KR20070045724A - The eco-paint and the manufacturing method thereof with the zeolite base - Google Patents

The eco-paint and the manufacturing method thereof with the zeolite base Download PDF

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KR20070045724A
KR20070045724A KR1020050102318A KR20050102318A KR20070045724A KR 20070045724 A KR20070045724 A KR 20070045724A KR 1020050102318 A KR1020050102318 A KR 1020050102318A KR 20050102318 A KR20050102318 A KR 20050102318A KR 20070045724 A KR20070045724 A KR 20070045724A
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zeolite
eco
binder
paint
friendly
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KR100802255B1 (en
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김순호
성진경
김태영
이상진
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(주) 대동종합건설
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/20—Diluents or solvents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/43—Thickening agents
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/80—Processes for incorporating ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide

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  • Organic Chemistry (AREA)
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  • Wood Science & Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
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  • Paints Or Removers (AREA)

Abstract

본 발명은 친환경 도료 및 그 제조방법에 관한 것에 관한 것으로서, 상세하게는 제올라이트(Zeolite), 탄산칼슘(CaCO3), 음이온석(Anion), 무기항균제(Antibiotic), 이산화티탄(TiO2), 친환경바인더를 활용한 친환경 도료 및 그 제조방법에 관한 것이다. 본 발명은 제올라이트를 활용한 환경 친환경 건축 도료로서 휘발성 유기물질(VOCs)을 제거하며, 흡착, 탈취, 항균, 항 곰팡이 효과와 온도, 습도의 조절기능뿐만 아니라 음이온 발생 효과를 발현하는 제올라이트를 활용한 친환경 도료 및 그 제조방법에 관한 것이다.The present invention relates to an environmentally friendly paint and a method for manufacturing the same, and specifically, zeolite, calcium carbonate (CaCO 3 ), anion stone (Anion), inorganic antimicrobial agent (Antibiotic), titanium dioxide (TiO 2 ), environmentally friendly It relates to an eco-friendly paint using a binder and a method of manufacturing the same. The present invention removes volatile organic substances (VOCs) as an environmentally friendly building paint using zeolite, and utilizes zeolite to express anion generating effects as well as adsorption, deodorization, antibacterial, anti-fungal effects and temperature and humidity control functions. It relates to an environmentally friendly paint and a method of manufacturing the same.

도료, 제올라이트, 음이온석, 무기항균제, 친환경바인더 Paint, zeolite, anion stone, inorganic antibacterial agent, eco-friendly binder

Description

제올라이트를 활용한 친환경 도료 및 그 제조방법{the eco-paint and the manufacturing method thereof with the zeolite base}Environment-friendly paints using zeolite and its manufacturing method {the eco-paint and the manufacturing method

도 1은 본 발명에 따른 제올라이트를 활용한 친환경 도료의 제조방법을 나타내는 도면이다.1 is a view showing a method for manufacturing an environmentally friendly paint using a zeolite according to the present invention.

본 발명은 친환경 도료 및 그 제조방법에 관한 것에 관한 것으로서, 특히 제올라이트(Zeolite), 탄산칼슘(CaCO3), 음이온석(Anion), 무기항균제(Antibiotic), 이산화티탄(TiO2), 친환경바인더를 활용한 친환경 도료 및 그 제조방법에 관한 것이다. 상세하게는 본 발명은 제올라이트를 활용한 친환경 건축 도료로서 휘발성 유기물질(VOCs)를 제거하며, 흡착, 탈취, 항균, 항 곰팡이 효과와 온도,습도 조절기능뿐만 아니라 음이온 발생 효과를 발현하는 친환경 도료 및 그 제조방법에 관한 것이다.The present invention relates to an environmentally friendly paint and a method for manufacturing the same, in particular, zeolite, calcium carbonate (CaCO 3 ), anion stone (Anion), inorganic antibacterial (Antibiotic), titanium dioxide (TiO 2 ), environmental binder It relates to an eco-friendly paint used and a method of manufacturing the same. In detail, the present invention removes volatile organic substances (VOCs) as an eco-friendly building paint using zeolite, and is an eco-friendly paint that expresses anion generating effects as well as adsorption, deodorization, antibacterial, antifungal effects and temperature and humidity control functions. It relates to a manufacturing method.

일반적으로 종래의 실내공기 정화방법은 휘발성 유기화합물(VOCs) 제거를 주재로 하여 공기 정화기 등 공기의 순환 및 여과를 통하여 실내 공기의 청정도를 유 지하여 왔다. 그러나 이러한 방법은 단기적으로 효과를 거둘 수 있으나, 소모성 부품의 교체 및 고장 등의 이유로 지속적인 성능발현에 문제점이 있었다. 아울러 에너지의 소모 및 소음의 발생 등의 부가 2차 오염요소가 내재한 방안이었다.In general, the indoor air purification method has maintained the cleanliness of the indoor air through the circulation and filtration of air, such as an air purifier, mainly based on the removal of volatile organic compounds (VOCs). However, this method can be effective in the short term, but there was a problem in continuous performance expression due to replacement and failure of consumable parts. In addition, additional secondary pollution factors such as energy consumption and noise generation were inherent.

또한, 기존의 건축용 내장 도료는 그 자체로서 환경오염 물질을 방출하며, 친환경적인 기능보다는 미려함과 시공성에 대하여 중점을 두어 개발되었다. 그런데 이러한 기존의 건축용 내장 도료에서 방출되는 환경 오염물질은 실내 마감 후 6~12개월 또는 그 이상 실내 거주자에게 나쁜 영향을 주게 되어, 실내 거주자의 두통, 피곤함 등 원인이 규명되지 않는 질병을 유발하는 문제가 발생하고 있었다. 특히, 고분자 유기화합물의 독성은 인체에 미치는 나쁜 영향이 완전히 규명되지 않았지만, 발암 물질 등이 지속적으로 발생하고 있는 문제점이 있다.    In addition, the existing interior paints for building itself emit environmental pollutants, and was developed with emphasis on beauty and workability rather than eco-friendly functions. However, the environmental pollutants emitted from the existing interior paints for buildings have a bad effect on the indoor residents 6-12 months or more after finishing the interior, causing problems such as headaches, tiredness of the indoor residents unidentified cause Was occurring. In particular, the toxicity of the polymer organic compound has not been fully identified a bad effect on the human body, there is a problem that the carcinogens continue to occur.

또한, 종래의 도료 중에는 제올라이트를 사용하여 유기화합물 등 오염물을 제거하는 친환경 용도의 도료는 그 개발이 미진한 상태였다.     In addition, among the conventional paints, the development of environmentally friendly paints for removing contaminants such as organic compounds using zeolites has been underdeveloped.

따라서 본 발명은 상기 문제점을 개선하여 환경오염을 방지하며, 오염된 공기의 질을 향상해 쾌적한 실내 환경을 유지 및 개선하는 건축 내장용 도료의 조성물 및 그 제조방법을 제공하며, 또한 환경 습도 조절로 세균의 번식을 억제하면서 보습기능과 탈취율, 항균, 항 곰팡이 성능이 높은 제올라이트를 활용한 친환경 도료 및 그 제조방법을 제공함에 그 목적이 있다.Accordingly, the present invention improves the above problems to prevent environmental pollution, improves the quality of contaminated air, provides a composition for building interior paint and a method of manufacturing the same, and maintains and improves a comfortable indoor environment. The purpose of the present invention is to provide an eco-friendly paint using the zeolite with high moisturizing function, deodorization rate, antibacterial and antifungal performance while suppressing the growth of bacteria and a method of manufacturing the same.

상기의 목적을 달성하기 위하여 본 발명에 따른 제올라이트를 활용한 친환경 도료는 건축용 도료(Paint)에 있어서, 제올라이트를 포함하는 충전제(filler) 55~65 wt% 및 상기 충전제를 결합시켜주는 바인더(Binder) 수용액 37~45 wt%를 포함하는 것을 특징으로 한다.Eco-friendly paint using the zeolite according to the present invention in order to achieve the above object in the building paint (Paint), 55 to 65 wt% filler containing a zeolite and a binder (Binder) to combine the filler It characterized in that it comprises an aqueous solution 37 ~ 45 wt%.

또한, 상기 충전제는 분말형태의 제올라이트 22~24 wt%, 탄산칼슘 38~47 wt%, 이산화티탄 23~27 wt% 및 음 이온석 8~11 wt%를 포함할 수 있다.In addition, the filler may include 22 to 24 wt% of zeolite in powder form, 38 to 47 wt% of calcium carbonate, 23 to 27 wt% of titanium dioxide, and 8 to 11 wt% of anionic ions.

또한, 상기 충전제는 무기항균제 2~4 wt%;를 더 포함할 수 있다.In addition, the filler may further comprise an inorganic antimicrobial agent 2 ~ 4 wt%.

또한, 상기 친환경 바인더(Binder) 수용액은 친환경 바인더 39~43 wt%, 분산액 0.8~1.2 wt%, 증점액 1.3~1.7 wt%, PH조절제 0.4~0.6 wt%, 소포제 0.8~1.2 wt% 및 희석액 53~58 wt%를 포함할 수 있다.In addition, the environmentally friendly binder (Binder) aqueous solution is an environmentally friendly binder 39 ~ 43 wt%, dispersion 0.8 ~ 1.2 wt%, thickener 1.3 ~ 1.7 wt%, PH regulator 0.4 ~ 0.6 wt%, antifoam 0.8 ~ 1.2 wt% and diluent 53 And 58 wt%.

상기의 목적을 달성하기 위하여 본 발명에 따른 제올라이트를 활용한 친환경 도료의 제조방법은 친환경 도료의 충전제(Filler)를 소정의 혼합방법으로 혼합하는 단계와 pH 조절제와 소포제가 투입된 증점액, 친환경 바인더(Binder), 분산액을 물과 혼합하여 교반하는 단계를 포함하는 친환경 바인더(Binder) 수용액을 제조하는 단계 및 상기 제조된 친환경 도료의 충전제(Filler)와 상기 친환경 바인더(Binder) 수용액을 고속 교반기에 넣고 교반하는 단계를 포함하는 것을 특징으로 한다.In order to achieve the above object, the manufacturing method of the eco-friendly paint using the zeolite according to the present invention comprises the steps of mixing the filler (Filler) of the eco-friendly paint in a predetermined mixing method and a thickener, eco-friendly binder (a pH adjusting agent and an antifoaming agent) Binder), preparing an environmentally friendly binder (Binder) aqueous solution comprising the step of mixing the dispersion with water and stirring and the filler and the environmentally friendly binder (Binder) aqueous solution of the environmentally friendly paint prepared in a high speed stirrer and stirred Characterized in that it comprises a step.

또한, 상기 충전제는 분말형태의 제올라이트 22~24 wt%, 탄산칼슘 38~47 wt%, 이산화티탄 23~27 wt% 및 음 이온석 8~11 wt%를 포함할 수 있다.In addition, the filler may include 22 to 24 wt% of zeolite in powder form, 38 to 47 wt% of calcium carbonate, 23 to 27 wt% of titanium dioxide, and 8 to 11 wt% of anionic ions.

또한, 상기 충전제는 무기항균제 2~4 wt%를 더 포함할 수 있다.In addition, the filler may further comprise 2 to 4 wt% of an inorganic antibacterial agent.

또한, 상기 친환경 바인더(Binder) 수용액은 친환경 바인더 39~43 wt%, 분산액 0.8~1.2 wt%, 증점액 1.3~1.7 wt%, PH조절제 0.4~0.6 wt%, 소포제 0.8~1.2 wt% 및 희석액 53~58 wt%를 포함할 수 있다.In addition, the environmentally friendly binder (Binder) aqueous solution is an environmentally friendly binder 39 ~ 43 wt%, dispersion 0.8 ~ 1.2 wt%, thickener 1.3 ~ 1.7 wt%, PH regulator 0.4 ~ 0.6 wt%, antifoam 0.8 ~ 1.2 wt% and diluent 53 And 58 wt%.

이와 같은 본 발명에 의하면, 공동주택, 실내 벽면의 도장용 도료로서 기존의 화학도료로 인한 실내 공기 오염이 사전에 방지되고, 그 외 내장재, 가구, 벽지에서 발생하는 휘발성 유기화합물이 본 발명에 의해 제거되는 효과와 인체에 유익한 음이온이 다량 방출됨으로써 친환경 실내 공간, 공동주택의 건축문화를 구현할 수 있고, 실내 공기의 질을 향상시킬 수 있으며, 보습기능으로 인간이 거주하기에 적합한 습도를 유치하며 탁월한 흡착력으로 냄새를 제거하고 우수한 항균성으로 곰팡이 등의 세균의 번식을 억제하여 주거환경에 적합하고 쾌적한 실내공간을 제공하는 효과가 있다.According to the present invention, indoor air pollution due to the existing chemical paint is prevented in advance as a coating material for apartment houses, interior walls, and other volatile organic compounds generated in interior materials, furniture, and wallpaper by the present invention. By removing the effect and releasing large amount of negative ions which are beneficial to the human body, it is possible to realize the eco-friendly interior space, the building culture of apartment houses, improve the quality of indoor air, and moisturizing function to attract humidity suitable for human being It has the effect of removing odor by adsorption power and suppressing propagation of bacteria such as mold with excellent antimicrobial properties, providing comfortable indoor space suitable for residential environment.

이하, 본 발명의 바람직한 일 실시예를 도면을 참조하여 상세히 설명한다.Hereinafter, a preferred embodiment of the present invention will be described in detail with reference to the drawings.

도 1은 본 발명에 따른 제올라이트를 활용한 친환경 도료의 제조방법을 나타내는 도면이다. 이는 친환경 도료의 충전제(Filler)를 혼합단계, 친환경인더(Binder) 수용액을 제조단계 및 상기 제조된 친환경 도료의 충전제와 상기 친환경 바인더(Binder) 수용액을 교반하는 단계로 이루어진다. 1 is a view showing a method for manufacturing an environmentally friendly paint using a zeolite according to the present invention. This consists of mixing the filler (eco-friendly) of the environmentally friendly paint, manufacturing an environmentally friendly binder (Binder) aqueous solution, and stirring the prepared environmentally friendly paint and the environmentally friendly binder (Binder) aqueous solution.

좀 더 상세하게는 본 발명에 따른 제올라이트를 활용한 친환경 도료 및 그 제조방법은 친환경 도료의 충전제(Filler)를 소정의 혼합방법으로 혼합하는 단계, pH 조절제와 소포제가 투입된 증점액과 친환경 바인더(Binder), 분산액을 각각 물과 혼합하여 교반하는 단계를 포함하는 친환경인더(Binder) 수용액을 제조하는 단계 및 상기 제조된 친환경 도료의 충전제와 상기 친환경 바인더(Binder) 수용액을 고속 교반기에 넣고 교반하는 단계를 포함한다.More specifically, the eco-friendly paint and its manufacturing method using the zeolite according to the present invention is a step of mixing the filler (Filler) of the eco-friendly paint in a predetermined mixing method, a thickener and an eco-friendly binder (Pinder added pH adjuster and antifoaming agent) ), Preparing an environment-friendly binder (Aqueous solution) solution comprising the step of mixing the dispersion with water, respectively, and stirring and putting the prepared eco-friendly paint filler and the environment-friendly binder (Binder) solution in a high speed stirrer and stirring It includes.

상기 친환경 도료의 충전제는 소정 비율의 제올라이트, 탄산칼슘, 이산화티탄 분말을 포함한다. 또한, 상기 친환경 도료의 충전제에는 소정 비율의 음이온석, 무기항균제가 더 포함할 수 있다. 이하 구체적인 구성요소를 상세히 설명한다.Filler of the environmentally friendly paint comprises a predetermined proportion of zeolite, calcium carbonate, titanium dioxide powder. In addition, the filler of the environmentally friendly paint may further include a predetermined amount of anionic stones and inorganic antibacterial agents. Hereinafter, specific components will be described in detail.

본 발명에의 가장 큰 특징 조성물인 제올라이트(Zeolite)는 알칼리 및 알칼리토금속의 규산알루미늄 수화물(水化物)인 광물로서 비석(沸石)이라고도 한다. 본 발명에 따른 제올라이트의 중요한 종류로는 소다비석, 로몬타이트, 이네사이트, 휼란다이트, 방비석, 어안석, 캐버자이트, 스틸바이트 등이 바람직하다. Zeolite, which is the most characteristic composition of the present invention, is a mineral which is an aluminum silicate hydrate of an alkali and alkaline earth metal, and is also referred to as zeolite. As an important kind of zeolite according to the present invention, soda zeolite, lomontite, eniteite, hulandite, gypsum, fisheye stone, caberzite, steel bite and the like are preferable.

본 발명에 따른 제올라이트는 결정구조적으로 각 원자의 결합이 느슨하여, 그 사이를 채우고 있는 수분을 고열로 방출시켜도 골격은 그대로 있으므로 다른 미립물질을 흡착할 수가 있다. 본 발명에서는 제올라이트의 이러한 흡착성질을 이용해서 공동주택, 실내 벽면의 도장용 도료로서 기존의 화학도료로 인한 실내 공기 오염을 사전에 예방하고, 그 외 내장재, 가구, 벽지에서 발생하는 휘발성 유기화합물을 제거되는 효과가 있다. In the zeolite according to the present invention, the bonds of the atoms are loosely crystallized, and even when the water filling the spaces is released at high heat, the skeleton remains the same, so that other particulates can be adsorbed. In the present invention, by using such adsorbent properties of zeolites to prevent indoor air pollution caused by conventional chemical paints as a coating material for apartment houses, interior walls, and other volatile organic compounds generated from interior materials, furniture, wallpaper It has the effect of being removed.

다음으로 본 발명에 따른 탄산칼슘(calcium carbonate, CaCO3)은 탄산의 칼슘염으로서 자연계에 존재하는 염 중에서 가장 많으며 그 형태도 여러 가지로서 대리석, 방해석, 선석(霰石), 석회석, 백악, 빙주석(氷洲石), 조개껍질, 달걀껍질, 산호 등에서 얻을 수 있다. 특히, 조개껍질을 습식분쇄한 것을 호분(胡粉)이라 하며 호분의 형태로 수성도료에 탄산칼슘을 사용함도 바람직하다. 본 발명에 따른 탄산칼슘은 중화제(中和劑)역할 및 보강제 역할을 한다.Next, calcium carbonate (CaCO 3 ) according to the present invention is the calcium salt of carbonate, which is the most among the salts present in nature, and in various forms, marble, calcite, calcite, limestone, chalk, ice tin ( It can be obtained from stone, shells, egg shells, corals, etc. In particular, the wet grinding of the clam shell is called a whistle (胡 粉) and it is also preferable to use calcium carbonate in the aqueous coating in the form of a whistle. The calcium carbonate according to the present invention serves as a neutralizing agent and a reinforcing agent.

다음으로 본 발명에 따른 이산화티탄(titanium dioxide, TiO2)은 티탄의 산화물로서 티탄산무수물, 티타니아라고도 하며 보통은 산화티탄(Ⅳ)을 말한다. 본 발명에 따른 이산화티탄은 천연으로는 브루카이트, 예추석(銳錐石), 판(板)티탄석, 일메나이트(티탄철석) 등의 광물에서 얻을 수 있다. 본 발명에 따른 이산화티탄은 내산(耐酸)성 및 내알칼리성이 있어서 도료로서 적합하며, 특히 무해(無害)하여 특히 화장품이나 그림물감, 완구의 도료, 식품의 포장용지 등에 사용될 수 있는 천연 도료의 조성물이다. 본 발명에 따른 티탄의 산화물로는 산화티탄(Ⅱ), 산화티탄(Ⅲ), 과산화티탄 등이 사용될 수 있다. 본 발명에 따른 이산화티탄은 다른 조성물과 혼합이 용이하도록 분말형태로 사용함이 바람직하다.Next, titanium dioxide according to the present invention (titanium dioxide, TiO 2 ) is an oxide of titanium, also referred to as titanate anhydride, titania, and usually refers to titanium oxide (IV). Titanium dioxide according to the present invention can be naturally obtained from minerals such as brookite, anatase, flat titaniumite and ilmenite (titanium iron). The titanium dioxide according to the present invention is suitable as a paint because of its acid resistance and alkali resistance, and is particularly harmless, and thus a composition of natural paints that can be used in cosmetics, paints, paints for toys, packaging paper for food, and the like. to be. Titanium (II) oxide, titanium (III) oxide, titanium peroxide, etc. may be used as the oxide of titanium according to the present invention. The titanium dioxide according to the present invention is preferably used in powder form to facilitate mixing with other compositions.

다음으로 음이온석을 설명한다. 음이온석은 육방정계(六方晶系)에 속하는 광물로서 전기석(電氣石, tourmaline)이라고도 한다. 본 발명에 따른 음이온석은 마찰에 의해서 전기가 생기며, 가열하면 양끝이 양,음으로 대전(帶電)하여 음이온을 방출하는 성질이 있다. 본 발명에 따른 음이온석에는 마그네슘이 많은 마그네슘전기석이, 알칼리금속이 많은 알칼리전기석 등이 사용될 수 있다, 특히 알칼리전기석으로는 홍전기석(루벨라이트), 남전기석(인디고라이트), 녹전기석(벨데라이트 또는 브라질에메랄드) 등이 사용될 수 있다. Next, anion stone is demonstrated. Anion stone is a mineral belonging to the hexagonal system (六 方 晶 系), also known as tourmaline (電氣石, tourmaline). The anion stone according to the present invention generates electricity by friction, and when heated, both ends are positively and negatively charged to discharge negative ions. Magnesium tourmaline with a lot of magnesium, alkali tourmaline with a lot of alkali metals, etc. may be used for the anion stone according to the present invention. Or Brazil emerald) may be used.

음이온의 효능으로는 세포의 활성화, 저항력 증진, 혈액정화, 그리고 자율신경에 영향을 주어 교감신경의 흥분을 억제하는 역할을 하게 되며, 또한 사람의 피부 중 전기저항이 낮은 모공으로 들어오는 음이온은 세포를 활성화하고 피로회복, 근육통, 신경통, 혈액장애, 불면증, 만성변비, 내장질환, 성인병, 제한(땀흘림 방지), 혈압강하, 부인병에 효과가 뛰어나며, 기타 주변환경에 미치는 효과로는 공기정화, 탈취, 항균작용, 계면 활성작용 등을 하며, 모든 물질에 대하여 강력한 환원력을 발휘한다. The effects of negative ions affect cell activation, resistance, blood purification, and autonomic nerves, thereby inhibiting the excitability of sympathetic nerves. Also, negative ions entering the pores with low electrical resistance in human skin It is effective in relieving fatigue, muscle pain, neuralgia, blood disorder, insomnia, chronic constipation, visceral disease, adult disease, restriction (preventing sweating), lowering blood pressure, gynecological diseases. It acts as an antibacterial, surfactant, etc., and has strong reducing power against all substances.

본 발명에 따른 음이온석은 인체에 유익한 음이온을 발생시켜 사계절 실내 냄새를 없애주고 실내습도를 조절하여 실내습도가 높으면 흡수하고, 낮으면 발산하는 기능을 가지고 있으므로 흡수력 및 탈취율이 우수한 효과가 있다. 또한 천연소재 그대로 사용하여 환경 친화적인 기능이 있다. 또한, 사람 몸이나 환경 속에서 먼지를 통해 많은 세균이 번식하는 것을 방지하는 우수한 항균 작용을 한다.The anion stone according to the present invention generates an anion beneficial to the human body to eliminate the indoor odor of the four seasons, and to control the indoor humidity to absorb when the indoor humidity is high, and to emit when the humidity is low, so the absorption and deodorization rate is excellent. In addition, using natural materials as it is an environmentally friendly function. In addition, it has an excellent antimicrobial action to prevent the growth of many bacteria through the dust in the human body or environment.

다음으로 무기항균제(Antibiotic)를 설명한다. 무기항균제는 유기항균제와는 달리 고온에서도 안정하며 휘발 및 용출현상이 없기 때문에 항균력이 장시간 지속하는 특성이있다. 제올라이트를 담지체로 하여 제조된 본 발명에 따른 무기항균제는 항균금속이온에 의한 항균작용, 활성산소에 의한 항균작용 및 세라믹에 의한 흡착 항균작용을 수행한다. Next, antibiotic is described. Inorganic antimicrobial agents, unlike organic antimicrobial agents, are stable at high temperatures and do not evaporate or dissolve. Inorganic antimicrobial agent according to the present invention prepared using a zeolite carrier performs antibacterial action by antibacterial metal ions, antibacterial action by active oxygen and adsorption antibacterial action by ceramic.

다음으로 본 발명에 따른 제올라이트를 활용한 친환경 도료 및 그 제조방법의 친환경 바인더(Binder) 수용액을 설명한다.Next, an environmentally friendly binder (Binder) aqueous solution of an eco-friendly paint using the zeolite according to the present invention and a manufacturing method thereof will be described.

친환경 바인더(Binder) 수용액은 pH 조절제와 소포제가 투입된 증점액, 친환경 바인더(Binder), 분산액을 각각 물과 혼합하여 만들어진다.Eco-friendly binder (Binder) aqueous solution is made by mixing the pH adjuster and the antifoaming agent thickener, eco-friendly binder (Binder), and dispersion with water, respectively.

증점액에는 pH 조절제와 소포제가 투입된다. 증점액(viscosity watter)은 액체의 점성을 높이기 위해 증점제를 첨가한 물로서, 일반적인 증점액의 사용이 가능 하며 특히, 하이드록시에탤셀룰로우즈를 사용함이 바람직하다. PH조절제로는 암모니아 등을 사용해도 되며, 특히 2Amino-2methyl-1propanol를 사용함이 가장 바람직하다. 소포제는 유해한 기포를 제거하는 약품으로서 본 발명에서는 지방산을 사용함이 바람직하다.In the thickener, a pH adjuster and an antifoaming agent are added. Viscosity watter (viscosity watter) is a water to which the thickener is added to increase the viscosity of the liquid, it is possible to use a general thickener, in particular, it is preferable to use hydroxy ethal cellulose. Ammonia etc. may be used as a PH regulator, and it is most preferable to use 2Amino-2methyl-1propanol. Antifoaming agent is a drug for removing harmful bubbles, it is preferable to use a fatty acid in the present invention.

친환경 바인더는 결합제 역할을 하는 것으로서 다양한 친환경 바인더를 사용할 수 있으며, 특히 저취형 수성 폴리머 디스퍼젼을 사용하는 것이 가장 바람직하다.The eco-friendly binder may serve as a binder, and various eco-friendly binders may be used, and in particular, it is most preferable to use a low odor type aqueous polymer dispersion.

분산액(suspension)은 액체 속에 고체의 미립자가 분산되어 있는 것으로서 현탁액(懸濁液)이라고도 하며, 도료(塗料)나 먹물 등에서 그 예를 찾아 볼 수 있다. 미립자의 크기는 보통의 광학현미경으로 볼 수 있는 0.1∼10μ 정도이다. 이 정도의 고체 미립자를 액체 속에 장시간 방치하면 침강(沈降)하는데, 그동안에는 비교적 안정상태를 유지한다. 본 발명에서는 일반적인 분산액을 사용해도 되며, 특히 테트라포타슘파이로우포스페이트(Tetra potassium pyrophosphate)를 사용하는 것이 가장 바람직하다.A dispersion is a dispersion of solid fine particles in a liquid, also called a suspension, and examples thereof can be found in paints and ink. The size of the fine particles is about 0.1 to 10 탆, which can be seen with a normal optical microscope. If these solid particles are left in the liquid for a long time, they are precipitated, and in the meantime, they remain relatively stable. In the present invention, a general dispersion may be used, and in particular, tetra potassium pyrophosphate is most preferably used.

이하, 본 발명에 따른 제올라이트를 활용한 친환경 도료 및 그 제조방법의 바람직한 실시예를 설명한다.Hereinafter, a preferred embodiment of an eco-friendly paint using the zeolite according to the present invention and a manufacturing method thereof.

본 발명의 바람직한 실시예에 사용된 구성요소는 아래 표1 내지 표 4에 나타나있다.The components used in the preferred embodiment of the present invention are shown in Tables 1-4 below.

또한, 그 시험 결과는 건자재의 시험, 검사 업무를 수행하는 국가공인 시험연구기관인 한국건자재시험연구원(韓國建資材試驗硏究院, Korea Institute of Construction Materials)에 의뢰하여 얻은 결과로서 표 5 내지 표 8에 나타내었다. In addition, the test results are obtained from the Korea Institute of Construction Materials (National Institute of Construction Materials), a national test and research institute that conducts testing and inspection of construction materials. Shown in

우선, 실시예에 사용된 구성원소와 무게중량(wt%)은 아래와 같다.First, the component and weight (wt%) used in the examples are as follows.

전체 조성물의 구성요소와 무게중량비 Component to Weight Ratio of Total Composition 조성물의 구성요소Components of the Composition wt% wt% 충전제 [充塡劑, filler]Filler [充 塡 劑, filler] 6060 친환경 바인더(Binder) 수용액Eco-friendly binder solution 4040 합계Sum 100 wt% 100 wt%

충전제의 구성요소와 무게중량비Filler Components and Weight to Weight Ratio 충전제의 구성요소Filler Components wt% wt% 제올라이트Zeolite 2323 탄산칼슘 Calcium carbonate 4040 이산화티탄Titanium dioxide 2525 음이온석Anion stone 99 무기항균제Inorganic antimicrobial agents 33 합계Sum 100 wt% 100 wt%

친환경 바인더(Binder) 수용액의 구성요소와 무게중량비Components and Weight-to-Weight Ratio of Environment-friendly Binder Solution 친환경 바인더(Binder) 수용액의 구성요소 Components of Eco-friendly Binder Solution wt% wt% 구체적인 Concrete 실시예Example 친환경 바인더Eco-friendly binder 4141 수성 폴리머 디스퍼젼 (저취형)Aqueous Polymer Dispersion (Low Odor) 분산액Dispersion 1One Tetrapotassium pyrophosphateTetrapotassium pyrophosphate 증점액Thickening 1.51.5 하이드록시에틸 셀룰로우즈Hydroxyethyl cellulose PH조절제PH regulator 0.50.5 2Amino-2methyl -1propanol2Amino-2methyl -1propanol 소포제Antifoam 1One 지방산/실리콘유Fatty acid / silicone oil 희석액diluent 5555 물water 합계Sum 100 wt%  100 wt%

발명에 사용한 재료의 입자크기Particle Size of Materials Used in the Invention 입자크기Particle size 이산화티탄Titanium dioxide 탄산칼슘Calcium carbonate 제올라이트Zeolite 음이온석Anion stone 무기항균제Inorganic antimicrobial agents 최소값Minimum value 60 nm60 nm 1 ㎛1 μm 1 ㎛1 μm 1 ㎛1 μm 2 ㎛2 μm 최대값Value 100 nm100 nm 10 ㎛10 μm 10 ㎛10 μm 7 ㎛7 μm 4 ㎛4 μm

본 발명에서 친환경 도료의 충전제(Filler)로 제올라이트, 탄산칼슘, 이산화티탄, 음이온석, 무기항균제 분말들은 볼밀링법을 이용하여 혼합하였으며, 볼 : 분말의 비는 10:1, 볼밀의 회전 속도는 1500rpm으로 고정하여 30분간 혼합하였다. In the present invention, the zeolite, calcium carbonate, titanium dioxide, anionite, and inorganic antimicrobial powders were mixed using a ball milling method as a filler of environmentally friendly paint, and the ball: powder ratio was 10: 1 and the rotation speed of the ball mill was Fixed at 1500 rpm and mixed for 30 minutes.

그 후 pH 조절제와 소포제를 투입한 증점액, 친환경 바인더(Binder), 분산액을 각각 물과 혼합하고 교반하였다. 이렇게 제조된 친환경 바인더(Bider) 수용액을 충전제(Filler) 분말과 함께 고속 교반기에 넣고 1500rpm으로 30분간 교반하여 친환경 도료를 제조하였다.Then, the thickener, eco-friendly binder, and dispersion into which the pH adjuster and the antifoam were added were mixed with water and stirred. The eco-friendly binder (Bider) aqueous solution thus prepared was put in a high speed stirrer together with the filler (Filler) powder and stirred at 1500 rpm for 30 minutes to prepare an eco-friendly paint.

본 발명에 따른 친환경 도료는 뿜칠과 붓칠로 활용할 수 있도록 농도의 조절을 하였으며, 건조 시간 및 시공 조건인 온, 습도에 따라 발명 효과의 편차를 최소화하고자 최적의 배합조건을 실험을 통하여 획득하였다.Environmentally friendly paint according to the present invention was adjusted to the concentration to be utilized as the spraying and brushing, the optimum mixing conditions were obtained through experiments to minimize the variation of the invention effect according to the drying time and construction conditions, temperature, humidity.

본 발명에 따른 제올라이트를 활용한 친환경 도료를 뿜칠과 붓 칠을 이용하여 도포 두께는 1mm미만의 얇은 표면 도포로 탈취효능, 음이온 발생특성, 항균 및 항 곰팡이 특성, 휘발성 유기화합물 방출 여부에 대한 시험을 실시하여 표 5 내지 표 8의 결과를 얻어내었다.The coating thickness using the zeolite according to the present invention by spraying and brushing the coating thickness is less than 1mm thin surface coating to test the deodorizing effect, anion generation characteristics, antibacterial and anti-fungal properties, volatile organic compounds released It carried out and the result of Table 5-Table 8 was obtained.

본 발명에 따른 시험체의 시간경과에 따른 탈취율Deodorization rate with the passage of time of the test body according to the present invention 경과시간(분)Elapsed time (minutes) 3030 6060 9090 120120 대조실험군 (Blank) 농도(ppm)Control group concentration (ppm) 194194 152152 131131 116116 친환경 도료 농도(ppm)Eco-friendly Paint Concentration (ppm) 2121 1010 77 55 탈 취 율(%)Deodorization rate (%) 89.289.2 93.493.4 94.794.7 95.795.7

표 5에서 볼 수 있듯이 본 발명에 따른 친환경 도료가 대조실험군(Blank)에 비하여 시간의 경과에 따른 탈취율이 상당히 높은 것을 알 수 있다.As can be seen in Table 5, the environmentally friendly paints according to the present invention can be seen that the deodorization rate over time is significantly higher than the control group (Blank).

본 발명에 따른 시험체의 음이온 발생 특성Anion Generation Characteristics of Test Specimens According to the Present Invention 구 분division 대조실험군 (Blank) Control group (Blank) 친환경 도료Eco-friendly paints 음이온 개수 (ION/CC)Anion Count (ION / CC) 7373 939939 비고Remarks 대기중의 음이온 개수 : 73개 (ION/CC)Number of negative ions in the air: 73 (ION / CC)

표 6에서 볼 수 있듯이 본 발명에 따른 친환경 도료를 사용하는 경우 대기중의 음이온의 수나 통상의 도료를 사용한 경우에 비해서 음이온의 발생이 수십배에 이름을 알 수 있다. As can be seen in Table 6, when using an environmentally friendly paint according to the present invention, the name of the generation of negative ions can be seen in several tens of times compared to the number of anions in the air or a conventional paint.

본 발명에 따른 시험체의 항균 및 항 곰팡이 특성Antibacterial and Antifungal Properties of Test Subjects According to the Present Invention 시 험 항 목Test Items 시 험 결 과Test result 초기농도 (CFU/40ppm)Initial concentration (CFU / 40ppm) 24시간 후 농도 (CFU/40ppm)Concentration after 24 hours (CFU / 40ppm) 세균 감소율(%)Bacterial Reduction (%) 대장균에 의한 항균시험Antibacterial test by E. coli 대조실험군(Blank) Control group (Blank) 381381 19261926 증가increase 친환경 도료Eco-friendly paints 381381 1One 99.799.7 녹농균에 의한 항균시험Antibacterial test by Pseudomonas aeruginosa 대조실험군(Blank) Control group (Blank) 400400 20262026 증가increase 친환경 도료Eco-friendly paints 400400 22 99.599.5

시 험 항 목Test Items 항 곰 팡 이 시 험Antifungal test 배 양 시 험 의 기 간Period of culture test 1주후1 week later 2주후after 2 weeks 3주후3 weeks later 4주후4 weeks later 시 험 결 과Test result 00 00 00 00 0 : 시료에서 균의 성장을 인지할 수 없음0: Growth of bacteria is not recognized in the sample

표 7에서 볼 수 있듯이 본 발명에 따른 친환경 도료를 사용하는 경우 대장균에 의한 항균효과나 녹농균에 의한 항균효과가 통상의 도료를 사용한 경우에 비하여 월등함을 알 수 있다.As can be seen in Table 7 when using the eco-friendly paints according to the present invention it can be seen that the antibacterial effect by E. coli or antibacterial effect by Pseudomonas aeruginosa is superior to when using the conventional paint.

본 발명에 따른 시험체의 휘발성 유기화합물 방출 여부 검출 시험Test for detecting the release of volatile organic compounds of the test body according to the present invention 시 험 항 목Test Items 단 위unit 시험결과Test result 휘발성 유기 화합물 (VOCs)Volatile Organic Compounds (VOCs) 아세톤Acetone g/Lg / L 불검출(검출한계 0.01)Not detected (detection limit 0.01) 메탄올Methanol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 메틸에틸케톤Methyl ethyl ketone 불검출(검출한계 0.005)Not detected (detection limit 0.005) 에탄올ethanol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 벤젠benzene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 2-프로판올2-propanol 불검출(검출한계 0.005)Not detected (detection limit 0.005) 메틸이소부틸케톤Methyl Isobutyl Ketone 불검출(검출한계 0.005)Not detected (detection limit 0.005) 이소부탄올Isobutanol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 톨루엔toluene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 아세트산부틸Butyl acetate 불검출(검출한계 0.005)Not detected (detection limit 0.005) 1-부틸알코올1-butyl alcohol 불검출(검출한계 0.01)Not detected (detection limit 0.01) 셀로솔브Cellosolve 불검출(검출한계 0.01)Not detected (detection limit 0.01) o-자이렌o-xylene 불검출(검출한계 0.005)Not detected (detection limit 0.005) m-자이렌m-xylene 불검출(검출한계 0.005)Not detected (detection limit 0.005) p-자이렌p-xylene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 스티렌Styrene 불검출(검출한계 0.005)Not detected (detection limit 0.005) 부틸셀로솔브Butyl Cellosolve 불검출(검출한계 0.01)Not detected (detection limit 0.01) 기타 VOCsOther VOCs 불검출(검출한계 0.005)Not detected (detection limit 0.005)

역시 표 8에 볼 수 있듯이 본 발명에 따른 친환경 도료를 사용하는 경우 휘발성 유기화합물 방출이 되지 않음을 알 수 있다.As can be seen in Table 8, it can be seen that volatile organic compounds are not released when the eco-friendly paint according to the present invention is used.

즉, 본 발명인 제올라이트 및 친환경 바인더를 사용한 실내공기의 질 향상을 위한 친환경 도료에 의하면 탈취율은 최대 95.7%, 음이온은 900개 이상 발생하고, 시공된 건물의 습도가 인간에 적합하게 조절되며, 탁월한 흡착력으로 냄새를 제거하고 우수한 항균성으로 곰팡이 등 세균의 번식을 억제하는 효과가 있는 것으로 밝혀 졌다.That is, according to the eco-friendly paint for improving the quality of the indoor air using the zeolite and eco-friendly binder of the present invention, the deodorization rate is up to 95.7%, more than 900 anions are generated, the humidity of the constructed building is adjusted to be suitable for humans, and excellent adsorption power It was found to have the effect of suppressing the growth of bacteria such as mold by removing odor and excellent antimicrobial activity.

이상에서 설명한 바와 같이 본 발명에 따른 제올라이트를 활용한 친환경 도료 및 그 제조방법에 의하면, 공동주택, 실내 벽면의 도장용 도료로써 기존의 화학도료로 인한 실내 공기 오염을 사전에 예방하고, 그 외 내장재, 가구, 벽지에서 발생하는 휘발성 유기화합물을 본 발명품에 의해 제거되는 효과가 있다.As described above, according to the eco-friendly paint using the zeolite according to the present invention and a method for manufacturing the same, it is possible to prevent indoor air pollution due to the existing chemical paint as a coating material for apartment houses, interior walls, and other interior materials. It is effective to remove volatile organic compounds generated in furniture, wallpaper and wallpaper by the present invention.

또한, 본 발명에 의하면 인체에 유익한 음이온이 다량 방출됨으로 친환경 실내 공간, 공동주택의 건축문화를 구현할 수 있는 장점도 있다.In addition, according to the present invention there is also an advantage that can be implemented environmentally friendly interior space, the building culture of apartment houses by the release of a large amount of negative ions beneficial to the human body.

또한, 본 발명은 제올라이트 및 친환경 바인더를 사용하여 실내 공기의 질을 향상하였고, 보습기능으로 인간이 거주하기에 적합한 습도를 유치하며 탁월한 흡착력으로 냄새를 제거하고 우수한 항균성으로 곰팡이 등의 세균의 번식을 억제하며 우리의 주거환경에 적합하고 쾌적한 실내공간을 제공하는 효과도 있다.In addition, the present invention improves the quality of indoor air by using zeolite and eco-friendly binder, moisturizing function to attract humidity suitable for human dwelling, to remove odor with excellent adsorption power and to proliferate bacteria such as mold with excellent antibacterial activity. It also has the effect of providing a comfortable indoor space that is suitable for our living environment.

Claims (8)

건축용 도료(Paint)에 있어서,In paint for construction, 제올라이트를 포함하는 충전제(filler) 55~65 wt%; 및 55 to 65 wt% of a filler including a zeolite; And 상기 충전제를 결합시켜주는 바인더(Binder) 수용액 37~45 wt%;을 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료.Eco-friendly paint using a zeolite comprising a; 37 to 45 wt% binder solution for bonding the filler. 제 1항에 있어서,The method of claim 1, 상기 충전제는The filler 분말형태의 제올라이트 22~24 wt%;22-24 wt% of zeolite in powder form; 탄산칼슘 38~47 wt%; Calcium carbonate 38-47 wt%; 이산화티탄 23~27 wt%; 및Titanium dioxide 23-27 wt%; And 음 이온석 8~11 wt%;를 포함하여 구성되는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료.Negative ionic stone 8 ~ 11 wt%; Eco-friendly paint using zeolite, characterized in that comprising a. 제 2항에 있어서,The method of claim 2, 상기 충전제는 The filler 무기항균제 2~4 wt%;를 더 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료.Inorganic antimicrobial agent 2 ~ 4 wt%; Eco-friendly paint using zeolite, characterized in that it further comprises. 제 1항 내지 제 3항 중 어느 하나의 항에 있어서,The method according to any one of claims 1 to 3, 상기 친환경 바인더(Binder) 수용액은The environmentally friendly binder (Binder) aqueous solution 친환경 바인더 39~43 wt%;Eco-friendly binder 39-43 wt%; 분산액 0.8~1.2 wt%;Dispersion 0.8-1.2 wt%; 증점액 1.3~1.7 wt%;Thickener 1.3-1.7 wt%; PH조절제 0.4~0.6 wt%;0.4 ~ 0.6 wt% PH regulator; 소포제 0.8~1.2 wt%; 및 Antifoam 0.8-1.2 wt%; And 희석액 53~58 wt%; 를 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료.Diluent 53-58 wt%; Eco-friendly paint using a zeolite, characterized in that it comprises a. 친환경 도료의 충전제(Filler)를 소정의 혼합방법으로 혼합하는 단계;Mixing a filler of an eco-friendly paint by a predetermined mixing method; pH 조절제와 소포제가 투입된 증점액, 친환경 바인더(Binder), 분산액을 물과 혼합하여 교반하는 단계를 포함하는 친환경 바인더(Binder) 수용액을 제조하는 단계; 및 preparing a green binder solution including a step of mixing and mixing a thickener, an environmentally friendly binder, and a dispersion liquid into which a pH adjuster and an antifoam agent are added; And 상기 제조된 친환경 도료의 충전제(Filler)와 상기 친환경 바인더(Binder) 수용액을 고속 교반기에 넣고 교반하는 단계;를 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료의 제조방법.Putting the prepared environmentally friendly paint (Filler) and the environmentally friendly binder (Binder) aqueous solution into a high speed stirrer and stirring; manufacturing method of an environmentally friendly paint using a zeolite comprising a. 제 5항에 있어서,The method of claim 5, 상기 충전제는The filler 분말형태의 제올라이트 22~24 wt%;22-24 wt% of zeolite in powder form; 탄산칼슘 38~47 wt%; Calcium carbonate 38-47 wt%; 이산화티탄 23~27 wt%; 및Titanium dioxide 23-27 wt%; And 음 이온석 8~11 wt%;를 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료의 제조방법.Negative ion stone 8 ~ 11 wt%; Eco-friendly paint production method using a zeolite comprising a. 제 6항에 있어서,The method of claim 6, 상기 충전제는 The filler 무기항균제 2~4 wt%;를 더 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료의 제조방법.Inorganic antimicrobial agent 2 ~ 4 wt%; Eco-friendly coating method using a zeolite, characterized in that it further comprises. 제 5항 내지 제 7항 중 어느 하나의 항에 있어서,The method according to any one of claims 5 to 7, 상기 친환경 바인더(Binder) 수용액은The environmentally friendly binder (Binder) aqueous solution 친환경 바인더 39~43 wt%;Eco-friendly binder 39-43 wt%; 분산액 0.8~1.2 wt%;Dispersion 0.8-1.2 wt%; 증점액 1.3~1.7 wt%;Thickener 1.3-1.7 wt%; PH조절제 0.4~0.6 wt%;0.4 ~ 0.6 wt% PH regulator; 소포제 0.8~1.2 wt%; 및 Antifoam 0.8-1.2 wt%; And 희석액 53~58 wt%; 를 포함하는 것을 특징으로 하는 제올라이트를 활용한 친환경 도료의 제조방법.Diluent 53-58 wt%; Method for producing an environmentally friendly paint using a zeolite, characterized in that it comprises a.
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KR20230119791A (en) 2022-02-08 2023-08-16 김나연 a method manufacturing the zeolite composition for paint

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KR101049885B1 (en) * 2010-09-29 2011-07-19 (주)서일테크씨에프 The construction infrastructure the environment-friendly functional paint
KR20230119791A (en) 2022-02-08 2023-08-16 김나연 a method manufacturing the zeolite composition for paint

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