CN101585691B - Attapulgite interior wall powder coating - Google Patents
Attapulgite interior wall powder coating Download PDFInfo
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- CN101585691B CN101585691B CN2009100262910A CN200910026291A CN101585691B CN 101585691 B CN101585691 B CN 101585691B CN 2009100262910 A CN2009100262910 A CN 2009100262910A CN 200910026291 A CN200910026291 A CN 200910026291A CN 101585691 B CN101585691 B CN 101585691B
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- CN
- China
- Prior art keywords
- interior wall
- powder coating
- attapulgite
- wall powder
- attapulgite interior
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- 239000011248 coating agent Substances 0.000 title claims abstract description 56
- 238000000576 coating method Methods 0.000 title claims abstract description 56
- 229960000892 attapulgite Drugs 0.000 title claims abstract description 53
- 229910052625 palygorskite Inorganic materials 0.000 title claims abstract description 53
- 239000000843 powder Substances 0.000 title claims abstract description 51
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 6
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000002518 antifoaming agent Substances 0.000 claims abstract description 6
- 239000006081 fluorescent whitening agent Substances 0.000 claims abstract description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 6
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 6
- 239000000428 dust Substances 0.000 claims description 7
- 238000010298 pulverizing process Methods 0.000 claims description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 11
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003086 colorant Substances 0.000 abstract description 4
- 238000005034 decoration Methods 0.000 abstract description 2
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 238000000227 grinding Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229940068984 polyvinyl alcohol Drugs 0.000 abstract 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 abstract 1
- 239000012855 volatile organic compound Substances 0.000 abstract 1
- 239000004927 clay Substances 0.000 description 7
- 239000012535 impurity Substances 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000005416 organic matter Substances 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 239000010433 feldspar Substances 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- XQSFXFQDJCDXDT-UHFFFAOYSA-N hydroxysilicon Chemical compound [Si]O XQSFXFQDJCDXDT-UHFFFAOYSA-N 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011022 opal Substances 0.000 description 1
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 230000007096 poisonous effect Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000008234 soft water Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000002277 temperature effect Effects 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 230000002087 whitening effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses an attapulgite interior wall powder coating. The key point of the technical proposal of the invention is that the attapulgite interior wall powder coating consists of purified attapulgite, precipitated calcium carbonate, polyvinyl alcohol ultrafines, instant sodium silicate, anatase titanium dioxide, a solid polyether defoaming agent and a fluorescent whitening agent VBL. The method for producing the attapulgite interior wall powder coating comprises the steps of material mixing, crashing, grinding into powder and packaging to obtain a finished product of the attapulgite interior wall powder coating. The attapulgite interior wall powder coating has strong adhesive force, high durability, water resistance, friction resistance and dirt resistance, and can absorb formaldehyde and volatile organic compound to purify air. The attapulgite paste interior wall powder coating is a white reference coating and can be directly adjusted in color to produce color washes of various colors; and the attapulgite interior wall powder coating is applicable to building decoration.
Description
Technical field
The present invention relates to coating, be specifically related to a kind of attapulgite interior wall powder coating.
Background technology
Interior wall coating directly is coated on the internal surface of buildings or structures, and is more close with people's life or work relationship.The decorative effect of interior wall coating, the feel of filming, planeness and color, texture etc. can be subjected to people's more concern, interior wall coating can produce bigger influence to indoor environment, should have suitable ventilation property and water absorbability, airtight fully, nonhygroscopic filming can be caused the dewfall of metope, is unfavorable for the improvement of indoor environment and the raising of and comfortable for living.Can not contain poisonous, objectionable impurities in the interior wall coating, otherwise can work the mischief environment and health; Interior wall coating must have suitable water tolerance, alkali resistance and scrub resistance.
Chinese patent publication number CN 1035672, open day is on September 20th, 1989, name is called " swelled ground powder coating ", discloses " a kind of swelled ground powder coating that is used for the house inner wall surface decoration.Be characterized in the wilkinite being main raw material, production cost is low, and anti-xerotripsis is good, dry linting not, and manufacture method is simple and be easy to packed and transported.”
The weak point of above-mentioned patent is that to select wilkinite in this technology for use be main raw material, and normal association has impurity such as quartz, feldspar, zeolite, gypsum, calcite, pyrite, ferric oxide mineral and landwaste in the wilkinite, and bentonitic chemical ingredients of the mineral pair of these associations and processing performance influence are bigger, bentonitic colloid viscosity, dispersiveness and the suspension property of process purification are all not poor, therefore can have influence on the quality product of coating.
Summary of the invention
The objective of the invention is to overcome weak point in the prior art, a kind of attapulgite interior wall powder coating is provided.
Attapulgite interior wall powder coating is made up of Concavo-convex stick after purifying, superfine light calcium carbonate, polyvinyl alcohol ultrafine powder, quick dissolved sodium silicate, anatase thpe white powder, SOLID ORGANIC silicon defoaming agent and fluorescent whitening agent VBL.
The production method of attapulgite interior wall powder coating is: batching, pulverizing, abrasive dust, be packaged as the finished product of attapulgite interior wall powder coating.
Attapulgite clay is a kind of nanometer porous fibrous silicate clay mineral of Shuifu County's magnesium that contains, and when Attapulgite content 〉=80% in the attapulgite clay was above, its specific surface area was bigger, can reach 500m
2More than/the g.Use " Attapulgite wet beneficiation craft ", the screening of mineral such as the hydromica in the attapulgite clay, quartz, opal and carbonate is got rid of, obtain a kind of Concavo-convex stick after purifying.
Attapulgite clay soil property exquisiteness, smooth surface, quality is lighter, is viscosity and plasticity-when moist, and its viscosity can reach more than the 3000mPas, helps the bonding between the raw material; The attapulgite clay drying shrinkage is little, and do not produce be full of cracks, can improve the sticking power of interior wall powder coating to building wall, Concavo-convex stick after purifying adds in the coating solution, forms stable not stratified gelinite under external force stirs fast, and viscosity and thixotropy are preferably arranged, the Photomicrograph that attapulgite clay coating is filmed shows, its crystal is netted arrangement, is evenly distributed in the coating, so the film coated surface wear resisting property is good.
Attapulgite clay has the selection adsorptive power, as polar molecule water, ammonia, methyl alcohol, ethanol, aldehyde, ketone, alkene, hydrocarbon etc. can be absorbed by access opening, then can not enter the duct to non-polar molecule such as oxygen etc., utilize this characterization of adsorption, formaldehyde and volatile organic matter in the energy absorbed air purify air.
Superfine light calcium carbonate has exquisiteness, even, advantages such as whiteness is high, good in optical property, helps to improve the gloss and the sticking power of attapulgite paste interior wall coating.
The polyvinyl alcohol ultrafine powder has good cold water instant dissolving, excellent film-forming properties, stronger cementability and perviousness, can improve the sticking power and the crocking resistance of attapulgite interior wall powder coating, prevents to produce efflorescence, chap and peel off behind the coating application.
Quick dissolved sodium silicate can be dissolved in water fast, behind the adding attapulgite interior wall powder coating, can infiltrate in slit and the hole, and solidified silicon gel can stop up capillary porosity duct, improves the density and the intensity of coating, thereby improves the wear resistance of interior wall coating.
Anatase thpe white powder has excellent water dispersible and remarkable optical property, form and aspect stability, size-grade distribution is good, behind the adding attapulgite interior wall powder coating, characteristics with high gloss, high reducing power, high covering power help producing the colour inner wall coating of various different colours.
The SOLID ORGANIC silicon defoaming agent is to form by multiple components such as modified polyorganosiloxane, hydroxy silicon oil are composite, and outward appearance is the white powder solid particulate, have easy to use, advantage such as storing is convenient, be not afraid of high temperature and severe cold, is not subjected to environment, temperature effect, and is not perishable.
Fluorescent whitening agent VBL dissolves in 80 times the soft water, is used to improve the whitening effect of attapulgite interior wall powder coating.
The present invention is achieved by following technical proposals:
1, the batching of attapulgite interior wall powder coating is made up of following component by weight percentage: Concavo-convex stick after purifying 55～85%, superfine light calcium carbonate 5～25%, polyvinyl alcohol ultrafine powder 1～15%, quick dissolved sodium silicate 1～15%, anatase thpe white powder 0.1～5%, SOLID ORGANIC silicon defoaming agent 0.01～1% and fluorescent whitening agent VBL 0.01～1%.
Described Concavo-convex stick after purifying is: the wet beneficiation craft that uses Attapulgite, the Attapulgite ore deposit mixture that will contain earth impurity, import in the hydrolytic tank after crushed, soak after 24 hours, dash with high-pressure pump and to turn over, and the sieve of the drum by making with stainless steel steel wire sieve removes the impurity more than 1 millimeter, send in the acclive settling tank, continuation is dashed with high-pressure pump and is turned over, after 12 hours, because the proportion in Attapulgite ore deposit is lighter, its the superiors in whole throw out draws this part Attapulgite ore deposit with slush pump and sends in the flat settling tank, emits unnecessary water after 15 hours, through 2-3 days seasoning, take out this part Attapulgite and be Concavo-convex stick after purifying;
Above-mentioned technology is to adopt " the Attapulgite wet beneficiation craft " in application on September 18th, 2003 by the inventor, and the Chinese patent Granted publication number is: CN1224463, Granted publication day: on October 26th, 2005.
2, the production method of attapulgite interior wall powder coating is: after the batch mixes with attapulgite interior wall powder coating, pulverize in the input pulverizer, particle fineness after the pulverizing is less than 0.250 millimeter, carry out abrasive dust in the mixture input superfine mill after will pulverizing again, particle fineness behind the abrasive dust is packaged as the finished product of attapulgite interior wall powder coating less than 0.015 millimeter.
Using method: attapulgite interior wall powder coating is put into container, added water infiltration 0.5～2 hour, the ratio of attapulgite interior wall powder coating and water is 1: 1.5～1: 4, through after stirring, just can spray or brush.
Attapulgite interior wall powder coating sticking power is good, has weather resistance, water tolerance, rub resistance and contamination resistance preferably, and formaldehyde and volatile organic matter in the energy absorbed air purify air.
Attapulgite interior wall powder coating is a white standard paint, can directly mix colours and produce the colo(u)r coating of various different colours.
Attapulgite interior wall powder coating is applicable to decorating building.
Embodiment
The invention will be further described below in conjunction with embodiment:
1, the batching of attapulgite interior wall powder coating is made up of following component by weight percentage: Concavo-convex stick after purifying 75%, superfine light calcium carbonate 10%, polyvinyl alcohol ultrafine powder 8%, quick dissolved sodium silicate 5%, anatase thpe white powder 1.5%, SOLID ORGANIC silicon defoaming agent 0.3% and fluorescent whitening agent VBL 0.2%.
2, the production method of attapulgite interior wall powder coating is: after the batch mixes with attapulgite interior wall powder coating, pulverize in the input pulverizer, particle fineness after the pulverizing is less than 0.250 millimeter, carry out abrasive dust in the mixture input superfine mill after will pulverizing again, particle fineness behind the abrasive dust is packaged as the finished product of attapulgite interior wall powder coating less than 0.015 millimeter.
Claims (2)
1. attapulgite interior wall powder coating, it is characterized in that the batching of attapulgite interior wall powder coating is made up of following component by weight percentage: Concavo-convex stick after purifying 55～85%, superfine light calcium carbonate 5～25%, polyvinyl alcohol ultrafine powder 1～15%, quick dissolved sodium silicate 1～15%, anatase thpe white powder 0.1～5%, SOLID ORGANIC silicon defoaming agent 0.01～1% and fluorescent whitening agent VBL 0.01～1%.
2. the production method of attapulgite interior wall powder coating according to claim 1, it is characterized in that, after the batch mixes with attapulgite interior wall powder coating, pulverize in the input pulverizer, particle fineness after the pulverizing is less than 0.250 millimeter, carry out abrasive dust in the mixture input superfine mill after will pulverizing again, the particle fineness behind the abrasive dust is packaged as the finished product of attapulgite interior wall powder coating less than 0.015 millimeter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100262910A CN101585691B (en) | 2009-03-27 | 2009-03-27 | Attapulgite interior wall powder coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100262910A CN101585691B (en) | 2009-03-27 | 2009-03-27 | Attapulgite interior wall powder coating |
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| Publication Number | Publication Date |
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| CN101585691A CN101585691A (en) | 2009-11-25 |
| CN101585691B true CN101585691B (en) | 2011-06-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN2009100262910A Expired - Fee Related CN101585691B (en) | 2009-03-27 | 2009-03-27 | Attapulgite interior wall powder coating |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101973060B (en) * | 2010-07-30 | 2012-05-23 | 许庆华 | Production method of fluorescent colour attapulgite clay |
| CN104559790A (en) * | 2015-01-27 | 2015-04-29 | 海安县亚太助剂有限公司 | Building powder coating |
| CN105482516A (en) * | 2015-12-05 | 2016-04-13 | 刘传新 | Attapulgite interior wall coating drier and production method thereof |
| CN106189369A (en) * | 2016-07-11 | 2016-12-07 | 滁州格锐矿业有限责任公司 | A kind of titanium white composite powder preparation method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050009937A1 (en) * | 2003-06-16 | 2005-01-13 | Dukles Jean M. | High build coating compositions |
| CN101077951A (en) * | 2007-07-04 | 2007-11-28 | 曾技 | Environmental protection coating material with main component of attapulgite clay |
| CN101104766A (en) * | 2006-07-12 | 2008-01-16 | 上海雅达特种涂料有限公司 | Colorful coating for purifying indoor air and producing method thereof |
-
2009
- 2009-03-27 CN CN2009100262910A patent/CN101585691B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050009937A1 (en) * | 2003-06-16 | 2005-01-13 | Dukles Jean M. | High build coating compositions |
| CN101104766A (en) * | 2006-07-12 | 2008-01-16 | 上海雅达特种涂料有限公司 | Colorful coating for purifying indoor air and producing method thereof |
| CN101077951A (en) * | 2007-07-04 | 2007-11-28 | 曾技 | Environmental protection coating material with main component of attapulgite clay |
Non-Patent Citations (1)
| Title |
|---|
| 李梅.凹凸棒土在涂料中的应用.《上海涂料》.1994,(第2期),第112-114页. * |
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Owner name: JIANGSU LIWANG TECHNOLOGY CO., LTD. Effective date: 20140814 Owner name: LI WANG CHEMICAL (NANTONG) CO., LTD. Free format text: FORMER OWNER: NANTONG TONGZHOU DISTRICT PRODUCTIVITY PROMOTION CENTER Effective date: 20140814 |
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Effective date of registration: 20140814 Address after: 226300, Jiangsu province Nantong Tongzhou District Tongling bridge village 24 groups Patentee after: Liwang Chemical (Nantong) Co., Ltd. Patentee after: LIWANG (JIANGSU) CO., LTD. Address before: 226300, six floor, Xianghe Road, Jinsha Road, Jinsha Town, Nantong, Jiangsu, Tongzhou District Patentee before: Tongzhou District Nantong Productivity Promotion Center |
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Address after: 226300 the 24 groups of Tongling bridge village, Tongzhou District, Nantong, Jiangsu Co-patentee after: JIANGSU LYNWON TECHNOLOGY CO., LTD. Patentee after: Liwang Chemical (Nantong) Co., Ltd. Address before: 226300 the 24 groups of Tongling bridge village, Tongzhou District, Nantong, Jiangsu Co-patentee before: LIWANG (JIANGSU) CO., LTD. Patentee before: Liwang Chemical (Nantong) Co., Ltd. |
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Granted publication date: 20110629 Termination date: 20190327 |