CN105153830A - Nanometer-anion functional interior-wall latex paint and preparing method thereof - Google Patents
Nanometer-anion functional interior-wall latex paint and preparing method thereof Download PDFInfo
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Abstract
The invention discloses nanometer-anion functional interior-wall latex paint and a preparing method thereof. The interior-wall latex paint is prepared from, by weight, 120 parts to 150 parts of polymer emulsion, 3 parts to 5 parts of hydroxyethyl cellulose, 2 parts to 5 parts of water-soluble compound nanometer anion powder, 15 parts to 25 parts of antifreezing agents, 7 parts to 9 parts of film forming assistants, 3 parts to 6 parts of thickening agents, 3 parts to 5 parts of flatting agents, 180 parts to 220 parts of packing and 350 parts to 450 parts of water. According to the nanometer-anion functional interior-wall latex paint and the preparing method, as a formula structure is adjusted, and the water-soluble compound nanometer sterilizing powder is added, the interior-wall latex paint has the effects of continuously releasing anions, purifying air and improving body immunity, wherein the water-soluble compound nanometer anion powder is prepared in the mode that nanometer grinding is carried out on two or more kinds of crystals, quartz, vermiculite, medical stone and tourmaline. The interior-wall latex paint is environmentally friendly, efficient, safe, low in cost, high in practicability and broad in application prospect, energy is saved, and the anions can be efficiently released.
Description
Technical field
The present invention relates to interiro wall latex paint technical field, disclose a kind of nano-negative ion functional form inner-wall emulsion paint and preparation method thereof especially.
Background technology
The interiro wall latex paint that market is sold, brand mixes, and quality is uneven, and what have all contains harmful material as heavy metal etc., and discharge as formaldehyde, VOC (volatile organic compounds) etc., these materials all can cause murder by poisoning, cause severe contamination to environment human body.And negative ion is described as " air VITAMIN and growth hormone ", as the VITAMIN of food, the vital movement of negative ion on human body and other biological has very important positive impact.The height of anion concentration is the important indicator evaluating environment and Air quality.
Existing partial monopoly technology adds negative ion, to obtain the effect of environmental protection in interior wall coating.Such as, interiro wall latex paint in patent CN1673294A contains composite Nano negative ion powder, and this powder is the silicate minerals powder of nano photo-catalytic material modification, and its negative ion releasability is strong not enough.Interior wall coating in CN104059445A contains activating negative ion powder, but does not illustrate its composition, also its negative ion releasability of undetermined.In CN104513572A, base paint adopts electric shock nano-tourmaline as anionic additive, and in CN104371436A, interiro wall latex paint adopts nano-tourmaline slurry to starch as negative ion, but the two negative ion raw material is relative to the large usage quantity of paint, and cost is higher.
Containing raw materials such as medical stone nano powder, silica nanometer powder, titanic oxide nano, calcium carbonate superfine powder nano powders in the green inner wall paint of CN103305070A, wherein containing metal oxides raw material, and these raw material dosage are comparatively large, and this patent does not illustrate the ability of its anion releasing yet in addition.Similar, what in CN102093791A, coating contained receives silicon-dioxide, tourmalinite and medical stone nano powder content also comparatively greatly, and its negative ion releasability is also unexposed.
Therefore, be badly in need of a kind of raw material addition producing negative ion few, but the environment protection energy-saving efficient nagative ion inner wall latex paint of the low cost of the efficient anion releasing of energy, this paint has the effect of environmental protection, sustained release negative ion, the middle toxic and harmful that purifies air, raising body immunity.
Summary of the invention
The object of the present invention is to provide a kind of nano-negative ion functional form inner-wall emulsion paint, it contains polymer emulsion and Water Soluble Compound negative ion powder etc.This interiro wall latex paint safety and environmental protection, low cost also can continue efficient anion releasing.
Another object of the present invention is to provide a kind of method preparing nano-negative ion functional form inner-wall emulsion paint.This preparation method is simple to operate, can industrialization produce.
The invention provides a kind of plant sterilization function for expelling pests type interiro wall latex paint, it is containing, for example the component of lower weight part: polymer emulsion 120-150 part, Natvosol 3-5 part, Water Soluble Compound nanometer anion powder 2-5 part, frostproofer 15-25 part, film coalescence aid 7-9 part, thickening material 3-6 part, flow agent 3-5 part, filler 180-220 part, water 350-450 part.
Wherein, polymer emulsion can be the conventional various emulsions for coating, preferred benzene emulsion and/or pure-acrylic emulsion (i.e. acrylic ester emulsion).Wherein benzene emulsion particle diameter is tiny, and viscosity is suitable for, and paint film is hard, alkaline-resisting, scrub resistance and the calcium ion property stablized, and cohesive strength is high, strong adhesion, and filler bearing capacity is good, the color developing of pigment and the feature such as various good stability and satisfactory stability.Corresponding emulsion film chemical resistant properties, abrasion resistance, good leveling property, and comparatively environmental protection.
For Natvosol, it is a kind of tensio-active agent of non-ionic type, has thickening, suspension, bonding, floatingization, film forming, dispersion, water conservation and provides the effect of protective colloid.Its water retention capacity exceeds one times than methylcellulose gum, has good flow adjustment; It is the poorest that dispersive ability and the methylcellulose gum of generally acknowledging and Vltra tears compare dispersive ability, but protective colloid ability is the strongest; There is large-scale solvability, viscosity characteristics, non-thermal gelation; Can coexist with other interior on a large scale water-soluble polymerss, tensio-active agent, salt, be a kind of excellent colloidal thickener containing high density electrolyte solution.The Natvosol of rain field, Natvosol preferred Feicheng chemical industry.
For Water Soluble Compound nanometer anion powder, preferably, its be crystal, two or more through the nano-milled nanometer grade composit powder body made in quartz, vermiculite, medical stone, tourmalinite.
Better, in described Water Soluble Compound nanometer anion powder, each parts by weight of raw materials proportioning is nanometer water crystalline flour: nanometer silica powder: nanometer vermiculite powder: nano medical stone: nano-tourmaline=0-3:1-3:0-2:1-3:1-5.
Preferred, the particle diameter of described nano powder is 40-100nm.The particle diameter of usual nano powder is less, and its specific surface is larger, and it provides the energy of ion-transfer higher, and negative ion releasing function is stronger.
Negative ion is the free particle in a kind of air, if having enough energy in molecule, molecule will discharge an electronics, and electronics and the molecule near it combine and will form negative ion.Molecule is made up of atom, ion, neutral.Nanoparticle has that particle size is little, specific surface area is large, surface energy is high, surface atom proportion is large, for molecular ionization provides huge energy, and therefore can continuous anion releasing.When pyroelectricity and piezoelectricity refer to that temperature and pressure changes (even if small change) just can cause the potential difference between composition crystal, this electrostatic is up to 1,000,000 electron-volts, thus air is ionized, be electronically attached to contiguous water and oxygen molecule and make it be converted into negative aeroion by what hit, be i.e. negative ion.
Crystal is a kind of quartz crystals body mineral, and its main chemical is silicon-dioxide, and chemical formula is SiO
2.Crystal has very strong piezoelectricity, can produce electric charge, and ionizing event occurs when crystal crystal is under pressure, continuous anion releasing.
Quartz main component is SiO
2, water white transparency, has very strong piezoelectricity, can produce electric charge, and ionizing event occurs when quartz crystal is under pressure, continuous anion releasing.
Vermiculite is a kind of natural, nontoxic mineral substance, because vermiculite has the ability of ion-exchange, molecule is very easily lost or obtains electronics and become ion, thus anion releasing, it has great effect to purifying air.
Medical stone belongs to volcanic rocks, and main chemical compositions is inorganic silico-aluminate, and medical stone is a kind of to biological nontoxic, harmless and have certain bioactive composite minerals or medicinal rock.Contain natural mineral matter and oxygen in medical stone, discharge in aperture that can be countless from medical stone, the continuous releasing negative oxygen ion through ionizing event afterwards.
The nonmetal silicate minerals of the aluminium of tourmalinite to be a kind of boracic be feature, sodium, iron, lithium ring texture, have piezoelectricity and pyroelectricity, electric crystal is column, and aggregate is bar-shaped, radial, little needle-like, also in compact mass or hidden lenticular.Because tourmalinite has unique physical and chemical performance such as piezoelectricity and pyroelectricity, therefore negative ion can be produced.
The present invention is refined into nanometer grade powder by nano-milled production technology two or more natural non-metallic ore, has prepared new type water-solubility nanometer anion powder by the compound of nanometer grade powder.The present invention utilizes the piezoelectricity of ore itself, pyroelectricity and ion exchangeable to make pure natural non-metallic minerals nano material, it has natural, environmental protection, nontoxic, security, soluble in water, directly can add in aqueous coating system product, after interpolation, not change the production technique of former coating, performance; Do not affect the stabilising system of former coating.And the addition of this water-soluble nano negative ion powder can be very low, but its anion releasing ability is very strong.
Water Soluble Compound nanometer anion powder joins in interiro wall latex paint by the present invention, this interiro wall latex paint is made to have effect of sustainable anion releasing, adsorb toxic and harmful formaldehyde, VOC etc. in environment thus reach and purify air, improve human breathing environment, useful HUMAN HEALTH.
Preferably, the environment-friendly type film coalescence aid ester alcohol 12 that provides for Yi Shiman Teanol of film coalescence aid.This auxiliary agent is a kind of coalescing aid excellent especially, is the film coalescence aid of emulsion, is also the good solvent of polymerized emulsion simultaneously, effectively can reduces the minimum film-forming temperature of polymerized emulsion.This auxiliary agent has certain volatility, is trapped in film and plays filming function, all volatilize after film forming in film process, does not remain in dry film, therefore also can not affect film performance.The solvability of itself and water is low, adds the stability not affecting polymerized emulsion after using, but can significantly improve the film forming properties of film, improve the weathering resistance of film, wear resistance, stain resistance and chemical resistant properties, can improve coating color developing simultaneously.
The BYK-375 of the preferred Bi Ke chemistry of flow agent, it is specially adapted to, in the water-based system of low solubility promoter content, to have good consistency with these systems.It is reacted by its primary hydroxyl and base-material, and be thus applicable to very much cross-linking type system, this flow agent can promote slipping, and solvent resistant is weather-proof, few laying dust.Compared with the non-reactive organic silicone of standard, this auxiliary agent is cross-linked due to its active group and paint film, and above-mentioned performance can be more lasting in coating system, obvious reduction surface tension, promote ground to soak, they promote again flowing and levelling, and prevent the formation of Bei Nade whirlpool simultaneously.
The preferred propylene glycol of frostproofer, its environmental protection and cost performance is high.The 2020NPR non-ionic polyurethane association type that the preferred Rhom and Hass of thickening material produces, plays efficient middle shear thickening, promotes flow levelling, provide good paint film fullness ratio.
The combination of various auxiliary agent above, can improve the physics and chemistry function with enhanced coating film.
For filler, can be conventional various fillers.Preferably, it is selected from one or more in light calcium carbonate, water-ground limestone, talcum powder.
Preferably, the water in raw material is pure water, and tap water is owing to the addition of chlorinated lime etc., more containing impurity, and the stability in storage of interiro wall latex paint product may be caused not good.
In addition, according to nano-negative ion functional form inner-wall emulsion paint product needs of different nature, other materials can also be added.Such as in order to obtain the product of different colours, different pigment can be added again, such as, in titanium dioxide (titanium dioxide), environment friendly inorganic compound yellow slurry, the bright red slurry of environment friendly inorganic compound etc.The wherein R-996 of titanium dioxide preferred Sichuan Long Mangtai industry company limited, its surface, through silicon, aluminium, zirconium coating and organic process, has without physiological-toxicity, stable chemical performance, pigment performance brilliance, whiteness, brightness, good luster, opacifying power, reducing power and mobility strong.The preferred Hunan Ju Fa Science and Technology Ltd. composite titanium bloom of yellow slurry ready-made mill base before use in environment friendly inorganic compound.Environment friendly inorganic compound pigment preferred Hunan Ju Fa Science and Technology Ltd. composite titanium rouge and powder ready-made mill base before use.
Add titanium dioxide (titanium dioxide) R-996120-160 weight part again; Water 10-20 weight part can form nano-negative ion functional type white interiro wall latex paint.
Add environment friendly inorganic composite titanium bloom 40-60 weight part again; Water 3-8 weight part can form the yellow interiro wall latex paint of nano-negative ion functional type.Or directly add yellow slurry 5-20 weight part in environment friendly inorganic compound and can form the yellow interiro wall latex paint of nano-negative ion functional type.
Add environment friendly inorganic composite titanium rouge and powder 40-60 weight part again; Water 3-8 weight part can form the red interiro wall latex paint of nano-negative ion functional type.Or directly add environment friendly inorganic compound bright red slurry 5-20 weight part and can form the red interiro wall latex paint of nano-negative ion functional type.
According to the length of interiro wall latex paint product duration of service, can select whether to add sanitas, as fruit product was directly finished using in one week, can not adding preservative agent.When the construction usage phase is longer, then add sanitas, the high-performance fungicidal preservative KathonLxe that its preferred ROHM AND HAAS is produced, its the growing of anti-bacteria and fungi in production inventory process, there is higher field of activity, can effectively anti-bacteria (comprising Gram-positive, Gram-negative) mould, yeast, not release formaldehyde, hypotoxicity.
The present invention also provides a kind of method preparing above-mentioned nano-negative ion functional form inner-wall emulsion paint, the method comprises the following steps: Natvosol, water, frostproofer, Water Soluble Compound nanometer anion powder, filler are put in container and carry out high-speed stirring, grind afterwards, proceed to again in mixing vessel to suitable fineness, under stirring, add polymer emulsion, film coalescence aid, flow agent and thickening material again.
Preferably, high-speed stirring speed is 1200-1600 rpm, and the time is 20-30 minute; Grinding plant is Horizontal sand shredder; Mesh-of-grind≤30 μm; When adding polymer emulsion, stirring velocity is 600-900 rpm, and churning time is 5-15 minute.
Same with aforementioned, according to the needs of the finished product different colours, different types of pigment can be added again.According to the needs of product final viscosity, according to customer requirement, thickening material adjustment can be added again.
Beneficial effect of the present invention has:
1, especially benzene emulsion is as filming emulsion to adopt polymer emulsion, and corresponding paint product has satisfactory stability, abrasion resistance, alkali resistance, water tolerance and color developing.
2, with the addition of water-soluble nano negative ion powder in raw material, it is not containing heavy metal, and also can not produce radiation, Environmental Safety is nontoxic; And its addition is low, but can continue efficient anion releasing, water-soluble nano negative ion powder purity can reach 99%, and the most high-negative ion burst size of sterling is 80,000 ion/cc.Through the test of long-term research practice, in end product, the addition of nanometer anion powder just can reach sustained release negative ion 0.1%, and the negative ion burst size of end products reaches 4000-5000/cm of international expert recommendation
3best effect concentration.I.e. this water-soluble nano negative ion mealiness not only safety and environmental protection, and cost performance is very high.
3, by adding different auxiliary agents, the interiro wall latex paint product of different performance can be obtained.Product category is enriched, and is widely used, and the preparation technology of interiro wall latex paint is also simple, with low cost, can industrialization produce.
4, do not add the solubility promoter containing volatile organic compounds in formula for a product design, not containing harmful heavy metal, product can reach zero VOC, has the good feature of environmental protection.
Embodiment
Can be well understood to the present invention further by specific embodiments of the invention given below, but they not limitation of the invention.The part do not described in detail in specific embodiment adopts prior art, known technology means and industry standard to obtain.
Except as otherwise noted, the number adopted in the present invention is weight part.
The concrete proportioning composition of Water Soluble Compound nanometer anion powder in each embodiment, particle diameter are as shown in table 1.
Table 1 Water Soluble Compound nanometer anion powder formula and particle diameter
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Nanometer water crystalline flour | 1 | — | 2 | 3 |
| Nanometer silica powder | 2 | 3 | 1 | 1 |
| Nanometer vermiculite powder | 1 | — | 2 | 1 |
| Nano medical stone | 2 | 3 | 1 | 2 |
| Nano-tourmaline | 4 | 4 | 5 | 1 |
| Particle diameter (average, nm) | 50 | 80 | 100 | 40 |
embodiment 1
Prepare nano-negative ion functional type white interiro wall latex paint by formulation weight part of table 2, comprise the following steps:
A) raw material is equipped with according to the weight part of formula setting, by Natvosol, pure water, frostproofer, titanium dioxide, water-soluble nano negative ion powder, filler, drop into container high speed stirring 1400 ~ 1600 rpms successively, grind on horizontal sand mill after stirring, after being ground to fineness≤30 μm, proceed to again in mixing vessel, rotating speed is reduced to 800 rpms, adds polymer emulsion, film coalescence aid, flow agent, adds thickening material and adjusts to viscosity needed for client.
B) detect-filter-pack-keep sample.
embodiment 2
The adjustment of this Example formulations ratio refers to table 2, and specific implementation process is substantially the same manner as Example 1, and difference is only that high-speed stirring speed is 1200-1400 rpm, and churning time is 30 minutes.
embodiment 3
The adjustment of this Example formulations ratio refers to table 2, and specific implementation process is substantially the same manner as Example 1, and difference is only that high-speed stirring speed is 1200-1400 rpm, and churning time is 15 minutes.
embodiment 4
The adjustment of this Example formulations ratio refers to table 2, and specific implementation process is substantially the same manner as Example 1.
Table 2 nano-negative ion functional form inner-wall latex paint formulation
The nano-negative ion functional form inner-wall emulsion paint of above-mentioned preparation, according to standard GB/T/T9756-2009 " resin latex dope " and HG/T4109-2009 anion function coating, it is carried out to the detection of technical feature, detected result is in table 3.
Table 3 plant sterilization function for expelling pests type interiro wall latex paint the performance test results
Above disclosedly be only the preferred embodiments of the present invention, certainly can not limit the interest field of the present invention with this, therefore according to the equivalent variations that the present patent application the scope of the claims is done, still belong to the scope that the present invention is contained.
Claims (9)
1. a nano-negative ion functional form inner-wall emulsion paint, is characterized in that: the component comprising following weight part: polymer emulsion 120-150 part, Natvosol 3-5 part, Water Soluble Compound nanometer anion powder 2-5 part, frostproofer 15-25 part, film coalescence aid 7-9 part, thickening material 3-6 part, flow agent 3-5 part, filler 180-220 part and water 350-450 part.
2. the functional form inner-wall emulsion paint of nano-negative ion according to claim 1, is characterized in that: described polymer emulsion is benzene emulsion and/or pure-acrylic emulsion.
3. nano-negative ion functional form inner-wall emulsion paint according to claim 1, is characterized in that: described Water Soluble Compound nanometer anion powder is crystal, two or more in quartz, vermiculite, medical stone, tourmalinite be through the nano-milled nanometer grade composit powder body made.
4. nano-negative ion functional form inner-wall emulsion paint according to claim 3, is characterized in that: in described Water Soluble Compound nanometer anion powder, each parts by weight of raw materials proportioning is nanometer water crystalline flour: nanometer silica powder: nanometer vermiculite powder: nano medical stone: nano-tourmaline=0-3:1-3:0-2:1-3:1-5; The particle diameter of described nano powder is 40-100nm.
5. nano-negative ion functional form inner-wall emulsion paint according to claim 1, is characterized in that: described filler be selected from light calcium carbonate, water-ground limestone, talcum powder one or more.
6. the nano-negative ion functional form inner-wall emulsion paint according to any one of claim 1 to 5, is characterized in that: also comprise the pigment being selected from yellow slurry or the bright red slurry of environment friendly inorganic compound in titanium dioxide, environment friendly inorganic compound.
7. nano-negative ion functional form inner-wall emulsion paint according to claim 6, is characterized in that: described titanium dioxide is 120-160 weight part, and in environment friendly inorganic compound, yellow slurry is 5-20 weight part, and the bright red slurry of environment friendly inorganic compound is 5-20 weight part.
8. the preparation method of the nano-negative ion functional form inner-wall emulsion paint according to any one of claim 1 to 7, it is characterized in that: comprise the following steps: Natvosol, water, frostproofer, Water Soluble Compound nanometer anion powder, filler are put in container and carried out high-speed stirring, grind afterwards, proceed to again in mixing vessel to suitable fineness, under stirring, add polymer emulsion, film coalescence aid, flow agent and thickening material again.
9. according to Claim 8 described in preparation method, it is characterized in that: high-speed stirring speed is 1200-1600 rpm, the time is 20-30 minute; Grinding plant is Horizontal sand shredder; Mesh-of-grind≤30 μm; When adding polymer emulsion, stirring velocity is 600-900 rpm, and churning time is 5-15 minute.
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| CN106398407A (en) * | 2016-10-08 | 2017-02-15 | 深圳市富粤新材料有限公司 | Base material of negative ion antimicrobial coating and preparation method thereof |
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| CN109553959A (en) * | 2018-12-07 | 2019-04-02 | 青岛福离子环保科技有限公司 | A kind of production method and application of negative oxygen ion triggering agent |
| CN109553959B (en) * | 2018-12-07 | 2020-12-22 | 青岛福离子环保科技有限公司 | Preparation method and application of negative oxygen ion trigger |
| CN110240880A (en) * | 2019-05-22 | 2019-09-17 | 广州和新实业有限公司 | It is a kind of to discharge nail-free glue of anion and preparation method thereof |
| CN113969087A (en) * | 2021-10-11 | 2022-01-25 | 安徽朗凯奇防水科技股份有限公司 | Nano negative ion interior wall latex paint and preparation method thereof |
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