CN105220579B - A kind of pollution-free anion facing paper of environment-friendly novel - Google Patents
A kind of pollution-free anion facing paper of environment-friendly novel Download PDFInfo
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- CN105220579B CN105220579B CN201510565726.4A CN201510565726A CN105220579B CN 105220579 B CN105220579 B CN 105220579B CN 201510565726 A CN201510565726 A CN 201510565726A CN 105220579 B CN105220579 B CN 105220579B
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- 150000001450 anions Chemical class 0.000 title claims abstract description 83
- 239000007788 liquid Substances 0.000 claims abstract description 31
- 230000003115 biocidal effect Effects 0.000 claims abstract description 30
- 239000000463 material Substances 0.000 claims abstract description 26
- 239000002245 particle Substances 0.000 claims abstract description 23
- 239000000843 powder Substances 0.000 claims abstract description 22
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 20
- 239000011707 mineral Substances 0.000 claims abstract description 20
- 238000001035 drying Methods 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 238000012545 processing Methods 0.000 claims abstract description 11
- QROGIFZRVHSFLM-QHHAFSJGSA-N [(e)-prop-1-enyl]benzene Chemical compound C\C=C\C1=CC=CC=C1 QROGIFZRVHSFLM-QHHAFSJGSA-N 0.000 claims abstract description 10
- 229910052613 tourmaline Inorganic materials 0.000 claims abstract description 10
- 229940070527 tourmaline Drugs 0.000 claims abstract description 10
- 239000011032 tourmaline Substances 0.000 claims abstract description 10
- 229920002521 macromolecule Polymers 0.000 claims abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 8
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Substances [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 8
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 239000000470 constituent Substances 0.000 claims abstract description 5
- 238000003672 processing method Methods 0.000 claims abstract description 3
- 239000000123 paper Substances 0.000 claims description 65
- 238000003756 stirring Methods 0.000 claims description 30
- 238000002156 mixing Methods 0.000 claims description 26
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims description 22
- 238000010438 heat treatment Methods 0.000 claims description 21
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000004094 surface-active agent Substances 0.000 claims description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 14
- 239000003381 stabilizer Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 11
- 238000007639 printing Methods 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 9
- 229910052747 lanthanoid Inorganic materials 0.000 claims description 9
- 150000002602 lanthanoids Chemical class 0.000 claims description 9
- 150000003839 salts Chemical class 0.000 claims description 9
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 229910000420 cerium oxide Inorganic materials 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 claims description 7
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- CSNIZNHTOVFARY-UHFFFAOYSA-N 1,2-benzothiazole Chemical compound C1=CC=C2C=NSC2=C1 CSNIZNHTOVFARY-UHFFFAOYSA-N 0.000 claims description 5
- ZHTRFSJGUKYTPR-UHFFFAOYSA-N 2-octyl-1,2-thiazolidin-4-one Chemical class CCCCCCCCN1CC(=O)CS1 ZHTRFSJGUKYTPR-UHFFFAOYSA-N 0.000 claims description 5
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 5
- 235000013539 calcium stearate Nutrition 0.000 claims description 5
- 239000008116 calcium stearate Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 5
- 229920002635 polyurethane Polymers 0.000 claims description 5
- 239000004814 polyurethane Substances 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- 150000005846 sugar alcohols Polymers 0.000 claims description 5
- 230000000630 rising effect Effects 0.000 claims description 4
- 230000003750 conditioning effect Effects 0.000 claims description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 2
- 239000000908 ammonium hydroxide Substances 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 5
- 230000000505 pernicious effect Effects 0.000 abstract description 4
- 239000000796 flavoring agent Substances 0.000 abstract description 3
- 235000019634 flavors Nutrition 0.000 abstract description 3
- 235000021180 meal component Nutrition 0.000 abstract 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 36
- 230000000694 effects Effects 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 241000894006 Bacteria Species 0.000 description 5
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 229910052684 Cerium Inorganic materials 0.000 description 4
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 238000001179 sorption measurement Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 230000006870 function Effects 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- -1 oxygen ion Chemical class 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- QROGIFZRVHSFLM-UHFFFAOYSA-N prop-1-enylbenzene Chemical class CC=CC1=CC=CC=C1 QROGIFZRVHSFLM-UHFFFAOYSA-N 0.000 description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- 238000009423 ventilation Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 210000004072 lung Anatomy 0.000 description 2
- 210000000653 nervous system Anatomy 0.000 description 2
- 239000011782 vitamin Substances 0.000 description 2
- 229940088594 vitamin Drugs 0.000 description 2
- 229930003231 vitamin Natural products 0.000 description 2
- 235000013343 vitamin Nutrition 0.000 description 2
- 150000003722 vitamin derivatives Chemical class 0.000 description 2
- 102000005606 Activins Human genes 0.000 description 1
- 108010059616 Activins Proteins 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 1
- 206010020772 Hypertension Diseases 0.000 description 1
- 244000211187 Lepidium sativum Species 0.000 description 1
- 235000007849 Lepidium sativum Nutrition 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 208000013738 Sleep Initiation and Maintenance disease Diseases 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000488 activin Substances 0.000 description 1
- 206010003246 arthritis Diseases 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000017531 blood circulation Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000019522 cellular metabolic process Effects 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 230000005686 electrostatic field Effects 0.000 description 1
- 230000002964 excitative effect Effects 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 210000000987 immune system Anatomy 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 206010022000 influenza Diseases 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 206010022437 insomnia Diseases 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 230000002107 myocardial effect Effects 0.000 description 1
- 230000010016 myocardial function Effects 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000001766 physiological effect Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 229910052604 silicate mineral Inorganic materials 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 238000013268 sustained release Methods 0.000 description 1
- 239000012730 sustained-release form Substances 0.000 description 1
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Landscapes
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
A kind of pollution-free anion facing paper of environment-friendly novel, wherein, decorative paper layer processing method is：Nanoscale natural mineral matter meal component is put into Ultramicro-powder mixer respectively, is uniformly mixed；Nanoscale natural mineral powder is added in stirred tank with macromolecule tourmaline particle and is stirred evenly, obtains anion layer woollen；Anion layer woollen is added in high speed dispersor with diatomite and nano-calcium carbonate and is stirred, obtains anion layer mixture；Anion layer mixture is added in reaction kettle with propenyl benzene and is stirred, obtains anion layer base-material；The constituent of moisture-proof, antibiotic complex liquid is added in stirred tank and is stirred evenly, obtains moisture-proof, antibiotic complex liquid；Anion layer base-material is uniformly applied to by quick-frozen decorative paper layer upper surface, by moisture-proof, antibiotic complex liquid print to pass through quick-frozen decorative paper layer lower surface, after the completion of carry out drying and processing；The anion layer of the present invention can discharge anion, remove pernicious gas and the foreign flavor indoors such as formaldehyde, play the role of purifying air.
Description
Technical field
The present invention relates to a kind of indoor floor and the ornament materials of furniture surfacing, more specifically, more particularly to a kind of
Environment-friendly novel is pollution-free anion facing paper.
Background technology
With China's expanding economy, the housing condition of people is greatly improved, one in the house just fitted up
As can all have one niff, this taste mostlys come from harmful gas such as the formaldehyde of the releases such as furniture, sofa, paint
Body；Formaldehyde is a kind of gas for having intense irritation smell, and certain density formaldehyde is to devices such as the nervous system of people, lung, livers
Official can produce injury.In general, the deenergized period of the formaldehyde in furniture is up to 5 to 10 years, if long-term life is stayed at home,
Formaldehyde is removed not in time, necessarily affects the health of people；At present, the common method except formaldehyde of family include ventilation method,
Plant absorption method, active carbon adsorption, purification of chemical reagents method etc.；Ventilation method is good method, can effectively reduce room
The content of interior formaldehyde, but when sleep at night, it is often necessary to door and window are closed, limits the use of ventilation method；Plant inhales
The assimilation effect of receipts method is not fine；Active carbon adsorption can be by formaldehyde absorbing, but can not remove, and activity
Charcoal has been used after a certain period of time, its adsorption effect is greatly lowered；Purification of chemical reagents method is complicated, and there is secondary pollution
Risk, and can not use daily, limit its clean-up effect；The facing paper of existing floor and furniture surfacing is mainly
Double-layer structure, i.e., be made of the ink on body paper and front, and the body paper back side is pressed together on substrate during use, and substrate is mainly wood base board
Or fiberboard, this showpiece has been difficult to survive under the overall situation for the green structural material that prevails instantly, while this decoration
Paper uses easily mouldy growth bacterium, and mouldy growth bacterium often all starts from inside to outside after a period of time, i.e., former
Easily mouldy growth bacterium causes facing paper integrally mouldy growth bacterium at the back side that paper is bonded with substrate, easily produces wound to human body
Evil, and do not possess mosquito dispersing, the function for pressure of releiving cannot meet the daily demand of people, and give living environment
Bring secondary pollution；By negative aeroion Technology application in decorating in paper product, negative aeroion is discharged for a long time indoors, especially
Negative oxygen ion, due to its in structure it is similar to ultra-oxygen anion free radical (O2-), there is similar bioactivity,
Biological cell living can be made negatively charged, so that virus loses the attacking ability to cell；For example, artificial air bear from
In subenvironment, mould, bacterial population can reduce by more than 90% in air after measured.After negative oxygen ion is inhaled into human body, god can be adjusted
Excitatory state through maincenter, improves the ventilatory of lung, improves blood circulation, boost metabolism, strengthen immune system ability,
Make one in high spirits, improve work efficiency etc., it also has one to many diseases such as hypertension, asthma, influenza, insomnia, arthritis
Fixed therapeutic effect, so people's anion is referred to as " vitamin in air " " long-lived element "；So for home environment, Neng Goukai
Hair one kind can recycle, effectively remove the pernicious gases such as formaldehyde, while the environmentally-friendly decorative paper of antimildew and antibacterial is very necessary
's.
The content of the invention
To solve the above-mentioned problems, the present invention provides a kind of pollution-free anion facing paper of environment-friendly novel, and the present invention can be held
Continuous release anion, removes harmful substance and the foreign flavor indoors such as formaldehyde, and antibacterial bacteriostatic, purifies the air of a room, and antimildew and antibacterial,
It can effectively prevent veneer product moisture damage, extend the service life of product, improve practicality, the energy-saving and emission-reduction of product.
In order to realize above-mentioned goal of the invention, present invention employs following technical solution：
A kind of pollution-free anion facing paper of environment-friendly novel, including decorative paper layer, wherein, decorative paper layer one side is set
There is anion layer, the decorative paper layer another side is equipped with moisture-proof, antibiotic layer, and the moisture-proof, antibiotic layer is being decorated by intaglio printing
Moisture-proof, antibiotic complex liquid in ply of paper one side prints to be formed；The constituent of the anion layer is counted as follows in parts by weight：
35-65 parts of macromolecule tourmaline particle
17-47 parts of nanoscale natural mineral powder
15-20 parts of surfactant
13-18 parts of diatomite
0.1-0.5 parts of nano-calcium carbonate
9-12 parts of propenyl benzene；
The moisture-proof, antibiotic complex liquid includes following components by mass percentage：
Deionized water 85-90%
Propenyl benzene 2-4%
Propylene glycol monomethyl ether 3-7%
Stabilizer 1.5-5.5%
Benzisothiazole 0.1-0.4%
N- octylisothiazolinones 0.1-0.4%
PH value conditioning agent 0.1-0.5%
Sodium carbonate 0.1-0.5%.
The nanoscale natural mineral powder is by titanium dioxide, manganese dioxide, lanthanide rare composite salt and cerium oxide
Particle forms, the manganese dioxide, and the weight ratio of lanthanide rare composite salt and cerium oxide particle is 2：3：2：4.
The titanium dioxide is with the manganese dioxide particle diameter at 200-300 nanometers.
The cerium oxide particle particle diameter is at 30-40 microns.
The surfactant is by maleic anhydride and polyurethanes with weight ratio 3:7 mix.
The stabilizer is by calcium stearate and polyalcohol with 2:3 weight ratio, which is mixed with, to be formed.
The viscosity of the moisture-proof, antibiotic complex liquid is between 19-26S.
The pH value conditioning agent is one kind in ammonium hydroxide, sodium carbonate, sodium acid carbonate.
A kind of above-mentioned pollution-free anion facing paper of environment-friendly novel, wherein, the decorative paper layer processing method is：
（1）By the titanium dioxide in above-mentioned nanoscale natural mineral powder, manganese dioxide, lanthanide rare composite salt and oxygen
Change cerium particle to put into respectively in Ultramicro-powder mixer, mixing velocity 300-900r/min is spare；
（2）By step（1）The nanoscale natural mineral powder of middle mixing is added in stirred tank with macromolecule tourmaline particle
Stir evenly, mixing speed 700-1800r/min；Heated after stirring, heating-up temperature is 150-260 DEG C, heating time
For 2.5 ~ 3h, anion layer woollen is obtained；
（3）By step（2）In obtained anion layer woollen add high speed dispersor with diatomite and nano-calcium carbonate
In be stirred, mixing time 20min, obtains anion layer mixture；
（4）By step（3）In obtained anion layer mixture add in reaction kettle and be stirred with propenyl benzene, stirring speed
Spend for 500-800r/min, mixing time 45-60min, is heated after the completion of stirring, and heating-up temperature is 230-360 DEG C, is added
The hot time is 1h, adds surfactant stirring, room temperature is naturally cooled to after stirring, you can obtain anion layer base-material；
（5）The constituent of above-mentioned moisture-proof, antibiotic complex liquid is added in stirred tank and is stirred evenly, mixing speed 500-
1500r/min, is heated after stirring, and heating-up temperature is 70-90 DEG C, and viscosity reaches rear stopping heating between 19-26S, heating
After naturally cool to room temperature, you can moisture-proof, antibiotic complex liquid；
（6）The decorative paper layer of machine-shaping is put into liquid nitrogen carry out it is quick-frozen, then by step（4）In obtained anion layer
Base-material is uniformly applied to by quick-frozen decorative paper layer upper surface, and thickness of the anion layer base-material in decorative paper layer is 0.8-
1.5mm；Drying and processing is carried out after the completion of smearing, drying initial temperature is 35 DEG C, is uniformly risen with the speed of 15 DEG C/min, until
70-80 DEG C is risen to, then persistently dries 15-20min；
（7）By step（5）In obtained moisture-proof, antibiotic complex liquid be printed on the print speed printing speed full version of 100-120m/min
Step（6）In smeared anion layer base-material decorative paper layer lower surface on, carry out drying and processing after being completed for printing,
20min is dried at a temperature of 80-90 DEG C.
Beneficial effects of the present invention are：
1st, there is the pollution-free anion facing paper of environment-friendly novel of negative ion-releasing function；Wrapped up on original wallpaper layer
Anion layer, by using macromolecule tourmaline particle and nanoscale natural mineral powder, can release more times of anions, improve
Environment, can large area absorption room air in harmful substance；Also, moisture-proof, antibiotic complex liquid has been printed in facing paper bottom surface, makes
Facing paper all keeps the function of moisture-proof, antibiotic in the long-term use, solves what traditional facing paper paper started from inside to outside
Grow the mouldy situation of bacterium；
2nd, tourmaline is a kind of silicate mineral, it is contacted with hydrone under electrostatic field, can be by hydrone electricity
From into hydrogen ion（H+）With hydroxide ion (OH-), hydroxide ion forms basic hydroxide group anion with water molecules
（H2OOH-）, it is " negative aeroion " that scientific research at present proves：Anion can not only facilitate human body to synthesize and store dimension life
Element, strengthens the physiological activity with human activin, has highly important influence to the vital movement of human body and other biological, claimed
For " air vitamin "；Harmful substance in the effective adsorption chamber of anion, such as formaldehyde, toluene construction and decoration harmful substance, not only
Itself do not increase pollution, and Cress room air, ensure that health is unaffected, be a kind of environmentally protective decoration
Material；
3rd, in the process of facing paper, first decorative paper layer is carried out with liquid nitrogen quick-frozen, can effectively protects facing paper
Layer will not be destroyed during smearing, dried after smearing in a manner of gradually heating up, can effectively remove unnecessary water
Part, ensure the original color of facing paper and image quality, it is relatively reliable；The anion layer of the present invention can be born with sustained release anion
Formaldehyde in air, radon gas and benzene etc. can be resolved into carbon dioxide and water by ion, can also be adsorbed neutral or positively charged
Pernicious gas be allowed to precipitate, therefore can effectively remove the pernicious gases such as formaldehyde and foreign flavor indoors, antibacterial bacteriostatic, plays purification
The effect of air；Anion layer property is stablized, and high temperature high voltage resistant is non-toxic, colorless and odorless, and any side effect will not be produced to human body,
And anion can be constantly produced, reach lasting antibacterial and mouldproof and other effects；In addition anion can stimulate the nervous system of people
Good effect is produced, improves the myocardial function of people, strengthens myocardial nutrition and cell metabolism, lessens fatigue, make one energetic, carry
High immunity, is beneficial to health；The configuration of the present invention is simple, it is easily manufactured, it is very practical.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of pollution-free anion facing paper of environment-friendly novel, its preparation method are as follows：
1st, nanoscale natural mineral powder is first configured, by titanium dioxide, manganese dioxide, lanthanide rare composite salt and oxidation
Cerium particle is by weight 2：3：2：4 ratio is uniformly mixed, and obtains nanoscale natural mineral powder；
2nd, surfactant is reconfigured at, by maleic anhydride and polyurethanes with weight ratio 3:7 are uniformly mixed, and obtain
Surfactant；
3rd, stabilizer is configured, by calcium stearate and polyalcohol with weight ratio 2:3 ratio is uniformly mixed, and obtains stabilizer；
4th, 20 parts of nanoscale natural mineral powders are added in stirred tank with 36 parts of macromolecule tourmaline particles and stirred evenly,
Mixing speed is 1000r/min；Heated after stirring, heating-up temperature is 180 DEG C, and heating time 2.5h, obtains anion layer
Woollen；
5th, the anion layer woollen and 14 parts of diatomite and 0.3 part of nano-calcium carbonate obtained step 4 is added and divided at a high speed
Dissipate and be stirred in machine, mixing time 20min, obtains anion layer mixture；
6th, the anion layer mixture that step 5 obtains is added in reaction kettle with 9 parts of propenyl benzenes and be stirred, mixing speed
For 500r/min, mixing time 45min, is heated after the completion of stirring, and heating-up temperature is 230 DEG C, heating time 1h, then
15 parts of surfactant stirrings are added, naturally cool to room temperature after stirring, you can obtain anion layer base-material；
7th, moisture-proof, antibiotic complex liquid is configured, is 85% deionized water, 2% propenyl benzene, 3% propane diols by percentage
Methyl ether, 1.5% stabilizer, 0.2% benzisothiazole, 0.1% N- octylisothiazolinones, 0.1% pH value tune
Section agent, 0.2% sodium carbonate are added in stirred tank and stirred evenly, and mixing speed 600r/min, is heated after stirring, heating
Temperature is 70 DEG C, and viscosity stops heating after reaching 23S, naturally cools to room temperature after heating, obtains moisture-proof, antibiotic complex liquid；
8th, the decorative paper layer of machine-shaping is put into liquid nitrogen and carries out anion layer base that is quick-frozen, then will being obtained in step 6
Material is uniformly applied to by quick-frozen decorative paper layer upper surface, and thickness of the anion layer base-material in decorative paper layer is 1mm；Smear
After the completion of carry out drying and processing, drying initial temperature is 35 DEG C, is uniformly risen with the speed of 15 DEG C/min, until rising to 80
DEG C, then persistently dry 15min；
9th, the moisture-proof, antibiotic complex liquid obtained in step 7 is printed in step 8 with the print speed printing speed full version of 100m/min
On the lower surface for having smeared the decorative paper layer of anion layer base-material, drying and processing is carried out after being completed for printing, in 80 DEG C of temperature
Lower drying 20min can obtain finished product.
Embodiment 2
A kind of pollution-free anion facing paper of environment-friendly novel, its preparation method are as follows：
1st, nanoscale natural mineral powder is first configured, by titanium dioxide, manganese dioxide, lanthanide rare composite salt and oxidation
Cerium particle is by weight 2：3：2：4 ratio is uniformly mixed, and obtains nanoscale natural mineral powder；
2nd, surfactant is reconfigured at, by maleic anhydride and polyurethanes with weight ratio 3:7 are uniformly mixed, and obtain
Surfactant；
3rd, stabilizer is configured, by calcium stearate and polyalcohol with weight ratio 2:3 ratio is uniformly mixed, and obtains stabilizer；
4th, 25 parts of nanoscale natural mineral powders are added in stirred tank with 41 parts of macromolecule tourmaline particles and stirred evenly,
Mixing speed is 1200r/min；Heated after stirring, heating-up temperature is 200 DEG C, and heating time 2.8h, obtains anion layer
Woollen；
5th, the anion layer woollen and 16 parts of diatomite and 0.4 part of nano-calcium carbonate obtained step 4 is added and divided at a high speed
Dissipate and be stirred in machine, mixing time 20min, obtains anion layer mixture；
6th, the anion layer mixture that step 5 obtains is added in reaction kettle with 11 parts of propenyl benzenes and be stirred, stirring speed
Spending for 800r/min, mixing time 55min, is heated after the completion of stirring, and heating-up temperature is 280 DEG C, heating time 1h,
17 parts of surfactant stirrings are added, naturally cool to room temperature after stirring, you can obtain anion layer base-material；
7th, moisture-proof, antibiotic complex liquid is configured, is 86% deionized water, 3% propenyl benzene, 4% propane diols by percentage
Methyl ether, 1.7% stabilizer, 0.3% benzisothiazole, 0.2% N- octylisothiazolinones, 0.2% pH value tune
Section agent, 0.3% sodium carbonate are added in stirred tank and stirred evenly, and mixing speed 1000r/min, is heated after stirring, added
Hot temperature is 80 DEG C, and viscosity stops heating after reaching 25S, naturally cools to room temperature after heating, obtains moisture-proof, antibiotic complex liquid；
8th, the decorative paper layer of machine-shaping is put into liquid nitrogen and carries out anion layer base that is quick-frozen, then will being obtained in step 6
Material is uniformly applied to by quick-frozen decorative paper layer upper surface, and thickness of the anion layer base-material in decorative paper layer is 1.3mm；Apply
Drying and processing is carried out after the completion of smearing, drying initial temperature is 35 DEG C, is uniformly risen with the speed of 15 DEG C/min, until rising to 85
DEG C, then persistently dry 15min；
9th, the moisture-proof, antibiotic complex liquid obtained in step 7 is printed in step 8 with the print speed printing speed full version of 110m/min
On the lower surface for having smeared the decorative paper layer of anion layer base-material, drying and processing is carried out after being completed for printing, in 85 DEG C of temperature
Lower drying 20min can obtain finished product.
Embodiment 3
A kind of pollution-free anion facing paper of environment-friendly novel, its preparation method are as follows：
1st, nanoscale natural mineral powder is first configured, by titanium dioxide, manganese dioxide, lanthanide rare composite salt and oxidation
Cerium particle is by weight 2：3：2：4 ratio is uniformly mixed, and obtains nanoscale natural mineral powder；
2nd, surfactant is reconfigured at, by maleic anhydride and polyurethanes with weight ratio 3:7 are uniformly mixed, and obtain
Surfactant；
3rd, stabilizer is configured, by calcium stearate and polyalcohol with weight ratio 2:3 ratio is uniformly mixed, and obtains stabilizer；
4th, 25 parts of nanoscale natural mineral powders are added in stirred tank with 45 parts of macromolecule tourmaline particles and stirred evenly,
Mixing speed is 1200r/min；Heated after stirring, heating-up temperature is 230 DEG C, and heating time 3h, obtains anion layer hair
Material；
5th, the anion layer woollen and 18 parts of diatomite and 0.4 part of nano-calcium carbonate obtained step 4 is added and divided at a high speed
Dissipate and be stirred in machine, mixing time 20min, obtains anion layer mixture；
6th, the anion layer mixture that step 5 obtains is added in reaction kettle with 10 parts of propenyl benzenes and be stirred, stirring speed
Spending for 800r/min, mixing time 60min, is heated after the completion of stirring, and heating-up temperature is 300 DEG C, heating time 1h,
20 parts of surfactant stirrings are added, naturally cool to room temperature after stirring, you can obtain anion layer base-material；
7th, moisture-proof, antibiotic complex liquid is configured, is 88% deionized water, 3% propenyl benzene, 4% propane diols by percentage
Methyl ether, 1.9% stabilizer, 0.4% benzisothiazole, 0.1% N- octylisothiazolinones, 0.2% pH value tune
Section agent, 0.2% sodium carbonate are added in stirred tank and stirred evenly, and mixing speed 1300r/min, is heated after stirring, added
Hot temperature is 85 DEG C, and viscosity stops heating after reaching 25S, naturally cools to room temperature after heating, obtains moisture-proof, antibiotic complex liquid；
8th, the decorative paper layer of machine-shaping is put into liquid nitrogen and carries out anion layer base that is quick-frozen, then will being obtained in step 6
Material is uniformly applied to by quick-frozen decorative paper layer upper surface, and thickness of the anion layer base-material in decorative paper layer is 0.9mm；Apply
Drying and processing is carried out after the completion of smearing, drying initial temperature is 35 DEG C, is uniformly risen with the speed of 15 DEG C/min, until rising to 75
DEG C, then persistently dry 15min；
9th, the moisture-proof, antibiotic complex liquid obtained in step 7 is printed in step 8 with the print speed printing speed full version of 120m/min
On the lower surface for having smeared the decorative paper layer of anion layer base-material, drying and processing is carried out after being completed for printing, in 90 DEG C of temperature
Lower drying 20min can obtain finished product.
Performance test, the moist room for having formaldehyde gas is attached to by facing paper obtained in three embodiments（10 squares
Rice）Interior, the negative ion concentration in room air is 30/cm3, and the concentration of formaldehyde in air is 20 mg/ ㎡, by incite somebody to action this
When the obtained facing paper 24 of invention is small, 72 it is small when, 168 it is small when, 360 it is small when the test space in anion and concentration of formaldehyde content
It is as follows：
It is as shown in table 1 a kind of pollution-free anion facing paper performance indicator of environment-friendly novel of the present invention：
。
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, the change or replacement that can readily occur in,
It should all cover within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection domain of claims
Subject to.
Claims (7)
1. a kind of pollution-free anion facing paper of environment-friendly novel, it is characterized in that, including decorative paper layer, wherein, the facing paper
Laminated to be equipped with anion layer, the decorative paper layer another side is equipped with moisture-proof, antibiotic layer, and the moisture-proof, antibiotic layer is by intaglio process
The moisture-proof, antibiotic complex liquid brushed in decorative paper layer one side prints to be formed；The constituent of the anion layer is counted in parts by weight
It is as follows：
35-65 parts of macromolecule tourmaline particle
17-47 parts of nanoscale natural mineral powder
15-20 parts of surfactant
13-18 parts of diatomite
0.1-0.5 parts of nano-calcium carbonate
9-12 parts of propenyl benzene；
The moisture-proof, antibiotic complex liquid includes following components by mass percentage：
Deionized water 85-90%
Propenyl benzene 2-4%
Propylene glycol monomethyl ether 3-7%
Stabilizer 1.5-5.5%
Benzisothiazole 0.1-0.4%
N- octylisothiazolinones 0.1-0.4%
PH value conditioning agent 0.1-0.5%
Sodium carbonate 0.1-0.5%；
The decorative paper layer processing method is：
（1）By the titanium dioxide in above-mentioned nanoscale natural mineral powder, manganese dioxide, lanthanide rare composite salt and cerium oxide
Particle is put into Ultramicro-powder mixer respectively, mixing velocity 300-900r/min, spare；
（2）By step（1）The nanoscale natural mineral powder of middle mixing is added in stirred tank with macromolecule tourmaline particle and stirred
Uniformly, mixing speed 700-1800r/min；Heated after stirring, heating-up temperature is 150-260 DEG C, heating time 2.5
~ 3h, obtains anion layer woollen；
（3）By step（2）In obtained anion layer woollen and diatomite and nano-calcium carbonate add in high speed dispersor into
Row stirring, mixing time 20min, obtains anion layer mixture；
（4）By step（3）In obtained anion layer mixture add in reaction kettle and be stirred with propenyl benzene, mixing speed is
500-800r/min, mixing time 45-60min, is heated after the completion of stirring, and heating-up temperature is 230-360 DEG C, during heating
Between be 1h, add surfactant stirring, naturally cool to room temperature after stirring, you can anion layer base-material；
（5）The constituent of moisture-proof, antibiotic complex liquid is added in stirred tank and is stirred evenly, mixing speed 500-1500r/
Min, is heated after stirring, and heating-up temperature is 70-90 DEG C, and viscosity reaches rear stopping heating between 19-26S, after heating
Naturally cool to room temperature, you can obtain moisture-proof, antibiotic complex liquid；
（6）The decorative paper layer of machine-shaping is put into liquid nitrogen carry out it is quick-frozen, then by step（4）In obtained anion layer base-material
Uniformly it is applied to by quick-frozen decorative paper layer upper surface, thickness of the anion layer base-material in decorative paper layer is 0.8-1.5mm；
Drying and processing is carried out after the completion of smearing, drying initial temperature is 35 DEG C, is uniformly risen with the speed of 15 DEG C/min, until rising to
70-80 DEG C, then persistently dry 15-20min；
（7）By step（5）In obtained moisture-proof, antibiotic complex liquid step is printed on the print speed printing speed full version of 100-120m/min
（6）In smeared anion layer base-material decorative paper layer lower surface on, drying and processing is carried out after being completed for printing, in 80-90
20min is dried at a temperature of DEG C；
The nanoscale natural mineral powder is by titanium dioxide, manganese dioxide, lanthanide rare composite salt and cerium oxide particle
The weight ratio of composition, the manganese dioxide, lanthanide rare composite salt and cerium oxide particle is 2：3：2：4.
A kind of 2. pollution-free anion facing paper of environment-friendly novel as claimed in claim 1, it is characterised in that the titanium dioxide
With the manganese dioxide particle diameter at 200-300 nanometers.
A kind of 3. pollution-free anion facing paper of environment-friendly novel as claimed in claim 1, it is characterised in that the cerium oxide
Grain particle diameter is at 30-40 microns.
A kind of 4. pollution-free anion facing paper of environment-friendly novel as claimed in claim 1, it is characterised in that the surface-active
Agent is by maleic anhydride and polyurethanes with weight ratio 3:7 mix.
A kind of 5. pollution-free anion facing paper of environment-friendly novel as claimed in claim 1, it is characterised in that the stabilizer by
Calcium stearate is with polyalcohol with 2:3 weight ratio, which is mixed with, to be formed.
A kind of 6. pollution-free anion facing paper of environment-friendly novel as claimed in claim 1, it is characterised in that the moisture-proof, antibiotic
The viscosity of complex liquid is between 19-26S.
7. a kind of pollution-free anion facing paper of environment-friendly novel as claimed in claim 1, it is characterised in that the pH value is adjusted
Agent is one kind in ammonium hydroxide, sodium carbonate, sodium acid carbonate.
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| CN106835856A (en) * | 2016-12-27 | 2017-06-13 | 常州市阿曼特化工有限公司 | A kind of preparation method of the wallpaper with air-cleaning function |
| CN107327102A (en) * | 2017-07-17 | 2017-11-07 | 安徽三品技术服务有限公司 | A kind of decorative wall panels with air-cleaning function |
| CN107815213A (en) * | 2017-10-05 | 2018-03-20 | 镇江泽枫霖建筑材料有限公司 | A kind of environmental protection removes the preparation method of formaldehyde building materials |
| CN110499672A (en) * | 2019-09-05 | 2019-11-26 | 沭阳宇涛新型装饰材料有限公司 | A kind of novel wear resistant anion facing paper |
| CN111576080A (en) * | 2020-04-27 | 2020-08-25 | 佛山市高明金湘坊装饰材料有限公司 | Decorative paper and manufacturing method thereof |
| CN111593609A (en) * | 2020-04-29 | 2020-08-28 | 佛山市高明金湘坊装饰材料有限公司 | Environment-friendly decorative paper and manufacturing method thereof |
| CN113638269A (en) * | 2021-07-22 | 2021-11-12 | 左众文 | Environment-friendly antibacterial moisture-proof decorative paper and manufacturing method thereof |
| CN113718557A (en) * | 2021-08-20 | 2021-11-30 | 乔永恒 | Novel pollution-free negative ion decorative paper of environmental protection |
| CN114250650B (en) * | 2021-12-30 | 2023-02-24 | 上海欣旺优能材料股份有限公司 | Mildew-proof flame-retardant wallpaper and preparation method thereof |
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| CN102979007B (en) * | 2012-11-28 | 2017-02-08 | 上海艺亨实业有限公司 | Multifunctional ecological anion wallpaper |
| CN104278597A (en) * | 2014-09-09 | 2015-01-14 | 刘广来 | Production method of decorative wallpaper |
| CN204530324U (en) * | 2015-03-06 | 2015-08-05 | 罗良芬 | Wallpaper containing anion layer |
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