CN113372795A - Color-changeable interior wall coating, preparation method thereof and color-changeable interior wall using same - Google Patents

Color-changeable interior wall coating, preparation method thereof and color-changeable interior wall using same Download PDF

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Publication number
CN113372795A
CN113372795A CN202110674928.8A CN202110674928A CN113372795A CN 113372795 A CN113372795 A CN 113372795A CN 202110674928 A CN202110674928 A CN 202110674928A CN 113372795 A CN113372795 A CN 113372795A
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color
interior wall
changeable
parts
acrylamide
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Inventor
高捷
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Sichuan Gda Architecture Design Co ltd
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Sichuan Gda Architecture Design Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/26Thermosensitive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The application relates to the field of coatings, and particularly discloses a color-changeable interior wall coating, a preparation method thereof and a color-changeable interior wall using the same. The color-changeable interior wall coating is prepared from the following raw materials in parts by weight: 30-50 parts of novolac epoxy acrylate, 5-10 parts of 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder, 1-2 parts of inorganic filler, 1-2 parts of film-forming assistant and 10-20 parts of deionized water; the preparation method comprises the following steps: firstly, adding the novolac epoxy acrylate into deionized water under stirring, uniformly stirring to form a mixed solution, continuously stirring the mixed solution, adding the rest raw materials into the mixed solution, and uniformly mixing to obtain the color-changeable interior wall coating. The color-changeable interior wall coating can be used for decorating interior wall bodies, and the color-changeable interior wall coating prepared by the method improves the dispersibility of color-changeable substances in the coating and reduces the possibility of agglomeration of the color-changeable substances in the coating.

Description

Color-changeable interior wall coating, preparation method thereof and color-changeable interior wall using same
Technical Field
The application relates to the field of coatings, in particular to a color-changeable interior wall coating, a preparation method thereof and a color-changeable interior wall using the same.
Background
The coating is a liquid or solid material which can form a film to play a role in protection, decoration or other special functions (insulation, rust prevention, mildew prevention, heat resistance and the like) when being coated on the surface of an object under certain conditions. In recent years, with the rapid development of the coating industry, more and more different kinds of coatings are beginning to be applied in many industries. Especially in the decoration of inner walls of buildings, the coating is more widely applied. In order to make a building more beautiful, a color-changing paint is generally used as a finishing material for an interior wall of the building.
The common color-changing coating in the related technology is formed by adding a color-changing substance into a conventional coating and mixing, and then brushing the color-changing coating on a wall.
In view of the above-mentioned related art, the inventors have artificially had the following drawbacks: the color-changeable substance is easy to agglomerate when being added into the coating and mixed and stirred, so that the dispersibility of the color-changeable substance in the coating is reduced, and the integral aesthetic degree of the color-changeable coating coated on a wall is further reduced.
Disclosure of Invention
In order to improve the dispersibility of the color-changeable substance in the paint and reduce the possibility of agglomeration of the color-changeable substance in the paint, the application provides a color-changeable interior wall paint, a preparation method thereof and a color-changeable interior wall using the same.
The color-changeable interior wall coating, the preparation method thereof and the color-changeable interior wall adopting the technical scheme are as follows:
in a first aspect, the application provides a color-changeable interior wall coating, which adopts the following technical scheme:
the color-changeable interior wall coating is prepared from the following raw materials in parts by weight: 30-50 parts of novolac epoxy acrylate, 5-10 parts of 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder, 1-2 parts of inorganic filler, 1-2 parts of film-forming assistant and 10-20 parts of deionized water.
By adopting the technical scheme, the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder can enable a wall body to show different colors along with the change of the external temperature when the coating is coated on the wall body, so that the visual effect of the wall body is improved; meanwhile, the residents in the room can know the outside temperature change according to the different colors of the wall body; when the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder is mixed with various components, the sulfonic acid groups in the 2-acrylamide-2-methylpropanesulfonic acid on the surface of the thermochromic powder show stronger electronegativity, and electrostatic repulsion is shown among modified thermochromic powder particles, so that a good dispersion effect can be achieved in a coating, the possibility of agglomeration of common thermochromic powder in the coating is reduced, and meanwhile, the 2-acrylamide-2-methylpropanesulfonic acid has larger steric hindrance, so that the repulsion among the modified thermochromic powder particles can be further increased, and the dispersibility of the modified thermochromic powder in the coating is improved.
Preferably, the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder is prepared by adopting the following method: weighing 2-acrylamide-2-methylpropanesulfonic acid and temperature-sensitive color-changing powder in a weight ratio of 1:1, mixing and stirring the 2-acrylamide-2-methylpropanesulfonic acid and deionized water in a ratio of 1:2 uniformly to prepare a 2-acrylamide-2-methylpropanesulfonic acid solution, adding the temperature-sensitive color-changing powder into the 2-acrylamide-2-methylpropanesulfonic acid solution, stirring uniformly, heating and stirring until water is evaporated to dryness to obtain the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder.
By adopting the technical scheme, the 2-acrylamide-2-methylpropanesulfonic acid is prepared into the aqueous solution, and then the 2-acrylamide-2-methylpropanesulfonic acid aqueous solution and the thermochromic powder are mixed and stirred, so that the 2-acrylamide-2-methylpropanesulfonic acid is coated on the surface of the thermochromic powder, the effect of the 2-acrylamide-2-methylpropanesulfonic acid can be better played, and the dispersibility of the thermochromic powder is improved.
Preferably, the diameter of the temperature-sensitive color-changing powder is 5-10 μm.
By adopting the technical scheme, the thermochromic powder with the diameter of 5-10 mu m can be more easily dispersed in the coating; when the diameter of the temperature-sensitive color-changing powder is less than 5 mu m, the temperature-sensitive color-changing powder is too thin, so that the temperature-sensitive color-changing powder is easy to suspend above the coating and is not easy to mix into the coating; when the diameter of the temperature-sensitive color-changing powder is larger than 10 mu m, the temperature-sensitive color-changing powder is easy to precipitate in the coating, and the bottom precipitation phenomenon is generated, so that the temperature-sensitive color-changing powder is influenced to play a role.
Preferably, the color-changeable interior wall coating further comprises 2-5 parts by weight of polypropylene glycol.
By adopting the technical scheme, the polypropylene glycol is added into the coating, hydrogen bonds are formed between hydroxyl groups on the polypropylene glycol and sulfonic acid groups in the 2-acrylamide-2-methylpropanesulfonic acid, polypropylene glycol molecules are gathered around the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder through the hydrogen bonds, the steric hindrance around the modified thermochromic powder is increased, the mutual repulsion of particles of the modified thermochromic powder is increased, and the dispersion effect of the modified thermochromic powder in the coating is further improved.
Preferably, the weight ratio of the polypropylene glycol to the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder is 1: 2-3.
By adopting the technical scheme, the weight ratio of the polypropylene glycol to the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder is adjusted to be 1:2-3, so that the steric hindrance effect can be further exerted, and the dispersibility of the modified temperature-sensitive color-changing powder is improved.
Preferably, the inorganic filler is one or a mixture of two of nano zinc oxide and nano titanium dioxide.
By adopting the technical scheme, the inorganic filler can improve the thickness of a paint film and improve the wear resistance and durability of the paint.
In a second aspect, the application provides a preparation method of a color-changeable interior wall coating, which adopts the following technical scheme: a preparation method of a color-changeable interior wall coating comprises the following steps:
weighing the raw materials in parts by weight, adding the novolac epoxy acrylate into deionized water under stirring, uniformly stirring to form a mixed solution, continuously stirring the mixed solution, adding the rest raw materials into the mixed solution, and uniformly mixing to obtain the color-changeable interior wall coating.
By adopting the technical scheme, the raw material components in the coating can be mixed more fully, the functions of the components can be exerted, and the dispersibility of the components in the coating is improved.
In a third aspect, the present application provides a color-changeable interior wall, which adopts the following technical scheme:
the color-changeable inner wall is coated with color-changeable inner wall paint.
By adopting the technical scheme, the color-changeable coating coated on the inner wall of the building can be changed into different colors when the environmental temperature changes, so that the diversity of interior decoration can be increased, and the aesthetic feeling of the interior decoration can be improved; meanwhile, the environment temperature can be judged according to the color on the wall, so that the resident can conveniently take corresponding measures.
In summary, the present application has the following beneficial effects:
1. the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder can enable a wall body to show different colors along with the change of external temperature when the coating is coated on the wall body, so that the visual effect of the wall body is improved; meanwhile, the residents in the room can know the outside temperature change according to the different colors of the wall body; when the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder is mixed with various components, the sulfonic acid groups in the 2-acrylamide-2-methylpropanesulfonic acid on the surface of the thermochromic powder show stronger electronegativity, and electrostatic repulsion is shown among modified thermochromic powder particles, so that a good dispersion effect can be achieved in a coating, the possibility of agglomeration of common thermochromic powder in the coating is reduced, and meanwhile, the 2-acrylamide-2-methylpropanesulfonic acid has larger steric hindrance, so that the repulsion among the modified thermochromic powder particles can be further increased, and the dispersibility of the modified thermochromic powder in the coating is improved.
2. The polypropylene glycol is added into the paint, hydrogen bonds are formed between hydroxyl groups on the polypropylene glycol and sulfonic acid groups in the 2-acrylamide-2-methylpropanesulfonic acid, polypropylene glycol molecules are gathered around the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder through the hydrogen bonds, the steric hindrance around the modified thermochromic powder is increased, the mutual repulsion of particles of the modified thermochromic powder is increased, and the dispersion effect of the modified thermochromic powder in the paint is further improved.
3. Firstly, adding novolac epoxy acrylate into deionized water under stirring, uniformly stirring to form a mixed solution, continuously stirring the mixed solution, adding the rest raw materials into the mixed solution, and uniformly mixing; the raw material components in the coating can be mixed more fully, the functions of the components can be exerted, and the dispersibility of the components in the coating is improved.
Detailed Description
Examples of preparation of raw materials
Preparation example 1
Weighing 5g of 2-acrylamide-2-methylpropanesulfonic acid and 5g of temperature-sensitive color-changing powder with the average diameter of 5 mu m, mixing and stirring the 2-acrylamide-2-methylpropanesulfonic acid and 10g of deionized water according to the ratio of 1:2 uniformly to prepare a 2-acrylamide-2-methylpropanesulfonic acid solution, adding the temperature-sensitive color-changing powder into the 2-acrylamide-2-methylpropanesulfonic acid solution, stirring uniformly, heating to 80 ℃, stirring until the water is evaporated to dryness, and obtaining the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder.
Preparation example 2
Preparation example 2 was different from preparation example 1 in that the average diameter of the temperature sensitive color changing powder was 8 μm.
Preparation example 3
Preparation example 3 was different from preparation example 1 in that the average diameter of the temperature sensitive color changing powder was 10 μm.
The present application will be described in further detail with reference to examples.
The raw materials except the modified thermochromic powder are all commercial products, wherein the film-forming aid is alcohol ester dodecafilm-forming aid; the average particle size of the nano titanium dioxide and the nano zinc oxide is 50-200 nm.
Examples
Examples 1 to 5
Taking example 1 as an example, the preparation method of the color-changeable interior wall coating comprises the following steps:
weighing the raw materials, adding the novolac epoxy acrylate into deionized water under stirring, uniformly stirring to form a mixed solution, continuously stirring the mixed solution, adding the rest raw materials into the mixed solution, and uniformly mixing to obtain the color-changeable interior wall coating.
The starting materials of examples 1 to 5 are shown in Table 1, the 2-acrylamido-2-methylpropanesulfonic acid-modified thermochromic powder used was provided from production example 1, and the production methods of examples 2 to 5 were the same as those of example 1.
TABLE 1
Figure BDA0003120331090000041
Examples 6 to 11
Examples 6 to 7 differ from example 4 in the 2-acrylamido-2-methylpropanesulfonic acid-modified thermochromic toner used, the modified thermochromic powder of example 6 was provided from preparation example 2, and the modified thermochromic powder of example 7 was provided from preparation example 3. The preparation of examples 6-7 was carried out in the same manner as in example 4.
Examples 8-9 are compared to example 6, except that polypropylene glycol was added to the coating. The preparation of examples 8 to 9 was carried out in the same manner as in example 6.
Examples 10 to 11 are different from example 8 in the weight ratio of polypropylene glycol to 2-acrylamido-2-methylpropanesulfonic acid modified thermochromic toner, in that example 10 the weight ratio of polypropylene glycol to modified thermochromic toner is 1:2, and example 11 the weight ratio of polypropylene glycol to modified thermochromic toner is 1: 3. The preparation of examples 10 to 11 was carried out in the same manner as in example 8.
The raw material qualities of examples 6 to 11 are shown in Table 2.
TABLE 2
Figure BDA0003120331090000051
Example 12
The color-changeable inner wall comprises a wall body and a color-changeable inner wall coating coated on the wall body, wherein the color-changeable coating has good leveling property when coated on the wall body. When the ambient temperature changes, the wall body can show different colors, and the aesthetic degree of the wall body is improved. The resident can also make a judgment on the ambient temperature according to different colors on the wall body so as to take measures.
Comparative example
Comparative example 1
Comparative example 1 is different from example 1 in that the 2-acrylamido-2-methylpropanesulfonic acid-modified temperature-sensitive toner was replaced with an ordinary unmodified temperature-sensitive toner.
Comparative example 2
Comparative example 2 is different from example 6 in that 2-acrylamido-2-methylpropanesulfonic acid-modified temperature sensing was replaced with an equal amount of polypropylene glycol.
Performance test
Detection method
And (3) testing the dispersibility: adopting a direct observation method, mixing the coating, standing for 24h, and stirring by using an ink adjusting knife to observe whether the coating has hard blocks, agglomeration and precipitation.
And (3) fineness test: the blade test was carried out according to the national standard GB/T1724-1979 (89).
And (3) testing the adhesive force: the test is carried out according to the rating standard specified in the national standard GB/T9286-1988, the best rating of 0 is, and the worst rating of 5 is.
And (3) hardness testing: the test was carried out according to the pencil used as specified in the national standard GB/T6739-1986, with 13 grades from 6B to 6H.
The above-described tests were carried out for examples 1 to 11 and comparative examples 1 to 2, and the test results are shown in Table 3.
TABLE 3
Figure BDA0003120331090000061
Figure BDA0003120331090000071
Combining example 1 and comparative example 1 with table 3, it can be seen that the coating of example 1 has no hard lumps with only a small amount of precipitation, whereas comparative example 1 has a small amount of hard lumps with more precipitation; the fineness of example 1 is also smaller than that of comparative example 1. The temperature-sensitive color-changing powder modified by the 2-acrylamide-2-methylpropanesulfonic acid can improve the dispersibility of the color-changing coating, so that the temperature-sensitive color-changing powder and each component in the coating are mixed more uniformly, the possibility that the temperature-sensitive color-changing powder shows different color shades after being coated is reduced, and the attractiveness of a wall body is reduced. The sulfonic acid group in the 2-acrylamide-2-methylpropanesulfonic acid on the surface of the temperature-sensitive color-changing powder shows stronger electronegativity, and the modified temperature-sensitive color-changing powder particles show electrostatic repulsion, so that the paint has a good dispersion effect, the possibility of agglomeration of the common temperature-sensitive color-changing powder in the paint is reduced, and meanwhile, the 2-acrylamide-2-methylpropanesulfonic acid has larger steric hindrance, so that the repulsion force among the modified temperature-sensitive color-changing powder particles can be further increased, and the dispersibility of the modified temperature-sensitive color-changing powder in the paint is improved.
As can be seen by combining examples 1 to 9 with Table 3, the coatings of examples 1 to 7 had no hard lumps and a small amount of precipitates, while the coatings of examples 8 to 9 had less precipitates than those of examples 1 to 7, which indicates that the dispersibility of the coatings was further improved and the temperature-sensitive toner was less likely to agglomerate to generate precipitates, with the addition of polypropylene glycol, as compared with examples 1 to 7. The hydrogen bond is formed between the hydroxyl on the polypropylene glycol and the sulfonic acid group in the 2-acrylamide-2-methylpropanesulfonic acid, and the polypropylene glycol molecule is gathered around the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder through the hydrogen bond, so that the steric hindrance around the modified thermochromic powder is increased, the mutual repulsion of particles of the modified thermochromic powder is increased, and the dispersion effect of the modified thermochromic powder in the coating is further improved. It can be seen from the combination of example 8 and examples 10 to 11 that the dispersibility of the temperature sensitive toner can be further improved by adjusting the weight ratio of the polypropylene glycol to the modified temperature sensitive toner.
As can be seen by combining example 6, example 8 and comparative example 2, the overall performance of example 8 is higher than that of example 6 and comparative example 2, which indicates that the dispersibility of the coating with the modified temperature sensitive toner added alone and the coating with the polypropylene glycol added alone are inferior to those of the coating with the both mixed. The polypropylene glycol and the modified thermochromic powder can act together under the synergistic effect, so that the dispersibility of the coating is improved.
The present embodiment is only for explaining the present application, and it is not limited to the present application, and those skilled in the art can make modifications of the present embodiment without inventive contribution as needed after reading the present specification, but all of them are protected by patent law within the scope of the claims of the present application.

Claims (8)

1. The color-changeable interior wall coating is characterized by being prepared from the following raw materials in parts by weight: 30-50 parts of novolac epoxy acrylate, 5-10 parts of 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder, 1-2 parts of inorganic filler, 1-2 parts of film-forming assistant and 10-20 parts of deionized water.
2. The color-changeable interior wall coating according to claim 1, wherein the 2-acrylamide-2-methylpropanesulfonic acid modified thermochromic powder is prepared by the following method: weighing 2-acrylamide-2-methylpropanesulfonic acid and temperature-sensitive color-changing powder in a weight ratio of 1:1, mixing and stirring the 2-acrylamide-2-methylpropanesulfonic acid and deionized water in a ratio of 1:2 uniformly to prepare a 2-acrylamide-2-methylpropanesulfonic acid solution, adding the temperature-sensitive color-changing powder into the 2-acrylamide-2-methylpropanesulfonic acid solution, stirring uniformly, heating and stirring until water is evaporated to dryness to obtain the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder.
3. A color-changeable interior wall coating according to claim 1 or 2, characterized in that: the diameter of the temperature-sensitive color-changing powder is 5-10 μm.
4. A color-changeable interior wall coating according to claim 1 or 2, characterized in that: the color-changeable interior wall coating also comprises 2-5 parts by weight of polypropylene glycol.
5. The color-changeable interior wall coating according to claim 4, wherein: the weight ratio of the polypropylene glycol to the 2-acrylamide-2-methylpropanesulfonic acid modified temperature-sensitive color-changing powder is 1: 2-3.
6. A color-changeable interior wall coating according to claim 1 or 2, characterized in that: the inorganic filler is one or a mixture of two of nano zinc oxide and nano titanium dioxide.
7. The method for preparing a color-changeable interior wall coating material according to any one of claims 1 to 6, comprising the steps of:
weighing the raw materials in parts by weight, adding the novolac epoxy acrylate into deionized water under stirring, uniformly stirring to form a mixed solution, continuously stirring the mixed solution, adding the rest raw materials into the mixed solution, and uniformly mixing to obtain the color-changeable interior wall coating.
8. A variable color interior wall using the variable color interior wall coating material according to any one of claims 1 to 6, wherein: the color-changeable inner wall is coated with color-changeable inner wall paint.
CN202110674928.8A 2021-06-17 2021-06-17 Color-changeable interior wall coating, preparation method thereof and color-changeable interior wall using same Pending CN113372795A (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104533044A (en) * 2014-12-29 2015-04-22 赖信潮 Temperature sensing color changing space pattern wall poster and preparing method thereof
CN106504628A (en) * 2016-10-27 2017-03-15 南丹县青少年学生校外活动中心 A kind of color mud that can be used to make teaching aid
CN107841234A (en) * 2017-11-20 2018-03-27 广东华兹卜新材料科技有限公司 A kind of silicon-modified epoxy acrylic acid allochroic paint and preparation method thereof
CN109929436A (en) * 2019-04-04 2019-06-25 享居派(上海)科技股份有限公司 A kind of environment-friendly type temperature becomes interior wall coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104533044A (en) * 2014-12-29 2015-04-22 赖信潮 Temperature sensing color changing space pattern wall poster and preparing method thereof
CN106504628A (en) * 2016-10-27 2017-03-15 南丹县青少年学生校外活动中心 A kind of color mud that can be used to make teaching aid
CN107841234A (en) * 2017-11-20 2018-03-27 广东华兹卜新材料科技有限公司 A kind of silicon-modified epoxy acrylic acid allochroic paint and preparation method thereof
CN109929436A (en) * 2019-04-04 2019-06-25 享居派(上海)科技股份有限公司 A kind of environment-friendly type temperature becomes interior wall coating and preparation method thereof

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Application publication date: 20210910