CN101333788B - Functional wallpaper material capable of purifying air - Google Patents

Functional wallpaper material capable of purifying air Download PDF

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Publication number
CN101333788B
CN101333788B CN2008100414463A CN200810041446A CN101333788B CN 101333788 B CN101333788 B CN 101333788B CN 2008100414463 A CN2008100414463 A CN 2008100414463A CN 200810041446 A CN200810041446 A CN 200810041446A CN 101333788 B CN101333788 B CN 101333788B
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percent
micro mist
powder
wallpaper
wallpaper material
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CN101333788A (en
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陈建强
楼少波
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NINGBO BONNY DECORATE MATERIAL CO Ltd
Shanghai Jiaotong University
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NINGBO BONNY DECORATE MATERIAL CO Ltd
Shanghai Jiaotong University
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Abstract

Disclosed is a functional type wallpaper material having the air purification function, belonging to the interior decoration material technique field, and containing the components, in weight percentage: 2.5 percent of titanium dioxide nano-sized powder, 2.5 percent of silicon dioxide nano-sized powder, 1.5 percent of zinc oxide powder, 3.5 percent of negative ion powder, 1.5 percent of inorganic antibacterial powder, 1 percent of iron trioxide, 6 percent of conductive powder, 5 percent of polyaniline, 31 percent of polyvinyl chloride, 5.5 percent of dioctyl phthalate, 18.5 percent of di-n-octyl phthalate dioctyl phthalate, 18 percent of calcium carbonate, and 3.5 percent of auxiliary agent. The wallpaper prepared by the materials can remove formaldehyde and peculiar smell, and is antibacterial and mildew-proof, and can release negative ions and resist electromagnetic radiation, as well as greatly improving the indoor air quality for people and solving the indoor air pollution.

Description

The functional wallpaper material that can purify air
Technical field
The present invention relates to a kind of wallpaper material of house decorative material technical field, particularly relate to a kind of functional wallpaper material that can purify air.
Background technology
It is the main aspect that causes room air pollution at present that house decorative material and furniture pollute.Paint, wallpaper, glued board, the wood shavings filler, materials such as interior wall coating all contain formaldehyde, benzene, ethanol, harmful substances such as chloroform, above material all has suitable carcinogenic, the caused environmental pollution of interior decoration is more and more serious, the U.S., specialized agency's investigation of Japan is found, many civilian and room air pollution degree commercial building be the 2-5 that pollutes of outdoor air doubly, there is 30% resident to cause " new home syndrome " approximately because of using harmful chemical, in addition, business automation equipment and micro-wave oven, radio, television set, the electromagnetic wave of the various different wave length frequencies that household electric appliance operation such as computer and mobile phone produces, these electromagnetic waves are full of the space, can penetrate the many materials that comprise human body, receive the dosage of radiation that exceeds standard.
Literature search through prior art is found, Chinese patent publication number CN1752342A, and open day is on March 29th, 2006.Denomination of invention is: the wallpaper that is used to reduce syndrome of new house, this patent readme is: a kind of wallpaper that is used to reduce syndrome of new house is provided, owing to make from the harmful volatile organic compounds of indivisible use, the result does not just have the burst size of volatile organic compounds, even perhaps have also seldom, has the effect that reduces syndrome of new house.Its weak point: just when making wallpaper, the indivisible organic compound that adds less, reduce the burst size of organic compound, and can not effectively remove formaldehyde and electromagnetic radiation, indoor air pollution can not be removed again, the effect of antibiotic, mildew-resistant, release anion and anti-electromagnetic-radiation can not be played.And these air pollutions are very harmful to the mankind.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art and defective, a kind of functional wallpaper material that can purify air is provided, wallpaper with this material preparation can remove formaldehyde, eliminate the unusual smell, antibiotic, mildew-resistant, release anion, anti-electromagnetic-radiation, to improve people's IAQ greatly, solve indoor air pollution.
The present invention is achieved through the following technical solutions, functional wallpaper material of the present invention, and component that comprises and weight percentage are:
Figure GDA0000051552940000011
Figure GDA0000051552940000021
Described conducting powder is that the doping treatment by the activity processing and the conduction factor makes it form firm conductive layer at surface of base on the nano material basis, thereby makes this material have lasting electric conductivity, directly by commercial acquisition.
Described nano titania level micro mist, silica nanometer level micro mist, zinc oxide ultra_fine powders, anion micro mist, their particle diameter is the 50-500 nanometer.Described nano titania level micro mist is a kind of catalysis material.
Described anion micro mist is the tourmaline of the silicate of boracic, and containing in its composition is boron, aluminium, silicon, manganese, magnesium, calcium and iron etc.
Described inorganic antibacterial powder contains CuO in its composition, SnO, ZnO and argentiferous, the nitrogenous inorganic and compound antibacterial and mouldproof material of macromolecular compound.
Described auxiliary agent is the intermixture of brightening agent, thinner, stabilization agent, blowing agent.The preferred ingredient weight content is: brightening agent 25%, thinner 12%, stabilization agent 12%, blowing agent 50%, stabilizing agent 1%.
With proportionally weighing of above-mentioned material, in container, mix then, be stirred into thickener, thereby make PVC functional wallpaper material (this material is a kind of thickener), it is bonded on the basic paper of wallpaper through the thermosoling coating, through adding heat embossing (also can add the laggard row foaming of heat embossing), it is functional that printed patterns and forming has, the wallpaper of relief pattern.
Described basic paper also can be at least a basic paper that following basic paper substrates is used that is selected from, the basic paper of wallpaper, bondedfibre fabric, base cloth, and the composite sheet of bondedfibre fabric and basic paper.
Described bondedfibre fabric is artificial fibre preferably, and polyester, polypropylene, polyvinyl chloride and polyethylene terephthalate are main synthetic fiber bondedfibre fabric.
Described base cloth is meant the cotton product of weaving cotton cloth.
The present invention is used for wallpaper, and the wallpaper of employing material preparation of the present invention has possessed every performance indications of wallpaper itself, has elimination formaldehyde simultaneously again, eliminates peculiar smell, and is antibiotic, mildew-resistant, anti-electromagnetic-radiation and release anion, the effect that purifies air.Anti-biotic material in this wallpaper (inorganic antibacterial powder) can combine with bacterial cell membrane when contacting with bacterium, reaches the purpose of sterilization.When catalysis material in the wallpaper (nano titania level micro mist) under illumination condition, can produce electron transition, produce strong oxidizer and strong reductant, make wallpaper play degradable organic pollutant and antibacterial action, organic pollution is degraded to water and inorganic ions fully, removes formaldehyde, remove stink.The conducting powder of favorable dispersibility makes it form firm conductive layer at matrix surface, makes wallpaper have lasting electric conductivity, can effectively eliminate electromagnetic radiation.The anion micro mist can be passive discharge airborne vitamin--natural anion.
After testing: the formaldehyde clearance reaches 80-92%, peculiar smell clearance 70-85%, the anion release rate reaches 1200-2000/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 3-15, antibiotic rate is greater than 90% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence), 0 grade of antifungi--1 grade, far infrared emissivity (4-14 μ m) 75-82%
Testing result is compared with background technology, can not only remove formaldehyde in the air, removes peculiar smell. also have antibiotic, mildew-resistant. discharge anion, anti-electromagnetic-radiation, far infrared emissivity function.
The specific embodiment
Below embodiments of the invention are elaborated: present embodiment is being to implement under the prerequisite with the technical solution of the present invention, provided detailed embodiment and concrete operating process, but protection scope of the present invention is not limited to following embodiment.
In following examples, polyaniline adopts the commercially available prod of Chengdu organic chemistry company, the commercially available prod (ru ZY-H101 anion micro mist) of The Exhibition of Shanghai Raises Science Technologies Co., Ltd., the commercially available prod (ru T400-1 inorganic antibacterial powder) that the inorganic antibacterial powder adopts Shanghai to tie up new material Co., Ltd to provide are provided for nano titania level micro mist, anion micro mist.The commercially available prod (as the KY-D-03 conducting powder) that conducting powder adopts Shanghai color reputation nanosecond science and technology Co., Ltd to provide.Auxiliary agent is the intermixture of brightening agent, thinner, stabilization agent, blowing agent, is the commercially available prod.
Implementation column 1
The present embodiment material is made up of following constituent and percentage by weight:
Figure GDA0000051552940000031
Figure GDA0000051552940000041
With proportionally weighing of above-mentioned material, in container, mix then, be stirred into thickener, thereby make functional wallpaper or wall cloth material, it is bonded on the basic paper of wallpaper, through adding heat embossing through the thermosoling coating, it is functional that printed patterns and forming has, the wallpaper of relief pattern.
After testing: the formaldehyde clearance reaches 85%, peculiar smell clearance 72%, the anion release rate reaches 1300/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 3, antibiotic rate 90% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence).1 grade of antifungi, far infrared emissivity (4-14 μ m) 76%.
Implementation column 2
This implementation column material is made up of following constituent and percentage by weight:
Figure GDA0000051552940000042
Figure GDA0000051552940000051
With proportionally weighing of above-mentioned material, in container, mix then, be stirred into thickener, thereby make functional wallpaper or wall cloth material, it is bonded on the basic paper of wallpaper, through adding heat embossing through the thermosoling coating, it is functional that printed patterns and forming has, the wallpaper of relief pattern.
After testing: the formaldehyde clearance reaches 92%, peculiar smell clearance 80%, the anion release rate reaches 1800/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 8, antibiotic rate 92% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence).0 grade of antifungi, far infrared emissivity (4-14 μ m) 82%.
Implementation column 3
The present invention is made up of following constituent and percentage by weight
Figure GDA0000051552940000052
With proportionally weighing of above-mentioned material, described auxiliary agent is pressed brightening agent 25%, thinner 12%, stabilization agent 12%, blowing agent 50%, stabilizing agent 1% weighing mixes in container then, be stirred into thickener, thereby make functional wallpaper or wall cloth material, it is bonded on the basic paper of wallpaper, through adding heat embossing through the thermosoling coating, it is functional that cooling foaming printed patterns and forming has, the foaming wallpaper of relief pattern.
After testing: the formaldehyde clearance reaches 90%, peculiar smell clearance 75%, the anion release rate reaches 1600/cubic centimetre, anti-electromagnetic-radiation usefulness (dB) 9, antibiotic rate 91% (for trying bacterial classification: Escherichia coli, staphylococcus aureus, Bacillus megatherium, hay bacillus, Pseudomonas fluorescence), 1 grade of antifungi, far infrared emissivity (4-14 μ m) 80%.

Claims (4)

1. the functional wallpaper material that can purify air is characterized in that, component that comprises and weight percentage are: nano titania level micro mist: 2.5%, silica nanometer level micro mist: 2.5%, zinc oxide ultra_fine powders: 1.5%, anion micro mist: 3.5%, the inorganic antibacterial powder: 1.5%, di-iron trioxide: 1%, conducting powder: 6%, polyaniline: 5%, polyvinyl chloride: 31%, titanium dioxide: 5.5%, dioctyl phthalate: 18.5%, calcium carbonate: 18%, auxiliary agent: 3.5%.
2. the functional wallpaper material that can purify air according to claim 1 is characterized in that, described nano titania level micro mist, silica nanometer level micro mist, zinc oxide ultra_fine powders, anion micro mist, their particle diameter are 50 nanometers-500 nanometers.
3. the functional wallpaper material that can purify air according to claim 1 is characterized in that, described anion micro mist is the tourmaline of the silicate of boracic, contains boron, aluminium, silicon, manganese, magnesium, calcium and iron in its composition.
4. the functional wallpaper material that can purify air according to claim 1 is characterized in that, described auxiliary agent is the intermixture of brightening agent, thinner, stabilization agent, blowing agent.
CN2008100414463A 2008-08-07 2008-08-07 Functional wallpaper material capable of purifying air Expired - Fee Related CN101333788B (en)

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Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102345249B (en) * 2010-08-06 2015-06-03 范晓星 Photocatalytic wallpaper for indoor air purification
CN102251441B (en) * 2011-07-07 2013-09-04 广东玉兰装饰材料有限公司 Wall paper with deodorizing function and preparation method thereof
CN103103873A (en) * 2011-11-11 2013-05-15 赵曦轮 Novel wallpaper paste
CN102839564A (en) * 2012-08-02 2012-12-26 杭州嘉力丰化工有限公司 Nano-silver mouldproof wallpaper coating and preparation method thereof
CN102877305B (en) * 2012-10-15 2014-08-13 东华大学 Antistatic antibacterial odor removal coating adhesive for luggage fabric and preparation and application thereof
CN103726415B (en) * 2013-11-29 2016-02-03 淮北龙盘工贸有限责任公司 A kind of anti-formaldehyde waterproof mildew-proof wallpaper
CN103726414B (en) * 2013-11-29 2016-02-03 淮北龙盘工贸有限责任公司 The environmental and ecological wallpaper of a kind of anti-formaldehyde
CN103722856A (en) * 2013-12-05 2014-04-16 杭州汉居家居有限公司 Preparation method of wallpaper capable of purifying indoor air
CN105019312A (en) * 2014-04-29 2015-11-04 上海世展化工科技有限公司 Multifunctional wallpaper and coating composition for multifunctional wallpaper
CN104153241B (en) * 2014-07-15 2017-01-11 安徽紫荆花壁纸股份有限公司 High-hardness, high-toughness and anti-scratch PVC (Polyvinyl Chloride) paste for PVC foamed wallpaper and preparation method thereof
CN105220579B (en) * 2015-09-08 2018-04-20 沭阳宇涛新型装饰材料有限公司 A kind of pollution-free anion facing paper of environment-friendly novel
CN105196666A (en) * 2015-09-28 2015-12-30 凉山州锡成新材料股份有限公司 Ultrafine silicate high-filled polyolefin wallpaper base paper and production method thereof
CN106121150B (en) * 2016-06-30 2019-04-19 福建省优雅环保壁纸有限公司 A kind of moisture resistance high-air-permeability wallpaper and preparation method thereof
EP3505166A4 (en) * 2016-08-24 2020-05-13 Kamler, Anna Vladimirovna Three-dimensional antibacterial material, method for preparation thereof (variants), and unit for implementing the method
CN106835856A (en) * 2016-12-27 2017-06-13 常州市阿曼特化工有限公司 A kind of preparation method of the wallpaper with air-cleaning function
CN106827921A (en) * 2017-03-08 2017-06-13 哈尔滨联邦智能卡技术开发有限责任公司 The preparation method of environment-friendly type macromolecule polymerization one mural painting
CN107502077A (en) * 2017-09-06 2017-12-22 浙江爱丽莎环保科技股份有限公司 A kind of preparation method of pebble anion foam wallpaper, thickener used and thickener

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