CN107880685A - A kind of automatically cleaning mosquito proof interior wall coating and preparation method thereof - Google Patents

A kind of automatically cleaning mosquito proof interior wall coating and preparation method thereof Download PDF

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Publication number
CN107880685A
CN107880685A CN201711104092.8A CN201711104092A CN107880685A CN 107880685 A CN107880685 A CN 107880685A CN 201711104092 A CN201711104092 A CN 201711104092A CN 107880685 A CN107880685 A CN 107880685A
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parts
interior wall
automatically cleaning
thickener
defoamer
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汤谏好
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New Mstar Technology Ltd In Qingyuan
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New Mstar Technology Ltd In Qingyuan
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D143/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
    • C09D143/04Homopolymers or copolymers of monomers containing silicon
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/14Paints containing biocides, e.g. fungicides, insecticides or pesticides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • C09D5/1668Vinyl-type polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/18Spheres

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Plant Pathology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of automatically cleaning mosquito proof interior wall coating, and its raw material includes following components by weight:300 600 parts of silicone acrylic emulsion, 20 40 parts of covering emulsion, 150 250 parts of titanium dioxide, 38 parts of calcined kaolin, 25 parts of powdered whiting, 26 parts of nano inorganic negative ion antibiotic agent, 10 15 parts of the stupid ethylene butyl acrylate copolymer microballoon of methyl methacrylate, 58 parts of effective cypermethrin, 25 parts of biological mosquito repellent liquid, ethoxy are fine micro- plain 35 parts, 59 parts of thickener, 24 parts of defoamer, 59 parts of dispersant, 36 parts of wetting agent, 20 50 parts of coalescents,(AMP‑95)13 parts, 150 300 parts of deionized water.The present invention also provides its preparation method, decorative paint of the invention have the advantages that good antibacterial and mouldproof effect, resistance to artificial weathering aging, stain resistance, temperature-change resistance, resistance to worm's ovum grow, it is resistance to damage by worms, slow-release pesticidal effect, firmly indeformable, health environment-friendly, high-decoration are strong.

Description

A kind of automatically cleaning mosquito proof interior wall coating and preparation method thereof
Technical field
The present invention relates to a kind of coating, relates in particular to a kind of automatically cleaning mosquito proof interior wall coating and preparation method thereof.
Background technology
The ornament materials of building and ornament materials particularly house inner wall at present, the effect of beautification indoor and outdoor is primarily served, is made People is comfortable on warm, and house is more firm, and the material used is usually kaolin, silica ashes, talcum powder, mica powder, titanium The raw materials such as white powder add dispersant, wetting agent, propane diols, emulsion, water and reconcile and form, and serve landscaping effect and protect wall Still people to the requirement more and more higher of environmental protection, put forward new hope to decorative material for wall surface for effect --- automatically cleaning mosquito proof Interior wall coating.Although present exterior material can make indoor wall beautiful and clean, so that it is more comfortable with living environment to live, Many existing building and ornament materials are in use easily in wall top layer mould growth and worm's ovum, and especially coastal grade is flush Area, mould can under 20-38 DEG C, the suitable condition of relative humidity 85% or so amount reproduction, corrode building surface, destroy bottom Material, at the same dope for inner wall of architecture surface due to exposed area it is big, and fungi, bacterium, worm's ovum grow main positions.These are mould On the one hand bacterium, bacterium, fungi, worm's ovum destroy the attractive in appearance and erosion of coating surface, on the other hand also have a strong impact on people's Health and the destruction to domestic environment.
The content of the invention
Therefore, to be solved by this invention be to provide a kind of automatically cleaning mosquito proof interior wall coating and preparation method thereof, this hair There is bright decorative paint good antibacterial and mouldproof effect, resistance to artificial weathering aging, stain resistance, temperature-change resistance, resistance to worm's ovum to grow, be resistance to Damage by worms, slow-release pesticidal effect, firmly indeformable, health environment-friendly, high-decoration it is strong the advantages that.
In order to solve the above technical problems, the technical scheme is that:A kind of automatically cleaning mosquito proof interior wall coating, its raw material Include following components by weight:Silicone acrylic emulsion 300-600 parts, covering emulsion 20-40 parts, titanium dioxide 150-250 parts, calcination Kaolin 3-8 parts, powdered whiting 2-5 parts, nano inorganic negative ion antibiotic agent 2-6 parts, methyl methacrylate-stupid ethene- Butyl acrylate copolymer microballoon 10-15 parts, effective cypermethrin 5-8 parts, biological mosquito repellent liquid 2-5 parts, the fine micro- plain 3-5 of ethoxy Part, thickener 5-9 parts, defoamer 2-4 parts, dispersant 5-9 parts, wetting agent 3-6 parts, coalescents 20-50 parts,(AMP-95)1- 3 parts, deionized water 150-300 parts.
Further, a kind of described automatically cleaning mosquito proof interior wall coating, its raw material include following components by weight:Silicon 300 parts of acrylic emulsion, 20 parts of covering emulsion, 150 parts of titanium dioxide, 3 parts of calcined kaolin, 2 parts of powdered whiting, nano inorganic are born 2 parts of ion antibacterial agent, methyl methacrylate -10 parts of stupid ethylene-butyl acrylate copolymer microballoon, 5 parts of effective cypermethrin, Biological 2 parts of mosquito repellent liquid, ethoxy are fine micro- plain 3 parts, 5 parts of thickener, 2 parts of defoamer, 5 parts of dispersant, 3 parts of wetting agent, film forming help 20 parts of agent,(AMP-95)1 part, deionized water 150- parts.
Further, a kind of described automatically cleaning mosquito proof interior wall coating, its raw material include following components by weight:Silicon 600 parts of acrylic emulsion, 40 parts of covering emulsion, 250 parts of titanium dioxide, 8 parts of calcined kaolin, 5 parts of powdered whiting, nano inorganic are born 6 parts of ion antibacterial agent, methyl methacrylate -15 parts of stupid ethylene-butyl acrylate copolymer microballoon, 8 parts of effective cypermethrin, Biological 5 parts of mosquito repellent liquid, ethoxy are fine micro- plain 5 parts, 9 parts of thickener, 4 parts of defoamer, 9 parts of dispersant, 6 parts of wetting agent, film forming help 50 parts of agent,(AMP-95)3 parts, 300 parts of deionized water.
Further, a kind of described automatically cleaning mosquito proof interior wall coating, its raw material include following components by weight:Silicon 400 parts of acrylic emulsion, 30 parts of covering emulsion, 200 parts of titanium dioxide, 6 parts of calcined kaolin, 4 parts of powdered whiting, nano inorganic are born 4 parts of ion antibacterial agent, methyl methacrylate -12 parts of stupid ethylene-butyl acrylate copolymer microballoon, 6 parts of effective cypermethrin, Biological 4 parts of mosquito repellent liquid, ethoxy are fine micro- plain 4 parts, 7 parts of thickener, 3 parts of defoamer, 6 parts of dispersant, 4 parts of wetting agent, film forming help 30 parts of agent,(AMP-95)2 parts, 200 parts of deionized water.
Further, a kind of described automatically cleaning mosquito proof interior wall coating, its preparation method comprise the following steps:
S10, slow-released carrier and composite insecticidal additive adsorb in advance:In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization In thing microsphere powder, quantitative effective cypermethrin, biological mosquito repellent liquid in the scattered lower successively addition formula of low speed, after being well mixed 24h is stood fully to adsorb in advance;
S11, thickener predissolve:The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated Slurry;
S12, accurately add deionized water to dispersion cylinder in order(A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving Remain pre- slurrying), the fine micro- element of ethoxy is put under the rotating speed of bottom successively to being completely dissolved, then adds dispersant, wetting agent, half Defoamer, titanium dioxide, calcined kaolin, powdered whiting, ready desinsection powder, tune up rotating speed and disperse 30-40min to slurry Expect that fineness is less than or equal to 50 microns;
S13, rotating speed is reduced, be sequentially added into silicone acrylic emulsion, covering emulsion, coalescents, second half defoamer, stir 10- After 20min, pre- slurrying and remaining deionized water are slowly put into adjust viscosity to claimed range, AMP-95 is eventually adding and stirs Mix, packed after adjusting emulsion adhesive and pH value, filtering.
Further, described titanium dioxide be any one of anatase thpe white powder or rutile type titanium white or its The mixture arbitrarily matched.
Further, described biological mosquito repellent liquid is pyrethrum extract, the mixing by tree extract solution, wormwood extract solution Thing.
Further, the thickener is polyurethane thickener.
Further, described described defoamer is organic silicon defoamer, mineral oil defoaming agent or its group Close.
Beneficial effect of the present invention:It is characteristic of the invention that using new Methyl Methacrylate-Styrene-butyl acrylate The nearly saturation of copolymer microsphere adsorbs the compound insecticidal component of efficient effective cypermethrin and biological mosquito repellent liquid, is added to through the breast of silicon third In the basic coating of liquid improvement, being prepared a kind of has good antibacterial and mouldproof effect, resistance to artificial weathering aging, stain resistance, resistance to Temperature denaturation, resistance to worm's ovum grow, it is resistance to damage by worms, slow-release pesticidal effect, the firmly strong automatically cleaning of indeformable, health environment-friendly, high-decoration Mosquito proof interior wall coating, this decorative paint not only has green, slow-release pesticidal action effect, and the decorative paint can Penetrate into cement wall surface and form an entirety with cement, adhesive force is especially strong, and hardness is big;Metope after decoration also has resistance to old Change, resistance to artificial weathering aging, stain resistance, temperature-change resistance, growths of resistance to worm's ovum, resistance to erosion, firmly indeformable, high-decoration is by force Advantage.
Embodiment
In order that present disclosure is more likely to be clearly understood, below according to the specific embodiment of the present invention, to this Invention is described in further detail.
Embodiment 1
A kind of automatically cleaning mosquito proof interior wall coating, its raw material include following components by weight:300 parts of silicone acrylic emulsion, covering 20 parts of emulsion, 150 parts of titanium dioxide, 3 parts of calcined kaolin, 2 parts of powdered whiting, 2 parts of nano inorganic negative ion antibiotic agent, methyl Methyl acrylate -10 parts of stupid ethylene-butyl acrylate copolymer microballoon, 5 parts of effective cypermethrin, 2 parts of biological mosquito repellent liquid, hydroxyl second Base is fine micro- plain 3 parts, 5 parts of thickener, 2 parts of defoamer, 5 parts of dispersant, 3 parts of wetting agent, 20 parts of coalescents,(AMP-95)1 part, Deionized water 150- parts.
Its preparation method comprises the following steps:
S10, slow-released carrier and composite insecticidal additive adsorb in advance:In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization In thing microsphere powder, quantitative effective cypermethrin, biological mosquito repellent liquid in the scattered lower successively addition formula of low speed, after being well mixed 24h is stood fully to adsorb in advance;
S11, thickener predissolve:The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated Slurry;
S12, accurately add deionized water to dispersion cylinder in order(A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving Remain pre- slurrying), the fine micro- element of ethoxy is put under the rotating speed of bottom successively to being completely dissolved, then adds dispersant, wetting agent, half Defoamer, titanium dioxide, calcined kaolin, powdered whiting, ready desinsection powder, tune up rotating speed and disperse 30min to slurry Fineness is less than or equal to 50 microns;
S13, rotating speed is reduced, be sequentially added into silicone acrylic emulsion, covering emulsion, coalescents, second half defoamer, stirred After 10min, pre- slurrying and remaining deionized water are slowly put into adjust viscosity to claimed range, AMP-95 is eventually adding and stirs Mix, packed after adjusting emulsion adhesive and pH value, filtering.
Described titanium dioxide is anatase thpe white powder.
Described biological mosquito repellent liquid is pyrethrum extract, by tree extract solution, the mixture of wormwood extract solution.
The thickener is polyurethane thickener.
Described described defoamer is organic silicon defoamer.
Embodiment 2
A kind of automatically cleaning mosquito proof interior wall coating, its raw material include following components by weight:600 parts of silicone acrylic emulsion, covering 40 parts of emulsion, 250 parts of titanium dioxide, 8 parts of calcined kaolin, 5 parts of powdered whiting, 6 parts of nano inorganic negative ion antibiotic agent, methyl Methyl acrylate -15 parts of stupid ethylene-butyl acrylate copolymer microballoon, 8 parts of effective cypermethrin, 5 parts of biological mosquito repellent liquid, hydroxyl second Base is fine micro- plain 5 parts, 9 parts of thickener, 4 parts of defoamer, 9 parts of dispersant, 6 parts of wetting agent, 50 parts of coalescents,(AMP-95)3 parts, 300 parts of deionized water.
Its preparation method comprises the following steps:
S10, slow-released carrier and composite insecticidal additive adsorb in advance:In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization In thing microsphere powder, quantitative effective cypermethrin, biological mosquito repellent liquid in the scattered lower successively addition formula of low speed, after being well mixed 24h is stood fully to adsorb in advance;
S11, thickener predissolve:The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated Slurry;
S12, accurately add deionized water to dispersion cylinder in order(A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving Remain pre- slurrying), the fine micro- element of ethoxy is put under the rotating speed of bottom successively to being completely dissolved, then adds dispersant, wetting agent, half Defoamer, titanium dioxide, calcined kaolin, powdered whiting, ready desinsection powder, tune up rotating speed and disperse 40min to slurry Fineness is less than or equal to 50 microns;
S13, rotating speed is reduced, be sequentially added into silicone acrylic emulsion, covering emulsion, coalescents, second half defoamer, stirred After 20min, pre- slurrying and remaining deionized water are slowly put into adjust viscosity to claimed range, AMP-95 is eventually adding and stirs Mix, packed after adjusting emulsion adhesive and pH value, filtering.
Described titanium dioxide is rutile type titanium white.
Described biological mosquito repellent liquid is pyrethrum extract, by tree extract solution, the mixture of wormwood extract solution.
The thickener is polyurethane thickener.
Described described defoamer is mineral oil defoaming agent.
Embodiment 3
A kind of automatically cleaning mosquito proof interior wall coating, its raw material include following components by weight:400 parts of silicone acrylic emulsion, covering 30 parts of emulsion, 200 parts of titanium dioxide, 6 parts of calcined kaolin, 4 parts of powdered whiting, 4 parts of nano inorganic negative ion antibiotic agent, methyl Methyl acrylate -12 parts of stupid ethylene-butyl acrylate copolymer microballoon, 6 parts of effective cypermethrin, 4 parts of biological mosquito repellent liquid, hydroxyl second Base is fine micro- plain 4 parts, 7 parts of thickener, 3 parts of defoamer, 6 parts of dispersant, 4 parts of wetting agent, 30 parts of coalescents,(AMP-95)2 parts, 200 parts of deionized water.
Its preparation method comprises the following steps:
S10, slow-released carrier and composite insecticidal additive adsorb in advance:In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization In thing microsphere powder, quantitative effective cypermethrin, biological mosquito repellent liquid in the scattered lower successively addition formula of low speed, after being well mixed 24h is stood fully to adsorb in advance;
S11, thickener predissolve:The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated Slurry;
S12, accurately add deionized water to dispersion cylinder in order(A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving Remain pre- slurrying), the fine micro- element of ethoxy is put under the rotating speed of bottom successively to being completely dissolved, then adds dispersant, wetting agent, half Defoamer, titanium dioxide, calcined kaolin, powdered whiting, ready desinsection powder, tune up rotating speed and disperse 35min to slurry Fineness is less than or equal to 50 microns;
S13, rotating speed is reduced, be sequentially added into silicone acrylic emulsion, covering emulsion, coalescents, second half defoamer, stirred After 15min, pre- slurrying and remaining deionized water are slowly put into adjust viscosity to claimed range, AMP-95 is eventually adding and stirs Mix, packed after adjusting emulsion adhesive and pH value, filtering.
Described titanium dioxide is the mixture that anatase thpe white powder and rutile type titanium white arbitrarily match.
Described biological mosquito repellent liquid is pyrethrum extract, by tree extract solution, the mixture of wormwood extract solution.
The thickener is polyurethane thickener.
The combination that described described defoamer is organic silicon defoamer, mineral oil defoaming agent arbitrarily matches Thing.
The action effect of the present invention be able to can be showed by Tables 1 and 2
Testing result of the table 1 for the present invention in terms of environmental-protecting performance
Table 2 is evaluated for the present invention in insecticidal effect
The traditional performance table of a kind of the automatically cleaning mosquito proof interior wall coating and film of the present invention of table 3
By table 1, table 2, table 3 it can be seen that the present invention a kind of automatically cleaning mosquito proof interior wall coating it is characteristic of the invention that using The nearly saturation of new Methyl Methacrylate-Styrene-butyl acrylate copolymer microballoon adsorbs efficient effective cypermethrin and life The compound insecticidal component of thing mosquito repellent liquid, it is added in the basic coating through silicone acrylic emulsion improvement, one kind, which is prepared, has antibacterial Anti-mold effect is good, resistance to artificial weathering aging, stain resistance, temperature-change resistance, resistance to worm's ovum grow, it is resistance to damage by worms, slow-release pesticidal effect, jail Gu the strong automatically cleaning mosquito proof interior wall coating of indeformable, health environment-friendly, high-decoration, this decorative paint not only have green ring Protect, slow-release pesticidal action effect, and the decorative paint can penetrate into and form an entirety, attachment in cement wall surface with cement Power is especially strong, and hardness is big;Metope after decoration also have it is ageing-resistant, it is resistance to artificial weathering aging, stain resistance, temperature-change resistance, resistance to Worm's ovum growth, resistance to erosion, firmly it is indeformable, high-decoration is strong the advantages of.

Claims (9)

1. a kind of automatically cleaning mosquito proof interior wall coating, it is characterised in that its raw material includes following components by weight:Silicone acrylic emulsion 300-600 parts, covering emulsion 20-40 parts, titanium dioxide 150-250 parts, calcined kaolin 3-8 parts, powdered whiting 2-5 parts, Nano inorganic negative ion antibiotic agent 2-6 parts, methyl methacrylate-stupid ethylene-butyl acrylate copolymer microballoon 10-15 parts, Effective cypermethrin 5-8 parts, biological mosquito repellent liquid 2-5 parts, the fine micro- plain 3-5 parts of ethoxy, thickener 5-9 parts, defoamer 2-4 parts, Dispersant 5-9 parts, wetting agent 3-6 parts, coalescents 20-50 parts,(AMP-95)1-3 parts, deionized water 150-300 parts.
2. a kind of automatically cleaning mosquito proof interior wall coating according to claim 1, it is characterised in that its raw material wraps by weight Include following components:300 parts of silicone acrylic emulsion, 20 parts of covering emulsion, 150 parts of titanium dioxide, 3 parts of calcined kaolin, powdered whiting 2 Part, 2 parts of nano inorganic negative ion antibiotic agent, methyl methacrylate -10 parts of stupid ethylene-butyl acrylate copolymer microballoon, height Imitate fine micro- plain 3 parts 5 parts of cypermethrin, 2 parts of biological mosquito repellent liquid, ethoxy, 5 parts of thickener, 2 parts of defoamer, 5 parts of dispersant, profit 3 parts of humectant, 20 parts of coalescents,(AMP-95)1 part, deionized water 150- parts.
3. a kind of automatically cleaning mosquito proof interior wall coating according to claim 1, it is characterised in that its raw material wraps by weight Include following components:600 parts of silicone acrylic emulsion, 40 parts of covering emulsion, 250 parts of titanium dioxide, 8 parts of calcined kaolin, powdered whiting 5 Part, 6 parts of nano inorganic negative ion antibiotic agent, methyl methacrylate -15 parts of stupid ethylene-butyl acrylate copolymer microballoon, height Imitate fine micro- plain 5 parts 8 parts of cypermethrin, 5 parts of biological mosquito repellent liquid, ethoxy, 9 parts of thickener, 4 parts of defoamer, 9 parts of dispersant, profit 6 parts of humectant, 50 parts of coalescents,(AMP-95)3 parts, 300 parts of deionized water.
4. a kind of automatically cleaning mosquito proof interior wall coating according to claim 1, it is characterised in that its raw material wraps by weight Include following components:400 parts of silicone acrylic emulsion, 30 parts of covering emulsion, 200 parts of titanium dioxide, 6 parts of calcined kaolin, powdered whiting 4 Part, 4 parts of nano inorganic negative ion antibiotic agent, methyl methacrylate -12 parts of stupid ethylene-butyl acrylate copolymer microballoon, height Imitate fine micro- plain 4 parts 6 parts of cypermethrin, 4 parts of biological mosquito repellent liquid, ethoxy, 7 parts of thickener, 3 parts of defoamer, 6 parts of dispersant, profit 4 parts of humectant, 30 parts of coalescents,(AMP-95)2 parts, 200 parts of deionized water.
5. according to a kind of any described automatically cleaning mosquito proof interior wall coatings of claim 1-4, it is characterised in that its preparation method Comprise the following steps:
S10, slow-released carrier and composite insecticidal additive adsorb in advance:In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization In thing microsphere powder, quantitative effective cypermethrin, biological mosquito repellent liquid in the scattered lower successively addition formula of low speed, after being well mixed 24h is stood fully to adsorb in advance;
S11, thickener predissolve:The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated Slurry;
S12, accurately add deionized water to dispersion cylinder in order(A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving Remain pre- slurrying), the fine micro- element of ethoxy is put under the rotating speed of bottom successively to being completely dissolved, then adds dispersant, wetting agent, half Defoamer, titanium dioxide, calcined kaolin, powdered whiting, ready desinsection powder, tune up rotating speed and disperse 30-40min to slurry Expect that fineness is less than or equal to 50 microns;
S13, rotating speed is reduced, be sequentially added into silicone acrylic emulsion, covering emulsion, coalescents, second half defoamer, stir 10- After 20min, pre- slurrying and remaining deionized water are slowly put into adjust viscosity to claimed range, AMP-95 is eventually adding and stirs Mix, packed after adjusting emulsion adhesive and pH value, filtering.
A kind of 6. automatically cleaning mosquito proof interior wall coating according to claim 1, it is characterised in that described titanium dioxide be for Any one of anatase thpe white powder or rutile type titanium white or its mixture arbitrarily matched.
7. according to a kind of any described automatically cleaning mosquito proof interior wall coatings of claim 1-4, it is characterised in that described biology Mosquito repellent liquid is pyrethrum extract, by tree extract solution, the mixture of wormwood extract solution.
8. according to a kind of any described automatically cleaning mosquito proof interior wall coatings of claim 1-4, it is characterised in that the thickener For polyurethane thickener.
9. according to a kind of any described automatically cleaning mosquito proof interior wall coatings of claim 1-4, it is characterised in that described is described Described defoamer is organic silicon defoamer, mineral oil defoaming agent or its combination.
CN201711104092.8A 2017-11-10 2017-11-10 A kind of automatically cleaning mosquito proof interior wall coating and preparation method thereof Pending CN107880685A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109207006A (en) * 2018-08-22 2019-01-15 河北晨阳工贸集团有限公司 A kind of interior wall coating and preparation method thereof with sleeping
CN110643235A (en) * 2019-10-16 2020-01-03 江苏久诺建材科技股份有限公司 Water-based negative ion interior wall coating and preparation method thereof
CN110713769A (en) * 2019-11-22 2020-01-21 常树高 Insect-proof environment-friendly emulsion paint
CN112680046A (en) * 2020-12-25 2021-04-20 江苏科创建筑节能科技有限公司 Water-based interior wall insect-repellent coating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109207006A (en) * 2018-08-22 2019-01-15 河北晨阳工贸集团有限公司 A kind of interior wall coating and preparation method thereof with sleeping
CN110643235A (en) * 2019-10-16 2020-01-03 江苏久诺建材科技股份有限公司 Water-based negative ion interior wall coating and preparation method thereof
CN110713769A (en) * 2019-11-22 2020-01-21 常树高 Insect-proof environment-friendly emulsion paint
CN112680046A (en) * 2020-12-25 2021-04-20 江苏科创建筑节能科技有限公司 Water-based interior wall insect-repellent coating and preparation method thereof

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