CN101182402A - Aqueous antibiotic floor wax - Google Patents
Aqueous antibiotic floor wax Download PDFInfo
- Publication number
- CN101182402A CN101182402A CNA2006101384038A CN200610138403A CN101182402A CN 101182402 A CN101182402 A CN 101182402A CN A2006101384038 A CNA2006101384038 A CN A2006101384038A CN 200610138403 A CN200610138403 A CN 200610138403A CN 101182402 A CN101182402 A CN 101182402A
- Authority
- CN
- China
- Prior art keywords
- percent
- germicide
- wax
- antiseptic
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a water-based anti-bacterial floor wax. The floor wax has main components and weight ratio as follows: 10 percent to 70 percent of water-based polymer with 30 percent to 50 percent of solid content, 0 percent to 5 percent of alkaline soluble resin with 20 percent to 40 percent of solid content, 2 percent to 12 percent of plasticizing and film-forming auxiliary agent, 0.01 percent to 2 percent of defoamer, 1 percent to 10 percent of water-based wax emulsion, 0 percent to 1 percent of wetting flow agent, 0.01 percent to 5 percent of antibacterial agent, and 0 percent to 50 percent of deionized water. The invention has suppression functions for a plurality of common bacteria with the reasonable choice of composite antimicrobial products; the invention has the advantages of high antibacterial efficiency, long-time medicinal effect, good decorative effect, safety and environmentally protective performance.
Description
Technical field
The present invention relates to a kind of aqueous, environmental protective floor wax, particularly a kind of aqueous antibiotic floor wax.
Background technology
In recent years, along with the raising of people's living standard, the house fitting product is developed rapidly, and the floor wax demand that base protection is provided is increased thereupon fast, and simultaneously people have had higher more specifically demand more urgently to environmental protection and health.Watersoluble floor polish because of can provide anti-skidding, glazing, wear-resisting, prolong base material and base material decorations layer is more and more favored work-ing life; yet; because knowing from experience to produce with the people as the protective layer of base material, floor wax directly contacts; in order to keep health; prevent bacteria living breeding and harmful to human; usually adopt external treatment measures such as spraying medicine or medicine wiping to prevent; but its defective is a medicine to run off easily, bacterium easily regenerates, antimicrobial efficiency is low, and if having drug residue excessive to human body particularly the child can produce and poison and dangerous environmental protection.
Summary of the invention
The purpose of this invention is to provide that a kind of medicine be difficult for to run off, antibacterial ability is lasting, germ-killing efficiency is high and the aqueous antibiotic floor wax of safety and environmental protection, make it can overcome the deficiency that the general floorings wax product exists, the indispensable function that can have floor wax again, the more additional properties and the value of lifting watersoluble floor polish.
The present invention realizes that the technical scheme of above-mentioned purpose is, adopts a kind of aqueous antibiotic floor wax, and the main ingredient of this floor wax and weight proportion thereof are:
| A | Solids content is the waterborne polymeric of 30-50% | 10-70％ |
| B | Solids content is the alkali soluble resin of 20-40% | 0-5％ |
| C | Plasticising and film coalescence aid | 2-12％ |
| D | Defoamer | 0.01-2％ |
| E | Water-based wax emulsion | 1-10％ |
| F | Moistening flatting agent | 0-1％ |
| G | Antiseptic-germicide | 0.01-5％ |
| H | Deionized water | 0-50％ |
The total amount of above-mentioned A, B, C, D, E, F, G, H should be 100.
In the said components, described waterborne polymeric is water-based pure acrylic acid ester emulsion, cinnamic acrylic ester emulsion, fluorine-silicon modified acrylic ester emulsion or their mixture of metal corsslinking; Described alkali soluble resin is vinylformic acid alkali soluble resin, Abietyl modified vinylformic acid alkali soluble resin or their mixture; Described plasticising and film coalescence aid are 2,2,4-trimethylammonium-1, two fat or the aromatic ester or their mixture of 3-pentanediol-mono isobutyrate (TEXANOL), dipropylene glycol methyl ether (DPM), dipropylene glycol butyl ether (DPnB), propylene glycol butyl ether (PnB), diethylene glycol ether (DEE), Diethylene Glycol butyl ether (DB), butyl glycol ether (EB), ethylene glycol, propylene glycol, dibutyl phthalate (D.B.P), dibutyl phthalate (D.O.P), three butoxyethyl group phosphoric acid ester (KP-140), different ethohexadiol; Described defoamer is polysiloxane-polyether copolymer emulsion, polypropylene glycols, polyoxyethylene glycol-hydrophobic solid-polysiloxane mixture class, mineral oils or their mixture; Described water-based wax emulsion is aqueous polyethylene wax emulsion, aqueous polyacrylamide wax emulsion, water-based paraffin wax emulsions, water-based palm wax emulsion, water-based beeswax emulsion or their mixture; Described moistening flatting agent is wetting levelling product of alkylphenol polyoxyethylene, polysiloxane emulsion, silicone or fluorine carbon or their mixture; Described antiseptic-germicide is isothiazolinone antiseptic-germicide, nano-inorganic substance antiseptic-germicide, silver ions class antiseptic-germicide or their mixture.Described isothiazolinone antiseptic-germicide is octyl group-isothiazolinone, two chloro-n-octyl groups-4-isothiazoline-3-ketone, the mixture of n-octyl isothiazolinone and imdazole derivatives, nitrogen-2-methyl-4-isothiazoline-3-ketone, 2-methyl-4-isothiazoline-3-ketone or isothiazolinone and aryl urine derivative, thiram and diformazan ammonia zinc sulfate mixture etc., be preferably two chloro-n-octyl groups-4-isothiazoline-3-ketone and isothiazolinone and aryl urine derivative, thiram and diformazan ammonia zinc sulfate mixture, more preferably two chloro-n-octyl groups-4-isothiazoline-3-ketone; Described nano-inorganic substance antiseptic-germicide can be titanium dioxide quasi-metal oxides nanoparticle, the inorganics that contains the germ resistance heavy metal ion, nano silicon-based oxide antiseptic-germicide etc. and composition thereof, be preferably nano-titania particle, nano silicon-based oxide antiseptic-germicide, more preferably the nano silicon-based oxide antiseptic-germicide; Described silver ions class antiseptic-germicide can be zeolites antiseptic-germicide, phosphate-based antiseptic-germicide, solvability glass series antibacterial agent, montmorillonite germicide, silver-activated carbon fiber type antiseptic-germicide etc., be preferably zeolites antiseptic-germicide, montmorillonite germicide, more preferably the zeolites antiseptic-germicide.
After preferred, the component that the invention of this floor wax is adopted is as follows: described waterborne polymeric is the water-based cinnamic acrylic ester emulsion of metal corsslinking; Described alkali soluble resin is the vinylformic acid alkali soluble resin; Described plasticising and film coalescence aid are 2,2,4-trimethylammonium-1, the mixture of 3-pentanediol-mono isobutyrate, dipropylene glycol methyl ether, three butoxyethyl group phosphoric acid ester, dibutyl phthalate, diethylene glycol ether; Described defoamer is the polysiloxane-polyether copolymer emulsion; Described water-based wax emulsion is an aqueous polyethylene wax emulsion; Described moistening flatting agent is the wetting levelling product of fluorine carbon; Described antiseptic-germicide is the isothiazolinone antiseptic-germicide.
Compare with prior art, with aqueous antibiotic floor wax of the present invention is to add special antiseptic-germicide mixture in common watersoluble floor polish, can make floor wax form antibiotic layer at article surface, thereby to multiple common bacterium such as streptococcus aureus, intestinal bacteria, the Candida albicans bacterium, the rye mould, other fungi such as S. cervisiae, mould, yeast, phycomycete and virus etc. have inhibitory or killing effect, because being aggregated the sealing of thing film, antiseptic-germicide is difficult for running off, thereby have efficient, persistent antibacterial ability, and by selecting to reach the antiseptic-germicide product of food grade, thereby the effect that possesses safety and environmental protection simultaneously, detect through Chinese Center for Disease Control, its antimicrobial efficiency reaches 99.99%, and antibiotic persistence is greater than 98%.
Embodiment
The present invention is further illustrated below in conjunction with embodiment.These embodiment only are used to illustrate the present invention, and do not mean that and limit the invention in a certain scope.Aqueous antibiotic floor wax main ingredient of the present invention and weight proportion thereof are:
| A | Solids content is the waterborne polymeric of 30-50% | 10-70％ |
| B | Solids content is the alkali soluble resin of 20-40% | 0-5％ |
| C | Plasticising and film coalescence aid | 2-12％ |
| D | Defoamer | 0.01-2％ |
| E | Water-based wax emulsion | 1-10％ |
| F | Moistening flatting agent | 0-1％ |
| G | Antiseptic-germicide | 0.01-5％ |
| H | Deionized water | 0-50％ |
In the said components:
The water-based cinnamic acrylic ester polymkeric substance of described metal corsslinking can self-producedly also can be selected U.S.'s ROHM AND HAAS or Beijing east connection chemical plant or other manufacturer or their mixture for use, as U.S. ROHM AND HAAS polymer P RIMAL 3939 etc.
Described vinylformic acid alkali soluble resin can self-producedly also can be selected connection chemical plant, U.S.'s ROHM AND HAAS or Beijing east or other manufacturer or their mixture for use, as U.S. ROHM AND HAAS polymer A SR PLUS S 25, Guangzhou Zhong Shan Yi Shiman alkali soluble resin etc.
Described plasticising and film coalescence aid 2,2,4-trimethylammonium-1, the mixture of 3-pentanediol-mono isobutyrate, dipropylene glycol methyl ether, three butoxyethyl group phosphoric acid ester, dibutyl phthalate, diethylene glycol ether can select for use the related products of U.S. Eastman Chemical Co., Ltd. or Shandong Eastman Chemical and Dow Chemical Pacific Ocean company limited or German BASF or the production of Yangzhou China human relations chemical industry company limited to mix.
Described defoamer can be selected the froth breaking product of German BYK company or Germany public affairs credit chemical company or German TEGO company or the production of U.S. aerochemistry company for use for the polysiloxane-polyether copolymer emulsion, as TEGO 902W, the public PI 35 that shines of Germany etc.
The related products that described aqueous polyethylene wax emulsion can select for use U.S. MICHELLMAN company or German BYK company or German BASF or Longkou Hua Rui company to produce is as WP-1, the AF-1 of Longkou Hua Rui company etc. of ME 39235, the German BASF of U.S. MICHELLMAN company.
The wetting levelling product of described fluorine carbon can be selected the related products of du pont company or the U.S. three leaf companies for use, as FSJ of du pont company etc.
The related products that described isothiazolinone antiseptic-germicide can select for use U.S.'s ROHM AND HAAS or Britain's Sol or German Shu Mei or Hebei sunlight or sky, Beijing company such as hold up to produce is as the KATHON LXE of U.S. Rhom and Hass, ROZONE 2000, ROCIMA303, SKANE M-8 etc.
Embodiment 1
Select the Formulation Example of the single isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.05 | Antiseptic-germicide |
| 12 | Deionized water | 45.92 | Thinner |
| Add up to | 100.00 |
Embodiment 2
Select the Formulation Example of the single isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 5 | Antiseptic-germicide |
| 12 | Deionized water | 40.97 | Thinner |
| Add up to | 100.00 |
Embodiment 3
Select the isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass and the Formulation Example of SKANE M-8 for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.1 | Antiseptic-germicide |
| 12 | SKANE M-8 | 1.0 | Antibacterial mildew inhibitor |
| 13 | Deionized water | 44.87 | Thinner |
| Add up to | 100.00 |
Embodiment 4
Select the isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass and the Formulation Example of ROZONE 2000 for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.1 | Antiseptic-germicide |
| 12 | ROZONE 2000 | 1.0 | Antibacterial mildew inhibitor |
| 13 | Deionized water | 44.87 | Thinner |
| Add up to | 100.00 |
Embodiment 5
Select the isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass and the Formulation Example of ROCIMA 303 for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.1 | Antiseptic-germicide |
| 12 | ROCIMA 303 | 2.0 | Antibacterial mildew inhibitor |
| 13 | Deionized water | 43.87 | Thinner |
| Add up to | 100.00 |
Embodiment 6
Select the Formulation Example of the isothiazolinone antiseptic-germicide KATHON LXE and the Britain Sol EPW of U.S. Rhom and Hass for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.1 | Antiseptic-germicide |
| 12 | EPW | 5.0 | Antibacterial mildew inhibitor |
| 13 | Deionized water | 40.87 | Thinner |
| Add up to | 100.00 |
Embodiment 7
Select the isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass and the Formulation Example of nano silicon-based oxide antiseptic-germicide for use based on the water-based cinnamic acrylic ester polymer P RIMAL 3939 of the metal corsslinking of U.S. Rhom and Hass, the watersoluble floor polish of U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.1 | Antiseptic-germicide |
| 12 | The nano silicon-based oxide antiseptic-germicide | 1.0 | Antibacterial mildew inhibitor |
| 13 | Deionized water | 44.87 | Thinner |
| Add up to | 100.00 |
Embodiment 8
Selecting the isothiazolinone antiseptic-germicide KATHON LXE of U.S. Rhom and Hass and silver ions for use based on the watersoluble floor polish of water-based cinnamic acrylic ester polymer P RIMAL 3939, the U.S. ROHM AND HAAS alkali soluble resin ASR PLUS S 25 of the metal corsslinking of U.S. Rhom and Hass is the Formulation Example of zeolites antiseptic-germicide.
| Starting material | Addition | Function | |
| 1 | PRIMAL 3939(38％) | 36 | Film forming matter |
| 2 | ASR PLUS S 25 | 4 | Alkali soluble resin |
| 3 | AF-1 | 5 | Water-based wax emulsion |
| 4 | PI-35 | 0.03 | Defoamer |
| 5 | TEXANOL | 1.2 | Film coalescence aid |
| 6 | DPM | 2.9 | Film coalescence aid |
| 7 | DEE | 1.8 | Film coalescence aid |
| 8 | D.B.P | 0.5 | Softening agent |
| 9 | KP-140 | 1.6 | Softening agent |
| 10 | The aqueous solution of FSJ1% | 1.0 | Moistening flatting agent |
| 11 | KATHON LXE | 0.1 | Antiseptic-germicide |
| 12 | Silver ions is the zeolites antiseptic-germicide | 1.0 | Antibacterial mildew inhibitor |
| 13 | Deionized water | 44.87 | Thinner |
| Add up to | 100.00 |
The contrast of embodiment antibacterial test
Above embodiment is detected by Chinese Center for Disease Control, and the contrast test result is as follows:
Contrast test result, analysis isothiazolinone antiseptic-germicide and other antimicrobial product constituent and characteristic, embodiment 3 influences persistence because of water-soluble the pretending to component in the floor wax runs off easily relatively soon of SKANE M-8; Embodiment 6 is because of containing the component influence property Safety and Environmental Protection that is similar to agricultural chemicals among the EPW; Embodiment 1,2, and 7,8 because of only working and long-lasting can not the assurance to the part bacterial classification; Embodiment 5 is more satisfactory because of ROCIMA 303 effects, but owing to contain aryl derivatives etc., and not recommendedly directly contact with human body and do not confirmed as optimal selection by the inventor, silver ions has human body and certain is not badly also confirmed as optimal selection by the inventor among the embodiment 8 simultaneously; The inventor thinks antibacterial effect, persistence and safety and environmental protection performance the best of using isothiazolinone antiseptic-germicide LXE and compound ROZONE 2000 among the embodiment 4.
For convenience of description, the said sterilization of the present invention, antibiotic, antibacterial be synonym.
Claims (9)
1. aqueous antibiotic floor wax, it is characterized in that: this floor wax contains: waterborne polymeric and antiseptic-germicide.
2. aqueous antibiotic floor wax as claimed in claim 1 is characterized in that: described waterborne polymeric is water-based pure acrylic acid ester emulsion, cinnamic acrylic ester emulsion, fluorine-silicon modified acrylic ester emulsion or their mixture etc. of metal corsslinking.
3. as each described aqueous antibiotic floor wax among the claim 1-2, it is characterized in that: described antiseptic-germicide is isothiazolinone antiseptic-germicide, nano-inorganic substance antiseptic-germicide, silver ions class antiseptic-germicide or their mixture etc.
4. as each described aqueous antibiotic floor wax among the claim 1-3, it is characterized in that: described antiseptic-germicide is the isothiazolinone antiseptic-germicide.
5. as each described aqueous antibiotic floor wax among the claim 1-4, it is characterized in that: also contain alkali soluble resin, plasticising and film coalescence aid, defoamer, water-based wax emulsion, moistening flatting agent, deionized water etc. in the described floor wax.
6. aqueous antibiotic floor wax as claimed in claim 5 is characterized in that: described alkali soluble resin can be vinylformic acid alkali soluble resin, Abietyl modified vinylformic acid alkali soluble resin or their mixture.
7. aqueous antibiotic floor wax as claimed in claim 5 is characterized in that: described water-based wax emulsion is aqueous polyethylene wax emulsion, aqueous polyacrylamide wax emulsion, water-based paraffin wax emulsions, water-based palm wax emulsion, water-based beeswax emulsion or their mixture.
8. as each described aqueous antibiotic floor wax among the claim 1-7, it is characterized in that: described waterborne polymeric is that solids content is the waterborne polymeric of 30-50%, and its content is 10-70wt%.
9. as each described aqueous antibiotic floor wax among the claim 1-8, it is characterized in that: the content of described antiseptic-germicide is 0.01-5wt%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101384038A CN101182402A (en) | 2006-11-13 | 2006-11-13 | Aqueous antibiotic floor wax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2006101384038A CN101182402A (en) | 2006-11-13 | 2006-11-13 | Aqueous antibiotic floor wax |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101182402A true CN101182402A (en) | 2008-05-21 |
Family
ID=39447831
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA2006101384038A Pending CN101182402A (en) | 2006-11-13 | 2006-11-13 | Aqueous antibiotic floor wax |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101182402A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948662A (en) * | 2010-08-24 | 2011-01-19 | 王鹏 | Floor wax suitable for wooden floors and wooden furniture |
| CN102248564A (en) * | 2011-05-17 | 2011-11-23 | 南京林业大学 | Method for enhancing surface antibacterial and wear-resisting property of Chinese fir by using wood micron/nano fibril |
| CN102433074A (en) * | 2010-09-29 | 2012-05-02 | 周玥熠 | Floor wax |
| CN102634280A (en) * | 2012-04-23 | 2012-08-15 | 苏州晶瑞化学有限公司 | Solid hot-melting strong acid-resistant spray wax and preparation method thereof |
| CN102731947A (en) * | 2012-06-18 | 2012-10-17 | 深圳新宙邦科技股份有限公司 | Antistatic floor wax composition |
| CN102993803A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified water-soluble nanoscale silica sol-containing metal rust-proof wax and preparation method thereof |
| CN102993802A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified nanoscale titanium dioxide-containing metal rust prevention wax and preparation method thereof |
| CN103254797A (en) * | 2013-04-18 | 2013-08-21 | 东莞大宝化工制品有限公司 | Photocatalyst water wax and preparation method thereof |
| CN103992884A (en) * | 2014-05-11 | 2014-08-20 | 青岛兰兰生物科技有限公司 | Scented candle for purifying air and preparation method thereof |
| CN107286826A (en) * | 2017-05-11 | 2017-10-24 | 3M创新有限公司 | Antistatic floor wax and preparation method thereof, conductive flooring coating |
| CN107573856A (en) * | 2017-08-30 | 2018-01-12 | 合众（佛山）化工有限公司 | A kind of anti-skidding Wax composition of water-based ceramic tile |
| IT201600082632A1 (en) * | 2016-08-04 | 2018-02-04 | 4Hygiene S R L | PROTECTIVE EMULSION FOR SURFACES |
| CN110229616A (en) * | 2019-07-22 | 2019-09-13 | 刘忠 | A kind of nanometer of high brightness coating |
| CN115418171A (en) * | 2022-09-02 | 2022-12-02 | 湖北天喜达生物科技有限公司 | Water-soluble wood floor wax |
-
2006
- 2006-11-13 CN CNA2006101384038A patent/CN101182402A/en active Pending
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101948662B (en) * | 2010-08-24 | 2013-03-20 | 王鹏 | Floor wax suitable for wooden floors and wooden furniture |
| CN101948662A (en) * | 2010-08-24 | 2011-01-19 | 王鹏 | Floor wax suitable for wooden floors and wooden furniture |
| CN102433074A (en) * | 2010-09-29 | 2012-05-02 | 周玥熠 | Floor wax |
| CN102433074B (en) * | 2010-09-29 | 2013-07-10 | 王润佳 | Floor wax |
| CN102248564A (en) * | 2011-05-17 | 2011-11-23 | 南京林业大学 | Method for enhancing surface antibacterial and wear-resisting property of Chinese fir by using wood micron/nano fibril |
| CN102634280A (en) * | 2012-04-23 | 2012-08-15 | 苏州晶瑞化学有限公司 | Solid hot-melting strong acid-resistant spray wax and preparation method thereof |
| CN102731947A (en) * | 2012-06-18 | 2012-10-17 | 深圳新宙邦科技股份有限公司 | Antistatic floor wax composition |
| CN102993803B (en) * | 2012-11-13 | 2016-04-20 | 合肥市田源精铸有限公司 | A kind of metal rust-proofing wax containing modified soluble nano silicone colloidal sol and preparation method thereof |
| CN102993803A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified water-soluble nanoscale silica sol-containing metal rust-proof wax and preparation method thereof |
| CN102993802A (en) * | 2012-11-13 | 2013-03-27 | 合肥市田源精铸有限公司 | Modified nanoscale titanium dioxide-containing metal rust prevention wax and preparation method thereof |
| CN103254797A (en) * | 2013-04-18 | 2013-08-21 | 东莞大宝化工制品有限公司 | Photocatalyst water wax and preparation method thereof |
| CN103254797B (en) * | 2013-04-18 | 2015-10-28 | 东莞大宝化工制品有限公司 | A kind of Photocatalyst water wax and preparation method thereof |
| CN103992884A (en) * | 2014-05-11 | 2014-08-20 | 青岛兰兰生物科技有限公司 | Scented candle for purifying air and preparation method thereof |
| IT201600082632A1 (en) * | 2016-08-04 | 2018-02-04 | 4Hygiene S R L | PROTECTIVE EMULSION FOR SURFACES |
| CN107286826A (en) * | 2017-05-11 | 2017-10-24 | 3M创新有限公司 | Antistatic floor wax and preparation method thereof, conductive flooring coating |
| CN107286826B (en) * | 2017-05-11 | 2020-04-14 | 3M中国有限公司 | Anti-static floor wax, preparation method thereof and anti-static floor coating |
| CN107573856A (en) * | 2017-08-30 | 2018-01-12 | 合众（佛山）化工有限公司 | A kind of anti-skidding Wax composition of water-based ceramic tile |
| CN110229616A (en) * | 2019-07-22 | 2019-09-13 | 刘忠 | A kind of nanometer of high brightness coating |
| CN115418171A (en) * | 2022-09-02 | 2022-12-02 | 湖北天喜达生物科技有限公司 | Water-soluble wood floor wax |
| CN115418171B (en) * | 2022-09-02 | 2023-11-07 | 湖北天喜达生物科技有限公司 | Water-soluble wood floor wax |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101182402A (en) | Aqueous antibiotic floor wax | |
| US8858926B2 (en) | Antibacterial polymer emulsion and coating composition | |
| CN107936660A (en) | A kind of environmental friendly, anti-corrosive antibacterial interior wall negative ion paint | |
| US11976207B2 (en) | Water-based compositions that resist dirt pick-up | |
| US20130274395A1 (en) | Dibenzoate plasticizers/coalescent blends for low voc coatings | |
| CN104592841A (en) | Inorganic antibacterial formaldehyde-removing paint and preparation method thereof | |
| CN102329539A (en) | Interior wall coating and preparation method thereof | |
| AU2015232461B2 (en) | Allergen-reducing composition, spray agent and surface treating agent containing said composition, allergen-reducing method, and fiber structure and building core material from which allergens are reduced | |
| CN101671509A (en) | Emulsion paint for preventing mosquitoes and flies and preparation method thereof | |
| CN105112129A (en) | Flame-retardant, acid-proof, alkali-proof and anti-bacterial lubricating oil for mechanical bearing | |
| CN107903773A (en) | A kind of water-fast, antibacterial, automatically cleaning sealing wax and preparation method thereof | |
| CN104356792A (en) | Water-based stone nano-protector and preparation method thereof | |
| CN105255341A (en) | Negative-ion coating and preparation method thereof | |
| CN104629566A (en) | Antibacterial anion paint | |
| CN105567030A (en) | Waterborne carpentry paint | |
| WO2007079529A1 (en) | Antimicrobial paint | |
| CN103980770A (en) | Coating and preparation method thereof | |
| CN105017889A (en) | Conductive self-cleaning hydrophilic coating | |
| JPH10251565A (en) | Water-based polish for countermeasure against indoor pollution, water-based clear coating material and reduction in indoor pollution using the same | |
| CN108300414A (en) | A kind of anti-skidding nano material and preparation method thereof | |
| DE102020116036B4 (en) | Coating composition and use of the same | |
| CN103254797A (en) | Photocatalyst water wax and preparation method thereof | |
| CN112739212A (en) | Antimicrobial compositions containing wollastonite | |
| CN114364757B (en) | Non-overlapping water-based wood stain | |
| CN110724453A (en) | Water-based plant-based wood maintenance agent |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20080521 |