CN105153830B - Nano-negative ion functional form inner-wall emulsion paint and preparation method thereof - Google Patents
Nano-negative ion functional form inner-wall emulsion paint and preparation method thereof Download PDFInfo
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Abstract
The present invention discloses a kind of nano-negative ion functional form inner-wall emulsion paint and preparation method thereof.The interiro wall latex paint includes the component of following parts by weight：120 150 parts of polymer emulsion, 35 parts of hydroxyethyl cellulose, 25 parts of Water Soluble Compound nanometer anion powder, 15 25 parts of antifreezing agent, 79 parts of coalescents, 36 parts of thickener, 35 parts of levelling agent, 180 220 parts of filler, 350 450 parts of water.The present invention is by adjusting formulation composition, add Water Soluble Compound nano-disinfection powder, with sustained release anion, purify air, the effect of improving the immunity of the human body, Water Soluble Compound nanometer anion powder therein are made up of two or more in crystal, quartz, vermiculite, medical stone, tourmaline through nano-milled.The interiro wall latex paint of the present invention is environmentally friendly, efficient, energy saving, safe, of low cost, can efficiently discharge anion, highly practical, has a extensive future.
Description
Technical field
The present invention relates to interiro wall latex paint technical field, a kind of specifically disclosed nano-negative ion functional form inner-wall emulsion paint and
Its preparation method.
Background technology
Interiro wall latex paint on the market, brand mix, and quality is uneven, and some all contains harmful thing
Matter such as heavy metal etc., and such as formaldehyde, VOC (volatile organic compounds) are discharged, these materials all can cause poison to human body
Evil, cause environment seriously to pollute.And anion is known as " air vitamin and auxin ", such as the vitamin one of food
Sample, anion have highly important actively impact to the vital movement of human body and other biological.The height of anion concentration is
Evaluate an important indicator of environment and air quality.
Existing partial monopoly technology adds anion in interior wall coating, to obtain the effect of environmental protection.Such as patent
Interiro wall latex paint in CN1673294A contains composite Nano negative ion powder, which is the silicate of nano photo-catalytic material modification
Mineral powder, its anion releasability are strong not enough.Interior wall coating in CN104059445A contains activating negative ion powder, but
It is not illustrate its composition, also its anion releasability of undetermined.Base paint is received using electric shock in CN104513572A
Rice tourmaline is used as anionic additive, and interiro wall latex paint uses nano-tourmaline slurry as anion in CN104371436A
Slurry, but the two anion raw material is larger relative to the dosage of paint, cost is higher.
Contain medical stone nano powder, silica nanometer powder, titanium dioxide in the green inner wall paint of CN103305070A
The raw materials such as nano powder, calcium carbonate superfine powder nano powder, wherein containing metal oxides raw material, and these raw material dosages compared with
Greatly, in addition the patent do not illustrate yet its discharge anion ability.Similar, what coating contained in CN102093791A receives
Silica, tourmaline and medical stone nano powder content are also larger, its anion releasability is also undisclosed.
Therefore, it is few to be badly in need of a kind of raw material additive amount for producing anion, but can efficiently discharge the inexpensive of anion
Environment protection energy-saving efficient nagative ion inner wall latex paint, the paint have poisonous and harmful gas in environmental protection, sustained release anion, purification air
Body, the effect improved the immunity of the human body.
The content of the invention
It is an object of the invention to provide a kind of nano-negative ion functional form inner-wall emulsion paint, its contain polymer emulsion and
Water Soluble Compound negative ion powder etc..The interiro wall latex paint safety and environmental protection, low cost simultaneously can continue efficiently to discharge anion.
It is another object of the present invention to provide a kind of method for preparing nano-negative ion functional form inner-wall emulsion paint.Should
Preparation method is easy to operate, can industrialization production.
The present invention provides a kind of nano-negative ion functional form inner-wall emulsion paint, it contains the component of following parts by weight：Polymerization
120-150 parts of thing lotion, 3-5 parts of hydroxyethyl cellulose, 2-5 parts of Water Soluble Compound nanometer anion powder, 15-25 parts of antifreezing agent,
7-9 parts of coalescents, 3-6 parts of thickener, 3-5 parts of levelling agent, 180-220 parts of filler, 350-450 parts of water.
Wherein, polymer emulsion can be the conventional various lotions for coating, preferably styrene-acrylic emulsion and/or pure third breast
Liquid (i.e. acrylic acid ester emulsion).Wherein styrene-acrylic emulsion particle diameter is tiny, and viscosity is suitable, paint film is hard, alkaline-resisting, scrub resistance and calcium from
The son property stablized, adhesion strength is high, and strong adhesive force, filler bearing capacity is good, and the color developing of pigment and various stability are good and good
Stability the features such as.Corresponding emulsion film chemical resistance, abrasion resistance, good leveling property, and it is more environmentally friendly.
For hydroxyethyl cellulose, it is a kind of non-ionic surfactant, has thickening, suspends, bonds, is floating
Change, film forming, scattered, water conservation and the effect that protecting colloid is provided.Its water holding capacity is higher by one times than methylcellulose, has preferable
Flow adjustment；Dispersibility dispersibility compared with generally acknowledged methylcellulose and hydroxypropyl methyl cellulose is worst, but
Protecting colloid ability is most strong；With large-scale dissolubility, viscosity characteristics, non-thermal gelation；Can be with a wide range of other interior water
Soluble polymer, surfactant, salt coexist, and are a kind of excellent colloidal thickeners of the electrolyte solution containing high concentration electric.Hydroxyl second
The hydroxyethyl cellulose of the preferred Feicheng rain field chemical industry of base cellulose.
For Water Soluble Compound nanometer anion powder, preferably, it is in crystal, quartz, vermiculite, medical stone, tourmaline
It is two or more through nano-milled manufactured nanometer grade composit powder body.
More preferably, each parts by weight of raw materials proportioning is nanometer water crystalline flour in the Water Soluble Compound nanometer anion powder：Receive
Rice silica flour：Nanometer vermiculite powder：Nano medical stone：Nano-tourmaline=0-3：1-3：0-2：1-3：1-5.
It is furthermore preferred that the particle diameter of the nano powder is 40-100nm.The particle diameter of usual nano powder is smaller, its ratio surface is got over
Greatly, the energy of its offer ion-transfer is higher, and negative ion releasing function is stronger.
Anion is the free particle in a kind of air, and if enough energy act on molecule, molecule will discharge
Go out an electronics, electronics and the molecule combination near it will form anion.Molecule is made of atom, ion, neutral.
Nano-particle have particle size is small, specific surface area is big, surface energy is high, surface atom proportion is big, provided for molecular ionization
Huge energy, therefore can constantly discharge anion.Pyroelectricity and piezoelectricity refer in the case of having temperature and pressure change
(even if small change) with regard to that can cause the electrical potential difference between component crystal, this electrostatic is up to 1,000,000 electron-volts, so that empty
Gas ionizes, and that is hit is electronically attached to neighbouring water and oxygen molecule and it is converted into negative aeroion, that is, bear from
Son.
Crystal is a kind of quartz crystals body mineral, its main chemical is silica, chemical formula SiO2.Crystal
With very strong piezoelectricity, electric charge can be produced when crystal crystal is under pressure, and ionization occurs, constantly discharges anion.
Quartzy main component is SiO2, water white transparency, has very strong piezoelectricity, can be produced when quartz crystal is under pressure
Electric charge, and ionization occurs, constantly discharge anion.
Vermiculite is a kind of natural, nontoxic mineral matter, since vermiculite has the ability of ion exchange so that molecule easily loses
Or obtain electronics and become ion, so as to discharge anion, it has air purification great effect.
Medical stone category volcanic rocks, main chemical compositions are inorganic alumino-silicates, medical stone be it is a kind of to biological nontoxic,
Harmless and the complex mineral with certain bioactivity or medicinal rock.Contain natural mineral matter and oxygen in medical stone, can be from
Discharged on medical stone in countless apertures, afterwards the continuous releasing negative oxygen ion by ionization.
Tourmaline is aluminium, sodium, iron, the nonmetallic silicate mineral of lithium cyclic structure that a kind of boracic is characterized, and has pressure
Electrically it is in the form of a column with pyroelectricity, electric crystal, aggregate is in bar-shaped, radial, small needle-shaped, also in compact massive or cryptocrystal body
Shape.Since tourmaline has unique physical and chemical performance such as piezoelectricity and pyroelectricity, anion can be produced.
Two or more natural non-metallic ores are refined into nanometer grade powder by the present invention by nano-milled production technology, are led to
Cross the compound of nanometer grade powder and prepare new type water-solubility composite Nano negative ion powder.The present invention utilizes the piezoelectricity of ore in itself
Pure natural nonmetallic mineral nano material is made in property, pyroelectricity and ion exchangeable, it is with natural, environmentally friendly, nontoxic, safe
Property, it is soluble easily in water, it can be directly appended in aqueous coating system product, not change production technology, the property of former coating after addition
Energy；The stabilising system of former coating is not influenced.And the additive amount of the Water Soluble Compound nanometer anion powder can be very low, but it is released
It is but very strong to put anion ability.
Water Soluble Compound nanometer anion powder is added in interiro wall latex paint by the present invention, and having the interiro wall latex paint can
The effect of sustained release anion, adsorbing toxic and harmful gas formaldehyde, VOC etc. in environment, so as to reach purification air, improves people
Class breathing environment, beneficial to health.
Preferably, coalescents are the environment-friendly type coalescents ester alcohol 12 that Yi Shiman Teanol are provided.The auxiliary agent is a kind of
Particularly excellent coalescing aid, is the coalescents of lotion, while is also the good solvent of polymerized emulsion, can effectively reduce polymerization
The minimum film formation temperature of lotion.The auxiliary agent has certain volatility, is trapped in film forming procedure in film and plays filming function, into
All volatilize, do not ended up in dry film after film, therefore film performance will not be influenced.It is low with the dissolubility of water, and addition uses
Do not influence the stability of polymerized emulsion afterwards, but the filming performance of film can be significantly improved, improve weatherability, the antifriction of film
Property, stain resistance and chemical resistance, while coating color developing can be improved.
The BYK-375 of the preferred Bi Ke chemistry of levelling agent, in its water-based system especially suitable for low hydrotropy agent content, with this
A little systems have good compatibility.It is reacted by its primary hydroxyl and base-material, thus is readily applicable to cross-linking type system, the levelling
Agent can promote slipping, and solvent resistant is weather-proof, few dust accumulation.Compared with the non-reactive organic silicone of standard, the auxiliary agent is due to its activity
Group is crosslinked with paint film, and above-mentioned performance can be more longlasting in coating system, hence it is evident that is reduced surface tension, while is promoted ground profit
Wet, they promote flowing and levelling again, and prevent the formation of Bei Nade whirlpools.
The preferred propane diols of antifreezing agent, its is environmentally friendly and cost-effective.The preferred Rhom and Hass's production of thickener
2020NPR non-ionic polyurethane association types, shear thickening in playing efficiently, promotes flowing levelability, there is provided good paint film is rich
Full scale.
The combination of any of the above auxiliary agent, can improve the physics and chemistry function with enhanced coating film.
Can be conventional various fillers for filler.Preferably, it is selected from precipitated calcium carbonate, powdered whiting, talcum
One or more in powder.
Preferably, the water in raw material is pure water, tap water is more containing impurity due to the addition of bleaching powder etc., may
The storage stability of interiro wall latex paint product can be caused bad.
In addition, according to nano-negative ion functional form inner-wall emulsion paint product needs of different nature, other can also be added
Material.Such as in order to obtain the product of different colours, different pigment, such as titanium dioxide (titanium dioxide), ring can be added again
Protect compound bright red slurry of yellow slurry, environment friendly inorganic in inorganic compounding etc..The wherein R- of the preferred Sichuan Long Mangtai industry Co., Ltd of titanium dioxide
996, its surface through silicon, aluminium, zirconium coating and organic process, have physiological-toxicity-free, stable chemical performance, pigment performance it is remarkable,
Whiteness, brightness, good luster, covering power, reducing power and mobility are strong.The compound middle yellow huge hair science and technology in preferred Hunan of starching of environment friendly inorganic has
The compound titanium yellow powder of limit company ready-made mill base before use.The huge hair science and technology in the preferred Hunan of the compound pigment of environment friendly inorganic has
Limit company composite titanium rouge and powder ready-made mill base before use.
Titanium dioxide (titanium dioxide) R-996 120-160 parts by weight are added again；Water 10-20 parts by weight may be constructed nanometer and bear
Ion functional form white interiro wall latex paint.
The compound titanium yellow powder 40-60 parts by weight of environment friendly inorganic are added again；Water 3-8 parts by weight may be constructed nano-negative ion function
Type yellow interiro wall latex paint.Or the directly compound middle yellow slurry 5-20 parts by weight of addition environment friendly inorganic may be constructed nano-negative ion work(
Can type yellow interiro wall latex paint.
Environment friendly inorganic composite titanium rouge and powder 40-60 parts by weight are added again；Water 3-8 parts by weight may be constructed nano-negative ion function
Type red interiro wall latex paint.Or the directly addition compound bright red slurry 5-20 parts by weight of environment friendly inorganic may be constructed nano-negative ion work(
Can type red interiro wall latex paint.
According to the length of interiro wall latex paint product use time, can choose whether to add preservative, if fruit product is one
Direct use finishes in week, can not adding preservative agent.When the construction usage phase is longer, then preservative is added, its preferred Luo Menha
The high-performance sterilization antiseptic KathonLxe of this production, it inhibits bacteria the growth with fungi during production inventory, has
Higher field of activity, can effectively inhibit bacteria (including Gram-positive, Gram-negative) mould, saccharomycete, not discharge first
Aldehyde, hypotoxicity.
The present invention also provides a kind of method for preparing above-mentioned nano-negative ion functional form inner-wall emulsion paint, this method include with
Lower step：Hydroxyethyl cellulose, water, antifreezing agent, Water Soluble Compound nanometer anion powder, filler are put into height is carried out in container
Speed stirring, be ground afterwards, to suitable fineness after be transferred to again in stainless steel, added under stirring polymer emulsion, film forming
Auxiliary agent, levelling agent and thickener.
Preferably, high-speed stirred speed is 1200-1600 rpms, and the time is 20-30 minutes；Milling apparatus is horizontal
Sand grinder；Fineness of grind≤30 μm；Mixing speed is 600-900 rpms when adding polymer emulsion, and mixing time is
5-15 minutes.
With foregoing likewise, according to the needs of final products different colours, different types of pigment can be added again.According to
The needs of product final viscosity, according to customer requirement, can add thickener and be adjusted.
Beneficial effects of the present invention have：
1st, there is good stabilization as filming emulsion, the corresponding product that paints using polymer emulsion especially styrene-acrylic emulsion
Property, abrasion resistance, alkali resistance, water resistance and color developing.
2nd, it with the addition of Water Soluble Compound nanometer anion powder in raw material, it is free of heavy metal, will not produce radiation, environmental protection
It is safe and non-toxic；And its additive amount is low, it can but continue efficiently to discharge anion, Water Soluble Compound nano-negative ion powder purity can be with
Reach 99%, sterling highest anion burst size is 80,000 ion/cc.Test by long-term research practice, received in end product
For the additive amount of rice negative ion powder 0.1% with regard to that can reach sustained release anion, the anion burst size of end products reaches state
4000-5000/the cm that border expert recommends3Optimum efficiency concentration.I.e. the Water Soluble Compound nano-negative ion mealiness is not only pacified
Loopful is protected, and cost performance is very high.
3rd, can be by adding different auxiliary agents, to obtain the interiro wall latex paint product of different performance.Product category is enriched,
It is widely used, and the preparation process of interiro wall latex paint is also simple, it is of low cost, can industrialization production.
4th, the cosolvent containing volatile organic compounds is not added in product formula design, without harmful weight
Metal, product can reach zero VOC, have the good feature of environmental protection.
Embodiment
The present invention can be further well understood by the specific embodiment of invention now given below, but they are not
Limitation of the invention.The part for not having to describe in detail in specific embodiment is to use the prior art, known technology means and row
What industry standard obtained.
Unless otherwise indicated, the number employed in the present invention is parts by weight.
Specific proportioning composition, the particle diameter of Water Soluble Compound nanometer anion powder are as shown in table 1 in each embodiment.
1 Water Soluble Compound nanometer anion powder formula of table and particle diameter
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Nanometer water crystalline flour | 1 | — | 2 | 3 |
| Nanometer silica flour | 2 | 3 | 1 | 1 |
| Nanometer vermiculite powder | 1 | — | 2 | 1 |
| Nano medical stone | 2 | 3 | 1 | 2 |
| Nano-tourmaline | 4 | 4 | 5 | 1 |
| Particle diameter (average, nm) | 50 | 80 | 100 | 40 |
Embodiment 1
Nano-negative ion functional form white interiro wall latex paint is prepared by formulation weight part of table 2, is comprised the following steps：
A) raw material is equipped with according to the parts by weight of formula setting, by hydroxyethyl cellulose, pure water, antifreezing agent, titanium dioxide, water
Dissolubility composite Nano negative ion powder, filler, put into 1400~1600 rpms of container high speed stirring successively, stirs evenly it
It is ground on horizontal sand mill, after being ground to fineness≤30 μm, then is transferred in stainless steel afterwards, rotating speed is reduced to 800 turns
It is per minute, polymer emulsion, coalescents, levelling agent are added, thickener is added and is adjusted to viscosity needed for client.
B) detection-filtering-is packed-kept sample.
Embodiment 2
The adjustment of the Example formulations ratio refers to table 2, and specific implementation process is substantially the same manner as Example 1, and difference only exists
It it is 1200-1400 rpms in high-speed stirred speed, mixing time is 30 minutes.
Embodiment 3
The adjustment of the Example formulations ratio refers to table 2, and specific implementation process is substantially the same manner as Example 1, and difference only exists
It it is 1200-1400 rpms in high-speed stirred speed, mixing time is 15 minutes.
Embodiment 4
The adjustment of the Example formulations ratio refers to table 2, and specific implementation process is substantially the same manner as Example 1.
2 nano-negative ion functional form inner-wall latex paint formulation of table
The nano-negative ion functional form inner-wall emulsion paint of above-mentioned preparation, according to standard GB/T/T 9756-2009《Synthesis
Resin emulsion interior wall coating》With HG/T 4109-2009 anion function coating, the detection of technical performance, detection knot are carried out to it
Fruit is shown in Table 3.
3 nano-negative ion functional form inner-wall emulsion paint the performance test results of table
It is above disclosed to be merely a preferred embodiment of the present invention, the right of the present invention cannot be limited with this certainly
Scope, therefore the equivalent variations made according to scope of the present invention patent, are still within the scope of the present invention.
Claims (7)
- A kind of 1. nano-negative ion functional form inner-wall emulsion paint, it is characterised in that：Include the component of following parts by weight：Polymer breast 120-150 parts of liquid, 3-5 parts of hydroxyethyl cellulose, 2-5 parts of Water Soluble Compound nanometer anion powder, 15-25 parts of antifreezing agent, film forming 350-450 parts of 7-9 parts of auxiliary agent, 3-6 parts of thickener, 3-5 parts of levelling agent, 180-220 parts of filler and water；The polymer emulsion For styrene-acrylic emulsion and/or pure-acrylic emulsion, each parts by weight of raw materials proportioning of the Water Soluble Compound nanometer anion powder is nanometer water Crystalline flour：Nanometer silica flour：Nanometer vermiculite powder：Nano medical stone：Nano-tourmaline=0-3：1-3：0-2：1-3：1-5.
- 2. nano-negative ion functional form inner-wall emulsion paint according to claim 1, it is characterised in that：The Water Soluble Compound The particle diameter of nanometer anion powder is 40-100nm.
- 3. nano-negative ion functional form inner-wall emulsion paint according to claim 1, it is characterised in that：The filler is selected from light One or more in matter calcium carbonate, powdered whiting, talcum powder.
- 4. nano-negative ion functional form inner-wall emulsion paint according to any one of claims 1 to 3, it is characterised in that：Also wrap Include the pigment selected from titanium dioxide, the compound middle yellow slurry of environment friendly inorganic or the compound bright red slurry of environment friendly inorganic.
- 5. nano-negative ion functional form inner-wall emulsion paint according to claim 4, it is characterised in that：The titanium dioxide is 120-160 parts by weight, the compound middle yellow slurry of environment friendly inorganic are 5-20 parts by weight, and the compound bright red slurry of environment friendly inorganic is 5-20 parts by weight.
- 6. the preparation method of nano-negative ion functional form inner-wall emulsion paint according to any one of claims 1 to 5, its feature It is：Comprise the following steps：Hydroxyethyl cellulose, water, antifreezing agent, Water Soluble Compound nanometer anion powder, filler are put into High-speed stirred is carried out in container, is ground afterwards, to suitable fineness after be transferred to again in stainless steel, polymerization is added under stirring Thing lotion, coalescents, levelling agent and thickener.
- 7. according to the preparation method described in claim 6, it is characterised in that：High-speed stirred speed is 1200-1600 revolutions per minute Clock, time are 20-30 minutes；Milling apparatus is Horizontal sand grinder；Fineness of grind≤30 μm；Stirred when adding polymer emulsion Speed is 600-900 rpms, and mixing time is 5-15 minutes.
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Address after: 363601 Nanjing hi tech Industrial Park, Zhangzhou, Fujian, China Applicant after: ZHANGZHOU SANDELI PAINT & COATING CO., LTD. Applicant after: Shandong three environmental protection materials Limited by Share Ltd Address before: 363601 Nanjing hi tech Industrial Park, Zhangzhou, Fujian, China Applicant before: ZHANGZHOU SANDELI PAINT & COATING CO., LTD. Applicant before: SHANDONG SANDELI COATING CO., LTD. |
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