CN101333788A - Functional wallpaper material capable of purifying air - Google Patents
Functional wallpaper material capable of purifying air Download PDFInfo
- Publication number
- CN101333788A CN101333788A CNA2008100414463A CN200810041446A CN101333788A CN 101333788 A CN101333788 A CN 101333788A CN A2008100414463 A CNA2008100414463 A CN A2008100414463A CN 200810041446 A CN200810041446 A CN 200810041446A CN 101333788 A CN101333788 A CN 101333788A
- Authority
- CN
- China
- Prior art keywords
- percent
- micro mist
- powder
- agent
- purify air
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Paper (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Disclosed is a functional type wallpaper material having the air purification function, belonging to the interior decoration material technique field, and containing the components, in weight percentage: 1.5 percent to 2.5 percent of titanium dioxide nano-sized powder, 1 percent to 2.5 percent of silicon dioxide nano-sized powder, 0.5 percent to 1.5 percent of zinc oxide powder, 2 percent to 3.5 percent of negative ion powder, 0.5 percent to 1.5 percent of inorganic antibacterial powder, 0.5 percent to 1 percent of iron trioxide, 4 percent to 6 percent of conductive powder, 2.5 percent to 5 percent of polyaniline, 25 percent to 31 percent of polyvinyl chloride, 5 percent to 5.5 percent of titanium pigment, 15 percent to 18.5 percent of di-n-octyl phthalate dioctyl phthalate, 12.5 percent to 18 percent of calcium carbonate, and 3 percent to 30 percent of auxiliary agent. The wallpaper prepared by the materials can remove formaldehyde and peculiar smell, and is antibacterial and mildew-proof, and can release negative ions and resist electromagnetic radiation, as well as greatly improving the indoor air quality for people and solving the indoor air pollution.
Description
Technical field
The present invention relates to a kind of wallpaper material of house decorative material technical field, particularly relate to a kind of functional wallpaper material that can purify air.
Background technology
It is the main aspect that causes room air pollution at present that house decorative material and furniture pollute.Paint, wallpaper, glued board, the wood shavings filler, materials such as interior wall coating all contain formaldehyde, benzene, ethanol, harmful substances such as chloroform, above material all has suitable carcinogenic, the caused environmental pollution of interior decoration is more and more serious, the U.S., specialized agency's investigation of Japan is found, many civilian and room air pollution degree commercial building be the 2-5 that pollutes of outdoor air doubly, there is 30% resident to cause " new home syndrome " approximately because of using harmful chemical, in addition, business automation equipment and micro-wave oven, radio, television set, the electromagnetic wave of the various different wave length frequencies that household electric appliance operation such as computer and mobile phone produces, these electromagnetic waves are full of the space, can penetrate the many materials that comprise human body, receive the dosage of radiation that exceeds standard.
Literature search through prior art is found, Chinese patent publication number CN1752342A, and open day is on March 29th, 2006.Denomination of invention is: the wallpaper that is used to reduce syndrome of new house, this patent readme is: a kind of wallpaper that is used to reduce syndrome of new house is provided, owing to make from the harmful volatile organic compounds of indivisible use, the result does not just have the burst size of volatile organic compounds, even perhaps have also seldom, has the effect that reduces syndrome of new house.Its weak point: just when making wallpaper, the indivisible organic compound that adds less, reduce the burst size of organic compound, and can not effectively remove formaldehyde and electromagnetic radiation, indoor air pollution can not be removed again, the effect of antibiotic, mildew-resistant, release anion and anti-electromagnetic-radiation can not be played.And these air pollutions are very harmful to the mankind.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art and defective, a kind of functional wallpaper material that can purify air is provided, wallpaper with this material preparation can remove formaldehyde, eliminate the unusual smell, antibiotic, mildew-resistant, release anion, anti-electromagnetic-radiation, to improve people's IAQ greatly, solve indoor air pollution.
The present invention is achieved through the following technical solutions, functional wallpaper material of the present invention, and component that comprises and weight percentage are:
Nano titania level micro mist 1.5%-2.5%
Silica nanometer level micro mist 1%-2.5%
Zinc oxide ultra_fine powders 0.5%-1.5%
Anion micro mist 2%-3.5%
Inorganic antibacterial powder 0.5%-1.5%
Di-iron trioxide 0.5%-1%
Conducting powder 4%-6%
Polyaniline 2.5%-5%
Polyvinyl chloride 25%-31%
Titanium dioxide 5%-5.5%
O-phthalic ester dioctyl ester 15%-18.5%
Calcium carbonate 12.5%-18%
Auxiliary agent 3%-30%
Described conducting powder is that the doping treatment by the activity processing and the conduction factor makes it form firm conductive layer at surface of base on the nano material basis, thereby makes this material have lasting electric conductivity, directly by commercial acquisition.
Described nano titania level micro mist, silica nanometer level micro mist, zinc oxide ultra_fine powders, anion micro mist, their particle diameter are rice in the 50-500.Described nano titania level micro mist is a kind of catalysis material.
Described anion micro mist is the tourmaline of the silicate of boracic, and containing in its composition is boron, aluminium, silicon, manganese, magnesium, calcium, iron etc.
Described inorganic antibacterial powder contains CuO in its composition, SnO, ZnO and argentiferous, the nitrogenous inorganic and compound antibacterial and mouldproof material of macromolecular compound.
Described auxiliary agent is the intermixture of brightening agent, thinner, stabilization agent, blowing agent.The preferred ingredient weight content is: brightening agent 25%, thinner 12%, stabilization agent 12%, blowing agent 50%, stabilizing agent 1%.
With proportionally weighing of above-mentioned material, in container, mix then, be stirred into thickener, thereby make PVC functional wallpaper material (this material is a kind of thickener), it is bonded on the basic paper of wallpaper through the thermosoling coating, through adding heat embossing (also can add the laggard row foaming of heat embossing), it is functional that printed patterns and forming has, the wallpaper of relief pattern.
Described basic paper also can be at least a basic paper that following basic paper substrates is used that is selected from, the basic paper of wallpaper, bondedfibre fabric, base cloth, and the composite sheet of bondedfibre fabric and basic paper.
Described bondedfibre fabric is artificial fibre preferably, and polyester, polypropylene, polyvinyl chloride and polyethylene terephthalate are main synthetic fiber bondedfibre fabric.
Described base cloth is meant the cotton product of weaving cotton cloth.
The present invention is used for wallpaper, and the wallpaper of employing material preparation of the present invention has possessed every performance indications of wallpaper itself, has elimination formaldehyde simultaneously again, eliminates peculiar smell, and is antibiotic, mildew-resistant, anti-electromagnetic-radiation and release anion, the effect that purifies air.Anti-biotic material in this wallpaper (inorganic antibacterial powder) can combine with bacterial cell membrane when contacting with bacterium, reaches the purpose of sterilization.When catalysis material in the wallpaper (nano titania level micro mist) under illumination condition, can produce electron transition, produce strong oxidizer and strong reductant, make wallpaper play degradable organic pollutant and antibacterial action, organic pollution is degraded to water and inorganic ions fully, removes formaldehyde, remove stink.The conducting powder of favorable dispersibility makes it form firm conductive layer at matrix surface, makes wallpaper have lasting electric conductivity, can effectively eliminate electromagnetic radiation.The anion micro mist can be passive discharge airborne vitamin--natural anion.
After testing: the formaldehyde clearance reaches 80-92%, peculiar smell clearance 70-85%, the anion release rate reaches 1200-2000/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 3-15, antibiotic rate is greater than 90% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence), 0 grade of antifungi--1 grade, far infrared emissivity (4-14 μ m) 75-82%
Testing result is compared with background technology, can not only remove formaldehyde in the air, removes peculiar smell. also have antibiotic, mildew-resistant. discharge anion, anti-electromagnetic-radiation, far infrared emissivity function.
The specific embodiment
Below embodiments of the invention are elaborated: present embodiment is being to implement under the prerequisite with the technical solution of the present invention, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
In following examples, polyaniline adopts the commercially available prod of Chengdu organic chemistry company, the commercially available prod (ru ZY-H101 anion micro mist) of The Exhibition of Shanghai Raises Science Technologies Co., Ltd., the commercially available prod (ru T400-1 inorganic antibacterial powder) that the inorganic antibacterial powder adopts Shanghai to tie up new material Co., Ltd to provide are provided for nano titania level micro mist, anion micro mist.The commercially available prod (as the KY-D-03 conducting powder) that conducting powder adopts Shanghai color reputation nanosecond science and technology Co., Ltd to provide.Auxiliary agent is the intermixture of brightening agent, thinner, stabilization agent, blowing agent, is the commercially available prod.
Implementation column 1
The present embodiment material is made up of following constituent and percentage by weight:
Nano titania level micro mist 1.5%
Silica nanometer level micro mist 1%
Zinc oxide ultra_fine powders 0.5%
Anion micro mist 2%
Inorganic antibacterial powder 0.5%
Di-iron trioxide 0.5%
Conducting powder 4%
Polyaniline 2.5%
Polyvinyl chloride 25%
Titanium dioxide 5%
O-phthalic ester dioctyl ester 15%
Calcium carbonate 12.5%
Auxiliary agent 30%
With proportionally weighing of above-mentioned material, in container, mix then, be stirred into thickener, thereby make functional wallpaper or wall cloth material, it is bonded on the basic paper of wallpaper, through adding heat embossing through the thermosoling coating, it is functional that printed patterns and forming has, the wallpaper of relief pattern.
After testing: the formaldehyde clearance reaches 85%, peculiar smell clearance 72%, the anion release rate reaches 1300/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 3, antibiotic rate 90% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence).1 grade of antifungi, far infrared emissivity (4-14 μ m) 76%.
Implementation column 2
This implementation column material is made up of following constituent and percentage by weight:
Nano titania level micro mist 2.5%
Silica nanometer level micro mist 2.5%
Zinc oxide ultra_fine powders 1.5%
Anion micro mist 3.5%
Inorganic antibacterial powder 1.5%
Di-iron trioxide 1%
Conducting powder 6%
Polyaniline 5%
Polyvinyl chloride 31%
Titanium dioxide 5.5%
O-phthalic ester dioctyl ester 18.5%
Calcium carbonate 18%
Auxiliary agent 3.5%
With proportionally weighing of above-mentioned material, in container, mix then, be stirred into thickener, thereby make functional wallpaper or wall cloth material, it is bonded on the basic paper of wallpaper, through adding heat embossing through the thermosoling coating, it is functional that printed patterns and forming has, the wallpaper of relief pattern.
After testing: the formaldehyde clearance reaches 92%, peculiar smell clearance 80%, the anion release rate reaches 1800/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 8, antibiotic rate 92% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence).0 grade of antifungi, far infrared emissivity (4-14 μ m) 82%.
Implementation column 3
The present invention is made up of following constituent and percentage by weight
Nano titania level micro mist 2%
Silica nanometer level micro mist 2%
Zinc oxide ultra_fine powders 1%
Anion micro mist 3%
Inorganic antibacterial powder 1%
Di-iron trioxide 0.75%
Conducting powder 5%
Polyaniline 3.5%
Polyvinyl chloride 28%
Titanium dioxide 5.25%
O-phthalic ester dioctyl ester 17%
Calcium carbonate 15.5%
Auxiliary agent 16%
With proportionally weighing of above-mentioned material, described auxiliary agent is pressed brightening agent 25%, thinner 12%, stabilization agent 12%, blowing agent 50%, stabilizing agent 1% weighing mixes in container then, be stirred into thickener, thereby make functional wallpaper or wall cloth material, it is bonded on the basic paper of wallpaper, through adding heat embossing through the thermosoling coating, it is functional that cooling foaming printed patterns and forming has, the foaming wallpaper of relief pattern.
After testing: the formaldehyde clearance reaches 90%, peculiar smell clearance 75%, the anion release rate reaches 1600/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 9, antibiotic rate 91% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence), 1 grade of antifungi, far infrared emissivity (4-14 μ m) 80%.
Claims (7)
1, a kind of functional wallpaper material that can purify air, it is characterized in that, component that comprises and weight percentage are: nano titania level micro mist: 1.5%-2.5%, silica nanometer level micro mist: 1%-2.5%, zinc oxide ultra_fine powders: 0.5%-1.5%, anion micro mist: 2%-3.5%, inorganic antibacterial powder: 0.5%-1.5%, di-iron trioxide: 0.5%-1%, conducting powder: 4%-6%, polyaniline: 2.5%-5%, polyvinyl chloride: 25%-31%, titanium dioxide: 5%-5.5%, O-phthalic ester dioctyl ester: 15%-18.5%, calcium carbonate: 12.5%-18%, auxiliary agent: 3%-30%.
2, the functional wallpaper material that can purify air according to claim 1, it is characterized in that, component that comprises and weight percentage are: nano titania level micro mist: 2.5%, silica nanometer level micro mist: 2.5%, zinc oxide ultra_fine powders: 1.5%, anion micro mist: 3.5%, inorganic antibacterial powder: 1.5% di-iron trioxide: 1%, conducting powder: 6%, polyaniline: 5%, polyvinyl chloride: 31%, titanium dioxide: 5.5%, O-phthalic ester dioctyl ester: 18.5%, calcium carbonate: 18%, auxiliary agent: 3.5%.
3, the functional wallpaper material that can purify air according to claim 1 and 2 is characterized in that, described nano titania level micro mist, silica nanometer level micro mist, zinc oxide ultra_fine powders, anion micro mist, their particle diameter are 50 nanometers-500 nanometers.
4, the functional wallpaper material that can purify air according to claim 1 and 2 is characterized in that, described anion micro mist is the tourmaline of the silicate of boracic, contains boron, aluminium, silicon, manganese, magnesium, calcium, iron in its composition.
5, the functional wallpaper material that can purify air according to claim 1 and 2 is characterized in that, described inorganic antibacterial powder contains promising CuO in its composition, SnO, ZnO and argentiferous, the nitrogenous inorganic and compound antibacterial and mouldproof material of macromolecular compound.
6, the functional wallpaper material that can purify air according to claim 1 and 2 is characterized in that, described auxiliary agent is the intermixture of brightening agent, thinner, stabilization agent, blowing agent.
7, the functional wallpaper material that can purify air according to claim 6 is characterized in that, described auxiliary agent, and its component weight percent content is: brightening agent 25%, thinner 12%, stabilization agent 12%, blowing agent 50%, stabilizing agent 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100414463A CN101333788B (en) | 2008-08-07 | 2008-08-07 | Functional wallpaper material capable of purifying air |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008100414463A CN101333788B (en) | 2008-08-07 | 2008-08-07 | Functional wallpaper material capable of purifying air |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101333788A true CN101333788A (en) | 2008-12-31 |
| CN101333788B CN101333788B (en) | 2011-11-16 |
Family
ID=40196638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008100414463A Expired - Fee Related CN101333788B (en) | 2008-08-07 | 2008-08-07 | Functional wallpaper material capable of purifying air |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101333788B (en) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251441A (en) * | 2011-07-07 | 2011-11-23 | 广东玉兰装饰材料有限公司 | Wall paper with deodorizing function and preparation method thereof |
| CN102345249A (en) * | 2010-08-06 | 2012-02-08 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
| CN102839564A (en) * | 2012-08-02 | 2012-12-26 | 杭州嘉力丰化工有限公司 | Nano-silver mouldproof wallpaper coating and preparation method thereof |
| CN102877305A (en) * | 2012-10-15 | 2013-01-16 | 东华大学 | Antistatic antibacterial odor removal coating adhesive for luggage fabric and preparation and application thereof |
| CN103103873A (en) * | 2011-11-11 | 2013-05-15 | 赵曦轮 | Novel wallpaper paste |
| CN103722856A (en) * | 2013-12-05 | 2014-04-16 | 杭州汉居家居有限公司 | Preparation method of wallpaper capable of purifying indoor air |
| CN103726415A (en) * | 2013-11-29 | 2014-04-16 | 淮北龙盘工贸有限责任公司 | Novel methanol-resistant, water-proof and mould-proof wallpaper |
| CN103726414A (en) * | 2013-11-29 | 2014-04-16 | 淮北龙盘工贸有限责任公司 | Formaldehyde-resistant environment-friendly ecologic wall paper |
| CN104153241A (en) * | 2014-07-15 | 2014-11-19 | 安徽紫荆花壁纸股份有限公司 | High-hardness, high-toughness and anti-scratch PVC (Polyvinyl Chloride) paste for PVC foamed wallpaper and preparation method thereof |
| CN105019312A (en) * | 2014-04-29 | 2015-11-04 | 上海世展化工科技有限公司 | Multifunctional wallpaper and coating composition for multifunctional wallpaper |
| CN105196666A (en) * | 2015-09-28 | 2015-12-30 | 凉山州锡成新材料股份有限公司 | Ultrafine silicate high-filled polyolefin wallpaper base paper and production method thereof |
| CN105220579A (en) * | 2015-09-08 | 2016-01-06 | 沭阳宇涛新型装饰材料有限公司 | The pollution-free anion facing paper of a kind of environment-friendly novel |
| CN106121150A (en) * | 2016-06-30 | 2016-11-16 | 福建省优雅环保壁纸有限公司 | A kind of moisture resistance high-air-permeability wallpaper and preparation method thereof |
| CN106827921A (en) * | 2017-03-08 | 2017-06-13 | 哈尔滨联邦智能卡技术开发有限责任公司 | The preparation method of environment-friendly type macromolecule polymerization one mural painting |
| CN106835856A (en) * | 2016-12-27 | 2017-06-13 | 常州市阿曼特化工有限公司 | A kind of preparation method of the wallpaper with air-cleaning function |
| CN107502077A (en) * | 2017-09-06 | 2017-12-22 | 浙江爱丽莎环保科技股份有限公司 | A kind of preparation method of pebble anion foam wallpaper, thickener used and thickener |
| WO2018038627A1 (en) * | 2016-08-24 | 2018-03-01 | Анна Владимировна КАМЛЕР | Three-dimensional antibacterial material, method for preparation thereof (variants), and unit for implementing the method |
-
2008
- 2008-08-07 CN CN2008100414463A patent/CN101333788B/en not_active Expired - Fee Related
Cited By (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102345249B (en) * | 2010-08-06 | 2015-06-03 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
| CN102345249A (en) * | 2010-08-06 | 2012-02-08 | 范晓星 | Photocatalytic wallpaper for indoor air purification |
| CN102251441A (en) * | 2011-07-07 | 2011-11-23 | 广东玉兰装饰材料有限公司 | Wall paper with deodorizing function and preparation method thereof |
| CN103103873A (en) * | 2011-11-11 | 2013-05-15 | 赵曦轮 | Novel wallpaper paste |
| CN102839564A (en) * | 2012-08-02 | 2012-12-26 | 杭州嘉力丰化工有限公司 | Nano-silver mouldproof wallpaper coating and preparation method thereof |
| CN102877305A (en) * | 2012-10-15 | 2013-01-16 | 东华大学 | Antistatic antibacterial odor removal coating adhesive for luggage fabric and preparation and application thereof |
| CN102877305B (en) * | 2012-10-15 | 2014-08-13 | 东华大学 | Antistatic antibacterial odor removal coating adhesive for luggage fabric and preparation and application thereof |
| CN103726415A (en) * | 2013-11-29 | 2014-04-16 | 淮北龙盘工贸有限责任公司 | Novel methanol-resistant, water-proof and mould-proof wallpaper |
| CN103726414A (en) * | 2013-11-29 | 2014-04-16 | 淮北龙盘工贸有限责任公司 | Formaldehyde-resistant environment-friendly ecologic wall paper |
| CN103726414B (en) * | 2013-11-29 | 2016-02-03 | 淮北龙盘工贸有限责任公司 | The environmental and ecological wallpaper of a kind of anti-formaldehyde |
| CN103722856A (en) * | 2013-12-05 | 2014-04-16 | 杭州汉居家居有限公司 | Preparation method of wallpaper capable of purifying indoor air |
| CN105019312A (en) * | 2014-04-29 | 2015-11-04 | 上海世展化工科技有限公司 | Multifunctional wallpaper and coating composition for multifunctional wallpaper |
| CN104153241A (en) * | 2014-07-15 | 2014-11-19 | 安徽紫荆花壁纸股份有限公司 | High-hardness, high-toughness and anti-scratch PVC (Polyvinyl Chloride) paste for PVC foamed wallpaper and preparation method thereof |
| CN104153241B (en) * | 2014-07-15 | 2017-01-11 | 安徽紫荆花壁纸股份有限公司 | High-hardness, high-toughness and anti-scratch PVC (Polyvinyl Chloride) paste for PVC foamed wallpaper and preparation method thereof |
| CN105220579A (en) * | 2015-09-08 | 2016-01-06 | 沭阳宇涛新型装饰材料有限公司 | The pollution-free anion facing paper of a kind of environment-friendly novel |
| CN105196666A (en) * | 2015-09-28 | 2015-12-30 | 凉山州锡成新材料股份有限公司 | Ultrafine silicate high-filled polyolefin wallpaper base paper and production method thereof |
| CN106121150A (en) * | 2016-06-30 | 2016-11-16 | 福建省优雅环保壁纸有限公司 | A kind of moisture resistance high-air-permeability wallpaper and preparation method thereof |
| WO2018038627A1 (en) * | 2016-08-24 | 2018-03-01 | Анна Владимировна КАМЛЕР | Three-dimensional antibacterial material, method for preparation thereof (variants), and unit for implementing the method |
| EP3505166A4 (en) * | 2016-08-24 | 2020-05-13 | Kamler, Anna Vladimirovna | Three-dimensional antibacterial material, method for preparation thereof (variants), and unit for implementing the method |
| EA036413B1 (en) * | 2016-08-24 | 2020-11-09 | Анна Владимировна КАМЛЕР | Three-dimensional antibacterial material, method for preparation thereof (variants), unit for implementing the method |
| CN106835856A (en) * | 2016-12-27 | 2017-06-13 | 常州市阿曼特化工有限公司 | A kind of preparation method of the wallpaper with air-cleaning function |
| CN106827921A (en) * | 2017-03-08 | 2017-06-13 | 哈尔滨联邦智能卡技术开发有限责任公司 | The preparation method of environment-friendly type macromolecule polymerization one mural painting |
| CN107502077A (en) * | 2017-09-06 | 2017-12-22 | 浙江爱丽莎环保科技股份有限公司 | A kind of preparation method of pebble anion foam wallpaper, thickener used and thickener |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101333788B (en) | 2011-11-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101333788B (en) | Functional wallpaper material capable of purifying air | |
| CN1303168C (en) | Antibacterial, anti electromagnetic radiant interior wall coating with formaldehyde being removed | |
| CN105315727B (en) | The environmental multifunctional inorganic dry powder paint of releasable negative oxygen ion | |
| CN102277044B (en) | Bamboo charcoal odor-removing antibacterial emulsion paint and preparation method thereof | |
| KR20090097600A (en) | Paint composition of friendly-environmental type and manufacturing method thereof | |
| JP5616542B2 (en) | Adsorbed, decomposed, blocked and deodorized composition for harmful substances and method for producing the same | |
| CN102898902A (en) | Method for preparing composite multifunctional moisture-adjusting antibacterial interior wall coating | |
| CN103923536A (en) | Preparation method for ecological air-purifying humidity-regulating antibacterial interior wall paint | |
| KR101313009B1 (en) | Composition for blocking harmful substances | |
| CN101760067A (en) | Environmental friendly putty for removing formaldehyde, eliminating electromagnetic radiation and insulating and preserving heat | |
| CN103011682A (en) | Ecological shell powder inorganic nanometer composite coating material and preparation method thereof | |
| CN104497795A (en) | Negative ion-released antibacterial powdery paint | |
| CN104631769A (en) | Active ecological floor and preparation method thereof | |
| CN102532977A (en) | Composite multifunctional health paint mate and preparation method thereof | |
| CN103351698A (en) | Preparation method of aldehyde/benzene-removing radiation-resistant inner wall putty powder | |
| CN107859258B (en) | A kind of air cleaning and environment-friendly type diatom ooze wallpaper and preparation method | |
| CN107151941B (en) | Photocatalyst suspension, resist blocking and that automatically cleaning wood-based plate facing paper and preparation method thereof | |
| CN106675342A (en) | Ecological paint with negative ion release performance | |
| KR102294159B1 (en) | Watersoluble Fire Proof Paint for Coating | |
| CN105056948A (en) | Ozone elimination catalyst with porous substrate as carrier and preparation method thereof | |
| CN112358757A (en) | Strippable protective film coating and preparation method and application thereof | |
| CN116254020A (en) | Preparation method of interior wall coating integrating adsorption degradation and antimicrobial functions | |
| CN110938326A (en) | Ecological environment-friendly shell powder coating and preparation method thereof | |
| CN106689201B (en) | Nano silver antibacterial agent and preparation method thereof | |
| CN105419555A (en) | Formaldehyde sealant for blockboard |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20111116 Termination date: 20160807 |