CN106634180A - Thick film light-cured resin ink - Google Patents
Thick film light-cured resin ink Download PDFInfo
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- CN106634180A CN106634180A CN201611199631.6A CN201611199631A CN106634180A CN 106634180 A CN106634180 A CN 106634180A CN 201611199631 A CN201611199631 A CN 201611199631A CN 106634180 A CN106634180 A CN 106634180A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/24—Inking and printing with a printer's forme combined with embossing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M1/00—Inking and printing with a printer's forme
- B41M1/26—Printing on other surfaces than ordinary paper
- B41M1/30—Printing on other surfaces than ordinary paper on organic plastics, horn or similar materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
- B41M7/0081—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using electromagnetic radiation or waves, e.g. ultraviolet radiation, electron beams
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Physics & Mathematics (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Electromagnetism (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention provides thick film light-cured resin ink. A preparation method of the ink comprises the following steps: (1) carrying out temperature-raising stirring on resin of bisphenol A epoxy acrylate and 1,6-hexanediol diacrylate until the resin is uniformly dissolved, thus obtaining first ultraviolet light-cured resin; (2) carrying out temperature-raising stirring on acrylic resin, 1,6-hexanediol diacrylate and tripropylene glycol diacrylate until the resin is uniformly dissolved, thus obtaining second ultraviolet light-cured resin; (3) mixing a reactive diluent, a photoinitiator, a photosensitivity promoter, a defoaming agent, a polymerization inhibitor with the first ultraviolet light-cured resin and the second ultraviolet light-cured resin, carrying out mechanical shearing by a grinder, thus obtaining the thick film light-cured resin ink. The thick film light-cured resin ink provided by the invention is capable of performing quick defoaming and leveling; when a condensate thereof is applied to embossment printing and indentation process, there will be enough thickness and hardness, and the printing properties thereof are not damaged.
Description
Technical field
The invention belongs to printing-ink field, more particularly, to a kind of thick film light-cured resin ink.
Background technology
In the middle of traditional handicraft, anaglyph is realized, there are two kinds of solution routes：One kind is in card face printing screen
Ink, after being dried relief text and graph is formed；Another kind is that embossing pattern is made negative image rod, and producing card using pressure can not be extensive
Multiple is concavo-convex, so as to form relief text and graph.Both anaglyphs can all make card face become uneven, make card entirety
There is different degrees of warpage, calcellation rate that is near and lifting the operation such as the flat code of card personalization link, convex code, gold stamping increases production
Cost impact card is attractive in appearance.For the technical problem of traditional embossing technology, it is (interior that we develop impression false proof process on card
Embossing technology), special thick film light-curable ink is printed on card face using silk-screen plate, indentation pattern is formed, by ultraviolet
Line solidifies drying, finally laminated to be fabricated to card., be present levelling and froth breaking defect in the thick film light-curable ink of prior art, disappear
Bubble overlong time, makes the excessive levelling of ink layer, i.e., the brim height of the pattern layer of ink formed after photocuring is significantly lower than pattern ink
The height of layer center, affects finished product card impression, the perspective three dimensional effect of anaglyph layer.Additionally, thick film in prior art
Light-curable ink easily produces in the curing process coloring matter, affects the transparency of ink layer, it is same affect finished product card impression,
The perspective three dimensional effect of anaglyph layer.
The content of the invention
In view of this, it is contemplated that proposing a kind of thick film light-cured resin ink, being adapted to impression, interior embossing technology makes
With.
To reach above-mentioned purpose, the technical scheme is that what is be achieved in that：
A kind of thick film light-cured resin ink, the thick film light-cured resin ink is by the raw material system including following weight portion
Into：
The first described UV-cured resin be resin and 1,6- that base monomer is bisphenol A epoxy acrylate oneself
The mixture of omega-diol diacrylate, second described UV-cured resin is acrylic resin, 1,6- hexylene glycol dipropyls
The mixture of olefin(e) acid ester and tripropylene glycol diacrylate fat.
1,6 hexanediol diacrylate in the first described UV-cured resin is ultraviolet with described second
1,6 hexanediol diacrylate in light-cured resin is identical or different.
Further, base monomer is the resin of bisphenol A epoxy acrylate in the first described UV-cured resin
It is (1-1.5) with the mass ratio of 1,6 hexanediol diacrylate:(0.5-1)；In second described UV-cured resin
The mass ratio of acrylic resin, 1,6 hexanediol diacrylate and tripropylene glycol diacrylate fat is (1-2):(0.25-
0.75):(0.25-0.75)。
Preferably, described thick film light-cured resin ink is made up of the raw material including following weight portion：
Further, described reactive diluent is in tripropylene glycol diacrylate fat, 1,6- hexanediyl esters
One or two mixture；Described light trigger is 2- hydroxy-2-methyl -1- phenyl -1- acetone, o-benzoylbenzoic acid
One or two mixture in methyl esters；Described photosensitivity promotor is acroleic acid esterification reactive amines；Described defoamer is
Non- silicon polymer；Described polymerization inhibitor is N- nitrosophenyl hydroxylamine aluminium salts.
In tripropylene glycol diacrylate fat in described reactive diluent and second described UV-cured resin
Tripropylene glycol diacrylate fat it is identical or different；1,6 hexanediol diacrylate in described reactive diluent with it is described
The first UV-cured resin in 1,6 hexanediol diacrylate it is identical or different；In described reactive diluent 1,
6- hexanediyl esters are identical with 1,6 hexanediol diacrylate in second described UV-cured resin or not
Together.
The preparation method of described thick film light-cured resin ink, comprises the steps：
(1) resin of bisphenol A epoxy acrylate and 1,6- hexanediyl ester are carried out into intensification stirring, until tree
Fat is uniformly dissolved, that is, the first UV-cured resin is obtained；
(2) acrylic resin, 1,6- hexanediyl esters and tripropylene glycol diacrylate fat are carried out into intensification stirring,
Until resin is uniformly dissolved, that is, second UV-cured resin is obtained；
(3) by first obtained in reactive diluent, light trigger, photosensitivity promotor, defoamer, polymerization inhibitor and above-mentioned steps
Kind of UV-cured resin, second UV-cured resin are mixed, and by grinder mechanical shearing, that is, are obtained described
Thick film light-cured resin ink.
The application of described thick film light-cured resin ink, described thick film light-cured resin ink is in printing embossment, pressure
Application in trace technique.
Further, described application is by being screen printed onto stock table by described thick film light-cured resin ink
Face, described stock is irradiated by the ultraviolet lamp tube of 100W/cm, makes the ink solidification on described stock surface,
Form the transparent ink layer of drying.
Further, stock of the described surface with ink layer matches the PVC facial masks of same type, is laminated, described
Ink layer be pressed into inside described stock, described PVC facial masks produce perspective contrast, shape as hyaline layer and ink layer
Into impression, the 3-D effect of interior embossment.
Further, described stock is the PVC base with reflecting effect；The described PVC bases with reflecting effect
Material is radium-shine PVC, Jin Mo PVC or the one kind in silver inks PVC；Described radium-shine PVC is the PVC base for being covered with laser film；It is described
Gold ink PVC be the PVC base for being printed with Jin Mo；Described silver inks PVC are the PVC base for being printed with silver inks.
Further, the surface tension of the printing surface of described stock is more than 38 dynes.
Described thick film light-cured resin ink also includes other auxiliary agents.
Described thick film light-cured resin ink, its can quick froth breaking levelling, and its solidfied material is for printing floating
When carving, indentation process, can there are enough thickness and hardness and not damage its printing characteristic.
Relative to prior art, thick film light-cured resin ink of the present invention has the advantage that：
Thick film light-cured resin ink of the present invention can quick froth breaking levelling, and its solidfied material is for printing
When embossment, indentation process, can there are enough thickness and hardness and not damage its printing characteristic.
Description of the drawings
Fig. 1 is the schematic diagram before thick film light-cured resin ink lamination；
Fig. 2 is the schematic diagram after thick film light-cured resin ink lamination.
Description of reference numerals：
1- stocks；2- ink layers；3- hyaline layers；4- protective layers.
Specific embodiment
In addition to being defined, technical term used has universal with those skilled in the art of the invention in following examples
The identical meanings of understanding.Test reagent used in following examples, if no special instructions, is routine biochemistry reagent；It is described
Experimental technique, if no special instructions, is conventional method.
Each raw material sources, selection are as follows in following examples：
Wherein the first UV-cured resin, referred to as UV-01, its production technology is：The production of DSM company
AgiSynTM3020-A80, its base monomer is bisphenol A epoxy acrylate, with UV (ultraviolet light polymerization) monomer HDDA, its chemistry
Entitled 1, the 6- hexanediyl esters of formula, with (1-1.5):(0.5-1) quality is formed than mixed dissolution.
Wherein second UV-cured resin, referred to as UV-02, its preparing process is：With pure acrylic resin, such as
AgiSynTM260-AB50, is produced, with UV monomer TPGDA, the entitled tripropylene glycol dipropyl of its chemical formula by Dutch DSM company
Olefin(e) acid fat and UV monomer HDDA, entitled 1, the 6- hexanediyl esters of its chemical formula, with (1-2):(0.25-0.75):
(0.25-0.75) quality is formed than mixed dissolution.
Reactive diluent is the monomer diluent for participating in reaction.Conventional has AgiSynTM2815 (chemical entitled tripropylene glycols
Diacrylate fat), AgiSynTM2816 (chemical entitled 1,6 hexanediol diacrylates).
Light trigger is 1173 (chemical entitled 2- hydroxy-2-methyls -1- phenyl -1- acetone), 1056 (the entitled adjacent benzene of chemistry
Carbamoyl benzoate methyl esters).
Photosensitivity promotor is French Sartomer production CN371 (acroleic acid esterification reactive amines).
Defoamer is You Ka chemical companies of Britain production UNIQFOAM 7032 (non-silicon polymer).
Polymerization inhibitor is German BASF production Easepi 590 (chemical name N- nitrosophenyl hydroxylamine aluminium salts).
The present invention is described in detail with reference to embodiment and accompanying drawing.
Embodiment 1
As shown in Figure 1-2, a kind of thick film light-cured resin ink, the thick film light-cured resin ink is by including following weight
The raw material of part is made：
AgiSyn in wherein UV-01TM3020-A80 and AgiSynTM2815 ratio is 3:AgiSyn in 2, UV-02TM260-
AB50、AgiSynTM2815 and AgiSynTM2816 ratio is 3:1:1.
The preparation method of described thick film light-cured resin ink, comprises the steps：
(1) UV-01 each components are carried out into intensification stirring, until resin is uniformly dissolved, that is, the first ultraviolet light polymerization is obtained
Resin；
(2) UV-02 each components are carried out into intensification stirring, until resin is uniformly dissolved, that is, second ultraviolet light polymerization is obtained
Resin；
(3) by AgiSynTM2815 (reactive diluents), 1173, CN371, UNIQFOAM 7032, Easepi 590 with it is upper
State UV-01, UV-02 obtained in step to be mixed, by three-roll grinder mechanical shearing, that is, described thick film photocuring is obtained
Resin ink.
The application of the thick film light-cured resin ink, described thick film light-cured resin ink is in printing embossment, impression work
Application in skill.
The application be by described thick film light-cured resin ink by being screen printed onto golden ink PVC surface, will be described
Gold ink PVC is irradiated by the ultraviolet lamp tube of 100W/cm, makes the ink solidification in described gold ink PVC surface, forms drying
Transparent ink layer.
The golden ink PVC with ink layer is matched into the PVC facial masks of same type, is laminated, the thick film pattern quilt of protrusion
Inside press-in gold ink PVC base, the perspective contrast of hyaline layer and Jin Mo layer of ink defines impression, the 3-D effect of interior embossment.
UV ink layer Jing hot pressing, inside the golden ink PVC of press-in, patterned surfaces bubble-free, pattern edge is without levelling, and ink layer is saturating
Bright property is good, also imagines without xanthochromia, and Apparent Indentation, interior anaglyph layer is very clear, well arranged.
Embodiment 2
A kind of thick film light-cured resin ink, the thick film light-cured resin ink is by the raw material system including following weight portion
Into：
AgiSyn in wherein UV-01TM3020-A80 and AgiSynTM2815 ratio is 3:AgiSyn in 2, UV-02TM260-
AB50、AgiSynTM2815 and AgiSynTM2816 ratio is 3:1:1.
The preparation method of described thick film light-cured resin ink, comprises the steps：
(1) UV-01 each components are carried out into intensification stirring, until resin is uniformly dissolved, that is, the first ultraviolet light polymerization is obtained
Resin；
(2) UV-02 each components are carried out into intensification stirring, until resin is uniformly dissolved, that is, second ultraviolet light polymerization is obtained
Resin；
(3) by AgiSynTM2816 (reactive diluents), 1056, CN371, UNIQFOAM 7032, Easepi 590 with it is upper
State UV-01, UV-02 obtained in step to be mixed, by three-roll grinder mechanical shearing, that is, described thick film photocuring is obtained
Resin ink.
The application of the thick film light-cured resin ink, described thick film light-cured resin ink is in printing embossment, impression work
Application in skill.
Above-mentioned application is by being screen printed onto silver inks PVC surface, by institute by described thick film light-cured resin ink
Silver inks PVC stated are irradiated by the ultraviolet lamp tube of 100W/cm, make the ink solidification in described silver inks PVC surface, are formed
The transparent ink layer of drying.
Silver inks PVC with ink layer are matched into the PVC facial masks of same type, is laminated, the thick film pattern quilt of protrusion
Inside press-in silver inks PVC base, the perspective contrast of hyaline layer and silver inks layer of ink defines impression, the 3-D effect of interior embossment.
UV ink layer Jing hot pressing, inside press-in silver inks PVC, patterned surfaces bubble-free, pattern edge is without levelling, and ink layer is saturating
Bright property is good, and without the xanthochromia imagination, Apparent Indentation, interior anaglyph layer is clear.
Embodiment 3
A kind of thick film light-cured resin ink, the thick film light-cured resin ink is by the raw material system including following weight portion
Into：
AgiSyn in wherein UV-01TM3020-A80 and AgiSynTM2815 ratio is 3:AgiSyn in 2, UV-02TM260-
AB50、AgiSynTM2815 and AgiSynTM2816 ratio is 3:1:1.
The preparation method of described thick film light-cured resin ink, comprises the steps：
(1) UV-01 each components are carried out into intensification stirring, until resin is uniformly dissolved, that is, the first ultraviolet light polymerization is obtained
Resin；
(2) UV-02 each components are carried out into intensification stirring, until resin is uniformly dissolved, that is, second ultraviolet light polymerization is obtained
Resin；
(3) by AgiSynTM2815 (reactive diluents), AgiSynTM2816 (reactive diluents), 1056,1173,
CN371, UNIQFOAM 7032, Easepi 590 are mixed with UV-01, UV-02 obtained in above-mentioned steps, are ground by three rollers
Mill mechanical is sheared, that is, described thick film light-cured resin ink is obtained.
The application of the thick film light-cured resin ink, described thick film light-cured resin ink is in printing embossment, impression work
Application in skill.
Above-mentioned application is by being screen printed onto radium-shine PVC surface, by institute by described thick film light-cured resin ink
The radium-shine PVC for stating is irradiated by the ultraviolet lamp tube of 100W/cm, makes the ink solidification in described radium-shine PVC surface, is formed
It is dried transparent ink layer.
The radium-shine PVC with ink layer is matched into the PVC facial masks of same type, is laminated, the thick film pattern quilt of protrusion
It is pressed into inside radium-shine PVC base, the perspective contrast of hyaline layer and radium-shine layer of ink defines impression, the 3-D effect of interior embossment.
UV ink layer Jing hot pressing, is pressed into inside radium-shine PVC, and patterned surfaces bubble-free, pattern edge is mellow and full, slightly levelling,
The ink layer transparency is good, and without the xanthochromia imagination, Apparent Indentation, interior anaglyph layer is more visible.
Comparative example 1
A kind of ink, the ink is made up of the raw material including following weight portion：
Wherein, UVE3216 and UVA1000 is finished product liquid resin, is directly used, it is not necessary to prepare.
The preparation method of the ink, comprises the steps：By UVE3216, UVA1000, M-225,1173, UVB2000,
UNIQFOAM 7032, Easepi 590 are mixed, and by three-roll grinder mechanical shearing, that is, described ink are obtained.
By the ink by being screen printed onto radium-shine PVC surface, ink layer is formed, described radium-shine PVC is passed through into 100W/
The ultraviolet lamp tube of cm is irradiated, and makes the ink solidification in described radium-shine PVC surface, forms the transparent ink layer of drying.
The radium-shine PVC with ink layer is matched into the PVC facial masks of same type, is laminated, the thick film pattern quilt of protrusion
It is pressed into inside radium-shine PVC base, the perspective contrast of hyaline layer and radium-shine layer of ink defines impression, the 3-D effect of interior embossment.
UV ink layer Jing hot pressing, is pressed into inside radium-shine PVC, and patterned surfaces bubble-free, pattern edge is mellow and full, and levelling is obvious,
90 degree of views, ink layer has slight Yellowing, and Apparent Indentation, interior anaglyph vestige, 3-D effect is not obvious.
The ink layer that above-described embodiment 1-3 and comparative example 1 are prepared is carried out into ink detection, design parameter is as follows.
Printing equipment parameter：
Printing：The mesh of silk-screen plate mesh 120, conveys tape running speed 1m/s, UV lamp power 100W/cm, serigraphy
It is 5s with the time interval of ultra-violet curing.
Laminated portion：Hot pressing pressure 2.8Bar, 140 DEG C of hot pressing temperature, hot pressing time 15min, cold pressing pressure 3.0Bar is cold
25 DEG C of temperature of pressure, cold pressing time 15min,
The formula ink of embodiment 1-3 is compared with the ink technology parameter of comparative example 1：
Conclusion：
Compared to the prior art, new proportioning has been carried out newly emphatically the thick film light-cured resin ink formulations to resin and auxiliary agent
Design, make formula ink under the conditions of high-viscosity, it may have good printing adaptability (quick levelability and quick froth breaking
Property).
Presently preferred embodiments of the present invention is the foregoing is only, not to limit the present invention, all essences in the present invention
Within god and principle, any modification, equivalent substitution and improvements made etc. should be included within the scope of the present invention.
Claims (10)
1. a kind of thick film light-cured resin ink, it is characterised in that：The thick film light-cured resin ink is by including following weight portion
Raw material make：
Monomer is the resin and 1,6-HD of bisphenol A epoxy acrylate based on the first described UV-cured resin
The mixture of diacrylate, second described UV-cured resin is acrylic resin, 1,6- hexanediyls
The mixture of ester and tripropylene glycol diacrylate fat.
2. thick film light-cured resin ink according to claim 1, it is characterised in that：The first described ultraviolet light polymerization
Base monomer is (1- with the mass ratio of 1,6 hexanediol diacrylate for the resin of bisphenol A epoxy acrylate in resin
1.5):(0.5-1)；Acrylic resin, 1,6 hexanediol diacrylate and three in second described UV-cured resin
The mass ratio of propane diols diacrylate fat is (1-2):(0.25-0.75):(0.25-0.75).
3. thick film light-cured resin ink according to claim 1, it is characterised in that：Described thick film light-cured resin oil
Ink is made up of the raw material including following weight portion：
4. thick film light-cured resin ink according to claim 1, it is characterised in that：Described reactive diluent is 3 third
One or two mixture in glycol diacrylate fat, 1,6 hexanediol diacrylate；Described light trigger is 2-
One or two mixture in hydroxy-2-methyl -1- phenyl -1- acetone, methyl o-benzoylbenzoate；Described is photosensitive
Sensitizer is acroleic acid esterification reactive amines；Described defoamer is non-silicon polymer；Described polymerization inhibitor is N- nitrosophenyl hydroxylamines
Aluminium salt.
5. the preparation method of the thick film light-cured resin ink described in claim 1-4, it is characterised in that：Comprise the steps：
(1) resin of bisphenol A epoxy acrylate and 1,6- hexanediyl ester are carried out into intensification stirring, until resin is molten
Solution is uniform, that is, the first UV-cured resin is obtained；
(2) acrylic resin, 1,6- hexanediyl esters and tripropylene glycol diacrylate fat are carried out into intensification stirring, until
Resin is uniformly dissolved, that is, second UV-cured resin is obtained；
(3) by the first purple obtained in reactive diluent, light trigger, photosensitivity promotor, defoamer, polymerization inhibitor and above-mentioned steps
Outer light-cured resin, second UV-cured resin are mixed, and by grinder mechanical shearing, that is, described thick film are obtained
Light-cured resin ink.
6. the application of the thick film light-cured resin ink described in claim 1-4, it is characterised in that：Described thick film photocuring tree
Application of the fatty oil ink in printing embossment, indentation process.
7. the application of thick film light-cured resin ink according to claim 6, it is characterised in that：Described application is by institute
The thick film light-cured resin ink stated by being screen printed onto stock surface, the purple that described stock is passed through into 100W/cm
Outer fluorescent tube is irradiated, and makes the ink solidification on described stock surface, forms the transparent ink layer of drying.
8. the application of thick film light-cured resin ink according to claim 7, it is characterised in that：Described surface is with oil
The stock of layer of ink matches the PVC facial masks of same type, is laminated, and described ink layer is pressed into inside described stock,
Described PVC facial masks produce perspective contrast as hyaline layer and ink layer, define impression, the 3-D effect of interior embossment.
9. the application of thick film light-cured resin ink according to claim 7, it is characterised in that：Described stock is tool
There is the PVC base of reflecting effect；The described PVC base with reflecting effect is in radium-shine PVC, Jin Mo PVC or silver inks PVC
It is a kind of；Described radium-shine PVC is the PVC base for being covered with laser film；Described gold ink PVC is the PVC base for being printed with Jin Mo；Institute
Silver inks PVC stated are the PVC base for being printed with silver inks.
10. the application of the thick film light-cured resin ink according to any one of claim 7-9, it is characterised in that：It is described
Stock printing surface surface tension be more than 38 dynes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611199631.6A CN106634180A (en) | 2016-12-22 | 2016-12-22 | Thick film light-cured resin ink |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611199631.6A CN106634180A (en) | 2016-12-22 | 2016-12-22 | Thick film light-cured resin ink |
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| CN106634180A true CN106634180A (en) | 2017-05-10 |
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| CN201611199631.6A Pending CN106634180A (en) | 2016-12-22 | 2016-12-22 | Thick film light-cured resin ink |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107323115A (en) * | 2017-07-31 | 2017-11-07 | 缪秉强 | One kind is without electric carving version hot pressing gilding technology |
| CN108912813A (en) * | 2018-06-22 | 2018-11-30 | 泉州市同兴反光材料有限公司 | A kind of preparation method of light-curable ink glue |
| CN112980237A (en) * | 2021-02-25 | 2021-06-18 | 艺壹佳文化科技(广东)有限公司 | Propaganda logo product with strong plasticity and 36D crystal carving process thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099047A (en) * | 1994-06-27 | 1995-02-22 | 北京市富通光电工程公司 | Compositions of ultraviolet curing type |
| CN1580149A (en) * | 2004-05-17 | 2005-02-16 | 深圳市立美特环保油墨有限公司 | Ultraviolet light curable ink |
| CN102796417A (en) * | 2011-09-15 | 2012-11-28 | 武汉虹之彩包装印刷有限公司 | Gravure line ultraviolet (UV) frosted ink and method for preparing same |
| CN103614001A (en) * | 2013-12-04 | 2014-03-05 | 深圳九星印刷包装集团有限公司 | Ultraviolet-curing offset printing snow ink |
| CN104533044A (en) * | 2014-12-29 | 2015-04-22 | 赖信潮 | Temperature sensing color changing space pattern wall poster and preparing method thereof |
-
2016
- 2016-12-22 CN CN201611199631.6A patent/CN106634180A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1099047A (en) * | 1994-06-27 | 1995-02-22 | 北京市富通光电工程公司 | Compositions of ultraviolet curing type |
| CN1580149A (en) * | 2004-05-17 | 2005-02-16 | 深圳市立美特环保油墨有限公司 | Ultraviolet light curable ink |
| CN102796417A (en) * | 2011-09-15 | 2012-11-28 | 武汉虹之彩包装印刷有限公司 | Gravure line ultraviolet (UV) frosted ink and method for preparing same |
| CN103614001A (en) * | 2013-12-04 | 2014-03-05 | 深圳九星印刷包装集团有限公司 | Ultraviolet-curing offset printing snow ink |
| CN104533044A (en) * | 2014-12-29 | 2015-04-22 | 赖信潮 | Temperature sensing color changing space pattern wall poster and preparing method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107323115A (en) * | 2017-07-31 | 2017-11-07 | 缪秉强 | One kind is without electric carving version hot pressing gilding technology |
| CN108912813A (en) * | 2018-06-22 | 2018-11-30 | 泉州市同兴反光材料有限公司 | A kind of preparation method of light-curable ink glue |
| CN112980237A (en) * | 2021-02-25 | 2021-06-18 | 艺壹佳文化科技(广东)有限公司 | Propaganda logo product with strong plasticity and 36D crystal carving process thereof |
| CN112980237B (en) * | 2021-02-25 | 2022-07-19 | 艺壹佳文化科技(广东)有限公司 | Propaganda logo product with strong plasticity and 36D crystal carving process thereof |
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Application publication date: 20170510 |