CN106280998A - A kind of high-efficient purification and the diatom ooze coating of oil rub resistance - Google Patents
A kind of high-efficient purification and the diatom ooze coating of oil rub resistance Download PDFInfo
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- CN106280998A CN106280998A CN201610651349.0A CN201610651349A CN106280998A CN 106280998 A CN106280998 A CN 106280998A CN 201610651349 A CN201610651349 A CN 201610651349A CN 106280998 A CN106280998 A CN 106280998A
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- diatom ooze
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1668—Vinyl-type polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention provides a kind of energy high-efficient purification room air and there is the diatom ooze coating of fine oil rub resistance effect, this coating includes the kieselguhr that parts by weight are 15~20 parts, the fluorine richness organosilicon of 10~30 parts, the acrylic emulsion of 5~10 parts, the photocatalyst material of 1~5 part, the filler of 20~55 parts, the thickening agent of 1~3 part, the defoamer of 0.3~0.5 part, the wetting dispersing agent of 0.3~0.7 part, the antimildew disinfectant of 0.2~0.5 part and the water of 15~35 parts, wherein fluorine richness organosilicon is the organosilicon product that the trade mark is WACKER BS 38 that Wacker Chemie GmbH of Germany produces;Photocatalyst material is the photocatalyst that the trade mark is CLAUVIS P 10 that Guangdong Longhu Technology Shares Co., Ltd. produces;Thickening agent includes hydroxyethyl cellulose, polyurethane thickener and alkali swollen thickener.The diatom ooze coating of the present invention, not only good decorating effect, and can the indoor poisonous and harmful substance of efficient absorption, its low contamination and grease proofness, more can play the excellent specific property of diatom ooze coating to greatest extent.
Description
Technical field
The present invention relates to a kind of coating, particularly relate to a kind of diatom ooze coating for inner wall decoration, specifically relate to
A kind of can high-efficient purification room air and there is the diatom ooze coating of fine oil rub resistance effect.
Background technology
Along with improving constantly of people's living standard, home decoration is the most increasingly subject to people's attention, but research finds,
A lot of home decoration materials more or less can slowly discharge the little molecule harmful substances such as such as aldehydes, phenols, alcohols, easily to people
Body health damages.Along with the people's continuous lifting to health requirements, improve indoor environment, reduce finishing pollution by more
Many people are paid attention to.Diatom ooze is the new coating with kieselguhr as main raw material(s), due to its have excellence environmental-protecting performance and
Enjoying pursuing of finishing owner, in recent years, the home decoration using diatom ooze to substitute wallpaper and emulsion paint gets more and more.Diatom is
A kind of nano level porous material, porosity is up to 90%, rule, is fitly arranged in circle and aciculiform, in its unit are
Minute aperture quantity goes out thousands of times more than Linesless charcoal, therefore, it is possible to play moisturizing, absorption particulate in air and poisonous and harmful gas
The effect of body.The universal hygroscopicity of liquid diatom ooze coating currently on the market is fine, but its scrub performance is poor, spot-resistant also
Difference, the most all can produce certain oil smoke, and diatom ooze has extremely strong adsorptivity due to life staying idle at home environment, will certainly
Absorption oil smoke causes the hole of paint film blocked, not only affects attractive in appearance but also can lose original adsorption function, it addition, diatom
Mud absorption particulate in air and toxic and harmful reach to a certain degree, and its detergent power also can decline and lose.Therefore, as
What keeps the unimpeded of diatom ooze material hole, plays the excellent specific property of diatom ooze coating to greatest extent, to meet variation day by day
The demand of home furnishings market, becomes the emphasis of industry research.
Summary of the invention
For overcome with present on problem, it is an object of the invention to provide the diatom mash of a kind of high-efficient purification and oil rub resistance
Material.
For realizing object above, the high-efficient purification of the present invention and the diatom ooze coating of oil rub resistance, including following each component and
Parts by weight:
Kieselguhr 15~20 parts
Fluorine richness organosilicon 10~30 parts
Acrylic emulsion 5~10 parts
Photocatalyst material 1~5 parts
Filler 20~55 parts
Coalescents 1~3 parts
Thickening agent 0.6~1.5 parts
Defoamer 0.3~0.5 part
Wetting dispersing agent 0.3~0.7 part
Antimildew disinfectant 0.2~0.5 part
Water 15~35 parts
Above-mentioned fluorine richness organosilicon is that the organosilicon that the trade mark is WACKER BS 38 that Wacker Chemie GmbH of Germany produces produces
Product;Photocatalyst material is the photocatalyst that the trade mark is CLAUVIS P-10 that Guangdong Longhu Technology Shares Co., Ltd. produces;Increase
Thick dose includes hydroxyethyl cellulose, polyurethane thickener and alkali swollen thickener.
The granularity of above-mentioned kieselguhr and filler preferably 1000~1250 mesh.
One or more in the preferred fine particle calcium carbonate of above-mentioned filler, triple superphosphate, Pulvis Talci, Kaolin, titanium dioxide, mica powder.
In order to more preferably improve paint film feel, reduce cost, raising covering power, the preferred fine particle calcium carbonate of above-mentioned filler, triple superphosphate, Pulvis Talci
And titanium dioxide.
In order to further improve the covering power of coating, the preferred Rutile type titanium dioxide of above-mentioned titanium dioxide.
In order to reduce the abnormal smells from the patient of coating, the acid of above-mentioned defoamer preferred modified fat and alkoxide compound.
In order to more preferably reduce the abnormal smells from the patient of coating, above-mentioned coalescents preferably less than abnormal smells from the patient, high boiling alcohol ester type organic.
Above-mentioned wetting dispersing agent includes wetting agent and dispersant, and antimildew disinfectant includes antifungus agent and antibacterial.
In order to further reduce the abnormal smells from the patient of coating, above-mentioned dispersant particular certain cancers dispersant.
The high-efficient purification of the present invention and the diatom ooze coating of oil rub resistance, use the WACKER BS 38 of Wa Ke company of Germany
Fluorine richness organosilicon coordinates acrylic emulsion as binding agent, and WACKER BS 38 is a kind of silane, siloxanes and synthetic resin
Mixture, this organosilicon mixture is through fluorine richness, after paint film film forming, not only has the highest water vapour and sky
Vapor permeability, and have excellence hate functional oil, this greatly reduces the paint film absorption to oil smoke, more preferably keep diatom ooze
Hole penetrating, and add CLAUVIS P-10 photocatalyst in formula, due to this photocatalyst be by transition metal Co,
Ce, W or Ag etc. one or more be doped the nano titanium oxide of modification, it is possible to the formaldehyde that effective degraded diatom ooze absorbs
Deng harmful substance, more preferably extend the efficacy of adsorption of diatom ooze coating;It addition, use hydroxyethyl cellulose, polyurethane thickener and
Alkali swollen thickener is simultaneously as the thickening agent of system, it is possible to prevents powder precipitation, thickening aqueous phase and oil phase, makes coating system more
Add stable.The diatom ooze coating of the present invention, not only good decorating effect, and can the indoor poisonous and harmful substance of efficient absorption,
Its low contamination and grease proofness, more can play the excellent specific property of diatom ooze coating to greatest extent, be particularly well-suited to house, school etc.
The decoration of interior wall.
Detailed description of the invention
One, product example
Embodiment 1
Formula:
1250 15 parts of mesh kieselguhr
Wa Ke company WACKER BS 38 15 parts
A Kema acrylic emulsion 2,741 5 parts
Dragon lake science and technology CLAUVIS P-10 photocatalyst material 2 parts
2,295 5 parts of Down rutile titanium white lead
1250 mesh triple superphosphate 15 parts
1250 mesh fine particle calcium carbonates 5 parts
1250 mesh Pulvis Talci 5 parts
Dragon lake science and technology coalescents FA N1 1 part
Hydroxyethyl cellulose 0.5 part
Polyurethane thickener 0.3 part
Alkali swollen thickener 0.3 part
Bright icepro defoamer A351 0.4 part
Bright icepro wetting agent 388 0.2 parts
High safe dispersant P30 0.6 part
Antibacterial 0.3 part
Antifungus agent 0.4 part
29 parts of water
Total weight parts 100 parts
Embodiment 2
1250 15 parts of mesh kieselguhr
Wa Ke company WACKER BS 38 20 parts
A Kema acrylic emulsion 2,741 7 parts
Dragon lake science and technology CLAUVIS P-10 photocatalyst material 2 parts
2,295 10 parts of Down rutile titanium white lead
1250 mesh triple superphosphate 10 parts
1250 mesh fine particle calcium carbonates 5 parts
1250 mesh Pulvis Talci 5 parts
Dragon lake science and technology coalescents FA N1 2 parts
Hydroxyethyl cellulose 0.4 part
Polyurethane thickener 0.3 part
Alkali swollen thickener 0.3 part
Bright icepro defoamer A351 0.4 part
Bright icepro wetting agent 388 0.2 parts
High safe dispersant P30 0.7 part
Antibacterial 0.3 part
Antifungus agent 0.4 part
21 parts of water
Total weight parts 100 parts
Embodiment 3
Formula:
1250 15 parts of mesh kieselguhr
Wa Ke company WACKER BS 38 25 parts
A Kema acrylic emulsion 2,741 10 parts
Dragon lake science and technology CLAUVIS P-10 photocatalyst material 2 parts
2,295 15 parts of Down rutile titanium white lead
1250 mesh triple superphosphate 5 parts
1250 mesh fine particle calcium carbonates 5 parts
1250 mesh Pulvis Talci 5 parts
Dragon lake science and technology coalescents FA N1 3 parts
Hydroxyethyl cellulose 0.4 part
Polyurethane thickener 0.3 part
Alkali swollen thickener 0.3 part
Bright icepro defoamer A351 0.4 part
Bright icepro wetting agent 388 0.2 parts
High safe dispersant P30 0.7 part
Antibacterial 0.3 part
Antifungus agent 0.4 part
21 parts of water
Total weight parts 109 parts
Two, properties of product test
The coating prepared by above-described embodiment 1,2,3, recording pH value under the conditions of 23 DEG C is 8-8.5, according to GB/T 9756-
Product properties is tested by 2009 " resin latex dope " standard, and wherein stain resistant testing standard presses GB/T
9755-2014 " exterior wall coating material of synthetic resin emulsion " standard is tested, and result is as follows:
As can be seen from the above table, the present invention provides high-efficient purification and the diatom ooze coating of oil rub resistance have good scrubbing resistance,
Covering power and stain resistance.
It is more than the illustrating of the several embodiment of diatom ooze coating of the present invention, but these embodiments be not used to limit
Protection scope of the present invention, all equivalences without departing from technical solution of the present invention are implemented or change, such as filler or the conversion of auxiliary agent, all
Should be included within the scope of the invention.
Claims (9)
1. high-efficient purification and a diatom ooze coating for oil rub resistance, including following each component and parts by weight:
Kieselguhr 15~20 parts
Fluorine richness organosilicon 10~30 parts
Acrylic emulsion 5~10 parts
Photocatalyst material 1~5 parts
Filler 20~55 parts
Coalescents 1~3 parts
Thickening agent 0.6~1.5 parts
Defoamer 0.3~0.5 part
Wetting dispersing agent 0.3~0.7 part
Antimildew disinfectant 0.2~0.5 part
Water 15~35 parts
Above-mentioned fluorine richness organosilicon is that the organosilicon that the trade mark is WACKER BS 38 that Wacker Chemie GmbH of Germany produces produces
Product;Photocatalyst material is the photocatalyst that the trade mark is CLAUVIS P-10 that Guangdong Longhu Technology Shares Co., Ltd. produces;Increase
Thick dose includes hydroxyethyl cellulose, polyurethane thickener and alkali swollen thickener.
High-efficient purification the most according to claim 1 and the diatom ooze coating of oil rub resistance, it is characterised in that: described kieselguhr and
The granularity of filler is 1000~1250 mesh.
High-efficient purification the most according to claim 1 and 2 and the diatom ooze coating of oil rub resistance, it is characterised in that: described filler
For one or more in fine particle calcium carbonate, triple superphosphate, Pulvis Talci, Kaolin, titanium dioxide, mica powder.
High-efficient purification the most according to claim 3 and the diatom ooze coating of oil rub resistance, it is characterised in that: described filler is light
Calcium, triple superphosphate, Pulvis Talci and titanium dioxide.
High-efficient purification the most according to claim 4 and the diatom ooze coating of oil rub resistance, it is characterised in that: described titanium dioxide is
Rutile type titanium dioxide.
High-efficient purification the most according to claim 5 and the diatom ooze coating of oil rub resistance, it is characterised in that: described defoamer is
Modified fat acid and alkoxide compound.
High-efficient purification the most according to claim 6 and the diatom ooze coating of oil rub resistance, it is characterised in that: described coalescents
For low abnormal smells from the patient, high boiling alcohol ester type organic.
High-efficient purification the most according to claim 7 and the diatom ooze coating of oil rub resistance, it is characterised in that: described wetting and dispersing
Agent includes wetting agent and dispersant, and antimildew disinfectant includes antifungus agent and antibacterial.
High-efficient purification the most according to claim 8 and the diatom ooze coating of oil rub resistance, it is characterised in that: described dispersant is
Sodium salt dispersant.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107244878A (en) * | 2017-05-23 | 2017-10-13 | 欧亚绿邦(北京)科技有限公司 | High scrubbing resistance diatom ooze and preparation method thereof |
CN107573728A (en) * | 2017-09-20 | 2018-01-12 | 芜湖县双宝建材有限公司 | A kind of ageing-resistant diatom ooze coating of resistant |
CN108191375A (en) * | 2018-01-04 | 2018-06-22 | 童彬原 | A kind of organically-modified inorganic mineral coating material of aqueous diatom and preparation method thereof |
CN108299985A (en) * | 2018-01-15 | 2018-07-20 | 杭州力天金碧化工技术有限公司 | It is a kind of to produce zero methanal paint and technique after the preposition purified treatment of raw material |
CN112778854A (en) * | 2020-12-29 | 2021-05-11 | 沈阳康亿环保科技有限公司 | Intelligent luminous liquid diatom coating |
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CN102690572A (en) * | 2012-06-19 | 2012-09-26 | 谢锋 | Emulsion paint capable of absorbing automobile exhaust |
CN102888155A (en) * | 2012-10-26 | 2013-01-23 | 合众(佛山)化工有限公司 | Preparation method of odorless environment-friendly humidifying antibacterial paint |
CN104387816A (en) * | 2014-11-28 | 2015-03-04 | 佛山市南海万磊建筑涂料有限公司 | Multifunctional inorganic diatom ooze coating and preparation method thereof |
CN105542594A (en) * | 2016-02-25 | 2016-05-04 | 广东龙马化学有限公司 | Photocatalyst formaldehyde-buster internal wall paint and preparation method thereof |
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2016
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Patent Citations (4)
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CN102690572A (en) * | 2012-06-19 | 2012-09-26 | 谢锋 | Emulsion paint capable of absorbing automobile exhaust |
CN102888155A (en) * | 2012-10-26 | 2013-01-23 | 合众(佛山)化工有限公司 | Preparation method of odorless environment-friendly humidifying antibacterial paint |
CN104387816A (en) * | 2014-11-28 | 2015-03-04 | 佛山市南海万磊建筑涂料有限公司 | Multifunctional inorganic diatom ooze coating and preparation method thereof |
CN105542594A (en) * | 2016-02-25 | 2016-05-04 | 广东龙马化学有限公司 | Photocatalyst formaldehyde-buster internal wall paint and preparation method thereof |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107244878A (en) * | 2017-05-23 | 2017-10-13 | 欧亚绿邦(北京)科技有限公司 | High scrubbing resistance diatom ooze and preparation method thereof |
CN107573728A (en) * | 2017-09-20 | 2018-01-12 | 芜湖县双宝建材有限公司 | A kind of ageing-resistant diatom ooze coating of resistant |
CN108191375A (en) * | 2018-01-04 | 2018-06-22 | 童彬原 | A kind of organically-modified inorganic mineral coating material of aqueous diatom and preparation method thereof |
CN108299985A (en) * | 2018-01-15 | 2018-07-20 | 杭州力天金碧化工技术有限公司 | It is a kind of to produce zero methanal paint and technique after the preposition purified treatment of raw material |
CN112778854A (en) * | 2020-12-29 | 2021-05-11 | 沈阳康亿环保科技有限公司 | Intelligent luminous liquid diatom coating |
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