KR102294159B1 - Watersoluble Fire Proof Paint for Coating - Google Patents
Watersoluble Fire Proof Paint for Coating Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
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- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
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- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C08L35/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
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Abstract
Description
본 발명은 수용성 코팅 불연도료 조성물에 관한 것으로, 보다 상세하게는 실내 공기질을 개선할 뿐만 아니라 불연성능, 내구성, 내충격성, 피도면과의 접착성, 항균성능 및 탈취성능이 우수한, 수용성 코팅 불연도료 조성물에 관한 것이다.The present invention relates to a water-soluble coating non-combustible coating composition, and more particularly, to a water-soluble coating non-combustible coating composition that not only improves indoor air quality but also has excellent non-combustible performance, durability, impact resistance, adhesion to a surface, antibacterial performance and deodorization performance. is about
휘발성 유기화합물(Volatile Organic Compounds, VOC)은 자동차 배기가스와 함께 또 다른 오염물질인 오존을 지속적으로 발생시켜 공기 중 오존 농도를 상승시키는 원인이 된다. 오존은 휘발성 유기화합물이 햇빛과 반응하여 생성되므로 휘발성 유기화합물의 저감 없이는 오존 생성을 억제하기 어려운 상황이다. 이와 같은 휘발성 유기화합물로는 아세트알데히드, 아세틸렌, 벤젠, 부탄, 1,3-부타디엔, 메탄올, 에틸렌, 포름알데히드 등이 있으며, 이는 우리 일상에서 많이 쓰이는 유기용제에 다량 포함되어 있다.Volatile Organic Compounds (VOC) continuously generate ozone, another pollutant, together with automobile exhaust gas, causing the ozone concentration in the air to rise. Ozone is generated by reacting volatile organic compounds with sunlight, so it is difficult to suppress ozone production without reducing volatile organic compounds. Examples of such volatile organic compounds include acetaldehyde, acetylene, benzene, butane, 1,3-butadiene, methanol, ethylene, and formaldehyde, which are contained in large amounts in organic solvents used in our daily lives.
특히, 페인트, 유성도료 등에서 이와 같은 휘발성 유기화합물이 많이 발생하고, 이 중 벤젠, 할로겐화 탄화수소 등 일부는 발암성을 가지고 있으며, 휘발유 등 유류에 다량 함유된 벤젠 및 1,3-부타디엔의 경우에는 백혈병을 유발하기도 한다.In particular, many such volatile organic compounds are generated in paints and oil-based paints, and some of them, such as benzene and halogenated hydrocarbons, have carcinogenic properties. may also cause
이에 환경부는 수도권 대기환경 개선과 친환경 도료의 개발 및 활성화를 조기에 정착시키기 위해 현행 기준을 대폭 강화하였고, 국민 건강을 위한 국토교통부의 실내공기질 관리법에 따른 휘발성 유기화합물, 톨루엔, 포름알데히드의 규제를 강화하고 있다. 따라서 이 기준을 만족하는 환경 친화형 도료가 필요한 상황이다.Accordingly, the Ministry of Environment significantly strengthened the current standards to improve the air quality in the metropolitan area and to establish early development and activation of eco-friendly paints, and enforced regulations on volatile organic compounds, toluene, and formaldehyde in accordance with the Indoor Air Quality Control Act of the Ministry of Land, Infrastructure and Transport for public health. are strengthening Therefore, there is a need for an environmentally friendly paint that satisfies this standard.
한편, 가구 제조나 건물 인테리어 공사에 사용되는 패널(panel)로서 원목을 사용하게 되면, 일반적으로 원가가 상승하게 되고 가공함에 어려움이 발생하게 된다. 따라서 비용 절감이나 자원 재활용 측면에서 파티클 보드(particle board, PB), 파티클 보드 치장판, 중밀도 섬유판재(medium density fibreboard, MDF), 중밀도 섬유판재 치장판, 합판 등의 가공 합성판재에 도장이나 각종 시트류를 본드로 접착하여 사용하게 된다. 그런데, 파티클 보드, 중밀도 섬유판재 및 합판 등을 제조하는 과정에서도 접착제로 본드가 사용되고 있고, 표면처리용 시트를 접착할 때에도 본드를 사용하고 있으므로, 본드에 포함된 휘발성 유기화합물이 방출되어 새집증후군 등과 같은 문제가 발생되고 있다.On the other hand, when solid wood is used as a panel used for furniture manufacturing or building interior construction, the cost is generally increased and difficulty in processing occurs. Therefore, in terms of cost reduction or resource recycling, coating or processing synthetic boards such as particle board (PB), particle board decorative board, medium density fiberboard (MDF), medium density fiber board decorative board, and plywood It is used by bonding various sheets with a bond. However, since bond is used as an adhesive in the process of manufacturing particle board, medium-density fiberboard, and plywood, etc., and when bonding the sheet for surface treatment, the volatile organic compound contained in the bond is released and sick house syndrome Problems such as these are occurring.
따라서, 각 제조업체들은 친환경 접착제 개발 및 친환경 제조방법을 통해 가구 및 건물 인테리어 내장재로 사용되는 PB, PB 치장판, MDF, MDF 치장판, 합판 등의 합성목재를 생산하고 있으나, 친환경 접착제를 사용함에 따라 합성목재의 제조 시, 원가가 상승하는 문제와 생산성이 저하되는 문제점이 대두되고 있다.Therefore, each manufacturer is producing synthetic wood such as PB, PB decorative board, MDF, MDF decorative board, and plywood used as interior materials for furniture and buildings through eco-friendly adhesive development and eco-friendly manufacturing methods. During the manufacture of synthetic wood, a problem of increasing the cost and lowering the productivity is emerging.
대한민국등록특허공보 제10-1141046호(2012.07.11.)에는 친환경 수용성 코팅용 도료 및 이를 사용한 표면 코팅방법이 개시되어 있다.Republic of Korea Patent Publication No. 10-1141046 (2012.07.11.) discloses an eco-friendly water-soluble coating paint and a surface coating method using the same.
상기 친환경 수용성 코팅용 도료는 인체에 유해한 영향을 끼치지 않는 장점이 있지만, 불연 성능이 미흡한 단점이 있다. The eco-friendly water-soluble coating paint has the advantage of not having a harmful effect on the human body, but has a disadvantage in that the non-combustible performance is insufficient.
본 발명의 목적은 실내 공기질을 개선할 뿐만 아니라 불연성능이 우수한, 수용성 코팅 불연도료 조성물을 제공하는 것이다.It is an object of the present invention to provide a water-soluble coating non-combustible coating composition that not only improves indoor air quality but also has excellent non-combustible performance.
본 발명의 다른 목적은 내구성, 내충격성, 피도면과의 접착성, 항균성능 및 탈취성능이 우수한, 수용성 코팅 불연도료 조성물을 제공하는 것이다. Another object of the present invention is to provide a water-soluble coating non-combustible coating composition having excellent durability, impact resistance, adhesion to a surface, antibacterial performance and deodorization performance.
상기 목적을 달성하기 위하여 본 발명은 다음과 같은 수단을 제공한다.In order to achieve the above object, the present invention provides the following means.
본 발명은, 폴리에스테르폴리올 수지 25~30중량%, 폴리카보네이트폴리우레탄 디스퍼젼 20~25중량%, 아크릴레이트 수지 15~20중량%, 아크릴/스티렌 공중합 에멀젼 수지 5~10중량%, 실리카 에어로겔 5~10중량%, 2-프로펜산 나트륨 2-프로펜아마이드 중합체 1~5중량%, 난연제 1~5중량%, 혼합수 20~25중량% 및 첨가제 1~3중량%를 포함하되, 상기 난연제는 적인(Red Phosphorus) 50중량%, 질석 40중량% 및 붕산 10중량%를 포함하며, 상기 혼합수는 바이오세라믹 스톤 정제수 50~60중량%, 플라즈마 처리수 20~30중량% 및 원적외선 처리수 15~25중량%를 포함하며, 상기 바이오세라믹 스톤 정제수는 물 100중량부에 바이오세라믹 스톤 6~10중량부를 넣고 6~8시간 동안 방치한 것을 사용하며, 상기 바이오세라믹 스톤은 진주석 60~70중량%, 견운모 15~25중량% 및 황토 10~20중량%를 포함하는 혼합물을 물에 넣고 혼련한 후 숙성시킨 다음, 1,100~1,200℃의 온도에서 3~4시간 동안 소성시키는, 수용성 코팅 불연도료 조성물을 제공한다. The present invention, polyester polyol resin 25-30% by weight, polycarbonate polyurethane dispersion 20-25% by weight, acrylate resin 15-20% by weight, acrylic / styrene copolymer emulsion resin 5-10% by weight, silica airgel 5 ~10% by weight, sodium 2-propenate 2-propenamide polymer 1-5% by weight, flame retardant 1-5% by weight, mixing water 20-25% by weight, and additives 1-3% by weight, wherein the flame retardant is Contains 50% by weight of Red Phosphorus, 40% by weight of vermiculite, and 10% by weight of boric acid, and the mixed water is bioceramic stone purified water 50-60% by weight, plasma treated water 20-30% by weight, and far-infrared treated water 15~ It contains 25% by weight, and the bioceramic stone purified water is used in which 6-10 parts by weight of bioceramic stones are added to 100 parts by weight of water and left for 6-8 hours, and the bioceramic stones are pearlite 60-70% by weight , a mixture containing 15 to 25% by weight of sericite and 10 to 20% by weight of loess is put in water, kneaded, aged, and then calcined at a temperature of 1,100 to 1,200 ° C. for 3 to 4 hours. A water-soluble coating non-combustible paint composition to provide.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 충격강도증진제 1~5중량부를 추가적으로 포함하되, 상기 충격강도증진제는 스티렌-부타디엔 공중합체 40~50중량%, SIS(Styrene-Isoprene-Styrnene) 30~40중량%, 아크릴로니트릴-부타디엔 고무 10~20중량% 및 클로로프렌 고무 1~5중량%를 포함한다.1 to 5 parts by weight of an impact strength enhancer is additionally included with respect to 100 parts by weight of the water-soluble coating incombustible coating composition, wherein the impact strength enhancer is 40 to 50% by weight of a styrene-butadiene copolymer, 30 to 40 of Styrene-Isoprene-Styrnene (SIS) % by weight, 10 to 20% by weight of acrylonitrile-butadiene rubber, and 1 to 5% by weight of chloroprene rubber.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 접착증진제 1~5중량부를 추가적으로 포함하되, 상기 접착증진제는 칼슘 설포 알루미네이트 40~50중량%, 이산화규소 20~30중량%, 2-하이드록시에틸아크릴레이트 10~20중량%, 2-에틸헥실아크릴레이트 10~20중량% 및 메틸렌 디페닐 디이소시아네이트 1~5중량%를 포함한다.1 to 5 parts by weight of an adhesion promoter based on 100 parts by weight of the water-soluble coating non-combustible coating composition, wherein the adhesion promoter is 40 to 50 wt% of calcium sulfoaluminate, 20 to 30 wt% of silicon dioxide, 2-hydroxyethyl acrylic 10 to 20% by weight of the rate, 10 to 20% by weight of 2-ethylhexyl acrylate, and 1 to 5% by weight of methylene diphenyl diisocyanate.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 난연성향상제 1~5중량부를 추가적으로 포함하되, 상기 난연성향상제는 카르복시메틸셀룰로오스나트륨 30~40중량%, 삼산화안티몬 20~30중량%, 수화알루미늄실리케이트 10~20중량%, 수산화나트륨 10~20중량% 및 수산화마그네슘 1~5중량%를 포함한다. 1 to 5 parts by weight of a flame retardant improver is additionally included with respect to 100 parts by weight of the water-soluble coating non-combustible paint composition, wherein the flame retardant enhancer is 30 to 40 weight % of sodium carboxymethylcellulose, 20 to 30 weight % of antimony trioxide, 10 to 20 hydrated aluminum silicate % by weight, including 10 to 20% by weight of sodium hydroxide and 1 to 5% by weight of magnesium hydroxide.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 항균향상제 1~5중량부를 추가적으로 포함하되, 상기 항균향상제는 단삼발효물 40~50중량%, 어성초발효물 30~40중량%, 일라이트 10~20중량%, 벤토나이트 1~5중량% 및 맥반석 1~5중량%를 포함하며, 상기 단삼발효물은 단삼추출액 100중량부에 유산균 1~5중량부를 첨가하고 20~25℃에서 48~50시간 동안 발효시켜 제조하며, 상기 단삼추출액은 단삼 뿌리 100중량부에 95% 에탄올 800~900중량부를 가하고 4~5시간 동안 가열 환류 추출하고 여과하여 제조하며, 상기 어성초발효물은 어성초추출액 100중량부에 효모 1~5중량부를 첨가하고 40~45℃에서 4~5시간 동안 발효시켜 제조하며, 상기 어성초추출액은 어성초 잎 100중량부에 99% 메탄올 500~600중량부를 가하고 상온에서 12~14시간 동안 교반하여 추출하고 여과하여 제조한다.1 to 5 parts by weight of an antibacterial enhancer is additionally included with respect to 100 parts by weight of the water-soluble coating non-combustible coating composition, wherein the antibacterial enhancer is 40 to 50% by weight of fermented ginseng fermented material, 30 to 40% by weight of fermented Eosongcho ferment, 10 to 20% by weight of Illite %, bentonite 1 to 5% by weight, and elvan stone 1 to 5% by weight, and the fermented ginseng extract is added 1 to 5 parts by weight of lactic acid bacteria to 100 parts by weight of the ginseng extract and fermented at 20 to 25° C. for 48 to 50 hours. Manufactured, the ginseng extract is prepared by adding 800 to 900 parts by weight of 95% ethanol to 100 parts by weight of ginseng root, extracting under reflux for 4 to 5 hours, and filtration, and the fermented eoseongcho extract is yeast 1 to 100 parts by weight of eoseongcho extract It is prepared by adding 5 parts by weight and fermenting at 40 to 45° C. for 4 to 5 hours, and the eoseongcho extract is extracted by adding 500 to 600 parts by weight of 99% methanol to 100 parts by weight of eoseongcho leaves and stirring at room temperature for 12 to 14 hours. It is prepared by filtration.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 탈취향상제 1~5중량부를 추가적으로 포함하되, 상기 탈취향상제는 축분을 발효시킨 축산퇴비분말 50~60중량%, 이산화티탄 25~35중량% 및 목어석 분말 10~20중량%를 포함한다.1 to 5 parts by weight of a deodorant enhancer is additionally included with respect to 100 parts by weight of the water-soluble coating non-combustible coating composition, wherein the deodorization enhancer is 50 to 60% by weight of livestock compost powder fermented with livestock meal, 25 to 35% by weight of titanium dioxide and 10 -20% by weight.
본 발명에 따른 수용성 코팅 불연도료 조성물은 실내 공기질을 개선할 뿐만 아니라 불연성능, 내구성, 내충격성, 피도면과의 접착성, 항균성능 및 탈취성능이 우수한 장점이 있다.The water-soluble coating non-combustible paint composition according to the present invention not only improves indoor air quality, but also has excellent non-combustible performance, durability, impact resistance, adhesion to a surface to be coated, antibacterial performance and deodorizing performance.
이하, 본 발명을 상세히 설명하면 다음과 같다.Hereinafter, the present invention will be described in detail.
먼저, 본 발명에 따른 수용성 코팅 불연도료 조성물을 설명한다.First, the water-soluble coating nonflammable coating composition according to the present invention will be described.
본 발명의 수용성 코팅 불연도료 조성물은, The water-soluble coating nonflammable paint composition of the present invention,
폴리에스테르폴리올 수지 25~30중량%, 폴리카보네이트폴리우레탄 디스퍼젼 20~25중량%, 아크릴레이트 수지 15~20중량%, 아크릴/스티렌 공중합 에멀젼 수지 5~10중량%, 실리카 에어로겔 5~10중량%, 2-프로펜산 나트륨 2-프로펜아마이드 중합체 1~5중량%, 난연제 1~5중량%, 혼합수 20~25중량% 및 첨가제 1~3중량%를 포함한다. 25-30 wt% of polyester polyol resin, 20-25 wt% of polycarbonate polyurethane dispersion, 15-20 wt% of acrylate resin, 5-10 wt% of acrylic/styrene copolymer emulsion resin, 5-10 wt% of silica airgel , 2-propenate sodium 2-propenamide polymer 1-5% by weight, flame retardant 1-5% by weight, mixing water 20-25% by weight, and additives 1-3% by weight.
상기 폴리에스테르폴리올 수지는 3 관능기 이상의 다가알콜과, 카르복실기를 포함하는 산을 축합하여 제조되며, 상기 산의 카르복실기 1 당량당 0.5 내지 10.0 당량의 알콜기를 갖도록 포함될 수 있다. 다가알콜은 트리메틸올프로판, 트리메틸올에탄, 트리메틸올부탄 및 글리세린으로 이루어진 군에서 선택될 수 있으며, 바람직하게는 트리메틸올프로판일 수 있다. 다만, 이에 한정되지 않으며, 산의 카르복실기와 결합가능한 알콜을 모두 포함할 수 있다. 사용되는 산은 바람직하게는 다가산이다. 또한, 이와 같이 축합된 폴리에스테르폴리올 수지는 이소시아네이트기를 포함하는 것이 가장 바람직하다. 또한, 폴리에스테르폴리올 수지는 총 분자량이 1,000 내지 20,000일 수 있으며, 바람직하게는 2,000 내지 5,000 일 수 있다. 또한, 폴리에스테르폴리올 수지는 폴리에스테르폴리올 수지의 총 중량에 대하여 25 내지 45 중량%의 고형분을 포함할 수 있다. 고형분을 25 중량% 미만으로 포함하는 경우 도막을 형성하는데 필요한 경도가 낮아져 부착성 및 내마모성이 떨어지는 문제점이 있으며, 고형분을 45 중량% 초과하여 포함하는 경우에는 점도가 높아 도막의 스프레이 공정시 작업성이 저하되어 균일한 도막이 형성되지 않는 문제점이 있다.The polyester polyol resin is prepared by condensing a polyhydric alcohol having a trifunctional group or more and an acid including a carboxyl group, and may be included to have an alcohol group of 0.5 to 10.0 equivalents per equivalent of the carboxyl group of the acid. The polyhydric alcohol may be selected from the group consisting of trimethylolpropane, trimethylolethane, trimethylolbutane and glycerin, preferably trimethylolpropane. However, the present invention is not limited thereto, and may include all alcohols capable of bonding to a carboxyl group of an acid. The acid used is preferably a polyacid. In addition, it is most preferable that the polyester polyol resin condensed in this way contains an isocyanate group. In addition, the polyester polyol resin may have a total molecular weight of 1,000 to 20,000, preferably 2,000 to 5,000. In addition, the polyester polyol resin may contain a solid content of 25 to 45 wt % based on the total weight of the polyester polyol resin. When the solid content is less than 25 wt%, the hardness required to form a coating film is lowered, and there is a problem in adhesion and abrasion resistance. There is a problem in that a uniform coating film is not formed.
상기 폴리에스테르폴리올 수지는 25~30중량% 포함되는 것이 바람직하며, 25중량% 미만 포함되면 도막형성에 문제가 있고, 30중량% 초과 포함되면 도막에 크랙이 발생하는 문제가 있다.The polyester polyol resin is preferably included in an amount of 25 to 30% by weight, and when it is included in less than 25% by weight, there is a problem in coating film formation, and when it is included in more than 30% by weight, there is a problem in that the coating film is cracked.
상기 폴리카보네이트폴리우레탄 디스퍼젼은 폴리우레탄 수지 내에 카보네이트기를 갖는 화합물을 의미하는 것으로, 수평균 분자량이 5000 ~ 30000이고, 연신율이 300 ~ 800%인 것을 사용한다. 수지의 연신률이 상기 범위 보다 낮을 경우 도막의 경도가 높아져 충격성에 열세하며, 높을 경우 점성이 낮아 내오염성, 내스크래치, 내마모성 등의 물성이 저하될 수 있다. 또한, 수평균 분자량이 5000 미만인 경우 분자간 결합력이 강하지 못하여 충격성, 인장강도 등이 떨어지고, 30000을 초과하는 경우 점도가 너무 높아 도료내 다른 원료와의 혼합이 어렵다. The polycarbonate polyurethane dispersion refers to a compound having a carbonate group in the polyurethane resin, and has a number average molecular weight of 5000 to 30000 and an elongation of 300 to 800%. When the elongation of the resin is lower than the above range, the hardness of the coating film is increased and the impact property is inferior. In addition, when the number average molecular weight is less than 5000, the intermolecular bonding force is not strong, and the impact property and tensile strength are deteriorated.
상기 폴리카보네이트폴리우레탄 디스퍼젼은 20~25중량% 포함되는 것이 바람직하며, 20중량% 미만으로 사용되는 경우에는 도막형성에 문제가 있고, 25중량%를 초과하는 경우에는 도막에 크랙이 발생하는 문제가 있다.The polycarbonate polyurethane dispersion is preferably contained in an amount of 20 to 25% by weight, and when it is used in an amount of less than 20% by weight, there is a problem in coating film formation, and when it exceeds 25% by weight, a crack occurs in the coating film there is
상기 아크릴레이트 수지는 피착면에 대한 부착성을 제공하고 도막의 열 전도율을 최소화하는 역할을 수행한다. The acrylate resin serves to provide adhesion to the adherend and to minimize the thermal conductivity of the coating film.
상기 아크릴레이트 수지는 15~20중량% 포함되는 것이 바람직하며, 15중량% 미만 포함되면 피착면과의 접착력이 저하되는 문제가 있고, 20중량% 초과 포함되면 절연 성능이 떨어지는 문제가 있다. The acrylate resin is preferably included in an amount of 15 to 20% by weight, and when less than 15% by weight is included, there is a problem in that the adhesion with the adherend is lowered, and when it is included in more than 20% by weight, there is a problem in that insulation performance is deteriorated.
상기 아크릴/스티렌 공중합 에멀젼 수지(styrene acrylate emulsion)는 치밀한 조직구조를 가지고 있으며, 그 결합력이 우수하여 피착면에 도포시 쉽게 떨어지지 않는 바인더이다.The acrylic/styrene copolymer emulsion resin (styrene acrylate emulsion) has a dense tissue structure and is a binder that does not easily fall off when applied to an adherend due to its excellent bonding strength.
상기 아크릴/스티렌 공중합 에멀젼 수지는 5~10중량% 포함되는 것이 바람직하며, 5중량% 미만 포함되면 결합력이 떨어지는 문제가 있고, 10중량% 초과 포함되면 불연 성능이 떨어지는 문제가 있다.The acrylic/styrene copolymer emulsion resin is preferably included in 5 to 10% by weight, and when less than 5% by weight is included, there is a problem of poor bonding strength, and when included in more than 10% by weight, there is a problem in that non-combustible performance is deteriorated.
상기 실리카 에어로겔은 장기적으로 도막의 균열이 발생하는 경우에도 우수한 내구성을 나타내는 역할을 수행한다. The silica airgel serves to exhibit excellent durability even when cracks in the coating film occur in the long term.
상기 실리카 에어로겔은 5~10중량% 포함되는 것이 바람직하며, 5중량% 미만 포함되면 내구성이 떨어지는 문제가 있고, 10중량% 초과 포함되면 도장 작업성이 떨어지는 문제가 있다.The silica airgel is preferably contained in an amount of 5 to 10% by weight, and when it is included in less than 5% by weight, there is a problem of poor durability, and when it is included in more than 10% by weight, there is a problem in that the painting workability is deteriorated.
상기 2-프로펜산 나트륨 2-프로펜아마이드 중합체는 실리카 에어로겔과 혼합수가 잘 결합할 수 있도록 하는 역할을 수행한다. The sodium 2-propenate 2-propenamide polymer serves to allow the silica airgel and mixed water to bind well.
상기 2-프로펜산 나트륨 2-프로펜아마이드 중합체는 1~5중량% 포함되는 것이 바람직하며, 1중량% 미만 포함되면 실리카 에어로겔과 혼합수가 잘 결합되지 않는 문제가 있고, 5중량% 초과 포함되면 응집 현상으로 도장 작업성이 떨어지는 문제가 있다. The sodium 2-propenate 2-propenamide polymer is preferably included in an amount of 1 to 5% by weight, and when it is included in less than 1% by weight, there is a problem that the silica airgel and mixed water are not well combined, and when it is included in more than 5% by weight, agglomeration As a result, there is a problem in that the paint workability is deteriorated.
상기 난연제는 1~5중량% 포함되는 것이 바람직하고, 1중량% 미만 포함되면 난연성이 떨어지는 문제가 있고, 5중량% 초과 포함되면 기계적 물성이 떨어지는 문제가 있다.The flame retardant is preferably included in an amount of 1 to 5% by weight, and when it is included in less than 1% by weight, there is a problem in that the flame retardancy is deteriorated, and when it is included in more than 5% by weight, there is a problem in that mechanical properties are deteriorated.
상기 난연제는 적인(Red Phosphorus) 50중량%, 질석 40중량% 및 붕산 10중량%를 포함한다. The flame retardant includes 50% by weight of Red Phosphorus, 40% by weight of vermiculite and 10% by weight of boric acid.
상기 적인은 난연효과가 뛰어나며 시간이 오래 경과한 후에도 난연효과가 감소하지 않는 장점이 있다. 또한, 적인은 독성이 없고 열적으로 안정하다. The red has an advantage in that the flame retardant effect is excellent and the flame retardant effect does not decrease even after a long time has elapsed. In addition, red is non-toxic and thermally stable.
상기 질석은 화재시 팽창함으로써 도막에 공급되는 공기 차단막을 형성하여 강력한 난연작용을 한다.The vermiculite expands in case of fire to form an air barrier that is supplied to the coating film, thereby having a strong flame retardant action.
상기 붕산은 화재시 난연제가 분진으로 이탈되어 날아가는 것을 방지하는 역할을 한다.The boric acid serves to prevent the flame retardant from flying away as dust in case of fire.
상기 혼합수는 바이오세라믹 스톤 정제수 50~60중량%, 플라즈마 처리수 20~30중량% 및 원적외선 처리수 15~25중량%를 포함한다.The mixed water includes 50-60 wt% of bioceramic stone purified water, 20-30 wt% of plasma treated water, and 15-25 wt% of far-infrared treated water.
상기 바이오세라믹 스톤 정제수는 물 100중량부에 바이오세라믹 스톤 6~10중량부를 넣고 6~8시간 동안 방치한 것을 사용한다.The bioceramic stone purified water is used in which 6 to 10 parts by weight of bioceramic stones are added to 100 parts by weight of water and left for 6 to 8 hours.
상기 바이오세라믹 스톤은 진주석 60~70중량%, 견운모 15~25중량% 및 황토 10~20중량%를 포함하는 혼합물을 물에 넣고 혼련한 후 숙성시킨 다음, 1,100~1,200℃의 온도에서 3~4시간 동안 소성시킨다.The bioceramic stone is a mixture containing 60 to 70% by weight of pearlite, 15 to 25% by weight of sericite, and 10 to 20% by weight of loess in water, kneaded and aged, and then 3 to at a temperature of 1,100 to 1,200 ° C. Firing for 4 hours.
상기 플라즈마 처리수는 정제수에 직접 플라즈마를 조사하여 제조한다. The plasma-treated water is prepared by irradiating plasma directly to purified water.
플라즈마는 다양한 이온, 전자, 자유라디칼, 중성입자, 광자 등을 포함하여 창상, 혈전, 멸균 등에 효과가 있다. Plasma contains various ions, electrons, free radicals, neutral particles, photons, etc., and is effective for wounds, blood clots, and sterilization.
정제수 표면에서 이격된 지점에 플라즈마 방전부를 배치하고 정제수에 플라즈마가 방전 조사되게 하며, 이때 정제수의 증발을 방지할 수 있는 수단을 제공하는 것이 바람직하다. 플라즈마 처리시간은 35~40분 일 수 있다.Plasma discharge unit is disposed at a point spaced apart from the surface of purified water and plasma is irradiated to the purified water by electric discharge, and at this time, it is preferable to provide a means for preventing evaporation of purified water. Plasma treatment time may be 35 to 40 minutes.
상기 원적외선 처리수는 물을 원적외선 처리장치로 처리하여 물의 분자구조를 변화시켜 물분자와 수지의 혼합을 빠르게 한다.The far-infrared treated water treats water with a far-infrared treatment device to change the molecular structure of water to speed up mixing of water molecules and resin.
상기 혼합수는 20~25중량% 포함되는 것이 바람직하고, 20중량% 미만 포함되면 도막 형성이 잘 되지 않는 문제가 있고, 25중량% 초과 포함되면 점도 조절이 어려워지는 문제가 있다.The mixing water is preferably included in an amount of 20 to 25% by weight, and when it is included in less than 20% by weight, there is a problem that the coating film is not formed well, and when it is included in more than 25% by weight, there is a problem in that viscosity control becomes difficult.
상기 첨가제는 분산제, 소포제, 증점제, 침강방지제, 계면활성제 및 산화방지제로 구성된 군으로부터 선택되는 어느 하나 이상의 첨가제를 사용할 수 있다.As the additive, any one or more additives selected from the group consisting of a dispersant, an antifoaming agent, a thickener, an anti-settling agent, a surfactant, and an antioxidant may be used.
상기 분산제는 분말 가루를 액체 속에 분산, 현탁시켜 사용할 때 입자가 용제 내에 고르게 분산되도록 하며, 특히 아크릴레이트 수지와 혼합수와의 혼용성을 이루어 작업성을 향상시킬 수 있는 물질을 의미한다. 상기 분산제는 당해 분야에서 통상적으로 사용되는 것이면 제한없이 사용될 수 있다. The dispersing agent refers to a material capable of improving workability by dispersing and suspending powdered powder in a liquid so that the particles are uniformly dispersed in a solvent, and in particular, compatibility with an acrylate resin and mixing water is achieved. The dispersant may be used without limitation as long as it is commonly used in the art.
상기 소포제는 건조도막에 분화구 현상이나 도막을 약하게 하는 등의 표면결함을 일으키는 거품발생을 억제하기 위하여 사용되며, 공기량을 조절하고 기포를 감소시킨다. 이로 인해 품질의 안정성을 확보할 수 있게 되며, 강도를 증진시키는 효과가 있다. The antifoaming agent is used to suppress foaming that causes surface defects such as cratering or weakening of the dry coating film, and controls the amount of air and reduces bubbles. As a result, it is possible to secure the stability of the quality, and there is an effect of increasing the strength.
상기 증점제는 조성물의 점도를 증가시키는 물질을 의미하며, 당해 분야에서 통상적으로 사용되는 것이면 제한없이 사용될 수 있다.The thickener refers to a material that increases the viscosity of the composition, and may be used without limitation as long as it is commonly used in the art.
상기 침강방지제는 수지에 분산된 입자들의 재응집을 방지하여 조성물의 저장안정성을 유지하는 역할을 하는 것으로, 침강방지제는 공지의 침강방지제를 제한없이 사용할 수 있다.The anti-settling agent serves to maintain storage stability of the composition by preventing re-agglomeration of particles dispersed in the resin.
상기 계면활성제는 계면에 흡착하여 표면장력을 감소시킴으로써 유기성 물질과 친수성 물질이 잘 혼합되도록 하는 물질을 의미하며, 당해 분야에서 통상적으로 사용되는 것이면 제한없이 사용될 수 있다. 바람직하게 상기 계면활성제는 폴리옥시에틸렌 알킬아민, 폴리옥시에틸렌 다이아민, 폴리옥시에틸렌 알킬페닐에테르, 폴리옥시에틸렌 알킬에테르, 폴리옥시에틸렌 알킬아릴에테르 및 폴리옥시에틸렌 알킬페닐아릴에테르로 이루어진 군으로부터 선택된 어느 하나 이상일 수 있다. The surfactant means a material that allows the organic material and the hydrophilic material to be well mixed by adsorbing to the interface to reduce the surface tension, and may be used without limitation as long as it is commonly used in the art. Preferably, the surfactant is selected from the group consisting of polyoxyethylene alkylamine, polyoxyethylene diamine, polyoxyethylene alkylphenyl ether, polyoxyethylene alkyl ether, polyoxyethylene alkylaryl ether and polyoxyethylene alkylphenylaryl ether. It may be any one or more.
상기 산화방지제는 2,2-티오비스(4-메틸-6-t-부틸페놀) 또는 2,6-di-t-부틸페놀 중 어느 하나를 사용할 수 있다.The antioxidant may be either 2,2-thiobis(4-methyl-6-t-butylphenol) or 2,6-di-t-butylphenol.
본 발명의 수용성 코팅 불연도료 조성물은,The water-soluble coating nonflammable paint composition of the present invention,
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 충격강도증진제 1~5중량부를 추가적으로 포함할 수 있다.1 to 5 parts by weight of an impact strength enhancer may be additionally included with respect to 100 parts by weight of the water-soluble coating non-combustible coating composition.
상기 충격강도증진제는 스티렌-부타디엔 공중합체 40~50중량%, SIS(Styrene-Isoprene-Styrnene) 30~40중량%, 아크릴로니트릴-부타디엔 고무 10~20중량% 및 클로로프렌 고무 1~5중량%를 포함한다.The impact strength enhancer is styrene-butadiene copolymer 40-50% by weight, SIS (Styrene-Isoprene-Styrnene) 30-40% by weight, acrylonitrile-butadiene rubber 10-20% by weight and chloroprene rubber 1-5% by weight include
상기 스티렌-부타디엔 공중합체 및 SIS는 낮은 온도에서도 유연성을 제공하여 크랙 발생을 감소시키고, 탄성을 증가시켜 내충격성을 향상시키는 효과가 있다.The styrene-butadiene copolymer and SIS provide flexibility even at low temperatures to reduce cracking, and increase elasticity to improve impact resistance.
상기 아크릴로니트릴-부타디엔 고무 및 클로로프렌 고무는 도막의 연성을 향상시켜 도막의 크랙 방지 성능을 향상시키는 효과가 있다.The acrylonitrile-butadiene rubber and chloroprene rubber have the effect of improving the ductility of the coating film to improve the crack prevention performance of the coating film.
본 발명의 수용성 코팅 불연도료 조성물은, The water-soluble coating nonflammable paint composition of the present invention,
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 접착증진제 1~5중량부를 추가적으로 포함할 수 있다.1 to 5 parts by weight of an adhesion promoter may be additionally included with respect to 100 parts by weight of the water-soluble coating nonflammable coating composition.
상기 접착증진제는 칼슘 설포 알루미네이트 40~50중량%, 이산화규소 20~30중량%, 2-하이드록시에틸아크릴레이트 10~20중량%, 2-에틸헥실아크릴레이트 10~20중량% 및 메틸렌 디페닐 디이소시아네이트 1~5중량%를 포함한다.The adhesion promoter is calcium sulfoaluminate 40-50 wt%, silicon dioxide 20-30 wt%, 2-hydroxyethyl acrylate 10-20 wt%, 2-ethylhexyl acrylate 10-20 wt% and methylene diphenyl 1 to 5% by weight of diisocyanate.
상기 접착증진제는 수용성 코팅 불연도료와 피도면과의 접착력을 향상시키는 효과가 있다. The adhesion promoter has an effect of improving the adhesion between the water-soluble coating non-combustible paint and the surface to be coated.
본 발명의 수용성 코팅 불연도료 조성물은, The water-soluble coating nonflammable paint composition of the present invention,
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 난연성향상제 1~5중량부를 추가적으로 포함할 수 있다.1 to 5 parts by weight of a flame retardant improver may be additionally included with respect to 100 parts by weight of the water-soluble coating nonflammable coating composition.
상기 난연성향상제는 카르복시메틸셀룰로오스나트륨 30~40중량%, 삼산화안티몬 20~30중량%, 수화알루미늄실리케이트 10~20중량%, 수산화나트륨 10~20중량% 및 수산화마그네슘 1~5중량%를 포함한다. The flame retardant improving agent includes 30 to 40% by weight of sodium carboxymethylcellulose, 20 to 30% by weight of antimony trioxide, 10 to 20% by weight of hydrated aluminum silicate, 10 to 20% by weight of sodium hydroxide, and 1 to 5% by weight of magnesium hydroxide.
상기 난연성향상제는 수용성 코팅 불연도료의 난연성능을 향상시키는 효과가 있다.The flame retardant improving agent has an effect of improving the flame retardant performance of the water-soluble coating non-combustible paint.
본 발명의 수용성 코팅 불연도료 조성물은, The water-soluble coating nonflammable paint composition of the present invention,
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 항균향상제 1~5중량부를 추가적으로 포함할 수 있다.1 to 5 parts by weight of an antibacterial enhancer may be additionally included with respect to 100 parts by weight of the water-soluble coating nonflammable coating composition.
상기 항균향상제는 단삼발효물 40~50중량%, 어성초발효물 30~40중량%, 일라이트 10~20중량%, 벤토나이트 1~5중량% 및 맥반석 1~5중량%를 포함한다. The antibacterial enhancer comprises 40 to 50% by weight of fermented ginseng fermented material, 30 to 40% by weight of fermented eoseongcho by weight, 10 to 20% by weight of illite, 1 to 5% by weight of bentonite, and 1 to 5% by weight of elvan stone.
상기 단삼발효물은 단삼추출액 100중량부에 유산균 1~5중량부를 첨가하고 20~25℃에서 48~50시간 동안 발효시켜 제조한다.The fermented ginseng extract is prepared by adding 1 to 5 parts by weight of lactic acid bacteria to 100 parts by weight of the ginseng extract and fermenting at 20 to 25° C. for 48 to 50 hours.
상기 단삼추출액은 단삼 뿌리 100중량부에 95% 에탄올 800~900중량부를 가하고 4~5시간 동안 가열 환류 추출하고 여과하여 제조한다.The extract is prepared by adding 800 to 900 parts by weight of 95% ethanol to 100 parts by weight of dandelion root, extracting under reflux heating for 4 to 5 hours, and filtering.
상기 단삼은 인삼의 형태를 닮고 빛깔이 붉어서 단삼이라고 하며, 학명은 Salvia miltiorrhiza BUNGE이다. 단삼의 뿌리는 한약재로 쓰이고, 탄신논과 비타민 E가 함유되어 있으며, 동물실험에서는 말초혈관을 확장시키고 혈압을 내리는 작용이 인정되었다. 약성은 약간 차고 맛이 쓴데, 포도상구균·대장균·티푸스균·결핵균에 항균작용을 한다.The ginseng resembles the shape of ginseng and the color is red, so it is called dansam, and the scientific name is Salvia miltiorrhiza BUNGE. The root of ginseng is used as a herbal medicine and contains tansinnon and vitamin E. In animal experiments, the action of expanding peripheral blood vessels and lowering blood pressure was recognized. It has a slightly cold and bitter taste, and has antibacterial action against Staphylococcus aureus, Escherichia coli, Typhus bacillus, and tuberculosis bacillus.
상기 어성초발효물은 어성초추출액 100중량부에 효모 1~5중량부를 첨가하고 40~45℃에서 4~5시간 동안 발효시켜 제조한다.The fermented eoseongcho is prepared by adding 1-5 parts by weight of yeast to 100 parts by weight of the eoseongcho extract and fermenting it at 40-45° C. for 4-5 hours.
상기 어성초추출액은 어성초 잎 100중량부에 99% 메탄올 500~600중량부를 가하고 상온에서 12~14시간 동안 교반하여 추출하고 여과하여 제조한다.The eoseongcho extract is prepared by adding 500 to 600 parts by weight of 99% methanol to 100 parts by weight of eoseongcho leaves, stirring at room temperature for 12 to 14 hours, extracting and filtration.
상기 효모는 사카로마이세스 루시(Saccharomyces rouxii), 사카로마이세스 세레비시아에(Saccharomyces cereviciae), 사카로마이세스 오비폴미스(Saccharomyces oviformis) 및 사카로마이세스 스테이네리(Saccharomyces steineri)로 이루어진 군에서 선택된 어느 하나를 사용할 수 있다. The yeast is Saccharomyces ruxii ( Saccharomyces rouxii ), Saccharomyces cereviciae ( Saccharomyces cereviciae ), Saccharomyces oviformis ( Saccharomyces oviformis ) and Saccharomyces steineri ( Saccharomyces steineri ) Any one selected from the group may be used.
상기 어성초 (Houttuynia cordata)는 삼백초과(Saururaceae)에 속하는 다년생 초본으로써, 잎과 줄기에서 생선비린내가 난다하여 어성초라 불리게 되었다.The eoseongcho (Houttuynia cordata) is a perennial herb belonging to the family Saururaceae, and it was called eoseongcho because it smells fishy from the leaves and stems.
상기 어성초 추출물은 혈압강하작용과 혈당강하작용, 항균작용, 항바이러스작용, 항염증작용 및 항 알레르기성 작용, 항산화 작용 효과가 있다.The extract of eoseongcho has blood pressure lowering action, blood sugar lowering action, antibacterial action, antiviral action, anti-inflammatory action and antiallergic action, and antioxidant action.
상기 항균향상제는 수용성 코팅 불연도료의 항균성능을 향상시키는 효과가 있다.The antibacterial enhancer has an effect of improving the antibacterial performance of the water-soluble coating non-combustible paint.
본 발명의 수용성 코팅 불연도료 조성물은, The water-soluble coating nonflammable paint composition of the present invention,
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 탈취향상제 1~5중량부를 추가적으로 포함할 수 있다.1 to 5 parts by weight of a deodorizing agent may be additionally included with respect to 100 parts by weight of the water-soluble coating nonflammable coating composition.
상기 탈취향상제는 축분을 발효시킨 축산퇴비분말 50~60중량%, 이산화티탄 25~35중량% 및 목어석 분말 10~20중량%를 포함한다.The deodorizing agent includes 50 to 60% by weight of livestock compost powder fermented with livestock manure, 25 to 35% by weight of titanium dioxide and 10 to 20% by weight of wood fish stone powder.
상기 축분을 발효시킨 축산퇴비분말은 80~100mesh의 크기로 분쇄하여 사용하는 것이 바람직하다. 상기 축분은 우분, 돈분 및 계분 중 어느 하나 이상을 사용할 수 있다.It is preferable to use the livestock compost powder fermented with the livestock meal by pulverizing it to a size of 80-100 mesh. The livestock manure may use any one or more of cow manure, pig manure, and chicken manure.
상기 이산화티탄은 광촉매 효과를 통해 포름알데히드를 비롯한 휘발성 유기화합물(VOCs)을 제거한다. 또한, 광촉매에서 발생하는 슈퍼옥사이드 음이온(O2-)과 히드록시레디칼(-OH)은 박테리아 세포막에 달라붙어 세포막을 파괴해 항균, 살균 효과가 있다. 일반 항균제에 비해 박테리아와 접촉 가능성이 크고 박테리아의 잔해물까지 분해하는 뛰어난 항균 능력이 있다. 광촉매의 산화, 환원반응을 통해 실내에서 발생하는 악취의 원인이 되는 물질을 분해하는 탈취 효과가 있어 공기질을 개선한다. 이는 일반 탈취제에 비해 악취성분의 탈리 현상이 없고 2차 오염 방지와 교체 비용이 없어 경제적이다. 상기 이산화티탄은 표면에 부착된 유기물이나 NOx, SOx, Cl2, NH3 등의 분자들을 광촉매에 의해 발생된 활성산소로 분해하여 자연적으로 소멸하게 하는 셀프클리닝 효과가 있다. The titanium dioxide removes volatile organic compounds (VOCs) including formaldehyde through a photocatalytic effect. In addition, superoxide anion (O 2 - ) and hydroxy radical (-OH) generated from the photocatalyst adhere to the bacterial cell membrane and destroy the cell membrane, thereby having antibacterial and sterilizing effects. Compared to general antibacterial agents, it is more likely to come into contact with bacteria and has excellent antibacterial ability to decompose even the remains of bacteria. It has a deodorizing effect that decomposes substances that cause bad odors generated indoors through oxidation and reduction reactions of photocatalysts, thereby improving air quality. Compared to general deodorants, it is economical because there is no desorption of odor components, and there is no secondary pollution prevention and replacement cost. The titanium dioxide has a self-cleaning effect of decomposing organic substances or molecules such as NOx, SOx, Cl 2 , and NH 3 attached to the surface into active oxygen generated by a photocatalyst to naturally disappear.
상기 목어석은 고대 회목이라고 부르는 직경 3m 이상인 것으로서 히말라야산맥의 고산에서 자란 수령 400년 된 생목이 지각변동이나 지진으로 노목이 된 후 300년 이상을 화산이나 흙에 묻혀 잔재로 만든 매우 귀중한 화산석이다. 옛날부터 전해 내려오는 것으로 청건능시대에 대해 적혀 있는 서적에 의하면 태산남북쪽에서 생산된다고 하였고 본초강목에 의하면 목어석 학명은 태일여량이라고 했으며, 근대에는 1991년 태산산맥에서 지리학자들이 처음으로 목어석을 발견했다. 상기 목어석 분말은 목어석을 40~70mesh의 크기로 분쇄하여 사용하는 것이 바람직하다.The woodfish stone is a very precious volcanic stone made of remnants of more than 300 years after a 400-year-old tree grown in an alpine region of the Himalayas, which is called an ancient woody tree, became old due to a tectonic change or an earthquake. According to a book written about the Qinggeonneung period, it is said that it is produced in the north and south of Taishan. It is preferable to use the wood fish stone powder by pulverizing the wood fish stone to a size of 40 to 70 mesh.
본 발명에 따른 수용성 코팅 불연도료 조성물은 실내 공기질을 개선할 뿐만 아니라 불연성능, 내구성, 내충격성, 피도면과의 접착성, 항균성능 및 탈취성능이 우수한 장점이 있다.The water-soluble coating non-combustible paint composition according to the present invention not only improves indoor air quality, but also has excellent non-combustible performance, durability, impact resistance, adhesion to a surface to be coated, antibacterial performance and deodorizing performance.
또한, 본 발명의 수용성 코팅 불연도료 조성물은 건축물 실내 인테리어에 사용될 수 있을 뿐만 아니라 자동차 내장용 플라스틱에 도장되어 사용될 수 있다.In addition, the water-soluble coating non-combustible paint composition of the present invention can be used not only for the interior of a building, but also can be used by being painted on plastic for the interior of a vehicle.
이하, 실시 예를 통하여 본 발명의 구성 및 효과를 더욱 상세히 설명하고자 한다. 이들 실시 예는 오로지 본 발명을 예시하기 위한 것일 뿐 본 발명의 범위가 이들 실시 예에 의해 제한되는 것은 아니다. Hereinafter, the configuration and effects of the present invention will be described in more detail through examples. These examples are only for illustrating the present invention, and the scope of the present invention is not limited by these examples.
폴리에스테르폴리올 수지 25중량%, 폴리카보네이트폴리우레탄 디스퍼젼 20중량%, 아크릴레이트 수지 15중량%, 아크릴/스티렌 공중합 에멀젼 수지 7중량%, 실리카 에어로겔 5중량%, 2-프로펜산 나트륨 2-프로펜아마이드 중합체 2중량%, 난연제 5중량%, 혼합수 20중량%, 분산제 0.5중량%, 증점제 0.3중량% 및 계면활성제 0.2중량%를 혼합하고 2,000rpm으로 3시간 동안 교반하여 수용성 코팅 불연도료 조성물을 제조하였다. 상기 난연제는 적인(Red Phosphorus) 50중량%, 질석 40중량% 및 붕산 10중량%를 혼합하여 제조하였다. 상기 혼합수는 바이오세라믹 스톤 정제수 50중량%, 플라즈마 처리수 30중량% 및 원적외선 처리수 20중량%를 혼합하여 제조하였다. 상기 바이오세라믹 스톤 정제수는 물 100중량부에 바이오세라믹 스톤 10중량부를 넣고 8시간 동안 방치한 것을 사용하였다. 상기 바이오세라믹 스톤은 진주석 60중량%, 견운모 25중량% 및 황토 15중량%를 포함하는 혼합물을 물에 넣고 혼련한 후 숙성시킨 다음, 1,200℃의 온도에서 4시간 동안 소성시켜 제조하였다.25% by weight of polyester polyol resin, 20% by weight of polycarbonate polyurethane dispersion, 15% by weight of acrylate resin, 7% by weight of acrylic/styrene copolymer emulsion resin, 5% by weight of silica airgel, 2-propene sodium 2-propene 2 wt% of amide polymer, 5 wt% of flame retardant, 20 wt% of mixed water, 0.5 wt% of dispersant, 0.3 wt% of thickener and 0.2 wt% of surfactant were mixed and stirred at 2,000 rpm for 3 hours to prepare a water-soluble coating nonflammable paint composition did. The flame retardant was prepared by mixing 50% by weight of Red Phosphorus, 40% by weight of vermiculite and 10% by weight of boric acid. The mixed water was prepared by mixing 50% by weight of bioceramic stone purified water, 30% by weight of plasma treated water, and 20% by weight of far-infrared treated water. As the bioceramic stone purified water, 10 parts by weight of the bioceramic stone was added to 100 parts by weight of water and left for 8 hours. The bioceramic stone was prepared by putting a mixture containing 60% by weight of pearlite, 25% by weight of sericite, and 15% by weight of loess in water, kneading it, and then calcining at a temperature of 1,200° C. for 4 hours.
[실험예 1][Experimental Example 1]
실시예 1의 수용성 코팅 불연도료 조성물(시편 두께:0.55mm(습도막))에 대하여 흡착시험(KS I 3547:2012)을 실시하였으며, 그 결과는 아래 표 1과 같다. An adsorption test (KS I 3547:2012) was performed on the water-soluble coating non-combustible paint composition of Example 1 (specimen thickness: 0.55 mm (wet film)), and the results are shown in Table 1 below.
(50±2)% R.H.(25.0±0.3)℃
(50±2)% RH
표 1에서 같이, 실시예 1의 수용성 코팅 불연도료 조성물은 흡착율과 적산흡착량에서 건강친화형주택건설기준에 부합하는 결과를 나타냈다.As shown in Table 1, the water-soluble coating non-combustible paint composition of Example 1 showed results that met the health-friendly housing construction standards in terms of adsorption rate and accumulated adsorption amount.
[실험예 2][Experimental Example 2]
실시예 1의 수용성 코팅 불연도료 조성물에 대하여 실내공기질공정시험(환경부고시제2010-24호)을 실시하였으며, 시험 결과를 표 2에 나타내었다.An indoor air quality process test (Ministry of Environment Notification No. 2010-24) was performed on the water-soluble coating non-combustible paint composition of Example 1, and the test results are shown in Table 2.
(TVOC)Total odorous organic compounds
(TVOC)
온도: 24.8~25.2℃
상대습도 49~52%
시료부하율 0.4㎡/㎥
환기횟수 0.5회/h
경화시간 180분Application amount: 302 g/㎡
Temperature: 24.8~25.2℃
Relative Humidity 49~52%
Sample load rate 0.4㎡/㎥
Ventilation frequency 0.5 times/h
Curing time 180 minutes
(검출한계 0.001)non-detection
(detection limit 0.001)
(Formaldehyde)formaldehyde
(Formaldehyde)
표 2에서 같이, 실시예 1의 수용성 코팅 불연도료 조성물은 환경표지기준에 부합하는 결과이다.As shown in Table 2, the water-soluble coating non-combustible paint composition of Example 1 meets the environmental labeling standards.
[실험예 3][Experimental Example 3]
실시예 1의 수용성 코팅 불연도료 조성물에 대하여 4대 중금속시험을 실시하였으며, 시험 결과를 표 3에 나타내었다.Four heavy metal tests were performed on the water-soluble coating nonflammable coating composition of Example 1, and the test results are shown in Table 3.
표 3에서 같이, 실시예 1의 수용성 코팅 불연도료 조성물은 환경표지기준에 부합하는 결과이다.As shown in Table 3, the water-soluble coating non-combustible paint composition of Example 1 meets the environmental labeling standards.
[비교예 1][Comparative Example 1]
폴리우레탄 폴리머 50중량%, 나노세라믹 폴리머 25중량% 및 물 25중량%를 교반하여 수용성 코팅용 도료 조성물을 제조하였다.A coating composition for water-soluble coating was prepared by stirring 50% by weight of a polyurethane polymer, 25% by weight of a nanoceramic polymer, and 25% by weight of water.
[실험예 4][Experimental Example 4]
실시예 1의 수용성 코팅 불연도료 조성물 및 비교예 1의 수용성 코팅용 도료 조성물을 20×20㎝ 철판에 50㎛ 두께로 도포하고 24시간 동안 건조하여 도막을 제조하였다. 상기 도막을 태양광이 비추는 야외에 60일 동안 방치하고, 도막 표면을 관찰하여 그 결과를 표 4에 나타내었다.The water-soluble coating non-combustible coating composition of Example 1 and the water-soluble coating coating composition of Comparative Example 1 were applied to a thickness of 50 μm on a 20×20 cm iron plate and dried for 24 hours to prepare a coating film. The coating film was left outdoors in sunlight for 60 days, and the surface of the coating film was observed, and the results are shown in Table 4.
상기 표 4에서 보는 바와 같이, 실시예 1의 수용성 코팅 불연도료 조성물은 비교예 1의 수용성 코팅용 도료 조성물에 비하여 내구성이 우수한 것을 확인할 수 있다.As shown in Table 4, it can be seen that the water-soluble coating non-combustible coating composition of Example 1 has superior durability compared to the water-soluble coating coating composition of Comparative Example 1.
실시예 1에서 제조한 수용성 코팅 불연도료 조성물 100중량부에 충격강도증진제 5중량부를 혼합하였다.5 parts by weight of an impact strength enhancer was mixed with 100 parts by weight of the water-soluble coating non-combustible coating composition prepared in Example 1.
상기 충격강도증진제는 스티렌-부타디엔 공중합체 50중량%, SIS(Styrene-Isoprene-Styrnene) 30중량%, 아크릴로니트릴-부타디엔 고무 15중량% 및 클로로프렌 고무 5중량%를 혼합하여 제조하였다. The impact strength enhancer was prepared by mixing 50% by weight of a styrene-butadiene copolymer, 30% by weight of Styrene-Isoprene-Styrnene (SIS), 15% by weight of an acrylonitrile-butadiene rubber, and 5% by weight of a chloroprene rubber.
[실험예 5][Experimental Example 5]
실시예 2의 수용성 코팅 불연도료 조성물 및 비교예 1의 수용성 코팅용 도료 조성물을 상온에서 규정화된 시험편에 0.8㎜로 도포하고 3시간 방치한 후, 높이 50㎝에서 500g의 추를 자유낙하시켜 충격을 가한 후, 시료의 상태를 관찰하여 표 5에 나타내었다. The water-soluble coating nonflammable paint composition of Example 2 and the water-soluble coating paint composition of Comparative Example 1 were applied to a standardized test piece at room temperature at 0.8 mm and left for 3 hours, then a 500 g weight was freely dropped from a height of 50 cm to impact After adding, the state of the sample was observed and shown in Table 5.
상기 표 5에서 보는 바와 같이, 실시예 2의 수용성 코팅 불연도료 조성물은 비교예 1의 수용성 코팅용 도료 조성물에 비하여 내충격성이 우수한 것을 알 수 있다.As shown in Table 5, it can be seen that the water-soluble coating nonflammable coating composition of Example 2 has superior impact resistance compared to the water-soluble coating coating composition of Comparative Example 1.
실시예 1에서 제조한 수용성 코팅 불연도료 조성물 100중량부에 접착증진제 5중량부를 혼합하였다.5 parts by weight of an adhesion promoter was mixed with 100 parts by weight of the water-soluble coating nonflammable coating composition prepared in Example 1.
상기 접착증진제는 칼슘 설포 알루미네이트 50중량%, 이산화규소 25중량%, 2-하이드록시에틸아크릴레이트 10중량%, 2-에틸헥실아크릴레이트 10중량% 및 메틸렌 디페닐 디이소시아네이트 5중량%를 혼합하여 제조하였다. The adhesion promoter is a mixture of 50% by weight of calcium sulfoaluminate, 25% by weight of silicon dioxide, 10% by weight of 2-hydroxyethyl acrylate, 10% by weight of 2-ethylhexyl acrylate and 5% by weight of methylene diphenyl diisocyanate. prepared.
[실험예 6][Experimental Example 6]
실시예 3의 수용성 코팅 불연도료 조성물과 비교예 1의 수용성 코팅용 도료 조성물에 대하여 부착강도 시험(KS M ISO 4624: 2007)을 실시하였으며 그 결과를 표 6에 나타내었다.The adhesion strength test (KS M ISO 4624: 2007) was performed on the water-soluble coating nonflammable coating composition of Example 3 and the water-soluble coating coating composition of Comparative Example 1, and the results are shown in Table 6.
(45±5)% R.H.(23±2)℃
(45±5)% RH
표 6에 의하면, 실시예 3의 수용성 코팅 불연도료 조성물은 비교예 1의 수용성 코팅용 도료 조성물에 비하여 부착강도가 우수한 것을 알 수 있다.According to Table 6, it can be seen that the water-soluble coating non-combustible coating composition of Example 3 has superior adhesion strength compared to the water-soluble coating coating composition of Comparative Example 1.
실시예 1에서 제조한 수용성 코팅 불연도료 조성물 100중량부에 대하여 난연성향상제 5중량부를 혼합하였다. 5 parts by weight of the flame retardant improver was mixed with respect to 100 parts by weight of the water-soluble coating non-combustible coating composition prepared in Example 1.
상기 난연성향상제는 카르복시메틸셀룰로오스나트륨 40중량%, 삼산화안티몬 25중량%, 수화알루미늄실리케이트 15중량%, 수산화나트륨 15중량% 및 수산화마그네슘 5중량%를 혼합하여 제조하였다. The flame retardant enhancer was prepared by mixing 40% by weight of sodium carboxymethylcellulose, 25% by weight of antimony trioxide, 15% by weight of hydrated aluminum silicate, 15% by weight of sodium hydroxide and 5% by weight of magnesium hydroxide.
[실험예 7][Experimental Example 7]
실시예 4의 수용성 코팅 불연도료 조성물 및 비교예 1의 수용성 코팅 도료 조성물에 대하여 난연실험을 실시하여 그 결과를 표 7에 나타내었다.The water-soluble coating non-flammable coating composition of Example 4 and the water-soluble coating coating composition of Comparative Example 1 were subjected to a flame retardancy test, and the results are shown in Table 7.
Ds(4min)=0.3
Ds(10min)=4.1Ds(1.5min)=0.3
Ds(4min)=0.3
Ds(10min)=4.1
Ds(4min)=0.36
Ds(10min)=6.5Ds(1.5min)=0.36
Ds(4min)=0.36
Ds(10min)=6.5
Ds(4min)≤150
Ds(10min)≤300Ds(1.5min)≤75
Ds(4min)≤150
Ds(10min)≤300
표 7에 의하면 실시예 4의 수용성 코팅 불연도료 조성물은 비교예 1의 수용성 코팅 도료 조성물에 비해 난연성능이 우수한 것을 확인할 수 있다.According to Table 7, it can be seen that the water-soluble coating non-flammable coating composition of Example 4 has superior flame retardancy compared to the water-soluble coating coating composition of Comparative Example 1.
실시예 1에서 제조한 수용성 코팅 불연도료 조성물 100중량부에 대하여 향균향상제 5중량부를 혼합하였다. 5 parts by weight of an antibacterial agent was mixed with respect to 100 parts by weight of the water-soluble coating nonflammable coating composition prepared in Example 1.
상기 항균향상제는 단삼발효물 50중량%, 어성초발효물 30중량%, 일라이트 10중량%, 벤토나이트 5중량% 및 맥반석 5중량%를 혼합하여 제조하였다. The antibacterial enhancer was prepared by mixing 50% by weight of fermented ginseng fermented material, 30% by weight of fermented eoseongcho ferment, 10% by weight of illite, 5% by weight of bentonite, and 5% by weight of elvan stone.
상기 단삼발효물은 단삼추출액 100중량부에 유산균 5중량부를 첨가하고 25℃에서 48시간 동안 발효시켜 제조하였다. 상기 단삼추출액은 단삼 뿌리 100중량부에 95% 에탄올 800중량부를 가하고 4시간 동안 가열 환류 추출하고 여과하여 제조하였다. 상기 어성초발효물은 어성초추출액 100중량부에 효모 5중량부를 첨가하고 40℃에서 4시간 동안 발효시켜 제조하였다. 상기 어성초추출액은 어성초 잎 100중량부에 99% 메탄올 500중량부를 가하고 상온에서 12시간 동안 교반하여 추출하고 여과하여 제조하였다.The fermented ginseng extract was prepared by adding 5 parts by weight of lactic acid bacteria to 100 parts by weight of the ginseng extract and fermenting at 25° C. for 48 hours. The ginseng extract was prepared by adding 800 parts by weight of 95% ethanol to 100 parts by weight of dandelion root, extracting under reflux heating for 4 hours, and filtering. The fermented eoseongcho was prepared by adding 5 parts by weight of yeast to 100 parts by weight of the eoseongcho extract and fermenting at 40° C. for 4 hours. The eoseongcho extract was prepared by adding 500 parts by weight of 99% methanol to 100 parts by weight of eoseongcho leaves, stirring at room temperature for 12 hours, extracting and filtration.
[실험예 8][Experimental Example 8]
실시예 5의 수용성 코팅 불연도료 조성물을 도장한 시편 및 비교예 1의 수용성 코팅 도료 조성물을 도장한 시편에 박테리아를 첨가하여 24시간 후 박테리아 수를 측정하였다. 박테리아는 황색포도상구균, 대장균, 녹농균, 고초균, 살모넬라균을 사용하였고, 그 결과를 표 8에 나타내었다.Bacteria were added to the specimens coated with the water-soluble coating non-combustible coating composition of Example 5 and the water-soluble coating composition of Comparative Example 1, and the number of bacteria was measured after 24 hours. As bacteria, Staphylococcus aureus, Escherichia coli, Pseudomonas aeruginosa, Bacillus subtilis, and Salmonella were used, and the results are shown in Table 8.
박테리아수early stage
number of bacteria
박테리아 수after 24 hours
number of bacteria
감소율bacteria
decrease rate
박테리아-2: 대장균(Escherichia coli)
박테리아-3: 녹농균(Pseudomonas aeruginosa)
박테리아-4: 고초균(Bacillus subtilis)
박테리아-5: 살모넬라균(Salmonella typhimurium)Bacteria-1: Staphylococcus aureus
Bacteria-2: Escherichia coli
Bacteria-3: Pseudomonas aeruginosa
Bacteria-4: Bacillus subtilis
Bacteria-5: Salmonella typhimurium
표 8에 의하면, 실시예 5의 수용성 코팅 불연도료 조성물은 비교예 1의 수용성 코팅 도료 조성물에 비하여 항균특성이 매우 우수한 것을 알 수 있다.According to Table 8, it can be seen that the water-soluble coating non-combustible coating composition of Example 5 has very excellent antibacterial properties compared to the water-soluble coating coating composition of Comparative Example 1.
실시예 1에서 제조한 수용성 코팅 불연도료 조성물 100중량부에 대하여 탈취향상제 5중량부를 혼합하였다. 5 parts by weight of a deodorizing agent was mixed with respect to 100 parts by weight of the water-soluble coating nonflammable coating composition prepared in Example 1.
상기 탈취향상제는 축분을 발효시킨 축산퇴비분말 55중량%, 이산화티탄 30중량% 및 목어석 분말 15중량%를 혼합하여 제조하였다.The deodorizing agent was prepared by mixing 55% by weight of livestock compost powder fermented with livestock manure, 30% by weight of titanium dioxide and 15% by weight of woodfish powder.
축분 75중량%, 수분조절제 20중량% 및 고초균 5중량%를 발효조에 투입하고, 하루에 한번씩 교반하면서, 지속적으로 공기를 공급하여 60일 동안 발효시켜 축산퇴비를 만들었다. 상기 축분은 우분 70중량%, 돈분 10중량% 및 계분 20중량%를 혼합하여 사용하였다. 상기 수분조절제는 톱밥을 사용하였다. 상기 축산퇴비로부터 수분조절제를 분리하였다. 상기 수분조절제가 분리된 축산퇴비를 건조기에 투입하고 150℃에서 2시간 동안 건조시켰다. 상기 건조기는 내부 교반설비가 부착되어 상기 축산퇴비를 지속적으로 교반시켜 주고, 상기 교반설비에 구비된 교반드럼 외부에 열매유를 이용하여 열을 공급하였다. 건조시 발생되는 수증기를 주기적으로 강제 배출시켰다. 상기 건조된 축산퇴비를 분쇄기를 이용하여 100mesh로 분쇄하여 축산퇴비분말을 만들었다. 상기 목어석 분말은 목어석을 70mesh의 크기로 분쇄하여 사용하였다. Livestock manure 75% by weight, moisture control agent 20% by weight, and Bacillus subtilis 5% by weight were put into the fermenter, and while stirring once a day, air was continuously supplied and fermented for 60 days to make livestock compost. The livestock meal was used by mixing 70% by weight of cow manure, 10% by weight of pig manure, and 20% by weight of chicken manure. Sawdust was used as the moisture control agent. A moisture control agent was separated from the livestock compost. The livestock compost from which the moisture control agent was separated was put into a dryer and dried at 150° C. for 2 hours. The dryer was equipped with an internal stirring facility to continuously stir the livestock compost, and heat was supplied using heat oil to the outside of the stirring drum provided in the stirring facility. Water vapor generated during drying was periodically forced out. The dried livestock compost was pulverized into 100 mesh using a grinder to make livestock compost powder. The wood fish stone powder was used by grinding wood fish stone to a size of 70 mesh.
[실험예 9][Experimental Example 9]
실시예 6에서 제조된 수용성 코팅 불연도료 조성물 및 비교예 1에서 제조된 수용성 코팅 도료 조성물에 대해 시험가스(NH3)에 대한 처리효율(단위: PPM / V)을 측정하고 얻어진 결과를 하기 표 9에 나타내었다. 이때 시험 방법은 공지된 가스검지관법을 사용하였으며, Blank는 시료를 넣지 않은 상태에서 측정한 것이며, 시험편은 40 X 40 X 10 (mm)의 크기로 제작하였다.The treatment efficiency (unit: PPM / V) for the test gas (NH 3 ) was measured for the water-soluble coating non-combustible coating composition prepared in Example 6 and the water-soluble coating coating composition prepared in Comparative Example 1, and the results obtained are shown in Table 9 shown in In this case, the test method used a known gas detection tube method, and the blank was measured without a sample, and the test piece was manufactured in a size of 40 X 40 X 10 (mm).
(분)result time
(minute)
(ppm)Blank concentration
(ppm)
(ppm)sample concentration
(ppm)
(%)deodorization rate
(%)
(분)result time
(minute)
(ppm)Blank concentration
(ppm)
(ppm)sample concentration
(ppm)
(%)deodorization rate
(%)
표 9에 의하면, 실시예 6의 수용성 코팅 불연도료 조성물은 비교예 1의 수용성 코팅 도료 조성물에 비하여 탈취성능이 매우 우수한 것을 알 수 있다.According to Table 9, it can be seen that the water-soluble coating non-combustible coating composition of Example 6 has very excellent deodorization performance compared to the water-soluble coating coating composition of Comparative Example 1.
Claims (6)
상기 난연제는 적인(Red Phosphorus) 50중량%, 질석 40중량% 및 붕산 10중량%를 포함하며,
상기 혼합수는 바이오세라믹 스톤 정제수 50~60중량%, 플라즈마 처리수 20~30중량% 및 원적외선 처리수 15~25중량%를 포함하며,
상기 바이오세라믹 스톤 정제수는 물 100중량부에 바이오세라믹 스톤 6~10중량부를 넣고 6~8시간 동안 방치한 것을 사용하며,
상기 바이오세라믹 스톤은 진주석 60~70중량%, 견운모 15~25중량% 및 황토 10~20중량%를 포함하는 혼합물을 물에 넣고 혼련한 후 숙성시킨 다음, 1,100~1,200℃의 온도에서 3~4시간 동안 소성시키는,
수용성 코팅 불연도료 조성물.
25-30 wt% of polyester polyol resin, 20-25 wt% of polycarbonate polyurethane dispersion, 15-20 wt% of acrylate resin, 5-10 wt% of acrylic/styrene copolymer emulsion resin, 5-10 wt% of silica airgel , 2-propenate sodium 2-propenamide polymer 1-5% by weight, flame retardant 1-5% by weight, mixing water 20-25% by weight, and additives comprising 1 to 3% by weight,
The flame retardant comprises 50% by weight of Red Phosphorus, 40% by weight of vermiculite and 10% by weight of boric acid,
The mixed water contains 50-60 wt% of bioceramic stone purified water, 20-30 wt% of plasma treated water, and 15-25 wt% of far-infrared treated water,
The bioceramic stone purified water uses 6 to 10 parts by weight of bioceramic stones in 100 parts by weight of water and left for 6 to 8 hours,
The bioceramic stone is a mixture containing 60 to 70% by weight of pearlite, 15 to 25% by weight of sericite, and 10 to 20% by weight of ocher in water, kneaded and aged, and then 3 to at a temperature of 1,100 to 1,200 ° C. calcined for 4 hours,
Water-soluble coating nonflammable paint composition.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 충격강도증진제 1~5중량부를 추가적으로 포함하되,
상기 충격강도증진제는 스티렌-부타디엔 공중합체 40~50중량%, SIS(Styrene-Isoprene-Styrnene) 30~40중량%, 아크릴로니트릴-부타디엔 고무 10~20중량% 및 클로로프렌 고무 1~5중량%를 포함하는,
수용성 코팅 불연도료 조성물.
The method of claim 1,
Further comprising 1 to 5 parts by weight of an impact strength enhancer based on 100 parts by weight of the water-soluble coating non-combustible coating composition,
The impact strength enhancer is styrene-butadiene copolymer 40-50% by weight, SIS (Styrene-Isoprene-Styrnene) 30-40% by weight, acrylonitrile-butadiene rubber 10-20% by weight and chloroprene rubber 1-5% by weight containing,
Water-soluble coating nonflammable paint composition.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 접착증진제 1~5중량부를 추가적으로 포함하되,
상기 접착증진제는 칼슘 설포 알루미네이트 40~50중량%, 이산화규소 20~30중량%, 2-하이드록시에틸아크릴레이트 10~20중량%, 2-에틸헥실아크릴레이트 10~20중량% 및 메틸렌 디페닐 디이소시아네이트 1~5중량%를 포함하는,
수용성 코팅 불연도료 조성물.
The method of claim 1,
1 to 5 parts by weight of an adhesion promoter based on 100 parts by weight of the water-soluble coating non-combustible paint composition,
The adhesion promoter is calcium sulfoaluminate 40-50% by weight, silicon dioxide 20-30% by weight, 2-hydroxyethyl acrylate 10-20% by weight, 2-ethylhexyl acrylate 10-20% by weight and methylene diphenyl 1 to 5% by weight of diisocyanate,
Water-soluble coating nonflammable paint composition.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 난연성향상제 1~5중량부를 추가적으로 포함하되,
상기 난연성향상제는 카르복시메틸셀룰로오스나트륨 30~40중량%, 삼산화안티몬 20~30중량%, 수화알루미늄실리케이트 10~20중량%, 수산화나트륨 10~20중량% 및 수산화마그네슘 1~5중량%를 포함하는,
수용성 코팅 불연도료 조성물.
The method of claim 1,
1 to 5 parts by weight of a flame retardant improver based on 100 parts by weight of the water-soluble coating non-combustible paint composition,
The flame retardant improving agent comprises 30-40 wt% of sodium carboxymethylcellulose, 20-30 wt% of antimony trioxide, 10-20 wt% of hydrated aluminum silicate, 10-20 wt% of sodium hydroxide and 1-5 wt% of magnesium hydroxide,
Water-soluble coating nonflammable paint composition.
상기 수용성 코팅 불연도료 조성물 100중량부에 대하여 탈취향상제 1~5중량부를 추가적으로 포함하되,
상기 탈취향상제는 축분을 발효시킨 축산퇴비분말 50~60중량%, 이산화티탄 25~35중량% 및 목어석 분말 10~20중량%를 포함하는,
수용성 코팅 불연도료 조성물.The method of claim 1,
1 to 5 parts by weight of a deodorizing agent additionally included with respect to 100 parts by weight of the water-soluble coating non-combustible paint composition,
The deodorizing agent comprises 50 to 60% by weight of livestock compost powder fermented with livestock manure, 25 to 35% by weight of titanium dioxide, and 10 to 20% by weight of wood fish stone powder,
Water-soluble coating nonflammable paint composition.
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