CN109024093A - A kind of environment-friendly antibacterial wallpaper - Google Patents

A kind of environment-friendly antibacterial wallpaper Download PDF

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Publication number
CN109024093A
CN109024093A CN201811150873.5A CN201811150873A CN109024093A CN 109024093 A CN109024093 A CN 109024093A CN 201811150873 A CN201811150873 A CN 201811150873A CN 109024093 A CN109024093 A CN 109024093A
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CN
China
Prior art keywords
parts
layer
environment
friendly antibacterial
wallpaper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811150873.5A
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Chinese (zh)
Inventor
何凌峰
杨富国
王军飞
史亮
申坤
胡子萱
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Foshan University
Original Assignee
Foshan University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Foshan University filed Critical Foshan University
Priority to CN201811150873.5A priority Critical patent/CN109024093A/en
Publication of CN109024093A publication Critical patent/CN109024093A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/18Paper- or board-based structures for surface covering
    • D21H27/20Flexible structures being applied by the user, e.g. wallpaper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/002Layered products comprising a layer of paper or cardboard as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B29/00Layered products comprising a layer of paper or cardboard
    • B32B29/02Layered products comprising a layer of paper or cardboard next to a fibrous or filamentary layer
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00Coated paper; Coating material
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/30Multi-ply

Abstract

The invention discloses a kind of environment-friendly antibacterial wallpapers, are related to Environment-friendlywallpaper wallpaper technical field.The present invention includes base, and the back side of base is equipped with waterproof layer, and the upper surface of base is equipped with coating layer;Carbon fiber layer is equipped with above coating layer;Sandwich layer is equipped with above carbon fiber layer;Printed layer is equipped with above sandwich layer;Stain-proofing layer is equipped with above printed layer.The present invention carries out the effect of deodorization and sterilization by the coating layer and sandwich layer of design, and carbon fiber layer enhances the pull resistance of wallpaper, and stain-proofing layer avoids wallpaper from being infected with greasy dirt easy cleaning, solves the problems, such as the weak easy contamination greasy dirt of existing wallpaper tensile capacity and breeds bacterium.

Description

A kind of environment-friendly antibacterial wallpaper
Technical field
The invention belongs to Environment-friendlywallpaper wallpaper technical fields, more particularly to a kind of environment-friendly antibacterial wallpaper.
Background technique
Wallpaper, also referred to as wallpaper, it is a kind of quite extensive house decorative material of application.Because wallpaper has color more A variety of other house decorative materials such as sample, pattern be abundant, luxurious style, safety and environmental protection, easy for construction, affordable can not compare Quasi- feature, therefore obtained in developed countries and regions such as America and Europe, Southeast Asia, Japan considerable degree of universal.
In the past, wallpaper came into people's lives as just a kind of decorative material, and people require it mostly in dicoration Above aesthetics, as the improvement of people's living standards, people need to want the wallpaper of high-quality to decorate the life of oneself, people It is also more and more to other Functional Requirements of wallpaper.
The moisture resistance of wallpaper is a kind of important performance, if wallpaper does not have moisture resistance, not only wallpaper uses the longevity Life will be greatly reduced, while if wallpaper does not have moisture resistance, can slowly become moist through, then can also breed various bacteriums, make The environment for obtaining indoor inhabitation is deteriorated.Wallpaper a part currently on the market has the effect of moisture-proof, but the antibiotic property of wallpaper is not Foot appoints the Signs of Mould that so bacterium easy to breed causes surface to see under dark moist environment, and the pull resistance of wallpaper is insufficient It is easy damaged when pasting or wrinkles, while the printed layer on the surface of wallpaper becomes easily infected by spot and is not easily cleaned.
Summary of the invention
The purpose of the present invention is to provide a kind of environment-friendly antibacterial wallpapers, carry out sterilization by the coating layer and sandwich layer of design and remove Smelly effect, carbon fiber layer enhance the pull resistance of wallpaper, and stain-proofing layer avoids wallpaper from being infected with greasy dirt easy cleaning, solves existing wall The problem of weak easy contamination greasy dirt of paper tensile capacity and growth bacterium.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
The present invention is a kind of environment-friendly antibacterial wallpaper, including base, and the back side of the base is equipped with waterproof layer, the base It is equipped with coating layer above;Carbon fiber layer is equipped with above the coating layer;Sandwich layer is equipped with above the carbon fiber layer;On the sandwich layer Face is equipped with printed layer;Stain-proofing layer is equipped with above the printed layer;
The sandwich layer includes following composition by weight: 8-10 parts of nano-Ag particles, 5-12 parts of nano-titanium dioxide, carboxymethyl are fine Tie up plain 4-8 parts of sodium salt cellulose, 4-7 parts of ethylene glycol, 6-11 parts of dimethyl silicone polymer, 11-16 parts of negative oxygen ion powder, propylene 3-6 parts of yogurt liquid, 2-5 parts of poly aluminium sulfate, 2-5 parts of pearl powder, 4-9 parts of isocyanate resin, 2.5-5 parts of degasifier, remaining part It is divided into deionized water;Wherein negative oxygen ion powder generates anion, is identified it is to have to kill germ and net in medical field anion The effective means for changing air after mechanism essentially consists in anion in conjunction with bacterium, makes bacterium generate change or the energy of structure Transfer, lead to bacterial death, most final decline is sunken to ground, and electronegative particle increases oxygen content in air, is conducive to Blood oxygen conveying is absorbed and is utilized, and is had and is promoted human metabolism, improve human immunological competence, enhances human muscle energy, adjuster The effect of body function balance;Using forward position nanotechnology by silver nanoparticle, nanotechnology the nano silver occurs, makes silver in nanometer Sterilizing ability under state produces qualitative leap, and few nano silver can produce powerful bactericidal effect, can be in several minutes Kill 650 various bacterias, broad-spectrum sterilization and without any drug resistance can promote the healing of wound, the growth of cell and impaired The reparation of cell does not find any stimulate the reaction to skin without any toxic reaction yet;
The stain-proofing layer includes following composition by weight: ptfe micropowder 10%-15%, fatty alcohol polyoxyethylene ether 5%-10%, Glycolic acid 20%-25%, copper oleate 10%-15%, polyvinyl butyral 10%-15%, allyl alcohol 20%- 25%, non-ion fluorin carbon surface active agent 3%-5%, wherein polytetrafluoroethylene (PTFE) is the smallest surface tension in solid material, no Adhering to any substance, prevention wallpaper is infected with greasy dirt, the adhesion inhibiting properties that there is polyvinyl butyral good water resistance to be combined, Good mobility and excellent wet pigments.
Further, the coating layer is made of the material of following mass percent: 5-8 parts of sepiolite, 5-8 parts of zeolite, 1-2 portions of softening agent, 1-2 parts of wet strength agent, 3-5 parts of aluminum orthophoshpate, 2-3 parts of copper acid methyl cellulose, resists 0.3-0.5 parts of retention agent 4-5 parts of microbial inoculum, 3-4 parts of mould inhibitor, 3-4 parts of fire retardant, 2-3 parts of titanium dioxide, rest part is deionized water;Wherein Hai Pao Stone is a kind of fibrous rich-magnesium clay mineral, has the performances such as good absorption, fire-retardant, high temperature resistant, and be environment-protecting and non-poisonous in itself Substance can be used as the noxious materials such as the ammonia that deodorant is gone out in air, be also used as fire retardant use, zeolite is porous Property inorganic substances, there is absorption, catalyst and ion exchanging function, the excellent performance with adsorption of hydrogen sulfide and ammonia has very Good deodorizing effect.
Further, base's material includes chemical fabric, non-woven fabrics or brown paper;The thickness range of the base is 0.2-0.5mm。
Further, the thickness range of the waterproof layer is 0.1-0.2mm.
Further, the thickness range of the coating layer is 0.3-0.4mm.
Further, the thickness range of the carbon fiber layer be 0.1-0.2mm, carbon fiber have both the strong stretching resistance of carbon material and The big feature of fiber softening machinability two, carbon fiber are a kind of new materials of excellent in mechanical performance, and the light tensile strength of material is big, The thermal expansion coefficient of carbon fiber is different from other fibers, it has the characteristics of anisotropy, the specific heat capacity of carbon fiber is generally 7.12, Thermal conductivity increases with temperature and declines that be parallel to machine direction be negative value, has good heat-insulation and heat-preservation.
Further, the thickness range of the sandwich layer is 0.3-0.4mm.
Further, the thickness range of the printed layer is 0.2-0.3mm.
Further, the thickness range of the stain-proofing layer is 40-120um.
The invention has the following advantages:
1, after the anion that the present invention is generated by the coating layer and sandwich layer that design is in conjunction with bacterium, generate bacterium The change of structure or the transfer of energy lead to bacterial death to play the effect of sterilization, and internal few nano silver can produce Powerful bactericidal effect can kill 650 various bacterias in several minutes, have stronger contact sterilization effect, prevent wallpaper Bacteria breed.
2, the present invention is by increased carbon fiber layer, according to the strong stretching resistance of the excellent carbon material of carbon fiber layer and fiber softening The big feature of machinability two does not reduce the flexibility of wallpaper while enhancing wallpaper pull resistance, while carbon fiber thermal conductance is with temperature It increases and declines that be parallel to machine direction be negative value, there is good heat-insulation and heat-preservation, improve the heat insulating effect of wallpaper.
3, the present invention is the smallest surface tension in solid material by polytetrafluoroethylene (PTFE) in the stain-proofing layer on surface, is not adhered to Any substance, prevention wallpaper contamination greasy dirt while easy cleaning.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Detailed description of the invention
In order to illustrate the technical solution of the embodiments of the present invention more clearly, will be described below to embodiment required Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for ability For the those of ordinary skill of domain, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is a kind of structural schematic diagram of environment-friendly antibacterial wallpaper of the present invention;
In attached drawing, parts list represented by the reference numerals are as follows:
1- base, 2- waterproof layer, 3- coating layer, 4- carbon fiber layer, 5- sandwich layer, 6- printed layer, 7- stain-proofing layer.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts all other Embodiment shall fall within the protection scope of the present invention.
Refering to Figure 1, the present invention is a kind of environment-friendly antibacterial wallpaper, including base 1, the back side of base 1 is equipped with waterproof Layer 2, the upper surface of base 1 are equipped with coating layer 3;Coating layer 3 is equipped with carbon fiber layer 4 above;Carbon fiber layer 4 is equipped with sandwich layer 5 above;Core Layer 5 is equipped with printed layer 6 above;Printed layer 6 is equipped with stain-proofing layer 7 above;
Sandwich layer 5 includes following composition by weight: 9 parts of nano-Ag particles, 10 parts of nano-titanium dioxide, sanlose Fiber element 5 parts, 6 parts of ethylene glycol, 91 parts of dimethyl silicone polymer, 8 parts of negative oxygen ion powder, 5 parts of acrylic emulsion, poly aluminium sulfate 8 parts, 4 parts of pearl powder, 6 parts of isocyanate resin, 5 parts of degasifier, rest part is deionized water;Wherein negative oxygen ion powder generates Anion is identified it is the effective means with germ and purification air is killed in medical field anion, and mechanism essentially consists in After anion is in conjunction with bacterium, so that bacterium is generated the change of structure or the transfer of energy, lead to bacterial death, most final decline is sunken to ground Face, electronegative particle increases oxygen content in blood in air, is conducive to blood oxygen conveying, absorbs and utilize, has and promote human body Metabolism improves human immunological competence, enhances human muscle energy, adjusts the effect of body function balance;Nano silver utilizes forward position There is silver nanoparticle, nanotechnology in nanotechnology, so that sterilizing ability of the silver under nm regime is produced qualitative leap, seldom Nano silver can produce powerful bactericidal effect, 650 various bacterias can be killed in several minutes, broad-spectrum sterilization and without any resistance to Pharmacological property can promote the healing of wound, the growth of cell and the reparation of damaged cell, without any toxic reaction, also not to skin It was found that any stimulate the reaction;
Stain-proofing layer 7 includes following composition by weight: ptfe micropowder 15%, fatty alcohol polyoxyethylene ether 10%, glycol Sour 20%, copper oleate 10%, polyvinyl butyral 15%, allyl alcohol 25%, non-ion fluorin carbon surface active agent 5%, wherein Polytetrafluoroethylene (PTFE) is the smallest surface tension in solid material, does not adhere to any substance, and prevention wallpaper is infected with greasy dirt, polyvinyl alcohol The adhesion inhibiting properties that there is butyral good water resistance to be combined, good mobility and excellent wet pigments.
Wherein, coating layer 3 is made of the material of following mass percent: 8 parts of sepiolite, 2 parts of softening agent, helps 8 parts of zeolite Stay 0.5 part of agent, 2 parts of wet strength agent, 4 parts of aluminum orthophoshpate, 3 parts of copper acid methyl cellulose, 4 parts of antibacterial agent, 4 parts of mould inhibitor, fire retardant 4 Part, 3 parts of titanium dioxide, rest part is deionized water;Wherein sepiolite is a kind of fibrous rich-magnesium clay mineral, is had very well The performances such as absorption, fire-retardant, high temperature resistant, and be environment-protecting and non-poisonous substance in itself, can be used as the ammonia that deodorant is gone out in air The noxious materials such as gas are also used as fire retardant use, and zeolite is porous inorganic substances, has absorption, catalyst and ion Function of exchange, the excellent performance with adsorption of hydrogen sulfide and ammonia have good deodorizing effect.
Wherein, 1 material of base includes chemical fabric, non-woven fabrics or brown paper;Base 1 with a thickness of 0.3mm.
Wherein, waterproof layer 2 with a thickness of 0.1mm.
Wherein, coating layer 3 with a thickness of 0.3mm.
Wherein, carbon fiber layer 4 with a thickness of 0.2mm, it is processable that carbon fiber has both the strong stretching resistance of carbon material and fiber softening Property two big features, carbon fiber is a kind of new material of excellent in mechanical performance, and the light tensile strength of material is big, the thermal expansion of carbon fiber Coefficient is different from other fibers, it has the characteristics of anisotropy, the specific heat capacity of carbon fiber is generally 7.12, thermal conductivity with temperature liter It is negative value that high and decline, which is parallel to machine direction, has good heat-insulation and heat-preservation.
Wherein, sandwich layer 5 with a thickness of 0.3mm.
Wherein, printed layer 6 with a thickness of 0.2mm.
Wherein, stain-proofing layer 7 with a thickness of 80um.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the invention In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example. Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to better explain the present invention Principle and practical application, so that skilled artisan be enable to better understand and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (9)

1. the back side of a kind of environment-friendly antibacterial wallpaper, including base (1), the base (1) is equipped with waterproof layer (2), it is characterised in that:
The upper surface of described base (1) is equipped with coating layer (3);The coating layer (3) is equipped with carbon fiber layer (4) above;The carbon fiber It ties up layer (4) and is equipped with sandwich layer (5) above;The sandwich layer (5) is equipped with printed layer (6) above;The printed layer (6) is equipped with antifouling above Layer (7);
The sandwich layer (5) includes following composition by weight: 8-10 parts of nano-Ag particles, 5-12 parts of nano-titanium dioxide, carboxymethyl are fine Tie up plain 4-8 parts of sodium salt cellulose, 4-7 parts of ethylene glycol, 6-11 parts of dimethyl silicone polymer, 11-16 parts of negative oxygen ion powder, propylene 3-6 parts of yogurt liquid, 2-5 parts of poly aluminium sulfate, 2-5 parts of pearl powder, 4-9 parts of isocyanate resin, 2.5-5 parts of degasifier, remaining part It is divided into deionized water;
The stain-proofing layer (7) includes following composition by weight: ptfe micropowder 10%-15%, fatty alcohol polyoxyethylene ether 5%-10%, Glycolic acid 20%-25%, copper oleate 10%-15%, polyvinyl butyral 10%-15%, allyl alcohol 20%- 25%, non-ion fluorin carbon surface active agent 3%-5%.
2. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the coating layer (3) is by following quality The material of percentage forms: 5-8 parts of sepiolite, 5-8 parts of zeolite, 1-2 parts of softening agent, 0.3-0.5 parts of retention agent, wet strength agent 1-2 Part, 3-5 parts of aluminum orthophoshpate, 2-3 parts of copper acid methyl cellulose, 4-5 parts of antibacterial agent, 3-4 parts of mould inhibitor, 3-4 parts of fire retardant, titanium white 2-3 parts of powder, rest part is deionized water.
3. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that base (1) material includes chemical fibre Cloth, non-woven fabrics or brown paper;The thickness range of the base (1) is 0.2-0.5mm.
4. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the thickness range of the waterproof layer (2) For 0.1-0.2mm.
5. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the thickness range of the coating layer (3) For 0.3-0.4mm.
6. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the thickness model of the carbon fiber layer (4) It encloses for 0.1-0.2mm.
7. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the thickness range of the sandwich layer (5) is 0.3-0.4mm。
8. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the thickness range of the printed layer (6) For 0.2-0.3mm.
9. a kind of environment-friendly antibacterial wallpaper according to claim 1, which is characterized in that the thickness range of the stain-proofing layer (7) For 40-120um.
CN201811150873.5A 2018-09-29 2018-09-29 A kind of environment-friendly antibacterial wallpaper Pending CN109024093A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811150873.5A CN109024093A (en) 2018-09-29 2018-09-29 A kind of environment-friendly antibacterial wallpaper

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Application Number Priority Date Filing Date Title
CN201811150873.5A CN109024093A (en) 2018-09-29 2018-09-29 A kind of environment-friendly antibacterial wallpaper

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109914732A (en) * 2019-04-02 2019-06-21 常州龙城韩利壁衣有限公司 Multi-functional composite wallpaper
CN110524966A (en) * 2019-09-02 2019-12-03 同曦集团有限公司 A kind of antibacterial wallpaper and preparation method thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104060501A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Environment-friendly wallpaper capable of adjusting humidity
CN104060500A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Environment-friendly antibacterial moistureproof wallpaper
CN106243806A (en) * 2016-08-03 2016-12-21 东莞市蓝鲸化工科技有限公司 A kind of water proof anti-soil protection spray and preparation method thereof
CN107142792A (en) * 2017-06-20 2017-09-08 合肥尚涵装饰工程有限公司 A kind of wallpaper with antibacterial functions and preparation method thereof
CN108215376A (en) * 2016-12-22 2018-06-29 福建省优雅环保壁纸有限公司 A kind of antistatic wallpaper and its production method

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104060501A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Environment-friendly wallpaper capable of adjusting humidity
CN104060500A (en) * 2014-05-30 2014-09-24 苏州国昊壁纸有限公司 Environment-friendly antibacterial moistureproof wallpaper
CN106243806A (en) * 2016-08-03 2016-12-21 东莞市蓝鲸化工科技有限公司 A kind of water proof anti-soil protection spray and preparation method thereof
CN108215376A (en) * 2016-12-22 2018-06-29 福建省优雅环保壁纸有限公司 A kind of antistatic wallpaper and its production method
CN107142792A (en) * 2017-06-20 2017-09-08 合肥尚涵装饰工程有限公司 A kind of wallpaper with antibacterial functions and preparation method thereof

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109914732A (en) * 2019-04-02 2019-06-21 常州龙城韩利壁衣有限公司 Multi-functional composite wallpaper
CN110524966A (en) * 2019-09-02 2019-12-03 同曦集团有限公司 A kind of antibacterial wallpaper and preparation method thereof
CN110524966B (en) * 2019-09-02 2021-12-10 同曦集团有限公司 Antibacterial wallpaper and preparation method thereof

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