CN104533044A - Temperature sensing color changing space pattern wall poster and preparing method thereof - Google Patents

Temperature sensing color changing space pattern wall poster and preparing method thereof Download PDF

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Publication number
CN104533044A
CN104533044A CN201410836763.XA CN201410836763A CN104533044A CN 104533044 A CN104533044 A CN 104533044A CN 201410836763 A CN201410836763 A CN 201410836763A CN 104533044 A CN104533044 A CN 104533044A
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layer
relief
pattern
heat discoloration
dimensional
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CN201410836763.XA
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Chinese (zh)
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赖信潮
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赖信潮
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Priority to CN201410836763.XA priority Critical patent/CN104533044A/en
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Abstract

The invention discloses a temperature sensing color changing space pattern wall poster and a preparing method thereof. The wall poster comprises base paper which is used as a bottom layer, a pattern layer and a relief three-dimensional color changing layer which can show a relief three-dimensional effect. The pattern layer is arranged on the base paper. The relief three-dimensional color changing layer is arranged on the pattern layer and covers patterns on the pattern layer partially or wholly. An uneven structure is formed on the upper face of the pattern layer, and then the relief three-dimensional effect is shown. The relief three-dimensional color changing layer can generate color changing along with temperature changing, color changing comprises color development and transparency decoloration, and then the effect of covering or showing on pattern color covered on the pattern layer. The temperature sensing color changing space pattern wall poster has the advantages that color pattern changing is rich, color changing reaction speed is high, sensitivity is high, the three-dimensional visual effect is achieved, waterproof performance is achieved, a wall face cannot be damaged, cleaning is easy, implementation is easy, and the temperature sensing color changing space pattern wall poster can be widely used for indoor decorating.

Description

A kind of heat discoloration space pattern wall pastes and preparation method thereof
Technical field
The present invention relates to the technical field of interior decoration product, refer in particular to a kind of heat discoloration space pattern wall and paste and preparation method thereof.
Background technology
It is house ornamentation on a kind of wall oneself can easily settled that wall pastes, and it is simple that it puts up method.It is not only succinct convenient but also randomness is very strong, and decorative effect also very directly perceived, becomes the ornament of designer's overriding concern when interspersing the interior space.
And in existing technology, as Chinese patent CN 103061477 A, a kind of energy heat discoloration wallpaper, comprise base paper and photochromic layer, photochromic layer is printed on base paper.This technical pattern is single, and color changeable effect is simple, without stereoeffect.And for example Chinese patent CN 203866646 U, a kind of temperature sensing color changing wallpaper, comprise basic unit's wallpaper, photochromic layer and patterned layer, be connected in turn from bottom to top by basic unit's wallpaper, photochromic layer and patterned layer, adhesive layer is provided with between basic unit's wallpaper and photochromic layer, photochromic layer is pasted through adhesive layer and is connected on basic unit's wallpaper, patterned layer is provided with fireproof transparent layer, is filled with heat-sensitive variable colour powder in photochromic layer.This technical pattern is complicated, and cost of production is high, changes by photochromic layer generation variable color the color changeable effect underaction that patterned layer color produces, cannot Partial controll; And photochromic layer being provided with patterned layer and fireproof transparent layer, photochromic layer does not contact with air, and metachromasia speed is sensitive not; Stereoeffect is not had yet.
Along with living standard improves, the requirement that people paste interior decoration wall is more and more higher, for this reason, the work that develops that wall pastes new varieties never stops, can abundant, the metachromasia rate-sensitive of a kind of color pattern of development change, have the Novel wall of stereoeffect to paste, become the problem of manufacturing enterprise and customer's concern.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, provide a kind of color pattern to change abundant, metachromasia rate-sensitive, have the heat discoloration space pattern wall of stereoscopic visual effect to paste and preparation method thereof.
For achieving the above object, its heat discoloration space pattern wall of technical scheme provided by the present invention pastes and comprises as the base paper of bottom, patterned layer and the three-dimensional photochromic layer of relief that can present relief stereoeffect, wherein, described patterned layer is located on base paper, the three-dimensional photochromic layer of described relief is located in patterned layer, and the pattern in local or all this patterned layer of covering, on patterned layer, be formed with rough structure, and then present relief stereoeffect; The three-dimensional photochromic layer of described relief can vary with temperature and produce color change, and color change comprises colour developing and transparent colour killing, and then pattern color capped in patterned layer is played to the effect hiding or manifest.
Be provided with pattern protection hyaline layer between described patterned layer and the three-dimensional photochromic layer of relief, the surface of this pattern protection hyaline layer all standing patterned layer, shields to patterned layer.
The relief stereoeffect of the three-dimensional photochromic layer of described relief is made by the one or more combination of dripping in glue, the thick twine print of 200 order-60 order, VU photocuring, bat printing, transfer printing, artistic carving; The thickness of the three-dimensional photochromic layer of described relief is at more than 0.1mm.
The three-dimensional photochromic layer of described relief mixes obtained by heat discoloration powder with transparent resin, or mixes obtained with transparent PVC ink by heat discoloration powder; Wherein, the quality of described heat discoloration powder accounts for transparent resin 5-30%, account for transparent PVC ink 5-30%, described transparent resin is the one in polyvinyl chloride resin, acrylic resin, epoxy resin, mylar, EVA resin, vinyl chloride-vinyl acetate resin, unsaturated polyester (UP), epoxy acrylate, urethane acrylate.
Described base paper is pure paper, PVC can move one in self-adhesive paper, electrostatic film.
Described patterned layer is the one or more combination in printed layers, painting layer, smear layer, silk-screen layer.
Described pattern protection hyaline layer is pattern waterproofing protection hyaline layer.
Described pattern waterproofing protection hyaline layer is transparent emulsion layer coating or transparent resin film layer.
The preparation method that heat discoloration space pattern wall of the present invention pastes, comprises the following steps:
1) the required base paper of preparation, pastes bottom as wall;
2) on described base paper by printing, paint, smear, one or more combination in silk screen printing process obtains required patterned layer;
3) in described patterned layer, the three-dimensional photochromic layer of the required relief that can present relief stereoeffect is obtained by the one or more combination of dripping in glue, 200 order-60 order thick twine print, VU photocuring, bat printing, transfer printing, artistic carving, wherein, the three-dimensional photochromic layer local of described relief or the pattern all covered in this patterned layer, its thickness and area coverage are determined according to the actual requirements, on patterned layer, be formed with rough structure, and then relief stereoeffect can be presented; So far, the preparation that heat discoloration space pattern wall pastes just is completed.
When requiring to strengthen protecting the pattern in patterned layer, can after obtained patterned layer, this patterned layer is coated with anti-oxidant, waterproof, nontoxic, resistant to elevated temperatures transparent latex paint or transparent resin film, be formed with pattern protection hyaline layer, on this pattern protection hyaline layer, obtain the three-dimensional photochromic layer of the required relief that can present relief stereoeffect by the one or more combination of dripping in glue, 200 order-60 order thick twine print, VU photocuring, bat printing, transfer printing, artistic carving more afterwards, the preparation that heat discoloration space pattern wall pastes can be completed; And when requiring the three-dimensional photochromic layer of relief to present three-dimensional right angle effect, then 200 order-60 order half tone silk-screen systems adopting three-dimensional right angle PVC ink mixing heat discoloration powder and photoresists to make obtain.
Compared with prior art, tool has the following advantages and beneficial effect in the present invention:
1, relative common plane color changeable effect, the three-dimensional photochromic layer of relief of the present invention only needs the pattern in local or whole coverage diagram pattern layer, rough structure is formed on patterned layer, just can produce relief stereoeffect, raw materials for production cost can be saved the while of producing easy, also meet the enjoyment of people's vision and sense of touch.
2, the three-dimensional photochromic layer of relief also has pattern effect according to the area shapes itself covered, change along with temperature can hide and manifest the pattern color of patterned layer, and the three-dimensional photochromic layer of relief can produce strong visual contrast with the patterned layer covered without the three-dimensional photochromic layer of relief, can make more abundant variation effect.
3, the three-dimensional photochromic layer of relief directly contacts with air, and color changeable effect is sensitiveer to temperature reaction, and slightly giving a puff can temperature-sensitive change.
4, heat discoloration space pattern wall of the present invention paste waterproof, do not hinder metope, easy to clean.
Accompanying drawing explanation
Fig. 1 is one of structural representation of heat discoloration space pattern wall of the present invention subsides.
Fig. 2 is the structural representation two that heat discoloration space pattern wall of the present invention pastes.
Fig. 3 is the design sketch that heat discoloration space pattern wall of the present invention is attached to when temperature declines.
Detailed description of the invention
Below in conjunction with specific embodiment, the invention will be further described.
As depicted in figs. 1 and 2, heat discoloration space pattern wall described in the present embodiment pastes, include base paper 1, patterned layer 2, pattern protection hyaline layer 3 (is accepted or rejected according to the actual requirements, this pattern protection hyaline layer 3 can not be prepared, usually when requiring to strengthen protecting the pattern in patterned layer 2, just increase this pattern protection hyaline layer 3) and the three-dimensional photochromic layer 4 of relief of relief stereoeffect can be presented, wherein, the bottom that described base paper 1 pastes as this heat discoloration space pattern wall, it can be pure paper, PVC can move self-adhesive paper, one in electrostatic film, and in the present embodiment, specifically select and do not hinder metope, the PVC of trace can not move self-adhesive paper, described patterned layer 2 is located on base paper 1, is the one or more combination in printed layers, painting layer, smear layer, silk-screen layer, is that the one or more combination by printing, painting, smear, in silk screen printing process is made, described pattern protection hyaline layer 3 is located in patterned layer 2, be specially pattern waterproofing protection hyaline layer, anti-oxidant, waterproof, nontoxic, resistant to elevated temperatures transparent latex paint or roof made of transparent resin is adopted to obtain, can protect that patterned layer 2 is not oxidized fades, also avoid in process of production to the destruction of patterned layer 2, the three-dimensional photochromic layer 4 of described relief is located on pattern protection hyaline layer 3, and pattern in local or all coverage diagram pattern layer 2 (and in the present embodiment, pattern just in local complexity patterned layer 2), on pattern protection hyaline layer 3, be formed with rough structure, and then present relief stereoeffect.Certainly; in actual production; when not needing above-mentioned pattern to protect hyaline layer 3; the three-dimensional photochromic layer 4 of described relief is directly prepared in patterned layer 2; also local or whole pattern covered in this patterned layer 2; its thick end and area coverage are determined on a case-by-case basis, and the three-dimensional photochromic layer 4 of this relief is formed with rough structure on patterned layer 2, and then can present required relief stereoeffect.
The three-dimensional photochromic layer 4 of described relief mixes obtained by heat discoloration powder with transparent resin, or mixes obtained with transparent PVC ink by heat discoloration powder; Wherein, the quality of described heat discoloration powder accounts for transparent resin 5-30%, account for transparent PVC ink 5-30%, described transparent resin is the one in polyvinyl chloride resin, acrylic resin, epoxy resin, mylar, EVA resin, vinyl chloride-vinyl acetate resin, unsaturated polyester (UP), epoxy acrylate, urethane acrylate.The relief stereoeffect of the three-dimensional photochromic layer 4 of this relief is made by the one or more combination of dripping in glue, the thick twine print of 200 order-60 order, VU photocuring, bat printing, transfer printing, artistic carving, good touch sense can be obtained when three-dimensional photochromic layer 4 thickness of relief is at more than 0.1mm, be 0.1mm-1mm best results with thickness, and not easily fracture.
Along with rising, the decline of temperature, the three-dimensional photochromic layer 4 of the relief described in the present embodiment can produce color change repeatedly, and color change comprises colour developing and transparent colour killing, when actual production, we with 22 DEG C for critical point, when temperature is lower than 22 DEG C, the three-dimensional photochromic layer 4 of relief develops the color, as shown in Figure 3; When temperature is higher than 22 DEG C, the transparent colour killing of the three-dimensional photochromic layer 4 of relief; And when temperature is in 22 DEG C, be gray zone, the three-dimensional photochromic layer 4 of this relief presents half colour developing, translucent.The present invention, by the color change of the three-dimensional photochromic layer 4 of relief, realizes playing to pattern color capped in patterned layer 2 effect hiding or manifest, can produce strong visual contrast, and then can make more abundant variation effect.In addition, because the three-dimensional photochromic layer 4 of relief of the present invention is direct and contacting external air, therefore, its color changeable effect is sensitiveer to temperature reaction, and slightly giving a puff can temperature-sensitive change.
Be below the concrete preparation method that the present embodiment above-mentioned heat discoloration space pattern wall pastes, its process is as follows:
1) stir through the direct acting of roller with PVC raw material, roller bearing rotates and the film that rolls out of high temperature, enclose one deck back of the body by back of the body painting machine at the back side of film and be coated with, finally stick on strippable paper, produce PVC and can move self-adhesive paper as required base paper 1;
2) on described base paper 1 by printing, paint, smear, one or more combination in silk screen printing process obtains required patterned layer 2;
3) in described patterned layer 2, anti-oxidant, waterproof, nontoxic, resistant to elevated temperatures transparent latex paint or transparent resin film is coated with, obtained required pattern protection hyaline layer 3;
4) pass through to drip glue on described pattern protection hyaline layer 3, the thick twine print of 200 order-60 order, VU photocuring, bat printing, transfer printing, one or more combination in artistic carving obtains the three-dimensional photochromic layer 4 of the required relief that can present relief stereoeffect, wherein, the pattern of the three-dimensional photochromic layer 4 of described relief locally or in whole coverage diagram pattern layer 2 (and in the present embodiment, just local complexity), its thickness and area coverage are determined according to the actual requirements, because the three-dimensional photochromic layer 4 of this relief is formed with rough structure on pattern protection hyaline layer 3, and then relief stereoeffect can be presented, so far, the preparation that heat discoloration space pattern wall pastes just is completed.
Remarks: when not needing above-mentioned pattern to protect hyaline layer 3 to protect the pattern of patterned layer 2, when preparing the subsides of this heat discoloration space pattern wall, the three-dimensional photochromic layer 4 of described relief is also by dripping glue, the thick twine print of 200 order-60 order, VU photocuring, bat printing, transfer printing, one or more combination in artistic carving is directly prepared in patterned layer 2, also local or whole pattern covered in this patterned layer 2, its thick end and area coverage are determined on a case-by-case basis, and the three-dimensional photochromic layer 4 of this relief is formed with rough structure on patterned layer 2, and then required relief stereoeffect can be presented.
In addition, when requiring the three-dimensional photochromic layer 4 of relief to present three-dimensional right angle effect, 200 order-60 orders then adopting three-dimensional right angle PVC ink mixing heat discoloration powder and common photosensitive glue to make obtain than general slightly thick half tone silk-screen, its temperature of attentional manipulation during oven dry, dry but can not temperature too high, otherwise the effect at its three-dimensional right angle can be destroyed.
In sum, the three-dimensional photochromic layer of relief of the present invention only needs the pattern in local or whole coverage diagram pattern layer, be formed with rough structure, just can produce relief stereoeffect, raw materials for production cost can be saved the while of producing easy, also meet the enjoyment of people's vision and sense of touch, simultaneously because the three-dimensional photochromic layer of this relief directly contacts with air, so color changeable effect is sensitiveer to temperature reaction, slightly gives a puff and can change by temperature-sensitive; In addition, the three-dimensional photochromic layer of relief also has pattern effect according to the area shapes itself covered, change along with temperature can hide and manifest the pattern color of patterned layer, and the three-dimensional photochromic layer of relief can produce strong visual contrast with the patterned layer covered without the three-dimensional photochromic layer of relief, and then more abundant variation effect can be made.This compared to existing technology, heat discoloration space pattern wall of the present invention paste have that color pattern change is abundant, metachromasia rate-sensitive, have stereoscopic visual effect, waterproof, do not hinder metope, the feature such as easy to clean, implement easily, interior decoration can be widely used in, market prospects are good, are worthy to be popularized.
The examples of implementation of the above are only the preferred embodiment of the present invention, not limit practical range of the present invention with this, therefore the change that all shapes according to the present invention, principle are done, all should be encompassed in protection scope of the present invention.

Claims (10)

1. a heat discoloration space pattern wall pastes, it is characterized in that: comprise as the base paper (1) of bottom, patterned layer (2) and the three-dimensional photochromic layer (4) of relief that can present relief stereoeffect, wherein, described patterned layer (2) is located on base paper (1), the three-dimensional photochromic layer (4) of described relief is located in patterned layer (2), and the pattern in local or all this patterned layer of covering (2), on patterned layer (2), be formed with rough structure, and then present relief stereoeffect; The three-dimensional photochromic layer (4) of described relief can vary with temperature and produce color change, and color change comprises colour developing and transparent colour killing, and then plays to the upper capped pattern color of patterned layer (2) effect hiding or manifest.
2. a kind of heat discoloration space pattern wall according to claim 1 pastes; it is characterized in that: between described patterned layer (2) and the three-dimensional photochromic layer (4) of relief, be provided with pattern protection hyaline layer (3); the surface of this pattern protection hyaline layer (3) all standing patterned layer (2), shields to patterned layer (2).
3. a kind of heat discoloration space pattern wall according to claim 1 and 2 pastes, and it is characterized in that: the relief stereoeffect of the three-dimensional photochromic layer (4) of described relief is made by the one or more combination of dripping in glue, the thick twine print of 200 order-60 order, VU photocuring, bat printing, transfer printing, artistic carving; The thickness of the three-dimensional photochromic layer (4) of described relief is at more than 0.1mm.
4. a kind of heat discoloration space pattern wall according to claim 1 and 2 pastes, and it is characterized in that: the three-dimensional photochromic layer (4) of described relief mixes obtained by heat discoloration powder with transparent resin, or mixes obtained with transparent PVC ink by heat discoloration powder; Wherein, the quality of described heat discoloration powder accounts for transparent resin 5-30%, account for transparent PVC ink 5-30%, described transparent resin is the one in polyvinyl chloride resin, acrylic resin, epoxy resin, mylar, EVA resin, vinyl chloride-vinyl acetate resin, unsaturated polyester (UP), epoxy acrylate, urethane acrylate.
5. a kind of heat discoloration space pattern wall according to claim 1 pastes, and it is characterized in that: described base paper (1) is pure paper, PVC can move one in self-adhesive paper, electrostatic film.
6. a kind of heat discoloration space pattern wall according to claim 1 pastes, and it is characterized in that: described patterned layer (2) is printed layers, one or more combination in painting layer, smear layer, silk-screen layer.
7. a kind of heat discoloration space pattern wall according to claim 2 pastes, and it is characterized in that: described pattern protection hyaline layer (3) is pattern waterproofing protection hyaline layer.
8. a kind of heat discoloration space pattern wall according to claim 7 pastes, and it is characterized in that: described pattern waterproofing protection hyaline layer is transparent emulsion layer coating or transparent resin film layer.
9. a preparation method for heat discoloration space pattern wall subsides described in claim 1, is characterized in that, comprise the following steps:
1) the required base paper of preparation, pastes bottom as wall;
2) on described base paper by printing, paint, smear, one or more combination in silk screen printing process obtains required patterned layer;
3) in described patterned layer, the three-dimensional photochromic layer of the required relief that can present relief stereoeffect is obtained by the one or more combination of dripping in glue, 200 order-60 order thick twine print, VU photocuring, bat printing, transfer printing, artistic carving, wherein, the three-dimensional photochromic layer local of described relief or the pattern all covered in this patterned layer, its thickness and area coverage are determined according to the actual requirements, on patterned layer, be formed with rough structure, and then relief stereoeffect can be presented; So far, the preparation that heat discoloration space pattern wall pastes just is completed.
10. the preparation method of a kind of heat discoloration space pattern wall subsides according to claim 9, it is characterized in that: when requiring to strengthen protecting the pattern in patterned layer, can after obtained patterned layer, this patterned layer is coated with anti-oxidant, waterproof, nontoxic, resistant to elevated temperatures transparent latex paint or transparent resin film, be formed with pattern protection hyaline layer, pass through to drip glue again on this pattern protection hyaline layer afterwards, the thick twine print of 200 order-60 order, VU photocuring, bat printing, transfer printing, one or more combination in artistic carving obtains the three-dimensional photochromic layer of the required relief that can present relief stereoeffect, the preparation that heat discoloration space pattern wall pastes can be completed, and when requiring the three-dimensional photochromic layer of relief to present three-dimensional right angle effect, then 200 order-60 order half tone silk-screen systems adopting three-dimensional right angle PVC ink mixing heat discoloration powder and photoresists to make obtain.
CN201410836763.XA 2014-12-29 2014-12-29 Temperature sensing color changing space pattern wall poster and preparing method thereof Pending CN104533044A (en)

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Cited By (9)

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Publication number Priority date Publication date Assignee Title
CN105672052A (en) * 2016-01-12 2016-06-15 新乡市胜美壁纸有限公司 Preparation technology of matte imitating foamed wallpaper
CN106639201A (en) * 2016-12-09 2017-05-10 杜尧 Manufacturing method for crystal drop glue wall sticker
CN106634180A (en) * 2016-12-22 2017-05-10 天津环球磁卡股份有限公司 Thick film light-cured resin ink
CN106958169A (en) * 2016-01-09 2017-07-18 侯旭燕 The preparation method that a kind of crystal stereo drips glue wall paster
CN107447594A (en) * 2017-08-15 2017-12-08 广东玉兰集团股份有限公司 A kind of 3D wallpapers and its manufacture method
CN108047818A (en) * 2017-12-27 2018-05-18 惠州德斯坤实业有限公司 Sensitization discoloration ink and its application in field of intelligent cards or wrapping paper field
CN108824848A (en) * 2018-07-12 2018-11-16 广东长合建筑装饰工程有限公司 A kind of glass sunlight house and its decoration method
CN111719340A (en) * 2020-05-11 2020-09-29 江门市恒健实业有限公司 Environment-friendly crystal glue-dripping wall sticker and production process thereof
CN113372795A (en) * 2021-06-17 2021-09-10 四川国鼎建筑设计有限公司 Color-changeable interior wall coating, preparation method thereof and color-changeable interior wall using same

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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106958169A (en) * 2016-01-09 2017-07-18 侯旭燕 The preparation method that a kind of crystal stereo drips glue wall paster
CN105672052A (en) * 2016-01-12 2016-06-15 新乡市胜美壁纸有限公司 Preparation technology of matte imitating foamed wallpaper
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CN108824848A (en) * 2018-07-12 2018-11-16 广东长合建筑装饰工程有限公司 A kind of glass sunlight house and its decoration method
CN111719340A (en) * 2020-05-11 2020-09-29 江门市恒健实业有限公司 Environment-friendly crystal glue-dripping wall sticker and production process thereof
CN113372795A (en) * 2021-06-17 2021-09-10 四川国鼎建筑设计有限公司 Color-changeable interior wall coating, preparation method thereof and color-changeable interior wall using same

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Application publication date: 20150422