CN104074099B - A kind of environment-friendly type antibiotic mildew-proof wallpaper - Google Patents

A kind of environment-friendly type antibiotic mildew-proof wallpaper Download PDF

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CN104074099B
CN104074099B CN201410235340.2A CN201410235340A CN104074099B CN 104074099 B CN104074099 B CN 104074099B CN 201410235340 A CN201410235340 A CN 201410235340A CN 104074099 B CN104074099 B CN 104074099B
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mildew
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CN104074099A (en
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吴海军
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Suzhou Suerda Packaging Technology Co ltd
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Taicang Cass Tatum New Materials Co Ltd
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Abstract

The invention provides and give a kind of environment-friendly type antibiotic mildew-proof wallpaper, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, described basic unit is provided with coating layer above, bamboo is provided with above described coating layer, antibiotic layer is provided with above described bamboo, kieselguhr adsorption layer is provided with above described antibiotic layer, described kieselguhr adsorption layer is provided with printed pattern layer, described printed pattern layer coated thereon has mildew resistance coating, be provided with polytetrafluoroethylene floor above described mildew resistance coating, described polytetrafluoroethylene floor is provided with coating layer.The present invention is provided with coating layer, antibiotic layer, bamboo, and triple function makes wallpaper have excellent antibiotic property; The coating layer be provided with, mildew resistance coating, make wallpaper have excellent mildew resistance, and in addition, the kieselguhr adsorption layer be provided with, further enhancing the deodorizing capability of wallpaper, and final wallpaper of the present invention has excellent antibacterial, mildew-resistant, deodoriging properties.

Description

A kind of environment-friendly type antibiotic mildew-proof wallpaper
Technical field
The present invention relates to a kind of environment-friendly type antibiotic mildew-proof wallpaper.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material quite widely.The feature that other house decorative materials multiple such as color is various, pattern enriches because wallpaper has, luxurious style, safety and environmental protection, easy construction, affordable are incomparable, therefore obtain the universal of certain degree at developed countries and regions such as America and Europe, Southeast Asia, Japan.In recent years, China's indoor decorating is persistently overheating, and the wallpaper be once given the cold shoulder has come into parlor, bedroom, hotel, meeting room etc. again with its gorgeous new attitude.
In the past, wallpaper comes into the life of people as just a kind of decorative material, people to its require many ornamental with aesthetic property above, along with the raising of people's living standard, people need to want the wallpaper of high-quality to decorate the life of oneself, and people's other Functional Requirement to wallpaper also gets more and more.
The mildew resistance of wallpaper is a kind of important performance, if wallpaper does not have mildew resistance, so not only can greatly reduce the service life of wallpaper, if wallpaper does not have mildew resistance simultaneously, so can grow various bacterium, the environment of indoor inhabitation is deteriorated.
Along with improving constantly of people's material and cultural life, people for healthy and cleaning problems care and the life seek of the peaceful and comfortable equivalent comfort energy of gracefulness is also being improved day by day.But in the middle of daily life, unavoidable kitchen, toilet, hospital ward, bedroom peculiar smell and the life stink such as tobacco, body sweat, often affect the comfortableness of people's life.Particularly along with the arrival of aging society, the aged person of bed and the person of recuperating increase, and for preventing stench, the demand of environmental protect also increases thereupon, and these all can promote development that is antibacterial, deodorising product undoubtedly.
Wallpaper in the market also has the little of fungicidal properties when possessing antibacterial and deodouring simultaneously, is therefore necessary to develop a kind of environment-friendly type antibiotic mildew-proof wallpaper.
Summary of the invention
Goal of the invention: the object of the invention is to solve the deficiencies in the prior art, provide a kind of environment-friendly type antibiotic mildew-proof wallpaper, this wallpaper also has deodorization.
Technical scheme: in order to realize above object, a kind of environment-friendly type antibiotic mildew-proof wallpaper of the present invention, comprise basic unit, the back side of described basic unit is provided with water proofing property coating, described basic unit is provided with coating layer above, bamboo is provided with above described coating layer, antibiotic layer is provided with above described bamboo, kieselguhr adsorption layer is provided with above described antibiotic layer, described kieselguhr adsorption layer is provided with printed pattern layer, described printed pattern layer coated thereon has mildew resistance coating, polytetrafluoroethylene floor is provided with above described mildew resistance coating, described polytetrafluoroethylene floor is provided with coating layer, described coating layer is made up of the material of following mass percent: PP:30-35 part, sepiolite 5-7 part, zeolite 4-6 part, softener 1-2 part, retention agent 0.3-0.5 part, wet strength agent 1-2 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, sodium Diacetate 0.5-0.8 part, dimethyl fumarate 1-2 part, calcium propionate 0.4-0.6 part, fire retardant 3-4 part, nano titanium oxide 2-3 part, sorbic acid 1-1.5 part, ethanol 5-8 part, remainder is deionized water, and the thickness of described coating layer is 0.1-0.3mm, described antibiotic layer comprises following composition by weight: polyvinyl alcohol 20-22 part, zeolite with carrying silver 0.5-1 part, deionized water 75-80 part, and the thickness of described antibiotic layer is 0.1-0.3mm.Sepiolite is contained in coating layer of the present invention, zeolite, the deodorant such as copper acid methyl cellulose, wherein sepiolite is a kind of fibrous rich-magnesium clay mineral, there is good absorption, fire-retardant, the performance such as high temperature resistant, and itself be environment-protecting asepsis material, the noxious materials such as the ammonia in air can be gone out as deodorant, can also use as fire retardant, zeolite is porous inorganic substances, there is absorption, catalyst and ion exchanging function, there is the premium properties of adsorption of hydrogen sulfide and ammonia, there is good deodorizing effect, a kind of well deodorant of copper acid methyl cellulose, gas permeability is high, effective, deodorizing capability can keep six months, can eliminate completely in 30 minutes the stench of ammonia and hydrogen sulfide, this several deodorant merges use, substantially can stink completely in deodorization chamber * winding paper, include antiseptic and nano titanium oxide, sorbic acid in coating layer of the present invention, nano titanium oxide, sorbic acid have good antibacterial effect all respectively, include sodium Diacetate, dimethyl fumarate, calcium propionate in coating layer, these three kinds of materials all have excellent anti-mold effect, have the zeolite of deodorizing effect simultaneously, and it also has good anti-mold effect simultaneously, meanwhile, coating layer also comprises fire retardant, softener etc., makes the properties of wallpaper more balanced, superior, and the sepiolite in coating layer, except having deodorizing effect, also has good anti-flammability simultaneously, main component in coating layer is PP, but not PVC, can not produce Vinyl Chloride Monomer, environmental protection, other auxiliary agents of employing are also environmental protection toxic effects, the water proofing property coating that the bottom of wallpaper is provided with, the coating layer that topmost is provided with, protects wallpaper further, extends the service life of wallpaper, the present invention is also provided with bamboo, take full advantage of that bamboo-carbon fibre moisture absorption is ventilative, bacteriostasis antibiosis, cool in summer and warm in winter, environmental protection, the feature such as humidity regulation, be provided with antibiotic layer, employed polyvinyl alcohol and zeolite with carrying silver in antibiotic layer, the polyvinyl alcohol under aforementioned proportion and zeolite with carrying silver mixed liquor, have superior anti-microbial property, be provided with polytetrafluoroethylene floor, polytetrafluoroethylene (PTFE) is a kind of excellent environment-friendly type waterproof ventilative material, and wallpaper can be made to have water-proof breathable properties well, the present invention is also provided with mildew resistance coating in addition, adopts natural Flos Caryophylli extract to make mould inhibitor, and anti-mold effect is good simultaneously in environmental protection, makes wallpaper have excellent mildew resistance so further, be provided with kieselguhr adsorption layer, while enhancing the gas permeability of wallpaper, the deodorizing of the wallpaper also strengthened, antibiotic property.
The material of described water proofing property coating is JS water-repellent paint, and coating layer thickness is 0.2-0.4mm.
The material of described basic unit is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth.
The thickness of described bamboo is 0.2-0.4mm.
The thickness of described kieselguhr adsorption layer is 0.1-0.3mm.
What described mildew resistance coating adopted is Flos Caryophylli extract, and thickness is 0.05-0.1mm.
The thickness of described polytetrafluoroethylene floor is 0.2-0.3mm.
Described coating layer is polyethylene film, and thickness is 0.2-0.4mm.Polyethylene has excellent moisture resistance, makes the moisture resistance of wallpaper more superior.
Described softener is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is shitosan, and fire retardant is magnesium hydroxide.Used various reagents ratios comparatively environmental protection, the heavy metal prohibitted the use not containing national regulation.
Described Flos Caryophylli extract is after soaking 7-8h in ethanol cloves being positioned over 80%, more obtained after aseptic filtration, and the concentration of obtained Flos Caryophylli extract is 100-400mg/mL.
Beneficial effect: environment-friendly type antibiotic mildew-proof wallpaper provided by the invention compared with prior art, has the following advantages:
1, wallpaper of the present invention, is provided with coating layer, antibiotic layer, bamboo, and these three layers all have antibiotic property, and triple function makes wallpaper of the present invention have excellent antibiotic property; The coating layer be provided with, mildew resistance coating, all have mildew resistance, makes wallpaper of the present invention have excellent mildew resistance, in addition, the kieselguhr adsorption layer be provided with, further enhancing the deodorizing capability of wallpaper, and final wallpaper of the present invention has excellent antibacterial, mildew-resistant, deodoriging properties;
2, wallpaper of the present invention, is provided with the reagent such as fire retardant, softener at coating layer, makes the overall performance comparative superiority of wallpaper;
3, the water proofing property coating, the coating layer that are provided with of the present invention, protects wallpaper further, extends the service life of wallpaper;
4, the present invention has been provided with polytetrafluoroethylene floor, and polytetrafluoroethylene (PTFE) is a kind of excellent environment-friendly type waterproof ventilative material, and wallpaper can be made to have water-proof breathable properties well; Coating layer also has moisture resistance simultaneously; Make wallpaper of the present invention have excellent moisture resistance and gas permeability like this, the moisture resistance of wallpaper and good permeability, can wallpaper be avoided further to go mouldy, strengthen antibacterial, the mildew resistance of wallpaper to a certain extent;
5, the reagent environmental protection of each layer use of the present invention, meet the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer, also can not cause secondary pollution;
6, while wallpaper of the present invention has well antibacterial, mildew-resistant, deodorizing, also having good moisture resistance, is the multi-functional wallpaper of a environmental type on the whole.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention;
In figure: 1-water proofing property coating, 2-basic unit, 3-coating layer, 4-bamboo, 5-antibiotic layer, 6-kieselguhr adsorption layer, 7-printed pattern layer, 8-mildew resistance coating, 9-polytetrafluoroethylene floor, 10-coating layer.
Detailed description of the invention
Below in conjunction with specific embodiment, the present invention is described in detail; but illustrate that protection scope of the present invention is not limited to the concrete scope of the present embodiment simultaneously; based on the embodiment in the present invention; those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
embodiment 1
A kind of environment-friendly type antibiotic mildew-proof wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with bamboo 4 above, described bamboo 4 is provided with antibiotic layer 5 above, described antibiotic layer 5 is provided with kieselguhr adsorption layer 6 above, described kieselguhr adsorption layer 6 is provided with printed pattern layer 7, described printed pattern layer 7 coated thereon has mildew resistance coating 8, described mildew resistance coating 8 is provided with polytetrafluoroethylene floor 9 above, and described polytetrafluoroethylene floor 9 is provided with coating layer 10.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.2mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:30 part, sepiolite 5 parts, 4 parts, zeolite, softener stearic acid triethanolamine ester quaternary 1 part, retention agent guar gum 0.3 part, wet strength agent PAE resin 1 part, copper acid methyl cellulose 2 parts, antiseptic shitosan 4 parts, sodium Diacetate 0.5 part, dimethyl fumarate 1 part, calcium propionate 0.4 part, fire retardant magnesium hydroxide 3 parts, nano titanium oxide 2 parts, sorbic acid 1 part, ethanol 5 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.3mm;
The thickness of described bamboo 4 is 0.2mm;
Described antibiotic layer 5 comprises following composition by weight: polyvinyl alcohol 20 parts, zeolite with carrying silver 0.5 part, deionized water 75 parts, zeolite with carrying silver preparation method in described antibiotic layer 5 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7, 70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times, coating fluid in antibiotic layer 5 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution, the thickness of described antibiotic layer 5 is 0.3mm,
The thickness of described kieselguhr adsorption layer 6 is 0.1mm;
What described mildew resistance coating 8 adopted is Flos Caryophylli extract, and described Flos Caryophylli extract is after soaking 7-8h in ethanol cloves being positioned over 80%, more obtained after aseptic filtration, and the concentration of obtained Flos Caryophylli extract is 100-400mg/mL; Thickness is 0.06mm;
The thickness of described polytetrafluoroethylene floor 9 is 0.2mm;
Described coating layer 10 is polyethylene film, and thickness is 0.2mm.
embodiment 2
A kind of environment-friendly type antibiotic mildew-proof wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with bamboo 4 above, described bamboo 4 is provided with antibiotic layer 5 above, described antibiotic layer 5 is provided with kieselguhr adsorption layer 6 above, described kieselguhr adsorption layer 6 is provided with printed pattern layer 7, described printed pattern layer 7 coated thereon has mildew resistance coating 8, described mildew resistance coating 8 is provided with polytetrafluoroethylene floor 9 above, and described polytetrafluoroethylene floor 9 is provided with coating layer 10.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.3mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:33 part, sepiolite 6 parts, 5 parts, zeolite, softener stearic acid triethanolamine ester quaternary 1.5 parts, retention agent guar gum 0.4 part, wet strength agent PAE resin 1.5 parts, copper acid methyl cellulose 2.4 parts, antiseptic shitosan 4.6 parts, sodium Diacetate 0.7 part, dimethyl fumarate 1.5 parts, calcium propionate 0.5 part, fire retardant magnesium hydroxide 3.5 parts, nano titanium oxide 2.5 parts, sorbic acid 1.2 parts, ethanol 6 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.2mm;
The thickness of described bamboo 4 is 0.3mm;
Described antibiotic layer 5 comprises following composition by weight: polyvinyl alcohol 21 parts, zeolite with carrying silver 0.8 part, deionized water 78 parts, zeolite with carrying silver preparation method in described antibiotic layer 5 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7, 70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times, coating fluid in antibiotic layer 5 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution, the thickness of described antibiotic layer 5 is 0.2mm,
The thickness of described kieselguhr adsorption layer 6 is 0.2mm;
What described mildew resistance coating 8 adopted is Flos Caryophylli extract, and described Flos Caryophylli extract is after soaking 7-8h in ethanol cloves being positioned over 80%, more obtained after aseptic filtration, and the concentration of obtained Flos Caryophylli extract is 100-400mg/mL; Thickness is 0.08mm;
The thickness of described polytetrafluoroethylene floor 9 is 0.25mm;
Described coating layer 10 is polyethylene film, and thickness is 0.3mm.
embodiment 3
A kind of environment-friendly type antibiotic mildew-proof wallpaper, comprise basic unit 2, the back side of described basic unit 2 is provided with water proofing property coating 1, described basic unit 2 is provided with coating layer 3 above, described coating layer 3 is provided with bamboo 4 above, described bamboo 4 is provided with antibiotic layer 5 above, described antibiotic layer 5 is provided with kieselguhr adsorption layer 6 above, described kieselguhr adsorption layer 6 is provided with printed pattern layer 7, described printed pattern layer 7 coated thereon has mildew resistance coating 8, described mildew resistance coating 8 is provided with polytetrafluoroethylene floor 9 above, and described polytetrafluoroethylene floor 9 is provided with coating layer 10.
The material of described water proofing property coating 1 is JS water-repellent paint, and coating layer thickness is 0.4mm;
The material of described basic unit 2 is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth;
Described coating layer 3 is made up of the material of following mass percent: PP:35 part, sepiolite 7 parts, 6 parts, zeolite, softener stearic acid triethanolamine ester quaternary 2 parts, retention agent guar gum 0.5 part, wet strength agent PAE resin 2 parts, copper acid methyl cellulose 3 parts, antiseptic shitosan 5 parts, sodium Diacetate 0.8 part, dimethyl fumarate 2 parts, calcium propionate 0.6 part, fire retardant magnesium hydroxide 4 parts, nano titanium oxide 3 parts, sorbic acid 1.5 parts, ethanol 8 parts, remainder is deionized water, and the thickness of described coating layer 3 is 0.1mm;
The thickness of described bamboo 4 is 0.4mm;
Described antibiotic layer 5 comprises following composition by weight: polyvinyl alcohol 22 parts, zeolite with carrying silver 1 part, deionized water 80 parts, zeolite with carrying silver preparation method in described antibiotic layer 5 is: the AgNO3 crystal accurately taking about 4.2g, 0.1mol/L is diluted to by deionized water dissolving, stand-by, and then the zeolite taking about 10g is scattered in the AgNO3 of 100mL0.1mol/L, dust technology adjust pH is to about 7, 70 DEG C of Water Tank with Temp.-controlled heating, and stir, then lucifuge reacts 2-3h at this temperature, reaction terminates rear decompress filter and is separated, the filter cake obtained spends deionized water and is drying to obtain required zeolite with carrying silver for several times, coating fluid in antibiotic layer 5 is mainly first even by polyvinyl alcohol dissolution with deionized water, and then obtained zeolite with carrying silver is put into stirring and dissolving in poly-vinyl alcohol solution, the thickness of described antibiotic layer 5 is 0.1mm,
The thickness of described kieselguhr adsorption layer 6 is 0.3mm;
What described mildew resistance coating 8 adopted is Flos Caryophylli extract, and described Flos Caryophylli extract is after soaking 7-8h in ethanol cloves being positioned over 80%, more obtained after aseptic filtration, and the concentration of obtained Flos Caryophylli extract is 100-400mg/mL; Thickness is 0.1mm;
The thickness of described polytetrafluoroethylene floor 9 is 0.3mm;
Described coating layer 10 is polyethylene film, and thickness is 0.4mm.
The manufacture craft of the wallpaper of example wallpaper routinely time above-mentioned, through paste producing, coating, drying, printing, foaming, embossing, cooling, trimming, rolling.
The wallpaper obtained according to above-described embodiment meets the regulation of GB18585-2001, the heavy metal antimony, arsenic, barium, cadmium, chromium, lead, mercury, the selenium that prohibit the use not containing national regulation, not containing formaldehyde, not containing Vinyl Chloride Monomer, while wallpaper of the present invention has good antibacterial and mouldproof, be the multi-functional wallpaper of a environmental type on the whole.
Above-described embodiment, only for technical conceive of the present invention and feature are described, its objective is to allow and is familiar with these those skilled in the art and can understands content of the present invention and implement according to this, can not limit the scope of the invention with this.All equivalents done by Spirit Essence of the present invention or modification, all should be encompassed within protection scope of the present invention.

Claims (10)

1. an environment-friendly type antibiotic mildew-proof wallpaper, it is characterized in that: comprise basic unit (2), the back side of described basic unit (2) is provided with water proofing property coating (1), described basic unit (2) is provided with coating layer (3) above, described coating layer (3) is provided with bamboo (4) above, described bamboo (4) is provided with antibiotic layer (5) above, described antibiotic layer (5) is provided with kieselguhr adsorption layer (6) above, described kieselguhr adsorption layer (6) is provided with printed pattern layer (7), described printed pattern layer (7) coated thereon has mildew resistance coating (8), described mildew resistance coating (8) is provided with polytetrafluoroethylene floor (9) above, described polytetrafluoroethylene floor (9) is provided with coating layer (10), described coating layer (3) is made up of the material of following composition by weight: PP:30-35 part, sepiolite 5-7 part, zeolite 4-6 part, softener 1-2 part, retention agent 0.3-0.5 part, wet strength agent 1-2 part, copper acid methyl cellulose 2-3 part, antiseptic 4-5 part, sodium Diacetate 0.5-0.8 part, dimethyl fumarate 1-2 part, calcium propionate 0.4-0.6 part, fire retardant 3-4 part, nano titanium oxide 2-3 part, sorbic acid 1-1.5 part, ethanol 5-8 part, remainder is deionized water, and the thickness of described coating layer (3) is 0.1-0.3mm, described antibiotic layer (5) comprises following composition by weight: polyvinyl alcohol 20-22 part, zeolite with carrying silver 0.5-1 part, deionized water 75-80 part, and the thickness of described antibiotic layer (5) is 0.1-0.3mm.
2. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: the material of described water proofing property coating (1) is JS water-repellent paint, and coating layer thickness is 0.2-0.4mm.
3. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: the material of described basic unit (2) is nonwoven fabric, pure cotton cloth, chemical fabric or blended cloth.
4. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: the thickness of described bamboo (4) is 0.2-0.4mm.
5. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: the thickness of described kieselguhr adsorption layer (6) is 0.1-0.3mm.
6. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: what described mildew resistance coating (8) adopted is Flos Caryophylli extract, and thickness is 0.05-0.1mm.
7. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: the thickness of described polytetrafluoroethylene floor (9) is 0.2-0.3mm.
8. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: described coating layer (10) is polyethylene film, and thickness is 0.2-0.4mm.
9. environment-friendly type antibiotic mildew-proof wallpaper according to claim 1, is characterized in that: described softener is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, and wet strength agent is PAE resin, and antiseptic is shitosan, and fire retardant is magnesium hydroxide.
10. environment-friendly type antibiotic mildew-proof wallpaper according to claim 6, it is characterized in that: described Flos Caryophylli extract is that cloves to be positioned over mass percent be after soaking 7-8h in the ethanol of 80%, obtained after aseptic filtration again, the concentration of obtained Flos Caryophylli extract is 100-400mg/mL.
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JP2001123398A (en) * 1999-10-20 2001-05-08 Hakubi Kagaku Kk Wallpaper
CN102864692A (en) * 2012-09-18 2013-01-09 昆山帝豪装饰设计有限公司 Protective wallpaper
CN102953513A (en) * 2012-11-21 2013-03-06 吴江杰杰织造有限公司 Diatomite wallpaper
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