CN107699087A - A kind of water nano modification acrylate insecticidal and antibacterial coating and preparation method thereof - Google Patents
A kind of water nano modification acrylate insecticidal and antibacterial coating and preparation method thereof Download PDFInfo
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- CN107699087A CN107699087A CN201710968579.4A CN201710968579A CN107699087A CN 107699087 A CN107699087 A CN 107699087A CN 201710968579 A CN201710968579 A CN 201710968579A CN 107699087 A CN107699087 A CN 107699087A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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Abstract
The present invention provides a kind of water nano modification acrylate insecticidal and antibacterial coating, and its raw material includes following components by weight：35 50 parts of acrylic acid ester emulsion, 15 30 parts of titanium dioxide, 10 15 parts of nano titania slurry, 36 parts of antimicrobial nano titanium dioxide, 69 parts of oligomeric acrylic acid sodium solution, 59 parts of powdered whiting, 35 parts of the stupid ethylene butyl acrylate copolymer microballoon of methyl methacrylate, 0.5 0.8 parts of effective cypermethrin, 0.2 0.5 parts of plant extract wormwood extract solution, 0.1 0.3 parts of negative ion antibiotic additive, 25 parts of talcum powder, 0.3 0.9 parts of coalescents, 0.2 0.6 parts of dispersant, 0.3 0.6 parts of thickener, 0.3 0.6 parts of defoamer, 30 50 parts of deionized water.The present invention also provides its preparation method, coating of the invention have the advantages that good application property, resistance to artificial weathering aging, firmly indeformable, health environment-friendly, resistance to worm's ovum grow, it is resistance to damage by worms, slow-release pesticidal, antibacterial and mouldproof.
Description
Technical field
The present invention relates to a kind of coating, relate in particular to a kind of water nano modification acrylate insecticidal and antibacterial coating and
Its preparation method.
Background technology
The ornament materials of building and ornament materials particularly house inner wall at present, the effect of beautification indoor and outdoor is primarily served, is made
People is comfortable on warm, and house is more firm, and the material used is usually kaolin, silica ashes, talcum powder, mica powder, titanium
The raw materials such as white powder add dispersant, wetting agent, propane diols, emulsion, water and reconcile and form, and serve landscaping effect and protect wall
Still people to the requirement more and more higher of environmental protection, put forward new hope to decorative material for wall surface for effect --- and insecticidal and antibacterial applies
Material.Although present exterior material can make indoor wall beautiful and clean, so that it is more comfortable with living environment to live, it is many existing
Some building and ornament materials are in use easily in wall top layer mould growth and worm's ovum, especially coastal etc. humid area, mould
Can under 20-38 DEG C, the suitable condition of relative humidity 85% or so amount reproduction, corrode building surface, destroy ground, simultaneously
Dope for inner wall of architecture surface is because exposed area is big, and the main positions that fungi, bacterium, worm's ovum grow.It is these moulds, thin
On the one hand bacterium, fungi, worm's ovum destroy the attractive in appearance and erosion of coating surface, on the other hand also have a strong impact on people health and
Destruction to domestic environment.
The content of the invention
Therefore, to be solved by this invention be to provide a kind of water nano modification acrylate insecticidal and antibacterial coating and its system
Preparation Method, coating of the invention have good application property, firmly resistance to artificial weathering aging, indeformable, health environment-friendly, resistance to worm's ovum
Grow, it is resistance to damage by worms, slow-release pesticidal, antibacterial and mouldproof the advantages that.
In order to solve the above technical problems, the technical scheme is that：A kind of water nano modification acrylate desinsection resists
Bacterium coating, its raw material include following components by weight：Acrylic acid ester emulsion 35-50 parts, titanium dioxide 15-30 parts, nano-silica
Change titanium slurry 10-15 parts, antimicrobial nano titanium dioxide 3-6 parts, oligomeric acrylic acid sodium solution 6-9 parts, powdered whiting 5-9 parts,
Methyl methacrylate-stupid ethylene-butyl acrylate copolymer microballoon 3-5 parts, effective cypermethrin 0.5-0.8 parts, plant carry
Take wormwood extract solution 0.2-0.5 parts, negative ion antibiotic additive 0.1-0.3 parts, talcum powder 2-5 parts, coalescents 0.3-0.9
Part, dispersant 0.2-0.6 parts, thickener 0.3-0.6 parts, defoamer 0.3-0.6 parts, deionized water 30-50 parts.
Further, a kind of described water nano modification acrylate insecticidal and antibacterial coating, its raw material wrap by weight
Include following components：35 parts of acrylic acid ester emulsion, 15 parts of titanium dioxide, 10 parts of nano titania slurry, antimicrobial nano titanium dioxide 3
Part, 6 parts of oligomeric acrylic acid sodium solution, 5 parts of powdered whiting, methyl methacrylate-stupid ethylene-butyl acrylate copolymer are micro-
3 parts of ball, 0.5 part of effective cypermethrin, 0.2 part of plant extract wormwood extract solution, 0.1 part of negative ion antibiotic additive, talcum powder 2
Part, 0.3 part of coalescents, 0.2 part of dispersant, 0.3 part of thickener, 0.3 part of defoamer, 30 parts of deionized water.
Further, a kind of described water nano modification acrylate insecticidal and antibacterial coating, its raw material wrap by weight
Include following components：50 parts of acrylic acid ester emulsion, 30 parts of titanium dioxide, 15 parts of nano titania slurry, antimicrobial nano titanium dioxide
6 parts, 9 parts of oligomeric acrylic acid sodium solution, 9 parts of powdered whiting, methyl methacrylate-stupid ethylene-butyl acrylate copolymer
5 parts of microballoon, 0.8 part of effective cypermethrin, 0.5 part of plant extract wormwood extract solution, 0.3 part of negative ion antibiotic additive, talcum
5 parts of powder, 0.9 part of coalescents, 0.6 part of dispersant, 0.6 part of thickener, 0.6 part of defoamer, 50 parts of deionized water.
Further, a kind of described water nano modification acrylate insecticidal and antibacterial coating, its raw material wrap by weight
Include following components：45 parts of acrylic acid ester emulsion, 22 parts of titanium dioxide, 13 parts of nano titania slurry, antimicrobial nano titanium dioxide 5
Part, 7 parts of oligomeric acrylic acid sodium solution, 6 parts of powdered whiting, methyl methacrylate-stupid ethylene-butyl acrylate copolymer are micro-
4 parts of ball, 0.6 part of effective cypermethrin, 0.4 part of plant extract wormwood extract solution, 0.2 part of negative ion antibiotic additive, talcum powder 4
Part, 0.6 part of coalescents, 0.4 part of dispersant, 0.4 part of thickener, 0.4 part of defoamer, 35 parts of deionized water.
Further, described a kind of water nano modification acrylate insecticidal and antibacterial coating, its preparation method include with
Lower step：
S10, slow-released carrier and composite insecticidal additive adsorb in advance：In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization
In thing microsphere powder, quantitative effective cypermethrin, plant extract wormwood extract solution, are mixed in the scattered lower successively addition formula of low speed
24h, which is stood, after closing uniformly fully adsorbs to obtain pre- adsorption liquid in advance；
S11, thickener predissolve：The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated
Slurry；
S12, accurately add deionized water to dispersion cylinder in order（A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving
Remain pre- slurrying）, each nano material is put into successively to being completely dissolved under the rotating speed of bottom, then adds dispersant, coalescents, half
Defoamer, talcum powder, titanium dioxide, powdered whiting etc. and ready desinsection powder and negative ion antibiotic additive, tune up and turn
The scattered 30-40min of speed is to slurry fineness less than or equal to 50 microns；
S13, rotating speed is reduced, be sequentially added into acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, second half defoamer, stir 10-
After 20min, slowly put into pre- slurrying, pre- adsorption liquid and remaining deionized water low speed dispersion mixing both it is required a kind of water-based
Nano modified acrylic ester insecticidal and antibacterial coating.
Further, described titanium dioxide be any one of anatase thpe white powder or rutile type titanium white or its
The mixture arbitrarily matched.
Further, described powdered whiting was 1500 mesh sieve superfine powders.
Further, the dispersant is acrylic acid ammonia salt dispersant 1124 or ACSODIUM5045.
Further, described described defoamer is organic silicon defoamer, mineral oil defoaming agent or its group
Close.
The action effect of the present invention：
1st, the present invention in add nano titanium oxide after, nano material it is light scattering good, granularity is small and is evenly distributed, coating hide
Gai Li is significantly improved, and covering power growth rate is about 27.5%, improves the workability of coating；
2nd, the aqueous architectural coating for adding composite nano titanium dioxide in the present invention has sterilizing function, containing nano titanium oxide
Coating is preferable to staphylococcus aureus, Escherichia coli sterilization after ultraviolet irradiates 30min, and bacteriostasis rate is respectively
82.2% 79.2%, but in the case where being irradiated without ultraviolet, without obvious bactericidal effect；
3rd, it is characteristic of the invention that using new Methyl Methacrylate-Styrene-nearly saturation of butyl acrylate copolymer microballoon
The compound insecticidal component of efficient effective cypermethrin and plant extract wormwood extract solution is adsorbed, is added to the base of acrylic acid ester emulsion
In plinth coating, the water nano modification acrylate insecticidal and antibacterial coating being prepared can enduringly expel rapidly, tag respectively
Kind of insect, there is good antibacterial and mouldproof effect, resistance to artificial weathering aging, good application property, resistance to worm's ovum to grow, resistance to damage by worms, be sustained
Insecticidal effect, resistance to erosion, the coating for the high-decoration decoration that nontoxic to human body, environmental protection is attractive in appearance, this decorative paint not only have
There are green, slow-release pesticidal, antibacterial and mouldproof action effect, and the decorative paint can penetrate into cement wall surface and cement
An entirety is formed, adhesive force is especially strong, and hardness is big；Metope after decoration also have it is ageing-resistant, it is resistance to damage by worms, resistance to erosion, firmly
Indeformable, the characteristics of high-decoration is strong.
Embodiment
In order that present disclosure is more likely to be clearly understood, below according to the specific embodiment of the present invention, to this
Invention is described in further detail.
Embodiment 1
A kind of water nano modification acrylate insecticidal and antibacterial coating, its raw material include following components by weight：Acrylate
35 parts of emulsion, 15 parts of titanium dioxide, 10 parts of nano titania slurry, 3 parts of antimicrobial nano titanium dioxide, oligomeric acrylic acid sodium solution
6 parts, 5 parts of powdered whiting, methyl methacrylate -3 parts of stupid ethylene-butyl acrylate copolymer microballoon, effective cypermethrin
0.5 part, 0.2 part of plant extract wormwood extract solution, 0.1 part of negative ion antibiotic additive, 2 parts of talcum powder, 0.3 part of coalescents,
0.2 part of dispersant, 0.3 part of thickener, 0.3 part of defoamer, 30 parts of deionized water.
Its preparation method comprises the following steps：
S10, slow-released carrier and composite insecticidal additive adsorb in advance：In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization
In thing microsphere powder, quantitative effective cypermethrin, plant extract wormwood extract solution, are mixed in the scattered lower successively addition formula of low speed
24h, which is stood, after closing uniformly fully adsorbs to obtain pre- adsorption liquid in advance；
S11, thickener predissolve：The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated
Slurry；
S12, accurately add deionized water to dispersion cylinder in order（A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving
Remain pre- slurrying）, each nano material is put into successively to being completely dissolved under the rotating speed of bottom, then adds dispersant, coalescents, half
Defoamer, talcum powder, titanium dioxide, powdered whiting etc. and ready desinsection powder and negative ion antibiotic additive, tune up and turn
The scattered 30min of speed is to slurry fineness less than or equal to 50 microns；
S13, rotating speed is reduced, be sequentially added into acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, second half defoamer, stirred
After 10min, slowly put into pre- slurrying, pre- adsorption liquid and remaining deionized water low speed dispersion mixing both it is required a kind of water-based
Nano modified acrylic ester insecticidal and antibacterial coating.
Described titanium dioxide is anatase thpe white powder.
Described powdered whiting was 1500 mesh sieve superfine powders.
The dispersant is acrylic acid ammonia salt dispersant 1124.
Described described defoamer is organic silicon defoamer.
Embodiment 2
A kind of water nano modification acrylate insecticidal and antibacterial coating, its raw material include following components by weight：Acrylate
50 parts of emulsion, 30 parts of titanium dioxide, 15 parts of nano titania slurry, 6 parts of antimicrobial nano titanium dioxide, sodium low polyacrylate are molten
9 parts of liquid, 9 parts of powdered whiting, methyl methacrylate -5 parts of stupid ethylene-butyl acrylate copolymer microballoon, efficient chlorine cyanogen chrysanthemum
0.8 part of ester, 0.5 part of plant extract wormwood extract solution, 0.3 part of negative ion antibiotic additive, 5 parts of talcum powder, coalescents 0.9
Part, 0.6 part of dispersant, 0.6 part of thickener, 0.6 part of defoamer, 50 parts of deionized water.
Its preparation method comprises the following steps：
S10, slow-released carrier and composite insecticidal additive adsorb in advance：In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization
In thing microsphere powder, quantitative effective cypermethrin, plant extract wormwood extract solution, are mixed in the scattered lower successively addition formula of low speed
24h, which is stood, after closing uniformly fully adsorbs to obtain pre- adsorption liquid in advance；
S11, thickener predissolve：The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated
Slurry；
S12, accurately add deionized water to dispersion cylinder in order（A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving
Remain pre- slurrying）, each nano material is put into successively to being completely dissolved under the rotating speed of bottom, then adds dispersant, coalescents, half
Defoamer, talcum powder, titanium dioxide, powdered whiting etc. and ready desinsection powder and negative ion antibiotic additive, tune up and turn
The scattered 40min of speed is to slurry fineness less than or equal to 50 microns；
S13, rotating speed is reduced, be sequentially added into acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, second half defoamer, stirred
After 20min, slowly put into pre- slurrying, pre- adsorption liquid and remaining deionized water low speed dispersion mixing both it is required a kind of water-based
Nano modified acrylic ester insecticidal and antibacterial coating.
Described titanium dioxide is rutile type titanium white.
Described powdered whiting was 1500 mesh sieve superfine powders.
The dispersant is ACSODIUM5045.
Described described defoamer is mineral oil defoaming agent.
Embodiment 3
A kind of water nano modification acrylate insecticidal and antibacterial coating, its raw material include following components by weight：Acrylate
45 parts of emulsion, 22 parts of titanium dioxide, 13 parts of nano titania slurry, 5 parts of antimicrobial nano titanium dioxide, oligomeric acrylic acid sodium solution
7 parts, 6 parts of powdered whiting, methyl methacrylate -4 parts of stupid ethylene-butyl acrylate copolymer microballoon, effective cypermethrin
0.6 part, 0.4 part of plant extract wormwood extract solution, 0.2 part of negative ion antibiotic additive, 4 parts of talcum powder, 0.6 part of coalescents,
0.4 part of dispersant, 0.4 part of thickener, 0.4 part of defoamer, 35 parts of deionized water.
Its preparation method comprises the following steps：
S10, slow-released carrier and composite insecticidal additive adsorb in advance：In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization
In thing microsphere powder, quantitative effective cypermethrin, plant extract wormwood extract solution, are mixed in the scattered lower successively addition formula of low speed
24h, which is stood, after closing uniformly fully adsorbs to obtain pre- adsorption liquid in advance；
S11, thickener predissolve：The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated
Slurry；
S12, accurately add deionized water to dispersion cylinder in order（A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving
Remain pre- slurrying）, each nano material is put into successively to being completely dissolved under the rotating speed of bottom, then adds dispersant, coalescents, half
Defoamer, talcum powder, titanium dioxide, powdered whiting etc. and ready desinsection powder and negative ion antibiotic additive, tune up and turn
The scattered 35min of speed is to slurry fineness less than or equal to 50 microns；
S13, rotating speed is reduced, be sequentially added into acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, second half defoamer, stirred
After 15min, slowly put into pre- slurrying, pre- adsorption liquid and remaining deionized water low speed dispersion mixing both it is required a kind of water-based
Nano modified acrylic ester insecticidal and antibacterial coating.
Described titanium dioxide is the mixture of any proportioning in anatase thpe white powder or rutile type titanium white.
Described powdered whiting was 1500 mesh sieve superfine powders.
The dispersant is acrylic acid ammonia salt dispersant 1124.
Described described defoamer is organic silicon defoamer, the mixing of any proportioning of mineral oil defoaming agent
Thing.
A kind of water nano modification acrylate insecticidal and antibacterial coating property testing result of the present invention is as shown in table 1 below
Table 2 is a kind of water nano modification acrylate insecticidal and antibacterial coating covering power contrasting detection result table of the present invention
Table 3 is a kind of water nano modification acrylate insecticidal and antibacterial coating antibiosis performance detection table of the present invention
| For trying microbial strains | Coating clump count to be measured | Comparison coating clump count | Bacteriostasis rate/% |
| Staphylococcus aureus | 30 | 168 | 82.18 |
| Escherichia coli | 47 | 216 | 78.24 |
Table 4 is evaluated for a kind of water nano modification acrylate insecticidal and antibacterial coating of the present invention in insecticidal effect
By table 1, table 2, the table 4 of table 3 it can be seen that a kind of water nano modification acrylate insecticidal and antibacterial coating energy of the present invention
It is enough enduringly expel rapidly, tag various insects, there is good antibacterial and mouldproof effect, resistance to artificial weathering aging, the growth of resistance to worm's ovum, resistance to
Damage by worms, be slow-release pesticidal effect, resistance to erosion, good application property, nontoxic to human body, environmental protection high-decoration decoration attractive in appearance
Coating, this decorative paint not only has green, slow-release pesticidal, antibacterial and mouldproof action effect, and the decorative paint can
Penetrate into cement wall surface and form an entirety with cement, adhesive force is especially strong, and hardness is big；Metope after decoration also has resistance to old
Change, it is resistance to damage by worms, resistance to erosion, firmly it is indeformable, high-decoration is strong the characteristics of.
Claims (9)
1. a kind of water nano modification acrylate insecticidal and antibacterial coating, it is characterised in that its raw material includes following by weight
Component：Acrylic acid ester emulsion 35-50 parts, titanium dioxide 15-30 parts, nano titania slurry 10-15 parts, antimicrobial nano dioxy
Change titanium 3-6 parts, oligomeric acrylic acid sodium solution 6-9 parts, powdered whiting 5-9 parts, methyl methacrylate-stupid ethylene-acrylic acid
Acrylate copolymer microballoon 3-5 parts, effective cypermethrin 0.5-0.8 parts, plant extract wormwood extract solution 0.2-0.5 parts, anion
Antibacterial additives 0.1-0.3 parts, talcum powder 2-5 parts, coalescents 0.3-0.9 parts, dispersant 0.2-0.6 parts, thickener 0.3-
0.6 part, defoamer 0.3-0.6 parts, deionized water 30-50 parts.
2. a kind of water nano modification acrylate insecticidal and antibacterial coating according to claim 1, it is characterised in that it is former
Material includes following components by weight：35 parts of acrylic acid ester emulsion, 15 parts of titanium dioxide, 10 parts of nano titania slurry, antibacterial
3 parts of nano titanium oxide, 6 parts of oligomeric acrylic acid sodium solution, 5 parts of powdered whiting, methyl methacrylate-stupid ethylene-propylene
3 parts of butyl acrylate copolymer microballoon, 0.5 part of effective cypermethrin, 0.2 part of plant extract wormwood extract solution, negative ion antibiotic addition
0.1 part of agent, 2 parts of talcum powder, 0.3 part of coalescents, 0.2 part of dispersant, 0.3 part of thickener, 0.3 part of defoamer, deionized water
30 parts.
3. a kind of water nano modification acrylate insecticidal and antibacterial coating according to claim 1, it is characterised in that it is former
Material includes following components by weight：50 parts of acrylic acid ester emulsion, 30 parts of titanium dioxide, 15 parts of nano titania slurry, antibacterial
6 parts of nano titanium oxide, 9 parts of oligomeric acrylic acid sodium solution, 9 parts of powdered whiting, methyl methacrylate-stupid ethylene-propylene
5 parts of butyl acrylate copolymer microballoon, 0.8 part of effective cypermethrin, 0.5 part of plant extract wormwood extract solution, negative ion antibiotic addition
0.3 part of agent, 5 parts of talcum powder, 0.9 part of coalescents, 0.6 part of dispersant, 0.6 part of thickener, 0.6 part of defoamer, deionized water
50 parts.
4. a kind of water nano modification acrylate insecticidal and antibacterial coating according to claim 1, it is characterised in that it is former
Material includes following components by weight：45 parts of acrylic acid ester emulsion, 22 parts of titanium dioxide, 13 parts of nano titania slurry, antibacterial
5 parts of nano titanium oxide, 7 parts of oligomeric acrylic acid sodium solution, 6 parts of powdered whiting, methyl methacrylate-stupid ethylene-propylene
4 parts of butyl acrylate copolymer microballoon, 0.6 part of effective cypermethrin, 0.4 part of plant extract wormwood extract solution, negative ion antibiotic addition
0.2 part of agent, 4 parts of talcum powder, 0.6 part of coalescents, 0.4 part of dispersant, 0.4 part of thickener, 0.4 part of defoamer, deionized water
35 parts.
5. according to a kind of any described water nano modification acrylate insecticidal and antibacterial coating of claim 1-4, its feature exists
In its preparation method comprises the following steps：
S10, slow-released carrier and composite insecticidal additive adsorb in advance：In methyl methacrylate-stupid Ethylene-butyl acrylate copolymerization
In thing microsphere powder, quantitative effective cypermethrin, plant extract wormwood extract solution, are mixed in the scattered lower successively addition formula of low speed
24h, which is stood, after closing uniformly fully adsorbs to obtain pre- adsorption liquid in advance；
S11, thickener predissolve：The thickener for needing to add is well mixed with 15 times of deionized waters, sealing is stand-by i.e. prefabricated
Slurry；
S12, accurately add deionized water to dispersion cylinder in order（A reserved part can be used for adjustment viscosity, rinse casing wall, dissolving
Remain pre- slurrying）, each nano material is put into successively to being completely dissolved under the rotating speed of bottom, then adds dispersant, coalescents, half
Defoamer, talcum powder, titanium dioxide, powdered whiting etc. and ready desinsection powder and negative ion antibiotic additive, tune up and turn
The scattered 30-40min of speed is to slurry fineness less than or equal to 50 microns；
S13, rotating speed is reduced, be sequentially added into acrylic acid ester emulsion, oligomeric acrylic acid sodium solution, second half defoamer, stir 10-
After 20min, slowly put into pre- slurrying, pre- adsorption liquid and remaining deionized water low speed dispersion mixing both it is required a kind of water-based
Nano modified acrylic ester insecticidal and antibacterial coating.
6. according to a kind of any described water nano modification acrylate insecticidal and antibacterial coating of claim 1-4, its feature exists
In described titanium dioxide is any one of anatase thpe white powder or rutile type titanium white or its mixing arbitrarily matched
Thing.
7. according to a kind of any described water nano modification acrylate insecticidal and antibacterial coating of claim 1-4, its feature exists
In described powdered whiting was 1500 mesh sieve superfine powders.
8. according to a kind of any described water nano modification acrylate insecticidal and antibacterial coating of claim 1-4, its feature exists
In the dispersant is acrylic acid ammonia salt dispersant 1124 or ACSODIUM5045.
9. according to a kind of any described water nano modification acrylate insecticidal and antibacterial coating of claim 1-4, its feature exists
In described described defoamer is organic silicon defoamer, mineral oil defoaming agent or its combination.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135372A (en) * | 2018-07-24 | 2019-01-04 | 张家港市五湖新材料技术开发有限公司 | A kind of formula of antibacterium paint |
| CN109370350A (en) * | 2018-10-24 | 2019-02-22 | 江西豪邦实业有限公司 | A kind of antibacterial and mouldproof aqueous latex paint and preparation method thereof for inner wall of building |
-
2017
- 2017-10-18 CN CN201710968579.4A patent/CN107699087A/en active Pending
Non-Patent Citations (2)
| Title |
|---|
| 杨新革: ""纳米水性丙烯酸抗菌涂料的制备与性能研究"", 《临沂师范学院学报》 * |
| 陈明毅等: ""环保缓释杀虫内墙乳胶漆的制备"", 《中国涂料》 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109135372A (en) * | 2018-07-24 | 2019-01-04 | 张家港市五湖新材料技术开发有限公司 | A kind of formula of antibacterium paint |
| CN109370350A (en) * | 2018-10-24 | 2019-02-22 | 江西豪邦实业有限公司 | A kind of antibacterial and mouldproof aqueous latex paint and preparation method thereof for inner wall of building |
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