CN107217537A - Change colour wallpaper and preparation method thereof - Google Patents
Change colour wallpaper and preparation method thereof Download PDFInfo
- Publication number
- CN107217537A CN107217537A CN201610398185.5A CN201610398185A CN107217537A CN 107217537 A CN107217537 A CN 107217537A CN 201610398185 A CN201610398185 A CN 201610398185A CN 107217537 A CN107217537 A CN 107217537A
- Authority
- CN
- China
- Prior art keywords
- discoloration
- temperature
- layer
- wallpaper
- sensing color
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/18—Paper- or board-based structures for surface covering
- D21H27/20—Flexible structures being applied by the user, e.g. wallpaper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
Landscapes
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
The present invention provides a kind of discoloration wallpaper, wherein described wallpaper includes base paper layer and the photochromic layer on the surface for being laminated in the base paper layer, the photochromic layer includes temperature-sensing color-changing material, and the temperature-sensing color-changing material forms at least one of pattern and word shape on the surface of the base paper layer.Above-mentioned discoloration wallpaper, the heat discoloration powder of photochromic layer, which can be varied with temperature, shows different pattern, word or colors, enriches the visual experience of wallpaper, increases the aesthetics and interest of wallpaper.
Description
Technical field
The present invention relates to wallpaper field, more particularly to a kind of wallpaper and preparation method thereof that changes colour.
Background technology
In recent years, wallpaper was because of material environmental protection, sound-insulation and heat-insulation, lovely luster, and good visual effect and construction are all
The multiple advantage such as the phase is short, at home and abroad increasing consumer's selection wallpaper, has been current wall using wallpaper
The trend trend of face finishing.
At the same time, as the improvement of people's living standards, people wallpaper has not only been rested on it is attractive in appearance
Aspect, has begun to pursue more features.Many consumers like the wallpaper of different colours, lead to simultaneously
Cross discoloration prompt temperature, therefore, develop it is a can according to weather thermograde change color, in wallpaper
The upper wallpaper for forming different colour bands, has become the urgent demand of consumer.
The content of the invention
Based on this, it is necessary to there is no temperature sensing function for wallpaper, though and indoor coating have temperature sensing function its
Application method is complicated, long in time limit, the problem of inconvenience is changed, and proposes a kind of discoloration wallpaper and its manufacture method.
A kind of discoloration wallpaper that the present invention is provided, wherein the wallpaper includes base paper layer and is laminated in the base
The photochromic layer on the surface of ply of paper, the photochromic layer includes temperature-sensing color-changing material, and the temperature-sensing color-changing material is in institute
The surface for stating base paper layer forms at least one of pattern and word shape.
In one of the embodiments, the temperature-sensing color-changing material includes heat discoloration powder.
In one of the embodiments, the temperature-sensing color-changing material includes at least two heat discoloration powder.
In one of the embodiments, the photochromic layer is prepared by change mill base material, and the change mill base material is with weight
Number meter, including following components：
In one of the embodiments, the photochromic layer is by the change mill base material system comprising different temperature-sensing color-changing materials
It is standby, change mill base material formation at least one of pattern and the word shape comprising different temperature-sensing color-changing materials.
In one of the embodiments, the discoloration wallpaper also includes protective clear layer, the protective clear layer
It is layered in the discoloration layer surface.
A kind of preparation method for discoloration wallpaper that the present invention is provided, including the surface of base paper layer coating or
Printing prepares photochromic layer, and the photochromic layer includes temperature-sensing color-changing material, and the temperature-sensing color-changing material is in the base
The surface of ply of paper forms at least one of pattern and word shape.
In one of which embodiment, the photochromic layer is prepared by change mill base material, and the change mill base material is with weight
Measure number meter, including following components：
In one of which embodiment, the change mill base material is prepared using following method：
Step A:Dioctyl phthalate is well mixed with vinyl chloride mixture A is made；
Step B：By foaming agent, D80 environmentally friendly solvents oil, calcium carbonate, plasticizer, stabilizer, titanium dioxide,
The mixture A and well mixed obtained mixture B of temperature-sensing color-changing material；
Step C：By thickener, rate of drying conditioning agent, the well mixed obtained pulp layers of mixture B
Slurry.
In one of which embodiment, the viscosity for becoming mill base material is 15000~20000cps.
Above-mentioned discoloration wallpaper, the heat discoloration powder of photochromic layer, which can be varied with temperature, shows different patterns, text
Word or color, enrich the visual experience of wallpaper, increase the aesthetics and interest of wallpaper；
Above-mentioned discoloration wallpaper, the heat discoloration powder of photochromic layer can show different patterns, word according to temperature
Or color, visual cues temperature change, point out consumer to go out plus clothing or regulation indoor temperature.
Above-mentioned discoloration wallpaper preparation method, can from dioctyl phthalate and vinyl chloride as slurry film forming matter
To form the third dimension of a kind of " pebble " on wallpaper surface；
Above-mentioned discoloration wallpaper preparation method, because photochromic layer anti-scratch power is stronger, can greatly improve the anti-of wallpaper
Aqueous and anti-scouring performance；
Above-mentioned discoloration wallpaper preparation method, preparation method is simple, raw material environmental protection, to free of air pollution, construction
Can faster it be moved in after phase section, finishing.
Brief description of the drawings
Fig. 1 is the discoloration wallpaper structural representation of embodiment 1；
Fig. 2 is the discoloration wallpaper temperature-sensitive display schematic diagram of embodiment 2；
Fig. 3 is the discoloration wallpaper structural representation of embodiment 5.
Embodiment
It is an object of the invention to provide one kind discoloration wallpaper and preparation method thereof, the discoloration wallpaper is not due to using
Same temperature-sensitive powder or the combination of a variety of temperature-sensitive powder, color, pattern or the text that can be shown under different temperature conditionss
Word is different, can enrich the visual experience of wallpaper, increases the aesthetic degree and interest of wallpaper.In addition, the change
Color wallpaper can show different colors, pattern or word, temperature indicator change according to temperature.
The present invention discoloration wallpaper, including base paper layer and be laminated in the base paper layer surface photochromic layer,
The photochromic layer includes temperature-sensing color-changing material, and the temperature-sensing color-changing material forms figure on the surface of the base paper layer
At least one of case and word shape.
It is preferred that, temperature-sensing color-changing material includes heat discoloration powder, more there is choosing, and temperature-sensing color-changing material is included extremely
Few two kinds of heat discoloration powder.
It is preferred that, photochromic layer has change mill base material to prepare, and becomes mill base material in terms of parts by weight, including following components：
It is preferred that, foaming agent can be azodicarbonamide.
It is preferred that, plasticizer can be epoxidized soybean oil.
It is preferred that, stabilizer can be potassium zinc composite stabilizer.
It is preferred that, thickener can be the one or more in lithium magnesium silicate and aluminium-magnesium silicate.
It is preferred that, rate of drying conditioning agent can be the one or more in 1,3-BDO, n-butanol.
It is preferred that, base paper layer can be the one or more in non-woven fabrics, pure paper or PVC plastic.
It is preferred that, temperature-sensing color-changing material includes heat discoloration powder.
It is preferred that, the basic discoloring temperature of heat discoloration powder is：-5℃、0℃、5℃、10℃、16℃、
One or more in 21 DEG C, 31 DEG C, 33 DEG C, 38 DEG C., can be by coloured bleach or by nothing during discoloration
Discoloration is coloured, can change colour with cataclysm or progressively.By taking red heat discoloration powder as an example, it is in 31 DEG C of discolorations, temperature
Degree is red when being less than 31 DEG C, to be colourless when temperature is higher than 31 DEG C.
It is preferred that, heat discoloration powder basic colors is：It is black, red, yellow, green, blueness, dark blue
One or more in color, black.
Specifically, the discoloration wallpaper of the present invention is prepared by following methods：
Slurry is prepared, including：
Step A:By the vinyl chloride that dioctyl phthalate and parts by weight that parts by weight are 5-20 parts are 30-50 parts
Well mixed obtained mixture A；
Step B：By foaming agent that parts by weight are 1-2 parts, the D80 environmentally friendly solvents that parts by weight are 1-5 parts
Oil, the calcium carbonate that parts by weight are 10-30 parts, the plasticizer that parts by weight are 10-30 parts, parts by weight are
1-5 parts of stabilizer, the titanium dioxide that parts by weight are 10-20 parts, the mixture that parts by weight are 35-70 parts
A and 5-35 parts of one or more well mixed obtained mixture B of heat discoloration powder；
Step C：By thickener that parts by weight are 1-3 parts, the rate of drying regulation that parts by weight are 1-3 parts
Agent, parts by weight are well mixed the obtained slurry for 73-197 parts of mixture B.
It is preferred that, slurry is coated or is printed on base paper layer and forms photochromic layer, the heat discoloration material in slurry
Material is in base paper layer surface formation at least one of pattern and word shape.
The present invention is further described with reference to specific embodiment.
Embodiment 1
Using non-woven fabrics as base paper layer, blue heat discoloration powder and Huang are sprayed in the way of interval on non-woven fabrics
Color sensation temperature color-change powder prepares the photochromic layer of 0.1mm thickness, in side coating thickness of the photochromic layer away from base paper layer
Transparent pulp layer is prepared for 5mm slurries, discoloration wallpaper A1 is made.
Refer to shown in Fig. 1, the photochromic layer that discoloration wallpaper A1 is included on base paper layer 1, base paper layer 1 includes indigo plant
Slurry covered with layer of transparent on color sensation temperature photochromic layer band 21 and yellow heat discoloration layer band 22, photochromic layer
Layer 3, the wallpaper A1 that changes colour at a certain temperature shows blue stripe, yellow cord or blue yellow alternate striped.
Embodiment 2
Using PVC plastic as base paper layer, a layer thickness is sprayed in PVC plastic and is made for 0.1mm slurry
For pulp layer, different temperature-sensitive powder are sprayed in the side for coating slurry, to be formed with certain pattern or
It is the red heat discoloration powder of spraying in the photochromic layer of word, the present embodiment to form flower motif, yellow temperature-sensitive
Color-change powder is to form cloud pattern, and the thickness of spraying temperature-sensitive powder is 0.5mm, and discoloration wallpaper A2 is made.
Refer to shown in Fig. 2, discoloration wallpaper A2 can show the flower motif of red, yellow at a certain temperature
Cloud pattern or show simultaneously red flower motif and yellow cloud pattern.
Embodiment 3
Using common paper as base paper layer, one layer of 0.5mm thickness pulp layer slurry of spraying is used as slurry in common paper
The bed of material, sprays blue heat discoloration powder at the side interval for coating slurry and prepares the photochromic layer that thickness is 1mm,
Discoloration wallpaper A3 is made.
Discoloration wallpaper A3 shows blue stripe or does not show blue stripe at a certain temperature.
Embodiment 4
Using non-woven fabrics as base paper layer, sprayed on non-woven fabrics blue heat discoloration powder, green heat discoloration powder,
Red heat discoloration powder, the mixture of black heat discoloration powder are coating heat discoloration powder as photochromic layer
Side high temperature printing layer of transparent slurry, discoloration wallpaper A4 is made.
Wallpaper A4 change colour at different temperature, can have blueness, green, the red, vision of black respectively
Effect.
Embodiment 5
Weigh 5g dioctyl phthalates add agitator in, then weigh 30g vinyl chloride add agitator in
2000r/min stirs；Weigh 1g azodicarbonamides, 1gD80 environmentally friendly solvents oil, 10g calcium carbonate,
The blue heat discoloration powder of 10g epoxidized soybean oils, 1g potassium zinc composite stabilizer, 10g titanium dioxides, 5g, which is added, to be stirred
Mix in bucket and to be stirred with 2000r/min；1g lithium magnesium silicates, 1g n-butanols is weighed to add in agitator with 2000
R/min stirs；The pulp layer slurry B1 that viscosity is 15000cps is made.
Weigh 5g dioctyl phthalates add agitator in, then weigh 30g vinyl chloride add agitator in
2000r/min stirs；Weigh 1g azodicarbonamides, 1gD80 environmentally friendly solvents oil, 10g calcium carbonate,
10g epoxidized soybean oils, 1g potassium zinc composite stabilizer, 10g titanium dioxides, 5g yellow heat discolorations powder are added and stirred
Mix in bucket and to be stirred with 2000r/min；1g lithium magnesium silicates, 1g n-butanols is weighed to add in agitator with 2000
R/min stirs；The pulp layer slurry B2 that viscosity is 17000cps is made.
Pulp layer slurry B1, B2 high temperature in the way of interval are printed in non-woven fabrics base paper, discoloration wall is made
Paper A5.
Refer to shown in Fig. 3, the photochromic layer that discoloration wallpaper A5 is included on base paper layer 1, base paper layer 1 includes indigo plant
Color sensation temperature photochromic layer band 21 and yellow heat discoloration layer band 22, the wallpaper A5 that changes colour at a certain temperature show
Show blue stripe, yellow cord or blue yellow alternate striped.
Embodiment 6
Weigh 20g dioctyl phthalates add agitator in, then weigh 50g vinyl chloride add agitator in
2500r/min stirs；Weigh 2g azodicarbonamides, 5gD80 environmentally friendly solvents oil, 30g calcium carbonate,
30g epoxidized soybean oils, 5g potassium zinc composite stabilizer, 20g titanium dioxides are added to be stirred in agitator with 2500r/min
Mix uniform；Weigh and stirred in 3g lithium magnesium silicates, 3g1,3- butanediols addition agitator with 2500r/min；
The pulp layer slurry B3 that viscosity is 20000cps is made.
Weigh 20g dioctyl phthalates add agitator in, then weigh 50g vinyl chloride add agitator in
2500r/min stirs；Weigh 2g azodicarbonamides, 5gD80 environmentally friendly solvents oil, 30g calcium carbonate,
The blue heat discoloration powder of 30g epoxidized soybean oils, 5g potassium zinc composite stabilizer, 20g titanium dioxides, 35g, which is added, to be stirred
Mix in bucket and to be stirred with 2500r/min；3g lithium magnesium silicates, 3g1,3- butanediols is weighed to add in agitator
Stirred with 2500r/min；The pulp layer slurry B4 that viscosity is 20000cps is made.
Weigh 20g dioctyl phthalates add agitator in, then weigh 50g vinyl chloride add agitator in
2500r/min stirs；Weigh 2g azodicarbonamides, 5gD80 environmentally friendly solvents oil, 30g calcium carbonate,
30g epoxidized soybean oils, 5g potassium zinc composite stabilizer, 20g titanium dioxides, 35g black heat discolorations powder are added and stirred
Mix in bucket and to be stirred with 2500r/min；3g lithium magnesium silicates, 3g1,3- butanediols is weighed to add in agitator
Stirred with 2500r/min；The pulp layer slurry B5 that viscosity is 20000cps is made.
Pulp layer slurry B4 is printed in non-woven fabrics base paper with plum blossom design high temperature, by pulp layer slurry B5
Be printed on certain word high temperature in non-woven fabrics base paper, high temperature be printed with pulp layer slurry B4 or B5 with
Outer scope high temperature printing slurry layer slurry B3, is made discoloration wallpaper A6.
Change colour wallpaper A6 blue plum blossom design or black letters pattern, or discoloration wallpaper at a certain temperature
A6 shows blue plum blossom design and black letters pattern simultaneously at a certain temperature.
Embodiment 7
Weigh 20g dioctyl phthalates add agitator in, then weigh 50g vinyl chloride add agitator in
2500r/min stirs；Weigh 2g azodicarbonamides, 5gD80 environmentally friendly solvents oil, 30g calcium carbonate,
The blue heat discoloration powder of 30g epoxidized soybean oils, 5g potassium zinc composite stabilizer, 20g titanium dioxides, 5g, 5g are green
Color sensation temperature color-change powder, 5g yellow heat discolorations powder, 5g black heat discolorations powder are added in agitator with 2500
R/min stirs；Weigh and stirred in 3g lithium magnesium silicates, 3g1,3- butanediols addition agitator with 2500r/min
Mix uniform；The pulp layer slurry B6 that viscosity is 19000cps is made.
Pulp layer slurry B6 is sprayed in PVC plastic base paper, discoloration wallpaper A7 is made.
The color that discoloration wallpaper A7 is shown changes with thermograde, and different colors are presented at different temperature.
Embodiment 8
Weigh 10g dioctyl phthalates add agitator in, then weigh 40g vinyl chloride add agitator in
2500r/min stirs；Weigh 1.5g azodicarbonamides, 3gD80 environmentally friendly solvents oil, 20g calcium carbonate,
The blue heat discoloration powder of 20g epoxidized soybean oils, 4g potassium zinc composite stabilizer, 17g titanium dioxides, 4g, 3g are green
Color sensation temperature color-change powder, 5g yellow heat discolorations powder, 1g black heat discolorations powder are added in agitator with 2500
R/min stirs；Weigh and stirred in 2g lithium magnesium silicates, 2g1,3- butanediols addition agitator with 2500r/min
Mix uniform；The pulp layer slurry B7 that viscosity is 19000cps is made.
Pulp layer slurry B7 is sprayed on non-woven fabrics, discoloration wallpaper A8 is made.
The color that discoloration wallpaper A8 is shown is varied with temperature, and different colors are presented at different temperature.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed,
But therefore it can not be interpreted as the limitation to the scope of the claims of the present invention.It should be pointed out that for this area
Those of ordinary skill for, without departing from the inventive concept of the premise, can also make it is some deformation and
Improve, these belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be with appended
Claim is defined.
Claims (10)
1. one kind discoloration wallpaper, it is characterised in that the wallpaper includes base paper layer and is laminated in the base paper
The photochromic layer on the surface of layer, the photochromic layer includes temperature-sensing color-changing material, and the temperature-sensing color-changing material is described
The surface of base paper layer forms at least one of pattern and word shape.
2. discoloration wallpaper according to claim 1, it is characterised in that the temperature-sensing color-changing material includes
Heat discoloration powder.
3. discoloration wallpaper according to claim 2, it is characterised in that the temperature-sensing color-changing material includes
At least two heat discoloration powder.
4. change colour wallpaper according to Claims 2 or 3, it is characterised in that the photochromic layer is by change mill base
Prepared by material, the change mill base material is in terms of parts by weight, including following components：
5. discoloration wallpaper according to claim 4, it is characterised in that the photochromic layer is by including difference
Prepared by the change mill base material of temperature-sensing color-changing material, the change mill base material formation figure comprising different temperature-sensing color-changing materials
At least one of case and word shape.
6. the discoloration wallpaper according to any one of claim 1 to 5, it is characterised in that the discoloration wall
Paper also includes protective clear layer, and the protective clear layer is layered in the discoloration layer surface.
7. a kind of preparation method for the wallpaper that changes colour, it is characterised in that be included in the surface coating of base paper layer or print
Brush prepares photochromic layer, and the photochromic layer includes temperature-sensing color-changing material, and the temperature-sensing color-changing material is in the base paper
The surface of layer forms at least one of pattern and word shape.
8. the preparation method of discoloration wallpaper according to claim 7, it is characterised in that the photochromic layer
Prepared by change mill base material, the change mill base material is in terms of parts by weight, including following components：
9. the method for discoloration wallpaper according to claim 8, it is characterised in that the change mill base material is adopted
Prepare with the following method：
Step A:Dioctyl phthalate is well mixed with vinyl chloride mixture A is made；
Step B：By foaming agent, D80 environmentally friendly solvents oil, calcium carbonate, plasticizer, stabilizer, titanium dioxide,
The mixture A and well mixed obtained mixture B of temperature-sensing color-changing material；
Step C：By thickener, rate of drying conditioning agent, the well mixed obtained pulp layers of mixture B
Slurry.
10. the method for discoloration wallpaper according to claim 8, it is characterised in that the change mill base material
Viscosity be 15000~20000cps.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398185.5A CN107217537A (en) | 2016-06-06 | 2016-06-06 | Change colour wallpaper and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610398185.5A CN107217537A (en) | 2016-06-06 | 2016-06-06 | Change colour wallpaper and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN107217537A true CN107217537A (en) | 2017-09-29 |
Family
ID=59928116
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CN201610398185.5A Pending CN107217537A (en) | 2016-06-06 | 2016-06-06 | Change colour wallpaper and preparation method thereof |
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| Country | Link |
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| CN109479841A (en) * | 2018-11-19 | 2019-03-19 | 安徽宏飞钓具有限公司 | Heat discoloration bait |
| CN112211032A (en) * | 2020-09-02 | 2021-01-12 | 星光印刷（苏州）有限公司 | Preparation process of color-changing printing paper based on pH color-changing sol |
| CN112885026A (en) * | 2021-01-15 | 2021-06-01 | 浙江大华技术股份有限公司 | Fire monitoring system, method and device, monitoring equipment and storage medium |
| CN114312083A (en) * | 2021-12-03 | 2022-04-12 | 北京特普丽装饰装帧材料有限公司 | Temperature-sensitive intelligent wallpaper and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109479841A (en) * | 2018-11-19 | 2019-03-19 | 安徽宏飞钓具有限公司 | Heat discoloration bait |
| CN112211032A (en) * | 2020-09-02 | 2021-01-12 | 星光印刷（苏州）有限公司 | Preparation process of color-changing printing paper based on pH color-changing sol |
| CN112885026A (en) * | 2021-01-15 | 2021-06-01 | 浙江大华技术股份有限公司 | Fire monitoring system, method and device, monitoring equipment and storage medium |
| CN114312083A (en) * | 2021-12-03 | 2022-04-12 | 北京特普丽装饰装帧材料有限公司 | Temperature-sensitive intelligent wallpaper and preparation method thereof |
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