's production is the organic of WACKER BS 38 Silicon product；Photocatalyst material is the photocatalysis that the trade mark that Guangdong Longhu Technology Shares Co., Ltd. produces is CLAUVIS P-10 Agent；Thickener includes hydroxyethyl cellulose, polyurethane thickener and alkali swollen thickener.
The granularity of above-mentioned diatomite and filler preferably 1000~1250 mesh.
One or more of the preferred fine particle calcium carbonate of above-mentioned filler, coarse whiting, talcum powder, kaolin, titanium dioxide, mica powder.
In order to more preferably improve paint film feel, reduce cost, improve covering power, the preferred fine particle calcium carbonate of above-mentioned filler, coarse whiting, talcum powder And titanium dioxide.
In order to further improve the covering power of coating, the above-mentioned preferred rutile type titanium white of titanium dioxide.
In order to reduce the smell of coating, the preferred modified fat acid of above-mentioned antifoaming agent and alkoxide compound.
In order to more preferably reduce the smell of coating, the preferably low smell of above-mentioned coalescents, high boiling alcohol ester type organic.
Above-mentioned wetting dispersing agent includes wetting agent and dispersant, and antimildew disinfectant includes mould inhibitor and antiseptic.
In order to further reduce the smell of coating, above-mentioned dispersant particular certain cancers dispersant.
The high-efficient purification of the present invention and the diatom ooze coating of oil rub resistance, using the WACKER BS 38 of German Wa Ke companies Fluorine richness organosilicon coordinates acrylic emulsion, and as binding agent, WACKER BS 38 are a kind of silane, siloxanes and synthetic resin Mixture, this organosilicon mixture be by fluorine richness, paint film film forming after, not only have very high water vapour and sky Vapor permeability, and hate oily function with excellent, this greatly reduces absorption of the paint film to oil smoke, more preferably keep diatom ooze Hole it is penetrating, and add in CLAUVIS P-10 photochemical catalysts in formula, due to the photochemical catalyst be by transition metal Co, The one or more such as Ce, W or Ag are doped modified nano-titanium dioxide, the formaldehyde that the diatom ooze that can effectively degrade absorbs Etc. harmful substances, the more preferable efficacy of adsorption for extending diatom ooze coating；In addition, using hydroxyethyl cellulose, polyurethane thickener and Alkali swollen thickener while the thickener as system can prevent powder precipitation, thickening water phase and oil phase, make coating system more Add stabilization.The diatom ooze coating of the present invention, not only good decorating effect, but also can the indoor poisonous and harmful substance of efficient absorption, Its low contamination and grease proofness can more play the excellent specific property of diatom ooze coating, especially suitable for house, school etc. to greatest extent The decoration of interior wall.
Specific embodiment
First, product example
Embodiment 1
Formula：
1250 15 parts of mesh diatomite
38 15 parts of Wa Ke companies WACKER BS
2,741 5 parts of A Kema acrylic emulsions
Imperial 2 parts of lake science and technology CLAUVIS P-10 photocatalyst materials
2,295 5 parts of Down rutile titanium white powder
1250 15 parts of mesh coarse whitings
1250 5 parts of mesh fine particle calcium carbonates
1250 5 parts of mesh talcum powder
Imperial 1 part of lake science and technology coalescents FA N1
0.5 part of hydroxyethyl cellulose
0.3 part of polyurethane thickener
0.3 part of alkali swollen thickener
Bright 0.4 part of icepro antifoaming agent A351
Bright 388 0.2 parts of wetting agent of icepro
High 0.6 part of Thailand dispersant P30
0.3 part of fungicide
0.4 part of mould inhibitor
29 parts of water
100 parts of total weight parts
Embodiment 2
1250 15 parts of mesh diatomite
38 20 parts of Wa Ke companies WACKER BS
2,741 7 parts of A Kema acrylic emulsions
Imperial 2 parts of lake science and technology CLAUVIS P-10 photocatalyst materials
2,295 10 parts of Down rutile titanium white powder
1250 10 parts of mesh coarse whitings
1250 5 parts of mesh fine particle calcium carbonates
1250 5 parts of mesh talcum powder
Imperial 2 parts of lake science and technology coalescents FA N1
0.4 part of hydroxyethyl cellulose
0.3 part of polyurethane thickener
0.3 part of alkali swollen thickener
Bright 0.4 part of icepro antifoaming agent A351
Bright 388 0.2 parts of wetting agent of icepro
High 0.7 part of Thailand dispersant P30
0.3 part of fungicide
0.4 part of mould inhibitor
21 parts of water
100 parts of total weight parts
Embodiment 3
Formula：
1250 15 parts of mesh diatomite
38 25 parts of Wa Ke companies WACKER BS
2,741 10 parts of A Kema acrylic emulsions
Imperial 2 parts of lake science and technology CLAUVIS P-10 photocatalyst materials
2,295 15 parts of Down rutile titanium white powder
1250 5 parts of mesh coarse whitings
1250 5 parts of mesh fine particle calcium carbonates
1250 5 parts of mesh talcum powder
Imperial 3 parts of lake science and technology coalescents FA N1
0.4 part of hydroxyethyl cellulose
0.3 part of polyurethane thickener
0.3 part of alkali swollen thickener
Bright 0.4 part of icepro antifoaming agent A351
Bright 388 0.2 parts of wetting agent of icepro
High 0.7 part of Thailand dispersant P30
0.3 part of fungicide
0.4 part of mould inhibitor
21 parts of water
109 parts of total weight parts
2nd, properties of product are tested
By coating made from above-described embodiment 1,2,3, pH value is measured under the conditions of 23 DEG C as 8-8.5, according to GB/T 9756-2009《Resin latex dope》Standard tests product properties, wherein stain resistant testing standard By GB/T 9755-2014《Exterior wall coating material of synthetic resin emulsion》Standard is tested, as a result as follows：
As can be seen from the above table, the diatom ooze coating of high-efficient purification provided by the invention and oil rub resistance has good anti-scratch It washes, covering power and stain resistance.
It is illustrating for the several embodiments of diatom ooze coating of the present invention above, but these embodiments are not to limit Protection scope of the present invention, all equivalence enforcements or change without departing from technical solution of the present invention, such as the transformation of filler or auxiliary agent, It should be included within the scope of the invention.

Claims (9)

1. a kind of diatom ooze coating of high-efficient purification and oil rub resistance, including following each component and parts by weight：
15~20 parts of diatomite
10~30 parts of fluorine richness organosilicon
5~10 parts of acrylic emulsion
1~5 part of photocatalyst material
20~55 parts of filler
1~3 part of coalescents
0.6~1.5 part of thickener
0.3~0.5 part of antifoaming agent
0.3~0.7 part of wetting dispersing agent
0.2~0.5 part of antimildew disinfectant
15~35 parts of water
Above-mentioned fluorine richness organosilicon is the organosilicon production that the trade mark of German Wacker Chemie GmbH's production is WACKER BS 38 Product；Photocatalyst material is the photochemical catalyst that the trade mark that Guangdong Longhu Technology Shares Co., Ltd. produces is CLAUVIS P-10；Increase Thick dose is hydroxyethyl cellulose, polyurethane thickener and alkali swollen thickener.
2. the diatom ooze coating of high-efficient purification according to claim 1 and oil rub resistance, it is characterised in that：The diatomite and The granularity of filler is 1000~1250 mesh.
3. the diatom ooze coating of high-efficient purification according to claim 1 or 2 and oil rub resistance, it is characterised in that：The filler For one or more of fine particle calcium carbonate, coarse whiting, talcum powder, kaolin, titanium dioxide, mica powder.
4. the diatom ooze coating of high-efficient purification according to claim 3 and oil rub resistance, it is characterised in that：The filler is light Calcium, coarse whiting, talcum powder and titanium dioxide.
5. the diatom ooze coating of high-efficient purification according to claim 4 and oil rub resistance, it is characterised in that：The titanium dioxide is Rutile type titanium white.
6. the diatom ooze coating of high-efficient purification according to claim 5 and oil rub resistance, it is characterised in that：The antifoaming agent is Modified fat acid and alkoxide compound.
7. the diatom ooze coating of high-efficient purification according to claim 6 and oil rub resistance, it is characterised in that：The coalescents For low smell, high boiling alcohol ester type organic.
8. the diatom ooze coating of high-efficient purification according to claim 7 and oil rub resistance, it is characterised in that：The wetting and dispersing Agent is wetting agent and dispersant, and antimildew disinfectant is mould inhibitor and antiseptic.
9. the diatom ooze coating of high-efficient purification according to claim 8 and oil rub resistance, it is characterised in that：The dispersant is Sodium salt dispersant.
CN201610651349.0A 2016-08-09 2016-08-09 A kind of diatom ooze coating of high-efficient purification and oil rub resistance Active CN106280998B (en)

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107244878A (en) * 2017-05-23 2017-10-13 欧亚绿邦（北京）科技有限公司 High scrubbing resistance diatom ooze and preparation method thereof
CN107573728A (en) * 2017-09-20 2018-01-12 芜湖县双宝建材有限公司 A kind of ageing-resistant diatom ooze coating of resistant
CN108191375A (en) * 2018-01-04 2018-06-22 童彬原 A kind of organically-modified inorganic mineral coating material of aqueous diatom and preparation method thereof
CN108299985A (en) * 2018-01-15 2018-07-20 杭州力天金碧化工技术有限公司 It is a kind of to produce zero methanal paint and technique after the preposition purified treatment of raw material
CN112778854A (en) * 2020-12-29 2021-05-11 沈阳康亿环保科技有限公司 Intelligent luminous liquid diatom coating

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102690572A (en) * 2012-06-19 2012-09-26 谢锋 Emulsion paint capable of absorbing automobile exhaust
CN102888155A (en) * 2012-10-26 2013-01-23 合众（佛山）化工有限公司 Preparation method of odorless environment-friendly humidifying antibacterial paint
CN104387816A (en) * 2014-11-28 2015-03-04 佛山市南海万磊建筑涂料有限公司 Multifunctional inorganic diatom ooze coating and preparation method thereof
CN105542594A (en) * 2016-02-25 2016-05-04 广东龙马化学有限公司 Photocatalyst formaldehyde-buster internal wall paint and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102690572A (en) * 2012-06-19 2012-09-26 谢锋 Emulsion paint capable of absorbing automobile exhaust
CN102888155A (en) * 2012-10-26 2013-01-23 合众（佛山）化工有限公司 Preparation method of odorless environment-friendly humidifying antibacterial paint
CN104387816A (en) * 2014-11-28 2015-03-04 佛山市南海万磊建筑涂料有限公司 Multifunctional inorganic diatom ooze coating and preparation method thereof
CN105542594A (en) * 2016-02-25 2016-05-04 广东龙马化学有限公司 Photocatalyst formaldehyde-buster internal wall paint and preparation method thereof

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