CN106677482A - Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof - Google Patents
Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof Download PDFInfo
- Publication number
- CN106677482A CN106677482A CN201611227023.1A CN201611227023A CN106677482A CN 106677482 A CN106677482 A CN 106677482A CN 201611227023 A CN201611227023 A CN 201611227023A CN 106677482 A CN106677482 A CN 106677482A
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- Prior art keywords
- anion
- formaldehyde
- methanol
- layer
- catching agent
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Classifications
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- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F15/00—Flooring
- E04F15/02—Flooring or floor layers composed of a number of similar elements
Landscapes
- Engineering & Computer Science (AREA)
- Architecture (AREA)
- Civil Engineering (AREA)
- Structural Engineering (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a laminate flooring capable of removing methanol through negative ions. The laminate flooring is sequentially composed of a balance layer, a base material layer, a functional coating layer, a decorating layer and an abrasion resistance layer from bottom to top, wherein the functional coating layer, the decorating layer and the abrasion resistance layer are composited on the surface of the base material layer. The functional coating layer composited on the surface of the base material layer is composed of water based coating, negative ion powder and methanol capture agents. The invention further discloses a manufacturing method of the laminate flooring capable of removing the methanol through the negative ions. According to the laminate flooring capable of removing the methanol through the negative ions, the methanol capture agents have the effects of methanol adsorbing, fixing and degrading, and have a good removing effect on the methanol in surrounding materials. The negative ion powder has the functions of generating the negative ions constantly, releasing far infrared rays, sterilizing and inhibiting bacteria, and the negative ions released by the negative ion powder can conduct oxidative decomposition on the abnormal smell of the organic gas of the methanol and the like in the environment, so that the capacity of constant and permanent methanol removing of the methanol capture agents is improved.
Description
Technical field
The present invention relates to a kind of building material technical field, more particularly to a kind of anion is except formaldehyde consolidated floor and its system
Make method.
Background technology
Consolidated floor belongs to floor decorative material, typically constitutes i.e. balance layer (basal layer), substrate layer (core by four layer materials
Layer), the wearing layer on decorative layer and surface.Under normal circumstances, because its substrate layer is typically chosen Midst density or high-density plate, and put down
Weighing apparatus layer and the equal impregnated melamine resin of decorative layer, wearing layer mix the melmac of Lauxite, therefore can not keep away
The pollution problem of the presence formaldehyde exempted from.The Form aldehyde release figureofmerit E1 levels≤1.5mg/l of national Specification consolidated floor, E0 levels
≤0.5mg/l.During the use of mating formation of consolidated floor, the free formaldehyde of remaining can gradually be discharged into room ring in floor
In border, the health of habitant is caused damage.
Healthy, long-lived and ecological significant impact of the anion to people is domestic and international medical circle expert by clinical real
Trample and verified.Contemporary science has opened bioelectric secret, and each cell of organism is exactly a micro cell, in cell membrane
There is the potential difference of 50-90mv outward, if " cell battery " cannot get sufficient electric charge supplemented, the electric process of body is difficult to continue
Maintain, thus have influence on the normal activity of body, produce aging and senilism.Anion can not only facilitate human body to synthesize and store dimension
Raw element, strengthens the physiological activity with human activin, therefore it is otherwise known as " air vitamin ".
In air conditioner surroundings, because anion is almost complete after a series of process of air conditioning purges and very long ventilation shaft in air
Portion disappears, and wherein extended stationary periods can feel that uncomfortable in chest, dizzy, weak, work efficiency and health status decline to people, be referred to as
" air conditioner comprehensive disease ".In medical circle, it is have the effective means for killing pathogenic bacteria and purify air that anion is identified.Medical research
Show, electronegative microgranule increases oxygen content in blood in air, be conducive to blood oxygen conveying, absorb and utilize, with promotion people
Body metabolism, improves human body immunity, strengthens human body flesh energy, adjusts the effect of body function balance.
Chinese patent, the applying date is 2015.1.15 days, and Application No. 201510019200.6 is entitled《Anion ground
Plate》, its disclosed anion floor, the weight portion of its constitutive material is：100 parts of Corvic, chlorinated polyethylene 20-30
Part, tribasic lead sulfate 4-6 parts, barium stearate 1-3 parts, stearic acid 2-4 parts, anionic additive 20-40 parts, 3- aminopropyls
Trimethoxy silane 1-2 parts.The anion floor of the invention belongs to plastic floor, can permanent anion releasing, and release bear from
Quantum count is higher, is conducive to purifying the air of a room for a long time.
Chinese patent, the applying date is 2014.7.3, and Application No. 201410315549.X is entitled《Anion releasing
Plastic bottom board and manufacture method》Propose a kind of plastic floor and its production method for releasing from anion, the plastic floor by plastics,
Anion powder and plasticizer are constituted.Chinese patent, the applying date is 2016.1.11, and the applying date is 201610014223.2, entitled
《A kind of ecological anion floor and preparation method thereof》In, ecological anion floor includes log base plate, is attached to log base plate
On prime coat, be attached to prime coat Shang Hou roads enamelled coating, the putty enamelled coating being attached on rear road enamelled coating, be attached to putty enamelled coating
On wear-resisting enamelled coating, the elastic enamelled coating being attached on wear-resisting enamelled coating, the crystal enamelled coating being attached on elastic enamelled coating and be attached to
Top coat layer on crystal enamelled coating.Its preparation technology is to the addition of anion powder in each layer coating adhered to thereon, the bottom of by
The anion contained in paint is so that then anion permeable contains the covering of the coating of anion into log base plate by multilamellar
Anion is locked in the ecological anion floor so that the ecological anion floor of invention can continue anion.
Chinese patent, the applying date is 2016.1.15, and Application No. 201620037570.2 is entitled《A kind of anion is answered
Close floor》, it is that sandwich layer upper surface is provided with several grooves in genesis analysis, the inside grooves are filled with tourmaline
Powder, so as to realize the purpose of finished product floor anion releasing.
In above-mentioned prior art, and a kind of consolidated floor is found no, can effectively reduce the free formaldehyde on finished product floor,
Effective anion releasing, and with the function of removing environment harmful formaldehyde.
The content of the invention
Goal of the invention：It is an object of the invention to provide one kind can effective anion releasing, and can effectively remove harmful first
The anion of aldehyde removes formaldehyde consolidated floor.
Technical scheme：The present invention is realized using following technological means：A kind of anion removes formaldehyde consolidated floor, under
By balance layer, substrate layer and it is compound in function coatings, decorative layer and the wearing layer of base material layer surface and constitutes successively to upper, it is described
The function coatings for being compound in base material layer surface are made up of water paint, anion powder and formaldehyde catching agent.
Preferably, described function coatings are made up of each component of following parts by weight：Anion powder 0.5-15 parts,
Formaldehyde catching agent 0.5-15 parts, surplus adds water paint to 100 parts.
It is highly preferred that anion powder parts by weight are 1-10 parts, most preferably 3-5 parts；Formaldehyde catching agent parts by weight are more
Preferably 1-10 parts, most preferably 3-8 parts.
Preferably, the Particle size requirements of the anion powder are less than 15 μm, preferred particle diameter is 0.05-5 μm.
Preferably, the formaldehyde catching agent is the silica gel with physical absorption performance, zeolite molecular sieve or activated carbon, sea
The porous class material of the bigger serfaces such as afrodite, macroporous resin.
Preferably, described formaldehyde catching agent is chemical reaction type formaldehyde catching agent：For inorganic ammonium salt or sulphite,
Nitrogen-containing organic compound or polymer containing active amino or imino group.
Preferably, described formaldehyde catching agent be after chemical reaction type formaldehyde catching agent it is modified with physical absorption
The porous class material of performance.
Preferably, the Particle size requirements of the formaldehyde catching agent are less than 15 μm, it is highly preferred that Particle size requirements are less than 10 μm.
Preferably, described water paint includes film forming matter, auxiliary agent, effect is by anion powder and formaldehyde catching
Agent is dispersed to be dissolved into wherein, and forms film in base material layer surface.Its consumption can need to be adjusted according to substrate moisture rate etc.
It is whole.The present invention does not have any restriction to the water paint, be able to can use in the coating of substrate layer surface filming, this area
Technical staff can independently be selected according to the water content requirement of substrate layer.
The invention also discloses manufacture method of the above-mentioned anion except formaldehyde consolidated floor：
(1) anion powder needed for feature coatings, formaldehyde catching agent are added in water paint, dispersed with stirring is equal
It is even, obtain feature coatings mixture；
(2) technique applied using spraying, dip-coating or rod, by feature coatings mixture by every square metre 30-100 gram/
m2Consumption be applied to the surface of substrate layer；
(3) select as needed to carry out substrate layer single spreading or double spread feature coatings, by strong after coating
Change the normal production technology in floor overlayed, health preserving, fluting, edge sealing, packaging, obtain final product.
The anion that the present invention is provided is except in formaldehyde consolidated floor, formaldehyde catching agent has absorption, fixed and degradation of formaldehyde
Effect, there is good removal effect to the formaldehyde in periphery material；And anion powder not only have lasting generation bear from
Sub, releasing far infrared, good bactericidal function, and the anion of its release can be organic by the formaldehyde in environment etc.
The oxidation Decomposition such as gas abnormal flavour, continue, remove for a long time the ability of formaldehyde so as to improve formaldehyde catching agent.Experiment shows, of the invention
The anion of offer is capable of the formaldehyde removed in environment of continuous and effective except formaldehyde consolidated floor, purifies the air of a room, and keeps people
Body health.
Specific embodiment
In the present invention, anion powder is purchased from Nanjing Du Xiu developments in science and technology company limited, and model DX01-15, anion is released
It is high-volume 80,000/cm3；Anion test instrument be purchased from Guangzhou Yi Hong Electronics Co., Ltd.s, model IT-10 anionic textiles instrument,
It is mainly used in the detection of types of functionality anion material；Formaldehyde catching agent is purchased from Nanjing Lv Dun Environmental Protection Technology Co., Ltd, type
Number be LDHB01-16；Water paint is purchased from Hefei Ke Tian water paints company limited.
Embodiment 1
In embodiment 1-4, water paint is made up of each component of following parts by weight：0.8 part of isocyanates, 2 parts of polyester
Dihydroxylic alcohols, 0.5 part of dihydromethyl propionic acid, 0.2 part of ethylenediamine and 6.5 parts of water.
In the present embodiment, function coatings are made up of each component of following parts by weight：0.5 part of anion powder, 0.5 part of first
Aldehyde agent for capturing, 99 parts of water paints.
Manufacturing process：
The anion powder and formaldehyde catching agent of aforementioned proportion are added in hydrotropism's coating, mixture is obtained after stirring；
Dispersed with stirring is uniform, by 50 grams/m2Consumption spray be applied to the positive and negative of substrate layer, carry out double spread；
Overlayed by the normal production technology of consolidated floor, health preserving, fluting, edge sealing, packaging, obtain final product anion of the present invention and remove
Formaldehyde consolidated floor.
Embodiment 2
In the present embodiment, function coatings are made up of each component of following parts by weight：15 parts of anion powder, 15 parts of formaldehyde
Agent for capturing, 70 parts of water paints.
Manufacturing process：
The anion powder and formaldehyde catching agent of aforementioned proportion are added in hydrotropism's coating, mixture is obtained after stirring；
Dispersed with stirring is uniform, by 50 grams/m2Consumption spray be applied to the positive and negative of substrate layer, carry out double spread；
Overlayed by the normal production technology of consolidated floor, health preserving, fluting, edge sealing, packaging, obtain final product anion of the present invention and remove
Formaldehyde consolidated floor.
Embodiment 3
In the present embodiment, function coatings are made up of each component of following parts by weight：10 parts of anion powder, 10 parts of formaldehyde
Agent for capturing, 80 parts of water paints.
Manufacturing process：
The anion powder and formaldehyde catching agent of aforementioned proportion are added in hydrotropism's coating, mixture is obtained after stirring；
Dispersed with stirring is uniform, by 50 grams/m2Consumption spray be applied to the positive and negative of substrate layer, carry out double spread；
Overlayed by the normal production technology of consolidated floor, health preserving, fluting, edge sealing, packaging, obtain final product anion of the present invention and remove
Formaldehyde consolidated floor.
Embodiment 4
In the present embodiment, function coatings are made up of each component of following parts by weight：0.5 part of anion powder, 0.5 part of first
Aldehyde agent for capturing, 99 parts of water paints.
Manufacturing process：
The anion powder and formaldehyde catching agent of aforementioned proportion are added in hydrotropism's coating, mixture is obtained after stirring；
Dispersed with stirring is uniform, by 50 grams/m2Consumption spray be applied to the positive and negative of substrate layer, carry out double spread；
Overlayed by the normal production technology of consolidated floor, health preserving, fluting, edge sealing, packaging, obtain final product anion of the present invention and remove
Formaldehyde consolidated floor.
In order to further embody the beneficial effect of the application, following test example is now enumerated：
Comparative example 1
Take 10kg water paints, including following composition：0.8kg isocyanates, 2kg polyester diol, 0.5kg dihydroxymethyls
Propanoic acid, 0.2kg ethylenediamines and 6.5kg water, without anion powder and formaldehyde catching agent；
Dispersed with stirring is uniform, by 50 grams/m2Consumption spray be applied to the positive and negative of substrate layer, carry out double spread；
Overlayed by the normal production technology of consolidated floor, health preserving, fluting, edge sealing, packaging, obtain final product comparative example 1 production
Consolidated floor.
10kg is respectively taken from embodiments of the invention 1-4 again according to the function coatings made by manufacture method of the invention
Mixture, by 50 grams/m2Consumption spray be applied to the positive and negative of substrate layer, carry out double spread；
Overlayed by the normal production technology of consolidated floor, health preserving, fluting, edge sealing, packaging, obtain final product anion of the present invention and remove
Formaldehyde consolidated floor.
Formaldehyde consolidated floor embodiment and comparative example surface are directly removed to the anion of the present invention using anionic textiles instrument
The detection of negative ion concentration is carried out, 1 is the results are shown in Table.
Table 1：Anion release concentration test result
| Group | Anion release concentration (individual/cm3) |
| Embodiment 1 | 1024 |
| Embodiment 2 | 1225 |
| Embodiment 3 | 850 |
| Embodiment 4 | 1086 |
| Comparative example 1 | 25 |
According to standard GB/T 18580-2001《Indoor decorating and refurnishing materials wood-based plate and its product Form aldehyde release are limited the quantity》
Formaldehyde consolidated floor embodiment is removed to the anion of the present invention using 40L condensed steam waters and comparative example burst size of methanal is examined
Survey, the results are shown in Table 2.
Table 2：The burst size of methanal testing result of consolidated floor
From table 2 it can be seen that the obvious reduction compared with comparative example of the burst size of methanal of embodiment.
Above-mentioned test example result shows：Anion is obtained except formaldehyde consolidated floor by the manufacture method of the present invention, to institute
State anion consolidated floor carry out anion burst size and remove formaldehyde ability tested, as a result show, the present invention provide
Anion can not only effectively discharge a certain amount of anion beneficial to health except formaldehyde consolidated floor, and can grow
Phase, persistently remove formaldehyde.
Claims (9)
1. a kind of anion removes formaldehyde consolidated floor, it is characterised in that：By balance layer, substrate layer and it is compound in successively from top to bottom
The function coatings of base material layer surface, decorative layer and wearing layer composition, the function coatings for being compound in base material layer surface by
Water paint, anion powder and formaldehyde catching agent composition.
2. anion as claimed in claim 1 removes formaldehyde consolidated floor, it is characterised in that：Described function coatings are by following
The each component composition of parts by weight：Anion powder 0.5-15 parts, formaldehyde catching agent 0.5-15 parts, surplus adds water paint to 100
Part.
3. anion as claimed in claim 2 removes formaldehyde consolidated floor, it is characterised in that：The Particle size requirements of the anion powder
Less than 15 μm.
4. anion as claimed in claim 2 removes formaldehyde consolidated floor, it is characterised in that：The formaldehyde catching agent is with thing
Manage the porous class material of the bigger serfaces such as silica gel, zeolite molecular sieve or activated carbon, meerschaum, the macroporous resin of absorption property.
5. anion as claimed in claim 2 removes formaldehyde consolidated floor, it is characterised in that：Described formaldehyde catching agent is chemistry
Response type formaldehyde catching agent：For inorganic ammonium salt or sulphite, the nitrogen-containing organic compound containing active amino or imino group or
Polymer.
6. anion as claimed in claim 2 removes formaldehyde consolidated floor, it is characterised in that：Described formaldehyde catching agent be through
The modified porous class material with physical absorption performance of chemical reaction type formaldehyde catching agent.
7. anion as claimed in claim 2 removes formaldehyde consolidated floor, it is characterised in that：The particle diameter of the formaldehyde catching agent will
Ask less than 15 μm.
8. anion as claimed in claim 2 removes formaldehyde consolidated floor, it is characterised in that：Described water paint includes film forming
Material, auxiliary agent, effect is to be dissolved into anion powder and formaldehyde catching agent are dispersed wherein, and is formed in base material layer surface
Film.
9. the anion as any one of claim 1-8 is except the manufacture method of formaldehyde consolidated floor：
(1) anion powder needed for feature coatings, formaldehyde catching agent are added in water paint, dispersed with stirring is uniform,
Obtain feature coatings mixture；
(2) technique applied using spraying, dip-coating or rod, by feature coatings mixture by every square metre 30-100 gram/m2's
Consumption is applied to the surface of substrate layer；
(3) select as needed to carry out substrate layer single spreading or double spread feature coatings, by reinforcing ground after coating
The normal production technology of plate is overlayed, health preserving, fluting, edge sealing, packaging, obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611227023.1A CN106677482A (en) | 2016-12-27 | 2016-12-27 | Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611227023.1A CN106677482A (en) | 2016-12-27 | 2016-12-27 | Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106677482A true CN106677482A (en) | 2017-05-17 |
Family
ID=58872086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611227023.1A Pending CN106677482A (en) | 2016-12-27 | 2016-12-27 | Laminate flooring capable of removing methanol through negative ions and manufacturing method thereof |
Country Status (1)
| Country | Link |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107140292A (en) * | 2017-06-13 | 2017-09-08 | 南京双全科技有限公司 | Anion is except formaldehyde corrugated wrapping case and preparation method thereof |
| CN109113303A (en) * | 2018-08-30 | 2019-01-01 | 安徽扬子地板股份有限公司 | Stone plastic floor and preparation method thereof |
| CN110092982A (en) * | 2019-05-30 | 2019-08-06 | 湖南优尔康悬浮拼装地板有限公司 | A kind of suspension assembled floor-board having adsorption function |
| CN110341284A (en) * | 2019-08-19 | 2019-10-18 | 深圳冠特家居健康系统有限公司 | One kind removing aldehyde plate surface layer structure and its treatment process |
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| JP2000160716A (en) * | 1998-11-26 | 2000-06-13 | Shimizu Corp | Building material |
| CN201116392Y (en) * | 2007-09-29 | 2008-09-17 | 衡阳市湘竹木业有限公司 | Floor with negative ion layer |
| CN201245960Y (en) * | 2008-06-11 | 2009-05-27 | 欧阳林 | Novel composite multifunctional floor ground cushion |
| CN102828447A (en) * | 2011-06-13 | 2012-12-19 | 瑞宝(北京)装饰设计有限公司 | Negative-ion anti-formaldehyde ecological wallpaper |
| CN202689452U (en) * | 2012-06-27 | 2013-01-23 | 哈尔滨中润永翔环保科技有限公司 | Far infrared and negative ion composite floor with enhanced function |
| CN202913615U (en) * | 2012-06-20 | 2013-05-01 | 东莞矽孚复合材料有限公司 | Pasting-free composite floor |
| CN204225420U (en) * | 2014-06-18 | 2015-03-25 | 张磊 | A kind of containing diatomaceous strengthening composite floor |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2000160716A (en) * | 1998-11-26 | 2000-06-13 | Shimizu Corp | Building material |
| CN201116392Y (en) * | 2007-09-29 | 2008-09-17 | 衡阳市湘竹木业有限公司 | Floor with negative ion layer |
| CN201245960Y (en) * | 2008-06-11 | 2009-05-27 | 欧阳林 | Novel composite multifunctional floor ground cushion |
| CN102828447A (en) * | 2011-06-13 | 2012-12-19 | 瑞宝(北京)装饰设计有限公司 | Negative-ion anti-formaldehyde ecological wallpaper |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107140292A (en) * | 2017-06-13 | 2017-09-08 | 南京双全科技有限公司 | Anion is except formaldehyde corrugated wrapping case and preparation method thereof |
| CN109113303A (en) * | 2018-08-30 | 2019-01-01 | 安徽扬子地板股份有限公司 | Stone plastic floor and preparation method thereof |
| CN110092982A (en) * | 2019-05-30 | 2019-08-06 | 湖南优尔康悬浮拼装地板有限公司 | A kind of suspension assembled floor-board having adsorption function |
| CN110341284A (en) * | 2019-08-19 | 2019-10-18 | 深圳冠特家居健康系统有限公司 | One kind removing aldehyde plate surface layer structure and its treatment process |
| CN110341284B (en) * | 2019-08-19 | 2024-04-26 | 深圳冠特家居健康系统有限公司 | Surface layer structure of aldehyde removal plate and treatment process thereof |
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Application publication date: 20170517 |