CN107386010A - A kind of oil-stain-preventing wallpaper and preparation method thereof - Google Patents
A kind of oil-stain-preventing wallpaper and preparation method thereof Download PDFInfo
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- CN107386010A CN107386010A CN201710647065.9A CN201710647065A CN107386010A CN 107386010 A CN107386010 A CN 107386010A CN 201710647065 A CN201710647065 A CN 201710647065A CN 107386010 A CN107386010 A CN 107386010A
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- oil
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/38—Corrosion-inhibiting agents or anti-oxidants
Abstract
The invention discloses a kind of oil-stain-preventing wallpaper and preparation method thereof, including wallpaper body, wallpaper body is followed successively by overcoat, printed layer, adsorption layer, peel ply by upper strata to bottom.The overcoat of wallpaper in the present invention, esterification effectively can be occurred with the unrighted acid in greasy dirt by the esterifying agent of zinc hydroxide used, Kocide SD, the ester of generation is soluble in water, beneficial to wiping, reaches the effect of oil-stain-preventing.
Description
Technical field
The present invention relates to interior decoration field, specifically a kind of oil-stain-preventing wallpaper and preparation method thereof.
Background technology
With the development in epoch, various house decorative materials also begin to develop therewith, and obtain widely should very much
With wallpaper is exactly one of material wherein with fastest developing speed.The popularity rate that Japanese, Russian wallpaper is decorate indoors now according to statistics
Close to 100%, also there is 50%-60% popularity rate in American-European countries, and also have very in our this house decorative materials of China
Big development space, at present popularity rate be less than 1%.With the change and progress of present consumer's idea, from former
" coating epoch " have entered " wallpaper epoch ", and increasing people starts to recognize wallpaper, and wallpaper is used when decorating indoors,
Make Chinese wallpaper industry towards popular advance.The hotel of currently the majority, department stores, government organs are medium-to-high grade
The place such as dining room all has begun to widely use wallpaper, and the accreditation of increasing people is also obtained the advantages of wallpaper, is obtained more next
More it is widely applied.
When wallpaper is used in modern kitchen, oil-stain-preventing turns into the characteristics of indispensable, and most wallpaper of in the market makes
Used time, oil-stain-preventing DeGrain.
The content of the invention
It is an object of the invention to provide a kind of oil-stain-preventing wallpaper and preparation method thereof, to solve to carry in above-mentioned background technology
The problem of going out.
To achieve the above object, the present invention provides following technical scheme：
A kind of oil-stain-preventing wallpaper, including wallpaper body, the wallpaper body are followed successively by overcoat, stamp by upper strata to bottom
Layer, adsorption layer, peel ply, the overcoat are formed again in mass ratio by following raw material:
The PVC resin powder of 56.2 parts by weight, the esterifying agent of 8.4 parts by weight, the antioxidant of 4.5 parts by weight, 27 parts by weight
Plasticizer, diluent, the stabilizer of 1.1 parts by weight of 2.8 parts by weight, plasticizer composition proportion is：6.25 parts by weight
Epoxidized soybean oil, the dioctyl phthalates of 31.25 parts by weight, 31.25 parts by weight phthalic acid butyl- phenyl ester,
The antimony oxide of 31.25 parts by weight, the esterifying agent include zinc hydroxide, Kocide SD, catalyst, and composition quality proportion is
The zinc hydroxide of 45 parts by weight, 45 parts of Kocide SDs, the catalyst of 10 parts by weight, the antioxidant include zinc oxide, oxidation
Copper, composition quality proportion are zinc oxide, the cupric oxide of 50 parts by weight of 50 parts by weight；
The printed layer is formed again in mass ratio by following raw material:
The PVC resin powder of 47.2 parts by weight, the plasticizer of 50.9 parts by weight, 1.43 parts by weight facilitate agent, 0.47 weight
The stabilizer of part, the plasticizer composition proportion are：The O-phthalic of the epoxidized soybean oil of 2.78 parts by weight, 50.94 parts by weight
Dioctyl phthalate, the phthalic acid butyl- phenyl ester of 13.89 parts by weight, the azodicarbonamide of 9.25 parts by weight, 13.89 parts by weight
Antimony oxide, the titanium dioxide of 9.25 parts by weight；
The adsorption layer is formed again in mass ratio by following raw material:
The PVC resin powder of 44.1 parts by weight, the plasticizer of 55.1 parts by weight, the stabilizer of 0.8 parts by weight, the plasticizer
Forming proportion is：Three oxidations of the epoxidized soybean oil of 2.4 parts by weight, the dioctyl phthalate of 60 parts by weight, 5.6 parts by weight
Two antimony, the titanium dioxide of 24 parts by weight, the calcium carbonate of 8 parts by weight；Adsorption layer and the one side of peel ply compacting connection are provided with uniformly
Sucker, suction cup lateral is provided with one layer of adhesive film in the adsorption layer, and the adhesive film has following raw material to remake into mass ratio:
The acrylate polymer of 37 parts by weight, the tackifying resin of 20 parts by weight, the polyvinyl alcohol of 26 parts by weight, the activity of 12 parts by weight
The antioxidant of diluent, 5 parts by weight；
The peel ply is by using CCK release liners, and its surface sets one layer of silicon layer, and the silicon layer is arranged on adhesive film
Between, the body paper of the CCK release liners is that surface is coated with one layer of china clay material.
As the further scheme of the present invention：The stabilizer is preferably zinc or barium.
As the further scheme of the present invention：The sucker is preferably shaped to tooth form.
As the further scheme of the present invention：The tackifying resin is preferably terpene resin.
As the further scheme of the present invention：The reactive diluent is preferably KN4010.
A kind of preparation method of oil-stain-preventing wallpaper, is divided into following steps：
S1, printed layer preparation, a body paper is taken by the way of coating, to use painting cloth-knife to its surface corona bottoming
Its upper surface is evenly coated in by the ready-made thickener of the formula of printed layer；
S2, using gas heater, by hot air circulating system at 150-170 DEG C, to body paper face coat
Carry out gel；S3, by two cooling wheels hardening by cooling is carried out to hotter fabric with circulated refrigerated water；
S4, with print wheel and circulation ink, no pattern use different print wheels, in web surface print
Upper required pattern；
S5, using a single gas heater, be dried by hot air circulation；
S6, overcoat and adsorption layer are prepared in the same way, it is utilized to electrically heated heating mantles to soft or hard fabric
Carrying out heating makes its softening；
S7, overcoat is added and added in the upper surface of printed layer, adsorption layer in the lower surface of printed layer；
S8, using the embossed wheel with tooth form, be pressed in adsorption layer, make adsorption layer that there is tooth form sucker；
S9, one layer of adhesive film is printed in the lower surface of adsorption layer, and print one layer of silicon layer, add peel ply.
Compared with prior art, the beneficial effects of the invention are as follows：
1. zinc hydroxide, Kocide SD in oil-stain-preventing wallpaper overcoat used in esterifying agent can effectively with greasy dirt not
Esterification occurs for saturated fatty acid, and the ester of generation is soluble in water, beneficial to wiping；
2. the antioxidant in oil-stain-preventing wallpaper overcoat can be moistureproof, and zinc oxide, the cupric oxide in antioxidant absorb water
Afterwards, the zinc hydroxide easily in generation esterifying agent, Kocide SD, and be used effectively, environmental protection and saving；
3. the tooth form sucker that oil-stain-preventing wallpaper adsorption layer is set is more beneficial for wallpaper and is pasted onto on the wall in kitchen.
Brief description of the drawings
Fig. 1 is a kind of structural representation of oil-stain-preventing wallpaper.
In figure：1- overcoats, 2- printed layers, 3- adsorption layers, 4- peel plies, 5- suckers.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment
Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area
The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects
Enclose.
Referring to Fig. 1, a kind of oil-stain-preventing wallpaper, including wallpaper body, wallpaper body are followed successively by protection by upper strata to bottom
Layer 1, printed layer 2, adsorption layer 3, peel ply 4, overcoat 1 are formed again in mass ratio by following raw material:
The PVC resin powder of 56.2 parts by weight, the esterifying agent of 8.4 parts by weight, the antioxidant of 4.5 parts by weight, 27 parts by weight
Plasticizer, diluent, the stabilizer of 1.1 parts by weight of 2.8 parts by weight, plasticizer composition proportion is：6.25 parts by weight
Epoxidized soybean oil, the dioctyl phthalates of 31.25 parts by weight, 31.25 parts by weight phthalic acid butyl- phenyl ester,
The antimony oxide of 31.25 parts by weight, the esterifying agent include zinc hydroxide, Kocide SD, catalyst, and composition quality proportion is
The zinc hydroxide of 45 parts by weight, 45 parts of Kocide SDs, the catalyst of 10 parts by weight, the antioxidant include zinc oxide, oxidation
Copper, form quality proportion and be the zinc oxide of 50 parts by weight, be the cupric oxide of 50 parts by weight, zinc hydroxide, hydrogen used in esterifying agent
Effectively with the unrighted acid in greasy dirt esterification can occur for cupric oxide, and the ester of generation is soluble in water, beneficial to wiping；
Printed layer 2 is formed again in mass ratio by following raw material:
The PVC resin powder of 47.2 parts by weight, the plasticizer of 50.9 parts by weight, 1.43 parts by weight facilitate agent, 0.47 weight
The stabilizer of part, the plasticizer composition proportion are：The O-phthalic of the epoxidized soybean oil of 2.78 parts by weight, 50.94 parts by weight
Dioctyl phthalate, the phthalic acid butyl- phenyl ester of 13.89 parts by weight, the azodicarbonamide of 9.25 parts by weight, 13.89 parts by weight
Antimony oxide, the titanium dioxide of 9.25 parts by weight；
Adsorption layer 3 is formed again in mass ratio by following raw material:
The PVC resin powder of 44.1 parts by weight, the plasticizer of 55.1 parts by weight, the stabilizer of 0.8 parts by weight, the plasticizer
Forming proportion is：Three oxidations of the epoxidized soybean oil of 2.4 parts by weight, the dioctyl phthalate of 60 parts by weight, 5.6 parts by weight
Two antimony, the titanium dioxide of 24 parts by weight, the calcium carbonate of 8 parts by weight；Adsorption layer 3 and the one side of the compacting connection of peel ply 4 are provided with suction
Disk 5, the side of sucker 5 is provided with one layer of adhesive film in adsorption layer 3, and adhesive film has following raw material to remake into mass ratio:37 parts by weight
Acrylate polymer, the tackifying resin of 20 parts by weight, the polyvinyl alcohol of 26 parts by weight, the reactive diluent of 12 parts by weight, 5
The antioxidant of parts by weight；
Peel ply 4 is by using CCK release liners, and its surface sets one layer of silicon layer, and silicon layer is arranged between adhesive film, just
In tearing for peel ply 4, the body paper surface of CCK release liners is coated with one layer of china clay material, high temperature-proof.
Stabilizer is preferably zinc or barium.
Sucker is preferably shaped to tooth form.
Tackifying resin is preferably terpene resin.
Reactive diluent is preferably KN4010.
A kind of preparation method of oil-stain-preventing wallpaper, is divided into following steps：
S1, printed layer 2 preparation, a body paper is taken by the way of coating, to use painting cloth-knife to its surface corona bottoming
Its upper surface is evenly coated in by the ready-made thickener of the formula of printed layer 2；
S2, using gas heater, by hot air circulating system at 150-170 DEG C, to body paper face coat
Carry out gel；S3, by two cooling wheels hardening by cooling is carried out to hotter fabric with circulated refrigerated water；
S4, with print wheel and circulation ink, no pattern use different print wheels, in web surface print
Upper required pattern；
S5, using a single gas heater, be dried by hot air circulation；
S6, overcoat 1 and adsorption layer 3 are prepared in the same way, it is utilized to electrically heated heating mantles to soft or hard face
Material, which carries out heating, makes its softening；
S7, overcoat 1 is added and added in the upper surface of printed layer 2, adsorption layer 3 in the lower surface of printed layer 2；
S8, using the embossed wheel with tooth form, be pressed in adsorption layer 3, make adsorption layer 3 that there is tooth form sucker 5；
S9, one layer of adhesive film is printed in the lower surface of adsorption layer 3, and print one layer of silicon layer, add peel ply 4.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.Any reference in claim should not be considered as to the involved claim of limitation.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (6)
1. a kind of oil-stain-preventing wallpaper, including wallpaper body, the wallpaper body is followed successively by overcoat, stamp by upper strata to bottom
Layer, adsorption layer, peel ply, it is characterised in that the overcoat is formed again in mass ratio by following raw material:
The increasing of the PVC resin powder of 56.2 parts by weight, the esterifying agent of 8.4 parts by weight, the antioxidant of 4.5 parts by weight, 27 parts by weight
Agent, the diluent of 2.8 parts by weight, the stabilizer of 1.1 parts by weight are moulded, the plasticizer composition proportion is：The ring of 6.25 parts by weight
Oxygen soybean oil, the dioctyl phthalate of 31.25 parts by weight, phthalic acid butyl- phenyl ester, 31.25 weights of 31.25 parts by weight
The antimony oxide of part is measured, the esterifying agent includes zinc hydroxide, Kocide SD, catalyst, and composition quality proportion is 45 weight
The zinc hydroxide, 45 parts of Kocide SDs, the catalyst of 10 parts by weight of part, the antioxidant include zinc oxide, cupric oxide, composition
Quality proportion is the zinc oxide of 50 parts by weight, is the cupric oxide of 50 parts by weight；The printed layer is heavy in mass ratio by following raw material
Form:
The PVC resin powder of 47.2 parts by weight, the plasticizer of 50.9 parts by weight, 1.43 parts by weight facilitate agent, 0.47 parts by weight
Stabilizer, the plasticizer composition proportion are：The phthalic acid two of the epoxidized soybean oil of 2.78 parts by weight, 50.94 parts by weight
Monooctyl ester, the phthalic acid butyl- phenyl ester of 13.89 parts by weight, the azodicarbonamide of 9.25 parts by weight, the three of 13.89 parts by weight
Aoxidize two antimony, the titanium dioxide of 9.25 parts by weight；
The adsorption layer is formed again in mass ratio by following raw material:
The PVC resin powder of 44.1 parts by weight, the plasticizer of 55.1 parts by weight, the stabilizer of 0.8 parts by weight, the plasticizer composition
Proportion is：Three oxidations two of the epoxidized soybean oil of 2.4 parts by weight, the dioctyl phthalate of 60 parts by weight, 5.6 parts by weight
Antimony, the titanium dioxide of 24 parts by weight, the calcium carbonate of 8 parts by weight；Adsorption layer and the one side of peel ply compacting connection are provided with uniform
Sucker, the adsorption layer suction cup lateral are provided with one layer of adhesive film, and the adhesive film has following raw material to remake into mass ratio:37 weights
Measure the activity dilution of the acrylate polymer of part, the tackifying resin of 20 parts by weight, the polyvinyl alcohol of 26 parts by weight, 12 parts by weight
Agent, the antioxidant of 5 parts by weight；
The peel ply uses CCK release liners, and its surface sets one layer of silicon layer, and the silicon layer is arranged between adhesive film,
The body paper surface of the CCK release liners is coated with one layer of china clay material.
2. a kind of oil-stain-preventing wallpaper according to claim 1, it is characterised in that the stabilizer is preferably zinc or barium.
3. a kind of oil-stain-preventing wallpaper according to claim 1, it is characterised in that the sucker is preferably shaped to tooth form.
4. a kind of oil-stain-preventing wallpaper according to claim 1, it is characterised in that the tackifying resin is preferably terpenes tree
Fat.
5. a kind of oil-stain-preventing wallpaper according to claim 1, it is characterised in that the reactive diluent is preferably
KN4010。
6. the preparation method of a kind of oil-stain-preventing wallpaper as described in claim 1-5 is any one, it is characterised in that be divided into following step
Suddenly：
S1, printed layer preparation, a body paper are taken to its surface corona bottoming, by the way of coating, with painting cloth-knife by printing
The ready-made thickener of formula of flower layer is evenly coated in its upper surface；
S2, using gas heater, by hot air circulating system at 150-170 DEG C, gel is carried out to body paper face coat；S3、
Hardening by cooling is carried out to hotter fabric with circulated refrigerated water by two cooling wheels；
S4, with print wheel and circulation ink, no pattern uses different print wheels, required figure stamped in web surface
Case；
S5, using a single gas heater, be dried by hot air circulation；
S6, overcoat and adsorption layer are prepared in the same way, it is carried out using electrically heated heating mantles to soft or hard fabric
Heating makes its softening；
S7, overcoat is added and added in the upper surface of printed layer, adsorption layer in the lower surface of printed layer；
S8, using the embossed wheel with tooth form, be pressed in adsorption layer, make adsorption layer that there is tooth form sucker；
S9, one layer of adhesive film is printed in the lower surface of adsorption layer, and print one layer of silicon layer, add peel ply.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710647065.9A CN107386010A (en) | 2017-08-01 | 2017-08-01 | A kind of oil-stain-preventing wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710647065.9A CN107386010A (en) | 2017-08-01 | 2017-08-01 | A kind of oil-stain-preventing wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN107386010A true CN107386010A (en) | 2017-11-24 |
Family
ID=60344617
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710647065.9A Pending CN107386010A (en) | 2017-08-01 | 2017-08-01 | A kind of oil-stain-preventing wallpaper and preparation method thereof |
Country Status (1)
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108660853A (en) * | 2018-06-01 | 2018-10-16 | 合肥月煌新型装饰材料有限公司 | A kind of PVC foam Wallpaper paste material composition |
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| JP2005125781A (en) * | 2003-09-30 | 2005-05-19 | Dainippon Printing Co Ltd | Decorative material |
| CN202401345U (en) * | 2012-01-06 | 2012-08-29 | 昆山视之高涂层材料有限公司 | Traceless suction-cup type paste wallpaper |
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| CN206357721U (en) * | 2016-12-14 | 2017-07-28 | 杭州尊尚壁装饰材料有限公司 | A kind of silk wallpaper |
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2017
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005125781A (en) * | 2003-09-30 | 2005-05-19 | Dainippon Printing Co Ltd | Decorative material |
| CN202401345U (en) * | 2012-01-06 | 2012-08-29 | 昆山视之高涂层材料有限公司 | Traceless suction-cup type paste wallpaper |
| CN202626712U (en) * | 2012-06-11 | 2012-12-26 | 汪煜伟 | Seamless wall cloth |
| CN104060500A (en) * | 2014-05-30 | 2014-09-24 | 苏州国昊壁纸有限公司 | Environment-friendly antibacterial moistureproof wallpaper |
| CN104074099A (en) * | 2014-05-30 | 2014-10-01 | 苏州国昊壁纸有限公司 | Environment-friendly antibacterial and mildew-proof wallpaper |
| CN104328887A (en) * | 2014-11-10 | 2015-02-04 | 漪丽科技(深圳)有限公司 | Multi-function protection wallpaper |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108660853A (en) * | 2018-06-01 | 2018-10-16 | 合肥月煌新型装饰材料有限公司 | A kind of PVC foam Wallpaper paste material composition |
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