CN108314944A - A kind of wall environment friendly emulsion paint and preparation method thereof - Google Patents
A kind of wall environment friendly emulsion paint and preparation method thereof Download PDFInfo
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- CN108314944A CN108314944A CN201810117361.2A CN201810117361A CN108314944A CN 108314944 A CN108314944 A CN 108314944A CN 201810117361 A CN201810117361 A CN 201810117361A CN 108314944 A CN108314944 A CN 108314944A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a kind of wall environment friendly emulsion paints and preparation method thereof, are related to coating for wall surface technical field, include the raw material of following parts by weight meter：Expect 35 42 parts, 3 10 parts of algae clay, 6 15 parts of wollastonite in powder, 8 16 parts of calcium carbonate, 5 10 parts of mica, 38 parts of attapulgite, 46 parts of titanium dioxide, 48 parts of bamboo fibre, 38 parts of ceramic fibre, 13 parts of nano silicon dioxide, 13 parts of nano-titanium dioxide, 13 parts of nano zine oxide, 47 parts of silane coupling agent, 58 parts of polymer dispersion powder, 12 parts of dispersant, 24 parts of 24 parts of bacteria mildew-proof agent and coalescents；Wall environment friendly emulsion paint raw material of the present invention be mostly it is nontoxic be not easy volatile chemical substance, be free of formaldehyde substance, chemical property stablize; to human health no damage, caking property is good, easy to apply uniform; preparation process is simple, and cost of material is low, is suitble to large-scale promotion production.
Description
Technical field
The present invention relates to coating for wall surface technical fields, and in particular to a kind of wall environment friendly emulsion paint and preparation method thereof.
Background technology
Currently, there are many type of the coating used in daily finishing, emulsion paint is that extensive wall dress is made in current use
One of exterior material.In recent years, with the development of economy, people's environmental protection, health perception are continuously improved, to what is used in building decoration
The selection of wall surfacing material is increasingly stringenter, and fact explanation develops coating environmentally friendly, that pollution is small and has become trend of the times, because
It is the principal element for causing people's body damage to be hindered in air pollution for noxious material in coating, medical evidence works as indoor formaldehyde
Content can cause people to have the malaise symptoms such as headache, Nausea and vomiting, weak when being more than a certain amount of, if leaving scene not in time, sternly
It can twitch, go into a coma when weight, failure of memory, injuring the liver, kidney, brain and nervous system of people.The emulsion paint of the prior art
Various nuisances are constantly waved outward in production, use, smearing drying process, to cause air pollution, injure people's
Body.Even the volatilization phase of some noxious materials is up to some months or several years as long as, is a kind of potential to human health
It threatens.
Invention content
For problems of the prior art, the present invention provides a kind of wall environment friendly emulsion paint and preparation method thereof,
Wall environment friendly emulsion paint raw material of the present invention be mostly it is nontoxic be not easy volatile chemical substance, be free of formaldehyde substance, chemical property
Stablize, to human health no damage, caking property is good, and easy to apply uniformly preparation process is simple, and cost of material is low, is suitble to scale
Promote production.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of wall environment friendly emulsion paint includes the raw material of following parts by weight meter：
35-42 parts of major ingredient, 3-10 parts of algae clay, 6-15 parts of wollastonite in powder, 8-16 parts of calcium carbonate, 5-10 parts of mica, bumps
3-8 parts of stick soil, 4-6 parts of titanium dioxide, 4-8 parts of bamboo fibre, 3-8 parts of ceramic fibre, 1-3 parts of nano silicon dioxide, nanometer titanium dioxide
It is 1-3 parts of titanium, 1-3 parts of nano zine oxide, 4-7 parts of silane coupling agent, 5-8 parts of polymer dispersion powder, 1-2 parts of dispersant, antibacterial anti-
Mould dose 2-4 parts and 2-4 parts of coalescents；
The major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio (5-8):(1-2):(0.2-0.5)
Mixing composition.
Preferably, include the raw material of following parts by weight meter:38 parts of major ingredient, 6 parts of algae clay, 9 parts of wollastonite in powder, calcium carbonate 12
Part, 6 parts of mica, 7 parts of attapulgite, 5 parts of titanium dioxide, 6 parts of bamboo fibre, 6 parts of ceramic fibre, 2 part, nanometer two of nano silicon dioxide
It is 1.8 parts of titanium oxide, 1.5 parts of nano zine oxide, 6 parts of silane coupling agent, 6 parts of polymer dispersion powder, 1.4 parts of dispersant, antibacterial anti-
Mould dose 3 parts and 2.8 parts of coalescents；
The major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio 6:1.2:0.4 mixing composition.
Preferably, the silane coupling agent is vinyltriethoxysilane, vinyltrimethoxysilane, β-(3,4 rings
Oxygen cyclohexyl) one or more of ethyl trimethoxy silane and γ-(methacryloxy) propyl trimethoxy silicane
In conjunction with.
Preferably, the polymer dispersion powder is that ethylene-vinyl acetate copolymer or polyvinyl acetate-carboxylic acids are total
Polymers.
Preferably, the dispersant is that one or more of pyrophosphate, tertiary sodium phosphate, calgon combine；
Bacteria mildew-proof agent is 1,2-benzisothiazolin-3-one or 2- (4- thiazolyls) benzimidazole；
Coalescents are that one or more of ethylene glycol, propylene glycol, hexylene glycol and diglycol combine.
A kind of preparation method of above-mentioned wall environment friendly emulsion paint is also disclosed in the present invention specifically to include the following steps：
(1) major ingredient is prepared：Polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol are weighed according to mass ratio, is mixed, is warming up to
55-75 degrees Celsius, with 800-1200 revs/min stirring 20-40 minutes to get major ingredient, it is spare；
(2) raw material is weighed：Each raw material is weighed according to the raw material weight number of wall environment friendly emulsion paint；
(3) successively by algae clay, wollastonite in powder, calcium carbonate, mica, attapulgite, titanium dioxide, bamboo fibre, ceramic fibre
It puts into ball mill and is uniformly mixed, abrasive grains grain size to 200-500 mesh is spare to get mixture M；
(4) by major ingredient, mixture A, nano silicon dioxide, nano-titanium dioxide, nano zine oxide, silane coupling agent, can
Dispersed latex powder, dispersant, bacteria mildew-proof agent and coalescents and suitable solvent are uniformly mixed, and are warming up to 40-55 degrees Celsius,
It is stirred 30-60 minutes with 600-900 revs/min, is cooled to room temperature to get the wall environment friendly emulsion paint.
Preferably, the dosage of solvent is 0.5-0.8 times of major ingredient dosage in the step (4).
Preferably, the solvent in the step (4) is deionized water or 25wt% ethanol solutions.
The present invention has following advantageous effect：
(1) wall environment friendly emulsion paint raw material of the present invention be mostly it is nontoxic be not easy volatile chemical substance, be free of formaldehydes object
Matter, chemical property are stablized, and to human health no damage, caking property is good, and easy to apply uniformly preparation process is simple, and cost of material is low,
It is suitble to large-scale promotion production.
(2) major ingredient added in raw material of the present invention is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio (5-
8):(1-2):(0.2-0.5) mixing composition, the mixing major ingredient chemical property under this ratio are stablized, water resistance, alkali resistance and resistance to old
It is good to change performance, coating surface of wall easily scrubs；And there is very high caking property coating surface of wall, fastening adhesion, no
It is easy to fall off, and this three kinds of substances all have at low cost, chemical property stabilization and environmental-friendly feature, mixed material tool
For higher chemical stability and comprehensive performance；
(2) algae clay is added in raw material of the present invention as raw material, algae clay rough surface is orderly, different skin texture figures
Case, the extinction material in different colors and material change the reflection of light, refraction, reduce light pollution, are inside algae clay
Many compact arranged microcellular structures can adsorb the noxious material in air and extra moisture, have environment purification and tune
The advantages of saving air humidity is added in emulsion paint, can improve the characteristic of traditional emulsion paint release noxious material；
(4) mica is added in raw material of the present invention, mica can improve the mechanical strength of emulsion paint, enhancing toughness, attachment
Power and anti-aging corrosion resistance etc., while the surface smoothness of emulsion paint can be enhanced；
(5) it is added with bamboo fibre in raw material of the present invention, a kind of " bamboo a kind of jade " chemical substance is contained in bamboo fibre, is had naturally
Antibacterial, anti-mite, deodorization, insect prevention function.It is primarily due to own and has antibacterial, bacteria resistance function, bacterium in the above can not be numerous
It grows, can not even survive, be added to the usage time and bacteriostasis property that can enhance emulsion paint in emulsion paint；
(6) in raw material of the present invention be added with nano zine oxide, nano zine oxide can improve emulsion paint product smoothness,
Wearability, mechanical strength and anti-aging property performance indicator, extend the service life of emulsion paint；
(7) silane coupling agent is added in raw material of the present invention, silane coupling agent can be with the inorganic matter in latex raw materials for varnish
In conjunction with, and can interact with the organic matter in raw material, so that raw material of different nature is combined, so as to improve emulsion paint
Various performances and compactness.
Specific implementation mode
The specific implementation mode of the present invention is further described with reference to embodiment, following embodiment is only used for more
Technical scheme of the present invention is clearly demonstrated, and not intended to limit the protection scope of the present invention.
Embodiment 1
A kind of wall environment friendly emulsion paint includes the raw material of following parts by weight meter：
35 parts of major ingredient, 3 parts of algae clay, 6 parts of wollastonite in powder, 8 parts of calcium carbonate, 5 parts of mica, 3 parts of attapulgite, titanium dioxide 4
Part, 4 parts of bamboo fibre, 3 parts of ceramic fibre, 1 part of nano silicon dioxide, 1 part of nano-titanium dioxide, 1 part of nano zine oxide, silane are even
Join 2 parts of 4 parts of agent, 5 parts of polymer dispersion powder, 1 part of dispersant, 2 parts of bacteria mildew-proof agent and coalescents；
Major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio 5:1:0.2 mixing composition.
Silane coupling agent is vinyltriethoxysilane and vinyltrimethoxysilane according to mass ratio 2:1 mixing group
At.
Polymer dispersion powder is ethylene-vinyl acetate copolymer.
Dispersant is sodium pyrophosphate；
Bacteria mildew-proof agent is 1,2-benzisothiazolin-3-one；
Coalescents are ethylene glycol and propylene glycol according to mass ratio 1:1 mixing composition.
A kind of preparation method of above-mentioned wall environment friendly emulsion paint is also disclosed in the present embodiment, specifically, including following step
Suddenly：
(1) major ingredient is prepared：Polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol are weighed according to mass ratio, is mixed, is warming up to
55 degrees Celsius, with 800 revs/min stirring 20 minutes to get major ingredient, it is spare；
(2) raw material is weighed：Each raw material is weighed according to the raw material weight number of wall environment friendly emulsion paint；
(3) successively by algae clay, wollastonite in powder, calcium carbonate, mica, attapulgite, titanium dioxide, bamboo fibre, ceramic fibre
It puts into ball mill and is uniformly mixed, abrasive grains grain size to 200 mesh is spare to get mixture M；
(4) by major ingredient, mixture A, nano silicon dioxide, nano-titanium dioxide, nano zine oxide, silane coupling agent, can
Dispersed latex powder, dispersant, bacteria mildew-proof agent and coalescents and suitable solvent are uniformly mixed, and are warming up to 40 degrees Celsius, with
600 revs/min are stirred 30 minutes, are cooled to room temperature to get the wall environment friendly emulsion paint.
The dosage of solvent is 0.5 times of major ingredient dosage in step (4).
Solvent in step (4) is deionized water.
Embodiment 2
A kind of wall environment friendly emulsion paint includes the raw material of following parts by weight meter：
42 parts of major ingredient, 10 parts of algae clay, 15 parts of wollastonite in powder, 16 parts of calcium carbonate, 10 parts of mica, 8 parts of attapulgite, titanium white
6 parts of powder, 8 parts of bamboo fibre, 8 parts of ceramic fibre, 3 parts of nano silicon dioxide, 3 parts of nano-titanium dioxide, 3 parts of nano zine oxide, silicon
4 parts of 7 parts of alkane coupling agent, 8 parts of polymer dispersion powder, 2 parts of dispersant, 4 parts of bacteria mildew-proof agent and coalescents；
Major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio 8:2:0.5 mixing composition.
Silane coupling agent be vinyltrimethoxysilane and β-(3,4 epoxycyclohexyl) ethyl trimethoxy silanes according to
Mass ratio 1:2 mixing compositions.
Polymer dispersion powder is polyvinyl acetate-carboxylic acid copolymer.
Dispersant is tertiary sodium phosphate and calgon according to mass ratio 1:1 mixing composition；
Bacteria mildew-proof agent is 2- (4- thiazolyls) benzimidazole；
Coalescents are ethylene glycol.
A kind of preparation method of above-mentioned wall environment friendly emulsion paint is also disclosed in the present embodiment, specifically, including following step
Suddenly：
(1) major ingredient is prepared：Polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol are weighed according to mass ratio, is mixed, is warming up to
75 degrees Celsius, with 1200 revs/min stirring 40 minutes to get major ingredient, it is spare；
(2) raw material is weighed：Each raw material is weighed according to the raw material weight number of wall environment friendly emulsion paint；
(3) successively by algae clay, wollastonite in powder, calcium carbonate, mica, attapulgite, titanium dioxide, bamboo fibre, ceramic fibre
It puts into ball mill and is uniformly mixed, abrasive grains grain size to 500 mesh is spare to get mixture M；
(4) by major ingredient, mixture A, nano silicon dioxide, nano-titanium dioxide, nano zine oxide, silane coupling agent, can
Dispersed latex powder, dispersant, bacteria mildew-proof agent and coalescents and suitable solvent are uniformly mixed, and are warming up to 40-55 degrees Celsius,
It is stirred 60 minutes with 900 revs/min, is cooled to room temperature to get the wall environment friendly emulsion paint.
The dosage of solvent is 0.8 times of major ingredient dosage in step (4).
Solvent 25wt% ethanol solutions in step (4).
Embodiment 3
A kind of wall environment friendly emulsion paint includes the raw material of following parts by weight meter：
38 parts of major ingredient, 6 parts of algae clay, 9 parts of wollastonite in powder, 12 parts of calcium carbonate, 6 parts of mica, 7 parts of attapulgite, titanium dioxide 5
Part, 6 parts of bamboo fibre, 6 parts of ceramic fibre, 2 parts of nano silicon dioxide, 1.8 parts of nano-titanium dioxide, 1.5 parts of nano zine oxide, silicon
2.8 parts of 6 parts of alkane coupling agent, 6 parts of polymer dispersion powder, 1.4 parts of dispersant, 3 parts of bacteria mildew-proof agent and coalescents；
The major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio 6:1.2:0.4 mixing composition.
Silane coupling agent is β-(3,4 epoxycyclohexyl) ethyl trimethoxy silanes and γ-(methacryloxy) third
Base trimethoxy silane mixing composition.
Polymer dispersion powder is ethylene-vinyl acetate copolymer.
Dispersant is tertiary sodium phosphate；
Bacteria mildew-proof agent is 1,2-benzisothiazolin-3-one；
Coalescents are ethylene glycol and diglycol according to mass ratio 1:1 mixing composition.
A kind of preparation method of above-mentioned wall environment friendly emulsion paint is also disclosed in the present embodiment, specifically, including following step
Suddenly：
(1) major ingredient is prepared：Polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol are weighed according to mass ratio, is mixed, is warming up to
60 degrees Celsius, with 1000 revs/min stirring 30 minutes to get major ingredient, it is spare；
(2) raw material is weighed：Each raw material is weighed according to the raw material weight number of wall environment friendly emulsion paint；
(3) successively by algae clay, wollastonite in powder, calcium carbonate, mica, attapulgite, titanium dioxide, bamboo fibre, ceramic fibre
It puts into ball mill and is uniformly mixed, abrasive grains grain size to 400 mesh is spare to get mixture M；
(4) by major ingredient, mixture A, nano silicon dioxide, nano-titanium dioxide, nano zine oxide, silane coupling agent, can
Dispersed latex powder, dispersant, bacteria mildew-proof agent and coalescents and suitable solvent are uniformly mixed, and are warming up to 50 degrees Celsius, with
800 revs/min are stirred 45 minutes, are cooled to room temperature to get the wall environment friendly emulsion paint.
The dosage of solvent is 0.6 times of major ingredient dosage in step (4).
Solvent in step (4) is 25wt% ethanol solutions.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of wall environment friendly emulsion paint, which is characterized in that including following raw material by weight：35-42 parts of major ingredient, seaweed
3-10 parts of mud, 6-15 parts of wollastonite in powder, 8-16 parts of calcium carbonate, 5-10 parts of mica, 3-8 parts of attapulgite, 4-6 parts of titanium dioxide, bamboo
4-8 parts of fiber, 3-8 parts of ceramic fibre, 1-3 parts of nano silicon dioxide, 1-3 parts of nano-titanium dioxide, 1-3 parts of nano zine oxide,
2-4 parts of 4-7 parts of silane coupling agent, 5-8 parts of polymer dispersion powder, 1-2 parts of dispersant, 2-4 parts of bacteria mildew-proof agent and coalescents；
The major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio (5-8):(1-2):(0.2-0.5) is mixed
Composition.
2. wall environment friendly emulsion paint according to claim 1, which is characterized in that include the raw material of following parts by weight meter:It is main
38 parts of material, 6 parts of algae clay, 9 parts of wollastonite in powder, 12 parts of calcium carbonate, 6 parts of mica, 7 parts of attapulgite, 5 parts of titanium dioxide, bamboo fibre 6
Part, 6 parts of ceramic fibre, 2 parts of nano silicon dioxide, 1.8 parts of nano-titanium dioxide, 1.5 parts of nano zine oxide, silane coupling agent 6
2.8 parts of part, 6 parts of polymer dispersion powder, 1.4 parts of dispersant, 3 parts of bacteria mildew-proof agent and coalescents；
The major ingredient is polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol according to mass ratio 6:1.2:0.4 mixing composition.
3. wall environment friendly emulsion paint according to claim 1, which is characterized in that the silane coupling agent is three second of vinyl
Oxysilane, vinyltrimethoxysilane, β-(3,4 epoxycyclohexyl) ethyl trimethoxy silanes and γ-(methacryls
Oxygroup) one or more of propyl trimethoxy silicane combines.
4. wall environment friendly emulsion paint according to claim 1, which is characterized in that the polymer dispersion powder is ethylene-vinegar
Vinyl acetate copolymer or polyvinyl acetate-carboxylic acid copolymer.
5. wall environment friendly emulsion paint according to claim 1, which is characterized in that the dispersant is pyrophosphate, phosphoric acid
One or more of trisodium, calgon combine, and bacteria mildew-proof agent is 1,2-benzisothiazolin-3-one or 2- (4-
Thiazolyl) benzimidazole, coalescents are one or more of ethylene glycol, propylene glycol, hexylene glycol and diglycol knot
It closes.
6. a kind of preparation method of wall environment friendly emulsion paint as described in any one in claim 1-5, which is characterized in that including with
Lower step：
(1) major ingredient is prepared：Polyacrylate, phenylpropyl alcohol breast and polyvinyl alcohol are weighed according to mass ratio, is mixed, is warming up to 55-
75 degrees Celsius, with 800-1200 revs/min stirring 20-40 minutes to get major ingredient, it is spare；
(2) raw material is weighed：Each raw material is weighed according to the raw material weight number of wall environment friendly emulsion paint；
(3) algae clay, wollastonite in powder, calcium carbonate, mica, attapulgite, titanium dioxide, bamboo fibre, ceramic fibre are put into successively
It is uniformly mixed in ball mill, abrasive grains grain size to 200-500 mesh is spare to get mixture M；
(4) by major ingredient, mixture A, nano silicon dioxide, nano-titanium dioxide, nano zine oxide, silane coupling agent, dispersible
Latex powder, dispersant, bacteria mildew-proof agent and coalescents and suitable solvent are uniformly mixed, and are warming up to 40-55 degrees Celsius, with
600-900 revs/min is stirred 30-60 minutes, is cooled to room temperature to get the wall environment friendly emulsion paint.
7. wall environment friendly emulsion paint according to claim 6, which is characterized in that the dosage of solvent is in the step (4)
0.5-0.8 times of major ingredient dosage.
8. the preparation method of wall environment friendly emulsion paint according to claim 7, which is characterized in that in the step (4)
Solvent is deionized water or 25wt% ethanol solutions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810117361.2A CN108314944A (en) | 2018-02-06 | 2018-02-06 | A kind of wall environment friendly emulsion paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810117361.2A CN108314944A (en) | 2018-02-06 | 2018-02-06 | A kind of wall environment friendly emulsion paint and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN108314944A true CN108314944A (en) | 2018-07-24 |
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| CN201810117361.2A Withdrawn CN108314944A (en) | 2018-02-06 | 2018-02-06 | A kind of wall environment friendly emulsion paint and preparation method thereof |
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| CN108997847A (en) * | 2018-08-29 | 2018-12-14 | 尚晴 | A kind of high abrasion high durable dry powder emulsion paint and preparation method thereof |
| CN109021632A (en) * | 2018-08-19 | 2018-12-18 | 柳州市家富连装饰有限公司 | A kind of environment-friendly type indoor wall emulsion paint and preparation method thereof |
| CN109280440A (en) * | 2018-09-25 | 2019-01-29 | 贵州毕节浩昇环保建材有限公司 | A kind of environment friendly emulsion paint and preparation method thereof |
| CN109734990A (en) * | 2018-12-28 | 2019-05-10 | 北京理工大学 | Two-dimensional material nano modification flame-proof ethylene-vinyl acetate copolymer method |
| CN110003756A (en) * | 2019-02-25 | 2019-07-12 | 常州市奥普泰克光电科技有限公司 | A kind of preparation method of resistant Lacquer finish material |
| CN110054950A (en) * | 2019-03-23 | 2019-07-26 | 上海雷鸟涂料有限公司 | A kind of acrylic wall emulsion paint and its preparation process |
| CN111690298A (en) * | 2020-07-08 | 2020-09-22 | 吉林省家森林量子科技有限公司 | Quantum energy multifunctional interior wall coating and preparation method thereof |
| CN111851858A (en) * | 2020-06-23 | 2020-10-30 | 浙江艺玛材料科技有限公司 | Building energy-saving humidifying porcelain plate and preparation method thereof |
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| CN109021632A (en) * | 2018-08-19 | 2018-12-18 | 柳州市家富连装饰有限公司 | A kind of environment-friendly type indoor wall emulsion paint and preparation method thereof |
| CN108997847A (en) * | 2018-08-29 | 2018-12-14 | 尚晴 | A kind of high abrasion high durable dry powder emulsion paint and preparation method thereof |
| CN109280440A (en) * | 2018-09-25 | 2019-01-29 | 贵州毕节浩昇环保建材有限公司 | A kind of environment friendly emulsion paint and preparation method thereof |
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| CN110003756A (en) * | 2019-02-25 | 2019-07-12 | 常州市奥普泰克光电科技有限公司 | A kind of preparation method of resistant Lacquer finish material |
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| CN111851858A (en) * | 2020-06-23 | 2020-10-30 | 浙江艺玛材料科技有限公司 | Building energy-saving humidifying porcelain plate and preparation method thereof |
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| CN111690298A (en) * | 2020-07-08 | 2020-09-22 | 吉林省家森林量子科技有限公司 | Quantum energy multifunctional interior wall coating and preparation method thereof |
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Application publication date: 20180724 |