CN106079763A - A kind of wallpaper containing white bamboo carbon fiber - Google Patents

A kind of wallpaper containing white bamboo carbon fiber Download PDF

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Publication number
CN106079763A
CN106079763A CN201610443302.5A CN201610443302A CN106079763A CN 106079763 A CN106079763 A CN 106079763A CN 201610443302 A CN201610443302 A CN 201610443302A CN 106079763 A CN106079763 A CN 106079763A
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layer
white bamboo
bamboo carbon
antibacterial
carbon fiber
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钱学东
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Individual
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/12—Layered products comprising a layer of synthetic resin next to a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • B32B5/08—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer the fibres or filaments of a layer being of different substances, e.g. conjugate fibres, mixture of different fibres
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/02—Homopolymers or copolymers of unsaturated alcohols
    • C08L29/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/02—Coating on the layer surface on fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2255/00—Coating on the layer surface
    • B32B2255/28—Multiple coating on one surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/06—Vegetal fibres
    • B32B2262/062—Cellulose fibres, e.g. cotton
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/106—Carbon fibres, e.g. graphite fibres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/14—Mixture of at least two fibres made of different materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/40—Properties of the layers or laminate having particular optical properties
    • B32B2307/402—Coloured
    • B32B2307/4026—Coloured within the layer by addition of a colorant, e.g. pigments, dyes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/73—Hydrophobic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00—Walls, panels
    • B32B2607/02—Wall papers, wall coverings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Laminated Bodies (AREA)

Abstract

The invention discloses a kind of wallpaper containing white bamboo carbon fiber, including white bamboo, the back side of described white bamboo is provided with waterproof mildew-resistant layer, described white bamboo be arranged above with antibacterial and deodouring layer, described antibacterial and deodouring layer is arranged above with cotton/chitin/white bamboo carbon blend fibre layer, described cotton/chitin/white bamboo carbon blend fibre layer is provided with printed pattern layer, and described printed pattern layer coated thereon has antibacterial and mouldproof layer, described antibacterial and mouldproof layer to be provided with coating layer.The wallpaper safety and environmental protection of the present invention, cheap, economic and practical, there is good mildew-resistant, antibacterial, moisture absorbing and deodorizing, there is promotion and use value.

Description

A kind of wallpaper containing white bamboo carbon fiber
Technical field
The present invention relates to a kind of wallpaper, a kind of wallpaper containing white bamboo carbon fiber.
Background technology
Wallpaper, also referred to as wallpaper, it is a kind of application house decorative material the most widely.Because it is many that wallpaper has color Other house decorative materials multiple such as sample, pattern are abundant, luxurious style, safety and environmental protection, easy construction, affordable cannot compare The feature intended, therefore obtain considerable degree of universal at developed countries and regions such as America and Europe, Southeast Asia, Japan.In recent years, China room Interior trim finishing is persistently overheating, the wallpaper that had once been given the cold shoulder with its gorgeous new attitude again come into parlor, bedroom, hotel, Meeting room etc..
In the past, wallpaper comes into the life of people as just a kind of decorative material, and it is required many in dicoration by people Above aesthetic property, along with the raising of people's living standard, people need the wallpaper wanting high-quality to decorate the life of oneself, people Other Functional Requirement of wallpaper is also got more and more.
The environment of human living is the significant problem that present society is extremely paid close attention to.In recent years at the construction quality being exposed by the media In problem, body of wall condensation is gone mouldy and is had become as one of hot issue, and especially China southern Jiangsu, Shanghai one carries, and is in north subtropical Moistening monsoon climate, the most all can have plum rains season, and plum rain season temperature height, high humidity, air pressure are low, and indoor moisture is dark, ventilates In the case of poor, can inevitably grow various mycete, according to investigations, between June to November, there is the resident of half in Shanghai There is Signs of Mould in house, and therefore this is accomplished by the wallpaper mildew resistance to be had for interior decoration, on the one hand can extend wall Paper service life in wet environment, another convenient protection body of wall, it is to avoid body of wall has wallpaper mouldy, and then avoids the taste of antibacterial Raw, the environment of the indoor inhabitation of protection, protection resident's is healthy.
Along with improving constantly of people's material and cultural life, people are for the healthy and care of cleaning problems and to gracefulness The life of peaceful and comfortable equivalent comfort energy is pursued and is also day by day being improved.But, in the middle of daily life, it is impossible to the kitchen avoided, health Between, hospital ward, bedroom abnormal flavour and the life stink such as Nicotiana tabacum L., body antiperspirant, often affect the comfortableness of people's life.Particularly Increase along with the arrival of aging society, the aged person of bed and the person of recuperating, for preventing stench, improving the demand of environment also Increasing therewith, these are desirable that the wallpaper as interior decoration needs to have the functions such as antibacterial, deodorization undoubtedly.
White bamboo carbon fiber is the one in bamboo carbon fiber, has stronger moisture absorbing and deodorizing, purifies air, antibacterial, antibacterial, anti- The functions such as ultraviolet, current white bamboo carbon fiber is mainly used in field of textiles, there is no application on wallpaper.
Therefore, it is necessary to develop a kind of white bamboo carbon fiber wallpaper with performances such as antibacterial, deodorization, mildew-resistant.
Summary of the invention
Goal of the invention: the invention aims to solve the deficiencies in the prior art, it is provided that a kind of containing white bamboo carbon fiber Wallpaper.
Technical scheme: in order to realize object above, the present invention is by the following technical solutions.
A kind of wallpaper containing white bamboo carbon fiber, including white bamboo, the back side of described white bamboo is provided with Waterproof mildew-resistant layer, described white bamboo be arranged above with antibacterial and deodouring layer, described antibacterial and deodouring layer is arranged above with cotton/carapace Element/white bamboo carbon blend fibre layer, described cotton/chitin/white bamboo carbon blend fibre layer is provided with printed pattern layer, described printing pressure Flower layer coated thereon has antibacterial and mouldproof layer, described antibacterial and mouldproof layer to be provided with coating layer；Described waterproof mildew-resistant layer is by following quality The material composition of percentage ratio: modified polyvinylalcohol: 30-35 part, sodium alginate: 6-8 part, 3-iodo-2-propynyl butylamino first Acid esters: 5-7 part, halloysite nanotubes: 4-6 part, silicone acrylic emulsion: 20-22 part, deionized water: 30-35 part；Described antibacterial and mouldproof Layer is made up of the material of following mass percent: modified polyvinylalcohol: 20-22 part, zeolite with carrying silver: 0.5-1 part, chitosan: 4-5 Part, calcium lignosulfonate: 4-5 part, camphor leaf extract: 10-15 part, DDAC: 1-1.5 part, pectin with Sodium lactate compound: 4-5 part, deionized water: 75-80 part.
Preferably, cotton fiber/chitin fiber/white bamboo carbon in described cotton/chitin/white bamboo carbon blend fibre layer The weight ratio of fiber is 2/2/1.Cotton/chitin/white bamboo carbon blend fibre is by the cotton fiber of environmental protection, chitin fiber, white Bamboo carbon fiber carries out blending so that it is have cooperative effect, finally makes the blend fibre of three have the moisture absorbing and sweat releasing of excellence, resist The functions such as bacterium, deodorization, uvioresistant.
Preferably, described pectin and sodium lactate compound are 5mg/mL hawthorn pectin oligosaccharide and 10mg/mL lactic acid Compound.
Preferably, described antibacterial and deodouring layer is made up of the material of following mass percent: PE:80-90 part, diatom Soil: 6-8 part, activated carbon: 6-8 part, chitosan: 4-5 part, Hinokitiol: 4-5 part, glass fibre: 4-6 part, organo montmorillonite: 4-6 Part, octaphenyl eight silsesquioxane: 1-2 part, carbon fiber: 1-2 part, PPS:2-4 part, dimethyl fumarate: 1-2 part, meerschaum: 5-7 part, sorbic acid: 1-1.5 part, softening agent: 1-2 part, retention agent: 0.3-0.5 part, wet strength agent: 1-2 part, ethanol: 5-8 part, goes Ionized water: 30-35 part.
As further preferred scheme, the thickness of described antibacterial and deodouring layer is 0.1-0.3mm；
As further preferred scheme, described softening agent is stearic acid triethanolamine ester quaternary, and retention agent is guar gum, wet by force Agent is PAE resin.
As further preferred scheme, described organo montmorillonite is 3-hexadecane epoxide-2-hydroxypropyl trimethyl chlorination The organo montmorillonite that ammonium is modified.
As further preferred version, the preparation method of described organo montmorillonite is: by the inorganic illiteracy that mass ratio is 1:1 De-soil and 3-hexadecane epoxide-2-trimethyl ammonium chloride are dissolved in the ethanol water that mass fraction is 50%, mixing Uniformly post-heating is to 75 DEG C, reacts 1 hour, filters, filter cake ethanol purge, is drying to obtain described organo montmorillonite.
Wherein: the ethanol water that the inorganic montmorillonite of 1g needs 15-20ml mass fraction to be 50%.
Preferably, the thickness of described waterproof mildew-resistant layer is 0.2-0.4mm.
Preferably, the thickness of described antibacterial and mouldproof layer is 0.1-0.3mm.
Preferably, halloysite nanotubes pipe range is 0.5-1.5 μm.
Preferably, described modified polyvinylalcohol is citric acid-modified polyvinyl alcohol, and its preparation method is: according to matter Amount number meter, by 9-11 part polyvinyl alcohol, 0.1-0.3 part citric acid, 0.5-1.5 part glycerol, 88-90 part deionized water, 95 At DEG C constant temperature stir 3 hours, then deaerate under-0.1 MPa 1 h, finally at 60 DEG C be dried 3 h i.e. obtain described modification gather Vinyl alcohol.
Preferably, the preparation method of described camphor leaf extract is as follows: Folium cinnamomi camphorae powder is positioned over quality and divides In the ethanol water of several 60%, insulated and stirred 2-3 hour at 55 DEG C, then to filter, filter residue, filtrate is in 55 DEG C of decompressions Distilling and i.e. obtain described camphor leaf extract, during extraction, Folium cinnamomi camphorae powder is V ethanol with the solid-liquid ratio of ethanol water: m tree Leaf=16: 1.
Preferably, the thickness of described cotton/chitin/white bamboo carbon blend fibre layer is 0.1-0.3mm.
Preferably, described coating layer is polyethylene film, and thickness is 0.2-0.4mm.Polyethylene has excellent Moisture resistance so that the moisture resistance of wallpaper is the most superior.
The above-mentioned silicone acrylic emulsion used of the present invention uses commercially available, and can be such as that Nantong is raw reaches the limited public affairs of chemical industry The SD-528 silicone acrylic emulsion that department produces.
Beneficial effect: compared with prior art, the present invention has a following significance beneficial effect:
1, the wallpaper of the present invention, uses white bamboo carbon fiber to do wallpaper basic unit, makes wallpaper have excellent moisture absorbing and deodorizing, purify sky The functions such as gas, antibacterial, antibacterial, uvioresistant, the most additional cotton/chitin/white bamboo carbon blend fibre layer, further enhancing The moisture absorbing and sweat releasing of wallpaper, antibacterial, deodorization functions, be simultaneously provided with waterproof mildew-resistant layer, antibacterial and deodouring layer, antibacterial and mouldproof layer, multiple Ensure the antimildew and antibacterial of wallpaper, made the wallpaper environmental protection of the present invention, economy, it is adaptable to hygrothermal environment has used；It is additionally provided with and covers Film layer protects wallpaper further, extends the service life of wallpaper；
2, the reagent environmental protection that each layer of the present invention uses, meets the regulation of GB18585-2001, does not contains the taboo of national regulation Only the heavy metal antimony of use, arsenic, barium, cadmium, chromium, lead, hydrargyrum, selenium, do not contain formaldehyde, do not contain Vinyl Chloride Monomer, do not result in yet Secondary pollution；
In a word, the wallpaper of the present invention is a mildew-resistant, moisture absorbing and deodorizing, antibacterial, fire-retardant, moistureproof multi-functional environment-protection green wallpaper, There is promotion and use value.
Accompanying drawing explanation
Fig. 1 is the structural representation of the embodiment of the present invention；
In figure: 1-waterproof mildew-resistant layer, the white bamboo of 2-, 3-antibacterial and deodouring layer, 4-cotton/chitin/white bamboo carbon blend fibre Layer, 5--printed pattern layer, 6-antibacterial and mouldproof layer, 7-coating layer.
Detailed description of the invention
Below in conjunction with embodiment, technical solution of the present invention is described in further detail and completely.
Embodiment 1
A kind of wallpaper containing white bamboo carbon fiber, including white bamboo 2, the back side of described white bamboo 2 is provided with anti- Water mildew-resistant layer 1, described white bamboo 2 be arranged above with antibacterial and deodouring layer 3, described antibacterial and deodouring layer 3 is arranged above with cotton/first Shell element/white bamboo carbon blend fibre layer 4, described cotton/chitin/white bamboo carbon blend fibre layer 4 is provided with printed pattern layer 5, described Printed pattern layer 5 coated thereon has antibacterial and mouldproof layer 6, described antibacterial and mouldproof layer 6 to be provided with coating layer 7.
Wherein:
Waterproof mildew-resistant layer 1 is made up of the material of following mass percent: modified polyvinylalcohol: 30 parts, sodium alginate: 6 parts, 3- Iodo-2-propynyl butyl carbamate: 5 parts, halloysite nanotubes: 4 parts, silicone acrylic emulsion: 20 parts, deionized water: 30 parts；Anti- The thickness of water mildew-resistant layer 1 is 0.2mm.
Antibacterial and deodouring layer 3 is made up of the material of following mass percent: PE:80 part, kieselguhr: 6 parts, activated carbon: 6 parts, Chitosan: 4 parts, Hinokitiol: 4 parts, glass fibre: 4 parts, organo montmorillonite: 4 parts, octaphenyl eight silsesquioxane: 1 part, carbon is fine Dimension: 1 part, PPS:2 part, dimethyl fumarate: 1 part, meerschaum: 5 parts, sorbic acid: 1 part, softening agent: triethanolamine stearate Ester quat: 1 part, retention agent: guar gum: 0.3 part, wet strength agent: PAE resin: 1 part, ethanol: 5 parts, deionized water: 30 parts；Anti- The thickness of bacterium deodorizing layer 3 is 0.3mm.
The thickness of cotton/chitin/white bamboo carbon blend fibre layer 4 is 0.1mm.
Antibacterial and mouldproof layer 6 is made up of the material of following mass percent: modified polyvinylalcohol: 20 parts, zeolite with carrying silver: 0.5 Part, chitosan: 4 parts, calcium lignosulfonate: 4 parts, camphor leaf extract: 10 parts, DDAC: 1 part, pectin With sodium lactate compound, 4 parts, deionized water: 75 parts；The thickness of antibacterial and mouldproof layer 6 is 0.1mm.
Coating layer 7 is polyethylene film, and thickness is 0.2mm.
Embodiment 2
A kind of wallpaper containing white bamboo carbon fiber, including white bamboo 2, the back side of described white bamboo 2 is provided with anti- Water mildew-resistant layer 2, described white bamboo 2 be arranged above with antibacterial and deodouring layer 3, described antibacterial and deodouring layer 3 is arranged above with cotton/first Shell element/white bamboo carbon blend fibre layer 4, described cotton/chitin/white bamboo carbon blend fibre layer 4 is provided with printed pattern layer 5, described Printed pattern layer 5 coated thereon has antibacterial and mouldproof layer 6, described antibacterial and mouldproof layer 6 to be provided with coating layer 7.
Wherein:
Waterproof mildew-resistant layer 2 is made up of the material of following mass percent: modified polyvinylalcohol: 33 parts, sodium alginate: 7 parts, 3- Iodo-2-propynyl butyl carbamate: 6 parts, halloysite nanotubes: 5 parts, silicone acrylic emulsion: 21 parts, deionized water: 33 parts；Anti- The thickness of water mildew-resistant layer 2 is 0.3mm.
Antibacterial and deodouring layer 3 is made up of the material of following mass percent: PE:85 part, kieselguhr: 7 parts, activated carbon: 7 parts, Chitosan: 4.5 parts, Hinokitiol: 4.5 parts, glass fibre: 5 parts, organo montmorillonite: 5 parts, octaphenyl eight silsesquioxane: 1.5 Part, carbon fiber: 1.5 parts, PPS:3 part, dimethyl fumarate: 1.5 parts, meerschaum: 6 parts, sorbic acid: 1.3 parts, softening agent: hard Fat acid triethanol amine ester quat: 1.5 parts, retention agent: guar gum: 0.4 part, wet strength agent: PAE resin: 1-.5 part, ethanol: 6.5 Part, deionized water: 33 parts；The thickness of antibacterial and deodouring layer 3 is 0.2mm.
The thickness of cotton/chitin/white bamboo carbon blend fibre layer 4 is 0.2mm.
Antibacterial and mouldproof layer 6 is made up of the material of following mass percent: modified polyvinylalcohol: 21 parts, zeolite with carrying silver: 0.8 Part, chitosan: 4.5 parts, calcium lignosulfonate: 4.5 parts, camphor leaf extract: 13 parts, DDAC: 1.3 Part, pectin and sodium lactate compound: 4.5 parts, deionized water: 780 parts；The thickness of antibacterial and mouldproof layer 6 is 0.2mm.
Coating layer 7 is polyethylene film, and thickness is 0.3mm.
Embodiment 3
A kind of wallpaper containing white bamboo carbon fiber, including white bamboo 2, the back side of described white bamboo 2 is provided with anti- Water mildew-resistant layer 2, described white bamboo 2 be arranged above with antibacterial and deodouring layer 3, described antibacterial and deodouring layer 3 is arranged above with cotton/first Shell element/white bamboo carbon blend fibre layer 4, described cotton/chitin/white bamboo carbon blend fibre layer 4 is provided with printed pattern layer 5, described Printed pattern layer 5 coated thereon has antibacterial and mouldproof layer 6, described antibacterial and mouldproof layer 6 to be provided with coating layer 7.
Wherein:
Waterproof mildew-resistant layer 2 is made up of the material of following mass percent: modified polyvinylalcohol: 35 parts, sodium alginate: 8 parts, 3- Iodo-2-propynyl butyl carbamate: 7 parts, halloysite nanotubes: 6 parts, silicone acrylic emulsion: 22 parts, deionized water: 35 Part；The thickness of waterproof mildew-resistant layer 2 is 0.4mm.
Antibacterial and deodouring layer 3 is made up of the material of following mass percent: PE:90 part, kieselguhr: 8 parts, activated carbon: 8 Part, chitosan: 5 parts, Hinokitiol: 5 parts, glass fibre: 6 parts, organo montmorillonite: 6 parts, octaphenyl eight silsesquioxane: 2 parts, carbon fiber: 2 parts, PPS:4 part, dimethyl fumarate: 2 parts, meerschaum: 7 parts, sorbic acid: 1.5 parts, softening agent: Stearic acid triethanolamine ester quaternary: 2 parts, retention agent: guar gum: 0.5 part, wet strength agent: PAE resin: 2 parts, ethanol: 8 Part, deionized water: 35 parts；The thickness of antibacterial and deodouring layer 3 is 0.3mm.
The thickness of cotton/chitin/white bamboo carbon blend fibre layer 4 is 0.3mm.
Antibacterial and mouldproof layer 6 is made up of the material of following mass percent: modified polyvinylalcohol: 22 parts, zeolite with carrying silver: 1 Part, chitosan: 5 parts, calcium lignosulfonate: 5 parts, camphor leaf extract: 15 parts, DDAC: 1.5 Part, pectin and sodium lactate compound: 5 parts, deionized water: 80 parts；The thickness of antibacterial and mouldproof layer 6 is 0.3mm.
Coating layer 7 is polyethylene film, and thickness is 0.4mm.
Cotton/chitin in above-described embodiment/white bamboo carbon blend fibre is by cotton fiber, chitin fiber, white bamboo charcoal fibre Dimension carries out blending according to weight ratio 2/2/1 and obtains.
Modified polyvinylalcohol in above-described embodiment, is to be prepared via a method which and obtain: according to mass fraction meter, by 10 Part polyvinyl alcohol, 0.2 part of citric acid, 1 part of glycerol, 89 parts of deionized waters, at 95 DEG C, constant temperature stirs 3 hours, then-0.1 Deaerate under MPa 1 h, is finally dried 3 h at 60 DEG C and i.e. obtains described modified polyvinylalcohol.
Camphor leaf extract in above-described embodiment, is to be prepared via a method which and obtain: be positioned over by Folium cinnamomi camphorae powder In the ethanol water of mass fraction 60%, insulated and stirred 2-3 hour at 55 DEG C, then to filter, filter residue, filtrate is in 55 DEG C decompression distill and is i.e. obtained described camphor leaf extract, and during extraction, the solid-liquid ratio of Folium cinnamomi camphorae powder and ethanol water is V second Alcohol: m leaves=16: 1.
Organo montmorillonite in above-described embodiment, is to be prepared via a method which and obtain:
Inorganic montmorillonite and 3-hexadecane epoxide-2-trimethyl ammonium chloride that mass ratio is 1:1 are dissolved in quality and divide Number be 50% ethanol water in (ethanol water that the inorganic montmorillonite of 1g needs 15-20ml mass fraction to be 50%), mixing Uniformly post-heating is to 75 DEG C, reacts 1 hour, filters, filter cake ethanol purge, is drying to obtain described organo montmorillonite.
The processing technology of the wallpaper of example wallpaper routinely time above-mentioned, through paste producing, coating, is dried, prints, sends out Bubble, embossing, cooling, trimming, rolling.
The wallpaper prepared according to above-described embodiment meets the regulation of GB18585-2001, do not contain national regulation forbid make Heavy metal antimony, arsenic, barium, cadmium, chromium, lead, hydrargyrum, selenium, do not contain formaldehyde, do not contain Vinyl Chloride Monomer.
The wallpaper prepared according to above-described embodiment, does basic unit with white bamboo carbon fiber, the most additional cotton/chitin/white bamboo carbon Blend fibre layer, has excellent moisture absorbing and deodorizing.
The wallpaper prepared according to above-described embodiment, carries out mildew resistance test to it, and concrete method of testing is: by 30x60 milli The wallpaper of rice be exposed to containing escherichia coli, Salmonella, staphylococcus aureus suspension in, be placed in beneficially mushroom raw Long environment (temperature 25 DEG C, relative humidity 85%), this environment tackles the wet environment of daily household, including the Huang that south is common Rainy season gas, after one month, wallpaper surface occurs without macula lutea and mildew, and this explanation wallpaper has superior mildew resistance.
The wallpaper prepared according to above-described embodiment, carries out antibiotic property test to it, with reference to JISZ2801:2000 " antibacterial system The detection of product anti-microbial property and evaluation)) standard detects, and carries out antibacterial to common escherichia coli, staphylococcus aureus Test, experimental result display the present invention wallpaper to escherichia coli, staphylococcus aureus bacteriostasis rate all up to 99.99%；Tool There is superior bacteriostasis antibiosis.
It addition, the wallpaper prepared according to above-described embodiment, carrying out anti-flammability test, test result shows, its UL-94 hangs down Direct combustion burns and reaches V-0 level, and LOI reaches more than 30, has good anti-flammability.In a word, the wallpaper of the present invention be a mildew-resistant, Antibacterial, fire-retardant, moisture absorbing and deodorizing, moistureproof multi-functional environment-protection green wallpaper, have promotion and use value.
Finally need it is pointed out here that: be the most only the part preferred embodiment of the present invention, it is impossible to be interpreted as this The restriction of bright protection domain, some nonessential improvement that those skilled in the art makes according to the foregoing of the present invention and Adjustment belongs to protection scope of the present invention.

Claims (10)

1. the wallpaper containing white bamboo carbon fiber, it is characterised in that: include white bamboo, described white bamboo The back side is provided with waterproof mildew-resistant layer, described white bamboo be arranged above with antibacterial and deodouring layer, set above described antibacterial and deodouring layer Cotton/chitin/white bamboo carbon blend fibre layer, described cotton/chitin/white bamboo carbon blend fibre layer is had to be provided with printed pattern layer, Described printed pattern layer coated thereon has antibacterial and mouldproof layer, described antibacterial and mouldproof layer to be provided with coating layer；Described waterproof mildew-resistant layer It is made up of the material of following mass percent: modified polyvinylalcohol: 30-35 part, sodium alginate: 6-8 part, the iodo-2-propynyl of 3- Butyl carbamate: 5-7 part, halloysite nanotubes: 4-6 part, silicone acrylic emulsion: 20-22 part, deionized water: 30-35 part；Institute State antibacterial and mouldproof layer to be made up of the material of following mass percent: modified polyvinylalcohol: 20-22 part, zeolite with carrying silver: 0.5-1 part, Chitosan: 4-5 part, calcium lignosulfonate: 4-5 part, camphor leaf extract: 10-15 part, DDAC: 1-1.5 Part, pectin and sodium lactate compound: 4-5 part, deionized water: 75-80 part.
Wallpaper containing white bamboo carbon fiber the most according to claim 1, it is characterised in that: described cotton/chitin/white bamboo carbon In blend fibre layer, the weight ratio of cotton fiber/chitin fiber/white bamboo carbon fibre is 2/2/1.
Wallpaper containing white bamboo carbon fiber the most according to claim 1, it is characterised in that: described pectin compounds with sodium lactate Thing is the compound of 5mg/mL hawthorn pectin oligosaccharide and 10mg/mL lactic acid.
Wallpaper containing white bamboo carbon fiber the most according to claim 1, it is characterised in that: PE:80-90 part, kieselguhr: 6- 8 parts, activated carbon: 6-8 part, chitosan: 4-5 part, Hinokitiol: 4-5 part, glass fibre: 4-6 part, organo montmorillonite: 4-6 part, eight Phenyl eight silsesquioxane: 1-2 part, carbon fiber: 1-2 part, PPS:2-4 part, dimethyl fumarate: 1-2 part, meerschaum: 5-7 Part, sorbic acid: 1-1.5 part, softening agent: 1-2 part, retention agent: 0.3-0.5 part, wet strength agent: 1-2 part, ethanol: 5-8 part, go from Sub-water: 30-35 part.
Wallpaper containing white bamboo carbon fiber the most according to claim 4, it is characterised in that: described softening agent is stearic acid three Ethanolamine ester quat, retention agent is guar gum, and wet strength agent is PAE resin.
Wallpaper containing white bamboo carbon fiber the most according to claim 4, it is characterised in that: described organo montmorillonite is 3-ten The organo montmorillonite that six alkoxyl-2-trimethyl ammonium chloride are modified.
Wallpaper containing white bamboo carbon fiber the most according to claim 6, it is characterised in that: the preparation of described organo montmorillonite Method is: inorganic montmorillonite and 3-hexadecane epoxide-2-trimethyl ammonium chloride that mass ratio is 1:1 are dissolved in quality Mark is in the ethanol water of 50%, mix homogeneously post-heating to 75 DEG C, reacts 1 hour, filters, filter cake ethanol purge, dry Dry i.e. obtain described organo montmorillonite.
Wallpaper containing white bamboo carbon fiber the most according to claim 1, it is characterised in that: described modified polyvinylalcohol is lemon Lemon acid modified polyvinylalcohol, its preparation method is: according to mass fraction meter, by 9-11 part polyvinyl alcohol, 0.1-0.3 part Fructus Citri Limoniae Acid, 0.5-1.5 part glycerol, 88-90 part deionized water, at 95 DEG C, constant temperature stirs 3 hours, then degassing 1 under-0.1 MPa H, is finally dried 3 h at 60 DEG C and i.e. obtains described modified polyvinylalcohol.
Wallpaper containing white bamboo carbon fiber the most according to claim 1, it is characterised in that: the system of described camphor leaf extract Preparation Method is as follows: being positioned in the ethanol water of mass fraction 60% by Folium cinnamomi camphorae powder, at 55 DEG C, insulated and stirred 2-3 is little Time, then to filter, filter residue, filtrate is distilled in 55 DEG C of decompressions and is i.e. obtained described camphor leaf extract, Folium cinnamomi camphorae during extraction Powder is V ethanol with the solid-liquid ratio of ethanol water: m leaves=16: 1.
Wallpaper containing white bamboo carbon fiber the most according to claim 1, it is characterised in that: described coating layer is polyethylene Thin film.
CN201610443302.5A 2016-06-21 2016-06-21 A kind of wallpaper containing white bamboo carbon fiber Pending CN106079763A (en)

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